EP3294476A2 - Procédé de coulage et moule en sable pourvu d'un système d'admission pour produire des pièces coulées en aluminium à parois au moins partiellement minces avec la technologie de moulage au sable au moyen d'un coulage par gravité - Google Patents

Procédé de coulage et moule en sable pourvu d'un système d'admission pour produire des pièces coulées en aluminium à parois au moins partiellement minces avec la technologie de moulage au sable au moyen d'un coulage par gravité

Info

Publication number
EP3294476A2
EP3294476A2 EP16774976.1A EP16774976A EP3294476A2 EP 3294476 A2 EP3294476 A2 EP 3294476A2 EP 16774976 A EP16774976 A EP 16774976A EP 3294476 A2 EP3294476 A2 EP 3294476A2
Authority
EP
European Patent Office
Prior art keywords
casting
mould
sand
sand mould
gating system
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP16774976.1A
Other languages
German (de)
English (en)
Other versions
EP3294476B1 (fr
EP3294476B2 (fr
Inventor
Gergely HAJAS
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Alu-Oentoe Kft
Original Assignee
Alu Oentoe Kft
Alu-Onto Kft
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Alu Oentoe Kft, Alu-Onto Kft filed Critical Alu Oentoe Kft
Publication of EP3294476A2 publication Critical patent/EP3294476A2/fr
Publication of EP3294476B1 publication Critical patent/EP3294476B1/fr
Application granted granted Critical
Publication of EP3294476B2 publication Critical patent/EP3294476B2/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C9/00Moulds or cores; Moulding processes
    • B22C9/08Features with respect to supply of molten metal, e.g. ingates, circular gates, skim gates
    • B22C9/082Sprues, pouring cups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D21/00Casting non-ferrous metals or metallic compounds so far as their metallurgical properties are of importance for the casting procedure; Selection of compositions therefor
    • B22D21/02Casting exceedingly oxidisable non-ferrous metals, e.g. in inert atmosphere
    • B22D21/04Casting aluminium or magnesium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C9/00Moulds or cores; Moulding processes
    • B22C9/02Sand moulds or like moulds for shaped castings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C9/00Moulds or cores; Moulding processes
    • B22C9/12Treating moulds or cores, e.g. drying, hardening
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D15/00Casting using a mould or core of which a part significant to the process is of high thermal conductivity, e.g. chill casting; Moulds or accessories specially adapted therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D15/00Casting using a mould or core of which a part significant to the process is of high thermal conductivity, e.g. chill casting; Moulds or accessories specially adapted therefor
    • B22D15/04Machines or apparatus for chill casting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D21/00Casting non-ferrous metals or metallic compounds so far as their metallurgical properties are of importance for the casting procedure; Selection of compositions therefor
    • B22D21/002Castings of light metals
    • B22D21/007Castings of light metals with low melting point, e.g. Al 659 degrees C, Mg 650 degrees C
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D25/00Special casting characterised by the nature of the product
    • B22D25/02Special casting characterised by the nature of the product by its peculiarity of shape; of works of art
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D27/00Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
    • B22D27/04Influencing the temperature of the metal, e.g. by heating or cooling the mould

Definitions

  • the subject of the invention is a casting process to produce at least partly thin-walled aluminium castings by gravity casting and with sand moulding technology.
  • the wall thickness of the thin-walled part is 1 -3 mm.
  • a further subject of the invention is a sand mould and an inlet system (gating system), which will allow manufacturing cast parts of this nature.
  • sand moulding techniques have been applied for a long time.
  • the basic principle behind this technology is that a die cavity adjusted to the casting's geometry is made from suitable moulding sand. This cavity is then poured with molten aluminium according to the required temperature and other casting conditions. The moulding sand will then be removed from the solidified casting, which will be used for the specific purpose.
  • the sand moulding technology offers the benefit of producing the sand mould in a relatively simple way; its drawback, however, is that a new sand mould is needed for each casting procedure, which requires producing a sand mould for every single casting, thus the mould cannot be reused.
  • the method to be applied in producing thin-walled castings of large surfaces is the high-pressure die casting process, in which the molten metal is fed by means of a pressure casting machine in a short period of time (0.01 -0.05 s) and at an extremely high flow rate (20-80 m/s in the conduit) into the cavity of the cooled (cooled in a cooling system to 150-250 °C) where during the solidification process extremely high pressure (500-1500 bar) is applied.
  • the casting machine and the casting mould are complex and costly, which makes them cost-effective only if large series of castings (several ten or hundred thousands, depending on the casting mass) are manufactured.
  • CN 1709612 Chinese patent description provides information on the process of manufacturing super-thin walled aluminium casts by means of high speed pressure. This process includes the following steps: a model casting mould is fitted into the die-casting machine then the parameters of die-casting are set. The casting pressure is 780 kg/cm 2 , the temperature of the model casting mould is set to 250°C, the dissolvent temperature is 700°C, then the alumina alloy is injected into the die- casting machine. In order to achieve smaller than 1 .0 mm wall thickness, 0.23 m/sec injection speed is applied. This is followed by removing the cast, which will be tested if it fulfils the international patent requirements. A casting produced in this way can primarily be applied in 3C products, such as for computer frames, digital cameras and mobile phones.
  • the conventional sand moulding technology and the pressure technology greatly differ from each other.
  • the conventional sand moulding technology is a complicated procedure, consisting of several steps, compared to high-pressure casting, in which almost the complete manufacturing process is performed by machines in order to achieve high manufacturing series.
  • Modelling has two different methods. One of them is virtual modelling, which is made by most foundries applying pressure die casting. A program related to the given technical parameters models the casting process and highlights the expected difficulties of casting. This method offers the advantage of quickness, but its drawback is that it will not provide evidence of the behaviour of the mould in real operating conditions.
  • the other modelling process is sand casting, which means that the actual casting is produced by a sand casting foundry.
  • the casting produced with this method is like the original one as regards its geometry and structure.
  • the piece allows measurements, helps design the technology, and draws the attention to the technological demand (e.g. running and feeding systems, etc.)
  • a given product or casting has basic properties that determine the technology to be applied; these are as follows: expected annual product number, dimensions, raw material, geometry, weight, and prescribed mechanical properties.
  • test manufacture Once the customer has decided to employ test manufacture, he has the choice between two ways. One of them is to order the product with testing according to the final technology, which (concerning our case) is basically pressure die casting. The customer orders the pressure die and the casting technology, and waits for it to be prepared. Once the die has been produced, test casting is ordered, and providing it is based on a drawing or a model, the testing phase will be started.
  • This method is time consuming and costly, and includes a lot of uncertainties and risks on the customer's part until the test results meet the requirements.
  • the cast produced in this way will ensure safe and quick testing and assembly according to the customer's demand, provides possibility for the introduction to the market, provides low level of producing costs (related to the cost level of pressure die-casting technology); what is even more important, it ensures quick and cost-effective modification and execution of possible design faults.
  • This process allows the developer-customer to provide such safe products for mass production, which will not carry technical and design risks and can be adjusted to market competition as related to both quickness and cost efficiency.
  • the objective of developing the process applied in the invention is to establish such a casting process, which is suitable for producing articulated, thin- walled aluminium casts by means of gravity sand mould casting supposing 1 -3 mm wall thickness and 200-400 times larger sizes are provided.
  • the process applied in the invention allows manufacturing larger sized cast parts as compared to the well-known process of gravity die casting.
  • the process is suitable for manufacturing cast parts, which can be applied in practice.
  • the products are mainly indoor and outdoor luminaires, engine parts - spare parts, cylinder-heads, machine components, spare parts for mechanical and precision engineering, fittings, etc. All these products can be produced through this invention in such quality that they will be suited for practical application under operational conditions. This will result in cost-effective development and more effective testing before the manufacture on large scale starts. Aluminium casts for different purposes are to be produced with this process economically, on small to medium scale, even in several hundred items.
  • This process enables manufacturing larger sized cast parts at a much lower cost - in contrast to pressure casting - which will appear in the initial die cost and production time.
  • the subject of the invention is the process included in item 1 of the patent claim and the sand mould fitted with an gating system according to item 10 of the claim.
  • Figure 1 a shows a rough perspective sketch of the inner structure of a sand mould fitted with a gating system according to the invention.
  • Figure 1 b shows a rough cross sectional sketch of the sprues of the sand mould fitted with a gating system as regards Figure 1 a.
  • Figure 1 c shows a perspective image of a casting produced by means of a sand mould.
  • Figure 2 shows another rough perspective sketch of the inner layout of the sand mould with a gating system.
  • 'Aluminium casting ' a casting part which is made of Aluminium or Aluminium alloy.
  • 'Aluminium alloy' generally 'silumin' alloys specifically (ENAC or other) alloy groups according to the patent such as AISi12MgTi, AISi7Mg, AISM OMg, AISi9Cu (these are mainly used in the technology relative to the invention, but in certain cases other Al alloys can also be used).
  • 'Thin-walled' 1 -3 mm average wall thickness of the alloy, the size is larger than 50 times or a 100 times of the wall thickness and change in the wall thickness will not exceed 50% of that.
  • 'Sand mould' refractory sand of 0.2-0.4 mm grain sizes (typically quartz sand but other kind of artificial sand can also occur) hardened with organic or non-organic bonding agent system in cold state (with chemical bond) or by heat (under the effect of being heated)
  • such -at least partly- thin-walled aluminium castings can be produced by gravity casting, in which the wall thickness of one or more parts is 1 - 3 mm and the largest dimension is multiplied by 100 times, or even 200-400 times compared to the wall thickness.
  • the largest dimension means the largest linear dimension of the given part of a cast, i.e. the longest side of the smallest prism which can involve the given part of the cast.
  • FIG 1 a and 1 b the inner structure of the sand mould (12) fitted with a gating system (10) is shown.
  • FIG 1 a the outer edges of the sand mould are shown only as illustration around the inner formation in a perspective view.
  • the sand mould (12) includes an upper half (12a) and a bottom half (12b), which are joined in a joint surface (13) and these two parts form the mould cavity (16).
  • the mould cavity (16) is completely thin walled and provides casting parts (14) with 1 -3 mm wall thickness, which is also separately shown in figure 1 c.
  • the cast part is not separated from the complete casting (14'), which means that the solidified parts of the melt in the gating system (10) are joined to the casting part (14), which can be separated, e.g. by cutting them off the casting (14).
  • the gating system (10) consists of two sprues (18), one runner (20) by each sprue and 5 gates (22) with portholes (22) opening from each runner into the mould cavity (16).
  • the runners (20) allow the liquid metal to run in the joining surface (13) of the mould parts (12a and 12b) or in its surroundings from the sprues (18) to the runner gates (22).
  • segmented shaping allows complete filling of the mould cavity as well as reduces the formation of turbulence and foaming, and aids the formation of steady flow.
  • These runners are trapezoidal in various sizes; e.g. upper width 10 mm, bottom width 21 mm, height 17 mm.
  • Ingates (22) are channels connecting the runners (20) and the mould cavity (16) with the aim of allowing the liquid metal to run into the mould cavity, controlling flow rate and eliminating the formation of turbulence and foaming. They come in various sizes; e.g. gate width 42 mm, gate height adjusted to the wall thickness of the cast, e.g.2 mm, widening towards the runners: width e.g.10 mm, height 16 mm.
  • the sprue (18) is composed of the sprue itself, which is formed in the sand mould, and the riser (26) fitted to it from the outside.
  • the upper part of the latter one is a pouring cup (28) to allow easier pouring of the melt into the sprue (18).
  • the gating system is of narrowing cross section thus the flowing cross section is getting narrower (including even a transitional increase) towards the runners (22a). In this manner the flow rate of the melt will increase towards the runners (22a) and will reach its highest rate there.
  • This arrangement is in contrast to the conventional sand mould technology, in which gating systems of expanding cross sections are applied since slow and laminar flow will result in higher cast quality in case of thick walled casting parts.
  • a gating system of narrowing cross section (10) is any gating system that can achieve the highest flow rate at the runner (22a) by narrowing the flowing cross sections. For this reason at least the ingates are to be of narrowing cross section, i.e. the inner cross section of ingates is narrowing towards the runner (22) and becomes the narrowest at the runner (22a).
  • the flow rate is at least twice or more advantageously 3-5 times higher than the average flow rate in the runners (20), or when no such are applied, in the down sprues (18). This can be achieved by providing at least twice or even 3-5 times wider total cross section for the runners (22a) than that of the runners (20). In this case both runners (20) have 2 branches respectively, which start from the sprue (18).
  • Attachments (26) also contribute to the increase of flow rate.
  • the gradient height between the upper port (i.e. the upper edge of the cup) of the sprue (18) and the joining surface (13) of the sand mould (12) is to be 0.3 or even 0.6-1 .3 times multiple of the largest dimension of the mould cavity.
  • Risers (30) are also incorporated in the sand mould (12). Their task is to exhaust from the mould the gases that are formed during casting as well as to exhaust air accumulated in front of the liquid metal. To the purpose they have cylindrical shape. Their typical diameter is double the wall thickness of the cast (2-6 mm).
  • a cooling metal insert e.g. a cooling iron bar is applied (not shown). This cooling iron bar will allow thick walled segments to solidify at an identical rate with the thin walled segments.
  • Feeders can also be applied to feed the thick walled segments.
  • FIG 2 the inner layout of the sand mould (12) and gating system (10) is illustrated, which includes four sprues (18) and four runners (20). 5 ingates (22) belong to each runner along the longer sides of the mould cavity (16), while along the shorter sides 4 ingates (22) are joined to each runner (20).
  • the sand mould (12) has 2-5 ingates (22) on each runner (20).
  • the number and layout of the ingates and runners is designed in a way that at least one runner gate (22) should belong to each 100-1000 cm 2 segment of the mould cavity, which provides thin-walled casting parts. This arrangement will enable the melt to fill in the whole mould cavity (16) before getting solidified.
  • the runner In order to produce castings of smaller dimensions (14) the runner can even be neglected. In this case the ingates (22) are directly connected to the bottom of the sprue (18). In order to produce casting parts of larger dimensions (14) a number of segmented runners (20) or branching runners may be applied, or in a given case several sprues can be connected to one single runner (20).
  • the sand mould (12) fitted with a gating system (10) can be applied in the following way.
  • Plastic patterns and mould cores provide the manufacturing tool, which is applied to produce the mould halves (12) and cores. From moulding sand suitable for pre-heating the mould halves (12a, 12b) are produced, which will form the cavity related to the casting.
  • the sand mould is typically a chemically bonded dry mould which can tolerate heating.
  • Cross section, height and width of the gating elements are always determined by the features and casting position of the cast (14).
  • the sand mould (12) is pre-heated at least in the thin walled segment of the casting up to 100°C, better to 100-600°C, or even more advantageous to 300-500°C (or 0.5-0.8 times of the solidification temperature of the Aluminium alloy). Heating can be performed with gas flame.
  • the moulded cooling iron bars, supposing there are any, are also heated until vapour precipitates and dries from the surface (the surface of the cooling iron bars must remain pure); then the mould surfaces (16), runner gates (22) and the runners (20) and sprues (24) are heated up again before the mould halves are closed.
  • the Aluminium melt is produced by heating Aluminium (or Al alloy). Before being fed into the gating system, the melt is over-heated by 100°C, advantageously at least by 200°C, or even by 200-350°C, which will further contribute to avoiding too early solidification.
  • the liquid metal (melt) is introduced through the gating system (10) into the mould cavity of the preheated mould halves (12a, 12b).
  • the mould cavity is filled with liquid metal by means of pouring ladles, preferably through the pouring cup (12a) fitted on the sprue of the upper mould half (12a).
  • Moulding sand and excess parts are removed from the casting (14), which is followed by the casting being applied according to the purpose.
  • the manufacturing tool which enables producing a replica of the part from sand, is made according to a virtual model created by a generally used 3D design program or other suitable programs. This is followed by distributing the tool related to the user's demand, as well as shrinkage of the casting and moulding inclination is concerned. The next step is to determine the pouring position, which can be either vertical or horizontal, according to the geometry of the model then the coring position of the possible cavities of the part will be given.
  • the required ingates, sprues, risers, hidden feeders are designed, which will all be installed in the mould frame and be moulded together with the mould halves (12a, 12b), which will allow producing identical parts for the casting.
  • the manufacturing tool is then treated with mould remover and filled in with washed and sized, chemically bonded sand. During the filling up the designed cooling iron is moulded in the sand as well as the upper part of the core is made rigid with iron strands.
  • the mould halves (12a, 12b) are precisely joined by positioning devices, which are also included in the manufacturing tool.
  • Overflow preventers prevent flow-off occurring from the mould buckling on the joining surface, followed by the mould halves (12a, 12b) being treated, heated and closed.
  • the upper mould half (12a) is designed with an increased height and balanced. After casting the melt is allowed to cool and then the cores will be carefully removed from the casting, which is then cut off from the ingates and finely purified. This process is followed by checking the main dimensions and delivered to the supplier for testing. After the casting has been tested, small quantity production will be launched.
  • a direct economic benefit of the process applied in the invention is that it allows manufacturing castings of almost identical properties related to the technical parameters, with low financial investment and during a fraction of time as compared to the production of large scale casts with metal mould of otherwise high production cost.
  • the process is suitable for producing cast parts to be made costly even on large scale, which can be applied for practical purposes.
  • the products of this kind are mainly indoor and outdoor luminaires, engine parts - spare parts, cylinder-heads, machine components, spare parts for mechanical and precision engineering, fittings, etc. All these products can be produced through this invention in such quality that they will be suited for practical application under operational conditions. This will result in cost-effective development and more effective testing before the manufacture on large scale is launched. Aluminium castings for different purposes are to be produced with this process applied in the invention on small to medium scale, even in several hundred pieces.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Molds, Cores, And Manufacturing Methods Thereof (AREA)
  • Casting Devices For Molds (AREA)
  • Mold Materials And Core Materials (AREA)

Abstract

L'objet de l'invention est un procédé pour la production de pièces à parois au moins partiellement minces et en aluminium avec la technologie de moulage au sable au moyen d'un coulage par gravité, qui permet de produire des pièces coulées avec des dimensions globales 100 fois plus grandes ou de préférence 200 à 400 fois plus grandes dans le cas d'une épaisseur de paroi de 1 à 3 mm. L'idée principale du procédé est qu'un moule en sable contenant la cavité de moule est utilisé, un contenu de fonte d'aluminium est produit, la fonte est introduite dans la cavité de moule au niveau de plusieurs points à travers un système d'attaques de coulée ayant une coupe transversale se rétrécissant. Un autre objet de l'invention est un moule en sable équipé d'un système d'attaques de coulée afin de produire des pièces coulées à parois au moins partiellement minces avec une technologie de moulage au sable, au moyen d'un coulage par gravité. L'épaisseur de paroi des segments à paroi mince est de 1 à 3 mm et la plus grande dimension est supérieure à 100 fois, mais de préférence au moins 200 à 400 fois, l'épaisseur de la paroi. L'idée principale derrière le moule en sable avec un système d'attaques de coulée est qu'il contient une cavité de moule permettant la production de pièces coulées à parois au moins partiellement minces, et qu'il est équipé d'un système d'attaques de coulée, qui est composé d'au moins deux descentes de coulée et d'une amorce de coulée ayant chacune une lumière dans la cavité de moule et en contact liquide avec les descentes de coulée.
EP16774976.1A 2015-05-14 2016-05-12 Procédé de coulage et moule en sable pourvu d'un système d'admission pour produire des pièces coulées en aluminium à parois au moins partiellement minces avec la technologie de moulage au sable au moyen d'un coulage par gravité Active EP3294476B2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
HU1500230A HU230620B1 (hu) 2015-05-14 2015-05-14 Eljárás vékonyfalú, tagolt, részletgazdag alumínium öntvények homokformázásos technológiával, gravitációs öntéssel történő előállítására
PCT/HU2016/050019 WO2016181177A2 (fr) 2015-05-14 2016-05-12 Procédé de coulage et moule en sable pourvu d'un système d'admission pour produire des pièces coulées en aluminium à parois au moins partiellement minces avec la technologie de moulage au sable au moyen d'un coulage par gravité

Publications (3)

Publication Number Publication Date
EP3294476A2 true EP3294476A2 (fr) 2018-03-21
EP3294476B1 EP3294476B1 (fr) 2019-07-03
EP3294476B2 EP3294476B2 (fr) 2022-07-20

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EP16774976.1A Active EP3294476B2 (fr) 2015-05-14 2016-05-12 Procédé de coulage et moule en sable pourvu d'un système d'admission pour produire des pièces coulées en aluminium à parois au moins partiellement minces avec la technologie de moulage au sable au moyen d'un coulage par gravité

Country Status (4)

Country Link
US (1) US20170333981A1 (fr)
EP (1) EP3294476B2 (fr)
HU (2) HU230620B1 (fr)
WO (1) WO2016181177A2 (fr)

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EP3709430A4 (fr) 2017-11-10 2021-08-25 NGK Insulators, Ltd. Batterie au lithium entièrement solide et son procédé de fabrication
CN108436039B (zh) * 2018-05-31 2023-11-24 天津蒙德利尔集装箱配件有限公司 一种集装箱角件铸造工艺用模具
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CN110877096A (zh) * 2019-12-14 2020-03-13 台州市瑞达机械有限公司 一种水轴套的铸造模具
CN113414348B (zh) * 2021-06-18 2023-07-18 安徽博晟亿电力科技有限公司 一种生铁生产用高压升温的铸造装置及其实施方法
CN114367634B (zh) * 2021-10-29 2024-09-13 中国航发西安动力控制科技有限公司 铝合金铸件分区分段倾转铸造装置及其铸造方法
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TWI852194B (zh) * 2022-11-29 2024-08-11 財團法人金屬工業研究發展中心 重力鑄造流道系統之接頭與重力鑄造流道系統

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EP3294476B1 (fr) 2019-07-03
WO2016181177A9 (fr) 2017-04-20
HUP1500230A2 (hu) 2016-07-28
HU230866B1 (hu) 2018-11-29
WO2016181177A3 (fr) 2016-12-22
US20170333981A1 (en) 2017-11-23
WO2016181177A4 (fr) 2017-03-02
HUP1700498A2 (en) 2018-02-28
EP3294476B2 (fr) 2022-07-20
HU230620B1 (hu) 2017-04-28

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