EP3246426B1 - Procédé de fabrication d'une tôle d'acier épaisse de haute ténacité et de haute résistance - Google Patents
Procédé de fabrication d'une tôle d'acier épaisse de haute ténacité et de haute résistance Download PDFInfo
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- EP3246426B1 EP3246426B1 EP16737217.6A EP16737217A EP3246426B1 EP 3246426 B1 EP3246426 B1 EP 3246426B1 EP 16737217 A EP16737217 A EP 16737217A EP 3246426 B1 EP3246426 B1 EP 3246426B1
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- 229910000831 Steel Inorganic materials 0.000 title claims description 158
- 239000010959 steel Substances 0.000 title claims description 158
- 238000000034 method Methods 0.000 title claims description 20
- 238000004519 manufacturing process Methods 0.000 title claims description 19
- 238000003303 reheating Methods 0.000 claims description 51
- 239000010953 base metal Substances 0.000 claims description 33
- 238000001816 cooling Methods 0.000 claims description 31
- 230000009467 reduction Effects 0.000 claims description 26
- 238000005096 rolling process Methods 0.000 claims description 25
- 238000010438 heat treatment Methods 0.000 claims description 23
- 230000001186 cumulative effect Effects 0.000 claims description 15
- 238000009864 tensile test Methods 0.000 claims description 12
- 229910045601 alloy Inorganic materials 0.000 claims description 10
- 239000000956 alloy Substances 0.000 claims description 10
- 238000005242 forging Methods 0.000 claims description 10
- 238000005496 tempering Methods 0.000 claims description 10
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 9
- 238000005098 hot rolling Methods 0.000 claims description 8
- 229910052748 manganese Inorganic materials 0.000 claims description 7
- 229910052804 chromium Inorganic materials 0.000 claims description 6
- 239000012535 impurity Substances 0.000 claims description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 229910052720 vanadium Inorganic materials 0.000 claims description 6
- 229910052796 boron Inorganic materials 0.000 claims description 5
- 229910052791 calcium Inorganic materials 0.000 claims description 5
- 229910052758 niobium Inorganic materials 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- 229910052727 yttrium Inorganic materials 0.000 claims description 5
- 229910052726 zirconium Inorganic materials 0.000 claims description 5
- 229910052715 tantalum Inorganic materials 0.000 claims 4
- 238000010791 quenching Methods 0.000 description 56
- 230000000171 quenching effect Effects 0.000 description 56
- 230000000694 effects Effects 0.000 description 14
- 238000003466 welding Methods 0.000 description 13
- 238000007711 solidification Methods 0.000 description 12
- 230000008023 solidification Effects 0.000 description 12
- 230000015572 biosynthetic process Effects 0.000 description 10
- 239000000463 material Substances 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 229910001566 austenite Inorganic materials 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 238000005275 alloying Methods 0.000 description 6
- 238000004364 calculation method Methods 0.000 description 6
- 238000005266 casting Methods 0.000 description 6
- 229910000734 martensite Inorganic materials 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- 238000001556 precipitation Methods 0.000 description 4
- 230000009466 transformation Effects 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910001563 bainite Inorganic materials 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 238000009863 impact test Methods 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229910000859 α-Fe Inorganic materials 0.000 description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 238000009659 non-destructive testing Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000008439 repair process Effects 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 229910000746 Structural steel Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- ZPUCINDJVBIVPJ-LJISPDSOSA-N cocaine Chemical compound O([C@H]1C[C@@H]2CC[C@@H](N2C)[C@H]1C(=O)OC)C(=O)C1=CC=CC=C1 ZPUCINDJVBIVPJ-LJISPDSOSA-N 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- NRNCYVBFPDDJNE-UHFFFAOYSA-N pemoline Chemical compound O1C(N)=NC(=O)C1C1=CC=CC=C1 NRNCYVBFPDDJNE-UHFFFAOYSA-N 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
- C21D8/0263—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/38—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling sheets of limited length, e.g. folded sheets, superimposed sheets, pack rolling
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/004—Heat treatment of ferrous alloys containing Cr and Ni
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/005—Heat treatment of ferrous alloys containing Mn
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/008—Heat treatment of ferrous alloys containing Si
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0205—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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- C22C38/00—Ferrous alloys, e.g. steel alloys
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
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- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
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- C22C—ALLOYS
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- C22C—ALLOYS
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
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- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
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- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/54—Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/02—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling heavy work, e.g. ingots, slabs, blooms, or billets, in which the cross-sectional form is unimportant ; Rolling combined with forging or pressing
- B21B1/024—Forging or pressing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/02—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling heavy work, e.g. ingots, slabs, blooms, or billets, in which the cross-sectional form is unimportant ; Rolling combined with forging or pressing
- B21B1/026—Rolling
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/02—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling heavy work, e.g. ingots, slabs, blooms, or billets, in which the cross-sectional form is unimportant ; Rolling combined with forging or pressing
- B21B2001/028—Slabs
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B3/00—Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B3/00—Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
- B21B3/02—Rolling special iron alloys, e.g. stainless steel
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/002—Bainite
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/008—Martensite
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D7/00—Modifying the physical properties of iron or steel by deformation
- C21D7/13—Modifying the physical properties of iron or steel by deformation by hot working
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0081—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for slabs; for billets
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
Definitions
- the present invention relates to a method for manufacturing a thick-walled high-toughness high-strength steel plate for use in steel structures in construction, bridges, shipbuilding, offshore structures, construction and industrial machinery, tanks, penstocks, and the like.
- the surface of the steel plate has high toughness
- the inner part of the steel plate has high strength and toughness.
- the steel plate has a thickness of 100 mm or more and a yield strength of 620 MPa or more.
- steel for use in construction, bridges, shipbuilding, offshore structures, construction and industrial machinery, tanks, penstocks, and other fields is welded to have a desired shape.
- the strength and thickness of steel to be used have also been greatly increased.
- the cooling rate is higher on the surface of a steel plate than in the half-thickness portion.
- a martensite structure having low toughness is formed on the surface of the steel plate.
- a high-strength steel plate having a thickness of 100 mm or more rarely has both high surface toughness and high strength and toughness of the inner part thereof.
- Non Patent Literature 1 describes a material having a thickness of 210 mm
- Non Patent Literature 2 describes a material having a thickness of 180 mm.
- CN 102605280 A describes a method for manufacturing an ultra-thick high-strength high low-temperature toughness steel plate for ocean platforms, wherein the steel plate comprises, in weight percentage, 0.10-0.24% of C, 0.05-0.35% of Si, 0.60-1.15% of Mn, not more than 0.015% of P, not more than 0.005% of S, 0.01-0.030% of Ti, 1.45-1.75% of Cr, 0.15-0.44% of Mo, 0.80-2.50% of Ni, 0.010-0.070% of Nb, 0.020-0.080% of V, 0.02-0.06% of Alt, 0.001-0.004% of Ca, not more than 0.006% of N, 0.0007-0.0030% of B, the balance being Fe and unavoidable impurities and whereing the steel plate has a system of C, Ni-Cr-Mo alloyed and Nb-V-Ti microalloyed, and has a yield strength not smaller than 690MPa, a tensile strength not smaller than 770MPa
- the present invention has been made to solve such problems and aims to provide a method for manufacturing a thick-walled high-toughness high-strength steel plate that has high surface toughness and high strength and toughness of the inner part thereof.
- the present inventors have extensively studied the microstructure control factors that satisfy high toughness of the surface of a thick-walled steel plate having a yield strength of 620 MPa or more and a thickness of 100 mm or more and also satisfy high strength and toughness of the half-thickness portion of the thick-walled steel plate, and have found the following.
- the present invention provides a method for manufacturing a thick-walled high-toughness high-strength steel plate having a thickness of 100 mm or more and having a yield strength of 620 MPa or more and high toughness.
- the thick-walled high-toughness high-strength steel plate can be used to manufacture steel structures having high safety.
- a thick-walled high-toughness high-strength steel plate manufactured according to the present invention has a composition containing, on a mass percent basis, C: 0.08% to 0.20%, Si: 0.40% or less (including 0%), Mn: 0.5% to 5.0%, P: 0.010% or less (including 0%), S: 0.0050% or less (including 0%), Cr: 3.0% or less (including 0%), Ni: 0.1% to 5.0%, Al: 0.010% to 0.080%, N: 0.0070% or less (including 0%), and O: 0.0025% or less (including 0%).
- the symbol "%" in the component content refers to "% by mass”.
- C is an element useful for achieving the strength necessary for structural steel at low cost. This effect requires a C content of 0.08% or more. In a steel structure manufactured from a thick-walled high-toughness high-strength steel plate by welding, however, a C content of more than 0.20% significantly deteriorates toughness of the base metal and weld. Thus, the C content has an upper limit of 0.20%. The C content preferably ranges from 0.08% to 0.14%.
- Si is added for deoxidation.
- a steel plate according to the present invention does not necessarily contain Si.
- a Si content of more than 0.40% significantly deteriorates toughness of the base metal and heat-affected zone.
- the Si content is 0.40% or less, preferably 0.05% to 0.3%, more preferably 0.1% to 0.3%.
- Mn is added to ensure high strength of the base metal. This effect is insufficient at a Mn content of less than 0.5%.
- a Mn content of more than 5.0% promotes center segregation, results in a larger casting defect of the slab, and deteriorates mechanical properties of the base metal in a steel structure manufactured from a thick-walled high-toughness high-strength steel plate by welding.
- the Mn content has an upper limit of 5.0%.
- the Mn content preferably ranges from 0.6% to 2%, more preferably 0.6% to 1.6%.
- a P content of more than 0.010% significantly deteriorates toughness of the base metal and heat-affected zone.
- the P content is preferably minimized (may be zero) and is limited to 0.010% or less.
- a S content of more than 0.0050% significantly deteriorates toughness of the base metal and heat-affected zone.
- the S content is preferably minimized (may be zero) and is 0.0050% or less.
- the Cr is an element effective in strengthening the base metal. However, an excessively high Cr content deteriorates weldability. Thus, the Cr content is 3.0% or less, preferably 0.1% to 2%, more preferably 0.7% to 1.7%. The Cr content may be 0%.
- Ni is an element useful for improving the strength of steel and the toughness of the heat-affected zone. This effect requires a Ni content of 0.1% or more. However, a Ni content of more than 5.0% significantly deteriorates economic efficiency. Thus, the Ni content has an upper limit of 5.0%.
- the Ni content preferably ranges from 0.4% to 4%, more preferably 0.8% to 3.8%.
- Al is added for sufficient deoxidation of molten steel.
- An Al content of less than 0.010% is insufficient for the effect.
- an Al content of more than 0.080% deteriorates toughness of the base metal due to an increased dissolved Al content in the base metal in a steel structure manufactured from a thick-walled high-toughness high-strength steel plate by welding.
- the Al content is 0.080% or less, preferably 0.030% to 0.080%, more preferably 0.030% to 0.070%.
- N together with Ti, forms a nitride and thereby performs refinement of the structure and improves the toughness of the base metal and heat-affected zone in a steel structure manufactured from a thick-walled high-toughness high-strength steel plate by welding.
- the toughness can be improved by a constituent other than N.
- a steel plate according to the present invention does not necessarily contain N.
- the N content is preferably 0.0015% or more.
- a N content of more than 0.0070% deteriorates toughness of the base metal due to an increased dissolved N content in the base metal and deteriorates toughness of the heat-affected zone due to the formation of coarse carbonitride.
- the N content is 0.0070% or less, preferably 0.006% or less, more preferably 0.005% or less.
- O content of more than 0.0025% significantly deteriorates toughness due to the formation of a hard oxide in steel.
- the O content is preferably minimized (may be zero) and is 0.0025% or less.
- a thick-walled high-toughness high-strength steel plate manufactured according to the present invention can contain at least one of Cu, Mo, V, Nb, and Ti in order to further improve strength and/or toughness.
- Cu can improve the strength of steel without reducing toughness.
- a Cu content of more than 0.50% may cause a crack on the surface of a steel plate during hot working.
- the Cu content, if any, is 0.50% or less.
- Mo contributes to high strength of the base metal in a steel structure manufactured from a thick-walled high-toughness high-strength steel plate by welding.
- a Mo content of more than 1.50% results in increased hardness and deteriorates toughness due to the precipitation of alloy carbide.
- the Mo content if any, has an upper limit of 1.50%.
- the Mo content preferably ranges from 0.2% to 0.8%.
- V 0.400% or less
- V contributes to improved strength and toughness of the base metal in a steel structure manufactured from a thick-walled high-toughness high-strength steel plate by welding.
- V precipitates as VN and is effective in decreasing the amount of dissolved N.
- a V content of more than 0.400% deteriorates toughness due to the precipitation of hard VC.
- the V content, if any, is preferably 0.400% or less, more preferably 0.01% to 0.1%.
- Nb is effective in improving the strength of the base metal.
- a Nb content of more than 0.100% deteriorates toughness of the base metal.
- the Nb content has an upper limit of 0.100%.
- the Nb content is preferably 0.025% or less.
- Ti forms TiN during heating and effectively suppresses the coarsening of austenite.
- Ti improves the toughness of the base metal and heat-affected zone.
- a Ti content of more than 0.020% results in coarsening of Ti nitride and deteriorates toughness of the base metal.
- the Ti content if any, ranges from 0.005% to 0.020%, preferably 0.008% to 0.015%.
- a thick-walled high-toughness high-strength steel plate manufactured according to the present invention can further contain at least one of Mg, Ta, Zr, Y, B, Ca, and REM to improve the material quality.
- Mg forms a stable oxide at high temperatures, effectively suppresses the coarsening of prior ⁇ grains in the heat-affected zone, and is effective in improving the toughness of the weld.
- These effects require a Mg content of 0.0001% or more.
- a Mg content of more than 0.0050% results in an increased number of inclusions and deteriorates toughness.
- the Mg content, if any, is preferably 0.0050% or less, more preferably 0.0001% to 0.015%.
- Ta 0.01% to 0.20%
- Ta content 0.01% or more is effective.
- a Ta content of more than 0.20% deteriorates toughness due to formation of precipitates.
- the Ta content if any, ranges from 0.01% to 0.20%.
- Zr is an element effective in improving strength.
- a Zr content of 0.005% or more is effective in producing this effect.
- a Zr content of more than 0.1% deteriorates toughness due to the formation of a coarse precipitate.
- the Zr content, if any, ranges from 0.005% to 0.1%.
- Y forms a stable oxide at high temperatures, effectively suppresses the coarsening of prior ⁇ grains in the heat-affected zone, and is effective in improving the toughness of the weld.
- An Y content of 0.001% or more is effective in producing these effects.
- an Y content of more than 0.01% results in an increased number of inclusions and deteriorates toughness.
- the Y content, if any, ranges from 0.001% to 0.01%.
- B segregates at austenite grain boundaries, suppresses ferrite transformation from the grain boundaries, and improves hardenability.
- a B content of more than 0.0030% deteriorates hardenability and toughness due to the precipitation of B as a carbonitride.
- the B content is 0.0030% or less.
- the B content, if any, preferably ranges from 0.0003% to 0.0030%, more preferably 0.0005% to 0.002%.
- Ca is an element useful for the morphology control of a sulfide inclusion. This effect requires a Ca content of 0.0005% or more. However, a Ca content of more than 0.0050% deteriorates cleanliness and toughness. Thus, the Ca content, if any, is preferably 0.0050% or less, more preferably 0.0005% to 0.0025%.
- REM forms an oxide and a sulfide in steel and is effective in improving the material quality. This effect requires a REM content of 0.0005% or more. However, the effect levels off at a REM content of 0.0100% or more. Thus, the REM content, if any, is 0.0100% or less, preferably 0.0005% to 0.005%.
- the present invention provides a steel plate having desirable characteristics even when the steel plate is manufactured from steel casted under conditions where the cooling rate of a slab surface during solidification is 1°C/s or less.
- microsegregation needs to be reduced to achieve high toughness (vE-40 ⁇ 70 J) of the surface of a thick-walled high-toughness high-strength steel plate having a thickness of 100 mm or more, particularly manufactured from steel casted under conditions where the cooling rate of a slab surface during solidification is 1°C/s or less.
- C L 0.2 ⁇ ⁇ 0.1 ⁇ 0.2 ⁇ Si ⁇ 0.03 ⁇ 1.1 ⁇ Mn ⁇ 0.12 ⁇ 0.2 ⁇ Cu ⁇ 0.11 ⁇ 3 ⁇ Ni + 0.025 ⁇ 1.2 ⁇ Cr + 0.1 ⁇ 0.5 ⁇ Mo + 0.2 ⁇ 0.04 ⁇ V ⁇ 0.05 ⁇ 0.06 ⁇ Al
- the element symbols denote the respective alloy component contents (% by mass), and in the absence of an element, the element symbol is denoted by 0.
- the C content needs to be specified depending on each component other than C, such as Si or Mn.
- the effects of an alloying element on the C solid solubility limit (C L ) of the ⁇ phase were calculated using thermodynamic calculation software "Thermo-Calc". The result was used to determine the factor.
- the factor "-0.1" for "Si” means that 1% Si decreases the C solid solubility limit of the ⁇ phase by 0.1%, and the C content of the base metal needs to be decreased to achieve the required percentage of the ⁇ phase.
- the calculation of C L was based on the component of C: 0.12%, Si: 0.2%, Mn: 1.1%, Cu: 0.2%, Cr: 1.2%, Ni: 3%, Mo: 0.5%, V: 0.04% and Al: 0.06%, and the factors for the calculation of C L were determined by calculating a variation from the dissolved C content caused by a variation in each alloying element content.
- the percentage (C L - C)/C L x 100 of C to be added relative to the C solid solubility limit in the ⁇ phase thus calculated is 30% or more, the percentage of the ⁇ phase at the beginning of the formation of the ⁇ phase can be 30% or more.
- the reduction of area in the thickness direction at half the thickness of the plate is 40% or more when measured by a method described in the example.
- the temperature "°C” refers to the temperature in the half-thickness portion except for the quenching temperature in the case of quenching without leaving to cool after rolling.
- the quenching temperature in the case of quenching without leaving to cool after rolling is the surface temperature of the steel plate. This is because the temperature distribution of the steel plate in the thickness direction increases during rolling, and a decrease in the surface temperature of the steel plate needs to be considered.
- the temperature of the half-thickness portion is determined, for example, by simulation calculation from the thickness, surface temperature, and cooling conditions. For example, the temperature of the half-thickness portion is determined by calculating the temperature distribution in the thickness direction using finite difference methods.
- a molten steel having the composition described above is produced by a conventional method, such as with a converter, an electric furnace, or a vacuum melting furnace, and is formed into a piece of steel, such as a slab or billet, by a conventional casting method, such as a continuous casting process or an ingot casting process.
- the cooling rate during solidification is determined by direct measurement with a thermocouple or by simulation calculation, such as heat-transfer calculation.
- steel manufactured under conditions where the cooling rate of a surface during solidification is 1°C/s or less can preferably be used.
- the thickness of the material may be reduced by slabbing.
- a cast bloom or steel bloom having the composition described above is heated to a temperature in the range of 1200°C to 1350°C.
- a reheating temperature of less than 1200°C results in not only an insufficient rolling reduction due to an increased load to achieve a predetermined cumulative rolling reduction in hot working but also low production efficiency due to additional heating as required during working.
- the reheating temperature is 1200°C or more.
- a large amount of additive alloying element as steel having a carbon equivalent of 0.65% or more according to the present invention results in a casting defect such as a center porosity or porous shrinkage cavity, having a much increased size in steel. In order to make them harmless by pressure bonding, the cumulative rolling reduction needs to be 25% or more.
- a reheating temperature of more than 1350°C results in excessive energy consumption, increased likelihood of occurrence of surface flaws due to scales during heating, and increased repair load after hot forging.
- the upper limit is 1350°C.
- a cast bloom or steel bloom having the composition described above is heated to a temperature in the range of 1200°C to 1350°C.
- a reheating temperature of less than 1200°C results in not only an insufficient rolling reduction due to an increased load to achieve a predetermined cumulative rolling reduction in hot working but also low production efficiency due to additional heating as required during working.
- the reheating temperature is 1200°C or more.
- the cumulative rolling reduction is 30% or more, preferably 40% or more in terms of good reduction of area (RA).
- a reheating temperature of more than 1350°C results in excessive energy consumption, increased likelihood of surface flaws due to scales during heating, and increased repair load after hot forging.
- the upper limit is 1350°C.
- the heating temperature preferably ranges from 1000°C to 1200°C.
- the Ac3 transformation temperature is calculated using the following formula (4).
- Ac 3 937.2 ⁇ 476.5 C + 56 Si ⁇ 19.7 Mn ⁇ 16.3 Cu ⁇ 26.6 Ni ⁇ 4.9 Cr + 38.1 Mo + 124.8 V + 136.3 Ti + 198.4 Al + 3315 B
- the element symbols in the formula (4) denote the respective alloy component contents (% by mass).
- a steel plate is left to cool (for example, air cooling) after hot rolling or is rapidly cooled from the Ar3 temperature or more to 350°C or less without leaving to cool after hot rolling.
- the steel plate is reheated to the Ac3 temperature to 1050°C and is rapidly cooled from the Ac3 temperature or more to 350°C or less.
- the reason for the reheating temperature of 1050°C or less is that reheating at a high temperature of more than 1050°C results in coarsening of austenite grains and significantly deteriorates toughness of the base metal in a steel structure manufactured from a thick-walled high-toughness high-strength steel plate by welding.
- the reheating temperature is the Ac3 temperature or more in order that the steel plate may entirely have an austenite structure.
- the quenching temperature is the Ac3 temperature or more because the desirable characteristics are not obtained at a temperature below the Ac3 temperature due to the formation of a nonuniform structure composed of ferrite and austenite.
- the quenching temperature is the Ar3 temperature or more for quenching from the austenite single phase region.
- the rapid cooling stop temperature is a lower temperature selected from 350°C or less and the Ar3 temperature or less in order to ensure that the steel plate entirely has a transformed structure.
- the stop temperature should be the Ar3 temperature or less and 350°C or less.
- the Ar3 transformation temperature is calculated using the following formula (5).
- Ar 3 910 ⁇ 310 C ⁇ 80 Mn ⁇ 20 Cu ⁇ 15 Cr ⁇ 55 Ni ⁇ 80 Mo
- the element symbols in the formula (5) denote the respective alloy component contents (% by mass).
- the rapid cooling method is industrially water cooling. It is desirable that the cooling rate be as high as possible.
- the cooling method is not necessarily water cooling and may be gas cooling, for example.
- quenching is sometimes repeated to strengthen steel. Although quenching may be repeated also in the present invention, final quenching requires rapid cooling to 350°C or less after heating to the Ac3 temperature to 1050°C and requires subsequent tempering at 450°C to 700°C.
- Steel plate samples No. 1 to No. 38 were manufactured by melting and casting steel No. 1 to No. 30 listed in Table 1 under the conditions listed in Table 2, performing hot forging (except for the samples No. 5, No. 6, and No. 41) or slabbing (the samples No. 5, No. 6, and No. 41), hot-rolling the steel to form a steel plate having a thickness listed in Table 2, and subjecting the steel plate to water quenching and tempering.
- the steel plate samples No. 1 to No. 38 were subjected to the following tests. In reheating and quenching in this example, the reheating temperature corresponds to the quenching temperature.
- the percentage of the ⁇ phase is calculated using the formula (2) from C L calculated using the formula (3) with each base metal component and the C content of the base metal.
- the cooling rate during solidification in the manufacture of steel is determined by heat-transfer calculation from the mold surface temperature data measured with a radiation thermometer.
- a round bar tensile test piece ( ⁇ 12.5 mm, GL 50 mm) was taken from the half-thickness portion of each steel plate in the direction perpendicular to the rolling direction and was measured in terms of yield strength (YS) and tensile strength (TS).
- Three 2-mm V-notched Charpy impact test specimens were taken from each surface and half-thickness portion of the steel plates.
- the rolling direction was the longitudinal direction.
- the absorbed energies of the test specimens were measured at a test temperature of -40°C in a Charpy impact test and were averaged (the average value for the test specimens taken from the half-thickness portion and the average value for the test specimens taken from the surface).
- a round bar tensile test piece ( ⁇ 10 mm) was taken from a region including the half-thickness portion of each steel plate in the thickness direction and was measured in terms of reduction of area (RA).
- the reduction of area is the percentage of the difference between the minimum cross-sectional area after the test specimen was broken and the original cross-sectional area relative to the original cross-sectional area.
- Table 2 shows the test results.
- the results showed that the steel plates of the examples having a steel composition according to the present invention (samples No. 1 to No. 21 and No. 41) had YS of 620 MPa or more, TS of 720 MPa or more, and toughness (vE-40) of 70 J or more at -40°C in the surface and half-thickness portion of the base metal, showing high strength and toughness of the base metal.
- a comparison between Nos. 5 and 6 and No. 41 showed that reduction of area (RA) was also satisfactory under particular slabbing conditions.
- the base metal had at least one of YS of less than 620 MPa, TS of less than 720 MPa, and toughness (vE-40) of less than 70 J, thus deteriorating characteristics.
- Thickness of material Cooling rate during solidification °C/s Hot forging or slabbing Hot rolling Thickness of product (mm)
- Type of heat treatment Final heat treatment conditions Mechanical properties of base metal (1/2t) Toughness of base metal (surface) Heating (°C) Cumulative rolling reduction (%) Heating (°C) Cumulative rolling reduction (%) Quenching temperature (°C) Cooling stop (°C) Tempering (°C) YS (MPa) TS (MPa) vE-40 (J) Tensile RA in thickness direction RA (%) vE-40 (J) 1 1 1000 0.32 1270 80 1130 43 100 Direct quenching 850 150 630 695 786 108 73 98 2 2 500 0.64 1230 65 1130 43 100 Reheating quenching 930 100 650 698 795 167 63 105 3 3 300 0.90 1200 30 1130 50 100 Reheating quenching 930 100 630 725 793 102 70 116 4 4 1000 0.33 1270 70 1160 43 150 Re
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Claims (4)
- Procédé de fabrication d'une plaque d'acier épaisse à haute résistance et haute ténacité ayant une épaisseur de 100 mm ou plus, une limite d'élasticité de 620 MPa ou plus et comprenant, sur une base de pourcentage massique,
C : 0,08 % à 0,20 %,
Si : 0,40 % ou moins,
Mn : 0,5 % à 5,0 %,
P : 0,010 % ou moins,
S : 0,0050 % ou moins,
Cr : 3,0 % ou moins,
Ni : 0,1 % à 5,0 %,
Al : 0,010% à 0,080%,
N : 0,0070 % ou moins et
O : 0,0025 % ou moins,
les formules (1) et (2) suivantes étant satisfaites, éventuellement au moins un élément parmi
Cu : 0,50 % ou moins,
Mo : 1,50 % ou moins,
V : 0,400 % ou moins,
Nb : 0,100 % ou moins,
Ti : 0,005 % à 0,020 %,
Mg : 0,0001 % à 0,0050 %,
Ta : 0,01 % à 0,20 %,
Zr : 0,005 % à 0,1 %,
Y : 0,001 % à 0,01 %,
B : 0,0030 % ou moins,
Ca : 0,0005 % à 0,0050 %, et
Terres rares : 0,0005 % à 0,0100 %,
le reste étant du Fe et des impuretés inévitables, et comprenant une ténacité (vE-40) de 70 J ou plus à -40 °C dans la partie de surface du métal de base :
une réduction de surface dans un sens épaisseur à la moitié de l'épaisseur de la plaque, qui est le pourcentage de la différence entre l'aire de section transversale minimum après la rupture d'une éprouvette en barreau à section ronde incluant la partie à la moitié de l'épaisseur de la plaque d'acier dans le sens épaisseur lors d'un essai de traction et l'aire de section transversale d'origine, rapportée à l'aire de section transversale d'origine, est de 40 % ou plus,
le procédé comprenant :un chauffage de l'acier entre 1200 °C et 1350 °C,un forgeage à chaud de l'acier avec un taux de réduction cumulé de 25 % ou plus,un chauffage de l'acier à une température Ac3 ou plus et 1200 °C ou moins,un laminage à chaud de l'acier avec un taux de réduction par laminage cumulé de 40 % ou plus,un refroidissement naturel de l'acier,un réchauffage de l'acier à la température Ac3 ou plus et 1050 °C ou moins,un refroidissement rapide de l'acier depuis la température Ac3 ou plus jusqu'à une température inférieure qui est à la fois inférieure ou égale à 350 °C et inférieure ou égale à la température Ar3, etun revenu de l'acier à une température dans la plage de 450 °C à 700 °C. - Procédé de fabrication d'une plaque d'acier épaisse à haute résistance et haute ténacité ayant une épaisseur de 100 mm ou plus, une limite d'élasticité de 620 MPa ou plus et comprenant, sur une base de pourcentage massique,
C : 0,08 % à 0,20 %,
Si : 0,40 % ou moins,
Mn : 0,5 % à 5,0 %,
P : 0,010 % ou moins,
S : 0,0050 % ou moins,
Cr : 3,0 % ou moins,
Ni : 0,1 % à 5,0 %,
Al : 0,010% à 0,080 %,
N : 0,0070 % ou moins et
O : 0,0025 % ou moins,
les formules (1) et (2) suivantes étant satisfaites, éventuellement au moins un élément parmi
Cu : 0,50 % ou moins,
Mo : 1,50 % ou moins,
V : 0,400 % ou moins,
Nb : 0,100 % ou moins,
Ti : 0,005 % à 0,020 %,
Mg : 0,0001 % à 0,0050 %,
Ta : 0,01 % à 0,20 %,
Zr : 0,005 % à 0,1 %,
Y : 0,001 % à 0,01 %,
B : 0,0030 % ou moins,
Ca : 0,0005 % à 0,0050 %, et
Terres rares : 0,0005 % à 0,0100 %,
le reste étant du Fe et des impuretés inévitables, et comprenant une ténacité (vE-40) de 70 J ou plus à -40 °C dans la partie de surface du métal de base :
une réduction de surface dans un sens épaisseur à la moitié de l'épaisseur de la plaque, qui est le pourcentage de la différence entre l'aire de section transversale minimum après la rupture d'une éprouvette en barreau à section ronde incluant la partie à la moitié de l'épaisseur de la plaque d'acier dans le sens épaisseur lors d'un essai de traction et l'aire de section transversale d'origine, rapportée à l'aire de section transversale d'origine, est de 40 % ou plus,
le procédé comprenant :un chauffage de l'acier entre 1200 °C et 1350 °C,un forgeage à chaud de l'acier avec un taux de réduction cumulé de 25 % ou plus,un chauffage de l'acier à une température Ac3 ou plus et 1200 °C ou moins,un laminage à chaud de l'acier avec un taux de réduction par laminage cumulé de 40 % ou plus,un refroidissement rapide de l'acier depuis une température Ar3 ou plus jusqu'à une température inférieure qui est à la fois inférieure ou égale à 350 °C et inférieure ou égale à la température Ar3, etun revenu de l'acier à une température dans la plage de 450 °C à 700 °C. - Procédé de fabrication d'une plaque d'acier épaisse à haute résistance et haute ténacité ayant une épaisseur de 100 mm ou plus, une limite d'élasticité de 620 MPa ou plus et comprenant, sur une base de pourcentage massique, C : 0,08 % à 0,20 %,
Si : 0,40 % ou moins,
Mn : 0,5 % à 5,0 %,
P : 0,010 % ou moins,
S : 0,0050 % ou moins,
Cr : 3,0 % ou moins,
Ni : 0,1 % à 5,0 %,
Al : 0,010% à 0,080 %,
N : 0,0070 % ou moins et
O : 0,0025 % ou moins,
les formules (1) et (2) suivantes étant satisfaites, éventuellement au moins un élément parmi
Cu : 0,50 % ou moins,
Mo : 1,50 % ou moins,
V : 0,400 % ou moins,
Nb : 0,100 % ou moins,
Ti : 0,005 % à 0,020 %,
Mg : 0,0001 % à 0,0050 %,
Ta : 0,01 % à 0,20 %,
Zr : 0,005 % à 0,1 %,
Y : 0,001 % à 0,01 %,
B : 0,0030 % ou moins,
Ca : 0,0005 % à 0,0050 %, et
Terres rares : 0,0005 % à 0,0100 %,
le reste étant du Fe et des impuretés inévitables, et comprenant une ténacité (vE-40) de 70 J ou plus à -40 °C dans la partie de surface du métal de base :
une réduction de surface dans un sens épaisseur à la moitié de l'épaisseur de la plaque, qui est le pourcentage de la différence entre l'aire de section transversale minimum après la rupture d'une éprouvette en barreau à section ronde incluant la partie à la moitié de l'épaisseur de la plaque d'acier dans le sens épaisseur lors d'un essai de traction et l'aire de section transversale d'origine, rapportée à l'aire de section transversale d'origine, est de 40 % ou plus,
le procédé comprenant :un chauffage de l'acier entre 1200 °C et 1350 °C,un dégrossissage de l'acier avec un taux de réduction par laminage cumulé de 40 % ou plus,un chauffage de l'acier à une température Ac3 ou plus et 1200 °C ou moins,un laminage à chaud de l'acier avec un taux de réduction par laminage cumulé de 40 % ou plus, un refroidissement naturel de l'acier,un réchauffage de l'acier à la température Ac3 ou plus et 1050 °C ou moins,un refroidissement rapide de l'acier depuis la température Ac3 ou plus jusqu'à une température inférieure qui est à la fois inférieure ou égale à 350 °C et inférieure ou égale à une température Ar3, etun revenu de l'acier à une température dans la plage de 450 °C à 700 °C. - Procédé de fabrication d'une plaque d'acier épaisse à haute résistance et haute ténacité ayant une épaisseur de 100 mm ou plus, une limite d'élasticité de 620 MPa ou plus et comprenant, sur une base de pourcentage massique,
C : 0,08 % à 0,20 %,
Si : 0,40 % ou moins,
Mn : 0,5 % à 5,0 %,
P : 0,010 % ou moins,
S : 0,0050 % ou moins,
Cr : 3,0 % ou moins,
Ni : 0,1 % à 5,0 %,
Al : 0,010% à 0,080 %,
N : 0,0070 % ou moins et
O : 0,0025 % ou moins,
les formules (1) et (2) suivantes étant satisfaites, éventuellement au moins un élément parmi
Cu : 0,50 % ou moins,
Mo : 1,50 % ou moins,
V : 0,400 % ou moins,
Nb : 0,100 % ou moins,
Ti : 0,005 % à 0,020 %,
Mg : 0,0001 % à 0,0050 %,
Ta : 0,01 % à 0,20 %,
Zr : 0,005 % à 0,1 %,
Y : 0,001 % à 0,01 %,
B : 0,0030 % ou moins,
Ca : 0,0005 % à 0,0050 %, et
Terres rares : 0,0005 % à 0,0100 %,
le reste étant du Fe et des impuretés inévitables, et comprenant une ténacité (vE-40) de 70 J ou plus à -40 °C dans la partie de surface du métal de base :
une réduction de surface dans un sens épaisseur à la moitié de l'épaisseur de la plaque, qui est le pourcentage de la différence entre l'aire de section transversale minimum après la rupture d'une éprouvette en barreau à section ronde incluant la partie à la moitié de l'épaisseur de la plaque d'acier dans le sens épaisseur lors d'un essai de traction et l'aire de section transversale d'origine, rapportée à l'aire de section transversale d'origine, est de 40 % ou plus,
le procédé comprenant :un chauffage de l'acier entre 1200 °C et 1350 °C,un dégrossissage de l'acier avec un taux de réduction par laminage cumulé de 40 % ou plus,un chauffage de l'acier à une température Ac3 ou plus et 1200 °C ou moins,un laminage à chaud de l'acier avec un taux de réduction par laminage cumulé de 40 % ou plus,un refroidissement rapide de l'acier depuis une température Ar3 ou plus jusqu'à une température inférieure qui est à la fois inférieure ou égale à 350 °C et inférieure ou égale à la température Ar3, etun revenu de l'acier à une température dans la plage de 450 °C à 700 °C.
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JP2015006670 | 2015-01-16 | ||
PCT/JP2016/000197 WO2016114146A1 (fr) | 2015-01-16 | 2016-01-15 | Tôle d'acier épaisse de haute ténacité et de haute résistance, et procédé de fabrication de celle-ci |
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EP3246426A1 EP3246426A1 (fr) | 2017-11-22 |
EP3246426A4 EP3246426A4 (fr) | 2018-01-10 |
EP3246426B1 true EP3246426B1 (fr) | 2020-06-24 |
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EP16737217.6A Active EP3246426B1 (fr) | 2015-01-16 | 2016-01-15 | Procédé de fabrication d'une tôle d'acier épaisse de haute ténacité et de haute résistance |
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US (1) | US20170369958A1 (fr) |
EP (1) | EP3246426B1 (fr) |
JP (1) | JP6048626B1 (fr) |
KR (1) | KR101994784B1 (fr) |
CN (1) | CN107208212B (fr) |
CA (1) | CA2969200C (fr) |
SG (1) | SG11201704242TA (fr) |
WO (1) | WO2016114146A1 (fr) |
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JP6447253B2 (ja) * | 2015-03-06 | 2019-01-09 | 新日鐵住金株式会社 | 溶接用高張力鋼 |
CN113737103A (zh) * | 2017-09-08 | 2021-12-03 | 杰富意钢铁株式会社 | 钢板及其制造方法 |
JP6984319B2 (ja) * | 2017-10-31 | 2021-12-17 | 日本製鉄株式会社 | 靭性に優れた低温用ニッケル含有鋼板およびその製造方法 |
KR101999024B1 (ko) * | 2017-12-26 | 2019-07-10 | 주식회사 포스코 | 수소유기균열 저항성이 우수한 강재 및 그 제조방법 |
CN110318008B (zh) * | 2019-06-20 | 2022-01-14 | 江阴兴澄特种钢铁有限公司 | 一种大厚度抗层状撕裂屈服强度960MPa级高强钢板及其生产方法 |
CN110172646A (zh) * | 2019-06-24 | 2019-08-27 | 南京钢铁股份有限公司 | 一种船用储罐p690ql1钢板及制造方法 |
KR102255821B1 (ko) * | 2019-09-17 | 2021-05-25 | 주식회사 포스코 | 저온 충격인성이 우수한 고강도 극후물 강재 및 이의 제조방법 |
KR102509355B1 (ko) | 2020-12-21 | 2023-03-14 | 주식회사 포스코 | 표면품질 및 내 라멜라티어링 품질이 우수한 스팀드럼용 극후물 강재 및 그 제조방법 |
CN114032453B (zh) * | 2021-10-14 | 2022-06-21 | 首钢集团有限公司 | 一种大厚度1000MPa级非调质高韧性结构用钢及其制备方法 |
KR20230094388A (ko) | 2021-12-21 | 2023-06-28 | 주식회사 포스코 | 강도 및 저온 충격인성이 우수한 플랜지용 극후물 강재 및 그 제조방법 |
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JP2002210502A (ja) * | 2001-01-19 | 2002-07-30 | Kawasaki Steel Corp | 極厚鋼材の製造方法 |
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- 2016-01-15 CA CA2969200A patent/CA2969200C/fr active Active
- 2016-01-15 WO PCT/JP2016/000197 patent/WO2016114146A1/fr active Application Filing
- 2016-01-15 EP EP16737217.6A patent/EP3246426B1/fr active Active
- 2016-01-15 CN CN201680005979.9A patent/CN107208212B/zh active Active
- 2016-01-15 JP JP2016532648A patent/JP6048626B1/ja active Active
- 2016-01-15 SG SG11201704242TA patent/SG11201704242TA/en unknown
- 2016-01-15 US US15/543,364 patent/US20170369958A1/en not_active Abandoned
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CN107208212B (zh) | 2020-01-17 |
SG11201704242TA (en) | 2017-06-29 |
JP6048626B1 (ja) | 2016-12-21 |
CA2969200A1 (fr) | 2016-07-21 |
KR101994784B1 (ko) | 2019-07-01 |
KR20170095307A (ko) | 2017-08-22 |
CN107208212A (zh) | 2017-09-26 |
WO2016114146A1 (fr) | 2016-07-21 |
EP3246426A1 (fr) | 2017-11-22 |
EP3246426A4 (fr) | 2018-01-10 |
US20170369958A1 (en) | 2017-12-28 |
JPWO2016114146A1 (ja) | 2017-04-27 |
CA2969200C (fr) | 2020-06-02 |
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