Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
  • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
  • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
  • B01D53/047—Pressure swing adsorption
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D51/00—Auxiliary pretreatment of gases or vapours to be cleaned
  • B01D51/10—Conditioning the gas to be cleaned
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
  • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
  • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
  • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
  • B01D53/0407—Constructional details of adsorbing systems
  • B01D53/0431—Beds with radial gas flow
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
  • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
  • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
  • B01D53/047—Pressure swing adsorption
  • B01D53/0476—Vacuum pressure swing adsorption
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
  • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
  • B01D53/06—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
  • B01D53/26—Drying gases or vapours
  • B01D53/261—Drying gases or vapours by adsorption
• • C—CHEMISTRY; METALLURGY
  • C01—INORGANIC CHEMISTRY
  • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
  • C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
  • C01B13/02—Preparation of oxygen
  • C01B13/0229—Purification or separation processes
  • C01B13/0248—Physical processing only
  • C01B13/0259—Physical processing only by adsorption on solids
  • C01B13/0262—Physical processing only by adsorption on solids characterised by the adsorbent
• • C—CHEMISTRY; METALLURGY
  • C01—INORGANIC CHEMISTRY
  • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
  • C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
  • C01B13/02—Preparation of oxygen
  • C01B13/0229—Purification or separation processes
  • C01B13/0248—Physical processing only
  • C01B13/0259—Physical processing only by adsorption on solids
  • C01B13/0262—Physical processing only by adsorption on solids characterised by the adsorbent
  • C01B13/0266—Carbon based materials
• • C—CHEMISTRY; METALLURGY
  • C01—INORGANIC CHEMISTRY
  • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
  • C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
  • C01B13/02—Preparation of oxygen
  • C01B13/0229—Purification or separation processes
  • C01B13/0248—Physical processing only
  • C01B13/0259—Physical processing only by adsorption on solids
  • C01B13/0262—Physical processing only by adsorption on solids characterised by the adsorbent
  • C01B13/027—Zeolites
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
  • B01D2253/10—Inorganic adsorbents
  • B01D2253/104—Alumina
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
  • B01D2253/10—Inorganic adsorbents
  • B01D2253/106—Silica or silicates
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
  • B01D2253/10—Inorganic adsorbents
  • B01D2253/106—Silica or silicates
  • B01D2253/108—Zeolites
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
  • B01D2253/10—Inorganic adsorbents
  • B01D2253/106—Silica or silicates
  • B01D2253/108—Zeolites
  • B01D2253/1085—Zeolites characterized by a silicon-aluminium ratio
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
  • B01D2253/20—Organic adsorbents
  • B01D2253/204—Metal organic frameworks (MOF's)
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2256/00—Main component in the product gas stream after treatment
  • B01D2256/10—Nitrogen
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2256/00—Main component in the product gas stream after treatment
  • B01D2256/12—Oxygen
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2257/00—Components to be removed
  • B01D2257/10—Single element gases other than halogens
  • B01D2257/102—Nitrogen
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2259/00—Type of treatment
  • B01D2259/40—Further details for adsorption processes and devices
  • B01D2259/40001—Methods relating to additional, e.g. intermediate, treatment of process gas
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2259/00—Type of treatment
  • B01D2259/40—Further details for adsorption processes and devices
  • B01D2259/414—Further details for adsorption processes and devices using different types of adsorbents
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
  • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
  • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents

Definitions

• the present invention relates to an adsorption purification unit comprising the combination of a regenerative element comprising structured adsorbents and an adsorber filled with a particulate adsorbent.
• adsorption processes can be used.
• several adsorbers filled with selective adsorbent materials are used with respect to at least one of the constituents of the feed stream.
• the gas circulates vertically through an adsorbent bed
• the gas circulates radially, either from the inside to the outside (relative to the adsorption phase) in centrifugal configuration, or from the outside in centripetal configuration.
• V PSA designating one or the other 2 units but also a combination of 2.
• Axial technology is inexpensive but when dealing with high flow rates, head losses and attrition problems become limiting.
• one solution consists in moving in radial geometry resulting in a limitation of the pressure drops without increasing the radius of the adsorber.
• the radial adsorber provides an increased passage area for a given adsorber volume and is theoretically not subject to limitation vis-à-vis the attrition phenomena.
• the adsorbent bed can be suspended between vertical perforated grids suspended from the top.
• the most known disadvantages of this radial technology are an increase in dead volumes and a high manufacturing cost.
• a PSA or TSA type adsorption process comprising two types of adsorbents (A and B) requiring a passage of gas in A before B in the adsorption phase and the amount of adsorbent B required is very large relative to the amount A.
• the adsorber comprising 2 beds, 3 grids are generally used to maintain the particulate materials.
• the material A is situated between the so-called “external” grid and the so-called “intermediate” grid, while the material B is maintained between the same intermediate grid and the so-called “internal” grid.
• This disproportion A / B then accentuates on the one hand the difficulties of construction of said radial adsorber since the diameters of the outer and intermediate grids are close together, and consequently makes it difficult to maintain a regular thickness of the bed due to idealities and possible deformations of the grids may lead to preferential passages in areas where the thickness of sieve would be less.
• one solution consists in reversing the flow direction of the gases as well as the distribution of the adsorbents, so that the adsorbent A is located between the internal gate and the intermediate gate and that the adsorbent B is between the intermediate grid and the external grid.
• the adsorber With a flow of gas from the inside to the outside of the bottle in the adsorption phase, the adsorber is thus in a "radial centrifugal" configuration (FIG. 1).
• centrifugal configuration may be less energy efficient than the centripetal solution.
• VSA 02 where this centrifugal configuration substantially increases the pressure losses and therefore penalizes the specific energy of the process, as well as the case of TSA where the regeneration of the outside towards the inside will increase the losses. thermal.
• VSA 02 are conventionally constituted of two beds, the first being a low-volume layer of alumina (silica gel or certain zeolites are also used alone or in combination) whose purpose is to stop the water contained in the supply air and the second is a layer of zeolite selectively retaining nitrogen with respect to oxygen.
• alumina silicon gel or certain zeolites are also used alone or in combination
• VSA 02. A geometry allowing to preserve the centripetal configuration called “mushroom” was used for these VSA 02. It consisted in installing in the bottom of the adsorber a layer of granulated alumina retained between two grids with a radial circulation of the fluid or more simply disposed in axial configuration. Yes this solution makes it possible to maintain a centripetal radial configuration for the zeolite, it nonetheless considerably complicates the construction and entails a significant additional cost.
• a solution of the present invention is a purification unit by adsorption of a gas stream of (V) PSA type comprising successively in the direction of flow of the feed gas stream:
• a rotatable structured adsorbent wheel configured to cause the gas flow to pass axially and to dry the feed gas to a level corresponding to a dew point of less than -30 ° C (which is will then qualify as "dry" flow);
• an adsorber of centripetal radial configuration comprising a bed of particulate adsorbent.
• particulate adsorbent material is meant an adsorbent in the form of grains, balls, rods ... of millimeter size, generally of equivalent diameter (diameter equivalent to the sphere of the same volume) in the range of 0.5 to 5 mm .
• Structured adsorbent means solid materials ranging in size from a few centimeters to a few meters and having free passageways gas, such as monoliths, foams or fabrics.
• the structured adsorbents have (in comparison with granulated adsorbents) the peculiarity of allowing very good kinetics and very low pressure losses without having a known limit of attrition.
• the structured adsorbent used preferentially is a contactor with parallel passages.
• parallel passage contactor is meant a device in which the fluid passes into channels whose walls contain adsorbent.
• the fluid circulates in essentially obstacle free channels, these channels allowing the fluid to flow from an input to an output of the contactor.
• These channels can be rectilinear connecting directly the input to the output of the contactor or present changes of direction.
• the fluid is in contact with at least one adsorbent present at said walls.
• the unit according to the invention may have one or more of the following characteristics:
• the adsorbent wheel comprises at least one zone dedicated to adsorption and at least one zone dedicated to regeneration;
• the zone dedicated to the regeneration comprises at least a first portion subjected to a hot flow, ie at a temperature greater than the temperature of the feed stream, preferably at least 20 ° C. higher than the temperature of the feed stream ; and a second portion subjected to a flow (cold flow) at a temperature below the temperature of the flow (hot flow) to which the first portion is subjected, preferably at plus or minus 10 degrees Celsius of the temperature of the feed stream;
• the adsorber consists of a cylindrical shell and two bottoms and the particulate adsorbent bed is held in place by means of two perforated grids arranged in a concentric manner; the ratio of the volume of particulate adsorbent to the volume of structured adsorbent is between 2 and 100.
• the particulate adsorbent comprises alumina balls, silica gel, active charcoal, MOF or type A, X or Y zeolites.
• the structured adsorbent comprises channels whose walls contain an adsorbent.
• the adsorbent contained in the walls of the channels is chosen from alumina, silica gel, activated carbon or zeolites of type A, X or Y.
• the subject of the present invention is also a process for purification by adsorption of a gaseous flow using a purification unit according to the invention, in which the adsorbent wheel follows a pressure cycle comprising an adsorption step and a regeneration step and a rotation of the adsorbent wheel is performed at the end of each adsorption step.
• the method according to the invention may have one or more of the following characteristics:
• the adsorbent wheel comprises at least one zone dedicated to adsorption and at least one zone dedicated to regeneration, the zone dedicated to adsorption receives the gaseous feed flow, the zone dedicated to regeneration receives a flow gaseous regeneration, and continuously the area dedicated to adsorption becomes the area dedicated to regeneration and conversely the area dedicated to regeneration becomes the area dedicated to the adsorption by rotation of the adsorbent wheel;
• the purified stream or the residual stream is used as the regeneration flow of the adsorber of centripetal radial configuration
• said process processes an air flow rate of at least 10000 Nm 3 / h.
• the structured adsorbent preferentially used is in the form of a wheel thus allowing its partition into several dedicated zones.
• zone is meant at least one zone dedicated to the adsorption phase B1 and at least one zone dedicated to the regeneration phase B2 (FIG. 3).
• the operation of a centripetal radial adsorber having only a single selective adsorbent is shown in FIG. 2.
• the fluid to be purified or separated 1 enters at the bottom of the radial adsorber 10, passes through the adsorbent mass 20 and the product exits in the upper part 2.
• the regeneration fluid 3 enters the countercurrent by the upper part, desorbs the impurities contained in the adsorbent mass 20 and the waste gas 4 leaves at the bottom.
• the adsorber itself 10 consists of a cylindrical shell of vertical axis AA and two funds.
• the adsorbent mass is held in place by means of a perforated outer grid 1 1 and an internally perforated grid 12 fixed on the upper bottom and a solid plate 13 in the lower part.
• the gas 1 circulates vertically at the periphery in the outer free zone 14 between the cylindrical shell and the external grid, passes radially through the adsorbent mass 20 and then flows vertically in the internal free zone 15 before leaving the adsorber from above. Regeneration is carried out in the opposite direction.
• FIG. 4 The operation of a "rotary" wheel having several dedicated sectors is shown in FIG. 4.
• the feed gas stream to be dried or separated 1 enters the lower part of wheel A via zone 1, the dry product then exiting in 2.
• the regeneration is carried out in the opposite direction, the hot flow arrives at 3, passes through the wheel A via the zone 2; the flow then loaded with impurity leaves at 4.
• a possible zone 3 can be used for the complete regeneration of the wheel A and to best prepare the next adsorption phase, the cold flow used between in 5 and out of the sector 3 in 6. Note that it is preferable to cool the adsorbent mass before going into adsorption to avoid disturbing the downstream process and more simply because if the adsorbent mass is hot, it adsorbs little. This flow must be imperatively dry, ie with a dew point below -30 ° C
• VSA 02 the supply of the air flow and the adsorbent volume regeneration are provided by rotating machines, usually of the volumetric type.
• rotating machines usually of the volumetric type.
• root technology machines are used both for blowing / compressing the incoming air and for purging the adsorber, respectively called “blower” and "vacuum pump”.
• Blower and "vacuum pump”.
• vacuum pump we will move to a vacuum pump technology to provide a dry gas or optionally at low humidity at a temperature above 80 ° C or to the final oxygen compressor to provide a dry gas and hot.
• the coupled operation of said radial adsorber and of said wheel is shown in FIG. 5.
• the fluid to be purified or separated 1 is compressed via a rotating machine A generally of the fan type and is then sent into the wheel B via the flow 2.
• the flow 2 crosses the adsorbent mass of the wheel B, via the zone dedicated to the purification B1.
• the purified stream 3 is sent to the radial adsorber.
• the end product leaves the adsorber C in centripetal circulation via the flow 4.
• the regeneration is carried out in the opposite direction, the impurities are desorbed by the rotating machine D generally of the vacuum pump type by the flow 5.
• the flow of impurities 6 heated via the operation of the rotating machine D enters the regeneration sector B2 of said desiccant wheel B.
• the flow 7 containing the impurities of said radial adsorber C and said wheel B is sent to a vent.
• FIG. 6 Another possible operating scheme is shown in FIG. 6.
• the general operation of the method presented is similar to that of FIG. 5.
• the regeneration of the desiccant wheel B via the zone B2 is here ensured by the flow 5, dry and hot from the final product compressor E.
• the stream 6 then contains the recoverable product and the impurities contained in the desiccant wheel B.
• Figure 7 provides an illustration of this mode of operation.
• a possible cooling of the regeneration zone of the desiccant wheel B in particular by the use of a zone B3 can be provided via the flow 10 previously cooled by the establishment of a cold circuit E at the output of the rotating machine D.
• This optional cooling to complete the regeneration of the desiccant wheel B and prepare the best zone B1 dedicated to the adsorption phase.
• the speed and cycle of rotation of the desiccant wheel are related to the operating cycle of the process (V) PSA.
• An adsorption process according to the invention has the following advantages: it allows
• the unit according to the invention presented can be used in various PSA processes such as H2 PSA to produce high purity hydrogen, PSA C0 2 , PSA 0 2 , ... It can also be used to dry, decarbonate or stopping secondary impurities of a gas stream, in particular from atmospheric air.
• secondary impurities we mean the traces of hydrocarbons, NOx, SOx ...
• the adsorber according to the invention can be used in VSA 0 2 processes making it possible to treat an air flow rate ranging from a thousand to more than 40,000 Nm 3 / h, or even more than 60,000 Nm 3 / h.
• VSA 02s (allowing the production of more than 30 tonnes / day of oxygen with a standard purity greater than 90%) are economically advantageous to be radial and of centrifugal configuration in order to preserve a sufficiently large thickness of alumina.
• a rotating structured adsorbent wheel comprising alumina or silica gel creating little pressure drop and lowering the dew point of the gas feeding at a temperature below -30 ° C, and through which the gas would flow axially;
• a particulate adsorbent bed composed of granulated LiLSX sieve, for separating oxygen from nitrogen, and conventionally disposed between two concentric grids in said centripetal adsorber, and whose hot waste gas is used to regenerate the rotating unit upstream.

Landscapes

• Chemical & Material Sciences (AREA)
• Analytical Chemistry (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Engineering & Computer Science (AREA)
• Organic Chemistry (AREA)
• Oil, Petroleum & Natural Gas (AREA)
• General Chemical & Material Sciences (AREA)
• Inorganic Chemistry (AREA)
• Materials Engineering (AREA)
• Life Sciences & Earth Sciences (AREA)
• General Life Sciences & Earth Sciences (AREA)
• Geology (AREA)
• Separation Of Gases By Adsorption (AREA)
• Drying Of Gases (AREA)
• Solid-Sorbent Or Filter-Aiding Compositions (AREA)
• Drying Of Solid Materials (AREA)

Applications Claiming Priority (2)

Publications (1)

Family

ID=51862445

Family Applications (1)

Country Status (5)

Families Citing this family (8)

Family Cites Families (13)

• 2014
  • 2014-08-01 FR FR1457481A patent/FR3024376B1/fr active Active
• 2015
  • 2015-07-20 CN CN201580050049.0A patent/CN107073383A/zh active Pending
  • 2015-07-20 EP EP15751050.4A patent/EP3174618A1/fr not_active Withdrawn
  • 2015-07-20 WO PCT/FR2015/051992 patent/WO2016016543A1/fr active Application Filing
  • 2015-07-20 US US15/500,832 patent/US10413859B2/en active Active

Non-Patent Citations (2)

Also Published As

Similar Documents

Legal Events