EP3125351B1 - Batterie rechargeable tout solide - Google Patents
Batterie rechargeable tout solide Download PDFInfo
- Publication number
- EP3125351B1 EP3125351B1 EP15769914.1A EP15769914A EP3125351B1 EP 3125351 B1 EP3125351 B1 EP 3125351B1 EP 15769914 A EP15769914 A EP 15769914A EP 3125351 B1 EP3125351 B1 EP 3125351B1
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- EP
- European Patent Office
- Prior art keywords
- current collector
- positive electrode
- electrode current
- layer
- solid
- Prior art date
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- 239000007784 solid electrolyte Substances 0.000 claims description 36
- 238000012360 testing method Methods 0.000 claims description 29
- 229910003480 inorganic solid Inorganic materials 0.000 claims description 15
- 239000002131 composite material Substances 0.000 claims description 14
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 9
- 239000011888 foil Substances 0.000 claims description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 6
- 125000000101 thioether group Chemical group 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 4
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 40
- 229910001416 lithium ion Inorganic materials 0.000 description 40
- 239000000463 material Substances 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 10
- 238000000465 moulding Methods 0.000 description 9
- 239000007772 electrode material Substances 0.000 description 8
- 229910009297 Li2S-P2S5 Inorganic materials 0.000 description 7
- 229910009228 Li2S—P2S5 Inorganic materials 0.000 description 7
- 239000007773 negative electrode material Substances 0.000 description 5
- 239000007774 positive electrode material Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 4
- 230000032798 delamination Effects 0.000 description 4
- 150000002484 inorganic compounds Chemical class 0.000 description 4
- 229910010272 inorganic material Inorganic materials 0.000 description 4
- 229910052744 lithium Inorganic materials 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229910001216 Li2S Inorganic materials 0.000 description 3
- 238000000469 dry deposition Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229910052718 tin Inorganic materials 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 229910032387 LiCoO2 Inorganic materials 0.000 description 1
- 229910002995 LiNi0.8Co0.15Al0.05O2 Inorganic materials 0.000 description 1
- 229910003005 LiNiO2 Inorganic materials 0.000 description 1
- 229910013485 LiNixM1-xO2 Inorganic materials 0.000 description 1
- 229910013495 LiNixM1−xO2 Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910021383 artificial graphite Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- QHGJSLXSVXVKHZ-UHFFFAOYSA-N dilithium;dioxido(dioxo)manganese Chemical compound [Li+].[Li+].[O-][Mn]([O-])(=O)=O QHGJSLXSVXVKHZ-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 229910021440 lithium nickel complex oxide Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 229910021382 natural graphite Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- -1 oxide Chemical compound 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
- H01M10/0562—Solid materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
- H01M10/0585—Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/661—Metal or alloys, e.g. alloy coatings
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/60—Other road transportation technologies with climate change mitigation effect
- Y02T10/70—Energy storage systems for electromobility, e.g. batteries
Definitions
- the present invention relates to an all-solid-state secondary battery.
- electrode materials interposed between a positive electrode current collector and a negative electrode current collector is pressure-molded in order to reduce the grain boundary resistance of an electrode material consisting of particulate matters.
- a sulfide inorganic solid electrolyte used as an electrode material particularly has high binding strength and ductility and thus the pressure molding improves adhesion between particles in the electrode material. Moreover, a sulfide inorganic solid electrolyte has lower ionic conductance than an oxide inorganic solid electrolyte and thus the pressure molding is important. Furthermore, the positive electrode current collector and the negative electrode current collector are made of high adhesive materials, thereby reducing an electric resistance between the positive electrode current collector and the negative electrode current collector and the electrode material.
- the all-solid-state lithium ion secondary battery in which a sulfide inorganic solid electrolyte is used as an electrode material, is however warped to the positive side or the negative side by the pressure molding. If the all-solid-state lithium ion secondary battery has a small maximum outside dimension, the amount of curving is negligibly small, and therefore may not be a problem, whereas if the all-solid-state lithium ion secondary battery has a large maximum outside dimension, the amount of curving is disadvantageously large, and therefore may be a problem. Correcting such a warp may crack the electrode material.
- An all-solid-state lithium ion secondary battery for preventing such a warp is proposed, in which a positive-electrode active material layer, a solid electrolyte layer, a negative-electrode active material layer, and a negative electrode current collector are stacked on each side of a positive electrode current collector (for example, Patent Literature 1).
- JP 2009 289534 A relates to an electrode for an all-solid lithium battery.
- Patent Literature 1 Japanese Patent Laid-Open No. 2001-126756
- an all-solid-state secondary battery is a single cell battery, the manufacturing process can be advantageously shortened with simple wiring.
- the all-solid-state lithium ion secondary battery of Patent Literature 1 has a multilayer cell. In other words, unfortunately, the all-solid-state lithium ion secondary battery cannot be a single-cell battery.
- An object of the present invention is to provide a single-cell all-solid-state secondary battery capable of suppressing warping.
- an all-solid-state secondary battery according to the present invention is defined in claim 1.
- the all-solid-state secondary battery allows a warp of the positive electrode current collector and the positive electrode layer and a warp of the negative electrode current collector and the negative electrode layer to cancel each other in a single cell, thereby suppressing warping even in a single cell.
- an all-solid-state secondary battery according to an embodiment of the present invention will be described below in accordance with the accompanying drawings.
- the all-solid-state secondary battery is exemplified by an all-solid-state secondary battery containing a solid electrolyte having lithium ion conductivity, that is, an all-solid-state lithium ion secondary battery.
- the all-solid-state lithium ion secondary battery includes a lithium-ion-conductivity solid electrolyte layer (which, hereinafter, will be simply referred to as a solid electrolyte layer 3) disposed (stacked) between a positive electrode layer 2 and a negative electrode layer 4.
- a positive electrode current collector 1 is disposed (stacked) on the opposite surface of the positive electrode layer 2 from the solid electrolyte layer 3 while a negative electrode current collector 5 is disposed (stacked) on the opposite surface of the negative electrode layer 4 from the solid electrolyte layer 3.
- the positive electrode layer 2 and the negative electrode layer 4 naturally act as electrodes, that is, electrode layers.
- the positive electrode layer 2 and the negative electrode layer 4 both contain a sulfide inorganic solid electrolyte, which will be specifically described later.
- the positive electrode layer 2, the solid electrolyte layer 3, and the negative electrode layer 4 are all made of powder materials.
- An insulating film 6 may be disposed around the circumference of the positive electrode layer 2.
- the positive electrode layer 2 disposed on the surface of the positive electrode current collector 1 is pressure-molded.
- the positive electrode layer 2 tends to be compressed in the thickness (stacking) direction and to expand in the width direction but cannot be expanded in the width direction because of a friction force F applied opposite to the width direction from the positive electrode current collector 1.
- This generates a residual stress for expansion in the width direction on the positive electrode layer 2, but as shown in FIG. 4 , the pressure-molded positive electrode layer 2 becomes free of the residual stress so as to tend to be expanded in the width direction.
- the peel strength of the positive electrode current collector 1 relative to the sulfide inorganic solid electrolyte in a 90° peel test is smaller than 0.2 N/mm, adhesion is low between the positive electrode current collector 1 and the positive electrode layer 2 (containing the sulfide inorganic solid electrolyte). In this case, as shown in FIG. 5 , the positive electrode layer 2 expanding so as to slide on the surface of the positive electrode current collector 1 does not affect the shape of the positive electrode current collector 1.
- the peel strength of the positive electrode current collector 1 relative to the sulfide inorganic solid electrolyte in a 90° peel test is not smaller than 0.2 N/mm, adhesion is high between the positive electrode current collector 1 and the positive electrode layer 2.
- the positive electrode layer 2 expands while digging into the surface of the positive electrode current collector 1. This causes a warp of the positive electrode current collector 1.
- a warp of the positive electrode current collector 1 and the positive electrode layer 2 and a warp of the negative electrode current collector 5 and the negative electrode layer 4 cancel each other so as to suppress warping of the overall all-solid-state lithium ion secondary battery.
- the positive electrode layer 2 contains a mixture of a positive-electrode active material and a lithium-ion-conductivity solid electrolyte.
- the weight ratio between the positive-electrode active material and the lithium-ion-conductivity solid electrolyte in the mixture is, for example, 7:3.
- the positive-electrode active material is an ordinary material used in the battery field, for example, lithium-nickel complex oxide (LiNi x M 1-x O 2 ; M is at least one element selected from Co, Al, Mn, V, Cr, Mg, Ca, Ti, Zr, Nb, Mo, and W), lithium cobaltate (LiCoO 2 ), lithium nickelate (LiNiO 2 ), or lithium manganate (LiMnO 2 ).
- lithium-nickel complex oxide LiNi x M 1-x O 2
- M is at least one element selected from Co, Al, Mn, V, Cr, Mg, Ca, Ti, Zr, Nb, Mo, and W
- LiCoO 2 lithium cobaltate
- LiNiO 2 lithium nickelate
- LiMnO 2 lithium manganate
- the negative electrode layer 4 contains a mixture of a negative-electrode active material and a lithium-ion-conductivity solid electrolyte.
- the weight ratio between the negative-electrode active material and the lithium-ion-conductivity solid electrolyte in the mixture is, for example, 6:4.
- the negative-electrode active material is an ordinary powder or foil material used in the battery field, for example, a carbon material such as natural graphite, artificial graphite, graphite carbon fibers, and resin baked carbon, silicon, tin, lithium, oxide, sulfide, nitrides or an alloy regardless of the shape of the material.
- the lithium-ion-conductivity solid electrolyte for the positive electrode layer 2, the solid electrolyte layer 3, and the negative electrode layer 4 is, for example, an organic compound, an inorganic compound, a material containing organic and inorganic compounds, or an ordinary material used in the field of lithium ion batteries.
- sulfides such as Li 2 S-P 2 S 5 of inorganic compounds have higher ionic conductance than other inorganic compounds.
- the positive electrode current collector 1 and the negative electrode current collector 5 are made of materials such as tin on an untreated surface, etched aluminum ( FIG. 8 ) on a surface where multiple spongiform pores are formed by etching, and roughened copper on a surface where multiple low pyramids are formed ( FIG. 9 ). These materials are shaped like a plate, foil, a film, or a metal foil composite.
- the metal foil composite is a composite which is coated metallic foil, for example, stainless foil coated with carbon.
- the positive electrode current collector 1 and the negative electrode current collector 5 may be made of the same material or different materials.
- the positive electrode current collector 1 and the negative electrode current collector 5 achieve a high peel strength (at least 0.2 N/mm) relative to the sulfide inorganic solid electrolyte in a 90° peel test.
- the current collector 1 or 5 (positive electrode current collector 1 or negative electrode current collector 5) with a size of 50 mm (width direction) ⁇ 100 mm (longitudinal direction) had an Li 2 S-P 2 S 5 layer L of 14 mg/cm 2 with an even thickness formed.
- the thus obtained collector was pressed into a test piece with 300 MPa in the thickness (stacking) direction.
- test piece included the Li 2 S-P 2 S 5 layer L (not made of the same material as the positive electrode layer 2 or the negative electrode layer 4) in the peel test will be discussed below.
- an electrode composite material Pressure molding on the same material (hereinafter, will be referred to as an electrode composite material) as the positive electrode layer 2 or the negative electrode layer 4 reduces binding strength among fine particles.
- the binding strength is smaller than adhesion between the layer made of the electrode composite material and the current collector 1 or 5.
- the layer made of the electrode composite material is broken (may be called delamination) in a peel test. This does not cause peeling between the layer made of the electrode composite material and the current collector 1 or 5.
- a value measured by the peel test is not a peel strength between the layer made of the electrode composite material and the current collector 1 or 5 but a delamination strength of layer made of the electrode composite material.
- the peel test is to be precisely called a 90° peel test and thus the layer is peeled in the thickness (stacking) direction.
- the test piece includes the layer made of the electrode composite material
- the layer made of the electrode composite material undergoes delamination in a peel test.
- the actual all-solid-state lithium ion secondary battery tends to expand in the width direction instead of the thickness (stacking) direction, thereby preventing delamination of an electrode material.
- the current collector 1 or 5 is bonded with equal adhesion to any one of the layer made of the electrode composite material and the Li 2 S-P 2 S 5 layer L.
- One end of the Li 2 S-P 2 S 5 layer L (in the longitudinal direction) of the test piece is fixed to a testing stand B with adhesive A while the other end of the test piece (in the longitudinal direction) is pulled by a chuck C.
- the pulling direction of the chuck C is always orthogonal to the surface of the testing stand B.
- the Li 2 S-P 2 S 5 layer L with one end fixed to the testing stand B and the other end pulled by the chuck C is broken sometime.
- the Li 2 S-P 2 S 5 layer L fixed to the testing stand B and the current collector 1 or 5 start peeling off from each other.
- a load is measured by the chuck C.
- the completion of peeling as shown in FIG. 12 , the measurement is also completed.
- the mean value of loads thus obtained by the measurement is divided by the widthwise length of the test piece to determine the peel strength of a 90° peel test.
- the positive electrode layer 2 is formed on the surface of the positive electrode current collector 1 by a dry deposition method.
- the solid electrolyte layer 3 is formed on the opposite surface of the positive electrode layer 2 from the positive electrode current collector 1 by the dry deposition method.
- the negative electrode layer 4 is formed on the opposite surface of the solid electrolyte layer 3 from the positive electrode layer 2 by the dry deposition method.
- the negative electrode current collector 5 is then stacked on the opposite surface of the negative electrode layer 4 from the solid electrolyte layer 3.
- a pressure is applied from the positive electrode current collector 1 and the negative electrode current collector 5 in the thickness (stacking) direction so as to apply a pressure of 98kN/cm 2 (10 tf/cm 2 , 980 MPa) to the positive electrode layer 2.
- the all-solid-state lithium ion secondary battery is thus fabricated.
- the all-solid-state lithium ion secondary battery allows a warp of the positive electrode current collector 1 and the positive electrode layer 2 and a warp of the negative electrode current collector 5 and the negative electrode layer 4 to cancel each other in a single cell, thereby suppressing warping even in a single cell.
- the positive electrode current collector was made of etched aluminum (high adhesion) while the negative electrode current collector was made of electrolytic copper foil (low adhesion).
- the amount of curving caused by warping was 15 to 20 mm ( FIG. 13 ).
- the positive electrode current collector was made of stainless foil (low adhesion) while the negative electrode current collector was made of roughened copper (high adhesion).
- the same amount of curving was caused by warping as in comparative example 1.
- the positive electrode current collector 1 was made of etched aluminum (high adhesion) while the negative electrode current collector was made of roughened copper (high adhesion).
- the amount of curving caused by warping could be suppressed to 5 to 6 mm, which is one third that of the comparative example ( FIG. 14 ).
- the positive electrode current collector 1 was made of tin (high adhesion) while the negative electrode current collector 5 was made of roughened copper (high adhesion).
- the amount of curving caused by warping could be suppressed as in example 1, although not shown.
- the all-solid-state lithium ion secondary battery was described as an example of an all-solid-state secondary battery.
- the present invention is not limited to all-solid-state lithium ion secondary batteries, as long as it is an all-solid-state secondary battery.
- the specific materials of the positive electrode current collector 1 and the negative electrode current collector 5 were described.
- the present invention is not limited to these materials as long as the peel strength of the positive electrode current collector 1 and the negative electrode current collector 5 relative to the sulfide inorganic solid electrolyte in a 90° peel test is at least 0.2 N/mm.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Secondary Cells (AREA)
- Cell Electrode Carriers And Collectors (AREA)
- Battery Electrode And Active Subsutance (AREA)
Claims (1)
- Batterie rechargeable tout solide comprenant:une couche d'électrode positive (2) et une couche d'électrode négative (4) qui sont disposées sur un collecteur de courant d'électrode positive (1) et un collecteur de courant d'électrode négative (5), respectivement, et sont mises sous pression sur celui-ci; etune couche d'électrolyte solide (3) interposée entre la couche d'électrode positive (2) et la couche d'électrode négative (4),caractérisée en ce quela couche d'électrode positive (2) et la couche d'électrode négative (4) contiennent un électrolyte solide inorganique sulfuré, et le collecteur de courant d'électrode positive (1) et le collecteur de courant d'électrode négative (5) ont une résistance à l'arrachement d'au moins 0,2 N/mm par rapport à la couche d'électrolyte solide inorganique sulfuré (L) dans un test d'arrachement à 90°, dans lequel, pour le test d'arrachement à 90°, le collecteur de courant d'électrode positive (1) ou le collecteur de courant d'électrode négative (5) sont pourvus d'une couche de l'électrolyte solide inorganique sulfuré d'épaisseur égale et le collecteur ainsi obtenu est comprimé dans une éprouvette avec une force dans le sens de l'épaisseur (empilement) de 300 MPa,la couche d'électrolyte solide (3) contient un électrolyte solide inorganique sulfuré,le collecteur de courant d'électrode positive (1) est un composite qui est une feuille métallique revêtue ou est constitué d'aluminium gravé ou d'étain, etle collecteur de courant d'électrode négative (5) est en cuivre rugueux.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2014067318 | 2014-03-28 | ||
PCT/JP2015/059286 WO2015147122A1 (fr) | 2014-03-28 | 2015-03-26 | Batterie rechargeable tout solide |
Publications (3)
Publication Number | Publication Date |
---|---|
EP3125351A4 EP3125351A4 (fr) | 2017-02-01 |
EP3125351A1 EP3125351A1 (fr) | 2017-02-01 |
EP3125351B1 true EP3125351B1 (fr) | 2019-06-05 |
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ID=54195629
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP15769914.1A Active EP3125351B1 (fr) | 2014-03-28 | 2015-03-26 | Batterie rechargeable tout solide |
Country Status (6)
Country | Link |
---|---|
US (1) | US20170179519A1 (fr) |
EP (1) | EP3125351B1 (fr) |
JP (1) | JP6639383B2 (fr) |
KR (1) | KR102350322B1 (fr) |
CN (1) | CN106068577B (fr) |
WO (1) | WO2015147122A1 (fr) |
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JP6647077B2 (ja) * | 2016-02-29 | 2020-02-14 | 日立造船株式会社 | 全固体二次電池およびその製造方法 |
JP6647113B2 (ja) * | 2016-03-31 | 2020-02-14 | 日立造船株式会社 | 全固体二次電池の製造方法 |
WO2017150354A1 (fr) * | 2016-02-29 | 2017-09-08 | 日立造船株式会社 | Batterie rechargeable entièrement solide et son procédé de fabrication |
US10446873B2 (en) * | 2016-12-30 | 2019-10-15 | Intel Corporation | Solid-state battery |
JP6931293B2 (ja) * | 2017-03-28 | 2021-09-01 | 三洋電機株式会社 | 二次電池の製造方法 |
JP7100798B2 (ja) * | 2018-01-09 | 2022-07-14 | トヨタ自動車株式会社 | 非水電解液二次電池 |
JP7182159B2 (ja) | 2018-12-12 | 2022-12-02 | パナソニックIpマネジメント株式会社 | 全固体電池 |
KR20220132175A (ko) * | 2021-03-23 | 2022-09-30 | 주식회사 엘지에너지솔루션 | 습윤 상태의 전극 시편에 대한 접착력 측정 시스템 및 이를 이용한 습윤 상태의 전극 시편에 대한 접착력 측정 방법 |
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JP3512549B2 (ja) * | 1995-01-25 | 2004-03-29 | 株式会社リコー | リチウム二次電池用負極および該負極を用いたリチウム二次電池 |
JP2001126756A (ja) | 1999-10-25 | 2001-05-11 | Kyocera Corp | リチウム固体電解質電池およびその製造方法 |
JP2009289534A (ja) * | 2008-05-28 | 2009-12-10 | Idemitsu Kosan Co Ltd | 全固体リチウム電池用電極、全固体リチウム電池および装置 |
JP5747506B2 (ja) * | 2009-11-25 | 2015-07-15 | トヨタ自動車株式会社 | 電極積層体の製造方法および電極積層体 |
JP5679748B2 (ja) * | 2010-09-21 | 2015-03-04 | 日立造船株式会社 | 全固体電池の製造方法 |
KR101303433B1 (ko) * | 2010-11-29 | 2013-09-05 | 제이에스알 가부시끼가이샤 | 전지용 결합제 조성물, 전지 전극용 슬러리, 고체 전해질 조성물, 전극 및 전고체형 전지 |
JP2013105679A (ja) * | 2011-11-15 | 2013-05-30 | Sumitomo Electric Ind Ltd | 非水電解質電池用電極、及び非水電解質電池、並びに電動車両 |
JP5902287B2 (ja) * | 2012-03-16 | 2016-04-13 | 株式会社東芝 | リチウムイオン伝導性硫化物、固体電解質二次電池および電池パック |
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- 2015-03-26 EP EP15769914.1A patent/EP3125351B1/fr active Active
- 2015-03-26 CN CN201580012833.2A patent/CN106068577B/zh active Active
- 2015-03-26 US US15/129,695 patent/US20170179519A1/en not_active Abandoned
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US20170179519A1 (en) | 2017-06-22 |
KR102350322B1 (ko) | 2022-01-11 |
KR20160138967A (ko) | 2016-12-06 |
CN106068577B (zh) | 2019-09-24 |
CN106068577A (zh) | 2016-11-02 |
JPWO2015147122A1 (ja) | 2017-04-13 |
WO2015147122A1 (fr) | 2015-10-01 |
JP6639383B2 (ja) | 2020-02-05 |
EP3125351A1 (fr) | 2017-02-01 |
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