EP3093549A1 - Véhicule comprenant un moteur à combustion interne,au moins une cuve de stockage et une chambre de refroidissement et/ou une unité de conditionnement d'air - Google Patents

Véhicule comprenant un moteur à combustion interne,au moins une cuve de stockage et une chambre de refroidissement et/ou une unité de conditionnement d'air Download PDF

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Publication number
EP3093549A1
EP3093549A1 EP15167069.2A EP15167069A EP3093549A1 EP 3093549 A1 EP3093549 A1 EP 3093549A1 EP 15167069 A EP15167069 A EP 15167069A EP 3093549 A1 EP3093549 A1 EP 3093549A1
Authority
EP
European Patent Office
Prior art keywords
storage vessel
fuel
vehicle
sorption
storage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP15167069.2A
Other languages
German (de)
English (en)
Inventor
Mathias WEICKERT
Lena Arnold
Ulrich Mueller
Stefan Marx
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to EP15167069.2A priority Critical patent/EP3093549A1/fr
Priority to PCT/EP2016/060389 priority patent/WO2016180807A1/fr
Publication of EP3093549A1 publication Critical patent/EP3093549A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C11/00—Use of gas-solvents or gas-sorbents in vessels
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C11/00—Use of gas-solvents or gas-sorbents in vessels
    • F17C11/005—Use of gas-solvents or gas-sorbents in vessels for hydrogen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C11/00—Use of gas-solvents or gas-sorbents in vessels
    • F17C11/007—Use of gas-solvents or gas-sorbents in vessels for hydrocarbon gases, such as methane or natural gas, propane, butane or mixtures thereof [LPG]

Definitions

  • the temperature increase constitutes a limitation especially for the ANG technique as for example carbon fiber tanks are presently only approved to operate at temperatures to up to 80°C.
  • a charge cycle normally will be performed in a fuel station, at least for mobile applications, where the released sorption heat can be removed.
  • desorption is an endothermic process and heat has to be supplied when gas is taken from the storage vessel.
  • the rate of discharge is dictated by the energy demand of the application.
  • Heat management is therefore of great importance when storage vessels with sorption medium are used. Heat management systems have to be optimized with regard to a minimum of required space and a minimum of additional weight in mobile applications, a minimum of additionally required electrical power and limited costs.
  • a vehicle comprising an internal combustion engine, at least one storage vessel and a cooling chamber and/or an air condition unit, wherein a sorption medium is disposed in the at least one storage vessel and the at least one storage vessel contains a fuel for the internal combustion engine, the combustion engine and the at least one storage vessel are connected by a pipe for conducting the fuel, and the at least one storage vessel is thermally coupled with the cooling chamber and/or air condition unit.
  • the desorption during discharge of the fuel from the at least one storage vessel leads to a temperature decrease in the at least one storage vessel, which is used to cool the cooling chamber and/or the air-condition unit as soon as the maximum temperature T max in the at least one storage vessel of less than 35°C is reached.
  • At least one pressure sensor and at least one temperature sensor are disposed in the interior of the at least one storage vessel. Sensors commonly used in the art and known for example from the CNG technique can be used for this purpose.
  • the position of the at least one pressure sensor can be freely selected at and/or in the at least one storage vessel as the pressure is equally distributed in the system.
  • the at least one temperature sensor is disposed in the at least one storage vessel in a position characterized by a temperature from which the average temperature of the interior of the at least one storage vessel is deducable. It is further preferred to provide a temperature sensor in a location in the at least one storage vessel, where maximum temperatures are expected. This is typically the case in a highest position at the storage vessel wall.
  • Remaining storage vessels can be filled up to 250 bar, these can be used later for cooling or fuel can be transferred from these storage vessels to the storage vessels with lower filling level.
  • all storage vessels comprise the sorption medium and all storage vessels are filled up to 250 bar, it is also possible to cool only one of the storage vessels during filling with the fuel.
  • a vehicle can for example comprise one storage vessel with a sorption medium and one storage vessel without sorption medium, both filled at the gas station to typically 250 bar.
  • fuel is first taken from the storage vessel without sorption medium, especially when no cooling, over the air condition unit for example, is currently required.
  • fuel can be transferred from the storage vessel with sorption medium to the storage vessel without sorption medium, which is already partly emptied, thus desorption occurs, even when no fuel is consumed at that instance, and the cooling power can be used.
  • the vehicle comprises the compressor and in the driving step (b) the fuel is recirculated from the at least one storage vessel to the compressor and back to the at least one storage vessel.
  • only one compressor can be used for both, recirculation of the fuel and supply of the fuel at a sufficient pressure level to the internal combustion engine.
  • the storage vessel is a pressure vessel for the storage of fuel at a pressure in the range of up to 500 bar, preferably in a range of 1 bar to 400 bar, most preferably in the range of 1 bar to 250 bar. In other embodiments, also the range of 1 bar to 100 bar can be preferred.
  • different cross-sectional areas are suitable for the storage vessel, for example circular, elliptical or rectangular. Irregularly shaped cross-sectional areas are also possible, e. g. when the storage vessel is to be fitted into a hollow space of a vehicle body. It is also possible to divide the total storage volume into more than one storage vessel.
  • the wall of the storage vessel comprises at least one outlet and at least one inlet. More preferably, the at least one inlet and the at least one outlet are provided at the same half of the storage vessel. The half can also be named as side or end.
  • the at least one inlet and the at least one outlet can be located in the same position and/or combined in one constructional part or adapter. The close arrangement of the at least one inlet and the at least one outlet is especially advantageous in order to establish the flow-through regime during filling or for recirculation of the fuel between the at least one storage vessel and the heat exchange.
  • the ratio of the permeability of the pellets to the smallest pellet diameter is between 1 ⁇ 10 -11 m 2 /m and 1 ⁇ 10 -16 m 2 /m, preferably between 1 ⁇ 10 -12 m 2 /m and 1 ⁇ 10 14 m 2 /m, and most preferably 1 ⁇ 10 -13 m 2 /m.
  • the sorption medium is present in form of at least one monolith and the at least one monolith has an extension in one direction in space in a range from 10 cm to 100 cm.
  • this extension in one direction in space is the radial diameter, referring to the at least one storage vessel, having preferably a cylindrical shape, with a longer axial extension than radial extension.
  • a monolith is understood to be a shaped body with a greater size compared to known sizes of typical shaped bodies like pellets.
  • the longest second extension of the monolith is in the range from 100 cm to 300 cm, more preferably from 150 cm to 200 cm and the longest first extension of the monolith is in a range from 30 cm to 100 cm, more preferably from 40 cm to 60 cm.
  • the at least one storage vessel has a cylindrical shape
  • each of the at least two monoliths has a disk-like shape and the at least two monoliths are arranged one next to the other in longitudinal axial direction of the at least one storage vessel.
  • the form of the circumference of the at least one storage vessel corresponds to the form of the circumference of each of the at least two monoliths.
  • the longest diameter of the opening is in the range from 0.3 % to 20 % of the longest diameter of the radial cross-sectional area of the at least one storage vessel. It is further preferred when the opening in the at least one monolith is arranged centrally with respect to the at least one storage vessel.
  • the sorption medium is preferably selected from the group consisting of activated charcoal, zeolites, activated aluminia, silica gels, open-pore polymer foams, metal hydrides, metal-organic frameworks (MOF) and combinations thereof.
  • Metal-organic frameworks are known in the prior art and are described for example in US 5,648,508 , EP-A 0 700 253 , M. O'Keeffe et al., J. Sol. State Chem., 152 (2000), pages 3 to 20 , H. Li et al., Nature 402, 1 (1999), page 276 , M. Eddaoudi et al., Topics in Catalysis 9, (1999), pages 105 to 111 , B.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
EP15167069.2A 2015-05-11 2015-05-11 Véhicule comprenant un moteur à combustion interne,au moins une cuve de stockage et une chambre de refroidissement et/ou une unité de conditionnement d'air Withdrawn EP3093549A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP15167069.2A EP3093549A1 (fr) 2015-05-11 2015-05-11 Véhicule comprenant un moteur à combustion interne,au moins une cuve de stockage et une chambre de refroidissement et/ou une unité de conditionnement d'air
PCT/EP2016/060389 WO2016180807A1 (fr) 2015-05-11 2016-05-10 Véhicule comprenant un moteur à combustion interne, au moins un récipient de stockage et une chambre de refroidissement et, facultativement, une unité de conditionnement d'air

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP15167069.2A EP3093549A1 (fr) 2015-05-11 2015-05-11 Véhicule comprenant un moteur à combustion interne,au moins une cuve de stockage et une chambre de refroidissement et/ou une unité de conditionnement d'air

Publications (1)

Publication Number Publication Date
EP3093549A1 true EP3093549A1 (fr) 2016-11-16

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP15167069.2A Withdrawn EP3093549A1 (fr) 2015-05-11 2015-05-11 Véhicule comprenant un moteur à combustion interne,au moins une cuve de stockage et une chambre de refroidissement et/ou une unité de conditionnement d'air

Country Status (2)

Country Link
EP (1) EP3093549A1 (fr)
WO (1) WO2016180807A1 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017009458A1 (fr) 2015-07-15 2017-01-19 Basf Se Procédé de préparation d'un arylpropène
EP3504277B1 (fr) 2016-08-23 2020-10-07 Basf Se Materiaux composite
US11091425B2 (en) 2016-11-30 2021-08-17 Basf Se Process for the conversion of ethylene glycol to ethylenediamine employing a zeolite catalyst
EP3585765A1 (fr) 2016-11-30 2020-01-01 Basf Se Procédé de conversion de la monoéthanolamine en éthylènediamine utilisant une zéolite modifiée par du cuivre de la structure d'ossature de mor
EP3619190B1 (fr) 2017-05-03 2021-08-04 Basf Se Procédé de conversion d'oxyde d'éthylène en monoéthanolamine et éthylènediamine au moyen d'une zéolite

Citations (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0200260A2 (fr) 1985-04-23 1986-12-10 ENICHEM SYNTHESIS S.p.A. Catalyseur à base de silicium et de titane ayant une haute résistance mécanique
EP0102544B1 (fr) 1982-08-25 1988-06-01 BASF Aktiengesellschaft Procédé de préparation de catalyseurs durs, résistant à la rupture, à partir de poudre de zéolite
EP0389041A1 (fr) 1989-03-23 1990-09-26 Shell Internationale Researchmaatschappij B.V. Extrudats d'oxyde de titane
EP0412161A1 (fr) 1989-01-12 1991-02-13 Innovatsionny Tsentr "Interlab" Procédé de refroidissement d'un objet en utilisant un refrigérateur à adsorption cryogénique
JPH0337156A (ja) 1989-07-03 1991-02-18 Sumitomo Metal Mining Co Ltd ゼオライト成型焼成体及びその製造方法
EP0592050A1 (fr) 1992-10-08 1994-04-13 Shell Internationale Researchmaatschappij B.V. Procédé d'extrusion d'aluminosilicate crystallins
WO1994013584A1 (fr) 1992-12-16 1994-06-23 Chevron Research And Technology Company, A Division Of Chevron U.S.A. Inc. Preparation de zeolites d'aluminosilicate
WO1994029408A1 (fr) 1993-06-03 1994-12-22 Mobil Oil Corporation Procede de preparation d'un catalyseur de zeolithe lie par de l'alumine
WO1995019222A1 (fr) 1994-01-12 1995-07-20 E.I. Du Pont De Nemours And Company Microcomposite poreux prepare a partir d'un polymere perfluore echangeur d'ions et d'un oxyde metallique, a l'aide d'un procede sol-gel
EP0700253A1 (fr) 1993-04-27 1996-03-13 Gist-Brocades B.V. Production de fromage avec une protease aspartique de recombinaison
US5648508A (en) 1995-11-22 1997-07-15 Nalco Chemical Company Crystalline metal-organic microporous materials
EP0840077A2 (fr) 1996-10-29 1998-05-06 Lutz, Johannes Machine frigorifique à adsorption et procédé de sa mise en oeuvre
US5961697A (en) * 1996-05-20 1999-10-05 Advanced Technology Materials, Inc. Bulk storage and dispensing system for fluids
DE10028030A1 (de) 2000-06-09 2001-12-13 Zeolith Tech Sorptionsvorrichtung zum Heizen und Kühlen von Gasströmen
DE10111230A1 (de) 2001-03-08 2002-09-19 Basf Ag Metallorganische Gerüstmaterialien und Verfahren zu deren Herstellung
WO2003102000A1 (fr) 2002-05-30 2003-12-11 Basf Aktiengesellschaft Corps formes contenant des structures organometalliques
WO2005049892A1 (fr) 2003-11-24 2005-06-02 Basf Aktiengesellschaft Procede de production electrochimique d'un squelette organometallique poreux cristallin
EP1647786A1 (fr) 2004-10-18 2006-04-19 Thermagen Bouteille auto-refrigerante
EP1652817A1 (fr) 2003-06-20 2006-05-03 Mitsubishi Chemical Corporation Zeolite, procede de production de celui-ci, adsorbant comprenant ledit zeolite, systeme d'utilisation de la chaleur, pompe thermique d'adsorption, systeme de stockage de chauffage et de refroidissement et appareil de climatisation a regulation de l'humidite
EP1279908B1 (fr) 2001-07-23 2007-01-03 Vaillant GmbH Pompe à chaleur à adsorption
WO2007023134A1 (fr) 2005-08-22 2007-03-01 Basf Aktiengesellschaft Procede pour produire des materiaux a structure organometallique comportant des ions metalliques du groupe principal
US7213401B2 (en) 2002-02-28 2007-05-08 Thermagen Self-refrigerating packaging and associated actuation device
DE102005053430A1 (de) 2005-11-09 2007-05-16 Basf Ag Dotierte metallorganische Gerüstmaterialien
WO2007054581A2 (fr) 2005-11-14 2007-05-18 Basf Se Materiau structurel organometallique poreux contenant un autre polymere
DE102006011410A1 (de) 2005-12-07 2007-06-14 Sortech Ag Adsorptionsmaschine
DE102006059504A1 (de) 2005-12-14 2007-06-28 Behr Gmbh & Co. Kg Wärmepumpe
EP1826051A1 (fr) * 2004-11-18 2007-08-29 Kabushiki Kaisha Toyota Jidoshokki Dispositif de refroidissement à réservoir d'hydrogène et procédé de refroidissement pour automobile à hydrogène combustible et automobile à hydrogène combustible
EP1840486A1 (fr) 2005-01-21 2007-10-03 Japan Exlan Company Limited Module d'echange de chaleur de type a sorption et procede pour sa fabrication
DE102006052109A1 (de) * 2006-11-06 2008-05-08 Robert Bosch Gmbh Fluidspeicher mit Thermomanagement
WO2008075291A2 (fr) * 2006-12-19 2008-06-26 L'air Liquide-Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Procédé et véhicule de remplissage d'une cuve de stockage de gaz à des débits accrus
WO2009071436A1 (fr) 2007-12-06 2009-06-11 Robert Bosch Gmbh Procédé de stockage d'hydrocarbures gazeux
DE102008043927A1 (de) 2008-11-20 2010-05-27 Robert Bosch Gmbh Vorrichtung zur Speicherung eines Gases sowie Verfahren zur Entnahme eines Gases aus einem Sorptionsspeicher
EP2230288A2 (fr) 2009-03-20 2010-09-22 Basf Se Matériaux à structure organométallique pour des machines à froid ou à chaleur
WO2014057416A1 (fr) 2012-10-09 2014-04-17 Basf Se Procédé permettant de charger un accumulateur à sorption avec un gaz

Patent Citations (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0102544B1 (fr) 1982-08-25 1988-06-01 BASF Aktiengesellschaft Procédé de préparation de catalyseurs durs, résistant à la rupture, à partir de poudre de zéolite
EP0200260A2 (fr) 1985-04-23 1986-12-10 ENICHEM SYNTHESIS S.p.A. Catalyseur à base de silicium et de titane ayant une haute résistance mécanique
EP0412161A1 (fr) 1989-01-12 1991-02-13 Innovatsionny Tsentr "Interlab" Procédé de refroidissement d'un objet en utilisant un refrigérateur à adsorption cryogénique
EP0389041A1 (fr) 1989-03-23 1990-09-26 Shell Internationale Researchmaatschappij B.V. Extrudats d'oxyde de titane
JPH0337156A (ja) 1989-07-03 1991-02-18 Sumitomo Metal Mining Co Ltd ゼオライト成型焼成体及びその製造方法
EP0592050A1 (fr) 1992-10-08 1994-04-13 Shell Internationale Researchmaatschappij B.V. Procédé d'extrusion d'aluminosilicate crystallins
WO1994013584A1 (fr) 1992-12-16 1994-06-23 Chevron Research And Technology Company, A Division Of Chevron U.S.A. Inc. Preparation de zeolites d'aluminosilicate
EP0700253A1 (fr) 1993-04-27 1996-03-13 Gist-Brocades B.V. Production de fromage avec une protease aspartique de recombinaison
WO1994029408A1 (fr) 1993-06-03 1994-12-22 Mobil Oil Corporation Procede de preparation d'un catalyseur de zeolithe lie par de l'alumine
WO1995019222A1 (fr) 1994-01-12 1995-07-20 E.I. Du Pont De Nemours And Company Microcomposite poreux prepare a partir d'un polymere perfluore echangeur d'ions et d'un oxyde metallique, a l'aide d'un procede sol-gel
US5648508A (en) 1995-11-22 1997-07-15 Nalco Chemical Company Crystalline metal-organic microporous materials
US5961697A (en) * 1996-05-20 1999-10-05 Advanced Technology Materials, Inc. Bulk storage and dispensing system for fluids
EP0840077A2 (fr) 1996-10-29 1998-05-06 Lutz, Johannes Machine frigorifique à adsorption et procédé de sa mise en oeuvre
DE10028030A1 (de) 2000-06-09 2001-12-13 Zeolith Tech Sorptionsvorrichtung zum Heizen und Kühlen von Gasströmen
DE10111230A1 (de) 2001-03-08 2002-09-19 Basf Ag Metallorganische Gerüstmaterialien und Verfahren zu deren Herstellung
EP1279908B1 (fr) 2001-07-23 2007-01-03 Vaillant GmbH Pompe à chaleur à adsorption
US7213401B2 (en) 2002-02-28 2007-05-08 Thermagen Self-refrigerating packaging and associated actuation device
WO2003102000A1 (fr) 2002-05-30 2003-12-11 Basf Aktiengesellschaft Corps formes contenant des structures organometalliques
EP1652817A1 (fr) 2003-06-20 2006-05-03 Mitsubishi Chemical Corporation Zeolite, procede de production de celui-ci, adsorbant comprenant ledit zeolite, systeme d'utilisation de la chaleur, pompe thermique d'adsorption, systeme de stockage de chauffage et de refroidissement et appareil de climatisation a regulation de l'humidite
WO2005049892A1 (fr) 2003-11-24 2005-06-02 Basf Aktiengesellschaft Procede de production electrochimique d'un squelette organometallique poreux cristallin
DE10355087A1 (de) 2003-11-24 2005-06-09 Basf Ag Verfahren zur elektrochemischen Herstellung eines kristallinen porösen metallorganischen Gerüstmaterials
EP1647786A1 (fr) 2004-10-18 2006-04-19 Thermagen Bouteille auto-refrigerante
EP1826051A1 (fr) * 2004-11-18 2007-08-29 Kabushiki Kaisha Toyota Jidoshokki Dispositif de refroidissement à réservoir d'hydrogène et procédé de refroidissement pour automobile à hydrogène combustible et automobile à hydrogène combustible
EP1840486A1 (fr) 2005-01-21 2007-10-03 Japan Exlan Company Limited Module d'echange de chaleur de type a sorption et procede pour sa fabrication
WO2007023134A1 (fr) 2005-08-22 2007-03-01 Basf Aktiengesellschaft Procede pour produire des materiaux a structure organometallique comportant des ions metalliques du groupe principal
DE102005053430A1 (de) 2005-11-09 2007-05-16 Basf Ag Dotierte metallorganische Gerüstmaterialien
WO2007054581A2 (fr) 2005-11-14 2007-05-18 Basf Se Materiau structurel organometallique poreux contenant un autre polymere
DE102006011410A1 (de) 2005-12-07 2007-06-14 Sortech Ag Adsorptionsmaschine
DE102006059504A1 (de) 2005-12-14 2007-06-28 Behr Gmbh & Co. Kg Wärmepumpe
DE102006052109A1 (de) * 2006-11-06 2008-05-08 Robert Bosch Gmbh Fluidspeicher mit Thermomanagement
WO2008075291A2 (fr) * 2006-12-19 2008-06-26 L'air Liquide-Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Procédé et véhicule de remplissage d'une cuve de stockage de gaz à des débits accrus
WO2009071436A1 (fr) 2007-12-06 2009-06-11 Robert Bosch Gmbh Procédé de stockage d'hydrocarbures gazeux
DE102008043927A1 (de) 2008-11-20 2010-05-27 Robert Bosch Gmbh Vorrichtung zur Speicherung eines Gases sowie Verfahren zur Entnahme eines Gases aus einem Sorptionsspeicher
EP2230288A2 (fr) 2009-03-20 2010-09-22 Basf Se Matériaux à structure organométallique pour des machines à froid ou à chaleur
WO2014057416A1 (fr) 2012-10-09 2014-04-17 Basf Se Procédé permettant de charger un accumulateur à sorption avec un gaz

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