EP3093549A1 - Fahrzeug mit verbrennungsmotor, mindestens einem aufbewahrungsbehälter und einer kühlkammer und/oder einer klimaanlageneinheit - Google Patents
Fahrzeug mit verbrennungsmotor, mindestens einem aufbewahrungsbehälter und einer kühlkammer und/oder einer klimaanlageneinheit Download PDFInfo
- Publication number
- EP3093549A1 EP3093549A1 EP15167069.2A EP15167069A EP3093549A1 EP 3093549 A1 EP3093549 A1 EP 3093549A1 EP 15167069 A EP15167069 A EP 15167069A EP 3093549 A1 EP3093549 A1 EP 3093549A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- storage vessel
- fuel
- vehicle
- sorption
- storage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C11/00—Use of gas-solvents or gas-sorbents in vessels
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C11/00—Use of gas-solvents or gas-sorbents in vessels
- F17C11/005—Use of gas-solvents or gas-sorbents in vessels for hydrogen
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C11/00—Use of gas-solvents or gas-sorbents in vessels
- F17C11/007—Use of gas-solvents or gas-sorbents in vessels for hydrocarbon gases, such as methane or natural gas, propane, butane or mixtures thereof [LPG]
Definitions
- the temperature increase constitutes a limitation especially for the ANG technique as for example carbon fiber tanks are presently only approved to operate at temperatures to up to 80°C.
- a charge cycle normally will be performed in a fuel station, at least for mobile applications, where the released sorption heat can be removed.
- desorption is an endothermic process and heat has to be supplied when gas is taken from the storage vessel.
- the rate of discharge is dictated by the energy demand of the application.
- Heat management is therefore of great importance when storage vessels with sorption medium are used. Heat management systems have to be optimized with regard to a minimum of required space and a minimum of additional weight in mobile applications, a minimum of additionally required electrical power and limited costs.
- a vehicle comprising an internal combustion engine, at least one storage vessel and a cooling chamber and/or an air condition unit, wherein a sorption medium is disposed in the at least one storage vessel and the at least one storage vessel contains a fuel for the internal combustion engine, the combustion engine and the at least one storage vessel are connected by a pipe for conducting the fuel, and the at least one storage vessel is thermally coupled with the cooling chamber and/or air condition unit.
- the desorption during discharge of the fuel from the at least one storage vessel leads to a temperature decrease in the at least one storage vessel, which is used to cool the cooling chamber and/or the air-condition unit as soon as the maximum temperature T max in the at least one storage vessel of less than 35°C is reached.
- At least one pressure sensor and at least one temperature sensor are disposed in the interior of the at least one storage vessel. Sensors commonly used in the art and known for example from the CNG technique can be used for this purpose.
- the position of the at least one pressure sensor can be freely selected at and/or in the at least one storage vessel as the pressure is equally distributed in the system.
- the at least one temperature sensor is disposed in the at least one storage vessel in a position characterized by a temperature from which the average temperature of the interior of the at least one storage vessel is deducable. It is further preferred to provide a temperature sensor in a location in the at least one storage vessel, where maximum temperatures are expected. This is typically the case in a highest position at the storage vessel wall.
- Remaining storage vessels can be filled up to 250 bar, these can be used later for cooling or fuel can be transferred from these storage vessels to the storage vessels with lower filling level.
- all storage vessels comprise the sorption medium and all storage vessels are filled up to 250 bar, it is also possible to cool only one of the storage vessels during filling with the fuel.
- a vehicle can for example comprise one storage vessel with a sorption medium and one storage vessel without sorption medium, both filled at the gas station to typically 250 bar.
- fuel is first taken from the storage vessel without sorption medium, especially when no cooling, over the air condition unit for example, is currently required.
- fuel can be transferred from the storage vessel with sorption medium to the storage vessel without sorption medium, which is already partly emptied, thus desorption occurs, even when no fuel is consumed at that instance, and the cooling power can be used.
- the vehicle comprises the compressor and in the driving step (b) the fuel is recirculated from the at least one storage vessel to the compressor and back to the at least one storage vessel.
- only one compressor can be used for both, recirculation of the fuel and supply of the fuel at a sufficient pressure level to the internal combustion engine.
- the storage vessel is a pressure vessel for the storage of fuel at a pressure in the range of up to 500 bar, preferably in a range of 1 bar to 400 bar, most preferably in the range of 1 bar to 250 bar. In other embodiments, also the range of 1 bar to 100 bar can be preferred.
- different cross-sectional areas are suitable for the storage vessel, for example circular, elliptical or rectangular. Irregularly shaped cross-sectional areas are also possible, e. g. when the storage vessel is to be fitted into a hollow space of a vehicle body. It is also possible to divide the total storage volume into more than one storage vessel.
- the wall of the storage vessel comprises at least one outlet and at least one inlet. More preferably, the at least one inlet and the at least one outlet are provided at the same half of the storage vessel. The half can also be named as side or end.
- the at least one inlet and the at least one outlet can be located in the same position and/or combined in one constructional part or adapter. The close arrangement of the at least one inlet and the at least one outlet is especially advantageous in order to establish the flow-through regime during filling or for recirculation of the fuel between the at least one storage vessel and the heat exchange.
- the ratio of the permeability of the pellets to the smallest pellet diameter is between 1 ⁇ 10 -11 m 2 /m and 1 ⁇ 10 -16 m 2 /m, preferably between 1 ⁇ 10 -12 m 2 /m and 1 ⁇ 10 14 m 2 /m, and most preferably 1 ⁇ 10 -13 m 2 /m.
- the sorption medium is present in form of at least one monolith and the at least one monolith has an extension in one direction in space in a range from 10 cm to 100 cm.
- this extension in one direction in space is the radial diameter, referring to the at least one storage vessel, having preferably a cylindrical shape, with a longer axial extension than radial extension.
- a monolith is understood to be a shaped body with a greater size compared to known sizes of typical shaped bodies like pellets.
- the longest second extension of the monolith is in the range from 100 cm to 300 cm, more preferably from 150 cm to 200 cm and the longest first extension of the monolith is in a range from 30 cm to 100 cm, more preferably from 40 cm to 60 cm.
- the at least one storage vessel has a cylindrical shape
- each of the at least two monoliths has a disk-like shape and the at least two monoliths are arranged one next to the other in longitudinal axial direction of the at least one storage vessel.
- the form of the circumference of the at least one storage vessel corresponds to the form of the circumference of each of the at least two monoliths.
- the longest diameter of the opening is in the range from 0.3 % to 20 % of the longest diameter of the radial cross-sectional area of the at least one storage vessel. It is further preferred when the opening in the at least one monolith is arranged centrally with respect to the at least one storage vessel.
- the sorption medium is preferably selected from the group consisting of activated charcoal, zeolites, activated aluminia, silica gels, open-pore polymer foams, metal hydrides, metal-organic frameworks (MOF) and combinations thereof.
- Metal-organic frameworks are known in the prior art and are described for example in US 5,648,508 , EP-A 0 700 253 , M. O'Keeffe et al., J. Sol. State Chem., 152 (2000), pages 3 to 20 , H. Li et al., Nature 402, 1 (1999), page 276 , M. Eddaoudi et al., Topics in Catalysis 9, (1999), pages 105 to 111 , B.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP15167069.2A EP3093549A1 (de) | 2015-05-11 | 2015-05-11 | Fahrzeug mit verbrennungsmotor, mindestens einem aufbewahrungsbehälter und einer kühlkammer und/oder einer klimaanlageneinheit |
PCT/EP2016/060389 WO2016180807A1 (en) | 2015-05-11 | 2016-05-10 | Vehicle comprising an internal combustion engine, at least one storage vessel and a cooling chamber and optionally an air condition unit |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP15167069.2A EP3093549A1 (de) | 2015-05-11 | 2015-05-11 | Fahrzeug mit verbrennungsmotor, mindestens einem aufbewahrungsbehälter und einer kühlkammer und/oder einer klimaanlageneinheit |
Publications (1)
Publication Number | Publication Date |
---|---|
EP3093549A1 true EP3093549A1 (de) | 2016-11-16 |
Family
ID=53188875
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP15167069.2A Withdrawn EP3093549A1 (de) | 2015-05-11 | 2015-05-11 | Fahrzeug mit verbrennungsmotor, mindestens einem aufbewahrungsbehälter und einer kühlkammer und/oder einer klimaanlageneinheit |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP3093549A1 (de) |
WO (1) | WO2016180807A1 (de) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10202323B2 (en) | 2015-07-15 | 2019-02-12 | Basf Se | Process for preparing an arylpropene |
WO2018036997A1 (en) | 2016-08-23 | 2018-03-01 | Basf Se | Composite materials |
JP2019536774A (ja) | 2016-11-30 | 2019-12-19 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | Mor骨格構造の銅変性ゼオライトを用いて、モノエタノールアミンをエチレンジアミンに変換する方法 |
US11091425B2 (en) | 2016-11-30 | 2021-08-17 | Basf Se | Process for the conversion of ethylene glycol to ethylenediamine employing a zeolite catalyst |
EP3619190B1 (de) | 2017-05-03 | 2021-08-04 | Basf Se | Verfahren zur umwandlung von ethylenoxid in monoethanolamin und ethylendiamin mit einem zeolith |
Citations (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0200260A2 (de) | 1985-04-23 | 1986-12-10 | ENICHEM SYNTHESIS S.p.A. | Katalysator auf Basis von Silicium und Titanium, der eine hohe mechanische Festigkeit hat |
EP0102544B1 (de) | 1982-08-25 | 1988-06-01 | BASF Aktiengesellschaft | Verfahren zur Herstellung von harten, bruchfesten Katalysatoren aus Zeolith-Pulver |
EP0389041A1 (de) | 1989-03-23 | 1990-09-26 | Shell Internationale Researchmaatschappij B.V. | Titanoxyd-Extrudate |
EP0412161A1 (de) | 1989-01-12 | 1991-02-13 | Innovatsionny Tsentr "Interlab" | Verfahren zur Kühlung eines Objekts mittels einer kryogenen Adsorptionskältemaschine |
JPH0337156A (ja) | 1989-07-03 | 1991-02-18 | Sumitomo Metal Mining Co Ltd | ゼオライト成型焼成体及びその製造方法 |
EP0592050A1 (de) | 1992-10-08 | 1994-04-13 | Shell Internationale Researchmaatschappij B.V. | Extrusionsverfahren für kristalline Aluminosilikate |
WO1994013584A1 (en) | 1992-12-16 | 1994-06-23 | Chevron Research And Technology Company, A Division Of Chevron U.S.A. Inc. | Preparation of aluminosilicate zeolites |
WO1994029408A1 (en) | 1993-06-03 | 1994-12-22 | Mobil Oil Corporation | Process for preparing an alumina bound zeolite catalyst |
WO1995019222A1 (en) | 1994-01-12 | 1995-07-20 | E.I. Du Pont De Nemours And Company | Sol-gel derived porous microcomposite of perfluorinated ion-exchange polymer and metal oxide |
EP0700253A1 (de) | 1993-04-27 | 1996-03-13 | Gist-Brocades B.V. | Käsebereitung mit rekombinantem aspartat-protease |
US5648508A (en) | 1995-11-22 | 1997-07-15 | Nalco Chemical Company | Crystalline metal-organic microporous materials |
EP0840077A2 (de) | 1996-10-29 | 1998-05-06 | Lutz, Johannes | Adsorptionskältemaschine und Verfahren zu deren Betrieb |
US5961697A (en) * | 1996-05-20 | 1999-10-05 | Advanced Technology Materials, Inc. | Bulk storage and dispensing system for fluids |
DE10028030A1 (de) | 2000-06-09 | 2001-12-13 | Zeolith Tech | Sorptionsvorrichtung zum Heizen und Kühlen von Gasströmen |
DE10111230A1 (de) | 2001-03-08 | 2002-09-19 | Basf Ag | Metallorganische Gerüstmaterialien und Verfahren zu deren Herstellung |
WO2003102000A1 (en) | 2002-05-30 | 2003-12-11 | Basf Aktiengesellschaft | Shaped bodies containing metal-organic frameworks |
WO2005049892A1 (de) | 2003-11-24 | 2005-06-02 | Basf Aktiengesellschaft | Verfahren zur elektrochemischen herstellung eines kristallinen porösen metallorganischen gerüstmaterials |
EP1647786A1 (de) | 2004-10-18 | 2006-04-19 | Thermagen | Selbstkühlende Flasche |
EP1652817A1 (de) | 2003-06-20 | 2006-05-03 | Mitsubishi Chemical Corporation | Zeolith, herstellungsverfahren dafür, den zeolith enthaltendes adsorptionsmittel, wärmenutzungssystem, adsorptionswärmepumpe, heiz- und kühlspeichersystem und feuchtigkeitsregulierende klimaanlage |
EP1279908B1 (de) | 2001-07-23 | 2007-01-03 | Vaillant GmbH | Adsorptionswärmepumpe |
WO2007023134A1 (de) | 2005-08-22 | 2007-03-01 | Basf Aktiengesellschaft | Verfahren zur herstellung von metallorganischen gerüstmaterialien hauptgruppen metallionen enthaltend |
US7213401B2 (en) | 2002-02-28 | 2007-05-08 | Thermagen | Self-refrigerating packaging and associated actuation device |
DE102005053430A1 (de) | 2005-11-09 | 2007-05-16 | Basf Ag | Dotierte metallorganische Gerüstmaterialien |
WO2007054581A2 (de) | 2005-11-14 | 2007-05-18 | Basf Se | Poröses metallorganisches gerüstmaterial enthaltend ein weiteres polymer |
DE102006011410A1 (de) | 2005-12-07 | 2007-06-14 | Sortech Ag | Adsorptionsmaschine |
DE102006059504A1 (de) | 2005-12-14 | 2007-06-28 | Behr Gmbh & Co. Kg | Wärmepumpe |
EP1826051A1 (de) * | 2004-11-18 | 2007-08-29 | Kabushiki Kaisha Toyota Jidoshokki | Wasserstofftankkühlvorrichtung und -kühlverfahren in wasserstoffbrennstoffautomobil und wasserstoffbrennstoffautomobil |
EP1840486A1 (de) | 2005-01-21 | 2007-10-03 | Japan Exlan Company Limited | Sorptionswärmeaustauschmodul und verfahren zu dessen herstellung |
DE102006052109A1 (de) * | 2006-11-06 | 2008-05-08 | Robert Bosch Gmbh | Fluidspeicher mit Thermomanagement |
WO2008075291A2 (en) * | 2006-12-19 | 2008-06-26 | L'air Liquide-Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Method and vehicle for filling a gas storage vessel at enhanced flow rates |
WO2009071436A1 (de) | 2007-12-06 | 2009-06-11 | Robert Bosch Gmbh | Verfahren zur speicherung von gasförmigen kohlenwasserstoffen |
DE102008043927A1 (de) | 2008-11-20 | 2010-05-27 | Robert Bosch Gmbh | Vorrichtung zur Speicherung eines Gases sowie Verfahren zur Entnahme eines Gases aus einem Sorptionsspeicher |
EP2230288A2 (de) | 2009-03-20 | 2010-09-22 | Basf Se | Metallorganische Gerüstmaterialien in Kälte/Wärmemaschinen |
WO2014057416A1 (en) | 2012-10-09 | 2014-04-17 | Basf Se | Method of charging a sorption store with a gas |
-
2015
- 2015-05-11 EP EP15167069.2A patent/EP3093549A1/de not_active Withdrawn
-
2016
- 2016-05-10 WO PCT/EP2016/060389 patent/WO2016180807A1/en active Application Filing
Patent Citations (35)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0102544B1 (de) | 1982-08-25 | 1988-06-01 | BASF Aktiengesellschaft | Verfahren zur Herstellung von harten, bruchfesten Katalysatoren aus Zeolith-Pulver |
EP0200260A2 (de) | 1985-04-23 | 1986-12-10 | ENICHEM SYNTHESIS S.p.A. | Katalysator auf Basis von Silicium und Titanium, der eine hohe mechanische Festigkeit hat |
EP0412161A1 (de) | 1989-01-12 | 1991-02-13 | Innovatsionny Tsentr "Interlab" | Verfahren zur Kühlung eines Objekts mittels einer kryogenen Adsorptionskältemaschine |
EP0389041A1 (de) | 1989-03-23 | 1990-09-26 | Shell Internationale Researchmaatschappij B.V. | Titanoxyd-Extrudate |
JPH0337156A (ja) | 1989-07-03 | 1991-02-18 | Sumitomo Metal Mining Co Ltd | ゼオライト成型焼成体及びその製造方法 |
EP0592050A1 (de) | 1992-10-08 | 1994-04-13 | Shell Internationale Researchmaatschappij B.V. | Extrusionsverfahren für kristalline Aluminosilikate |
WO1994013584A1 (en) | 1992-12-16 | 1994-06-23 | Chevron Research And Technology Company, A Division Of Chevron U.S.A. Inc. | Preparation of aluminosilicate zeolites |
EP0700253A1 (de) | 1993-04-27 | 1996-03-13 | Gist-Brocades B.V. | Käsebereitung mit rekombinantem aspartat-protease |
WO1994029408A1 (en) | 1993-06-03 | 1994-12-22 | Mobil Oil Corporation | Process for preparing an alumina bound zeolite catalyst |
WO1995019222A1 (en) | 1994-01-12 | 1995-07-20 | E.I. Du Pont De Nemours And Company | Sol-gel derived porous microcomposite of perfluorinated ion-exchange polymer and metal oxide |
US5648508A (en) | 1995-11-22 | 1997-07-15 | Nalco Chemical Company | Crystalline metal-organic microporous materials |
US5961697A (en) * | 1996-05-20 | 1999-10-05 | Advanced Technology Materials, Inc. | Bulk storage and dispensing system for fluids |
EP0840077A2 (de) | 1996-10-29 | 1998-05-06 | Lutz, Johannes | Adsorptionskältemaschine und Verfahren zu deren Betrieb |
DE10028030A1 (de) | 2000-06-09 | 2001-12-13 | Zeolith Tech | Sorptionsvorrichtung zum Heizen und Kühlen von Gasströmen |
DE10111230A1 (de) | 2001-03-08 | 2002-09-19 | Basf Ag | Metallorganische Gerüstmaterialien und Verfahren zu deren Herstellung |
EP1279908B1 (de) | 2001-07-23 | 2007-01-03 | Vaillant GmbH | Adsorptionswärmepumpe |
US7213401B2 (en) | 2002-02-28 | 2007-05-08 | Thermagen | Self-refrigerating packaging and associated actuation device |
WO2003102000A1 (en) | 2002-05-30 | 2003-12-11 | Basf Aktiengesellschaft | Shaped bodies containing metal-organic frameworks |
EP1652817A1 (de) | 2003-06-20 | 2006-05-03 | Mitsubishi Chemical Corporation | Zeolith, herstellungsverfahren dafür, den zeolith enthaltendes adsorptionsmittel, wärmenutzungssystem, adsorptionswärmepumpe, heiz- und kühlspeichersystem und feuchtigkeitsregulierende klimaanlage |
WO2005049892A1 (de) | 2003-11-24 | 2005-06-02 | Basf Aktiengesellschaft | Verfahren zur elektrochemischen herstellung eines kristallinen porösen metallorganischen gerüstmaterials |
DE10355087A1 (de) | 2003-11-24 | 2005-06-09 | Basf Ag | Verfahren zur elektrochemischen Herstellung eines kristallinen porösen metallorganischen Gerüstmaterials |
EP1647786A1 (de) | 2004-10-18 | 2006-04-19 | Thermagen | Selbstkühlende Flasche |
EP1826051A1 (de) * | 2004-11-18 | 2007-08-29 | Kabushiki Kaisha Toyota Jidoshokki | Wasserstofftankkühlvorrichtung und -kühlverfahren in wasserstoffbrennstoffautomobil und wasserstoffbrennstoffautomobil |
EP1840486A1 (de) | 2005-01-21 | 2007-10-03 | Japan Exlan Company Limited | Sorptionswärmeaustauschmodul und verfahren zu dessen herstellung |
WO2007023134A1 (de) | 2005-08-22 | 2007-03-01 | Basf Aktiengesellschaft | Verfahren zur herstellung von metallorganischen gerüstmaterialien hauptgruppen metallionen enthaltend |
DE102005053430A1 (de) | 2005-11-09 | 2007-05-16 | Basf Ag | Dotierte metallorganische Gerüstmaterialien |
WO2007054581A2 (de) | 2005-11-14 | 2007-05-18 | Basf Se | Poröses metallorganisches gerüstmaterial enthaltend ein weiteres polymer |
DE102006011410A1 (de) | 2005-12-07 | 2007-06-14 | Sortech Ag | Adsorptionsmaschine |
DE102006059504A1 (de) | 2005-12-14 | 2007-06-28 | Behr Gmbh & Co. Kg | Wärmepumpe |
DE102006052109A1 (de) * | 2006-11-06 | 2008-05-08 | Robert Bosch Gmbh | Fluidspeicher mit Thermomanagement |
WO2008075291A2 (en) * | 2006-12-19 | 2008-06-26 | L'air Liquide-Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Method and vehicle for filling a gas storage vessel at enhanced flow rates |
WO2009071436A1 (de) | 2007-12-06 | 2009-06-11 | Robert Bosch Gmbh | Verfahren zur speicherung von gasförmigen kohlenwasserstoffen |
DE102008043927A1 (de) | 2008-11-20 | 2010-05-27 | Robert Bosch Gmbh | Vorrichtung zur Speicherung eines Gases sowie Verfahren zur Entnahme eines Gases aus einem Sorptionsspeicher |
EP2230288A2 (de) | 2009-03-20 | 2010-09-22 | Basf Se | Metallorganische Gerüstmaterialien in Kälte/Wärmemaschinen |
WO2014057416A1 (en) | 2012-10-09 | 2014-04-17 | Basf Se | Method of charging a sorption store with a gas |
Non-Patent Citations (6)
Title |
---|
"Ullmann's Enzykiopadie der Technischen Chemie", vol. 2, 1972, pages: 313 |
B. CHEN ET AL., SCIENCE, vol. 291, 2001, pages 1021 - 1023 |
DAVID FARRUSSENG: "Metal-Organic Frameworks", 2011, WILEY-VCH VERLAG |
H. LI ET AL., NATURE, vol. 402, no. 1, 1999, pages 276 |
M. EDDAOUDI ET AL., TOPICS IN CATALYSIS, vol. 9, 1999, pages 105 - 111 |
M. O'KEEFFE ET AL., J. SOL. STATE CHEM., vol. 152, 2000, pages 3 - 20 |
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18W | Application withdrawn |
Effective date: 20161209 |