EP3080305A1 - Verfahren zur reduzierung von co2-emissionen beim betrieb eines huttenwerks - Google Patents

Verfahren zur reduzierung von co2-emissionen beim betrieb eines huttenwerks

Info

Publication number
EP3080305A1
EP3080305A1 EP14815577.3A EP14815577A EP3080305A1 EP 3080305 A1 EP3080305 A1 EP 3080305A1 EP 14815577 A EP14815577 A EP 14815577A EP 3080305 A1 EP3080305 A1 EP 3080305A1
Authority
EP
European Patent Office
Prior art keywords
gas
blast furnace
production
converter
steelworks
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP14815577.3A
Other languages
German (de)
English (en)
French (fr)
Inventor
Reinhold ACHATZ
Jens Wagner
Markus Oles
Peter SCHMÖLE
Ralph Kleinschmidt
Christoph Meissner
Denis KROTOV
Olaf Von Morstein
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ThyssenKrupp AG
Original Assignee
ThyssenKrupp AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ThyssenKrupp AG filed Critical ThyssenKrupp AG
Publication of EP3080305A1 publication Critical patent/EP3080305A1/de
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B5/00—Making pig-iron in the blast furnace
    • C21B5/06—Making pig-iron in the blast furnace using top gas in the blast furnace process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/025—Preparation or purification of gas mixtures for ammonia synthesis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B7/00—Blast furnaces
    • C21B7/002—Evacuating and treating of exhaust gases
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28—Manufacture of steel in the converter
    • C21C5/38—Removal of waste gases or dust
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B1/00—Shaft or like vertical or substantially vertical furnaces
    • F27B1/10—Details, accessories, or equipment peculiar to furnaces of these types
    • F27B1/26—Arrangements of controlling devices
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00—Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D99/00—Subject matter not provided for in other groups of this subclass
    • F27D99/0001—Heating elements or systems
    • F27D99/0006—Electric heating elements or system
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/60—Process control or energy utilisation in the manufacture of iron or steel
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/60—Process control or energy utilisation in the manufacture of iron or steel
    • C21B2100/62—Energy conversion other than by heat exchange, e.g. by use of exhaust gas in energy production
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/10—Reduction of greenhouse gas [GHG] emissions
    • Y02P10/122—Reduction of greenhouse gas [GHG] emissions by capturing or storing CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/25—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/133—Renewable energy sources, e.g. sunlight

Definitions

  • the invention relates to a method for reducing CO2 emissions during operation of a metallurgical plant comprising at least one blast furnace for pig iron production and a converter steelworks for crude steel production.
  • blast furnace Iron ores, aggregates and coke and other reducing agents such as coal, oil, gas, biomass, recycled waste plastics or other substances containing carbon and / or hydrogen are used in the blast furnace to produce pig iron.
  • the products of the reduction reactions are inevitably CO, CO 2 , hydrogen and water vapor.
  • a blast-furnace top gas withdrawn from the blast furnace process often has a high nitrogen content in addition to the abovementioned constituents.
  • the amount of gas and the composition of the blast furnace gas depends on the feedstock and the operation and is subject to fluctuations. However, blast furnace top gas typically contains 35 to 60% by volume of N 2> 20 to 30% by volume of CO, 20 to 30% by volume of CO 2 and 2 to 15% by volume of H 2 .
  • About 30 to 40% of the blast-furnace top gas produced in the production of pig iron is generally used for heating the hot blast for the blast furnace process in blast furnaces; the remaining blast furnace gas can be used in other areas of the plant for heating purposes or to generate electricity.
  • pig iron is converted to crude steel. Inflating oxygen to molten pig iron removes interfering contaminants such as carbon, silicon, sulfur and phosphorus. Since the oxidation processes cause a strong evolution of heat, scrap is often added in amounts of up to 25% based on the pig iron as a coolant. Further, lime for slag formation and alloying agent are added. From the steel converter, a converter gas is withdrawn, which has a high content of CO and also contains nitrogen, hydrogen and CO 2 .
  • a typical converter gas composition comprises 50 to 70% by volume CO, 10 to 20% by volume N 2 , about 15% by volume CO 2 and about 2% by volume H 2 . The converter gas is
  • CONFIRMATION COPY either flared or caught in modern steelworks and fed to an energetic use.
  • An improvement in the C0 2 emissions in the iron and steel making is according to the prevailing doctrine requires process changes that affect the operation of the blast furnace. These include, for example, a nitrogen-free operation of the blast furnace, in which instead of a hot blast cold oxygen is blown in the blow mold and the majority of the blast furnace gas is supplied to CO 2 . It has also been proposed to heat the blast furnace with plasma. The process of the plasma-heated blast furnace requires neither hot air nor oxygen and no additional replacement reducing agent. However, the introduction of new blast furnace processes is a serious encroachment on the proven technology of pig iron and crude steel production and involves considerable risks. against this background, the object of the invention is to improve the CO 2 balance of a metallurgical plant which has a conventionally operated blast furnace for producing pig iron and a conventionally operated converter steelwork.
  • synthesis gas is generated from at least a subset of the blast-furnace top gas produced in the blast furnace in the blast furnace and / or a subset of the converter gas resulting from the crude steel production, which gas is used to produce chemical products.
  • the energy demand of the steelworks is no longer covered and is covered according to the invention at least in part by using electric power, which is obtained from renewable energy.
  • the smelting works is operated in conjunction with a coke oven plant, it is expedient to use at least a subset of a coke oven gas falling in the coke oven plant for producing syngas.
  • 1% to 60%, preferably a proportion of 10 to 60%, of the raw gases which are obtained as blast-furnace top gas and converter gas or as blast-furnace top gas, converter gas and coke-oven gas is used for synthesis gas production.
  • the synthesis gas production expediently includes gas purification and gas conditioning, wherein for gas conditioning, for example, a steam reforming with water vapor and / or a partial oxidation with air or oxygen and / or a water-gas shift reaction for the conversion of CO can be used.
  • the conditioning steps may be used singly or in combination.
  • the synthesis gas produced by the process according to the invention is a gas mixture which is used for the synthesis.
  • the term "synthesis gas" includes, for example, gas mixtures of N 2 and H 2 for ammonia synthesis and, above all, gas mixtures which mainly contain CO and H 2 or CO 2 and H 2 or CO, CO 2 and H 2 . From the synthesis gases chemical products can be produced in a chemical plant, which each contain the components of the educt. Chemical products may be, for example, ammonia or methanol or other hydrocarbon compounds.
  • a synthesis gas which contains nitrogen and hydrogen in the correct ratio.
  • the nitrogen can be obtained from blast furnace gas.
  • blast furnace gas or converter gas can be used as the hydrogen source, wherein hydrogen is converted by conversion of the CO fraction by a water-gas shift reaction (CO + H 2 O CO 2 + H 2 ) is generated.
  • a synthesis gas for ammonia synthesis a mixture of coke oven gas and blast furnace gas or a mixed gas of coke oven gas, converter gas and blast furnace gas can be used.
  • a synthesis gas consisting essentially of CO and / or CO 2 and H 2 which contains the components carbon monoxide and / or carbon dioxide and hydrogen in the correct ratio.
  • the ratio is often described by the module (H 2 -CO 2 ) / (CO + CO 2 ).
  • the hydrogen can be generated, for example, by converting the CO fraction in the blast furnace gas by a water-gas shift reaction.
  • Converter gas can be used to provide CO.
  • the CO 2 source can be blast furnace gas and / or converter gas.
  • For the production of hydrocarbon compounds is also a mixed gas of coke oven gas and converter gas or a mixed gas of coke oven gas, converter gas and blast furnace gas.
  • a biotechnological plant can be used within the scope of the invention.
  • This is a plant for the fermentation of synthesis gas.
  • synthesis gas are preferably to be understood with a high CO content, with which alcohols, acetone, or organic acids can be prepared in this case, mixtures of CO and H 2.
  • the hydrogen essentially comes from the water used as a medium during fermentation.
  • Converter gas is preferably used as the CO source.
  • the use of blast furnace gas or a mixed gas of converter gas and blast furnace gas is also possible.
  • the use of coke oven gas is unfavorable for a biotechnological process.
  • a further embodiment of the method according to the invention provides that synthesis gas is enriched with hydrogen, which is produced by electrolysis of water, wherein also electric power from renewable energy is used for the electrolysis of water.
  • the steelworks can be operated in an electrical network with an energy storage, which is fed with electricity from renewable energy and the stored energy with a time delay returns to electrical consumers of the steelworks.
  • the steelworks is used in conjunction with a power plant, which is designed as a gas turbine power plant or gas turbine steam turbine power plant and is operated with a part of the steel mill as blast furnace gas, converter gas or coke oven gas resulting gases.
  • the plant network including the power plant is designed so that the power plant can be used in stand-by mode and at least temporarily shut down.
  • the power plant can be used when the chemical plant or a biotechnological plant is out of service or the energy from regenerative sources or stored in an energy storage temporarily insufficient to meet the energy needs of the mill.
  • the energy store can be designed as a chemical or electrochemical storage.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Electrochemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
  • Manufacture Of Iron (AREA)
EP14815577.3A 2013-12-12 2014-12-11 Verfahren zur reduzierung von co2-emissionen beim betrieb eines huttenwerks Pending EP3080305A1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102013113942.6A DE102013113942A1 (de) 2013-12-12 2013-12-12 Verfahren zur Reduzierung von CO2-Emissionen beim Betrieb eines Hüttenwerks
PCT/EP2014/003314 WO2015086148A1 (de) 2013-12-12 2014-12-11 Verfahren zur reduzierung von co2-emissionen beim betrieb eines hüttenwerks

Publications (1)

Publication Number Publication Date
EP3080305A1 true EP3080305A1 (de) 2016-10-19

Family

ID=52134102

Family Applications (1)

Application Number Title Priority Date Filing Date
EP14815577.3A Pending EP3080305A1 (de) 2013-12-12 2014-12-11 Verfahren zur reduzierung von co2-emissionen beim betrieb eines huttenwerks

Country Status (13)

Country Link
US (1) US20160319381A1 (ru)
EP (1) EP3080305A1 (ru)
KR (3) KR20160098339A (ru)
CN (1) CN105960470A (ru)
AU (1) AU2014361203B2 (ru)
BR (1) BR112016012587B1 (ru)
CA (1) CA2930342A1 (ru)
DE (1) DE102013113942A1 (ru)
MX (1) MX2016006971A (ru)
RU (1) RU2693980C2 (ru)
TW (1) TWI660072B (ru)
UA (1) UA119337C2 (ru)
WO (1) WO2015086148A1 (ru)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102013113933A1 (de) 2013-12-12 2015-06-18 Thyssenkrupp Ag Verfahren zur Erzeugung von Synthesegas im Verbund mit einem Hüttenwerk
DE102013113950A1 (de) 2013-12-12 2015-06-18 Thyssenkrupp Ag Anlagenverbund zur Stahlerzeugung und Verfahren zum Betreiben des Anlagenverbundes
DE102013113913A1 (de) 2013-12-12 2015-06-18 Thyssenkrupp Ag Anlagenverbund zur Stahlerzeugung und Verfahren zum Betreiben des Anlagenverbundes
DE102013113921A1 (de) 2013-12-12 2015-06-18 Thyssenkrupp Ag Anlagenverbund zur Stahlerzeugung und Verfahren zum Betreiben des Anlagenverbundes
DE102013113958A1 (de) 2013-12-12 2015-06-18 Thyssenkrupp Ag Anlagenverbund zur Stahlerzeugung und Verfahren zum Betreiben des Anlagenverbundes
LU100453B1 (en) * 2017-09-25 2019-03-29 Wurth Paul Sa Method for Producing a Synthesis Gas, in particular for use in Blast Furnace Operation
DE102018211104A1 (de) * 2018-07-05 2020-01-09 Thyssenkrupp Ag Verfahren und Einrichtung zum Betrieb einer Produktionsanlage
EP3670705B1 (en) 2018-12-21 2022-02-02 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Carbon dioxide conversion process
RU2734215C1 (ru) * 2020-04-16 2020-10-13 Автономная некоммерческая организация «Научно-исследовательский институт проблем экологии» Способ выплавки чугуна в доменной печи
CN112662824A (zh) * 2020-12-18 2021-04-16 昆明理工大学 一种高效利用冶金废气的高炉富氢冶炼工艺
CN114657317B (zh) * 2022-03-24 2023-03-28 鞍山市恒成设备制造有限公司 一种低碳冶金方法
TW202348548A (zh) 2022-05-11 2023-12-16 丹麥商托普索公司 製造可再生燃料的方法及設備
KR20240058008A (ko) 2022-10-25 2024-05-03 한국화학연구원 제철 부생가스를 이용하여 플라스틱 원료를 제조하는 방법

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WO2011018124A1 (de) * 2009-08-13 2011-02-17 Silicon Fire Ag Verfahren und anlage zum bereitstellen eines kohlenwasserstoff-basierten energieträgers unter einsatz eines anteils von regenerativ erzeugtem methanol und eines anteils von methanol, der mittels direktoxidation oder über partielle oxidation oder über reformierung erzeugt wird
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Also Published As

Publication number Publication date
KR20160098339A (ko) 2016-08-18
KR20210038695A (ko) 2021-04-07
KR20220054444A (ko) 2022-05-02
TWI660072B (zh) 2019-05-21
UA119337C2 (uk) 2019-06-10
TW201546331A (zh) 2015-12-16
MX2016006971A (es) 2017-01-20
AU2014361203A1 (en) 2016-06-30
WO2015086148A1 (de) 2015-06-18
DE102013113942A1 (de) 2015-06-18
CN105960470A (zh) 2016-09-21
BR112016012587B1 (pt) 2021-04-20
US20160319381A1 (en) 2016-11-03
RU2693980C2 (ru) 2019-07-08
AU2014361203B2 (en) 2019-01-31
BR112016012587A2 (pt) 2017-08-08
CA2930342A1 (en) 2015-06-18

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