EP3024341B1 - Procédé et élément permettant de guider un brin de fibres de filtre, et confectionneuse de filtres - Google Patents
Procédé et élément permettant de guider un brin de fibres de filtre, et confectionneuse de filtres Download PDFInfo
- Publication number
- EP3024341B1 EP3024341B1 EP14771374.7A EP14771374A EP3024341B1 EP 3024341 B1 EP3024341 B1 EP 3024341B1 EP 14771374 A EP14771374 A EP 14771374A EP 3024341 B1 EP3024341 B1 EP 3024341B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- strand
- filter
- fibers
- filter fibers
- guiding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000835 fiber Substances 0.000 title claims description 60
- 238000000034 method Methods 0.000 title claims description 6
- 238000005520 cutting process Methods 0.000 claims description 9
- 241000208125 Nicotiana Species 0.000 claims description 7
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 7
- 230000000087 stabilizing effect Effects 0.000 claims description 2
- 239000011324 bead Substances 0.000 description 24
- 229920006221 acetate fiber Polymers 0.000 description 8
- 239000012634 fragment Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 235000013773 glyceryl triacetate Nutrition 0.000 description 1
- 239000001087 glyceryl triacetate Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0275—Manufacture of tobacco smoke filters for filters with special features
- A24D3/0287—Manufacture of tobacco smoke filters for filters with special features for composite filters
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0204—Preliminary operations before the filter rod forming process, e.g. crimping, blooming
- A24D3/0212—Applying additives to filter materials
- A24D3/0216—Applying additives to filter materials the additive being in the form of capsules, beads or the like
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0229—Filter rod forming processes
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0229—Filter rod forming processes
- A24D3/0233—Filter rod forming processes by means of a garniture
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/025—Final operations, i.e. after the filter rod forming process
- A24D3/0254—Cutting means
Definitions
- the object of the invention is a method and a member for guiding a strand of filter fibers, and a filter rod making machine.
- filter rod making machines used to manufacture filter cigarettes are used whereas the filter rods are formed by cutting a continuous filter rod containing multiple filter fibers.
- a continuous filter rod is manufactured by a gradual compression of an acetate strand in narrowing channels; the rod usually has a circular section.
- a continuous filter rod is wrapped into a wrapper, and then divided into rods with a specific length by a cutting mechanism. The cutting is carried out by means of a rotating cutting head with knives situated on its circumference whereas the axis of rotation of a cutting head is put at an angle to the horizontal plane. If during the formation of a continuous filter rod beads with flavour substances or other objects with special characteristics are placed, it is expected that the beads or objects will take specific set positions relative to the rod tips. An axial position of the beads in the rods outside the allowable field of tolerance causes that the rods are rejected as defective, which results in production wastes.
- a machine for making bead-containing filter rods was presented in the document WO 2012/042343 .
- the beads are placed into a continuous filter rod by means of a delivery wheel with a vertical axis of rotation.
- a member working together with a delivery wheel has a monolithic structure which allows discharging the air along the filter fiber axis.
- the document US2013/102445A1 also discloses a machine for making filter rods containing beads with flavour or aromatic substances.
- the beads are placed into a continuous acetate rod by means of a delivery wheel with a horizontal axis of rotation.
- This solution also includes a member working together with a wheel having a monolithic structure similar to WO 2012/042343 .
- GB 2020158 A discloses discloses a further machine for making filter rods.
- the solutions presented above do not guarantee a suitable repeatability of placing the beads into a strand of filter fibers. With the increasing speed of delivery of filter fibers, the accuracy of placing objects, e.g. beads, is decreasing.
- the present invention solves the abovementioned problem.
- the object of the invention is a member for guiding a strand of filter fibers in the area of placing objects into the strand of filter fibers in a tobacco industry machine, adapted to work together with an apparatus for feeding the objects to the strand of filter fibers, having a slot in which the feeding member or members of an object feeder move(s), an inlet opening for a strand of filter fibers, an outlet opening for a strand of filter fibers, a guiding channel connecting an inlet opening and an outlet opening.
- the member is characterized by comprising vent holes stabilizing the converted strand of filter fibers and increasing the accuracy of object placing.
- a member according to the invention comprises holes whose axes are situated radially.
- a member according to the invention is characterized in that the axes of the holes are situated substantially perpendicular to the plane of the slot.
- a member according to the invention has holes situated substantially along at least one line.
- a member according to the invention has holes situated on both sides of the slot.
- the object of the invention is a tobacco industry machine for making filter rods containing objects, comprising a treating unit for a strand of filter fibers, a continuous filter rod converting unit, an object feeding unit, a unit for cutting a continuous rod into individual rods.
- the machine is characterized by having a member according to the invention.
- a machine according to the invention comprises an apparatus for feeding the objects to the strand of filter fibers comprising a delivery wheel.
- the object of the invention is also a method of guiding a strand of filter fibers in the area of placing objects into the strand of filter fibers in a tobacco industry machine, in a member for guiding a strand of filter fibers working together with an apparatus for feeding the objects to the strand of filter fibers, the member for guiding the fibers having a slot in which move(s) a feeding member or members of the object feeder, wherein the strand is guided in a guiding channel from an inlet opening for filter fibers to an outlet opening for the strand of filter fibers.
- a method according to the invention is characterized in that the excess air contained between the fibers of the filter strand is discharged through vent holes so that the converted strand of filter fibers is stabilized and the accuracy of object placing is increased.
- An advantage of the method and the member for guiding a strand of filter fibers and discharging the air is a more uniform distribution of acetate fibers around the beads in a cross section.
- Fig. 1 diagrammatically shows a machine 1 for making bead-containing rods.
- Acetate fibers 2 are fed from a fiber dispenser usually in the form of a bale 3 of compressed acetate fibers.
- the fibers 2 are stretched and loosened by means of compressed air and cylinders in a strand treating unit 4. As a result, the acetate fibers spread and can contain more air among them. Then the fibers are moistened with a softening liquid (e.g. triacetin).
- a machine 1 for making bead-containing rods is provided with an inserting member 5 in the form of a funnel through which a strand of fibers is conveyed and in which a preliminary compression of the fibers occurs.
- An inserting member 5 is usually provided with openings facilitating the discharge of excess air from among the fibers. Behind the inserting member 5, a member 6 for guiding a strand of acetate fibers is situated in which a preliminary strand conversion occurs, whereas the member 6 is adapted to work together with a member 7 for feeding beads which are placed into a strand of acetate fibers.
- a feeding member 7 operating in the bead placing area is a part of a not shown bead feeder.
- a feeding member 7 may be a rotary disc or drum with a plurality of bead feeding pockets disposed on the circumference.
- a bead feeding member can also be positioned by means of a feeder provided with feeding members feeding linearly arranged bead groups, with the feeding member having e.g.
- the feeder can be provided with multiple different members adapted to convey the objects from an object dispencer to the area of placing the objects into a strand of filter fibers. Further behind the area of placing the objects into a strand of acetate fibers in a direction of movement of the strand, an adhesive feeding unit 8 and the unit for wrapping a strand into a wrapper 9 are situated. A rotating cutting head 10 for cutting a continuous acetate rod into individual rods is provided in the machine.
- Fig. 2 shows a fragment of a machine 1 containing a member 6A for guiding a fiber strand adapted to work together with a feeding member 7 in the form of a disc provided with a plurality of bead 12 feeding pockets 11.
- a feeding member 7 in the area 20 of placing objects in the strand of filter fibers is inserted in a slot 13 of a member 6A shown in Fig. 3 depicting a vertical longitudinal section through a member 6A.
- a member 6A for guiding a strand of filter fibers has an inlet opening 14 and an outlet opening 15 as well as a guiding channel 16 running from an inlet opening 14 to an outlet opening 15, whereas an outlet opening 15 can be enlarged by a recess 17.
- a guiding channel is shaped usually conically, however, a different shape of the channel as a composition of a conical, cylindrical or hyperboloid opening is also possible.
- a member 6a is provided with at least one row of vent holes 18 situated along a guiding channel 16. Vent holes 18 can be arranged on both sides of a slot 13. The holes 18 can be linearly or randomly arranged.
- FIG. 4 shows a fragment of a machine 1 provided with a similar member 6B for guiding a strand of filter fibers having three rows of vent holes 18.
- a member 6B for guiding a strand is shown in a perspective view in Fig. 5 .
- Fig. 6 shows a cross section through a member 6B for guiding a strand marked as A-A in Fig. 4 .
- Vent holes 18 are situated perpendicular to a slot 13, with the slot 13 being substantially parallel to the plane of a feeding member 7.
- Fig. 7 shows a cross section through a member 6B for guiding a strand in another embodiment in which the vent holes 18 are arranged radially to a guiding channel 16.
- a member 6A, 6B for guiding filter fibers according to the invention can be used in a situation when a feeding member 7 operates in both a vertical and a horizontal plane, i.e. when a slot is situated vertically or horizontally. It can be also used in any other position.
- a suitably treated strand of acetate fibers 2 passes through an inserting member and then moves through a channel 16 of a member 6A 6B for guiding a strand of filter fibers in an area 20 of placing the objects within a strand.
- a member 6A, 6B for guiding a strand has a plurality of holes so that the air accumulated among the fibers is effectively removed and discharged through the holes 18. This allows placing the objects axially centrally in a continuous filter rod with a high repeatability. An effective removal of the air in the object placing area improves the repeatability of longitudinal arrangement of the objects. In this area, a fiber strand is finally converted to a continuous rod with a specific diameter.
Landscapes
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Manufacturing Of Cigar And Cigarette Tobacco (AREA)
Claims (8)
- Élément (6A, 6B) permettant de guider un brin de fibres de filtre dans une zone de placement d'objets dans le brin de fibres de filtre dans une machine de l'industrie du tabac (1), permettant de travailler conjointement avec un appareil destiné à faire avancer les objets vers le brin de fibres de filtres, et qui comporte une fente (13) dans laquelle se déplacent les éléments d'avancement (7) du dispositif d'avancement d'objets, une ouverture de sortie (15) pour brin de fibres de filtre, un canal de guidage (16) qui relie l'ouverture d'entrée (14) et l'ouverture de sortie (15).
caractérisé en ce qu'il
comprend des trous de ventilation (18) pour stabiliser un brin de fibres de filtre transformé et augmenter la précision du placement des objets. - Un élément selon la revendication 1 caractérisé en ce que les axes des trous (18) sont disposés radialement.
- Un élément selon la revendication 1 caractérisé en ce que les axes des trous (18) sont disposés de façon perpendiculairement substantielle au plan de la fente (13).
- Un élément selon la revendication 1 caractérisé en ce que les trous (18) sont disposés substantiellement le long d'une ligne au moins.
- Un élément selon la revendication 1 caractérisé en ce que les trous (18) sont disposés sur les deux côtés de la fente (13).
- Une machine de l'industrie du tabac destinée à confectionner des filtres contenant des objets, comprenant une unité de traitement pour brin de fibres de filtre, une unité d'avancement d'objets, une unité permettant de couper un filtre long en filtres distincts.
caractérisé en ce qu'il
est fourni avec un élément selon l'une quelconque des revendications 1 à 5. - Une machine selon la revendication 6 caractérisée en ce que l'appareil d'avancement d'objets pour brin de filtre de fibres comprend une roue de livraison.
- Un procédé permettant de guider un brin de fibres de filtre dans une zone de placement d'objets dans le brin de fibres de filtre dans une machine de l'industrie du tabac, dans un élément permettant de guider un brin de fibres de filtre permettant de travailler conjointement avec un appareil destiné à faire avancer les objets vers le brin de fibres de filtres, et qui comporte une fente (13) dans laquelle se déplacent les éléments d'avancement (7) du dispositif d'avancement d'objets, une ouverture de sortie pour brin de fibres de filtre (15), un canal de guidage (16) qui relie l'ouverture d'entrée (14) et l'ouverture de sortie (15).
caractérisé en ce que
l'excès d'air contenu parmi les fibres du brin de filtre est déchargé par les trous de ventilation dans l'élément permettant de guider de façon à ce que le brin de filtre de fibres transformé soit stabilisé et la précision du placement des objets soit augmentée.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL404795A PL225859B1 (pl) | 2013-07-22 | 2013-07-22 | Sposób i element do prowadzenia pasma włókien filtrowych oraz maszyna do wytwarzania sztabek filtrowych |
PCT/IB2014/063211 WO2015011619A2 (fr) | 2013-07-22 | 2014-07-18 | Procédé et élément permettant de guider un brin de fibres de filtre, et confectionneuse de filtres |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3024341A2 EP3024341A2 (fr) | 2016-06-01 |
EP3024341B1 true EP3024341B1 (fr) | 2017-09-13 |
Family
ID=52393899
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP14771374.7A Active EP3024341B1 (fr) | 2013-07-22 | 2014-07-18 | Procédé et élément permettant de guider un brin de fibres de filtre, et confectionneuse de filtres |
Country Status (9)
Country | Link |
---|---|
US (1) | US20160143350A1 (fr) |
EP (1) | EP3024341B1 (fr) |
JP (1) | JP6466441B2 (fr) |
CN (1) | CN105407747B (fr) |
BR (1) | BR112016000625A8 (fr) |
HU (1) | HUE034614T2 (fr) |
PL (1) | PL225859B1 (fr) |
RU (1) | RU2642552C9 (fr) |
WO (1) | WO2015011619A2 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11076635B2 (en) | 2013-02-15 | 2021-08-03 | International Tobacco Machinery Poland Sp. Z O. O. | Method, mechanism and apparatus for momentary compression of filter material |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11134713B2 (en) * | 2017-08-04 | 2021-10-05 | Altria Client Services Llc | Method and apparatus for producing micro bead bearing filter rod |
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US3016945A (en) * | 1960-04-25 | 1962-01-16 | Eastman Kodak Co | Method and apparatus for forming tobacco smoke filters |
US3050430A (en) * | 1959-11-12 | 1962-08-21 | Eastman Kodak Co | Jet and method of filter manufacture |
US3774508A (en) * | 1968-05-08 | 1973-11-27 | American Filtrona Corp | Apparatus for making filter means |
US4179323A (en) * | 1973-08-27 | 1979-12-18 | Liggett Group Inc. | Method for making a hollow filter rod |
US4024012A (en) * | 1973-08-27 | 1977-05-17 | Liggett & Myers Incorporated | Method and apparatus for making a hollow filter and a filter rod |
US4034765A (en) * | 1975-10-30 | 1977-07-12 | Liggett & Myers Incorporated | Tobacco smoke filter |
GB2020158B (en) * | 1978-04-21 | 1982-11-24 | Cigarette Components Ltd | Production of tobacco smoke filters |
US4522616A (en) * | 1982-03-10 | 1985-06-11 | Celanese Corporation | Method and apparatus for forming cigarette filter rods |
US4549875A (en) * | 1983-06-02 | 1985-10-29 | R. J. Reynolds Tobacco Co. | Manufacture of tobacco smoke filters |
US5203757A (en) * | 1986-11-29 | 1993-04-20 | Rhone Poulenc Rhodia Ag | Method and apparatus for producing tobacco smoke filter rods |
US4893637A (en) * | 1987-09-15 | 1990-01-16 | R. J. Reynolds Tobacco Co. | Apparatus and methods for making components of a smoking article |
CN1015865B (zh) * | 1988-05-07 | 1992-03-18 | 若迪阿公司 | 卷烟过滤嘴制造方法和设备 |
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US7074170B2 (en) * | 2002-03-29 | 2006-07-11 | Philip Morris Usa Inc. | Method and apparatus for making cigarette filters with a centrally located flavored element |
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GB2416662A (en) * | 2004-07-30 | 2006-02-08 | C B Kaymich & Company Ltd | Apparatus for applying an additive to cigarette filter tow material |
CN1265741C (zh) * | 2004-08-17 | 2006-07-26 | 常德烟草机械有限责任公司 | 输送烟草产品中杆状物的设备 |
ATE464799T1 (de) * | 2006-01-27 | 2010-05-15 | British American Tobacco Co | Herstellungsverfahren für eine stange zur herstellung eines raucherartikels |
US7972254B2 (en) * | 2007-06-11 | 2011-07-05 | R.J. Reynolds Tobacco Company | Apparatus for inserting objects into a filter component of a smoking article, and associated method |
CN102215705B (zh) * | 2008-11-14 | 2014-02-26 | 菲利普莫里斯生产公司 | 用于将物料引入发烟制品中的方法和设备 |
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KR20120071390A (ko) * | 2009-09-23 | 2012-07-02 | 필트로나 필터 프로덕츠 디벨롭먼트 씨오. 피티이. 엘티디 | 토우 절단기 |
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-
2013
- 2013-07-22 PL PL404795A patent/PL225859B1/pl unknown
-
2014
- 2014-07-18 WO PCT/IB2014/063211 patent/WO2015011619A2/fr active Application Filing
- 2014-07-18 BR BR112016000625A patent/BR112016000625A8/pt not_active IP Right Cessation
- 2014-07-18 RU RU2016104937A patent/RU2642552C9/ru active
- 2014-07-18 HU HUE14771374A patent/HUE034614T2/en unknown
- 2014-07-18 JP JP2016528632A patent/JP6466441B2/ja not_active Expired - Fee Related
- 2014-07-18 US US14/903,051 patent/US20160143350A1/en not_active Abandoned
- 2014-07-18 EP EP14771374.7A patent/EP3024341B1/fr active Active
- 2014-07-18 CN CN201480041624.6A patent/CN105407747B/zh active Active
Non-Patent Citations (1)
Title |
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None * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11076635B2 (en) | 2013-02-15 | 2021-08-03 | International Tobacco Machinery Poland Sp. Z O. O. | Method, mechanism and apparatus for momentary compression of filter material |
Also Published As
Publication number | Publication date |
---|---|
WO2015011619A3 (fr) | 2015-06-25 |
CN105407747B (zh) | 2019-08-23 |
PL404795A1 (pl) | 2015-02-02 |
HUE034614T2 (en) | 2018-02-28 |
RU2642552C9 (ru) | 2018-03-29 |
EP3024341A2 (fr) | 2016-06-01 |
RU2642552C2 (ru) | 2018-01-25 |
PL225859B1 (pl) | 2017-05-31 |
US20160143350A1 (en) | 2016-05-26 |
JP2016524924A (ja) | 2016-08-22 |
CN105407747A (zh) | 2016-03-16 |
WO2015011619A2 (fr) | 2015-01-29 |
JP6466441B2 (ja) | 2019-02-06 |
RU2016104937A (ru) | 2017-08-25 |
BR112016000625A8 (pt) | 2021-05-11 |
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