EP3003587A1 - Facility and procedure for treatment of waste with choice of quality of output products - Google Patents
Facility and procedure for treatment of waste with choice of quality of output productsInfo
- Publication number
- EP3003587A1 EP3003587A1 EP13752662.0A EP13752662A EP3003587A1 EP 3003587 A1 EP3003587 A1 EP 3003587A1 EP 13752662 A EP13752662 A EP 13752662A EP 3003587 A1 EP3003587 A1 EP 3003587A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- heat
- solidificate
- waste
- treatment
- quality
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 238000000034 method Methods 0.000 title claims abstract description 50
- 239000002699 waste material Substances 0.000 title claims description 43
- 230000008569 process Effects 0.000 claims abstract description 37
- 239000000292 calcium oxide Substances 0.000 claims abstract description 36
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 36
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000002440 industrial waste Substances 0.000 claims abstract description 6
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000006243 chemical reaction Methods 0.000 claims description 18
- 239000000126 substance Substances 0.000 claims description 16
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 14
- 238000010494 dissociation reaction Methods 0.000 claims description 13
- 230000005593 dissociations Effects 0.000 claims description 13
- 238000007711 solidification Methods 0.000 claims description 8
- 230000008023 solidification Effects 0.000 claims description 8
- 238000000265 homogenisation Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 238000002604 ultrasonography Methods 0.000 claims description 6
- 238000009825 accumulation Methods 0.000 claims description 5
- 238000009826 distribution Methods 0.000 claims description 5
- 238000005538 encapsulation Methods 0.000 claims description 5
- 238000010521 absorption reaction Methods 0.000 claims description 3
- 230000009467 reduction Effects 0.000 claims description 3
- 238000004321 preservation Methods 0.000 claims description 2
- 238000001179 sorption measurement Methods 0.000 claims 2
- 238000001311 chemical methods and process Methods 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000013078 crystal Substances 0.000 claims 1
- 238000010348 incorporation Methods 0.000 claims 1
- 238000006385 ozonation reaction Methods 0.000 claims 1
- 238000001556 precipitation Methods 0.000 claims 1
- 238000007493 shaping process Methods 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 239000007789 gas Substances 0.000 abstract description 20
- 239000012467 final product Substances 0.000 abstract description 15
- 239000000047 product Substances 0.000 abstract description 12
- 239000000654 additive Substances 0.000 abstract description 10
- 230000009466 transformation Effects 0.000 abstract description 8
- 239000011575 calcium Substances 0.000 abstract description 7
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract description 6
- 229910052791 calcium Inorganic materials 0.000 abstract description 6
- 239000010808 liquid waste Substances 0.000 abstract description 2
- 239000002910 solid waste Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 12
- 239000000920 calcium hydroxide Substances 0.000 description 12
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 12
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 11
- 239000002245 particle Substances 0.000 description 10
- 239000002956 ash Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
- 229910021529 ammonia Inorganic materials 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000000460 chlorine Substances 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 230000007935 neutral effect Effects 0.000 description 5
- 239000000376 reactant Substances 0.000 description 5
- 238000001914 filtration Methods 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 238000004364 calculation method Methods 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 230000008929 regeneration Effects 0.000 description 3
- 238000011069 regeneration method Methods 0.000 description 3
- 239000013049 sediment Substances 0.000 description 3
- 238000000844 transformation Methods 0.000 description 3
- MEUAVGJWGDPTLF-UHFFFAOYSA-N 4-(5-benzenesulfonylamino-1-methyl-1h-benzoimidazol-2-ylmethyl)-benzamidine Chemical compound N=1C2=CC(NS(=O)(=O)C=3C=CC=CC=3)=CC=C2N(C)C=1CC1=CC=C(C(N)=N)C=C1 MEUAVGJWGDPTLF-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000003466 anti-cipated effect Effects 0.000 description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 2
- 229910017464 nitrogen compound Inorganic materials 0.000 description 2
- 150000002830 nitrogen compounds Chemical class 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- KEQXNNJHMWSZHK-UHFFFAOYSA-L 1,3,2,4$l^{2}-dioxathiaplumbetane 2,2-dioxide Chemical compound [Pb+2].[O-]S([O-])(=O)=O KEQXNNJHMWSZHK-UHFFFAOYSA-L 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical class CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 1
- 229910017897 NH4 NO3 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910052924 anglesite Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 150000001722 carbon compounds Chemical class 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000002144 chemical decomposition reaction Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 150000002013 dioxins Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 150000002240 furans Chemical class 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- -1 mazut Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
- B09B3/20—Agglomeration, binding or encapsulation of solid waste
- B09B3/25—Agglomeration, binding or encapsulation of solid waste using mineral binders or matrix
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/02—Agglomerated materials, e.g. artificial aggregates
- C04B18/021—Agglomerated materials, e.g. artificial aggregates agglomerated by a mineral binder, e.g. cement
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/02—Agglomerated materials, e.g. artificial aggregates
- C04B18/023—Fired or melted materials
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G7/00—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
- F23G7/008—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals for liquid waste
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00767—Uses not provided for elsewhere in C04B2111/00 for waste stabilisation purposes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2203/00—Furnace arrangements
- F23G2203/20—Rotary drum furnace
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/20—Waste processing or separation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Definitions
- This invention falls into the following areas:
- E04 B (C03, C04), E04 C; E04 D; E04 F; B29 G, and: G21 F and G21 K.
- Such procedures reduce the harmfulness of material for at least one MAC (maximum allowable concentration) level. Also, the material is transformed into a dry, powdery solidificate with more favourable chemical and physical characteristics.
- CaC0 3 MgO.
- Ca(OH) 2 + CaO is typically a good and cost-effective way to achieve solidification. Some sorts of waste require only CaO, while others need only Ca(OH) 2 . We select reactants by analysing the waste.
- solidificate treated with less calcium oxide contains high levels of moisture, which decreases its quality and further industrial use.
- Cost is often the reason why waste is not treated this way, but instead by using other methods that do not meet basic ecological criteria.
- Solidification transformation of liquid, oily and muddy materials into powder
- solidification is a simpler and cheaper procedure, many opt for incineration because such waste contains certain amounts of energy, which improves cost-effectiveness of incineration.
- New regulations and European directives do not support incineration of such waste because of uncontrolled air pollution (dioxins, furans, hydrocarbons, nitrogen compounds, etc.)
- Other procedures that need other additives are no longer in frequent use because of their price and large quantities of solidificate coming from the process.
- Illustration 1 Layout of the facility
- Illustration 2 Blueprint of the facility
- Illustration 3 Regenerator for obtaining calcium oxide and ash from solidificate Drawings are marked as follows:
- This invention focuses on communal or industrial waste.
- waste usually contains chemical compounds with carbon, different compounds with hard metals, alkyl compounds, alkaline and / or acidic content as well as numerous nitrogen, chlorine and other compounds.
- Waste undergoes preparation to become a material of equal granulation (0-20 mm).
- Useful components are being recycled (metal, glass, plastic, paper) and the rest is chopped up and crushed to become a material awaiting treatment.
- Air pump is installed in the pipeline and placed in front of Injector, Air pump blows in the warm air and that is how the warm air comes into direct contact with incoming waste.
- Ozone circulates in 1-2 g/s and decomposes organic contents.
- Organic contents break down, molecular and physical water separate, physical characteristics (colour, granulation) change. This contributes to better molecular dissociation in Second reactor's line.
- Dissociation device conducts the initial ion separation from molecule's atoms into anions (especially OH ) and cations (especially H + ). This is followed by ionic dissociation of hard metals and carbon portion of organic fraction. This depends on the surrounding available energy and negative electric potential of ions in dissociated parts.
- Electromagnet is placed underneath the reactor's line and it creates a magnetic field. Electromagnet has a rounded shape as it follows the curvature of reactor's external surface. (Author has a registered Patent pertaining to this: HR/P20080004) g) Device for chopping up particles (9)
- Device for chopping up particles is placed between the first and second reactors' lines. It serves as a so-called micronizer as it chops up the particles.
- Parallel oxide encapsulators (12) are inside the second reactor's line (11). Particles need to be chopped up to less than 10 ⁇ m .
- Encapsulated performs the function of pozzolamic impact on atoms coming from dissociated molecules under the conditions of vacuum space.
- Vacuum space is located inside the whirlwind surrounded by steam and gases. This is followed by encapsulation of cations (especially heavy metals and non-carbons of the organic fraction) which depends on available surrounding energy.
- Filtration system for cleansing of gas, steam and particles consists of:
- Scrubber is a device for chemical treatment of gaseous content. Sediment containing mostly hydroxide is taken out, shaped as mud, and returned back into the process.
- Increased temperature of the filter is added to the Heat exchange system as a part of total accumulated heat energy needed for treatment.
- Gasses exiting scrubber consist of water steam, C0 2 and N 2 .
- Mud in the baggy filter and scrubber contain sulphate salts and together with mud from water filter, they are reintroduced to the process.
- Increased temperature inside scrubber is added to the Heat exchange system as a part of total accumulated heat energy needed for treatment.
- a small ozone exposure (1 g/s) is sufficient for waste with high portion of organic compounds. Transformation, oxidation, physical and chemical decomposition of organic compounds happens quickly regardless of temperature differences.
- Final product is defined on output transporters (24, 25).
- One transporter is for basic treatment without additional changes to the final product.
- Second output is designed for additional integration, including special additives, depending on product's further use.
- Product (E) leaving the facility after basic treatment is a so-called Neutral product. It has standard qualities expected from solidificate (according to Patent HR/P20100575 A2 by same Author).
- Adjusted final product can be the one intended for production of silicate granulates (Patent P20100300, same Author) or gascement (Patent HR/P20100325, same Author).
- Solidificate as the final product of basic treatment, is taken by transporter (35) into Regenerator's rotary kiln (36).
- Transporter (35) into Regenerator's rotary kiln (36).
- burner (37) to break down solidificate.
- Heat exchanger (39) to distribute heat for further use,
- Solidificate to be transformed into calcium oxide has the following content:
- So-called Calciner is a device for regeneration of solidificate. We use it to obtain calcium oxide as follows: transporter (35) takes solidificate to be roasted and then decomposed in regenerator's rotary kiln (36).
- Ash (41) collects in cyclone, while Heat exchanger (39) distributes hot air (VI). Some of hot air goes into burner to increase the use of heat energy. Function of ozone is shown by describing its influence on organic contents in waste. Here are the most common chemical reactions:
- Ozone breaks down organic carbon in amount of 0.55 g/s. If material has ⁇ 50% of organic content, ozone will penetrate the organic content in amount of 3 kg/h. Ozone will get through the organic content in amount of 0.55 g/s (ozone 0.02%) when the treatment capacity is 1.5 kg/s (5.4 t/h). The remaining ozone quickly transforms into O 2 This procedure lowers the amount of calcium oxide needed for treatment.
- Material awaiting treatment (communal and / or industrial waste) is chopped up to equal granulation and analysed.
- This total energy in MJ/kg is compared to energy needed to transform waste into a dry solidificate.
- Level of moisture in solidificate has to be ⁇ 10%.
- Temperature in reactors' lines has to be 100-125 °C.
- Temperature of output material has to be 75-85 °C. Losses pertain to energy taken within the process (endothermic reactions) and heat lost through facility's openings and surface.
- Quality of the final product determines the speed of the process. Calculation of energy balance tells us about needed treatment capacity. If we do not need solidificate as the final product, then the energy shortage can be solved by using heat released during its regeneration, temperatures of hot air being ⁇ 600 °C.
- Temperature of input waste can be 10-15% lower than temperature of gases and steam exiting reactors' lines. This depends on insulation of heat exchangers as well as length of the pipeline.
- Treatment is cost-effective because we harmonise all energy values in different phases of the process and utilise energy obtained through that same process.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Civil Engineering (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Processing Of Solid Wastes (AREA)
- Pretreatment Of Seeds And Plants (AREA)
- Disintegrating Or Milling (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP18208147.1A EP3513885B1 (en) | 2013-06-07 | 2013-06-17 | Facility and procedure for treatment of a solidificate |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| HRP20130502 | 2013-06-07 | ||
| PCT/HR2013/000018 WO2014195740A1 (en) | 2013-06-07 | 2013-06-17 | Facility and procedure for treatment of waste with choice of quality of output products |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP18208147.1A Division EP3513885B1 (en) | 2013-06-07 | 2013-06-17 | Facility and procedure for treatment of a solidificate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP3003587A1 true EP3003587A1 (en) | 2016-04-13 |
Family
ID=49029127
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP13752662.0A Ceased EP3003587A1 (en) | 2013-06-07 | 2013-06-17 | Facility and procedure for treatment of waste with choice of quality of output products |
| EP18208147.1A Active EP3513885B1 (en) | 2013-06-07 | 2013-06-17 | Facility and procedure for treatment of a solidificate |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP18208147.1A Active EP3513885B1 (en) | 2013-06-07 | 2013-06-17 | Facility and procedure for treatment of a solidificate |
Country Status (7)
| Country | Link |
|---|---|
| EP (2) | EP3003587A1 (sr) |
| CN (1) | CN105473245A (sr) |
| EA (1) | EA201592181A1 (sr) |
| ES (1) | ES2842000T3 (sr) |
| HR (1) | HRP20202060T1 (sr) |
| RS (1) | RS61353B1 (sr) |
| WO (1) | WO2014195740A1 (sr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2766454C1 (ru) * | 2021-03-22 | 2022-03-15 | Леонид Александрович Аминов | Способ переработки органических отходов |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1245346B (it) * | 1990-04-09 | 1994-09-20 | Blufin Spa | Metodo di preriscaldo rottame di ferro tramite pirolisi di residui resinosi in esso contenuti con recupero integrale del loro contenuto energetico e miglioramento del ciclo siderurgico |
| DE10158968B4 (de) * | 2001-11-30 | 2010-01-14 | Khd Humboldt Wedag Gmbh | Verfahren zur Emissionsminderung der Abgasschadstoffe Dioxine und/oder Furane bei einer Zementklinkerproduktionslinie |
| CN2912851Y (zh) * | 2006-02-27 | 2007-06-20 | 孙实庆 | 废弃物能源化装置 |
| CN101143370B (zh) * | 2006-09-15 | 2010-05-12 | 张榕倡 | 磁能垃圾分解设备 |
| EP1930303A1 (de) * | 2006-11-13 | 2008-06-11 | Montanuniversität Leoben | Verfahren und Vorrichtung zur thermischen Behandlung von Rohstoffen |
| HRP20080004B1 (en) | 2008-01-07 | 2011-10-31 | Španović Milli | Device for magnetic ionisation in solidifying process |
| DK200800141A (da) * | 2008-02-01 | 2009-08-02 | Smidth As F L | Anlæg til fremstilling af cement |
| TW200940158A (en) * | 2008-03-07 | 2009-10-01 | Taiheiyo Cement Corp | Cement kiln extracted gas treating system and treating method |
| US7959436B2 (en) * | 2008-07-29 | 2011-06-14 | Carmeuse Lime, Inc. | Fine dust removal system for lime kiln |
| RU2380615C1 (ru) * | 2008-10-01 | 2010-01-27 | ГринЛайтс Энерджи Солюшнс, Общество с ограниченной ответственностью | Способ переработки бытовых отходов с использованием пиролизного реактора, система для его осуществления и пиролизный реактор |
| CN101618929A (zh) * | 2008-11-04 | 2010-01-06 | 刘文治 | 含重金属碱性污泥的资源化处理方法 |
| HRP20090092A2 (hr) | 2009-02-13 | 2011-06-30 | Španović Milli | Uređaj za sušenje, isparavanje i hlađenje materijala naročito kod solidifikacije s kalcijevim oksidom i povratnim solidifikatom |
| HRP20090425A2 (hr) | 2009-08-03 | 2011-06-30 | �panovi� Milli | Uređaj za obradu koncentriranih otopina otpadnih procjednih voda komunalnih i industrijskih deponija |
| HRPK20100300B3 (hr) | 2010-05-27 | 2013-03-31 | Milli Španović | Postrojenje za silikatnu konglomeraciju solidifikata iz procesa obrade muljeva |
| HRPK20100325B3 (hr) | 2010-06-05 | 2013-04-30 | Milli Španović | Postupak proizvodnje silikatnih vrsta plino-betona na bazi solidifikata |
| HRPK20100575B3 (hr) | 2010-10-30 | 2013-08-31 | Milli Španović | Postrojenje i postupak proizvodnje neutralnog solidifikata iz obrade opasnog otpada |
| FI126564B (fi) * | 2011-02-28 | 2017-02-15 | Andritz Oy | Menetelmä ja laitteisto meesan polttamiseksi |
| DE102011050677B4 (de) * | 2011-05-27 | 2014-08-28 | Südbayerisches Portland-Zementwerk Gebr. Wiesböck & Co. GmbH | Vorrichtung und Verfahren zur Herstellung von Zementklinker |
| ITMI20111149A1 (it) * | 2011-06-23 | 2012-12-24 | Ecospray Technologies S R L | Apparato e metodo per la riduzione selettiva non catalitica sncr dei nox all'interno di impianti industriali di produzione del cemento |
| CN202539174U (zh) * | 2012-04-28 | 2012-11-21 | 安阳艾尔旺新能源环境有限公司 | 垃圾处理装置 |
| CN102716894A (zh) * | 2012-06-07 | 2012-10-10 | 泓天(大连)环境科技发展有限公司 | 一种热风辅助的城市原生垃圾好氧生物干化方法与系统 |
-
2013
- 2013-06-17 ES ES18208147T patent/ES2842000T3/es active Active
- 2013-06-17 WO PCT/HR2013/000018 patent/WO2014195740A1/en active Application Filing
- 2013-06-17 CN CN201380078752.3A patent/CN105473245A/zh active Pending
- 2013-06-17 EP EP13752662.0A patent/EP3003587A1/en not_active Ceased
- 2013-06-17 EP EP18208147.1A patent/EP3513885B1/en active Active
- 2013-06-17 RS RS20201577A patent/RS61353B1/sr unknown
- 2013-06-17 EA EA201592181A patent/EA201592181A1/ru unknown
-
2020
- 2020-12-23 HR HRP20202060TT patent/HRP20202060T1/hr unknown
Non-Patent Citations (2)
| Title |
|---|
| None * |
| See also references of WO2014195740A1 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2766454C1 (ru) * | 2021-03-22 | 2022-03-15 | Леонид Александрович Аминов | Способ переработки органических отходов |
Also Published As
| Publication number | Publication date |
|---|---|
| EA201592181A1 (ru) | 2016-07-29 |
| HRP20202060T1 (hr) | 2021-02-19 |
| WO2014195740A1 (en) | 2014-12-11 |
| ES2842000T3 (es) | 2021-07-12 |
| EP3513885B1 (en) | 2020-10-07 |
| CN105473245A (zh) | 2016-04-06 |
| EP3513885A1 (en) | 2019-07-24 |
| RS61353B1 (sr) | 2021-02-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Nowak et al. | Heavy metal removal from sewage sludge ash and municipal solid waste fly ash—a comparison | |
| Mousavi et al. | Removal of lead from aqueous solution using waste tire rubber ash as an adsorbent | |
| Chang et al. | Accelerated carbonation of steelmaking slags in a high-gravity rotating packed bed | |
| CA1311343C (en) | Method for scrubbing pollutants from an exhaust gas stream | |
| CA2876257C (en) | Removal device for radioactive cesium | |
| EP3104961B1 (en) | Reactive composition based on sodium bicarbonate and process for its production | |
| CN107922213A (zh) | 水处理系统、发电成套设备及水处理系统的控制方法 | |
| CN1169959A (zh) | 含有有机物的水介质的处理方法及水热反应装置 | |
| CN103052607B (zh) | 氯旁路粉尘及废气的处理方法及处理装置 | |
| CN102906502A (zh) | 通过水热分解和资源再循环使废料变能源 | |
| US20110251449A1 (en) | Treatment of fly ash | |
| US4384923A (en) | Process for the hygienization of carbonation sludges | |
| CN108706784A (zh) | 一种处理烧结烟气脱硫脱硝废水的系统和方法 | |
| US8673228B2 (en) | System for reducing environmental pollutants | |
| Wey et al. | The behavior of heavy metal Cr, Pb and Cd during waste incineration in fluidized bed under various chlorine additives | |
| Ishida et al. | Full-scale plant study on low temperature thermal dechlorination of PCDDs/PCDFs in fly ash | |
| WO2015052325A1 (en) | Capture of carbon dioxide | |
| JP3626459B2 (ja) | 有機ハロゲン化合物処理装置及びその処理方法 | |
| EP3513885B1 (en) | Facility and procedure for treatment of a solidificate | |
| CA2272631A1 (en) | Incinerator | |
| JP2004114003A (ja) | リン吸着材とその生成方法、リン回収方法、リン吸着材の処理方法、及びリン成分を含む水の処理方法 | |
| JP2005028312A (ja) | フッ素吸着剤及びその製法 | |
| KR20220104675A (ko) | 탄산형 층상 복수산화물의 재생방법 및 산성 배기가스 처리설비 | |
| Glazyrin et al. | Study of the possibilities of integrated treatment of flue gases and waste water from coal-fired heat power plants | |
| EP3363524A1 (de) | Verfahren zur abscheidung saurer schadgase aus einem eine niedrige abgastemperatur aufweisenden abgas |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| 17P | Request for examination filed |
Effective date: 20151230 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
| AX | Request for extension of the european patent |
Extension state: BA ME |
|
| 17Q | First examination report despatched |
Effective date: 20170321 |
|
| REG | Reference to a national code |
Ref country code: DE Ref legal event code: R003 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN REFUSED |
|
| 18R | Application refused |
Effective date: 20181126 |