EP2984227B1 - Sicherheitselement mit einer maskierungsstruktur mit einer mischung aus nanometrischen füllstoffen - Google Patents
Sicherheitselement mit einer maskierungsstruktur mit einer mischung aus nanometrischen füllstoffen Download PDFInfo
- Publication number
- EP2984227B1 EP2984227B1 EP14721533.9A EP14721533A EP2984227B1 EP 2984227 B1 EP2984227 B1 EP 2984227B1 EP 14721533 A EP14721533 A EP 14721533A EP 2984227 B1 EP2984227 B1 EP 2984227B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- security
- masking structure
- masking
- layer
- comprised
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 230000000873 masking effect Effects 0.000 title claims description 83
- 239000000945 filler Substances 0.000 title claims description 17
- 239000000203 mixture Substances 0.000 title claims description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 44
- 239000000049 pigment Substances 0.000 claims description 40
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 30
- 239000004408 titanium dioxide Substances 0.000 claims description 17
- 239000008119 colloidal silica Substances 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- 239000000853 adhesive Substances 0.000 claims description 7
- 230000001070 adhesive effect Effects 0.000 claims description 7
- 239000000891 luminescent agent Substances 0.000 claims description 7
- 239000011230 binding agent Substances 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 239000000835 fiber Substances 0.000 claims description 5
- 239000010445 mica Substances 0.000 claims description 5
- 229910052618 mica group Inorganic materials 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000011888 foil Substances 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 239000012815 thermoplastic material Substances 0.000 claims description 3
- 230000007423 decrease Effects 0.000 claims description 2
- 230000003247 decreasing effect Effects 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
- 239000011707 mineral Substances 0.000 claims description 2
- 239000012945 sealing adhesive Substances 0.000 claims 1
- 239000010410 layer Substances 0.000 description 65
- 239000000758 substrate Substances 0.000 description 15
- 229910052751 metal Inorganic materials 0.000 description 13
- 239000002184 metal Substances 0.000 description 13
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- 239000002245 particle Substances 0.000 description 9
- 230000003287 optical effect Effects 0.000 description 7
- 239000000123 paper Substances 0.000 description 7
- 230000005855 radiation Effects 0.000 description 6
- 230000005540 biological transmission Effects 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 238000009792 diffusion process Methods 0.000 description 5
- 229910021485 fumed silica Inorganic materials 0.000 description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 238000000149 argon plasma sintering Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000000295 complement effect Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000001465 metallisation Methods 0.000 description 3
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
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- 238000002955 isolation Methods 0.000 description 2
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- 238000004020 luminiscence type Methods 0.000 description 2
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- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 239000002966 varnish Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
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- 239000012790 adhesive layer Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 230000003321 amplification Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
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- 239000007850 fluorescent dye Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- 239000001056 green pigment Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
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- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
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- 239000011241 protective layer Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229920006352 transparent thermoplastic Polymers 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/355—Security threads
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/378—Special inks
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/40—Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
- D21H21/44—Latent security elements, i.e. detectable or becoming apparent only by use of special verification or tampering devices or methods
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/40—Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
- D21H21/44—Latent security elements, i.e. detectable or becoming apparent only by use of special verification or tampering devices or methods
- D21H21/48—Elements suited for physical verification, e.g. by irradiation
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
- D21H21/52—Additives of definite length or shape
Definitions
- “Secure document” means a means of payment, such as a bank note, a check or a restaurant ticket, an identity document, such as an identity card, a visa, a passport or a passport. driver's license, a lottery ticket, a ticket, a tax stamp or stamp, or a ticket for cultural or sporting events.
- a security thread into a paperboard substrate.
- This yarn is introduced totally in the paper or alternatively at least partly on the surface of the paper, especially in window.
- This thread usually includes a text that appears in transmitted light, sometimes called CLEARTEXT®. Except for any windows, it is preferable that the wire is not visible in reflection, so as not to detract from the aesthetics of the document and not to hinder the visibility of the impressions carried by the substrate. This also provides additional security, the wire and its text being little or not visible in reflected light and visible in transmitted light.
- a first solution is to use a highly reflective wire, by depositing a relatively large thickness of metal, to obtain a high optical density.
- metal layers for example of aluminum, of low optical density.
- a second solution is to apply a masking layer on the wire.
- a masking layer consisting of titanium dioxide, zinc oxide or other particles makes it possible to make the back of the white wire dull, reducing the metallic appearance of the wire.
- These layers are generally thin and do not allow to hide optimally a security thread.
- increasing the thickness of such layers affects the visibility of CLEARTEXT® in transmitted light.
- the masking layer evenly covers one side of the wire, its opacity reduces the visibility of the text in transmitted light. It is possible to deposit the masking layer only on the metal, but this complicates the manufacturing process. In addition, the masking layer can screen UV and thus oppose the use of luminescent layers within the wire.
- a third solution for reducing the visibility of the yarn consists in producing a masking layer in the form of a semi-reflecting, continuous or raster metal layer.
- the disadvantage of this solution is to reduce the visibility of the text.
- FR 2 87I 174 discloses a document comprising an information vector and a band masking element.
- US 2002/0056758 discloses an opaque protective layer affixed to both sides of a magnetic layer.
- This opaque layer may contain iridescent pigments.
- An alternative is to print the yarn with an opaque ink, for example containing titanium dioxide, which does not pass UV radiation, or optically variable pigments.
- US 2008/0030020 describes a security document comprising a semi-reflective coating comprising iridescent pigments, such as mica-based particles, which are micrometric, non-nanometric particles.
- iridescent pigments such as mica-based particles, which are micrometric, non-nanometric particles.
- such pigments have a relatively high opacity.
- US 2010/0213698 A1 discloses a security element.
- the invention achieves this goal by means of a security element according to claim 1.
- nuclear charge is meant a charge of one or more powdery compounds whose average size D50 is between 30 nm and 500 nm.
- at least one of the charges consists of a single particulate material, preferably transparent to UV radiation.
- the two charges may each consist of a single particulate material, these materials being different.
- the security element may comprise at least one luminescent agent and at least one of the nanometric charges is at least partially, preferably totally, transparent to UV radiation, in particular UV radiation useful for luminescence.
- the nanometric charge at least partially transparent to UV is present in a mass quantity of between 20 and 80%, better still between 30 and 70% and even more preferably between 40 and 60%, relative to the mass of the masking. All weights and weights are expressed in sec unless otherwise stated.
- Nanometric fillers such as silica, titanium dioxide, calcium carbonate, barium sulfate, and zinc oxide can be used.
- one of the, more preferably both, nanometric fillers has a dimension D50 of between 50 and 300 nm.
- said at least two nanometric charges differ in their refractive index by at least 0.8.
- the masking structure is preferably in the form of a single masking layer, comprising said mixture of at least two nanometric charges.
- the security element may comprise as titanium dioxide nanoscale in the masking structure.
- the amount of titanium dioxide is sufficiently small not to excessively absorb the UV radiation and to allow the use within the security element of at least one luminescent compound, in particular fluorescent under UV (365 nm), for example applied by printing or mixed with the masking layer or with a varnish or an adhesive of the security element.
- Titanium dioxide is preferably of anatase nature, because it then has the advantage of having a lower UV absorption compared to titanium dioxide of rutile nature.
- the anatase titanium dioxide is in particular at least partially transparent to UV, and in particular transparent over at least one wavelength range of the UV range.
- the multilayer interference pigment has the particularity of preferentially selecting certain wavelengths in reflection and in transmission.
- a blue iridescent pigment reflects in the specular direction (angle of reflection equal to the angle of incidence) more blue wavelengths than the others.
- the color obtained is then complementary to the color in reflection, that is to say red-orange.
- the multilayer interference pigments may be relatively transparent because they are not very absorbent, and consequently a layer of multilayer interference pigment will have diffuse reflection (in all other directions other than the specular direction) the same color as in transmission (complementary to the color in specular reflection).
- the layer of blue iridescent pigment spread on a white paper will give a red-orange color.
- the combination of the pigment and the nanometric charges enhances the diffusion of incident light within the masking structure, and decreases the reflective visibility of the security element. This combination also makes it possible to limit the proportion of the nanometric filler having the highest refractive index, in particular titanium dioxide, and thus to limit the opacification in transmitted light and, if appropriate, the absorption of UV.
- the multilayer interference pigment according to the invention comprises a transparent base, preferably mineral, coated with at least one layer of a refractive index material different from that of the base.
- the pigment may comprise a platelet base, preferably of mica or glass.
- the pigment comprises mica or silica (silicon dioxide) coated with titanium dioxide.
- the interference pigment has a blue, green or blue-green color.
- the average size D50 of the pigment is preferably between 2 and 150 microns, more preferably between 5 and 40 microns, more preferably between 5 and 25 microns.
- the mass quantity of multilayer interference pigment relative to the mass of the masking structure is preferably between 1 and 40%, better still between 2 and 30%, and more preferably between 5 and 15%.
- the security element is preferably a security thread
- the invention retains an interest when the security element is a foil or board or other security element.
- the security element may have two opposite major faces and the masking structure be arranged to reduce the visibility of at least one of said faces.
- the masking structure covers a support of the security element on one of its sides.
- the masking structure can be in the form of a continuous coating without openings, thanks to the low opacity of the filler and the pigment. Thus, the manufacture of the security element is facilitated.
- the masking structure may cover transparent or translucent areas of a security structure carried by the security element, as well as opaque areas of the security structure.
- the thickness of the masking structure may be between 5 and 20 microns, more preferably between 8 and 13 microns.
- the nanometric charges and, if appropriate, the multilayer interference pigment may be dispersed in a binder, which may be of any type, and in particular be applied in a fluid state to the element during its manufacture.
- This binder can crosslink on drying or under UV irradiation.
- the security element comprises a security structure according to the invention which can be implemented in various ways, but preferably the security structure comprises an opaque layer, in particular printed or deposited by a vacuum deposition method, and at least one aperture in this opaque layer.
- the security structure is reflective and comprises in particular a metallization / demetallization. It is preferably a reflective security structure of low optical density, especially associated with underlying opaque layers.
- the metal is, for example, aluminum, gold, copper, iron, silver, chromium, nickel, zinc, cadmium, bismuth, and their alloys and oxides. Openings in the form of text, for example in negative writing, are conventionally formed in the metal by demetallization.
- the security element according to the invention comprises a support, in particular a thermoplastic material, preferably PET or polyester.
- This support is preferably entirely transparent.
- the security structure may be located on one side of the support and the masking structure on the other side.
- the security structure and the masking structure can also be located on the same side of the support.
- the masking structure can also be present in duplicate on the security element, on each side of the support, which may be desirable for masking a magnetic wire for example.
- the security element may comprise a luminescent agent, in particular a fluorescent agent, for example applied by printing, mixed with a varnish or an adhesive of the security element or preferably incorporated in the masking structure, more preferably mixed with a layer. mask comprising the multilayer interference pigment and the nanoscale charge.
- the security element may comprise a heat-sealable adhesive, in particular in contact with the masking structure.
- the adhesive may comprise a luminescent agent, in particular fluorescent under UV.
- the security element may comprise a luminescent agent, preferably UV fluorescent, within a distinct layer of the masking structure, preferably within a layer opposite the safety structure relative to the support, when it exists.
- a luminescent agent preferably UV fluorescent
- the invention further relates, in another of its aspects, to a secure document incorporating a security element according to the invention.
- the security element is for example incorporated in mass, window or on the surface of the document substrate.
- the Masking structure may be present on the back of the security element, when the window is located on the front side.
- the security element may or may not extend from one edge to the other of the document.
- the document may include one or more additional security elements as defined below.
- additional security features some are detectable by eye, daylight or artificial light, without the use of a particular device.
- additional security elements comprise, for example, colored fibers or boards, fully or partially printed or metallized wires. These additional security features are said to be first level.
- additional security elements are detectable only with a relatively simple apparatus, such as a lamp emitting in the ultraviolet (UV) or infrared (IR).
- UV ultraviolet
- IR infrared
- additional security elements include, for example, fibers, boards, strips, wires or particles. These security elements can be visible to the naked eye or not, being for example luminescent under the lighting of a Wood lamp emitting at a wavelength of 365 nm. These security elements are said to be second level.
- Additional security elements require for their detection a more sophisticated device. These security elements are for example capable of generating a specific signal when they are subjected, simultaneously or not, to one or more external excitation sources. The automatic detection of the signal makes it possible to authenticate, if necessary, the document.
- additional security elements comprise, for example, tracers in the form of active materials, particles or fibers capable of generating a specific signal when these tracers are subjected to optronic, electrical, magnetic or electromagnetic excitation. These additional security features are said to be third-level.
- the additional security element (s) present in the document may have first, second or third level security features.
- the subject of the invention is also a method for authenticating a document as defined above, in which it is observed that light transmitted the security element. Observation can be done through a window of the document.
- the invention further relates, in another of its aspects, a method of manufacturing a document as defined above, wherein is incorporated in the window or on the surface of the security element.
- the document 1 comprises a substrate 2, preferably paper, formed of one or more jets.
- the document 1 integrates a security element 10 according to the invention, in the form of a thread ("thread” in English) in the example under consideration.
- the security element 10 comprises a support 11 made of thermoplastic material, which ensures the mechanical strength of the wire.
- This support 11 is for example in matter transparent thermoplastic such as PET or polyester.
- the thickness e of the support 11 is, for example, from 6 to 30 ⁇ m and the width w of the element 10 from 1 to 10 mm.
- the security element 10 comprises a security structure 12, for example formed by metallization / demetallization.
- the security structure 12 thus comprises, for example, a metal layer 12a, opaque, and openings 12b in the form of letters or other recognizable patterns. These openings 12b are visible in transmitted light through a window 3 of the document 1.
- the security structure 12 can also form a recognizable halftone image whose subject is for example present on the document.
- the security structure preferably comprises metallization / demetallization, it may also comprise printed patterns, for example with a metallic, magnetic or electrically conductive ink.
- the security element 10 comprises a masking structure 13, for example as illustrated in FIG. figure 2 in the form of a single layer opposite the safety structure 12 with respect to the support 11.
- the security element 10 may also comprise a layer of a heat-sealable adhesive 14, preferably located as illustrated on an outer face of the element 10, for example on the opposite side to the security structure 12 with respect to the support 11.
- the element 10 may comprise a layer of heat-sealable adhesive on each of its external faces.
- the layer 14 may comprise a luminescent agent, in particular a fluorescent agent.
- the masking structure 13 makes it possible to reduce the visibility of the element in the substrate 2 while preserving the transparency of the patterns 12b in transmission, as well as the UV transparency if necessary.
- the invention avoids allowance issue within the substrate because the masking structure 13 can be thick relatively low cost.
- the invention allows the use to achieve the security structure 12 of a metal layer of relatively low optical density, thanks to the presence of the masking layer 13, without this makes the wire too visible in reflection.
- the masking structure 13 comprises, according to the invention, a mixture of at least two nanometric charges.
- the masking structure 13 comprises colloidal fumed silica, the particle size of which is nanometric, combined with carbon dioxide.
- nanometric titanium for example titanium dioxide Rutile PGG 121 from the company Cristal whose particle size D50 is less than 220 nm.
- the colloidal fumed silica consists of silica nanoparticles, the size of which is less than 120 nm for half of the particles.
- the size of the silica particles is between 30 and 500 nm and more preferably between 50 and 300 nm.
- the thickness t of the masking layer is between 2 and 30 ⁇ m, preferably between 5 and 20 ⁇ m and better still between 8 and 13 ⁇ m.
- the mass quantity of colloidal fumed silica with respect to the mass of the masking structure is between 20 and 80%, better between 30 and 70% and preferably between 40 and 60%.
- the mass quantity of titanium dioxide relative to the mass of the masking structure is preferably between 1 and 40%, better still between 2 and 30% and preferably between 3 and 1.5%.
- This layer can be applied by gravure (or gravure coating) in the form of a coating of uniform thickness of 10 microns.
- the security structure 12 is a 300 nm thick aluminum layer, with a negative writing text, as illustrated in FIG. figure 4 .
- the support 11 is made of PET.
- At least one optically variable layer may also be deposited.
- This additional layer comprises for example liquid crystals, iridescent pigments and / or interferential layers or structures such as a hologram.
- the security element may also comprise a magnetic coating, for example in code form.
- the security structure 12 and the masking structure 13 can be located on the same side of the support 11.
- the other face of the support can receive any additional security means, for example a luminescent compound, an optically variable structure, a holographic structure or a lenticular network.
- FIG 4 there is shown a security element 10 in which the masking structure 13 is composed of two superimposed layers 13a and 13b respectively containing the nanometric charges and the multilayer interference pigment. These two layers can be applied to one another.
- the security element may be in the form of an integral security wire fully en masse in the security document substrate.
- the masking layer is advantageously applied to both sides of the wire to mask it in reflection and allow its observation in transmitted light.
- the security element 10 may also be in the form of a foil or patch applied to the surface of the substrate 2 of the document 1 as shown in figure 5 .
- the masking structure according to the invention then makes it possible to make the inner face 19 of the element 10 turned towards the substrate 2 less visible when the masking structure is interposed between the substrate 2 and the layer or layers of the element. security to conceal.
- the security element 10 is in the form of a planchette.
- the masking structure can extend on the two main faces of the board.
- the latter may comprise a luminescent compound, in particular a fluorescent compound.
- the security element is in the form of a fiber, in particular colored, metallic and / or magnetic.
- the substrate may have a color shade.
- the masking layer may be substantially white or have the same colored shade.
- the adjustment of the color of the masking layer can be done by adjusting the color of the mixture of the nanometric charges and, if appropriate, the iridescence color of the multilayer interference pigment.
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Credit Cards Or The Like (AREA)
- Printing Methods (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
Claims (17)
- Sicherheitselement (1), vorzugsweise Sicherheitsfaden, Folie, Plakette oder Faser, vorzugsweise Sicherheitsfaden, für ein sicheres Dokument (1), umfassend:- eine Maskierungsstruktur (13) um die Sichtbarkeit einer Oberfläche des Elements zu verringern, wenn letzteres innerhalb des Dokuments (1) oder auf seiner Oberfläche vorliegt, wobei die Maskierungsstruktur eine Mischung ist aus mindestens zwei nanoskaligen Füllstoffen aus einer oder mehren pulverförmigen Verbindungen, deren Durchschnittsgröße D50 zwischen 30 nm und 500 nm liegt, wobei die wenigstens zwei nanoskaligen Füllstoffe einen Brechungsindex haben, der sich um wenigstens 0,5 unterscheidet, wobei einer der wenigstens zwei nanoskaligen Füllstoffe kolloidale Kieselsäure mit einem Massenanteil zwischen 20 und 80% bezogen auf die Masse der Maskierungsstruktur enthält und die Dicke (t) der Maskierungsstruktur (13) zwischen 2 und 30 Mikrometern liegt.
- Sicherheitselement nach dem vorhergehenden Anspruch, wobei das Element (10) zwei gegenüberliegende Hauptseiten umfasst und die Maskierungsstruktur die Sichtbarkeit von wenigstens einer der Seiten verringert.
- Sicherheitselement nach einem der vorhergehenden Ansprüche, wobei die wenigstens zwei nanoskaligen Füllstoffe eine Durchschnittsgröße D50 haben, die zwischen 50 und 200 nm liegt.
- Sicherheitselement nach einem der vorhergehenden Ansprüche, wobei die mindestens zwei nanoskaligen Füllstoffe einen Brechnungsindex haben, der sich um wenigstens 0,8 unterscheidet.
- Sicherheitselement nach einem der vorhergehenden Ansprüche, wobei einer der mindestens zwei nanoskaligen Füllstoffe pyrogene kolloidale Kieselsäure enthält, wobei diese kolloidale Kieselsäure vorzugsweise mit einem Massenanteil zwischen 30 und 70%, besonders bevorzugt zwischen 40 und 60% bezogen auf die Masse der Maskierungsstruktur enthalten ist.
- Sicherheitselement nach einem der vorhergehenden Ansprüche, wobei die mindestens zwei nanoskaligen Füllstoffe Titandioxid, insbesondere vom Anatas-Typ enthält, wobei das Titandioxid vorzugsweise mit einem Masseanteil enthalten ist, der zwischen 1 und 40%, vorzugsweise zwischen 2 und 30%, besonders bevorzugt zwischen 3 und 15% bezogen auf die Gesamtmasse der zumindest zwei nanoskaligen Füllstoffe enthalten ist.
- Sicherheitselement nach einem der vorhergehenden Ansprüche, wobei die Dicke (t) der Maskierungsstruktur (13) zwischen 5 und 20 Mikrometern, weiter bevorzugt zwischen 8 und 13 Mikrometern liegt.
- Sicherheitselement nach einem der vorhergehenden Ansprüche, wobei nanoskaligen Füllstoffe in einem Bindemittel in einer Schicht der Maskierungsstruktur dispergiert sind.
- Sicherheitselement nach einem der vorhergehenden Ansprüche, umfassend eine Sicherheitsstruktur (12), die zumindest teilweise, vorzugsweise vollständig der Maskierungsstruktur (13) überlagert ist, insbesondere eine Sicherheitsstruktur (12) mit einer lichtundurchlässigen Schicht (12a) und zumindest einer Öffnung (12b) in der lichtundurchlässigen Schicht, vorzugsweise Öffnungen in Form von Negativschrift.
- Sicherheitselement nach einem der vorhergehenden Ansprüchen mit einem Träger (11), insbesondere aus einem thermoplastischen Material, vorzugsweise aus PET oder Polyester.
- Sicherheitselement nach den Ansprüchen 9 und 10, wobei die Sicherheitsstruktur (12) auf der einen Seite des Trägers (11) angeordnet ist und die Maskierungsstruktur (13) auf der anderen Seite.
- Sicherheitselement nach den Ansprüchen 9 und 10, wobei die Sicherheitsstruktur (12) und die Maskierungsstruktur (13) auf der gleichen Seite des Trägers (11) angeordnet sind.
- Sicherheitselement nach einem der vorhergehenden Ansprüche, wobei die Maskierungsstruktur ferner ein mehrschichtiges Interferenzpigment enthält, umfassend vorzugsweise eine mineralische Basis, die mit mindestens einer Schicht mit einem anderen Brechungsindex als demjenigen der Basis beschichtet ist, insbesondere einer plättchenförmigen Basis, vorzugsweise aus Glimmer oder Glas, wobei der Massenanteil des mehrschichtigen Interferenzpigments bezogen auf die Masse der Maskierungsstruktur zwischen 1 und 40%, vorzugsweise zwischen 2 und 30%, weiter bevorzugt zwischen 5 und 15% ausmacht, wobei die Größe des mehrschichtigen Interferenzpigments vorzugsweise zwischen 2 und 150 Mikrometern, bevorzugter zwischen 5 und 40 Mikrometern und am bevorzugtesten zwischen 5 und 25 Mikrometern liegt.
- Sicherheitselement nach einem der vorhergehenden Ansprüche, ferner umfassend ein lumineszierendes Mittel, insbesondere eingemischt in eine Schicht der Maskierungsstruktur.
- Sicherheitselement nach einem der vorhergehenden Ansprüche, umfassend einen heißsiegelbaren Klebstoff (14), insbesondere in Kontakt mit der Maskierungsstruktur (13), wobei der Klebstoff ein lumineszierendes, insbesondere fluoreszierendes Mittel enthält.
- Sicherheitselement nach einem der vorhergehenden Ansprüche, umfassend ein lumineszierendes Mittel, insbesondere in einer separaten Schicht der Maskierungsstruktur (13), vorzugsweise in einer Schicht, die bezogen auf der Träger gemäß Anspruch 10 der Sicherheitsstruktur gemäß Anspruch 9 gegenüberliegt.
- Dokument mit einem Sicherheitselement (10) nach einem der vorhergehenden Ansprüche, wobei das Sicherheitselement in der Form eines in ein Fenster oder in eine Masse eingebetteten Fadens ausgestaltet ist.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1353252A FR3004471B1 (fr) | 2013-04-11 | 2013-04-11 | Element de securite comportant une structure de masquage contenant un melange de charges nanometriques. |
PCT/IB2014/060625 WO2014167527A1 (fr) | 2013-04-11 | 2014-04-10 | Element de securite comportant une structure de masquage contenant un melange de charges nanometriques |
Publications (2)
Publication Number | Publication Date |
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EP2984227A1 EP2984227A1 (de) | 2016-02-17 |
EP2984227B1 true EP2984227B1 (de) | 2018-02-14 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP14721533.9A Active EP2984227B1 (de) | 2013-04-11 | 2014-04-10 | Sicherheitselement mit einer maskierungsstruktur mit einer mischung aus nanometrischen füllstoffen |
Country Status (5)
Country | Link |
---|---|
US (1) | US10328738B2 (de) |
EP (1) | EP2984227B1 (de) |
CN (1) | CN105308240B (de) |
FR (1) | FR3004471B1 (de) |
WO (1) | WO2014167527A1 (de) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3004470B1 (fr) * | 2013-04-11 | 2015-05-22 | Arjowiggins Security | Element de securite comportant un pigment interferentiel et une charge nanometrique. |
FR3004471B1 (fr) | 2013-04-11 | 2015-10-23 | Arjowiggins Security | Element de securite comportant une structure de masquage contenant un melange de charges nanometriques. |
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FR3004470B1 (fr) | 2013-04-11 | 2015-05-22 | Arjowiggins Security | Element de securite comportant un pigment interferentiel et une charge nanometrique. |
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2014
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- 2014-04-10 US US14/783,868 patent/US10328738B2/en active Active
- 2014-04-10 EP EP14721533.9A patent/EP2984227B1/de active Active
- 2014-04-10 CN CN201480033261.1A patent/CN105308240B/zh active Active
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Also Published As
Publication number | Publication date |
---|---|
EP2984227A1 (de) | 2016-02-17 |
CN105308240A (zh) | 2016-02-03 |
FR3004471B1 (fr) | 2015-10-23 |
US20160059611A1 (en) | 2016-03-03 |
FR3004471A1 (fr) | 2014-10-17 |
CN105308240B (zh) | 2019-04-05 |
US10328738B2 (en) | 2019-06-25 |
WO2014167527A1 (fr) | 2014-10-16 |
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