EP2984141A1

EP2984141A1 - Novel road markings for assisting the perception of the surroundings of vehicles

Info

Publication number: EP2984141A1
Application number: EP14710247.9A
Authority: EP
Inventors: Guido Protzmann; Jörn KIWITT; Dominik Kiefer; Günter Schmitt; Marita Kaufmann; Michael OLAPOJU
Original assignee: Evonik Roehm GmbH
Current assignee: Roehm GmbH Darmstadt
Priority date: 2013-04-08
Filing date: 2014-03-13
Publication date: 2016-02-17
Also published as: JP2016522338A; CN105143358A; CN105143358B; DE102013206116A1; US20160017151A1; KR102296019B1; KR20150140284A; WO2014166693A1; HK1213277A1; JP6320513B2

Abstract

The invention relates to a novel concept for marking traffic lanes, particularly roads. These novel markings have applicability and lifespans that are comparable to the prior art. The markings also correspond, with regard to night visibility, length of time before they can be driven over and surface quality, to properties comparable to the prior art. However, in addition the markings of the present invention help contribute to the support of modern driver assistance systems and autonomous driving. The invention particularly relates to road markings that, building on established systems, are provided with an additional reflection capacity for electromagnetic radiation, particularly for microwave and/or infrared radiation.

Description

New road markings to support the

Environment perception of vehicles

Field of the invention

The present invention comprises a novel concept for marking lanes, especially roads. In the process, these new markings have comparable applicability and lifetime compared to the prior art. The markings are also comparable in terms of night visibility, time to reusability and surface finish

Properties of the prior art. In addition, however, the markings of the present invention aid in assisting driver assistance systems and autonomous vehicles. For this purpose, the present invention relates in particular road markings, which are based on established systems with additional reflectivity for electromagnetic radiation, in particular for microwaves and / or infrared radiation equipped.

State of the art

Driver Assistance Systems (FAS) have long been in the focus of

Automotive development. The systems increase ride comfort and the

Road safety. Current systems are for example the Abstandstempomat, the emergency brake assistant, the parking aid and the lane change assistant. to

Environment perception are mostly radar, infrared, lidar, camera and / or ultrasonic sensors used. Many driver assistance systems, such as lane departure warning systems, require reliable road information such as lane width, number of lanes and route. In addition, the vehicle position must be known relative to the roadway. The reliable determination of this data is particularly important in view of the vision of the future "autonomous driving" of particular importance.

The information regarding the static vehicle environment may be in the form of a stored map. All that needs to be done is a positioning within the map. The localization can be performed, for example, with a Global Navigation Satellite System (GNSS) such as GPS or Galileo. The disadvantage here is that the localization accuracy is not sufficient to guarantee a reliable operation of driver assistance systems and autonomous vehicles. More accurate localization can be achieved with a local, radio or optical localization system along the roadway. The construction of this infrastructure is however complex and

expensive.

In the method with a stored map is additionally disadvantageous that the card must correspond exactly to reality. This can not be guaranteed by temporary disruptions or changes in the course of the road such as construction sites.

For these reasons, it is essential for FAS and autonomous vehicles, precise information regarding the lane / lane and the relative relative

Determine your own position while driving reliably.

Currently, this task is almost exclusively solved with video cameras, which are usually mounted behind the windshield on the rearview mirror. With the help of digital image processing, the lanes are detected in the video image. The lanes are detected primarily on the basis of the lane markings. However, the systems can not reliably detect the lanes in all situations. Problems occur in construction sites when temporary

Road markings are used. The optical measuring method reaches its limits even in adverse weather conditions such as fog, rain and snow. Difficulties also occur when the sun is shallow and therefore dazzling. In the absence of contrast between road markings and

Road surface, as well as eroded or nonexistent

Road markings, the lane can sometimes not be recognized.

In addition, tar joints on the roadway can lead to misinterpretations in the recognition of lanes.

For the reasons mentioned, there is a need that

Road markings of driver assistance systems and autonomous vehicles can be reliably detected. Road markings which are adapted to the requirements of automotive systems for environmental perception have not yet been described in the prior art.

There are different types of road markings.

Roadway marking materials are currently used in systems such as solvent-based paints, water-based paints, thermoplastic paints, reaction resin or cold plastic paints, as well as prefabricated adhesive tapes. The latter have the disadvantage that they are complex to produce and apply. Also, in view of a desirable longevity of the mark, there are only limited degrees of freedom in the design of the mark, e.g. with glass beads.

Solvent based paints are a very old state of the art and have the particular disadvantage that they are not covered with glass beads, for example

Improvement of the reflection of light can be equipped. Marking films, in particular those having glass beads on the surface for improving the night visibility, are described, for example, in WO 99/04099 and WO 99/04097. These documents also disclose a corresponding process for producing the marking films and for equipping these films with glass beads.

Reaction resin based road markings can be found for example in patent applications EP 2 054 453, EP 2 454 331, EP 2 528 967, WO 2012/100879 and WO 2012/146438.

Aqueous marking systems are described for example in EP 2 077 305, EP 1 162 237 and US 4,487,964.

task

Object of the present invention is to provide a new concept for road marking, which makes a contribution to the environment perception of vehicles, and in particular reflects microwave and / or infrared radiation particularly effective.

Object of the present invention is also that these

Road marking is easy to apply and has a long life.

A particular task is that these novel road markings are made available by modification of established systems and thus can be laid or applied with existing methods, without additional conversion of the corresponding machines.

Other not explicitly mentioned tasks arise from the

Overall context of the following description, claims and examples.

solution

The tasks are solved by a novel, radiant reflecting

Road marking, which contains spherical metal particles and / or cylindrical metal particles, each of particular dimensions. The spherical metal particles used according to the invention in this case have a diameter d between χ ^* 0.7 ^* λ / π and χ ^* 1, 3 ^* λ / π, preferably between χ ^* 0.9 ^* λ / π and χ ^* 1, 1 ^* λ / π on. Λ is the wavelength of the radiation to be reflected. X is an integer between 1 and 6, preferably between 1 and 4 and more preferably around 1. According to the invention, "spherical" in the ideal case means that the particles are almost perfect spheres, but according to the invention, spherically they are not perfect but also spherical Such particles have a maximum ratio of 1, 5, preferably 1, 3 between the thickest diameter to be measured and the thinnest diameter of the particle to be measured, whereby these diameters always pass through the geometric center of gravity of the particle Alternatively or additionally, a second type of metal particles, which are cylindrical metal particles, can be used

Reflection behavior also referred to as dipole antennas. These metal particles have a length-to-width ratio between 2 and 100, preferably between 4 and 50 and more preferably between 5 and 20. Furthermore, these particles have a length I between y ^* A / 1, 8 and y ^* A / 3, preferably between y ^* A / 1, 9 and y ^* A / 2.2. In this case, y is an integer between 1 and 20, preferably between 1 and 4 and particularly preferably around 1. The cylindrical metal particles in this case also comprise metal particles which consist of two or more, described cylindrical

Metal particles exist. In order to obtain optimum resonance to the electromagnetic radiation, the orientation of the small dipole antennas in or on the pavement marking should be adapted to the polarization of the radar waves. This means that these particles are ideally placed perpendicular to the direction of travel on the lane marking. As a result, the mark is no longer out of all

Detectable directions. The latter can even be an advantage depending on the application.

For spherical particles, however, an alignment is not necessary.

In automotive driver assistance systems in Europe radar sensors are used with in particular the following frequency bands: Between 24 and 24.25 GHz, between 21, 65 and 26.65 GHz, between 76 and 77 GHz, between 77 and 81 GHz and in the future most likely at about 122 GHz. Particularly interesting are the widely used frequency bands between 76 and 77 GHz and between 77 and 81 GHz.

With the frequency band at approx. 122 GHz a higher angular resolution is achieved, however in the far range a stronger damping is achieved. Therefore, this frequency band is expected to be used primarily for near-field detection.

In the US and Japan, automotive radar sensors also use bands between 46.7 and 46.9 GHz and between 60 and 61 GHz. In particular, the metal particles in the inventive

Road markings for a to be reflected electromagnetic radiation with a frequency between 20 and 130 GHz, preferably selected between 76 and 81 GHz. The particle size is calculated according to the above-mentioned information from the wavelength, which results directly from the frequency of the electromagnetic radiation used. Where λ = c / f, with f equal to the frequency and c equal to the propagation velocity at which it is in the case of

electromagnetic radiation is about the speed of light. Thus, for example, the following exemplary particle sizes result for spherical metal particles with a factor x = 1:

a) For the frequency band between 24 and 24.25 GHz and thus a mean frequency f = 24.125 GHz or λ = 12.4 mm results in an ideal

Diameter d of 3.95 mm.

b) For the frequency band between 76 and 77 GHz and thus a mean frequency f = 76.5 GHz or λ = 3.92 mm, the ideal diameter d is 1.25 mm.

c) For the frequency band between 77 and 81 GHz and thus a mean frequency f = 79 GHz or λ = 3.8 mm results in an ideal diameter d of 1, 21 mm.

d) For f = 122 GHz or λ = 2.46 mm an ideal diameter d of 0.78 mm results.

Thus, for example, the following exemplary particle lengths result for cylindrical metal particles with a factor y = 1:

a) For the frequency band between 24 and 24.25 GHz and thus a mean frequency f = 24.125 GHz or λ = 12.4 mm results in an ideal length I of 6.20 mm.

b) For the frequency band between 76 and 77 GHz and thus a mean frequency f = 76.5 GHz or λ = 3.92 mm results in an ideal length I of 1, 96 mm.

c) For the frequency band between 77 and 81 GHz and thus a mean frequency f = 79 GHz or λ = 3.8 mm results in an ideal length I of 1, 90 mm.

d) For f = 122 GHz or λ = 2.46 mm results in an ideal length I of 1, 23 mm.

These metal particles reflect electromagnetic radiation, which is emitted by a corresponding device on a vehicle, for example. At the same time, the vehicle may be equipped with a corresponding detector which detects the reflected radiation. In this way, information for controlling the vehicle directly on the road surface, at the

Road marking be read.

The metal particles are particularly preferably particles which consist wholly or partly of aluminum, iron, zinc, magnesium or an alloy which contains predominantly aluminum, iron or zinc. Particularly preferred are particles which consist wholly or partly of aluminum or iron. But it can also be combined with different materials. This can e.g. such that more than one type of metal particle is used.

In the simplest embodiment of the invention, it is solid

Metal particles, i. Particles made entirely of metal. However, the invention is not limited to such particles. So also metallic hollow balls can be used. Furthermore, the surface of the particle may be coated with the metal, while below it may be another material, e.g. Glass or a plastic. In a particular embodiment of the invention is a metal coated with glass, PMMA or polycarbonate, particularly preferably in spherical form. Particles of this last embodiment contribute not only to the reflection of said electromagnetic radiation, ie in particular of microwaves and / or infrared radiation, but also reflect visible light very well. As a result, when the particles are on the surface of the road marking, in addition, the reflection of visible light can be ensured. The latter is particularly important at night and according to the state of the art has so far been achieved predominantly by pure glass beads.

The particles may simply be embedded in the matrix material of the road marking. Even if the metal particles are completely enclosed by this matrix material, reflection of eg microwaves is still possible. Alternatively, the metal particles are on the surface of the road marking. In particular, in such an embodiment - but also in a

Full embedding - it is preferred if additional adhesion promoters are used to improve the adhesion of the metal particles to the material of the pavement marking.

There are two alternative embodiments for this. In the first one are the

Provide metal particles on the surface with a bonding agent. In the second embodiment, the matrix material of the pavement marker includes the

Adhesion promoters.

As a primer, a number of substances come into question. The selection of the adhesion promoter results for the person skilled in each specific case in particular from the choice of the matrix material and the metal used. Examples of such adhesion promoters are silanes, hydroxy esters, amino esters, urethanes, isocyanates and / or acids copolymerizable with (meth) acrylates. The silanes may be, for example, silanized - e.g. oxidic - glass or

Trade metal surface. But it can (meth) acrylate, as sold for example by the company Evonik Industries AG under the name Dynasylan ^® MEMO, for example, an alkoxy and / or Hydroxysilylalkyl be used. An example of a hydroxyester is hydroxyethyl methacrylate. Examples of a copolymerizable acid are itaconic acid, maleic acid, methacrylic acid,

Acrylic acid, β-carboxyethyl acrylate or the corresponding anhydrides. One

Aminoester is e.g. N-dimethylaminopropylmethacrylamide.

The amount of metal particles used can be chosen to be relatively variable. The limiting factor with respect to the minimum quantity is sufficient detection by a sensor. A sufficient minimum amount can already be achieved with 0.1 area% coverage of the marking by metal particles.

However, especially in view of the longevity of reflectivity, larger amounts are preferable. An orientation can be made on the basis of the commonly used amount of glass beads for the expert. In the process disturb similar quantities of glass beads, which are additionally scattered on the mark, not. Nevertheless, all in all, of course, care must be taken to ensure that the total area of glass beads and metal particles that are placed on the surface is so smaller than the area of the marking that the majority of the particles and beads get in contact with the surface of the material. If the metal particles are incorporated into the matrix in such a way that they are completely enclosed by the matrix, care must be taken that the cohesion of the matrix is not disturbed by too large a quantity of particles.

In the case of adhesive films, the number of metal balls with respect to the lower limit is analogous. With respect to the upper limit, a covering layer of the metal particles can be formed quite well.

The inventive solution of a metal particle-containing road marking can be based on various established road marking systems. Crucial for the execution is only that a road marking is selected, in which a sufficient adhesion for the metal particles is ensured. Basically, such road markings are suitable, can be incorporated into the glass beads. Preferably, the road markings that can be used are structural markings, in particular cold plastics, adhesive tapes or adhesive tapes

Watercolors. The latter in particular in the execution as a structural mark.

If the road marking is a prefabricated adhesive tape, the metal particles can be added analogously to the glass beads during the manufacture of the adhesive tape. Thus, in WO 99/04099 a method

described in which the adhesive tape is coated with a bonding agent layer or with the melt of a thermoplastic and then sprinkled in the same operation glass beads on this still adhering layer. The thermoplastic can also be applied in structures or local elevations, so that a local accumulation of the beads or a pattern of the same is achieved. This method is also simply analogous to metal particles

transferable. Alternatively, an adhesive layer can be applied to the top of the adhesive tape to which the metal particles - optionally together with the

Glass beads - are sprinkled and then cured and / or sealed with another layer of paint or foil. Furthermore, it is also possible the metal particles in the production of a multilayer film at a

Coextrusion or lamination between the two layers. Furthermore, it is possible, especially with very small metal particles, to extrude the metal particles directly in the production of adhesive tape. An equally good alternative to adhesive tapes

Structure markings that are applied directly to the road surface, there are two major variants. For one thing, it can be at the

Road marking to act around a water color. Alternatively, it can be a cold plastic. The latter is obtained by applying and curing a mostly filled reaction resin. Theoretically, solvent-based systems are also conceivable. However, these are rather insignificant in the area of structural markings.

Regardless of which structural marking technology is involved, the metal particles can be incorporated into the marker in a similar manner. Both systems are usually two-component systems whose components are mixed together shortly before application. In this case, the metal particles can be stirred in the same process step. Alternatively, the metal particles in one of

Components should be included beforehand. With this procedure you get

Road markings in which the metal particles are predominantly trapped in the matrix.

However, it is also possible during or immediately after the application of the aqueous varnish or the cold plastic to sprinkle the metal particles. This gives a road marking, the metal particles predominantly on the surface

exhibit. In the case that glass beads are applied, this can be done in one operation in the form of a mixture or directly one behind the other. Appropriate application technologies are known to those skilled in the art for the application of glass beads.

As already stated, the road marking on the surface may additionally comprise glass beads. This is independent of whether the metal particles are contained in the matrix or are also on the surface. If the

Metal particles on the surface, they additionally contribute to the light reflection. If the metal particles are contained in the matrix, this has the advantage that they are slowed down on the road and thus are a little more durable. The above embodiment of transparent with glass, PMMA or

Polycarbonate-coated metal particles are very preferably applied to the surface.

Glass beads are preferably used in formulations for pavement markings and surface markers as reflectants. The used

Commercially available glass beads have a diameter of 10 μιτι to 2000 μιτι, preferably 50 μιτι to 800 μιτι. The glass beads can be provided with a primer for better processing and adhesion. Preferably, the glass beads can be silanized.

In the following, the compositions of suitable

Cold sculptures shown. This is intended to describe only one possible embodiment in detail, without thereby limiting the present invention to such systems. As already stated, equipment is the

Road markings based on e.g. Adhesive tapes or aqueous systems with metal particles in analogy to the equipment with glass beads for the expert easy to implement.

Such a cold plastic is usually made from a 2K reaction resin. In this case, a component contains 1, 0 to 5.0% by weight of an initiator, preferably a peroxide or an azo initiator, particularly preferably dilauroyl peroxide and / or dibenzoyl peroxide. The other component contains 0.5 to 5.0% by weight of one Accelerator, preferably a tertiary, aromatic substituted amine. In this case, one of the two components may well only from the / mentioned

Connections exist. It is also possible that both components are otherwise identically composed, or only one of the two components contains the fillers or the pigments.

The two components of the reaction resin and thus the cold plastic formed therefrom preferably have the following additional ingredients in total:

0.1% to 18% by weight crosslinker, preferably di-, tri- or polyfunctional (meth) acrylates,

From 2% by weight to 50% by weight of monomers, preferably (meth) acrylates and / or styrene,

0% to 12% by weight of urethane (meth) acrylates,

From 0.5% to 30% by weight of prepolymers, preferably polymethacrylates and / or polyesters,

0 wt% to 15 wt% core-shell particles, preferably on

Poly (meth) acrylate,

7 wt% to 15 wt% of an inorganic pigment is preferred

titanium dioxide,

From 30% to 60% by weight of mineral fillers and

optionally further auxiliaries.

The formulation poly (meth) acrylates includes both polymethacrylates and polyacrylates as well as copolymers or mixtures of both. The formulation (meth) acrylates accordingly includes methacrylates, acrylates or mixtures of both.

The composition of particularly suitable cold plastics or the reaction resins based on these cold plastics can be read in particular in WO 2012/100879. There you will also find information on the other auxiliaries. However, the core shell listed in WO 2012/100879 are Particle is not an essential feature for practicing the present invention.

Instead, in particular, the proportion of prepolymers can be higher.

The road markings produced with this cold plastic show a particularly good Uberrollbarkeit. Under the term Uberrollbarkeit or the synonymously used term Wiederbefahrbarkeit becomes a burden of

Pavement marking, e.g. in the form of rolling over by vehicles, understood. The time to reach a rollover is the time between the application of the lane marking to the time at which none

Changes in the form of abrasion, a loss of liability to

Road surface or to the embedded metal particles and optional glass beads or deformation of the mark can be detected more. The dimensional and adhesion stability is measured in accordance with DIN EN 1542 99 in accordance with DAfStb-RiLi 01.

With regard to the application technology, the systems according to the invention can be used flexibly. The reaction resins or cold plastics according to the invention may e.g. be applied by spraying, by casting or by extrusion or manually by means of a trowel, a roller or a doctor blade.

In particular, a process for the preparation of an inventive

Road marking Part of the present invention, which is characterized by the following

Features: First, if necessary, the components of the 2K system are mixed. This mixture is applied to the road surface and during or immediately after application of the cold plastic on the road surface the metal particles and optionally glass beads are added. This is preferably done by sprinkling, more preferably in accelerated form.

When mixing the components, care must be taken that after mixing the hardener components, ie the initiators and the accelerator, only a limited open time, eg from 2 to 40 minutes, remains for application. Mixing during processing is, for example, in modern marking machines which precede one of the application nozzles

Mixing chamber available, possible.

Blending of the hardener after application may e.g. by subsequent application with two or more nozzles or by applying

Metal particles and / or glass beads, which are coated with hardener. Alternatively, a primer - containing the hardener component - can be pre-sprayed before the cold plastic or cold spray plastic is applied. The moderns

Marking machines usually have one or two additional nozzles with which the metal particles and optionally the glass beads are then sprayed on.

The reaction resins according to the invention or the cold plastics produced therefrom are preferably used for the production of long-lasting pavement markings. Likewise, the systems, in particular in the form of a

Adhesive tape for temporary markings, e.g. in a construction site area, are used. In addition, the use of the

Coating of bicycle paths conceivable. In a particular embodiment of the present invention, the road markings according to the invention are applied in such a way that only areas of the road marking are provided with the metal particles. Thus it is possible in particular by the equipment of areas of the

Road markings, the road markings as such with readable

Information be provided. For example, information in the form of a kind of bar code can be deposited on the road surface. These are read out by the vehicle equipped with a corresponding sensor. In this way, for example, on danger spots or

Speed limits. It is also possible on this basis to support a traffic control system. The examples given below are given for a better illustration of the present invention, but are not intended to limit the invention to the features disclosed herein.

Examples

The following examples are intended as a guide to the practice of the present invention. All examples show the same good properties as road marking as the underlying formulations without metal particles. In addition, the formulations of the examples show good reflection of

Microwave radiation with a frequency between 20 and 130 GHz. To produce the examples, aluminum particles from Eisenwerk Würth GmbH with the designations GRANAL S-80 and GRANAL S-100 were used. Such aluminum particles are sold for use as blasting agents. The shape of the particles is roundish with an uneven surface.

The particles have the following sizes:

GRANAL S-80: diameter between 0.80 and 1.20 mm

GRANAL S-100: Diameter between 1, 00 and 1, 80 mm

The glass beads used on the surface are silanized glass beads of the type Vialux 20 from Sovitec. These glass beads have a diameter in a range between 600 and 1400 μιτι.

The application of the metal particles and the glass beads (if present) on the surface of the cold plastic takes place by means of a pressure gun. Alternatively, a simple sprinkling would also be possible. The latter would lead to diminished yet sufficient liability.

The formulation of the cold plastic used is based on the composition disclosed in WO 2012/100879 as Example 2. There especially the

The composition of the core-shell particles can be read. Example 1 :

0.05 parts of Topanol-O, 13 parts of DEGACRYL® M 339, 9 parts of core-shell-shell particles and 0.5 part of paraffin are intimately mixed into 63 parts of methyl methacrylate and 5 parts of butyl diglycol methacrylate and heated to 63 ° C. with vigorous stirring all polymer components are dissolved or dispersed. For curing, 1 part of benzoyl peroxide (50% by weight formulation in dioctyl phthalate) and 2 parts of N, N-diisopropoxytoluidine are added and stirred for one minute at room temperature (21 ° C).

For curing, the mass was poured onto a metal sheet. Within one minute after pouring, the surface is sprinkled with GRANAL S-100 particles. In this case, an amount is used which corresponds to 500 g of particles / in ² . After curing, the production of test specimens according to DIN 50125 takes place. Pot life: 14 min; Curing time: 30 min; Flow time (4 mm): 252 sec

Example 2:

The operating principle of a radar sensor is a microwave

to send out, which is reflected on objects. This returning radar wave is subsequently detected in the sensor. The distance to the object is determined by the time difference between transmission and reception of the signal.

Usually, the radar reflectivity of objects with the

Radar cross-section RCS quantified. This is especially useful if it is a point-shaped object.

Point-shaped objects reflect the incoming radar wave, so that when

Receiver a single echo is measurable. However, if the object has an in

Propagation direction elongated reflection surface, the returning echo of the radar waves at the receiver is extended in time. Exactly this phenomenon is in the case of the lane marking. Therefore, it is no longer possible to reasonably determine an RCS (σ) of the lane marking. Instead, one RCS per unit length of lane marking is determined (Δσ / ΔΙ). Here, σ is the RCS and I is the length of the lane marking in the direction of propagation of the incoming radar wave. A measurement is then carried out to determine the quantitative radar reflectivity of the road mark Δσ / ΔΙ. This will be a pattern of

Road marking produced as described in Example 1. Instead of a metal sheet, a P L EX I G LAS® P aet with a width of 0.20 m and a length of 2 m is used as the substrate. The applied thereon mark has the width w and also the length 2 m.

This test mark will be on level ground and in an EM wave

installed absorbent environment. A radar sensor operating in the frequency band 76 to 77 GHz is installed at a horizontal distance l _min from the mark. The radar sensor is oriented so that the main radar lobe is aligned with the longitudinal direction of the lane marker. The radar sensor has a height of h _sen sor above the plane in which the lane marking is located.

For this experimental set-up, the target size to be measured can be calculated theoretically:

Δσ, h

w - μ · α sensor

Vh s ² ensor

Here μ is the gain factor of the reflection on the aluminum particles, which is caused by the Mie scattering in comparison to the optical reflection. The attenuation factor d takes into account that the surface of the

Marking is not entirely occupied by aluminum particles. If only 10% of the marking surface is occupied by aluminum particles, then d = 0.1. Of the

Attenuation factor d can theoretically be calculated for spherical particles:

, 3 - m / A

a =

4 · p - r

25 m / A is the mass of particles per area distributed on the marking. In example 1, this is 500 g / m ² . p is the density of the particles. For the aluminum particles used p = 2700 kg / m ³ , r is the radius of the spherical particles. For GRANAL S-100 a mean radius of r = 0.7 mm is assumed. With these parameters one obtains a theoretical attenuation factor d = 0.198 = 20%.

For the theoretical Δσ / ΔΙ results with the parameters

I = 2 m hsensor ^- 0.5 ΓΓΙ w = 0.15 m μ = 3 (as mean value, since the ball sizes do not correspond only to the maximum of the Mie scattering at μ = 3.75) one RCS per length element of

The practical test measured a Δσ / ΔΙ = 0.0314 m. The greater practical value can be explained by the fact that the radar lobe is not perpendicular to the marking plane. Due to the oblique viewing angle of the radar sensor on the marking, the theoretically calculated d is significantly larger and thus also the Δσ / ΔΙ.

Example 3:

The label is prepared as in Example 1. The measurement is carried out as in Example 2, except that instead of a radar sensor with 76/77 GHz, a radar sensor with the frequency band of 77 to 81 GHz is used. The result obtained is Δσ / ΔΙ = 0.0338 m. The relatively small change in frequency also results in a relatively small change in radar reflectivity. Example 4:

Same as example 1, except that the material GRANAL S-80 is used instead of GRANAL S-100 particles. To measure the radar reflectivity Δσ / ΔΙ, the procedure is as in Example 2. The result of the measurement is Ao / AI = 0.0156 m. The significantly lower radar reflectivity can be explained by the fact that the particle diameter no longer corresponds to the optimum of d = 1, 25 mm.

Example 5:

As in Example 1, except that instead of GRANAL S-100 as a material cylindrical aluminum particles are used. The length of the cylinders is between 1, 7 and 2.2 mm. The thickness of the particles is 0.2 mm. 100 g of particles per m ^{2 are} scattered on the mark. The measurement is carried out as in Example 2. The result of the measurement is Δσ / ΔΙ = 0,0121 m.

Example 6:

As in Example 1, except that additionally and from a prefabricated mixture with the GRANAL S-100 particles, glass beads are sprinkled in an amount corresponding to 280 g / m ² .

Example 7:

As in Example 3, except that the GRANAL S-100 particles are stirred into the composition together with the core-shell particles and after the

Pouring is sprinkled only with glass beads.

Comparative example

As Example 6, but without aluminum particles.

Claims

1 . Radiation-reflecting road marking, characterized in that the road marking spherical metal particles with a diameter d between χ ^* 0.7 ^* λ / π and x ^* 1, 3 ^* λ / π and / or cylindrical metal particles with a length-width ratio between 2 and 100 and a length I between y ^* A / 1, 8 and y ^* A / 3, where λ is the

Wavelength of the radiation to be reflected, where x is an integer between 1 and 6 and y is an integer between 1 and 20.

2. Road marking according to claim 1, characterized in that the metal particles are particles which consist wholly or partly of aluminum, iron, magnesium, zinc or an alloy containing predominantly aluminum, iron, magnesium or zinc.

3. Road marking according to claim 1 or 2, characterized in that the metal particles are made entirely of the metal, the surface is coated with the metal or it is a glass, PMMA or

Polycarbonate coated metal acts.

4. Road marking according to at least one of claims 1 to 3,

characterized in that the cylindrical metal particles a

Length-to-width ratio between 5 and 20 and y is an integer between 1 and 4

5. Road marking according to at least one of claims 1 to 4,

characterized in that the matrix material of the road marking contains an adhesion promoter and / or the metal particles are provided on the surface with an adhesion promoter, and that the adhesion promoter is at least one adhesion promoter selected from the group of silanes, Hydroxy esters, amino esters, urethanes, isocyanates and / or with

(Meth) acrylates copolymerizable acids.

, Road marking according to at least one of claims 1 to 5, characterized in that the road marking is a prefabricated adhesive tape or a water color.

, Road marking according to at least one of claims 1 to 5, characterized in that it is a cold plastic in the road marking.

, Road marking according to at least one of claims 1 to 7, characterized in that the road marking on the surface additionally comprises glass beads.

, Road marking according to at least one of claims 1 to 8, characterized in that the metal particles are located on the surface of the road marking.

0. Road marking according to claim 7, characterized in that the cold plastic was prepared from a 2K reaction resin, wherein one component 1, 0 to 5.0% by weight of an initiator, preferably dilauroyl peroxide and / or dibenzoyl peroxide, and the other component 0.5 contains up to 5.0% by weight of an accelerator, preferably a tertiary, aromatically substituted amine, and in that the reaction resin has in total the following further ingredients:

0.1% to 18% by weight crosslinker,

From 2% to 50% by weight of monomers,

0% to 12% by weight of urethane (meth) acrylates,

0.5% to 30% by weight of prepolymers,

0% to 15% by weight of core-shell particles, 7% to 15% by weight of an inorganic pigment, preferably titanium dioxide,

From 30% to 60% by weight of mineral fillers and

optionally further auxiliaries.

1 1. Road marking according to at least one of claims 1 to 10, characterized in that the frequency of the electromagnetic radiation to be reflected is between 20 and 130 GHz.

12 road marking according to claim 1 1, characterized in that the frequency is between 76 and 81 GHz.

13. Road marking according to at least one of claims 1 to 12, characterized in that only areas of the road marking are provided with the metal particles.

14. Road marking according to claim 13, characterized in that it is provided with readable information by equipping areas of the lane marking.

15. A method for producing a pavement marking according to claim 7 or 9, characterized in that, if necessary, 2K systems are mixed, the mixture is applied to the road surface and during or directly after the application of the cold plastic on the

Road surface, the metal particles and optionally glass beads are added.