EP2934229A1 - Verfahren zur herstellung einer mundpflegevorrichtung - Google Patents
Verfahren zur herstellung einer mundpflegevorrichtungInfo
- Publication number
- EP2934229A1 EP2934229A1 EP12810010.4A EP12810010A EP2934229A1 EP 2934229 A1 EP2934229 A1 EP 2934229A1 EP 12810010 A EP12810010 A EP 12810010A EP 2934229 A1 EP2934229 A1 EP 2934229A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cleaning elements
- tooth cleaning
- cavity
- wall
- head
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 238000004140 cleaning Methods 0.000 claims abstract description 263
- 238000000034 method Methods 0.000 claims abstract description 72
- 210000004872 soft tissue Anatomy 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 16
- 239000012528 membrane Substances 0.000 claims description 8
- 239000000155 melt Substances 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- 230000001419 dependent effect Effects 0.000 claims 2
- 210000003128 head Anatomy 0.000 description 89
- 239000000606 toothpaste Substances 0.000 description 8
- 229940034610 toothpaste Drugs 0.000 description 8
- 230000008901 benefit Effects 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 239000000551 dentifrice Substances 0.000 description 5
- 210000000214 mouth Anatomy 0.000 description 5
- 229920002725 thermoplastic elastomer Polymers 0.000 description 5
- -1 polypropylene Polymers 0.000 description 4
- 239000004677 Nylon Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 229920001778 nylon Polymers 0.000 description 3
- 238000005498 polishing Methods 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 238000003466 welding Methods 0.000 description 3
- 238000010276 construction Methods 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 2
- 210000003813 thumb Anatomy 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229920005570 flexible polymer Polymers 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000008375 oral care agent Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000012858 resilient material Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000011145 styrene acrylonitrile resin Substances 0.000 description 1
- 238000010408 sweeping Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000009732 tufting Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46B—BRUSHES
- A46B9/00—Arrangements of the bristles in the brush body
- A46B9/02—Position or arrangement of bristles in relation to surface of the brush body, e.g. inclined, in rows, in groups
- A46B9/025—Position or arrangement of bristles in relation to surface of the brush body, e.g. inclined, in rows, in groups the bristles or the tufts being arranged in an angled position relative to each other
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46B—BRUSHES
- A46B3/00—Brushes characterised by the way in which the bristles are fixed or joined in or on the brush body or carrier
- A46B3/06—Brushes characterised by the way in which the bristles are fixed or joined in or on the brush body or carrier by welding together bristles made of metal wires or plastic materials
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46B—BRUSHES
- A46B9/00—Arrangements of the bristles in the brush body
- A46B9/02—Position or arrangement of bristles in relation to surface of the brush body, e.g. inclined, in rows, in groups
- A46B9/04—Arranged like in or for toothbrushes
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46B—BRUSHES
- A46B9/00—Arrangements of the bristles in the brush body
- A46B9/06—Arrangement of mixed bristles or tufts of bristles, e.g. wire, fibre, rubber
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46D—MANUFACTURE OF BRUSHES
- A46D1/00—Bristles; Selection of materials for bristles
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46B—BRUSHES
- A46B2200/00—Brushes characterized by their functions, uses or applications
- A46B2200/10—For human or animal care
- A46B2200/1066—Toothbrush for cleaning the teeth or dentures
Definitions
- Oral care implements are used by many people on a daily basis.
- Typical oral care implements comprise an elongate handle and a head connected to one end of the handle.
- the handle provides a structure by which a user grips and manipulates the oral care implement during use.
- the head typically comprises one or more elements designed to perform their intended function, such as tooth cleaning elements, soft tissue cleaning elements, and/ or oral care agents.
- Toothbrushes are oral care implements having one or more tooth cleaning elements, which are used to clean teeth by removing plaque and debris from surfaces of the teeth.
- Conventional toothbrushes are limited in their ability to retain dentifrice for cleaning teeth.
- the dentifrice typically slips through the tooth cleaning elements, such as tufts of bristles, and away from the contact zone of the cleaning elements with the teeth.
- the dentifrice often is spread around the mouth, rather than being concentrated on the contact zone. Therefore, the efficiency of the cleaning process is reduced.
- the present invention provides a method of manufacturing an oral care implement, the method comprising: providing a member and providing a group of non-parallel tooth cleaning elements that together define therebetween a conically- shaped cavity, wherein the tooth cleaning elements extend through a passage formed in the member so that respective first portions of the tooth cleaning elements are disposed on a first side of the member and respective second portions of the tooth cleaning elements are disposed on a second side of the member; and then fixing together the second portions of the tooth cleaning elements at the second side of the member.
- the providing comprises: inserting the tooth cleaning elements into the passage, so that each of the tooth cleaning elements has a first portion on the first side of the member and has a second portion on the second side of the member, and then arranging the tooth cleaning elements so that together the tooth cleaning elements define therebetween the conically-shaped cavity.
- the method comprises inserting a plurality of picks of the tooth cleaning elements into the passage.
- the inserting comprises disposing the plurality of picks in the passage at respective different orientations.
- the method comprises inserting the plurality of picks in the passage from respective different directions.
- the inserting comprises disposing at least some of the tooth cleaning elements in the passage at a different orientation to others of the tooth cleaning elements.
- the method comprises inserting all the tooth cleaning elements into the passage with all the tooth cleaning elements being substantially parallel to one another.
- the arranging comprises moving at least some of the tooth cleaning elements relative to others of the tooth cleaning elements to cause the tooth cleaning elements to define therebetween the conically-shaped cavity.
- the arranging comprises moving the at least some of the tooth cleaning elements relative to the others of the tooth cleaning elements by introducing the first portions of the tooth cleaning elements into a mold.
- the arranging comprises allowing at least some of the tooth cleaning elements to move relative to others of the tooth cleaning elements to cause the tooth cleaning elements to define therebetween the conically-shaped cavity.
- the arranging comprises introducing the first portions of the tooth cleaning elements into a mold and allowing the tooth cleaning elements to conform to the shape of the mold, for example under the influence of gravity.
- the fixing comprises melting together the second portions of the tooth cleaning elements to form a melt matte at the second side of the member.
- the fixing comprises fixing the second portions of the tooth cleaning elements to the member.
- the method comprises bringing into contact with one another plural tooth cleaning elements of the group so that an apex of the cavity is defined by the plural tooth cleaning elements.
- the cavity has an apex on the second side of the member.
- the cavity has an apex in the passage.
- the cavity has the shape of a full cone.
- the cavity has the shape of a truncated cone, such as a frusto cone.
- the cavity has the shape of a right cone.
- the cavity has the shape of a circular cone or of an elliptical cone or of a pyramid.
- the cavity has an opening defined by distal ends of a plurality of the tooth cleaning elements, and wherein the cavity reduces in cross-sectional area as distance into the cavity from the opening increases.
- the group of non-parallel tooth cleaning elements together define a wall around the cavity, the wall having a proximal end adjacent the member and a distal end distal from the member, the distal end of the wall being defined by distal ends of a plurality of the tooth cleaning elements.
- the wall is a continuous wall.
- the wall is free of gaps therein.
- a thickness of the wall measured from an interior side of the wall facing the cavity to an opposite exterior side of the wall is less at the distal end of the wall than at the proximal end of the wall.
- the wall tapers in thickness from the proximal end of the wall to the distal end of the wall.
- the group of tooth cleaning elements comprises a tuft of bristles.
- some or all of the group of tooth cleaning elements are tapered bristles.
- the passage is a tapered passage.
- the passage has a length between the first and second sides of the member of from 0.5 to 2.0 mm.
- the member comprises part of a head of an oral care implement, and the group of non-parallel tooth cleaning elements extends from a first surface of the head.
- the member comprises a plate or membrane
- the method further comprises providing the plate or membrane in a head of an oral care implement so that the group of non-parallel tooth cleaning elements extends from a first surface of the head.
- the method comprises providing a soft tissue cleaner to form at least part of a second surface of the head, which second surface of the head is opposite to the first surface of the head.
- the method comprises flowing a material onto the above-mentioned melt matte and allowing the material to harden, to form the soft tissue cleaner.
- the method comprises adhering the soft tissue cleaner to the above-mentioned melt matte.
- Figure 1 is a perspective view of a first oral care implement manufactured according to a first embodiment of the method of the present invention
- Figure 2 is an enlarged plan view of a head of the implement of FIG. 1;
- Figure 3 is an enlarged perspective view of the head of the implement of FIG. l;
- Figure 4 is a partial cross-sectional view of the head taken along line 4-4 in Figure 2;
- Figure 5 is a perspective view of a second oral care implement manufactured according to a second embodiment of the method of the present invention.
- Figure 6 is an enlarged plan view of a head of the implement of FIG. 5;
- Figure 7 is a perspective view of a third oral care implement manufactured according to a third embodiment of the method of the present invention.
- Figure 8 is an enlarged plan view of a head of the implement of FIG. 7.
- the method of the invention is used in the manufacture of a powered toothbrush wherein one or more cleaning elements provided to the head of the implement are drivable so as to be moved relative to the handle of the implement.
- method of the invention is used in the manufacture of other forms of oral care implements, such as a soft-tissue cleansing implement, or another implement designed for oral care. It is to be understood that other embodiments may be utilised, and that structural and functional modifications may be made without departing from the scope of the present invention.
- the term “cone”, and derivatives thereof such as “conical” and “conically”, covers full cones and truncated cones, such as frusto-cones.
- the term “apex" of a cavity means a, or the, deepest portion or point of the cavity from an open end of the cavity.
- FIGS 1 to 4 illustrate an oral care implement 100, in this case a toothbrush, manufactured according to a first embodiment of the method of the present invention.
- the toothbrush 100 has a body 110 comprising a handle portion 120, a head portion 140, and a neck portion 130 that connects the handle portion 120 to the head portion 140.
- the head portion 140 is an end portion of the body 110 and is provided with a set 200 of cleaning elements for cleaning surfaces in a user's mouth, such as surfaces of their teeth.
- the implement 100 has a head 180, comprising the head portion 140 of the body 110, the set 200 of cleaning elements, and a soft tissue cleaner 160, each of which is described in more detail below.
- the soft tissue cleaner 160 is omitted.
- the head portion 140 has a first, proximal end 141 and a second, distal end 142.
- the handle portion 120 has a first, proximal end 121 and a second, distal end 122.
- the neck portion 130 connects the distal end 122 of the handle portion 120 to the proximal end 141 of the head portion 140.
- the neck portion 130 is generally of a narrower cross sectional area than at least the distal end 122 of the handle portion 120 and, in some embodiments, the neck portion 130 is generally of a narrower cross sectional area than all portions of the handle portion 120.
- the handle portion 120 of the body 110 provides the user with a mechanism by which he/she can readily grip and manipulate the toothbrush 100, includes ergonomic features which provide a high degree of control for the user while maintaining comfort, and may be formed of many different shapes and with a variety of constructions.
- the toothbrush 100 extends from a proximal end 101 (which is also the proximal end 121 of the handle portion 120) to a distal end 102 (which is also the distal end 142 of the head portion 140) along a longitudinal axis A- A.
- the handle portion 120 is a non-linear structure in the illustrated embodiment, the longitudinal axis A-A of the implement 100 is linear in the illustrated embodiment.
- the implement 100 may have a simple linear handle portion 120 that is longitudinally aligned along the linear longitudinal axis A-A of the implement 100.
- the head portion 140 is connected to the handle portion 120 via the neck portion 130.
- the head portion 140, neck portion 130 and handle portion 120 are formed as an integral structure using an injection molding process.
- the head portion 140 is substantially immovable relative to the neck portion 130 and handle portion 120.
- the head portion 140, handle portion 120 and neck portion 130 are together a single, unitary structure. That is, the body 110 is a unitary body.
- the head portion 140 and the neck portion 130 together may be formed as a separate component from the handle portion 120, which separate components are operably connected at a later stage of the manufacturing process by any suitable technique known in the art, including without limitation thermal welding, sonic welding, a tight-fit assembly, a coupling sleeve, adhesion, fasteners, and a snap-fit connection.
- any suitable technique known in the art including without limitation thermal welding, sonic welding, a tight-fit assembly, a coupling sleeve, adhesion, fasteners, and a snap-fit connection.
- head and neck portions 140, 130 and the handle portion 120 are constructed as a single piece or a multi-piece assembly (including connection techniques) is not limiting of the present invention in all embodiments.
- other manufacturing techniques may be used in place of and/ or in addition to injection molding to create the handle portion 120 and/ or the head portion 140 (or components thereof) and/ or the neck portion 130, such as milling and/ or machining.
- the body 110 comprising each of the head portion 140, neck portion 130 and handle portion 120 is constructed of a hard, substantially rigid material, specifically the hard plastic polypropylene (PP).
- the head portion 140 may instead or additionally be constructed of one or more of the following hard materials: polyethylene, polypropylene, polyamide, polyester, cellulosics, styrene-acrylonitrile (SAN), acrylic, acrylonitrile butadiene styrene (ABS) and a thermoplastic.
- the handle portion 120 and/ or the neck portion 130 may instead or additionally be constructed of one or more of those materials.
- An optional thumb grip 125 is provided on a front side of the handle portion 120, and an optional rear grip 127 is provided on a rear side of the handle portion 120 opposite to the front side of the handle portion 120.
- the thumb and rear grips 125, 127 are non-unitary with the body 110, and may be formed of any of the materials discussed below for the soft tissue cleaner 160.
- the head 180 generally comprises a first surface 183, on a front side of the head 180, and a second surface 184, on a rear side of the head 180 opposite to the first side and thus opposite to the first surface 183.
- the first surface 183 and the second surface 184 of the head 180 can take on a wide variety of shapes and contours, none of which are limiting of the present invention.
- the first and second surfaces 183, 184 can be planar, contoured or combinations thereof.
- the first surface 183 and second surface 184 are joined by a peripheral or lateral surface 145 of the head portion 140, which is a peripheral or lateral surface 185 of the head 180.
- the cleaning elements of the set 200 are provided at, and extend outward from, the first surface 183 of the head 180 for cleaning contact with an oral surface, preferably teeth.
- the set 200 of cleaning elements is particularly suited for cleaning teeth, the set 200 of cleaning elements can also be used to clean oral soft tissue, such as a tongue, gums, or cheeks instead of or in addition to teeth.
- cleaning element is used in a generic sense to refer to any structure that can be used to clean, massage or polish an oral surface, such as teeth or soft tissue, through relative surface contact.
- the set 200 of cleaning elements comprises the following different types of cleaning elements, each of which extends from the first surface 183 of the head 180 and is discussed in more detail below: groups 210 of non-parallel tooth cleaning elements 220, pointed cleaning elements 250, raised cleaning elements 260, and distal and proximal cleaning elements 270.
- the groups 210 of tooth cleaning elements 220 will be described.
- the implement 100 has a plurality of groups 210 of tooth cleaning elements 220.
- only one group 210 of non-parallel tooth cleaning elements 220 is provided.
- only one of the groups 210 of the first embodiment will be described in detail, but it will be understood that each of the groups 210 of the first embodiment is of substantially the same construction.
- Each of the non-parallel tooth cleaning elements 220 of the group 210 is a flexible, nylon bristle that extends from the first surface 183 of the head 180. Accordingly, the group 210 of non-parallel tooth cleaning elements 220 comprises a tuft of bristles. The non-parallel nature of the tooth cleaning elements 220 of the group 210 results from some, or all, of the tooth cleaning elements 220 of the group 210 not being parallel to others of the tooth cleaning elements 220 of the group 210.
- Each of the tooth cleaning elements 220 has a (optionally tapered) distal end 221 furthest from the first surface 183 of the head 180, an opposite proximal end 222, and is linear, or substantially linear, between its distal end 221 and the first surface 183 of the head 180.
- the tooth cleaning elements 220 define therebetween a cavity 230. That is, the cavity 230 is located between the tooth cleaning elements 220 and is bound by the tooth cleaning elements 220. More specifically, the tooth cleaning elements 220 together define a wall 240 around the cavity 230, the wall 240 having a proximal end 242 adjacent the first surface 183 of the head 180 and a distal end 241 distal from the first surface 183 of the head 180, the distal end 241 being defined by distal ends 221 of a plurality (optionally all) of the tooth cleaning elements 220. The wall 240 surrounds the cavity 230.
- the wall 240 is a continuous wall 240 around the cavity 230.
- the wall 240 extends for 360 degrees around the cavity 230.
- the wall 240 is free of gaps therein.
- the distal end 241 of the wall 240 has a substantially linear side profile.
- the distal end 241 of the wall 240 is substantially planar.
- the distal end 241 of the wall 240 is substantially parallel to the first surface 183 of the head 180.
- the distal end 241 of the wall 240 could be non-planar and/ or non-parallel to the first surface 183 of the head 180.
- the distal end 241 of the wall 240 may have an alternative side profile, such as a non-linear profile, an S- shaped profile, a wavy profile, a serrated profile, a U-shaped profile, a V-shaped profile, or a pointed profile.
- a thickness T of the wall 240 measured from an interior side 243 of the wall 240 facing the cavity 230 to an opposite, exterior side 244 of the wall 240 is less at the distal end 241 of the wall 240 than at the proximal end 242 of the wall 240. That is, the thickness T2 of the wall 240 at the distal end 241 of the wall 240 is less than the thickness Tl of the wall 240 at the proximal end 242 of the wall 240.
- the maximum thickness Tl of the wall 240 is at the proximal end 242 of the wall 240, while the minimum thickness T2 of the wall 240 is at the distal end 241 of the wall 240.
- the thickness of the wall 240 decreases linearly (i.e.
- the wall 240 tapers in thickness from the proximal end 242 of the wall 240 to the distal end 241 of the wall 240.
- a cross sectional area of the wall 240 at the distal end 241 of the wall 240 is substantially equal to a cross sectional area of the wall 240 at the proximal end 242 of the wall 240.
- the thickness of the wall 240 is substantially constant around a full perimeter of the cavity 230.
- the wall 240 is preferably rotationally symmetrical.
- the cavity 230 has an opening 232 at the distal end 241 of the wall 240 and an apex 231 at a position in the cavity 230 furthest from the distal ends 221 of the tooth cleaning elements 220 of the group 210, i.e. furthest from the opening 232 of the cavity 230.
- the apex 231 is formed at the point (see Figure 4) where plural of the tooth cleaning elements 220 of the group 210 are in contact with one another.
- the apex 231 is within a hole 186 in the head 180, and the group 210 of non-parallel tooth cleaning elements 220 extends from within the hole 186.
- the hole 186 has an axis H-H and a cross-sectional area orthogonal to the axis H-H.
- the cross-sectional area of the hole 186 varies along the axis H-H.
- the hole 186 is a tapered hole 186, whereby the cross-sectional area reduces as distance into the hole 186 from the first surface 183 increases. In other embodiments, the hole 186 is not tapered.
- the cavity 230 is conically-shaped, with an axis C of the cone being the imaginary straight line that passes through the apex 231 and about which the opening 232 has rotational symmetry. More specifically, in this embodiment the cavity 230 has the shape of a right circular full cone, whereby the opening 232 is circular and substantially planar, and the axis C of the cone passes through the opening 232 at right angles to the plane of the opening 232. In a variation, the opening 232 may instead by elliptical (and optionally substantially planar), so that the cavity has the shape of an elliptical cone, optionally a right elliptical cone.
- the cavity 230 may instead take the shape of an oblique circular or elliptical cone, in which the axis C is not at right angles to the plane of the opening 232.
- the opening 232 could take a still different shape, such as a square or rectangle, in which case the cavity 230 would have the shape of a pyramid (note that a pyramid is a cone with a polygonal base).
- the cavity 230 could instead have the shape of a truncated cone, such as a frusto-cone, n which case the apex 231 would not be a point as such, but instead would be an area preferably formed by material of plural of the tooth cleaning elements 220 of the group 210.
- a distance between two diametrically-opposed cavity-facing points on the wall 240 is at least 10 times the width of any one of the tooth cleaning elements 220.
- a width of the opening 232 is at least 10 times the width of any one of the tooth cleaning elements 220. More preferably, this multiple is at least 20 times, and most preferably, this multiple is at least 30 times or at least 40 times.
- the distance is at least 5 times the thickness T2 of the wall 240 at the distal end 241 of the wall 240, and most preferably the distance is at least 10 times the thickness T2 of the wall 240 at the distal end 241 of the wall 240.
- the internal angle a of the conical cavity i.e. the angle at the apex 231 of the cavity 230, is at least 20 degrees. More preferably, the angle a is at least 25 degrees, or at least 30 degrees. Preferably, the angle a is less than 45 degrees, and more preferably the angle a is less than 40 degrees, or less than 35 degrees. In some embodiments, this angle a is the angle between two diametrically-opposed cavity- facing tooth cleaning elements 220 of the group 210.
- each of the groups 210 of tooth cleaning elements 220 comprises a plurality of flexible, nylon bristles 220.
- the tooth cleaning elements 220 of the group(s) 210 may additionally or alternatively comprise any one or more of the following, without limitation: rigid bristles, filament bristles, fibre bristles, nylon bristles, spiral bristles, tapered bristles, rubber bristles, elastomeric protrusions, flexible polymer protrusions, co-extruded filaments, flag bristles, crimped bristles, anti-bacterial bristles and combinations thereof and/ or structures containing such materials or combinations.
- the tooth cleaning elements 220 of the group(s) 210 can be connected to the head 140 using anchor free tufting (AFT).
- AFT anchor free tufting
- the cleaning elements 220 could be mounted to tuft blocks or sections by extending through suitable openings in the tuft blocks so that the base of the cleaning elements 220 is mounted within or below the tuft block. Staple technology may instead be used.
- the tooth cleaning elements 220 are arranged to extend through a passage 156 in a member 150, which in this embodiment is a plate but in a variation to this embodiment is a membrane. Respective first portions, i.e. free distal ends, 221 of the tooth cleaning elements 220 on a first side 153 of the plate 150 perform the cleaning function. Respective second portions, e.g. proximal ends, 222 of the tooth cleaning elements 220 on a second side 154 of the plate 150 are fused, or melted together, by heat to form a melt matte 223 and to be anchored in place relative to the plate 150.
- the plate 150 is secured to the pre-made head portion 140, such as by ultrasonic welding. Alternatively, the material of the head portion 140 is subsequently moulded over the member 150 to envelop, or substantially envelop, the member 150.
- the member 150 is a plate or membrane that is a separate entity to the head portion 140
- the member 150 is part of the head portion 140 itself, which head portion 140 may be unitary with, or otherwise connected to, the handle portion 120 and/ or the neck portion 130 of the implement 100, and thus is part of the head 180.
- the hole 186 comprises the passage 156 through the member 150.
- the passage 156 has a length between the first and second sides 153, 154 of the member 150 of from 0.5 mm to 2.0 mm, more preferably from 0.75 mm to 1.5 mm.
- the apex 231 of the cavity 230 is disposed in the hole 186 on the second side 154 of the member 150.
- the apex 231 is disposed in the passage 156, which is comprised in the hole 186.
- the passage 156 in the member 150 is a tapered passage. However, in other embodiments, this need not be the case.
- the soft tissue cleaner 160 At the rear side of the head 180 is disposed the soft tissue cleaner 160, preferably formed from resilient material.
- the soft tissue cleaner 160 is comprised in the second surface 184 of the head 180.
- the soft tissue cleaner 160 comprises a pad and a plurality of flexible protrusions 162 protruding from the pad.
- the pad also is of a flexible material and the pad and protrusions 162 are a unitary component.
- the pad and the protrusions 162 are made of an elastomer, such as a thermoplastic elastomer (TPE), or styrene-ethylene/butylene-styrene (SEBS).
- TPE thermoplastic elastomer
- SEBS styrene-ethylene/butylene-styrene
- each of the methods comprises: providing a member 150 and providing a group 210 of non-parallel tooth cleaning elements 220 that together define therebetween a conically-shaped cavity 230, wherein the tooth cleaning elements 220 extend through a passage 156 formed in the member 150 so that respective first portions 221 of the tooth cleaning elements 220 are disposed on a first side 153 of the member 150 and respective second portions 222 of the tooth cleaning elements 220 are disposed on a second side 154 of the member 150, and then fixing together the second portions 222 of the tooth cleaning elements 220 at the second side 154 of the member 150.
- the member 150 may be a plate or membrane that is a separate entity to a head portion 140 of the implement 100. Alternatively, the member is part of the head portion 140.
- the head portion 140 may be unitary with, or otherwise connected to, the handle portion 120 and/ or the neck portion 130 of the implement 100.
- the method of manufacture of the implement 100 shown in Figure 1 comprises inserting the tooth cleaning elements 220 (each of which is a bristle, optionally a tapered bristle) into the tapered passage 156, so that each of the tooth cleaning elements 220 has a first portion 221 on the first side 153 of the member 150 and has a second portion 222 (in this embodiment, a proximal end) on the second side 154 of the member 150, and then arranging the tooth cleaning elements 220 so that together the tooth cleaning elements 220 define therebetween the conically- shaped cavity 230.
- the tooth cleaning elements 220 each of which is a bristle, optionally a tapered bristle
- the inserting comprises disposing a plurality of (preferably between two and four) picks (i.e. individual clusters) of mutually-aligned tooth cleaning elements 220 into the passage 156 with the picks at respective different orientations relative to one another.
- Each of the picks may be inserted into the passage 156 from a different direction to each of the other picks with the picks at respective different orientations relative to one another during the inserting, or all of the picks may be inserted into the passage 156 from the same direction, for example in a direction parallel to the shortest distance between the first and second sides 153, 154 of the member 150, with the picks at respective different orientations relative to one another during the inserting.
- the inserting comprises disposing at least some of the tooth cleaning elements 220 in the passage 156 at a different orientation to others of the tooth cleaning elements 220.
- the picks may be inserted into the passage 156 at the same time or successively.
- the tooth cleaning elements 220 are all inserted into the passage 156 with all the tooth cleaning elements 220 being substantially parallel to one another.
- the arranging may comprise moving at least some of the tooth cleaning elements 220 relative to others of the tooth cleaning elements 220 and relative to the member 150 to cause the tooth cleaning elements 220 to define therebetween the conically-shaped cavity 230, such as by introducing the first portions 221 of the tooth cleaning elements 220 into a mold (not shown) and using the mold to move the tooth cleaning elements 220.
- the arranging may comprise allowing at least some of the tooth cleaning elements 220 to move relative to others of the tooth cleaning elements 220 and relative to the member 150 to cause the tooth cleaning elements 220 to define therebetween the conically-shaped cavity 230, such as by introducing the first portions 221 of the tooth cleaning elements 220 into a mold and allowing the tooth cleaning elements 220 to conform to a shape of the mold, e.g. under the influence of gravity.
- each of the tooth cleaning elements 220 of the group 210 extends through the passage 156 with a distal end 221 thereof on the first side 153 of the member 150 and the proximal end 222 thereof on the second side 154 of the member 150.
- the tooth cleaning elements 220 of the group 210 are positioned so that they contact one another on the second side 154 of the member 150, and are splayed apart from one another on the first side 153 of the member 150. Over all, the tooth cleaning elements 220 define the conically-shaped cavity 230 therebetween.
- the tooth cleaning elements 220 may contact one another at their proximal ends 222, or at respective points a short distance from their respective proximal ends 222, to define the apex 231 of the cavity 230.
- the cavity 230 of the implement 100 has the shape of a right circular full cone. In other embodiments, depending on the relative orientations of the tooth cleaning elements 220, the cavity 230 may instead have any of the other shapes discussed above.
- the tooth cleaning elements 220 are fixed at respective different orientations relative to one another by holding the tooth cleaning elements 220 and heating up the second portions 222 (i.e. the proximal ends, in this embodiment) of the tooth cleaning elements 220 to cause the second portions 222 to melt and run into one another.
- the heat is then removed and the second portions 222 of the tooth cleaning elements 220 are allowed to cool and harden into one monolithic mass or melt matte 223, so that the picks of tooth cleaning elements 220 become fused together at the second side 154 of the member 150.
- the second portions 222 of the tooth cleaning elements 220 become fixed to the member 150 during this process.
- this process results in the apex 231 of the cavity 230 becoming formed on the second side 154 of the member 150.
- the apex 231 may become formed within the passage 156.
- the position of the apex 231 may change during the fixing process as material of the tooth cleaning elements 220 flows.
- the apex 231 is formed relative to the passage 156 and relative to the member 150 as a whole depends upon how close to one another tooth cleaning elements 220 are held, the length of time for which the heating is carried out, and the material of the tooth cleaning elements 220.
- the fixed group 210 of non- parallel tooth cleaning elements 220 together define the wall 240, discussed above.
- the wall 240 is a continuous wall, and more preferably the wall 240 is free of gaps therein.
- the passage 156 is tapered and has a length of between 0.5 and 2.0 mm, in variations to this embodiment the passage 156 is not tapered and/ or has a different length.
- the first side 153 of the member 150 effectively forms part or all of the first surface 183 of the head 180, so that the group 210 of non- parallel tooth cleaning elements 220 extends from the first surface 183 of the head 180.
- the member 150 may end up embedded within the head 180. In alternative embodiments where the member 150 comprises part of the head portion 140, then this attachment process can be omitted.
- the method of manufacturing the implement 100 shown in Figures 1 to 4 also includes providing the soft tissue cleaner 160 to form at least part of the second surface 184 of the head 180, which second surface 184 of the head 180 is opposite to the first surface 183 of the head 180.
- the soft tissue cleaner 160 is in contact with the tooth cleaning elements 220 of the group 210, more specifically with the proximal ends 222 thereof.
- the soft tissue cleaner 160 may be a pre-made entity, for example made of TPE, which is adhered to the head portion 140 and to the tooth cleaning elements 220 of the group 210.
- the method may involve flowing a material, such as a TPE, onto the melt matte 223, and into any gaps left between the tooth cleaning elements 220 at or around their proximal ends 222, and then allowing the material to harden to form the soft tissue cleaner 160.
- the soft tissue cleaner 160 thus can be bound to the tooth cleaning elements 220 of the group 210.
- the oral care implement 100 may be manufactured by a different method.
- the hole(s) 186, the passage 156 and the member 150 may be omitted altogether.
- the tooth cleaning elements 220 may be individually provided to the first side 183 of the head 180, or a unitary structure including the individual tooth cleaning elements 220 may be provided to the first side 183 of the head 180 or to the hole 186.
- Such a unitary structure may be made of TPE.
- a first benefit of the provision of the conically-shaped cavity 230 is that it provides the head 180 with a large volume for retaining toothpaste.
- a second benefit of this structure is that the cavity 230 is easy to clean of toothpaste following a teeth cleaning session, since toothpaste captured in the cavity 230 is entirely or substantially unable to work its way down to the first surface 183 of the head 180 where it may become trapped. It is preferable that the cavity 230 has an apex 231 in the form of a point. In such cases, the toothpaste still less able to work its way down to the first surface 183 of the head 180.
- a third benefit of the conically-shaped cavity 230 is that it holds the majority of the toothpaste at a position where it will be effective at cleaning the teeth. This is particularly the case in embodiments in which the wall 240 is a continuous wall 240 around the cavity 230, and more particularly the case when the cavity 230 has an apex 231 in the form of a point.
- a fourth benefit of the structure is that, in embodiments where the tooth cleaning elements 220 are flexible, during a teeth cleaning session the tooth cleaning elements 220 are able to bend, flex or rotate (about the point apex 231, when provided) to come into contact with each other at, or close to, their distal ends 221.
- the cavity 230 is able to be significantly reduced in volume to cause toothpaste held in the cavity 230 to be completely, or substantially completely, expelled from the cavity 230 onto the teeth during a teeth cleaning session.
- the toothpaste becomes positioned at a contact zone of the tooth cleaning elements 220 with the teeth, thus enabling improved cleaning and/ or polishing of a user's teeth using the toothpaste.
- the set 200 of cleaning elements comprises pointed cleaning elements 250 that extend from the first surface 183 of the head 180 and have respective pointed distal ends 251.
- the pointed distal end 251 is that part of the pointed cleaning element 250 furthest from the first surface 183 of the head 180.
- each pointed cleaning element 250 is an elastomeric component.
- each pointed cleaning element 250 comprises a group of bristles, wherein each of the bristles has a distal end furthest from the first surface 183 of the head 180, and wherein the distal ends of the bristles together define a pointed distal end 251 of the pointed cleaning element 250.
- the distal ends of some or all of the bristles themselves may be any shape, including flat, rounded or tapered.
- the distal ends 251 of the pointed cleaning elements 250 are further from the first surface 183 of the head 180 than the distal ends 221 of the non-parallel tooth cleaning elements 220 making up the groups 210. Due to their shape and height relative to the groups 210 of non-parallel tooth cleaning elements 220, the pointed cleaning elements 250 are particularly effective at cleaning between a user's teeth.
- the head 180 has a first end 181 and a second end 182.
- An axis extends between the first and second ends 181, 182, which axis is parallel to the longitudinal axis A-A of the implement 100 and extends along the longitudinal middle of the head 180.
- Plural ones of said pointed cleaning elements 250 are disposed on the head 180 spaced along this axis.
- the implement 100 comprises a plurality of said pointed cleaning elements 250, and a plurality of said groups 210 of non-parallel tooth cleaning elements 220.
- the pointed cleaning elements 250 alternate with the groups 210 of non-parallel tooth cleaning elements 220 between the first end 181 and the second end 182 of the head 180. That is, between any two of the pointed cleaning elements 250, there is provided a pair of laterally-spaced groups 210 of the non-parallel tooth cleaning elements 220.
- the set 200 of cleaning elements comprises raised cleaning elements 260 that extend from the first surface 183 of the head 180.
- Each of these cleaning elements 260 has a convex distal end 261 which is that part of the raised cleaning element 260 furthest from the first surface 183 of the head 180.
- each raised cleaning element 260 is an elastomeric component.
- each raised cleaning element 260 comprises a group of bristles, wherein each of the bristles has a distal end furthest from the first surface 183 of the head 180, and wherein the distal ends of the bristles together define a convex distal end 261 of the raised cleaning element 260.
- the distal ends of the bristles themselves may be any shape, including flat, rounded or tapered.
- the distal ends 261 of the raised cleaning elements 260 are further from the first surface 183 of the head 180 than the distal ends 221 of the non-parallel tooth cleaning elements 220 making up the groups 210, and approximately the same distance from the first surface 183 of the head 180 as the distal ends 251 of the pointed cleaning elements 250. Due to their shape and height relative to the groups 210 of non- parallel tooth cleaning elements 220, the raised cleaning elements 260 are particularly effective at sweeping away plaque and debris from surfaces in a user's mouth.
- plural ones of said raised cleaning elements 260 are disposed longitudinally spaced along the lateral edges of the first surface 183 of the head 180.
- the raised cleaning elements 260 alternate with the groups 210 of non- parallel tooth cleaning elements 220 between the first end 181 and the second end
- pairs of the raised cleaning elements 260 are longitudinally positioned on the head 180 in alignment with ones of the pointed cleaning elements 250, so that the raised cleaning elements 260 flank the pointed cleaning element 250 on their lateral sides.
- the set 200 of cleaning elements comprises distal and proximal cleaning elements 270 that extend from the first surface 183 of the head 180.
- the distal and proximal cleaning elements 270 are disposed at the first and second ends 181, 182 of the head 180.
- each of the distal and proximal cleaning elements 270 is an elastomeric component.
- each distal and proximal cleaning element 270 comprises a group of bristles, wherein each of the bristles has a distal end furthest from the first surface
- the distal ends of the bristles together define a sloped distal end 271 of the distal and proximal cleaning element 270 that has a peak furthest from the centre of the first surface 183 of the head 180.
- the distal ends of the bristles themselves may be any shape, including flat, rounded or tapered.
- the peaks of the sloped distal ends 271 are approximately the same distance from the first surface 183 of the head 180as the distal ends 251 of the pointed cleaning elements 250. Due to their shape, peak height and positioning on the head 180, the distal and proximal cleaning elements 270 are also effective at cleaning between a user's teeth.
- the distal cleaning elements 270 also are useable to reach far into the user's mouth, to clean effectively their rearmost molars.
- FIG. 5 A second implement 100 manufactured according to a second embodiment of the method of the present invention is shown in Figures 5 and 6. Like elements shown in Figures 1 to 4 are indicated in Figures 5 and 6 with the same reference numerals. In the interests of conciseness, the elements common to the two embodiments will not be described in detail again with reference to Figures 5 and 6. All of the above-described possible variations to the first embodiment are equally applicable to the second embodiment.
- the head 180 of the implement 100 of the second embodiment has an outer shape in plan view similar to the outer edge of a number 8.
- the head 180 has a first end 181 and a second end 182.
- An axis extends between the first and second ends 181, 182, which axis is parallel to the longitudinal axis A-A of the implement 100 and extends along the longitudinal middle of the head 180.
- the head 180 includes only two groups 210 of non-parallel tooth cleaning elements 220 disposed on the head 180 spaced along this axis.
- each of the two groups 210 Surrounding each of the two groups 210 is a plurality of wedge-shaped cleaning elements 280, each of which has a wedge shape in plan view.
- each of the wedge-shaped cleaning elements 280 is an elastomeric component.
- each wedge-shaped cleaning element 280 comprises a group of bristles, wherein each of the bristles has a distal end furthest from the first surface 183 of the head 180, and wherein the distal ends of the bristles together define a sloped distal end 281 of the wedge-shaped cleaning element 280 that has a peak furthest from the centre of the cavity 230.
- the distal ends of the bristles themselves may be any shape, including flat, rounded or tapered.
- each of the triangular-shaped cleaning elements 290 is an elastomeric component.
- each triangular- shaped cleaning element 290 comprises a group of bristles, wherein each of the bristles has a distal end furthest from the first surface 183 of the head 180, and wherein the distal ends of the bristles together define a pointed distal end 291 of the triangular-shaped cleaning element 290 that has a peak at the midpoint of the side of the triangle opposite from the inward-facing vertex.
- the distal ends of the bristles themselves may be any shape, including flat, rounded or tapered.
- the distal ends 291 of the triangular-shaped cleaning elements 290 are further from the first surface 183 of the head 180 than the distal ends 221 of the non-parallel tooth cleaning elements 220 making up the groups 210. Due to their shape and height relative to the groups 210 of non-parallel tooth cleaning elements 220, the triangular-shaped cleaning elements 290 are particularly effective at cleaning between a user's teeth.
- FIG. 7 and 8 A third implement manufactured according to a third embodiment of the method of the present invention is shown in Figures 7 and 8. Like elements shown in Figures 5 and 6 are indicated in Figures 7 and 8 with the same reference numerals. In the interests of conciseness, the elements common to the two embodiments will not be described in detail again with reference to Figures 7 and 8. All of the above- described possible variations to the first and second embodiments are equally applicable to the third embodiment.
- the head 180 of the third implement 100 manufactured according to the third embodiment of the method of the present invention has a substantially elliptical outer shape in plan view.
- the head 180 includes only one group 210 of non-parallel tooth cleaning elements 220.
- the tooth cleaning elements 220 together define therebetween a cavity 230 that has the shape of an elliptical cone.
- the group 210 is disposed on the head 180 with the cavity 230 substantially coaxial with the elliptical outer shape of the head 180.
- each wedge-shaped cleaning element 280 Surrounding the group 210 is a plurality of wedge-shaped cleaning elements 280, each of which has a wedge shape in plan view.
- each of the wedge-shaped cleaning elements 280 is an elastomeric component.
- each wedge-shaped cleaning element 280 comprises a group of bristles, wherein each of the bristles has a distal end furthest from the first surface 183 of the head 180, and wherein the distal ends of the bristles together define a sloped distal end 281 of the wedge-shaped cleaning element 280 that has a peak furthest from the centre of the cavity 230.
- the distal ends of the bristles themselves may be any shape, including flat, rounded or tapered.
Landscapes
- Brushes (AREA)
- Dental Tools And Instruments Or Auxiliary Dental Instruments (AREA)
- Physics & Mathematics (AREA)
- Geometry (AREA)
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PCT/US2012/070761 WO2014098854A1 (en) | 2012-12-20 | 2012-12-20 | Method of manufacturing an oral care implement |
Publications (2)
Publication Number | Publication Date |
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EP2934229A1 true EP2934229A1 (de) | 2015-10-28 |
EP2934229B1 EP2934229B1 (de) | 2017-03-22 |
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EP12810010.4A Active EP2934229B1 (de) | 2012-12-20 | 2012-12-20 | Verfahren zur herstellung einer mundpflegevorrichtung |
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US (1) | US20150327666A1 (de) |
EP (1) | EP2934229B1 (de) |
JP (1) | JP2016501615A (de) |
KR (1) | KR20150100777A (de) |
CN (1) | CN105188469B (de) |
AU (1) | AU2012397295B2 (de) |
BR (1) | BR112015014429A2 (de) |
CA (1) | CA2892503A1 (de) |
MX (1) | MX2015007881A (de) |
PH (1) | PH12015501253A1 (de) |
RU (1) | RU2606710C1 (de) |
TW (1) | TWI548363B (de) |
WO (1) | WO2014098854A1 (de) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
USD689286S1 (en) * | 2011-05-02 | 2013-09-10 | Colgate-Palmolive Company | Toothbrush |
USD764804S1 (en) * | 2013-11-05 | 2016-08-30 | Colgate-Palmolive Company | Oral care implement |
EP3622853B1 (de) * | 2014-12-23 | 2021-08-04 | Colgate-Palmolive Company | Mundpflegevorrichtung |
CA2970622C (en) * | 2014-12-23 | 2022-05-24 | Colgate-Palmolive Company | Oral care implement |
CN110432643B (zh) * | 2014-12-23 | 2021-07-16 | 高露洁-棕榄公司 | 口腔护理器具 |
US11291293B2 (en) | 2014-12-23 | 2022-04-05 | Colgate-Palmolive Company | Oral care implement |
CN113303584A (zh) * | 2014-12-23 | 2021-08-27 | 高露洁-棕榄公司 | 口腔护理器具 |
GB201600846D0 (en) * | 2016-01-18 | 2016-03-02 | Glaxosmithkline Consumer Healt | Novel device |
USD883677S1 (en) * | 2018-12-13 | 2020-05-12 | Colgate-Palmolive Company | Toothbrush |
EP3876786B1 (de) * | 2018-12-13 | 2023-12-06 | Colgate-Palmolive Company | Mundpflegegerät |
MX2021006780A (es) | 2018-12-13 | 2021-07-15 | Colgate Palmolive Co | Implemento para el cuidado bucal. |
USD961269S1 (en) | 2020-07-31 | 2022-08-23 | Colgate-Palmolive Company | Oral care implement |
CN117281349A (zh) * | 2022-06-16 | 2023-12-26 | 狮王株式会社 | 牙刷 |
USD1024571S1 (en) | 2022-06-17 | 2024-04-30 | Colgate-Palmolive Company | Oral care implement |
USD1024572S1 (en) | 2022-06-24 | 2024-04-30 | Colgate-Palmolive Company | Oral care implement |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2161349A (en) * | 1937-01-06 | 1939-06-06 | Gilbert E Hadden | Tooth brush |
CH215110A (de) * | 1938-12-09 | 1941-06-15 | Spyra Paul | Zahnbürste. |
US5144712A (en) * | 1991-05-06 | 1992-09-08 | Hansel Gail W | Disposable toothbrush |
US5590438A (en) * | 1991-11-21 | 1997-01-07 | Johnson & Johnson Consumer Products, Inc. | Bristled article |
DE19909435A1 (de) * | 1999-03-04 | 2000-09-07 | Coronet Werke Gmbh | Verfahren und Vorrichtung zur Herstellung von Borstenwaren und danach hergestellte Borstenwaren |
US8042217B2 (en) * | 2004-11-02 | 2011-10-25 | Colgate-Palmolive Company | Toothbrush and method of making the same |
EP1958534A1 (de) * | 2007-02-14 | 2008-08-20 | Trisa Holding AG | Zahnbürste |
EP2526815B1 (de) * | 2008-06-07 | 2018-04-18 | Trisa Holding AG | Zahnbürste mit gemischten Borstenbündeln und Verfahren zur Herstellung |
US20110047736A1 (en) * | 2009-08-26 | 2011-03-03 | Colgate Palmolive | Oral Care Implement Having Diverging Cleaning Elements |
-
2012
- 2012-12-20 US US14/653,936 patent/US20150327666A1/en not_active Abandoned
- 2012-12-20 AU AU2012397295A patent/AU2012397295B2/en not_active Ceased
- 2012-12-20 JP JP2015549333A patent/JP2016501615A/ja active Pending
- 2012-12-20 EP EP12810010.4A patent/EP2934229B1/de active Active
- 2012-12-20 CN CN201280077684.4A patent/CN105188469B/zh active Active
- 2012-12-20 KR KR1020157019492A patent/KR20150100777A/ko not_active Application Discontinuation
- 2012-12-20 MX MX2015007881A patent/MX2015007881A/es unknown
- 2012-12-20 WO PCT/US2012/070761 patent/WO2014098854A1/en active Application Filing
- 2012-12-20 RU RU2015124060A patent/RU2606710C1/ru not_active IP Right Cessation
- 2012-12-20 BR BR112015014429A patent/BR112015014429A2/pt not_active IP Right Cessation
- 2012-12-20 CA CA2892503A patent/CA2892503A1/en not_active Abandoned
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2013
- 2013-12-19 TW TW102147089A patent/TWI548363B/zh not_active IP Right Cessation
-
2015
- 2015-06-03 PH PH12015501253A patent/PH12015501253A1/en unknown
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US20150327666A1 (en) | 2015-11-19 |
JP2016501615A (ja) | 2016-01-21 |
RU2606710C1 (ru) | 2017-01-10 |
PH12015501253A1 (en) | 2015-08-17 |
AU2012397295B2 (en) | 2015-12-24 |
TW201446184A (zh) | 2014-12-16 |
TWI548363B (zh) | 2016-09-11 |
KR20150100777A (ko) | 2015-09-02 |
MX2015007881A (es) | 2015-09-21 |
AU2012397295A1 (en) | 2015-06-18 |
BR112015014429A2 (pt) | 2017-07-11 |
EP2934229B1 (de) | 2017-03-22 |
CN105188469A (zh) | 2015-12-23 |
CN105188469B (zh) | 2017-07-04 |
WO2014098854A1 (en) | 2014-06-26 |
CA2892503A1 (en) | 2014-06-26 |
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