EP2888112B1 - Procédé de fabrication d'un document de valeur - Google Patents

Procédé de fabrication d'un document de valeur Download PDF

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Publication number
EP2888112B1
EP2888112B1 EP13722684.1A EP13722684A EP2888112B1 EP 2888112 B1 EP2888112 B1 EP 2888112B1 EP 13722684 A EP13722684 A EP 13722684A EP 2888112 B1 EP2888112 B1 EP 2888112B1
Authority
EP
European Patent Office
Prior art keywords
drying
printing
value document
substrate
room temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP13722684.1A
Other languages
German (de)
English (en)
Other versions
EP2888112A2 (fr
Inventor
Alexander Bornschlegl
Christoph Mengel
Andreas BAADER
Günter OLSCHEWSKI
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Giesecke and Devrient GmbH
Original Assignee
Giesecke and Devrient GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Giesecke and Devrient GmbH filed Critical Giesecke and Devrient GmbH
Publication of EP2888112A2 publication Critical patent/EP2888112A2/fr
Application granted granted Critical
Publication of EP2888112B1 publication Critical patent/EP2888112B1/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/30—Identification or security features, e.g. for preventing forgery
    • B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
    • B42D25/378—Special inks
    • B42D25/387—Special inks absorbing or reflecting ultraviolet light
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
    • B41M3/14—Security printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41F—PRINTING MACHINES OR PRESSES
    • B41F23/00—Devices for treating the surfaces of sheets, webs, or other articles in connection with printing
    • B41F23/04—Devices for treating the surfaces of sheets, webs, or other articles in connection with printing by heat drying, by cooling, by applying powders
    • B41F23/044—Drying sheets, e.g. between two printing stations
    • B41F23/0443—Drying sheets, e.g. between two printing stations after printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41F—PRINTING MACHINES OR PRESSES
    • B41F23/00—Devices for treating the surfaces of sheets, webs, or other articles in connection with printing
    • B41F23/04—Devices for treating the surfaces of sheets, webs, or other articles in connection with printing by heat drying, by cooling, by applying powders
    • B41F23/044—Drying sheets, e.g. between two printing stations
    • B41F23/045—Drying sheets, e.g. between two printing stations by radiation
    • B41F23/0453—Drying sheets, e.g. between two printing stations by radiation by ultraviolet dryers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
    • B41M7/0081—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using electromagnetic radiation or waves, e.g. ultraviolet radiation, electron beams
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
    • B41M7/009—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using thermal means, e.g. infrared radiation, heat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
    • B42D25/29—Securities; Bank notes

Definitions

  • the invention relates to a method for producing a value document, such as a banknote, a document or a document of identification.
  • the printing equipment of the subsequent printing steps can be adjusted, which is associated with high costs and high costs.
  • the drying of a printed value document substrate can be further accelerated by the addition of metal-containing driers.
  • Oxidatively drying inks i.e., non-UV inks or UV inks
  • Drying agents are, in particular, organic salts of certain metals, such as cobalt (e.g., cobalt octoate, cobalt naphthenate), manganese, calcium (e.g., calcium octoate), zirconium, or cerium.
  • Metal-containing driers develop their effect only in the presence of oxygen. Provided that storage and transport are largely carried out under exclusion of air, a dry matter can already be incorporated into the paint ex works.
  • the disadvantage of these driers is that the use of (heavy) metal compounds for reasons of work-related safety and health hazards are problematic. A low use concentration would therefore be desirable, but this leads to long drying times.
  • the drying of a printed value-added substrate can be accelerated by the addition of peroxide-containing substances, such as inorganic or organic peroxides.
  • peroxide-containing substances such as inorganic or organic peroxides.
  • This also works in places where air or oxygen deficiency prevails, consequently also in non-impacting substrates and in high or large value document stacks.
  • the disadvantage is that peroxide-containing substances of color may be added relatively shortly before printing, because the color can not be stored for a longer period of time by the onset of the addition of the peroxide chemical reaction.
  • the WO 2009/013169 describes the drying of inks wherein an oxidatively curing ink comprises a combination of meltable wax and a UV-chelating binder component.
  • step b) the treatment of the value document substrate with UV radiation and additionally with ozone takes place.
  • the additional treatment with ozone is preferably carried out by applying the value document substrate with ozone in room air at a concentration in the range of 1 to 15 ppm.
  • step b) the treatment with UV radiation is carried out by a (simultaneous) printing machine equipped with a UV drying system, preferably a UV dose rate of 10 mJ / cm 2 to 200 mJ / cm 2 per side is selected. A UV dose rate of 15 mJ / cm 2 to 80 mJ / cm 2 per side is particularly preferred.
  • the measurement of the UV dose can be carried out by means of a photochromic film, for example by means of a 70 mm x 19 mm measuring strip "tesa® UV Strip" from Dr. Ing. Hönle AG.
  • step c) drying is preferably carried out at room temperature. Furthermore, it is preferred to carry out the drying of the value documents in the form of a document of value document, wherein the document of value documents, in particular 200 to 10,000 sheets, preferably 5000 to 7000 sheets.
  • the inventive method is applicable to all conventional value document substrates, in particular paper substrates, polymer substrates and so-called hybrid substrates, which are to be understood composite film substrates, either a paper-based core and polymer-based outer layers or a core of a plastic material and outer layers on a paper basis. It is preferred to use substrates based on cotton fibers.
  • the substrate may have certain coatings, impregnations or imprints and / or security elements or film elements.
  • a polymer substrate or composite substrate having a core of paper and polymer-based outer layers, it is desirable Apply to the polymeric material one or more coatings that ensure the adhesion of the applied to the respective substrate printing.
  • This layer applied to the polymeric material is commonly referred to as the ink accepting layer.
  • ink receiving layers are usually dispensable, but the paper substrate can be wholly or partially coated to provide it with certain properties, such as luminescent properties due to applied luminescent substances.
  • Oxidatively drying inks include (or consist of the following components): oxidatively drying film formers, (color) pigments, fillers, solvents, and additives.
  • the film former is that component of the binder which is essential for the formation of the film (see also: Thomas Brock: “textbook of paint technology", 2nd edition, Curt R. Vincentz Verlag, 2000, page 190 ). Film formers are especially macromolecular organic substances.
  • the term “binder” refers to the non-volatile content of a coating material without pigment and filler, but including plasticizers, driers and other nonvolatile excipients.
  • nonvolatile fraction is to be understood here as the non-volatile fraction according to ISO 4618.
  • oxidatively drying film former which can be used for the oxidatively drying printing ink
  • film former molecules which can be linked to aliphatic double bonds by the action of atmospheric oxygen via oxygen bridges are preferred.
  • oxidatively drying alkyd resins, Urethanalkyde, epoxy resin esters with unsaturated fatty acids, oil-modified phenolic resins, and natural or synthetic Triglycerides with at least partially unsaturated fatty acid residues as film formers preferred.
  • the oxidatively drying ink may preferably comprise driers or siccatives, especially organic salts of certain metals such as cobalt (e.g., cobalt octoate, cobalt naphthenate), manganese, calcium (e.g., calcium octoate), zirconium, cerium, zinc, lead, or iron.
  • Organic acids especially higher fatty acids such as linseed oil fatty acid or tall oil fatty acid, rosin acids, naphthenic acid or 2-ethylhexanoic acid can be used to form the organic salts.
  • the dry substances catalyze the oxygen transfer from the air by redox reactions and accelerate film formation by polymerization.
  • the oxidatively drying printing ink is in particular a background printing ink.
  • the step of treating the printed value document substrate with UV radiation is expediently carried out by using UV drying systems which can be based in particular on medium-pressure mercury UV lamps or iron or gallium-doped medium-pressure mercury UV lamps.
  • the emitter power per lamp is in the range of 120 W / cm to 250 W / cm, preferably 180 W / cm.
  • a suitable emitter system are, for example, the units BLK-5 or BLK-2 offered by the company IST METZ GmbH.
  • the method expediently takes place at a printing speed of 8000 to 12000 sheets / h, in particular 10,000 sheets / h, and a setting of a single-jet dose rate within a range of 4 mJ / cm 2 to 100 mJ / cm 2 .
  • the step of drying the UV-treated printed value-added substrate is at room temperature or elevated temperature.
  • room temperature is meant herein a temperature of 20 ° C.
  • the drying at elevated temperature can be carried out in particular at a temperature in a range of 35 ° C to 40 ° C.
  • the step of drying the value documents in the form of a document of value document In order to avoid the shrinkage of the value document substrate, it is preferred to perform the step of drying the value documents in the form of a document of value document.
  • the value document stack may in particular have 200 to 10,000 signatures, preferably 5000 to 7000 signatures. A value document stack with approximately 6000 signatures is particularly preferred for drying. Furthermore, it is preferred that the stack core temperature does not exceed a temperature of 40 ° C.
  • the drying of the value documents in the form of a document of value document is preferably carried out at room temperature.
  • a suitable for printing with conventionally drying inks suitable simultaneous printing machine with retrofitted UV drying system of IST Metz ("BLK-5", two spotlights per side with a radiator output of 180 W / cm) was used.
  • Cotton velor paper was printed on both sides in a simultaneous sheetfed press with one offset and two letter set inks.
  • the paints contained 3% by weight cobalt / manganese salt drier.
  • the printing speed was 8000 sheets / h.
  • the signatures were dried at room temperature in stacks of 6000 sheets each and could be further processed by intaglio printing after 48 hours at the earliest. After connecting two UV aggregates (IST Metz, model "BLK-5”) on each side at 40% of the maximum output and subsequent drying at room temperature in stacks of 6000 sheets each, further processability by intaglio printing could be achieved after only 20 hours.
  • the paper substrate is not appreciably changed in dimension or spatial dimension, whereas a higher heat input by hot air leads to a higher shrinkage of the substrate , In the event that increased shrinkage is desired, the power of the UV lamps can be increased.
  • Cotton velor paper was printed on both sides in a simultaneous sheetfed press with three letter set colors each.
  • the paints contained 3% by weight cobalt / manganese salt drier.
  • the printing speed was 10,000 sheets / h.
  • the signatures were dried at room temperature in batches of 6000 sheets each until further processing. Five sheets each from the stack top, the stack center and the bottom of the stack were taken from the stack after one hour, measured and the average of the measured values determined.
  • Cotton velvet paper with film elements applied in subregions was printed on both sides in each case with one offset and three letter set inks in a simultaneous sheetfed press.
  • the paints contained 3% by weight cobalt / manganese salt drier.
  • the printing speed was 8000 sheets / h.
  • the film areas that were printed with the wet offset ink were not sufficiently dried in the arrangement of the printed sheets in the stack, so that strong deposition was observed in the stack on the respective next sheet back page.
  • the print strips were dried open in the room air at a temperature of 20 ° C for four hours.
  • the print strips were irradiated immediately after printing in a continuous UV belt dryer at the indicated UV dose rate.
  • the UV lamps used were both normal mercury UV medium-pressure lamps (company IST, spectra type CK) and iron-doped mercury UV medium-pressure lamps (company IST, spectrum type CK-II).
  • the print strips were also fixed on a metal support for rapid heat dissipation. The temperature of the printing strips reached room temperature again after only 5 to 10 seconds after the dryer had been run through. The strips were then dried next to the reference strips for four hours.
  • the printing strips were dried in a drying oven at 35 ° C. for one, two or three hours immediately after printing. After each time, the strips were removed from the oven and further dried at room temperature for the remaining time to the total drying time of four hours, in addition to the reference stiffeners.
  • the printing strips were fumigated immediately after printing in a chamber with a mixture of atmospheric air and ozone under the conditions indicated at room pressure. At the end of the indicated time, the strips were removed from the chamber and further dried at room temperature for the remaining time to the total drying time of four hours, in addition to the reference stiffeners.
  • the connected ozone generator was operated with dried room air and worked with a corona discharge.
  • FIG. 1 shows the transferred by the compression of the unprinted substrate amount of ink. The larger this is, the worse the color was dried at the time of the Abklatschs.
  • a dry-free paint at room temperature has to dry for at least a week or more until the signatures can be further processed. So there is no industrial production possible.
  • the drying in the oven also requires a relatively long drying time and also changes the dimension of the paper substrate.
  • a three-hour heat input can not achieve a significant effect compared to the reference.
  • UV radiation already achieves a measurable effect.
  • FIG. 2 shows the transferred by the compression of the unprinted substrate amount of ink. The larger this is, the worse the paint was dried.
  • FIG. 3 shows the transferred by the compression of the unprinted substrate amount of ink. The larger this is, the worse the paint was dried.
  • UV radiation compared to the reference can achieve effects in the order of magnitude that otherwise can only be caused by heat. Ozone also shows a beneficial effect.

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  • Toxicology (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Electromagnetism (AREA)
  • Thermal Sciences (AREA)
  • Finance (AREA)
  • Accounting & Taxation (AREA)
  • Business, Economics & Management (AREA)
  • Printing Methods (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Claims (4)

  1. Procédé de fabrication d'un document de valeur, comprenant:
    a) l'impression d'un substrat pour documents de valeurs avec une encre d'impression à séchage oxydatif, c'est à dire une encre d'impression qui n'appartient pas aux encres UV ni aux vernis UV;
    b) le traitement du substrat pour documents de valeurs imprimé, avec un rayonnement UV par une machine à impression équipée d'un système de séchage par UV; et
    c) le séchage, à température ambiante et en une pile, du substrat pour documents de valeurs imprimé et traité avec un rayonnement UV.
  2. Procédé selon la revendication 1, cependant que, à l'étape b), le traitement du substrat pour documents de valeurs a lieu avec un rayonnement UV et en plus avec de l'ozone.
  3. Procédé selon une des revendications 1 ou 2, cependant que, à l'étape b), le traitement du substrat pour documents de valeurs avec un rayonnement UV a lieu par une machine à impression (simultanée) équipée d'un système de séchage par UV, dans laquelle, pour une vitesse d'impression de 10000 feuilles/h, c'est un débit de dosage UV situé entre 10mJ/cm2 et 40mJ/cm2 par émetteur de rayonnement qui est sélectionné.
  4. Procédé selon une des revendications de 1 à 3, le séchage des documents de valeurs étant effectué sous forme d'une pile de documents de valeurs, et la pile de documents de valeurs comportant entre 1000 et 10 000 feuilles d'impression, de préférence entre 5000 et 7000 feuilles d'impression.
EP13722684.1A 2012-05-29 2013-05-14 Procédé de fabrication d'un document de valeur Not-in-force EP2888112B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102012010534A DE102012010534A1 (de) 2012-05-29 2012-05-29 Verfahren zum Herstellen eines Wertdokuments
PCT/EP2013/001421 WO2013178325A2 (fr) 2012-05-29 2013-05-14 Procédé de fabrication d'un document de valeur

Publications (2)

Publication Number Publication Date
EP2888112A2 EP2888112A2 (fr) 2015-07-01
EP2888112B1 true EP2888112B1 (fr) 2016-07-13

Family

ID=48444319

Family Applications (1)

Application Number Title Priority Date Filing Date
EP13722684.1A Not-in-force EP2888112B1 (fr) 2012-05-29 2013-05-14 Procédé de fabrication d'un document de valeur

Country Status (9)

Country Link
EP (1) EP2888112B1 (fr)
CN (1) CN104321199B (fr)
BR (1) BR112014029183A2 (fr)
CA (1) CA2870463C (fr)
DE (1) DE102012010534A1 (fr)
HK (1) HK1201234A1 (fr)
MX (1) MX359340B (fr)
WO (1) WO2013178325A2 (fr)
ZA (1) ZA201408152B (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102517800B1 (ko) * 2015-04-28 2023-04-05 시크파 홀딩 에스에이 습식 옵셋 인쇄 공정용 환경 친화적 습수액 및 습식 옵셋 인쇄 공정
DE102017213226A1 (de) * 2016-09-27 2018-03-29 Heidelberger Druckmaschinen Ag Verfahren zum Herstellen eines Druckprodukts
WO2021197663A1 (fr) 2020-04-03 2021-10-07 Giesecke+Devrient Currency Technology Gmbh Substrat de document de valeur et procédé de désinfection

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH674989A5 (fr) * 1988-09-05 1990-08-15 Sicpa Holding Sa
JPH0369394A (ja) * 1989-08-09 1991-03-25 Hitachi Maxell Ltd 酸化重合型インキの乾燥方法および印刷情報記録媒体の製造方法
JPH03281249A (ja) * 1990-03-29 1991-12-11 Dainippon Printing Co Ltd オフセット印刷における裏移り防止方法
DE10243653A1 (de) 2002-09-19 2004-04-01 Giesecke & Devrient Gmbh Sicherheitspapier
AU2008280231B9 (en) * 2007-07-20 2013-06-27 Sicpa Holding Sa Intaglio printing inks
DE102008058397A1 (de) * 2008-11-21 2010-05-27 Giesecke & Devrient Gmbh Wertdokument mit matten und glänzenden Oberflächenbereichen und Verfahren zu seiner Herstellung
AR090178A1 (es) * 2012-03-23 2014-10-22 Sicpa Holding Sa Metodo de impresion con tinta calcografica de secado por oxidacion y tintas calcograficas curables por uv-vis

Also Published As

Publication number Publication date
ZA201408152B (en) 2015-11-25
MX2014014369A (es) 2015-02-05
HK1201234A1 (en) 2015-08-28
CA2870463A1 (fr) 2013-12-05
DE102012010534A1 (de) 2013-12-05
CN104321199A (zh) 2015-01-28
EP2888112A2 (fr) 2015-07-01
WO2013178325A3 (fr) 2014-04-24
MX359340B (es) 2018-09-26
WO2013178325A2 (fr) 2013-12-05
CA2870463C (fr) 2017-04-18
CN104321199B (zh) 2016-11-23
BR112014029183A2 (pt) 2017-06-27

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