EP2885220A1 - Emballage hydrosoluble doté d'un agent amérisant - Google Patents
Emballage hydrosoluble doté d'un agent amérisantInfo
- Publication number
- EP2885220A1 EP2885220A1 EP13742658.1A EP13742658A EP2885220A1 EP 2885220 A1 EP2885220 A1 EP 2885220A1 EP 13742658 A EP13742658 A EP 13742658A EP 2885220 A1 EP2885220 A1 EP 2885220A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- water
- soluble
- bitter
- agent
- cavity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- DBOVHQOUSDWAPQ-WTONXPSSSA-N amarogentin Chemical compound O([C@H]1[C@H](O[C@H]2[C@@H]([C@H]3C(C(OCC3)=O)=CO2)C=C)O[C@@H]([C@H]([C@@H]1O)O)CO)C(=O)C1=C(O)C=C(O)C=C1C1=CC=CC(O)=C1 DBOVHQOUSDWAPQ-WTONXPSSSA-N 0.000 description 1
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- 235000003704 aspartic acid Nutrition 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- RJWJHRPNHPHBRN-FKVJWERZSA-N aucubin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@H]1[C@@H]2C(CO)=C[C@@H](O)[C@@H]2C=CO1 RJWJHRPNHPHBRN-FKVJWERZSA-N 0.000 description 1
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- 229960001948 caffeine Drugs 0.000 description 1
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- ZTDFZLVUIVPZDU-BSDSXHPESA-N cnicin Natural products CC1=C/CCC(=C[C@H]2OC(=O)C(=C)[C@@H]2[C@@H](C1)OC(=O)C(=C)[C@@H](O)CO)CO ZTDFZLVUIVPZDU-BSDSXHPESA-N 0.000 description 1
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- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000012217 deletion Methods 0.000 description 1
- 230000037430 deletion Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000010017 direct printing Methods 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 229930003935 flavonoid Natural products 0.000 description 1
- 150000002215 flavonoids Chemical class 0.000 description 1
- 235000017173 flavonoids Nutrition 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 description 1
- 229930182489 iridoid glycoside Natural products 0.000 description 1
- 150000008145 iridoid glycosides Chemical class 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- MWDZOUNAPSSOEL-UHFFFAOYSA-N kaempferol Natural products OC1=C(C(=O)c2cc(O)cc(O)c2O1)c3ccc(O)cc3 MWDZOUNAPSSOEL-UHFFFAOYSA-N 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- VJQAFLAZRVKAKM-QQUHWDOBSA-N lactucin Chemical compound O[C@@H]1CC(C)=C2C(=O)C=C(CO)[C@@H]2[C@H]2OC(=O)C(=C)[C@@H]21 VJQAFLAZRVKAKM-QQUHWDOBSA-N 0.000 description 1
- VJQAFLAZRVKAKM-UHFFFAOYSA-N lactucine Natural products OC1CC(C)=C2C(=O)C=C(CO)C2C2OC(=O)C(=C)C21 VJQAFLAZRVKAKM-UHFFFAOYSA-N 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- KBDSLGBFQAGHBE-MSGMIQHVSA-N limonin Chemical compound C=1([C@H]2[C@]3(C)CC[C@H]4[C@@]([C@@]53O[C@@H]5C(=O)O2)(C)C(=O)C[C@@H]2[C@]34COC(=O)C[C@@H]3OC2(C)C)C=COC=1 KBDSLGBFQAGHBE-MSGMIQHVSA-N 0.000 description 1
- 150000002630 limonoids Chemical class 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- HQLLRHCTVDVUJB-UHFFFAOYSA-N marrubin Chemical compound CC1CC(C23)OC(=O)C3(C)CCCC2(C)C1(O)CCC=1C=COC=1 HQLLRHCTVDVUJB-UHFFFAOYSA-N 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 229930182817 methionine Natural products 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229930003658 monoterpene Natural products 0.000 description 1
- 235000002577 monoterpenes Nutrition 0.000 description 1
- 239000006199 nebulizer Substances 0.000 description 1
- KPDOJFFZKAUIOE-WNGDLQANSA-N nomilin Chemical compound C=1([C@H]2[C@]3(C)CC[C@H]4[C@@]([C@@]53O[C@@H]5C(=O)O2)(C)C(=O)C[C@H]2C(C)(C)OC(=O)C[C@@H]([C@]42C)OC(=O)C)C=COC=1 KPDOJFFZKAUIOE-WNGDLQANSA-N 0.000 description 1
- KPDOJFFZKAUIOE-HPFWCIFASA-N nomilin Natural products O=C(O[C@H]1[C@@]2(C)[C@@H](C(C)(C)OC(=O)C1)CC(=O)[C@]1(C)[C@@H]2CC[C@@]2(C)[C@H](c3cocc3)OC(=O)[C@@H]3O[C@@]123)C KPDOJFFZKAUIOE-HPFWCIFASA-N 0.000 description 1
- VSLDMVSILHVDSR-UHFFFAOYSA-N obacunone Natural products CC1(C)OC(=O)C=CC2(C)C1CC(=O)C3(C)C2CCC4(C)C(OC(=O)C5OC345)c6occc6 VSLDMVSILHVDSR-UHFFFAOYSA-N 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
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- 230000002688 persistence Effects 0.000 description 1
- COLNVLDHVKWLRT-UHFFFAOYSA-N phenylalanine Natural products OC(=O)C(N)CC1=CC=CC=C1 COLNVLDHVKWLRT-UHFFFAOYSA-N 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
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- 229920000570 polyether Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000011970 polystyrene sulfonate Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- IOSXSVZRTUWBHC-UHFFFAOYSA-N quassin Natural products C1C(C23C)OC(=O)CC3C(C)=C(OC)C(=O)C2C2(C)C1C(C)C=C(OC)C2=O IOSXSVZRTUWBHC-UHFFFAOYSA-N 0.000 description 1
- 229960001285 quercetin Drugs 0.000 description 1
- 235000005875 quercetin Nutrition 0.000 description 1
- 229960002522 quinine dihydrochloride Drugs 0.000 description 1
- RONWGALEIBILOG-VMJVVOMYSA-N quinine sulfate Chemical compound [H+].[H+].[O-]S([O-])(=O)=O.C([C@H]([C@H](C1)C=C)C2)C[N@@]1[C@@H]2[C@H](O)C1=CC=NC2=CC=C(OC)C=C21.C([C@H]([C@H](C1)C=C)C2)C[N@@]1[C@@H]2[C@H](O)C1=CC=NC2=CC=C(OC)C=C21 RONWGALEIBILOG-VMJVVOMYSA-N 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000024053 secondary metabolic process Effects 0.000 description 1
- 230000014860 sensory perception of taste Effects 0.000 description 1
- RXHIKAIVEMAPRU-JRIGQVHBSA-N sequiterpene Natural products C1=C(C)[C@@H](OC(C)=O)[C@H](O)[C@@]2(O)[C@H](C)CC[C@@H](C(C)=C)[C@H]21 RXHIKAIVEMAPRU-JRIGQVHBSA-N 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- 239000013042 solid detergent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 230000009747 swallowing Effects 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- VSJGJMKGNMDJCI-QXSNVGMTSA-N sweroside Natural products OC[C@H]1O[C@H](O[C@@H]2OC=C3[C@@H](CCOC3=O)[C@H]2C=C)[C@H](O)[C@@H](O)[C@@H]1O VSJGJMKGNMDJCI-QXSNVGMTSA-N 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 210000001779 taste bud Anatomy 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 150000003597 thujone derivatives Chemical class 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
- 239000004474 valine Substances 0.000 description 1
- USMNOWBWPHYOEA-MRTMQBJTSA-N α-thujone Chemical compound O=C([C@@H]1C)C[C@@]2(C(C)C)[C@@H]1C2 USMNOWBWPHYOEA-MRTMQBJTSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
- B65D65/38—Packaging materials of special type or form
- B65D65/46—Applications of disintegrable, dissolvable or edible materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B9/00—Enclosing successive articles, or quantities of material, e.g. liquids or semiliquids, in flat, folded, or tubular webs of flexible sheet material; Subdividing filled flexible tubes to form packages
- B65B9/02—Enclosing successive articles, or quantities of material between opposed webs
- B65B9/04—Enclosing successive articles, or quantities of material between opposed webs one or both webs being formed with pockets for the reception of the articles, or of the quantities of material
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/045—Multi-compartment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2215/00—Child-proof means
Definitions
- the invention relates to a water-soluble packaging comprising an agent and a water-soluble coating.
- the invention also relates to a process for producing a water-soluble packaging.
- Liquids, gels or sachets (tablets or filled bags).
- portion packs in the form of water-soluble packaging with liquid detergents or cleaning agents are becoming increasingly popular, on the one hand meeting the consumer's desire for simplified dosing and, on the other hand, increasingly preferring more
- Such a water-soluble bag contains an agent and a transparent, water-soluble wrapper.
- Denatonium benzoate is considered the bitterest known substance and has a bitter value greater than 100,000,000.
- a disadvantage of coating a water-soluble packaging with Bitrex® is that the users of the water-soluble packaging take the packaging for dosing into their hands and thus also come into contact with the Bitrex®. If a user, after touching the water-soluble packaging, puts his hand in the direction of the mouth, small amounts of Bitrex® remaining in the hand are enough to negatively affect the sense of taste for a few hours.
- the object of the invention is therefore to provide water-soluble packaging with high child safety, but without negative effects in normal use.
- a water-soluble packaging containing an agent and a water-soluble coating in which the water-soluble coating at least partially a bittering agent having a bitter value between 1 .000 and 200,000, solved. It has surprisingly been found that bitter substances with these bitterness values have a sufficiently high bitter taste to prevent children from keeping a water-soluble package with this bitter substance in or on the mouth, but at regular intervals
- water-soluble packaging are not so bitter that a residue of a bitter residue left on the hand in the event of accidental contact of the hand with the mouth irritates the taste buds of the user strongly and unpleasantly for a long period of time.
- the invention relates to a water-soluble packaging containing an agent and a
- the water-soluble wrapper contains water-soluble coating.
- the water-soluble wrapper has at least partially a bittering agent having a bitter value between 1,000 and 200,000.
- a water-soluble package contains a water-soluble envelope which forms a closed structure having in its interior one or more chambers for receiving one or more agents.
- the water-soluble coating is preferably by a
- the water-soluble packaging may be dimensionally stable or deformable.
- the water-soluble packaging may be formed as a dimensionally stable container, for example in the form of a capsule, box, box or container.
- the water-soluble packaging in principle it is also possible and preferred to mold the water-soluble packaging as a non-dimensionally stable container, for example as a bag.
- the shape of such a water-soluble packaging can be largely adapted to the conditions of use.
- various forms such as hoses, pillows, cylinders, bottles or discs in question.
- the water soluble package may include one or more chambers for storing one or more agents.
- the water-soluble packaging preferably has between two and five chambers.
- the water-soluble casing is preferably made of a water-soluble film material, which is selected from the group consisting of polymers or polymer mixtures formed.
- the wrapper may be formed of one or two or more layers of the water-soluble film material.
- the water-soluble film material of the first layer and the further layers, if present, may be the same or different. Particularly preferred are films which, for example, can be glued and / or sealed to packages such as hoses or cushions after being filled with an agent.
- the water-soluble coating be polyvinyl alcohol or a
- Water-soluble coatings containing polyvinyl alcohol or a polyvinyl alcohol copolymer have a good stability with a sufficiently high water solubility, in particular cold water solubility on.
- Suitable water-soluble films for producing the water-soluble coating are preferably based on a polyvinyl alcohol or a polyvinyl alcohol copolymer whose
- Molecular weight in the range of 10,000 to 1,000,000 gmol “1 , preferably from 20,000 to 500,000 gmol “ 1 , more preferably from 30,000 to 100,000 gmol “1 and in particular from 40,000 to 80,000 gmol “ 1 .
- polyvinyl alcohol is usually carried out by hydrolysis of polyvinyl acetate, since the direct synthesis route is not possible.
- polyvinyl alcohol copolymers which are prepared from correspondingly polyvinyl acetate copolymers. It is preferred if at least one layer of the water-soluble coating comprises a polyvinyl alcohol whose degree of hydrolysis makes up 70 to 100 mol%, preferably 80 to 90 mol%, particularly preferably 81 to 89 mol% and in particular 82 to 88 mol%.
- a polymer selected from the group comprising a polyvinyl alcohol-containing sheet material suitable for producing the water-soluble sheath is selected from the group comprising a polyvinyl alcohol-containing sheet material suitable for producing the water-soluble sheath
- (Meth) acrylic acid-containing (co) polymers polyacrylamides, oxazoline polymers, polystyrene sulfonates, polyurethanes, polyesters, polyethers, polylactic acid or mixtures of the above polymers may be added.
- a preferred additional polymer is polylactic acids.
- Preferred polyvinyl alcohol copolymers include, in addition to vinyl alcohol, dicarboxylic acids as further monomers.
- Suitable dicarboxylic acids are itaconic acid, malonic acid, succinic acid and
- polyvinyl alcohol copolymers include, in addition to vinyl alcohol, an ethylenically unsaturated carboxylic acid, its salt or its esters.
- Such polyvinyl alcohol copolymers particularly preferably contain, in addition to vinyl alcohol, acrylic acid, methacrylic acid, acrylates, methacrylates or mixtures thereof. It may be preferred that the film material contains further additives.
- the film material may include, for example, plasticizers such as dipropylene glycol, ethylene glycol, diethylene glycol,
- Additives include, for example, release aids, fillers, crosslinking agents, surfactants, antioxidants, UV absorbers, antiblocking agents, detackifiers, or mixtures thereof.
- water-soluble packaging according to the invention are films marketed by MonoSol LLC, for example under the designation M8630, C8400 or M8900.
- Other suitable films include films named Solublon® PT, Solublon® GA, Solublon® KC or Solublon® KL from Aicello Chemical Europe GmbH or the films VF-HP from Kuraray.
- the water-soluble wrapper has at least partially a bittering agent having a bitter value between 1,000 and 200,000.
- the bittering agent having a bitter value of between 1,000 and 200,000 may be applied, for example, to the outer surface of the water-soluble wrapper or contained in the water-soluble wrapper.
- the outer surface of the water-soluble casing is at least partially coated with a bittering agent having a bitter value between 1,000 and 200,000.
- a bittering agent having a bitter value between 1,000 and 200,000.
- the water-soluble coating is coated with at least 50%, preferably at least 75%, and most preferably at least 90%, with the bittering agent having a bitter value between 1,000 and 200,000.
- bittering agent with a bitter value between 1,000 and 200,000 can be used.
- any form of printing can be used to print the water-soluble wrapper, such as gravure, offset, screen, flexo, airbrush, inkjet or pad printing, or any combination of these printing technologies.
- Printing by means of ink-jet printing preferably takes place since no mechanical contact with and thus no mechanical loading of the water-soluble coating occurs with this printing technology. The same applies to direct printing with piezo technology, as it also takes place without contact.
- the printing medium which is applied to the water-soluble coating, contain other ingredients, such as a coloring substance.
- the bittering agent having a bitter value of between 1,000 and 200,000 may be painted on the outer wrapper by means of a brush, roller or the like.
- the bittering agent is sprayed with a bitter value between 1,000 and 200,000 by means of an atomizer.
- the application of the bittering agent with a bitter value between 1,000 and 200,000 may take place in the form of surfaces, so that the water-soluble coating is at least partially covered with a bitter substance having a bitter value between 1,000 and 200,000.
- the application of the bittering agent having a bitter value between 1,000 and 200,000 may be in the form of letters, numbers, symbols, ornaments or the like. The latter is particularly preferred when the bittering agent having a bitter value between 1 .000 and 200,000 is applied by means of printing and the printing medium contains, in addition to the bittering agent having a bitter value between 1 .000 and 200,000, a coloring substance.
- the bittering agent having a bitterness value of between 1, 000 and 200,000 may be incorporated into the film material of
- the bitter substance has a bitter value between 1 .000 and 200,000.
- the bitterness is the inverse of the dilution of a substance, a liquid or an extract that just tastes bitter.
- Suitable bitter substances with a bitter value between 1,000 and 200,000 which in the
- Foil material for producing the water-soluble wrapper or may be applied to the outer surface of the water-soluble wrapper are preferably natural bittering agents having a bitter value of between 1,000 and 200,000. Particularly preferred are the natural bittering agents with a bitter value between 1,000 and 200,000 selected from the Group consisting of glycosides, isoprenoids, alkaloids, amino acids and mixtures thereof.
- Glycosides are organic compounds of the general structure R-O-Z, in which an alcohol (R-OH) is connected via a glycosidic bond with a sugar moiety (Z).
- Suitable glycosides are, for example, flavonoids such as quercetin or naringin or
- Iridoid glycosides such as aucubin and especially seccoidoid glycosides such as amarogentin,
- Isoprenoids are compounds that formally derive from isoprene. Examples are in particular terpenes and terpenoids.
- Suitable isoprenoids include, for example, sequiterpene lactones such as absinthin, artabsin, cnicin, lactucin, lactucopikrin or salzolidideolide, monoterpene ketones (thujones) such as
- ⁇ -thujone or ⁇ -thujone tetranortriterpenes (limonoids) such as desoxylimones, deoxylmonic acid, limonin, ichangine, isobaconic acid, obacunone, obacunonic acid, nomilin or nomilinic acid, terpenes such as marrubin, premarubin, carnosol, carnosic acid or quassin.
- limonoids such as desoxylimones, deoxylmonic acid, limonin, ichangine, isobaconic acid, obacunone, obacunonic acid, nomilin or nomilinic acid, terpenes such as marrubin, premarubin, carnosol, carnosic acid or quassin.
- Alkaloids refer to naturally occurring, chemically heterogeneous, mostly alkaline, nitrogen-containing organic compounds of secondary metabolism which act on the animal or human organism.
- Suitable alkaloids are, for example, quinine hydrochloride, quinine hydrogen sulfate,
- Suitable amino acids include, for example, threonine, methionine, phenylalanine, tryptophan, arginine, histidine, valine and aspartic acid.
- Particularly preferred bitter substances having a bitter value between 1,000 and 200,000 are
- bittering agent may be advantageous because humans have a different number of taste cells on the tongue. In addition to so-called super-tasters and normal gourmets, there are also so-called non-gourmets, the individual bitter substances do not taste or slightly.
- the amount of bittering agent having a bitter value between 1,000 and 200,000 depends in particular on the desired intensity of the bitter taste. If the bittering agent is contained in the water-soluble coating, the amount of bittering agent is between 1 and 30 g per m 2 surface of the water-soluble coating. When the bittering agent is applied to the outer surface of the water-soluble wrapper, the amount of the bittering agent is from 1 to 30 g per m 2 of the coated surface of the water-soluble wrapper.
- water-soluble envelope the surface which is in contact with the means enclosed by the water-soluble wrapper, and accordingly, the term" outer surface of the water-soluble wrapper "designates the surface facing away from the means enclosed by the water-soluble wrapper.
- the water-soluble packaging has a means.
- this agent may be a solid agent and may comprise a powder, granules or tablet.
- the agent may be a liquid agent and may comprise a gel or a liquid.
- the agent is a liquid or solid wash or
- the water soluble package has a chamber for containing the agent.
- the agent in this embodiment may preferably comprise a powder, a granule, a gel or a liquid.
- the water-soluble packaging has two chambers.
- the first chamber preferably contains a liquid agent and the second chamber contains a solid or a liquid agent.
- both chambers may contain a fixed average.
- the water-soluble packaging may each contain a liquid or a solid agent. But it is also possible that one chamber contains a solid medium and two chambers a liquid medium. In addition, it is possible for a solid agent to be contained in two chambers and a liquid agent in a chamber.
- the agents contained in the different chambers of a water-soluble package may have the same composition.
- the agents in a water-soluble package having at least two chambers have compositions that are at least one ingredient or at least content of an ingredient
- the agent contains ingredients that do not destroy the structural integrity of the water-soluble wrapper. If the agent used is a liquid or solid washing or cleaning agent, it may contain one or more substances from the group of surfactants, builders, bleaching agents,
- Bleach activators bleach catalysts, enzymes, enzyme stabilizers, electrolytes, pH adjusters, perfumes, perfume carriers, fluorescers, dyes, hydrotopes, foam inhibitors, silicone oils, antiredeposition agents, grayness inhibitors, anti-shrinkage agents, anti-crease agents,
- Color transfer inhibitors antimicrobial agents, non-aqueous solvents, germicides, fungicides, antioxidants, preservatives, corrosion inhibitors, antistatic agents, bittering agents, ironing auxiliaries, repellents and impregnating agents, opacifiers, skin-care active ingredients, swelling and anti-slip agents, plasticizing components, fillers and UV stabilizers.
- Absorber included.
- the liquid detergents or cleaners may contain water, the content of water being less than 14% by weight and more preferably less than 9% by weight, based in each case on the total liquid washing or cleaning agent.
- the preparation of a water-soluble packaging may include the following steps:
- the bittering agent having a bitter value between 1,000 and 200,000 may be at least partially contained in the first water-soluble film (web).
- the bittering agent having a bitter value of between 1,000 and 200,000 may be at least partially contained in the second water-soluble film (web).
- an object of the application is a method for producing a
- water-soluble packaging containing an agent and a water-soluble coating having, at least in part, a bitter substance having a bitter value between 1,000 and 200,000, comprising the steps:
- bittering agent having a bitter value between 1,000 and 200,000 is contained in the first and / or second water-soluble film web.
- step c) is followed by a further process step d) which comprises at least partially coating the outer surface of the water-soluble casing with a medium containing a bitter substance having a bitter value between 1,000 and 200,000 , includes.
- step d) can be repeated as often as desired so that a plurality of identical or different coated regions are formed on the outer surface of the water-soluble casing.
- the coating can be done for example by means of printing, spraying or brushing.
- a further subject of the invention is therefore a process for the preparation of a water-soluble packaging which contains an agent and a water-soluble coating comprising at least partly a bitter substance having a bitter value of between 1,000 and 200,000, comprising the steps:
- the films used in this embodiment may be free of bittering agent having a bitter value between 1,000 and 200,000, but may also contain one or more bittering agents having a bittering value of between 1,000 and 200,000.
- the coating of the first water-soluble film with the bittering agent is carried out with a bitter value between 1,000 and 200,000 before the formation of the cavity.
- the second water-soluble film is coated with the bitter substance having a bitter value between 1 .000 and 200,000 prior to closing the cavity filled with the agent.
- a further subject of the application is therefore a process for the preparation of a water-soluble packaging which contains an agent and a water-soluble coating having, at least in part, a bitter substance with a bitter value of between 1,000 and 200,000, comprising the steps:
- Yet another object of the invention is a process for the preparation of a
- water-soluble packaging containing an agent and a water-soluble coating having, at least in part, a bitter substance having a bitter value between 1,000 and 200,000, comprising the steps:
- the coating of the water-soluble film web during the preparation of the water-soluble packages is carried out such that the bittering agent having a bitter value between 1 .000 and 200,000 is on the outer surface of the water-soluble coating.
- Packaging is that the coating is individualized, that is according to the
- the coating process may optionally be followed by a drying process in which by bubbling or overblowing tempered gas or irradiating with infrared light that contained in the medium containing the bitter substance with a bitter value between 1,000 and 200,000 Solvent evaporates / removes.
- the bittering agent having a bitter value of between 1,000 and 200,000 is added to the film material.
- a water-soluble polymer which preferably contains polyvinyl alcohol or a polyvinyl alcohol copolymer, alone or in combination with at least one other water-soluble polymer, a solvent, the bittering agent having a bitter value between 1,000 and 200,000 and optionally further additives a matrix is combined, (b) a film is formed from the matrix, and (c) the film is dried to a water-soluble film having, at least in part, a bitter substance having a bitterness value between 1,000 and 200,000.
- the formation of the film can be done, for example, by means of casting and Schwarzutzwalzenstichs.
- a film at least partially having a bittering value of between 1,000 and 200,000 may be obtained in which (a) a water-soluble polymer, preferably containing polyvinyl alcohol or a polyvinyl alcohol copolymer, alone or in combination with at least one other water-soluble polymer, a solvent, the bitter substance having a bitter value between 1,000 and 200,000 and optionally further additives is combined into a matrix; and (b) by extrusion of the matrix, a water-soluble film having, at least partially, a bitter substance having a bitter value of between 1,000 and 200,000 is obtained.
- a liquid detergent or cleaning agent was first prepared by conventional methods and methods. Table 1 below shows the composition of a liquid washing or cleaning agent E1.
- Cleaning agent E1 was a film of type M 8630 (ex Monosol) with a thickness of 76 ⁇ pulled to form a bulge by means of vacuum in a trough. Subsequently, the bulge was filled with 30 ml of the liquid detergent or cleaning agent E1. After covering the filled with the agent bulges with a second layer of a film containing polyvinyl alcohol, polylactic acid, 1, 2-propanediol and glycerol and has a thickness of 76 ⁇ , the first and second layers were sealed together. The sealing temperature was 150 ° C and the sealing time 1, 1 seconds.
- the entire outer surface of the water-soluble package was uniformly sprayed on both sides by means of a nebulizer with a sucrose octaacetate-containing aqueous medium.
- the amount of sucrose octaacetate per water-soluble package was 2000 ppm.
- the liquid was absorbed within 5 seconds by the water-soluble coating.
- Detergent E1 was a first layer of a film containing polyvinyl alcohol, polylactic acid, sucrose octaactetate, 1, 2-propanediol and glycerol, drawn with a thickness of 76 ⁇ to form a bulge by means of vacuum in a trough. Subsequently, the bulge was filled with 30 ml of the liquid detergent or cleaning agent E1. After covering the bulge filled with the agent with a second layer of a film containing polyvinyl alcohol, polylactic acid, sucrose octaactate, 1, 2-propanediol and glycerol and has a thickness of 76 ⁇ , the first and second layer were sealed together. The sealing temperature was 150 ° C and the sealing time was 1, 1 second. The first and second film webs each contained sucrose octaacetate in an amount of 2000 ppm.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Wrappers (AREA)
- Packages (AREA)
Abstract
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL13742658T PL2885220T3 (pl) | 2012-08-16 | 2013-08-01 | Rozpuszczalne w wodzie opakowanie z substancją gorzką |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102012214607.5A DE102012214607A1 (de) | 2012-08-16 | 2012-08-16 | Wasserlösliche Verpackung mit Bittermittel I |
PCT/EP2013/066199 WO2014026855A1 (fr) | 2012-08-16 | 2013-08-01 | Emballage hydrosoluble doté d'un agent amérisant |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2885220A1 true EP2885220A1 (fr) | 2015-06-24 |
EP2885220B1 EP2885220B1 (fr) | 2016-11-16 |
Family
ID=48906271
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP13742658.1A Active EP2885220B1 (fr) | 2012-08-16 | 2013-08-01 | Emballage hydrosoluble doté d'un agent amérisant |
Country Status (8)
Country | Link |
---|---|
US (2) | US20150158645A1 (fr) |
EP (1) | EP2885220B1 (fr) |
JP (1) | JP6181759B2 (fr) |
DE (1) | DE102012214607A1 (fr) |
ES (1) | ES2613406T3 (fr) |
HU (1) | HUE033109T2 (fr) |
PL (1) | PL2885220T3 (fr) |
WO (1) | WO2014026855A1 (fr) |
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DE102017223460A1 (de) | 2017-12-20 | 2019-06-27 | Henkel Ag & Co. Kgaa | Viskoselastische, festförmige Tensidzusammensetzung mit hohem Tensidgehalt |
DE102018201830A1 (de) | 2018-02-06 | 2019-08-08 | Henkel Ag & Co. Kgaa | Viskoelastische, festförmige Tensidzusammensetzung |
WO2020074144A1 (fr) | 2018-10-11 | 2020-04-16 | Henkel Ag & Co. Kgaa | Composition liquide comportant un composé de diamide d'acide dihydroxytéréphtalique et une quantité élevée de tensioactif |
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CA2940705A1 (fr) * | 2014-03-07 | 2015-09-11 | The Procter & Gamble Company | Compositions comprenant un amerisant |
EP3114201A1 (fr) * | 2014-03-07 | 2017-01-11 | The Procter & Gamble Company | Compositions comprenant un agent d'amertume |
WO2015134829A1 (fr) | 2014-03-07 | 2015-09-11 | The Procter & Gamble Company | Compositions comprenant un agent piquant |
US9873558B2 (en) | 2015-02-26 | 2018-01-23 | Monosol, Llc | Multi-dose cleaning product and method of manufacture |
US9828154B2 (en) | 2015-02-27 | 2017-11-28 | Monosol, Llc | Web of cleaning products and method of manufacture |
WO2017025255A1 (fr) * | 2015-08-11 | 2017-02-16 | Unilever Plc | Emballage hydrosoluble |
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CN109475890A (zh) * | 2016-08-05 | 2019-03-15 | 荷兰联合利华有限公司 | 服装清新中及与其相关的改进 |
EP3327107B1 (fr) | 2016-11-25 | 2021-04-07 | Henkel AG & Co. KGaA | Nettoyants pour surfaces dures contenant des particules abrasives |
CA3047813A1 (fr) | 2017-01-04 | 2018-07-12 | Church & Dwight Co., Inc. | Systeme et procede associes destines a la formation d'un emballage a chambres multiples |
DE102017210143A1 (de) | 2017-06-16 | 2018-12-20 | Henkel Ag & Co. Kgaa | Viskoelastische, festförmige Tensidzusammensetzung |
DE102017210141A1 (de) | 2017-06-16 | 2018-12-20 | Henkel Ag & Co. Kgaa | Portion zur Bereitstellung tensidhaltiger Flotten |
EP3399011B1 (fr) | 2017-05-04 | 2020-11-18 | Henkel AG & Co. KGaA | Compositions appropriées pour le nettoyage de toilettes comprenant des liants non hydrauliques |
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US11807834B2 (en) | 2017-10-13 | 2023-11-07 | Conopco, Inc. | Aqueous spray composition |
WO2019072647A1 (fr) | 2017-10-13 | 2019-04-18 | Unilever Plc | Composition de pulvérisation aqueuse |
US11987771B2 (en) | 2017-10-13 | 2024-05-21 | Conopco, Inc. | Fabric spray composition comprising a non-functionalized silicone nanoemulsion and peg-40 hydrogenated castor oil |
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EP3498812B1 (fr) | 2017-12-14 | 2020-06-17 | The Procter & Gamble Company | Films et articles en dose unitaire comprenant des agents répulsifs uv, utilisations et procédés associés |
DE102018221671A1 (de) | 2018-12-13 | 2020-06-18 | Henkel Ag & Co. Kgaa | Vorrichtung und Verfahren zur Herstellung einer wasserlöslichen Hülle sowie diese wasserlösliche Hülle enthaltene Wasch- oder Reinigungsmittelportionen mit viskoelastischer, festförmiger Füllsubstanz |
DE102018221674A1 (de) | 2018-12-13 | 2020-06-18 | Henkel Ag & Co. Kgaa | Vorrichtung und Verfahren zur Herstellung einer wasserlöslichen Hülle sowie diese wasserlösliche Hülle enthaltene Wasch- oder Reinigungsmittelportionen |
US20220127488A1 (en) * | 2019-02-06 | 2022-04-28 | Monosol, Llc | Water-soluble coatings for substrate surfaces |
EP3712237A1 (fr) | 2019-03-19 | 2020-09-23 | The Procter & Gamble Company | Articles fibreux de dose unitaire soluble dans l'eau comprenant des structures fibreuses solubles dans l'eau |
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2012
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2013
- 2013-08-01 EP EP13742658.1A patent/EP2885220B1/fr active Active
- 2013-08-01 ES ES13742658.1T patent/ES2613406T3/es active Active
- 2013-08-01 PL PL13742658T patent/PL2885220T3/pl unknown
- 2013-08-01 WO PCT/EP2013/066199 patent/WO2014026855A1/fr active Application Filing
- 2013-08-01 HU HUE13742658A patent/HUE033109T2/hu unknown
- 2013-08-01 JP JP2015526923A patent/JP6181759B2/ja active Active
-
2015
- 2015-02-13 US US14/621,429 patent/US20150158645A1/en not_active Abandoned
-
2019
- 2019-02-01 US US16/265,820 patent/US20190168938A1/en not_active Abandoned
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102017223456A1 (de) | 2017-12-20 | 2019-06-27 | Henkel Ag & Co. Kgaa | Viskoelastische, festförmige Tensidzusammensetzung mit hohem Tensidgehalt |
DE102017223460A1 (de) | 2017-12-20 | 2019-06-27 | Henkel Ag & Co. Kgaa | Viskoselastische, festförmige Tensidzusammensetzung mit hohem Tensidgehalt |
DE102018201830A1 (de) | 2018-02-06 | 2019-08-08 | Henkel Ag & Co. Kgaa | Viskoelastische, festförmige Tensidzusammensetzung |
WO2020074144A1 (fr) | 2018-10-11 | 2020-04-16 | Henkel Ag & Co. Kgaa | Composition liquide comportant un composé de diamide d'acide dihydroxytéréphtalique et une quantité élevée de tensioactif |
Also Published As
Publication number | Publication date |
---|---|
JP6181759B2 (ja) | 2017-08-16 |
US20150158645A1 (en) | 2015-06-11 |
PL2885220T3 (pl) | 2017-05-31 |
EP2885220B1 (fr) | 2016-11-16 |
WO2014026855A1 (fr) | 2014-02-20 |
JP2015528425A (ja) | 2015-09-28 |
US20190168938A1 (en) | 2019-06-06 |
ES2613406T3 (es) | 2017-05-24 |
DE102012214607A1 (de) | 2014-02-20 |
HUE033109T2 (hu) | 2017-11-28 |
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