EP2880198B1 - Verfahren zur metallisierung eines kraftfahrzeugsteil - Google Patents

Verfahren zur metallisierung eines kraftfahrzeugsteil Download PDF

Info

Publication number
EP2880198B1
EP2880198B1 EP13756653.5A EP13756653A EP2880198B1 EP 2880198 B1 EP2880198 B1 EP 2880198B1 EP 13756653 A EP13756653 A EP 13756653A EP 2880198 B1 EP2880198 B1 EP 2880198B1
Authority
EP
European Patent Office
Prior art keywords
solution
activation
activation solution
spraying
projection
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP13756653.5A
Other languages
English (en)
French (fr)
Other versions
EP2880198A1 (de
Inventor
Sophie Vidal
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Plastic Omnium SE
Original Assignee
Plastic Omnium SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Plastic Omnium SE filed Critical Plastic Omnium SE
Publication of EP2880198A1 publication Critical patent/EP2880198A1/de
Application granted granted Critical
Publication of EP2880198B1 publication Critical patent/EP2880198B1/de
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601—Process or apparatus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B13/00—Machines or plants for applying liquids or other fluent materials to surfaces of objects or other work by spraying, not covered by groups B05B1/00 - B05B11/00
    • B05B13/02—Means for supporting work; Arrangement or mounting of spray heads; Adaptation or arrangement of means for feeding work
    • B05B13/0221—Means for supporting work; Arrangement or mounting of spray heads; Adaptation or arrangement of means for feeding work characterised by the means for moving or conveying the objects or other work, e.g. conveyor belts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B13/00—Machines or plants for applying liquids or other fluent materials to surfaces of objects or other work by spraying, not covered by groups B05B1/00 - B05B11/00
    • B05B13/02—Means for supporting work; Arrangement or mounting of spray heads; Adaptation or arrangement of means for feeding work
    • B05B13/0221—Means for supporting work; Arrangement or mounting of spray heads; Adaptation or arrangement of means for feeding work characterised by the means for moving or conveying the objects or other work, e.g. conveyor belts
    • B05B13/0228—Means for supporting work; Arrangement or mounting of spray heads; Adaptation or arrangement of means for feeding work characterised by the means for moving or conveying the objects or other work, e.g. conveyor belts the movement of the objects being rotative
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B14/00—Arrangements for collecting, re-using or eliminating excess spraying material
    • B05B14/40—Arrangements for collecting, re-using or eliminating excess spraying material for use in spray booths

Definitions

  • the present invention relates to the metallization of a bodywork part for a motor vehicle, in particular a part comprising plastics material.
  • This type of process is particularly called electroless metallization process. It is thus distinguished from metallization implemented using an electric current, such as electroplating chrome plating, during which electrochemical deposition of chromium is performed. This chromium plating process is generally expensive and polluting.
  • the metal salt spraying step also known as the spraying step, is generally preceded by a step of activating the surface of the part to be metallized, by spraying an activation solution.
  • a number of solutions are projected onto the part, which are subsequently recovered with a view to their subsequent elimination.
  • the purpose of the invention is in particular to reduce the costs and the environmental impact of the metallization process.
  • the second piece is a separate part of the first piece, that is to say, it is another piece, which may be of identical shape or different from the first piece. This increases the number of parts that can be treated, or the number of successive uses (applications, sprinkles), with a given volume of activation solution and reduces the volume of activation solution to be removed for a given number of processed parts.
  • the remaining activation solution can be recovered more easily, by flow or by runoff.
  • the solution may in particular run off on walls of the enclosure or run off the surface of the part towards, for example, the bottom of the enclosure where it is recovered.
  • the chamber may not be hermetically closed.
  • the enclosure may include openings when little (or no) activating product reaches these openings and leaves the enclosure without being recovered.
  • the remaining solution of activation solution is recovered at the bottom of the chamber, by gravity.
  • the recovered solution can then be stored in a temporary storage tank before being used to project it back onto the workpiece or project it onto a second workpiece.
  • the recovered solution can be projected again on the first piece of anterior manner, simultaneous or posterior to the projection on a second piece.
  • the storage tank supplies at the same time in recovered solution several closed enclosures.
  • the non-electrolytic metallization process generally comprises, before the projection of activating solution and metal salts, a preliminary step of depositing a varnish, also called “basecoat” or primary, thus making it possible to metallize on any type of part, in particular on a part comprising plastic material.
  • the projection step of the activation solution can be followed by a rinsing step before the step of applying the metal salts.
  • the projection of metal salts is preferably followed by a step of depositing a protective varnish, also called "topcoat”.
  • activation solution or "activating product solution” is generally understood to mean a solution capable of modifying the state of the surface of the part so as to promote the initiation of an oxidation-reduction reaction and the hangs the metal particles projected later in the solution of metal salts.
  • the activation solution can activate the surface of the part by deposit, reaction, grafting of an active product to promote the deposit resulting from the subsequent spraying of metal salts.
  • the entire activation solution does not necessarily react with the surface of the room so that it is reusable, hence the recovery that can be implemented.
  • the physical properties of the activation solution such as the viscosity or evaporation rate, remain substantially constant throughout the process, so that its recovery is facilitated, unlike a conventional solution of paint, which could be more or less dry during the process.
  • metal salt solution is generally understood to mean a solution comprising oxidizing metal cations and a reducing solution.
  • the metal cations and the reducing solution are projected by two nozzles of the same sprayer, which create two mists that meet so that a layer of metal is deposited on the surface of the room.
  • the first or second part of a motor vehicle may be any part of the vehicle to which it is desired to give a metallized appearance, for example an air inlet grille, a rod, an optical outline, a hubcap, a bottom of crate, a protection strip, etc. It may be made of a thermoplastic or thermosetting or composite material.
  • the activation solution projection step lasts a certain time, so that the step of recovering part of the activation solution "after its projection" can be simultaneous with the step projecting another part of the activation solution.
  • FIG. 1 a first embodiment of a device 10 for projecting an activation solution 12 onto a surface of a part 14 for motor vehicle, for the metallization of this surface.
  • the part 14 can designate a first, a second or an n-th piece as presented above, or a first, second or n-th group of pieces.
  • This piece 14 may be for example a grid, a ring, an optical outline, a handle, a hubcap.
  • the device 10 comprises an enclosure 16 having an opening 18 and closing means 20 of the opening 18, such as a cover that can take an open or closed position.
  • the enclosure 16 also comprises a turntable 22, mounted movably in the enclosure, disposed in the lower part of the enclosure 16 and intended to receive the part 14 to be metallized, as well as means 24 for projecting the solution. activation on the part 14 when it is positioned on the plate 22.
  • the projection means 24, also called sprayer 24, are fixedly mounted in the chamber 16.
  • the chamber may have a volume of between 10 L (liters) and 2 m 3 .
  • the projection means 24 comprise, in this embodiment, a tube 26 having orifices 28, in this case four orifices 28, by means of which the activation solution can be projected onto the part 14. It will be understood that the means of projection 24 are shown here schematically and they may include including means for pressurizing the activation solution 12 to project it in the form of fine droplets of liquid.
  • the device 10 also comprises a reservoir 30 for temporarily storing the activation solution 12.
  • the reservoir 30 supplies the projection means 24 in activation solution 12 through a first channel 32.
  • the activation solution is for example pumped in the tank 30 by means of a first pump.
  • the chamber 16 is also connected to the reservoir 30 via a second pipe 34, which makes it possible to recover the activation solution projected onto the part 14 after run-off from the projections on the walls of the enclosure 16 and / or after trickling of the solution activation on the surface of the workpiece 14.
  • the activation solution can be recovered and directed to the reservoir 30 by gravity or by means of a pump.
  • the device 10 furthermore comprises, in this example, means 36 for processing the recovered activation solution.
  • processing means comprise, for example, filtration means for the activation solution. They are positioned between the chamber 16 and the tank 30. However, this location is just given as an example.
  • the reservoir 30 may optionally supply activation solution several pregnant 16, and also recover the activation solutions projected in several different speakers 16.
  • the device 10 further comprises a manipulator robot 40, for removing the part 14 and depositing in the chamber 16 another piece, identical or different. It may, however, include another means of handling a robot, such as a conveyor. The manipulation can also be performed by an operator.
  • a manipulator robot 40 for removing the part 14 and depositing in the chamber 16 another piece, identical or different. It may, however, include another means of handling a robot, such as a conveyor. The manipulation can also be performed by an operator.
  • the activation solution is a solution capable of modifying the state of the surface of the part 14 so as to favor the hangs on the metal particles projected later.
  • the activating solution may comprise stannous chloride.
  • the activating solution comprises more than 99% by weight of water. There is therefore an aqueous activation solution having a viscosity close to that of water, that is to say about 0.001 Pa.s.
  • the closure means 20 of the opening 18 of the enclosure 16, in this case a door 20, are moved so that the opening 18 is accessible.
  • the manipulator robot 40 deposits the part 14 of which at least one surface is to be metallized, acting as a first part, on the turntable 22 of the enclosure 16.
  • the door 20 is then closed, the enclosure 16 is thus closed.
  • the new activation solution that is to say having not yet been projected, is projected on the piece 14.
  • a first projection of the activation solution is thus carried out on the first 14.
  • the turntable 22 is rotated so that the part 14 is movable in the enclosure 16.
  • the activation solution being very fluid, it flows easily to the bottom of the chamber 16.
  • the activation solution trickles in particular on the walls of the chamber 16, on the part 14 and on the turntable 22. Once at the bottom of the chamber 16, it is recovered and sent to the tank 30.
  • these processing means 36 comprise a filter which makes it possible to eliminate solid particles, such as dust, which the solution of Recovered activation might contain.
  • the recovered activation solution is stored again in the tank 30.
  • the recovered activation solution is thus ready to be used for a new projection on the same piece 14 or a projection on another piece 14, separate from the first.
  • this step is relatively short, it is sufficient that the entire surface to be metallized of the part is wetted by the activation solution.
  • the door 20 of the enclosure 16 is opened, the manipulator robot 40 removes the first part 14 whose surface has been activated and which will subsequently be coated with metal salts and depositing a second piece 14 on the turntable 22.
  • the door 22 is closed.
  • the second projection is then carried out by spraying the activation solution recovered on the second part 14.
  • the activation solution contained in the reservoir is a mixture of new activation solution and recovered activation solution.
  • the first projection step can be performed with the solution having been recovered beforehand, since the projection is performed on a part and the solution is recovered to be projected on the same part or on a second part.
  • the activation solution recovered after projection onto a first part 14 in an enclosure 16 can be used to be projected into another enclosure 16 and thus onto a second part 14.
  • the recovery step of the activation solution can be carried out continuously or punctually after each projection.
  • part 14 There is shown a part 14, but one could also consider having on the plate 22 a support carrying several parts to be treated, so a group of parts.
  • the support can carry four pieces. We understand that this number is not limiting.
  • the part 14 is manipulated, that is to say deposited and removed, in the chamber 16 by a manipulator robot 40.
  • the part 14 could be manipulated by any other suitable means, even manually.
  • the recovery and second projection steps can be repeated for a period of time corresponding to the lifetime of the activation solution. After a certain period of time, which depends on the activation solution used, it no longer activates the surface on which it is projected or it still allows to activate the surface but the projection time of the solution must be increased, it is then advisable to change the activation solution, that is to say to no longer project the solution contained in the reservoir 30.
  • the tank 30 is then emptied and a new quantity of activating solution 12 is prepared and stored in the tank 30.
  • the enclosure 50 forms a spray booth comprising a manipulator robot 40 disposed inside the booth.
  • the size of this cabin varies depending on the size of the robot and the parts 14 to be treated. For example, its volume is between 10 m 3 to 100 m 3 .
  • the cabin comprises a floor 52 and side walls 54. It may also comprise an upper wall 56.
  • the floor 52, the side walls 54 and the upper wall 56 are partially represented in order to present the enclosure 50 in perspective.
  • the enclosure 50 comprises three sprayers 58, 60, 62 fixedly mounted in the enclosure 50.
  • This enclosure 50 may include openings, in particular to take the part 14 to be treated and deposit it after treatment. However, it is described as closed enclosure since these openings are sufficiently far from the sprayers 58, 60, 62 and that the solutions projected by these sprayers do not exit through these openings.
  • the robot 40 carries a support 64, or gripper 64, on which are fixed three parts 14 to be metallized, forming a group of parts.
  • the enclosure 50 also comprises an opening 66 for recovering the activation solution.
  • a given amount of activating solution 12 is prepared and stored in the reservoir 30.
  • the robot 40 takes the support 64 on a display stand.
  • This display can be positioned in or out of the enclosure 50, facing an opening of the enclosure 50 sufficiently far from the sprayers.
  • the robot will then present the parts 14 under the sprayers 58, 50, 62 which are connected to the reservoir 30.
  • the first spray step can be performed on the three parts 14 at the same time.
  • the activation solution flows on the parts and on the side walls 54 of the enclosure 50, towards the floor 52 where it is collected towards the opening 66.
  • the recovered activation solution is, as in the first embodiment stored in the reservoir 30 before being used for a second projection.
  • the robot 40 then deposits the support 64 on the display and takes a second support 64 which it will present under the sprayers 58, 60, 62 to carry out the second spraying step.
  • the different process variants that have been described can be similarly applied.
  • the step of recovering the activation solution can be carried out continuously or discontinuously, the recovery and second projection steps can be repeated for a period of time corresponding to the lifetime of the activation solution. activation solution, etc.
  • the sprayers 58, 60, 62 may not project the same solution.
  • the first sprayer 58 projects the activation solution
  • the second sprayer 60 projects a rinsing solution
  • the third sprayer 62 projects a solution of metal salts.
  • recovery of the activation solution can be considered in isolation from other solutions.
  • the closing means 20 may comprise a door, a hatch, a cover. Note that in the second embodiment, they are not necessary.
  • the solvent used for the activating solution is water but one could also consider using an alcohol.

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemically Coating (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Claims (10)

  1. Verfahren zur Metallisierung einer Oberfläche eines ersten Teils (14) für ein Kraftfahrzeug, wobei die Metallisierung nicht elektrolytisch ist, wobei das Verfahren einen Schritt des Aufbringens einer Lösung metallischer Salze auf der Oberfläche umfasst, dem ein Schritt des Aufsprühens einer Aktivierungslösung auf der Oberfläche, das so genannte erste Aufsprühen, vorangeht, wobei der Schritt des Aufsprühens in einem geschlossenen Raum (16, 50) erfolgt,
    dadurch gekennzeichnet, dass es ferner die folgenden Schritte umfasst:
    - Auffangen der Aktivierungslösung, die nach ihrem Aufsprühen in dem geschlossenen Raum (16, 50) verbleibt, und
    - Verwenden der aufgefangenen Aktivierungslösung, um sie in einem Schritt, der als zweites Aufsprühen bezeichnet wird, auf die Oberfläche des ersten Teils oder eines zweiten Teils (14) für ein Kraftfahrzeug aufzusprühen.
  2. Verfahren nach dem vorhergehenden Anspruch, bei dem die Schritte des Auffangens und des zweiten Aufsprühens über einen Zeitraum wiederholt werden, welcher der Lebensdauer der Aktivierungslösung entspricht.
  3. Verfahren nach einem der vorhergehenden Ansprüche, bei dem der Schritt des Auffangens der Aktivierungslösung kontinuierlich im Laufe der verschiedenen Schritte des Aufsprühens durchgeführt wird.
  4. Verfahren nach einem der Ansprüche 1 bis 2, bei dem der Schritt des Auffangens der Aktivierungslösung punktuell nach jedem Aufsprühen durchgeführt wird.
  5. Verfahren nach einem der vorhergehenden Ansprüche, bei dem während des zweiten Aufsprühens ferner neue Aktivierungslösung aufgesprüht wird.
  6. Verfahren nach einem der vorhergehenden Ansprüche, bei dem die Aktivierungslösung mehr als 90 Gew.-%, bevorzugt mehr als 95 Gew.-% und weiter bevorzugt mehr als 99 Gew.-% Lösungsmittel enthält.
  7. Verfahren nach einem der vorhergehenden Ansprüche, das vor dem zweiten Schritt des Aufsprühens einen Schritt des Behandelns der Aktivierungslösung vor ihrem zweiten Aufsprühen umfasst.
  8. Verfahren nach einem der vorhergehenden Ansprüche, bei dem der erste und zweite Schritt des Aufsprühens durch einen Zerstäuber (24, 58, 60, 62) durchgeführt werden, der in dem geschlossenen Raum (16, 50) feststehend montiert ist, wobei jedes Teil (14) in dem geschlossenen Raum (16, 50) beweglich montiert ist.
  9. Verfahren nach einem der vorhergehenden Ansprüche, bei dem, zwischen dem ersten und dem zweiten Aufsprühen, ein Handhabungsautomat (40) oder eine Fördereinrichtung oder ein Bediener (oder jede andere Handhabungseinrichtung) das erste Teil entnimmt und das zweite Teil in dem geschlossenen Raum (16, 50) ablegt.
  10. Verfahren nach einem der vorhergehenden Ansprüche, das, vor dem zweiten Schritt des Aufsprühens, einen Schritt des Prüfens der Aktivierungslösung durchgeführt wird, um zu bestimmen, ob sie für das zweite Aufsprühen verwendbar ist.
EP13756653.5A 2012-08-06 2013-08-01 Verfahren zur metallisierung eines kraftfahrzeugsteil Not-in-force EP2880198B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1257642A FR2994196B1 (fr) 2012-08-06 2012-08-06 Procede de metallisation d'une piece pour vehicule automobile
PCT/FR2013/051870 WO2014023899A1 (fr) 2012-08-06 2013-08-01 Procédé de métallisation d'une pièce pour véhicule automobile

Publications (2)

Publication Number Publication Date
EP2880198A1 EP2880198A1 (de) 2015-06-10
EP2880198B1 true EP2880198B1 (de) 2016-10-26

Family

ID=47191915

Family Applications (1)

Application Number Title Priority Date Filing Date
EP13756653.5A Not-in-force EP2880198B1 (de) 2012-08-06 2013-08-01 Verfahren zur metallisierung eines kraftfahrzeugsteil

Country Status (6)

Country Link
EP (1) EP2880198B1 (de)
CN (1) CN104704143B (de)
BR (1) BR112015002411A2 (de)
ES (1) ES2611934T3 (de)
FR (1) FR2994196B1 (de)
WO (1) WO2014023899A1 (de)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108728831A (zh) * 2018-06-04 2018-11-02 安徽天宇磁业股份有限公司 一种用于钕铁硼永磁材料的镀膜装置及其防护工艺
CN112044631A (zh) * 2020-09-10 2020-12-08 合肥常青机械股份有限公司 一种汽车车桥均匀喷涂装置
CN113477443B (zh) * 2021-08-11 2022-06-17 深圳市埔洋家居用品有限责任公司 一种工艺礼品表面修复液便携喷涂设备

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2934609B1 (fr) * 2008-07-30 2011-07-22 Jet Metal Technologies Procede non eletrolytique de metallisation en ligne de substrats par projection avec traitement de surface prealable et dispositif pour la mise en oeuvre du procede.
FR2954716B1 (fr) * 2009-12-29 2012-02-10 Plastic Omnium Cie Procede de traitement surfacique de pieces de grandes dimensions, prehenseur de pieces adapte pour la mise en oeuvre d'un tel procede, utilisation de ce prehenseur et cabine de traitement

Also Published As

Publication number Publication date
ES2611934T3 (es) 2017-05-11
CN104704143A (zh) 2015-06-10
FR2994196B1 (fr) 2014-08-22
BR112015002411A2 (pt) 2017-07-04
WO2014023899A1 (fr) 2014-02-13
FR2994196A1 (fr) 2014-02-07
EP2880198A1 (de) 2015-06-10
CN104704143B (zh) 2017-04-05

Similar Documents

Publication Publication Date Title
EP3263228B1 (de) Reinigungssystem mit einer trocknungsstation
EP2880198B1 (de) Verfahren zur metallisierung eines kraftfahrzeugsteil
EP2326747B1 (de) Nichtelektrolytisches inline-verfahren zur metallisierung eines substrats mit vorbehandlung der oberfläche und vorrichtung zur durchführung des verfahrens
EP0863793B1 (de) Reinigungsverfahren für eine unterwassermembranfitteranlage
WO2009151402A1 (en) A process for producing an image on a substrate
JP3191304U (ja) 遠心分離機
FR2511608A1 (fr) Dispositif et procede pour eliminer sur des objets des agents de traitement liquides qui y adherent et pour la recuperation de ceux-ci
FR2800390A1 (fr) Procede et dispositif d'application d'un revetement anti-corrosion
EP2880197B1 (de) Verfahren zur metallisierung einer oberfläche eines teils für ein kraftfahrzeug
CN213925073U (zh) 一种用于电镀前的喷洗装置
EP2805684A2 (de) Reinigungs- und Desinfektionsverfahren und -anlage für medizinische Vorrichtungen
JP5336718B2 (ja) 塑性加工用潤滑液の塗布装置
FR2880557A1 (fr) Installation industrielle de peinture
JP5125038B2 (ja) レジスト剥離装置及びレジスト剥離方法
JPS5923517A (ja) レジスト除去方法および装置
JPH01187567A (ja) 電子写真感光体の製造法
CN216501086U (zh) 一种旋转式自动高压喷淋清洗机
JPH07108208A (ja) 塗装前処理装置
JP2004018865A (ja) 塗装前処理装置及び塗装前処理方法
JP2004315837A (ja) ワークの処理システム
JP3825824B2 (ja) 水性塗料の貯蔵方法及び塗料タンク
BE1003464A6 (fr) Procede et dispositif de nettoyage d'un reservoir.
FR2802448A1 (fr) Procede de recyclage de peinture a base d'eau
JP2000290544A (ja) 水性塗料の塗装ラインの洗浄法
KR101589720B1 (ko) 강재류를 강 알칼리 전해수를 이용하여 세정하는 장치

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20150203

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

DAX Request for extension of the european patent (deleted)
GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

INTG Intention to grant announced

Effective date: 20160519

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 840103

Country of ref document: AT

Kind code of ref document: T

Effective date: 20161115

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: LANGUAGE OF EP DOCUMENT: FRENCH

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602013013260

Country of ref document: DE

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161026

REG Reference to a national code

Ref country code: NL

Ref legal event code: MP

Effective date: 20161026

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK05

Ref document number: 840103

Country of ref document: AT

Kind code of ref document: T

Effective date: 20161026

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161026

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161026

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170126

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170127

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2611934

Country of ref document: ES

Kind code of ref document: T3

Effective date: 20170511

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161026

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170226

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170227

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161026

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161026

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161026

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161026

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161026

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602013013260

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161026

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161026

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161026

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161026

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161026

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 5

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161026

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161026

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170126

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20170727

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161026

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161026

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20170801

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170831

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170831

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

REG Reference to a national code

Ref country code: BE

Ref legal event code: MM

Effective date: 20170831

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170801

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170801

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170801

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 6

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170831

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161026

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20180921

Year of fee payment: 6

Ref country code: FR

Payment date: 20180821

Year of fee payment: 6

Ref country code: DE

Payment date: 20180823

Year of fee payment: 6

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20130801

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161026

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161026

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 602013013260

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161026

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190831

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200303

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161026

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20210105

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190802