EP2840159A1 - Procédé destiné à la fabrication d'un composant en acier - Google Patents
Procédé destiné à la fabrication d'un composant en acier Download PDFInfo
- Publication number
- EP2840159A1 EP2840159A1 EP13181374.3A EP13181374A EP2840159A1 EP 2840159 A1 EP2840159 A1 EP 2840159A1 EP 13181374 A EP13181374 A EP 13181374A EP 2840159 A1 EP2840159 A1 EP 2840159A1
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- EP
- European Patent Office
- Prior art keywords
- flat steel
- steel product
- flat
- retained austenite
- product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 102
- 239000010959 steel Substances 0.000 title claims abstract description 102
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- 229910001566 austenite Inorganic materials 0.000 claims abstract description 42
- 230000000717 retained effect Effects 0.000 claims abstract description 38
- 238000000034 method Methods 0.000 claims abstract description 25
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 16
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 16
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 15
- 229910052802 copper Inorganic materials 0.000 claims abstract description 14
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 14
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 10
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 10
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 9
- 239000012535 impurity Substances 0.000 claims abstract description 8
- 229910052742 iron Inorganic materials 0.000 claims abstract description 8
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 7
- 229910000734 martensite Inorganic materials 0.000 claims description 34
- 229910001563 bainite Inorganic materials 0.000 claims description 22
- 238000001816 cooling Methods 0.000 claims description 19
- 229910052799 carbon Inorganic materials 0.000 claims description 15
- 239000010960 cold rolled steel Substances 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 6
- 229910000859 α-Fe Inorganic materials 0.000 claims description 6
- 239000011253 protective coating Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 2
- 239000000047 product Substances 0.000 description 53
- 238000005098 hot rolling Methods 0.000 description 12
- 230000009466 transformation Effects 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 6
- 239000000470 constituent Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 239000002243 precursor Substances 0.000 description 5
- 238000000137 annealing Methods 0.000 description 4
- 238000005096 rolling process Methods 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 238000005097 cold rolling Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000008092 positive effect Effects 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229910001562 pearlite Inorganic materials 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 238000003303 reheating Methods 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 241000446313 Lamella Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910000611 Zinc aluminium Inorganic materials 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- 230000035508 accumulation Effects 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910001567 cementite Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- KSOKAHYVTMZFBJ-UHFFFAOYSA-N iron;methane Chemical compound C.[Fe].[Fe].[Fe] KSOKAHYVTMZFBJ-UHFFFAOYSA-N 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/004—Heat treatment of ferrous alloys containing Cr and Ni
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/005—Heat treatment of ferrous alloys containing Mn
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/008—Heat treatment of ferrous alloys containing Si
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0205—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
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- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
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- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
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- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0236—Cold rolling
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/08—Ferrous alloys, e.g. steel alloys containing nickel
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/16—Ferrous alloys, e.g. steel alloys containing copper
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/34—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
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- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
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- C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
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- C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/52—Ferrous alloys, e.g. steel alloys containing chromium with nickel with cobalt
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
- C23C30/005—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/001—Austenite
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D7/00—Modifying the physical properties of iron or steel by deformation
- C21D7/02—Modifying the physical properties of iron or steel by deformation by cold working
- C21D7/10—Modifying the physical properties of iron or steel by deformation by cold working of the whole cross-section, e.g. of concrete reinforcing bars
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0068—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for particular articles not mentioned below
Definitions
- the invention relates to a method for producing a steel component, which has a tensile strength Rm of more than 1200 MPa and an elongation at break A50 of at least 6%.
- Steel components produced according to the invention are distinguished by a very high strength in combination with good elongation properties and, as such, are particularly suitable as components for motor vehicle bodies.
- flat steel product here by a rolling process produced steel sheets or steel strips and divided therefrom boards and the like understood.
- Steel components of the type according to the invention are produced by a forming process from such flat steel products.
- alloy contents are stated here only in “%”, this always means “% by weight”, unless expressly stated otherwise.
- Thickness of not more than 3.5 mm should have a uniform distribution of its mechanical properties and a particularly good Lochetzweitungs .
- the process envisages that a slab containing (in% by weight) 0.05-0.30% C, 0.03-1.0% Si, 1.5-3.5% Mn, up to 0.02% P, up to 0.005% S, up to 0.150 Al, up to 0.0200% N, and alternatively or in combination 0.003-0.20% Nb or 0.005-0.20% Ti, up to 1200 ° C is heated and then hot rolled at a hot rolling end temperature of at least 800 ° C, in particular 950 - 1050 ° C, to a hot strip.
- the hot strip obtained is cooled at a cooling rate of 20 - 150 ° C / sec to a reel temperature of 300 - 550 ° C, in which it is wound into a coil.
- the cooling starts within 2 seconds after the end of the hot rolling.
- the hot rolled strip thus obtained shall have a fine bainitic structure with a bainite content of at least 90%, the average grain size of which shall not exceed 3,0 ⁇ m, the ratio of the longest axis length to the shortest axis length of the grains not exceeding 1, 5 and the length of the longest axis of the grains should not exceed 10 microns.
- the remainder of the structure not occupied by bainite should consist of tempered martensite, which is very similar in its appearance and properties to bainite.
- Hot rolled strips produced and produced in this manner have tensile strengths of 850 - 1103 MPa at an elongation of 15 - 23%.
- a method for producing a steel sheet having a tensile strength of at least 1470 MPa in which the product of Elongation and tensile strength is at least 29000 MPa%.
- the steel constituting the steel sheet contains, in addition to iron and unavoidable impurities (in% by weight), 0.30-0.73% C, up to 3.0% Si, up to 3.0 Al, the Sum of the Si and Al contents is at least 0.7%, 0.2-8.0% Cr, up to 10.0% Mn, the sum of the Cr and Mn contents being at least 1.0%, up to 0.1% P, up to 0.07% S and up to 0.010% N.
- the steel sheet thus composed is processed such that the martensite area fraction in the range of 15-90% based on the total microstructure of the steel and the content of residual austenite of the structure is 10 - 50%. At least 50% of the martensite should be present as tempered martensite and the area fraction of tempered martensite should be at least 10%. If present in the structure, at the same time the area ratio of polygonal ferrites present in the structure should be at most 10%.
- a hot rolled steel strip as set forth by heating a steel precursor such as a slab to 1000-1300 ° C and thereafter rolling it to a hot strip at a hot rolling end temperature of 870-950 ° C.
- the resulting hot strip is then wound at a reel temperature of 350 - 720 ° C to form a coil. After coiling, pickling followed by cold rolling takes place at degrees of deformation of 40-90%.
- the cold-rolled strip thus obtained is annealed for 15-1000 seconds at a temperature where it has a purely austenitic structure, and then at a cooling rate of at least 3 ° C / s cooled to a temperature ranging from below the martensite start temperature and reaching a temperature lower than 150 ° C lower temperature range to produce tempered martensite in the structure of the steel sheet. Thereafter, the cold rolled steel strip is heated to 340-500 ° C over a period of 15-1000 seconds to stabilize the retained austenite.
- the cold-rolled steel sheets thus produced reached tensile strengths of more than 1600 MPa at an elongation of up to 27%.
- the object of the invention was to specify a method which makes it possible in a simple way to produce complex shaped components from flat steel products of the type described above.
- this object has been achieved by carrying out the operations specified in claim 1 for the production of high-strength steel components having good elongation properties.
- the invention is based on the recognition that a component which is produced by forming a 150-400 ° C warm flat steel product of the type according to the invention, after a subsequent cooling to room temperature over the strength of the original Stahlflachöns significantly increased strength with almost unchanged elongation properties has.
- the elongation properties of a component produced according to the invention thus do not decrease, in spite of the increased strength, compared to a component formed at room temperature.
- the invention thus results from a pre-deformation at 150 - 400 ° C a significant increase in strength with unchanged extensibility of each component obtained.
- the increase in strength achieved by the forming according to the invention is considerable.
- the expansion properties of the component obtained according to the invention correspond to the elongation properties of the component formed at room temperature, so that the component produced according to the invention is particularly suitable for use in automobile bodies due to its deformation behavior.
- the reason for the increase in strength achieved by the procedure according to the invention, according to the findings of the invention, is that in the structure of the present invention processed flat steel product present globular retained austenite, which is characterized by a grain size of at least 1 micron, under the load of the forming in accordance with the invention Temperature range of 150 - 400 ° C in film-like retained austenite and bainitic ferrite or below the martensite starting temperature converted into martensite. During the forming in the temperature range concerned, the globular retained austenite present in the steel flat product thus contributes to increasing the elongation at. After the forming and cooling of the component of the steel according to the invention then shows higher tensile strengths due to the additionally formed ferritic bainite or martensite.
- the parts of film-like retained austenite which remain unchanged over cooling ensure the good residual elongation achieved after the transformation. This effect can be used particularly reliably if the flat steel product for the inventive transformation to the component is heated to 200-400 ° C., in particular 200-300 ° C.
- the method according to the invention is particularly suitable for converting flat steel products which are provided with a metallic protective coating into components.
- the metallic protective layer is at most slightly influenced by the invention taking place heating.
- the protective coating may be a conventional zinc, zinc alloy, aluminum or aluminum alloy, magnesium or magnesium alloy coating.
- composition of a flat steel product processed according to the invention has been chosen taking into account the following aspects:
- the C content of the flat steel product according to the invention to at least 0.25 wt .-%, in particular at least 0.27 wt .-%, at least 0.28 wt .-% or at least 0.3 wt .-%, are set, wherein the be used by the comparably high carbon content effects particularly safe when the C content in the range of> 0.25 to 0.5 wt .-%, in particular 0.27 to 0.4 wt .-% or 0.28 - 0.4 wt .-%, is.
- Si Due to the presence of Si in contents of 0.4-2.5% by weight and Al in contents of up to 3% by weight in the flat steel product processed according to the invention, carbide formation in the bainite can be suppressed and consequently the residual austenite stabilized by dissolved carbon become.
- Si contributes to solid solution hardening. In order to avoid potentially harmful influences of Si, the Si content may be limited to 2.0 wt%. In order to use Si as a mixed-crystal former for increasing the strength, it may be expedient for the flat steel product processed according to the invention to contain at least 1% by weight of Si.
- Al can partially replace the Si content in the steel processed according to the invention.
- a minimum content of 0.4 wt .-% Al may be provided. This is especially true when the hardness or tensile strength of the steel is to be set to a lower value in favor of improved ductility by the addition of Al.
- the optionally additionally present contents of Cu, Cr and Ni also contribute to the formation of bainite.
- the martensite start temperature can be lowered and the tendency of the bainite to convert to pearlite or cementite can be suppressed.
- Cr at levels up to the upper limit of not more than 2% by weight given in accordance with the invention promotes the ferritic transformation, whereby optimum effects of the presence of Cr in a flat steel product according to the invention result if the Cr content is reduced to 1.5% by weight. is limited.
- Ti, V or Nb can support the formation of fine-grained microstructures and promote ferritic transformation.
- these micro-alloying elements contribute to increasing the hardness by forming precipitates.
- the positive effects of Ti, V and Nb in the flat steel product processed according to the invention can then be achieved particularly effectively use, if their content is in each case in the range of 0.002 to 0.15 wt .-%, in particular 0.14 wt .-% does not exceed.
- the formation of the structure provided according to the invention can be ensured, in particular, by the contents of the steel flat product of Mn, Cr, Ni, Cu and C processed according to the invention having the following condition 1 ⁇ 0 . 5 % Mn + 0 . 167 % Cr + 0 . 125 % Ni + 0 . 125 % Cu + 1 . 334 % C ⁇ 2 meet, where with% Mn the respective Mn content in wt .-%, with% Cr of the respective Cr content in wt .-%, with% Ni of the respective Ni content in wt .-%, with% Cu of the respective Cu content in wt .-% and with% C of the respective C content in wt .-% are designated.
- hot-rolled or cold-rolled flat steel products having a composition corresponding to the specifications according to the invention are suitable as the starting material for the process according to the invention.
- eligible hot rolled flat steel products and a process for their preparation are the subject of the European patent application EP 12 17 83 30.2 , the content of which is hereby expressly incorporated into the disclosure of the present patent application.
- the hot-rolled flat steel products produced according to this patent application are characterized by an optimum combination of elongation properties and strength.
- This combination of properties can be achieved in a particularly reliable way that the structure of flat steel products processed according to the invention, in addition to optionally present fractions of up to 5% by volume of ferrite and up to 10% by volume of martensite, to at least 60% by volume of bainite and the balance of retained austenite, the retained austenite content being at least 10% by volume, at least a portion of the retained austenite is in block form and the blocks of the retained austenite present in block form at least 98% have a mean diameter of less than 5 microns.
- obtained hot-rolled flat steel product has a two-phase dominated microstructure of which one dominant component is bainite and its second dominant component is retained austenite.
- small amounts of martensite and ferrite may be present, but their contents are too low to have an influence on the properties of the hot-rolled steel flat product.
- blocky retained austenite is referred to as the ratio of length / width, ie longest extent / thickness, of 1 to 5 in the structural components of retained austenite present in the structure.
- retained austenite is referred to as "film-like” if the ratio of length / width is greater than 5 for the retained austenite accumulations present in the microstructure and the width of the respective microstructure constituents of retained austenite is less than 1 ⁇ m. Accordingly, film-like retained austenite is typically present as a finely distributed lamella.
- a cold-rolled flat steel product suitable for carrying out the process according to the invention as starting material and a process for producing such a cold-rolled steel flat product are the subject of the European patent application 12 17 83 32.8 , the contents of which are hereby expressly included in the disclosure of the present patent application.
- the microstructure of the cold-rolled steel flat product preferably consists of at least 20% by volume of bainite, 10 to 35% by volume of retained austenite and the remainder of martensite. It goes without saying that in the structure of the flat steel product technically unavoidable traces of other structural constituents can be present. Accordingly, such a cold-rolled flat steel product suitable for the processing according to the invention has a three-phase structure whose dominant constituent is bainite and which furthermore consists of retained austenite and the remainder of martensite.
- the bainite content is at least 50% by volume, in particular at least 60% by volume, and the residual austenite content is in the range from 10 to 25% by volume, the remainder of the microstructure in each case also being filled with martensite.
- the optimum martensite content is at least 10% by volume.
- retained austenite In addition to the main components “Bainite”, “retained austenite” and “martensite” may be present in the cold-rolled steel flat product processed according to the invention contents of other microstructure constituents, but their proportions are too low to have an influence on the properties of the cold-rolled steel flat product.
- the retained austenite is predominantly film-like with small globular islands of blocky retained austenite with a grain size ⁇ 5 ⁇ m in the case of such a flat steel product suitable for processing according to the invention, so that the retained austenite has a high stability and, consequently, a low tendency to undesirable transformation into martensite ,
- the C content of the retained austenite is typically more than 1.0% by weight.
- the above-mentioned martensite starting temperature ie the temperature at which martensite forms in steel processed according to the invention, can be determined in each case according to the article " Thermodynamic Exatrapolation and Martensite Start-Temperature of Substitutionally Alloyed Steels "by H. Bhadeshia, published in Metal Science 15 (1981), pages 178-180 explained procedure can be calculated.
- the molten steel has been conventionally cast into slabs which have subsequently been heated to a reheating temperature TDC in a manner also conventional.
- the heated slabs were hot rolled in a likewise conventional hot rolling mill to hot strips W1 - W4 with a thickness of 2.0 mm each.
- the hot strips W1-W4 emerging from the hot rolling scale each had a hot rolling end temperature ET, from which they have been accelerated at a cooling rate KR to a coiling temperature HT. At this reel temperature HT, the hot strips W1 - W4 have been wound into coils.
- the coils were then each cooled in a temperature range whose upper limit was determined by the respective reel temperature HT and the lower limit by the martensite starting temperature MS calculated for the steel S1.
- the calculation of the martensite start temperature MS was carried out according to the article " Thermodynamic Exatrapolation and Martensite Start-Temperature of Substituted Alloyed Steels "by H. Bhadeshia, published in Metal Science 15 (1981), pages 178-180 explained procedure.
- the duration over which the coil was cooled in the temperature range defined in the manner described above was such that the hot strips thus obtained each had a structure consisting of bainite and retained austenite, in which the proportions of others Structural constituents were present at most in ineffective, against "0" going amounts.
- Table 3 also shows the mechanical properties tensile strength Rm, yield strength Rp, elongation at break A80, quality Rm * A80 and the respective retained austenite content RA determined for the individual hot strips W1-W4.
- Samples of the steel flat products obtained in the form of the hot strips W1-W4 are then heated to a forming temperature UT lying in the range of 200-250 ° C. and formed into a single component with a degree of deformation of up to 15%.
- the elongation at break A50 of the samples was> 30%, so that it was also possible to image complex shaped elements without the risk of crack formation in the temperature range of the forming process according to the invention.
- the components converted from the samples of the hot strips W1-W4 were air-cooled to room temperature and their breaking elongation A50 and their tensile strength Rm were determined.
- the tensile strength Rm of the samples formed according to the invention was 80-120 MPa higher than the samples converted at room temperature.
- Fig. 2 is a section of a structural sample shown, which has been removed at room temperature from the component, which has been formed from the consisting of the steel S1 hot strip W2 in accordance with the invention at temperatures of 200 - 250 ° C.
- Fig. 3a, 3b are in each case 20,000-fold magnification cut-outs of a structural sample of steel S1 existing steel component before ( Fig. 3a ) and after ( Fig. 3b ) reproduced the deformation of the invention.
- FIG. 4a, 4b corresponding photographs of the structural samples of the existing steel S1 steel component ( Fig. 4a ) and after ( Fig. 4b ) of the inventive transformation in 50000-fold magnification.
- FIG. 3a Comparison of FIG. 3a with the FIG. 3b and the FIG. 4a with the FIG. 4b clearly show the changes that are caused by a deformation according to the invention.
- a flat steel product which, in addition to iron and unavoidable impurities (in% by weight) C: 0.10-0.60%, Si: 0.4-2.5%, Al: up to 3.0% Mn: 0.4 - 3.0%, Ni: up to 1%, Cu: up to 2.0%, Mo: up to 0.4%, Cr: up to 2%, Co: up to 1.5 %, Ti: up to 0.2%, Nb: up to 0.2%, V: up to 0.5%, the structure of the flat steel product consisting of at least 10% by volume of retained austenite, the globular retained austenite islands having a grain size of at least 1 micron.
- the flat steel product is heated to 150-400 ° C forming temperature and formed at the forming temperature with a degree of deformation which is at most equal to the uniform strain Ag, to the component. Finally, the steel flat product thus obtained is cooled.
- Such molded at elevated temperatures component has over the same flat steel product, but molded at room temperature components significantly increased strength.
- Table 1 stolen C Si al Mn Ni Cu Cr other S1 0.48 1.5 0.02 1, 48 0.034 1.51 0.9 In% by weight, Remaining iron and unavoidable impurities hot strip OT [° C] ET [° C] KR [° C / s] HT [° C] MS [° C] W1 1150 970 20 350 245 W2 1200 1000 10 400 315 W3 1200 1000 20 450 270 W4 1150 1000 20 500 230 hot strip Rm [MPa] Rp [MPa] A80 [%] RM * A80 [MPa *%] RA [vol.%] W1 1357 807 22.2 27387 36 W2 1318 751 17, 8 21328 17 W3 1217 821 25.8 28544 32 W4 1345 889 21.0 25677 30
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EP13181374.3A EP2840159B8 (fr) | 2013-08-22 | 2013-08-22 | Procédé destiné à la fabrication d'un composant en acier |
ES13181374.3T ES2636780T3 (es) | 2013-08-22 | 2013-08-22 | Procedimiento para la fabricación de un componente de acero |
KR1020167006903A KR20160047495A (ko) | 2013-08-22 | 2014-08-18 | 강 부품의 제조 방법 |
CN201480046408.0A CN105518175B (zh) | 2013-08-22 | 2014-08-18 | 用于制造钢构件的方法 |
US14/913,592 US10301700B2 (en) | 2013-08-22 | 2014-08-18 | Method for producing a steel component |
PCT/EP2014/067571 WO2015024903A1 (fr) | 2013-08-22 | 2014-08-18 | Procédé permettant de produire un élément structural en acier |
JP2016535447A JP6606075B2 (ja) | 2013-08-22 | 2014-08-18 | 鋼部品を製造する方法 |
JP2019072123A JP2019151932A (ja) | 2013-08-22 | 2019-04-04 | 鋼部品を製造する方法 |
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DE102016104800A1 (de) * | 2016-03-15 | 2017-09-21 | Salzgitter Flachstahl Gmbh | Verfahren zur Herstellung eines warmumgeformten Stahlbauteils und ein warmumgeformtes Stahlbauteil |
CN106823880A (zh) * | 2016-12-14 | 2017-06-13 | 苏州纽东精密制造科技有限公司 | 一种高强度耐腐蚀的高速搅拌器 |
RU2768717C1 (ru) * | 2018-11-30 | 2022-03-24 | Арселормиттал | Холоднокатаный отожжённый стальной лист с высокой степенью раздачи отверстия и способ его изготовления |
US11502402B2 (en) | 2019-03-15 | 2022-11-15 | Taiwan Semiconductor Manufacturing Company, Ltd. | Integrated patch antenna having insulating substrate with antenna cavity and high-K dielectric |
US20230151468A1 (en) * | 2020-04-22 | 2023-05-18 | Thyssenkrupp Steel Europe Ag | Hot-Rolled Flat Steel Product and Method for the Production Thereof |
CN114774651A (zh) * | 2022-04-18 | 2022-07-22 | 营口中车型钢新材料有限公司 | 一种铁路承重用YZ25SiMnMoV扁钢的热处理设计 |
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CN113217603B (zh) * | 2021-04-30 | 2023-02-24 | 四川固锐德科技有限公司 | 用于重载车主减系统的圆柱轮及其制备方法 |
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JP2019151932A (ja) | 2019-09-12 |
WO2015024903A1 (fr) | 2015-02-26 |
EP2840159B1 (fr) | 2017-05-10 |
EP2840159B8 (fr) | 2017-07-19 |
JP2016530403A (ja) | 2016-09-29 |
US10301700B2 (en) | 2019-05-28 |
CN105518175B (zh) | 2017-07-11 |
JP6606075B2 (ja) | 2019-11-13 |
KR20160047495A (ko) | 2016-05-02 |
ES2636780T3 (es) | 2017-10-09 |
US20160201157A1 (en) | 2016-07-14 |
CN105518175A (zh) | 2016-04-20 |
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