EP2722406B1 - Acier pour filière de moulage présentant une excellente conductivité thermique, des propriétés de polissage en miroir et une excellente ténacité - Google Patents

Acier pour filière de moulage présentant une excellente conductivité thermique, des propriétés de polissage en miroir et une excellente ténacité Download PDF

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EP2722406B1
EP2722406B1 EP13166415.3A EP13166415A EP2722406B1 EP 2722406 B1 EP2722406 B1 EP 2722406B1 EP 13166415 A EP13166415 A EP 13166415A EP 2722406 B1 EP2722406 B1 EP 2722406B1
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Prior art keywords
steel
die
thermal conductivity
hardness
amount
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German (de)
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EP2722406A1 (fr
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Masamichi Kawano
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Daido Steel Co Ltd
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Daido Steel Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/60—Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18—Hardening; Quenching with or without subsequent tempering
    • C21D1/25—Hardening, combined with annealing between 300 degrees Celsius and 600 degrees Celsius, i.e. heat refining ("Vergüten")
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/52—Ferrous alloys, e.g. steel alloys containing chromium with nickel with cobalt
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/54—Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/004—Dispersions; Precipitations

Definitions

  • the present invention relates to a steel for a molding die, which is excellent in thermal conductivity, mirror polishing properties and toughness, and particularly to a steel for a molding die, which is suitable as a material for a plastic molding die.
  • the material for a die for molding plastic products is required to have good appearance with surface smoothness and glossiness, the material for the die is required to have high mirror polishing properties, which makes it possible to finish a molding surface into a smooth and mirror-like surface when the die is constructed.
  • a longer die life can reduce the die cost per product (that is to say, the product cost can be reduced), so that the toughness necessary for realizing a long life of the die has also been required.
  • the die for molding such a molded product sometimes becomes large such that the width thereof is more than 1 m and the thickness thereof is tens of centimeters or more.
  • the material for such a large-sized die must be high in hardenability during quenching.
  • the die material is necessary to have high mirror polishing properties.
  • the C amount When the C amount is large, the amount of carbides formed in a steel material is also increased.
  • the carbides are liable to appear on the surface of the die produced from such a steel material.
  • the die surface is mirror polished, the carbides drop off to form holes there as drop-off traces, and when the plastic product is molded, the holes are transferred to the product side to cause a disadvantage of impairing beauty of the product surface, thereby losing the commodity value thereof.
  • Patent Document 1 shows the invention of "Corrosion-Resistant Steel for Plastic Molding Die” and discloses that an intermetallic compound of Cu, Ni and Al is allowed to be precipitated at the time of tempering with the C amount decreased as small as 0.02 to 0.2%, thereby enhancing the hardness of the steel.
  • Patent Document 1 Cu and Ni are added in large amounts, and particularly, Al is added in an amount as large as 0.5% or more, thereby allowing the intermetallic compound to be precipitated in large amounts.
  • the cost is increased by increases in the added amounts of the alloy components, and the toughness becomes insufficient by addition of a large amount of Al.
  • Patent Document 1 is silent on enhancement of a cooling performance of the die, which is important for product molding in high cycles (reduction in cycle time), and a countermeasure therefor is not particularly taken.
  • the content of Si which plays an important role at the time of cooling the die is large (although described to be 1.5% or less in the claims, the lower limit thereof is 0.3% in the examples, and no content lower than this limit is disclosed therein).
  • Patent Document 2 shows the invention of "Steel for High-Strength Die Excellent in Machinability" and discloses a steel for a die for molding a plastic product and the like, in which the hardness of the steel is enhanced by a precipitation effect of Cu and precipitation of an intermetallic compound of Ni and Al, with the C amount decreased as small as 0.005 to 0.1%.
  • Ni is described to be 4.0% or less and Al is described to be 0.1 to 2.0% in the claims.
  • the lower limit of Al is 0.74% in the examples, and in all of the examples, the Al amount is larger than this limit.
  • the lower limit thereof is 1.78% in the examples, and in all of the examples, Ni is added in larger amounts than this limit.
  • the lower limit thereof is described to be 3.5% or less in the claims.
  • the lower limit thereof in the examples is 0.77%, and in all of the examples, the Cu amount is larger than this limit.
  • Patent Document 2 is also silent on enhancement of the cooling performance of the die, which becomes important for product molding in high cycles, and a countermeasure therefor is not particularly taken.
  • Patent Document 2 a large amount of Si is contained (although described to be 1.5% or less in the claims, the lower limit thereof is 0.28% in the examples, and no content lower than this limit is disclosed therein).
  • the invention has been made for the purpose of providing a steel for a molding die, which is high in thermal conductivity, excellent in mirror polishing properties and also excellent in toughness according to the appended claims.
  • the present invention provides the followings.
  • the invention is characterized by that in a steel in which the hardness is secured by aging precipitation of Cu, Ni and Al with the added amount of C decreased, the added amounts of Cu, Ni and Al are decreased with exertion of secondary hardening based on addition of Mo and V.
  • the present inventors have examined the added amounts of Cu, Ni and Al necessary for obtaining the steel having a predetermined hardness. As a result, it has been found that even when the added amounts of Cu, Ni and Al are decreased more than those of a conventional steel, the desired hardness such as 35 to 45 HRC can be sufficiently realized.
  • the invention has been made under such a finding.
  • the invention is characterized by that Al as an element for forming an intermetallic compound is restricted as low as less than 0.50%.
  • the toughness is decreased by the aging precipitation of the intermetallic compound. Further, Al not used for the aging precipitation is solid-dissolved into a matrix to decrease the toughness of the matrix itself.
  • the toughness of the steel is secured high by restricting the added amount of Al small.
  • the invention is also characterized by that the mirror polishing properties of the steel can be enhanced by decreasing the added amount of Ni as an element which forms the intermetallic compound together with Al.
  • Ni is an element which is easily segregated in a stripe form in the steel, and when segregation of Ni occurs in such a form, Ni-rich portions and Ni-poor portions are alternately generated in the steel.
  • the Ni-rich portions are different from the Ni-poor portions in mechanical properties such as hardness and toughness, so that striped (streaky) unevenness occurs in the steel at the time when mirror polishing is performed.
  • Ni and Cu are decreased more than those of a conventional steel containing Ni and Cu, so that the striped unevenness is difficult to occur at the time when mirror polishing is performed.
  • the invention is further greatly characterized by that the added amount of Si is decreased, thereby securing the thermal conductivity of the steel high.
  • a cooling performance of the die is enhanced to improve heat dissipation of the die at the time of injection molding, thereby being able to reduce the time per cycle of molding. That is to say, product molding by injection molding can be performed in high cycles, whereby productivity can be increased.
  • the steel of the invention is particularly suitable for a material for a die for forming plastic products, but is also suitable for a material for a die other than the die for plastic molding, for example, a material for a die for producing (molding) rubber products.
  • each numerical value associated with inequality sign means the amount of the element in terms of % by mass.
  • 0.040 ⁇ C ⁇ 0.100 indicates that the amount of C is more than 0.040% by mass and less than 0.100% by mass. Same shall apply to the others.
  • the preferred range is 0.05 ⁇ Si ⁇ 0.27 which is excellent in the balance of the machinability and the thermal conductivity.
  • Fig. 1 and Table 1 show the machinability after 0.078C-1.19Mn-0.72Cu-1.21Ni-4.02Cr-0.40Mo-0.10V-0.40Al-Si steel was soaked at 900°C for 3 hours and thereafter quenched, followed by tempering at 510°C for 5 hours, with respect to the Si amount.
  • a material for evaluation of the machinability had a hardness of 39 to 42 HRC, and the shape thereof was a square bar of 55 mm ⁇ 55 mm ⁇ 200 mm.
  • the time point when the major flank maximum wear amount of a cutting tool reached 300 ⁇ m was judged as the lifetime (machinability). The longer cutting distance is preferred because of better cutting.
  • Fig. 2 and Table 2 show the thermal conductivity at room temperature after the steels of the invention were soaked at 900°C for 3 hours and thereafter quenched, followed by tempering at 510°C for 5 hours, with respect to the Si amount.
  • the steel materials were the following three kinds:
  • a material for evaluation of the thermal conductivity had a hardness of 39 to 42 HRC, and the shape thereof was a small disk of 10 mm diameter ⁇ 2 mm.
  • the higher thermal conductivity is preferred, because the die formed is more excellent in cooling performance.
  • the thermal conductivity varies according to the components of the steel material, a tendency of an increase in thermal conductivity with a decrease in Si is the same.
  • a measure for judging whether the die formed is high in cooling performance or not is whether the thermal conductivity of the steel material at 200°C is 26 W/(m ⁇ K) or more or not.
  • the reason for paying attention to 200°C is that during an injection molding process, the temperature of a die surface is within the range of 30 to 300°C, particularly around 200°C, in many cases.
  • the steel material having a thermal conductivity of 28 W/(m ⁇ K) or more at 200°C is preferred.
  • the thermal conductivity is 26 W/(m ⁇ K) or more
  • the cooling performance is considerably high.
  • the thermal conductivity becomes somewhat low. Nevertheless, it is preferred that the steel material has a thermal conductivity of 26 W/(m ⁇ K) or more at 200°C.
  • the problems described above are solved, and the die can be efficiently cooled. That is to say, by increasing the thermal conductivity of the die, the sufficient cooling effect can be obtained without putting the cooling holes extremely close to the die surface. For this reason, the problem of early cracking of the die is hard to occur. Further, no special equipment is necessary for production of the die, and it is possible to produce the die in the same process as conventionally used. It is an outstanding characteristic of the invention to balance the thermal conductivity with the other characteristics as described above.
  • Mn hardenability during quenching is insufficient.
  • Mn 1.45, the thermal conductivity is significantly decreased.
  • Mn is easily segregated at the time of coagulation, and significant segmentation has adverse effects on the mirror polishing properties in the case where the die is formed of the steel.
  • the preferred range thereof is 1.15 ⁇ Mn ⁇ 1.39 which is excellent in the balance of the hardenability during quenching, the thermal conductivity and the mirror polishing properties.
  • the aging precipitation of Cu is an effective means for securing the strength of low-C steel.
  • Conventional steels utilizing the aging precipitation of Cu contain 1 to 3% of Cu in many cases.
  • the sufficient strength can be obtained by a combination of the secondary precipitation of the carbide with the aging precipitation of the intermetallic compound (composed of Ni and Al).
  • Ni ⁇ 0.30 an effect of improving the hardenability during quenching is small.
  • Ni ⁇ 1.78 the material cost is extremely increased.
  • Ni is easily segregated at the time of coagulation, and significant segmentation has adverse effects on the mirror polishing properties in the case where the die is formed of the steel.
  • the preferred range thereof is 0.39 ⁇ Ni ⁇ 1.55 which is excellent in the balance of the hardenability during quenching, the cost and the mirror polishing properties.
  • V ⁇ 0.02 it is difficult to obtain a hardness of 35 HRC or more which is necessary for securing the high mirror surface properties, particularly when the tempering temperature is high.
  • V ⁇ 0.50 the impact value and the mechanical fatigue strength are significantly decreased.
  • the preferred range thereof is 0.05 ⁇ V ⁇ 0.40 which is excellent in the balance of the hardness and the impact value.
  • Fig. 3 shows the HRC hardness at room temperature after 0.080C-0.19Si-1.23Mn-0.72Cu-1.20Ni-4.01Cr-0.38Mo-0.12V-Al steel was soaked at 900°C for 3 hours and thereafter quenched, followed by tempering at 525°C for 5 hours, with respect to the Al amount.
  • a hardness of 35 HRC or more which is necessary for securing the high mirror surface properties, it is necessary to be Al>0.10, and when Al>0.14, the hardness is more stably obtained.
  • Fig. 4 shows the impact value evaluated by performing a Charpy impact test using a JIS No. 3 impact test specimen of 10 mm ⁇ 10 mm ⁇ 55 mm , after a square bar of 11 mm ⁇ 11 mm ⁇ 55 mm of 0.080C-0.19Si-1.23Mn-0.72Cu-1.20Ni-4.01Cr-0.38Mo-0.12V-Al steel was soaked at 900°C for 3 hours and thereafter quenched by rapid cooling, followed by tempering at 500 to 550°C for 5 hours to obtain a hardness of 39 to 42 HRC, with respect to the Al amount.
  • the test temperature was room temperature.
  • the larger impact value is preferred because of higher cracking resistance.
  • the low impact value poses a problem.
  • the steel of the invention in order to solve this problem, it has been studied to decrease Al.
  • the impact value is increased by a decrease in Al, and an effect thereof becomes obvious in Al ⁇ 0.5.
  • Al ⁇ 0.47 a high impact value is more stably obtained.
  • the hardness is effectively obtained by utilizing 3 types of dispersion strengthening mechanisms, specifically, (1) the secondary precipitation of the carbide mainly composed of Mo or V, (2) the aging precipitation of Cu and (3) the aging precipitation of the intermetallic compound composed of Ni and Al.
  • Conventional steels utilizing intermetallic compounds contain 2 to 3% of Ni and 1 to 2% of Al in many cases.
  • the high impact value is achieved while effectively obtaining the hardness by a combination of (1) with (2) without using Ni and Al in such large amounts.
  • the steel of the invention contains C in small amounts, so that it is difficult to secure the strength depending on the tempering temperature.
  • W and/or Co is selectively added to maintain the strength.
  • W increases the strength by precipitation of a carbide.
  • Co increases the strength by solid dissolving thereof into a matrix, and at the same time, contributes to precipitation hardening through changes in carbide morphology. Specifically, at least one of 0.30 ⁇ W ⁇ 4.00 and 0.30 ⁇ Co ⁇ 3.00 is allowed to be contained.
  • the die size tends to become large with an increase in size and integration of parts. It is difficult to cool a large-sized die. For this reason, when the large-sized die of a steel material having low hardenability during quenching is quenched, ferrite, pearlite or coarse bainite is precipitated during quenching to deteriorate various characteristics.
  • the steel of the invention has considerably high hardenability during quenching, so that such a concern is less likely present.
  • the hardenability during quenching can be further enhanced by adding B.
  • 0.0001 ⁇ B ⁇ 0.0050 is allowed to be contained.
  • a nitride is allowed to be formed with an element having a stronger affinity with N than B to avoid the binding of B and N.
  • Examples of such elements include the respective elements enumerated in item 3 above.
  • the elements enumerated in item 3 above have an effect of fixing N, even when present at an impurity level. However, depending on the N amount which can be contained in a manufacturing process, they are preferably added within the ranges defined in item 3 above.
  • the steel of the invention is somewhat lower in the Si amount than a steel (Si>0.4) having extremely excellent machinability. For this reason, there is a concern that it becomes difficult to perform machine processing into a die configuration or to make holes. In such a case, S, Ca, Se, Te, Bi and/or Pb are selectively added to improve the machinability.
  • At least one of 0.003 ⁇ S ⁇ 0.050, 0.0005 ⁇ Ca ⁇ 0.2000, 0.03 ⁇ Se ⁇ 0.50, 0.005 ⁇ Te ⁇ 0.100, 0.01 ⁇ Bi ⁇ 0.30 and 0.03 ⁇ Pb ⁇ 0.50 is allowed to be contained.
  • Mn+Cr+0.5Ni>5.00 is adopted, thereby being able to further reduce a risk that ferrite, pearlite or coarse bainite is precipitated during quenching.
  • Mn+Cr+0.5Ni ⁇ 6.20 is adopted.
  • the range particularly excellent in the balance of the hardenability during quenching and the thermal conductivity is 5.00 ⁇ Mn+Cr+0.5Ni ⁇ 6.20, and the more preferred range is 5.20 ⁇ Mn+Cr+0.5Ni ⁇ 6.05.
  • Fig. 5 shows the impact value (2 mm U-notch) of a Charpy impact test at room temperature in a state where the steels of the invention were soaked at 900°C for 3 hours and thereafter quenched, followed by tempering at 520°C for 5 hours to obtain a hardness of 39 to 41 HRC, with respect to the Mn+Cr+0.5Ni amount.
  • the materials there are used all the following 22 steel grades:
  • Steel L has a composition in which Mn, Cr and Ni are added in the lower limit amounts
  • steel M has a composition in which Mn, Cr and Ni are added in the upper limit amounts.
  • steel R1 to R4 systems consist of 20 steel grades in which Mn and Ni are arbitrarily added within the range defined in item 8 above. Quenching is performed herein as a process in which a large section die is simulated. That is to say, the cooling rate is 15°C/min from 900°C to 600°C, and 3°C/min from 600°C to room temperature.
  • the material which provides a high impact value even by such slow quenching is excellent in hardenability during quenching, and can be used also for a large die without anxiety.
  • steel L also has a relatively high compact value of 21 J/cm 2 , which shows that the component systems of the steels of the invention are excellent in hardenability during quenching.
  • steel materials there are many steels having an impact value of 15 J/cm 2 or less. Paying attention to Mn+Cr+0.5Ni>5.00 herein, an increase in the impact value is observed, and it is apparent that this is a region particularly excellent in hardenability during quenching. When Mn+Cr+0.5Ni>5.20, the high thermal conductivity (appropriately 25 J/cm 2 or more) is further stably obtained.
  • Fig. 6 shows the relationship between the thermal conductivity at 200°C and Mn+Cr+0.5Ni.
  • the materials there are used the same 22 steel grades as in Fig. 5 .
  • the thermal conductivity decreases with an increase of alloy elements.
  • Steel M also has a relatively high thermal conductivity of 24.4 W/(m ⁇ K), which shows that the component systems of the steels of the invention are excellent in thermal conductivity.
  • thermal conductivity 24 W/(m ⁇ K) or less. Paying attention to Mn+Cr+0.5Ni ⁇ 6.20 herein, 28 W/(m ⁇ K) or more is observed, and it is apparent that this is a region of particularly high thermal conductivity.
  • Mn+Cr+0.5Ni ⁇ 6.05 the high thermal conductivity is further stably obtained.
  • Mn+Cr+0.5Ni ⁇ .20 when Cr>4.50, Mn+Cr+0.5Ni ⁇ .20 may be adopted.
  • the hardenability during quenching in that case can be said to be somewhat excessive.
  • the impact value is increased, and moreover, a larger die can also be quenched without anxiety.
  • the thermal conductivity thereof is lower than that of the steel in which Mn+Cr+0.5Ni ⁇ 6.20. Nevertheless, when the thermal conductivity is 26 W/(m ⁇ K) or more, cooling power as the die is sufficiently large. That is to say, for Mn+Cr+0.5Ni ⁇ 6.20, there is selected a component system in which the thermal conductivity becomes 26 W/(m ⁇ K) or more at 200°C.
  • 0.5Mo+V ⁇ 0.45 is adopted.
  • the range which is particularly excellent in the balance of the above-mentioned characteristics is 0.19 ⁇ 0.5Mo+V ⁇ 0.45.
  • the more preferred range is 0.22 ⁇ 0.5Mo+V ⁇ 0.42.
  • tempering is sometimes necessarily performed at high temperature in an after process such as nitriding.
  • 0.5Mo+V ⁇ 0.45 may be adopted.
  • Fig. 7 shows the HRC hardness at room temperature after the steels of the invention were soaked at 900°C for 3 hours and thereafter quenched, followed by tempering at 535°C for 5 hours, with respect to the 0.5Mo+V amount.
  • materials there are used all the following 22 steel grades:
  • Steel L2 contains Mo and V in the lower limit amounts
  • steel M2 contains Mo and V in the upper limit amounts
  • steel V1 to V4 systems consist of 20 steel grades in which V is arbitrarily added within the range defined in item 9 above.
  • Fig. 8 shows the relationship between the impact value and Mo+V.
  • the materials there are used the same 22 steel grades as in Fig. 7 .
  • the correlation is not simple. The reason for this is that influences of structural refinement, matrix embrittlement and crystallized materials are overlapped one another.
  • the impact value is increased up to a certain added amount because of structural refinement.
  • an increase in solid solution amount embrittles the matrix, so that the impact value is decreased by excessive addition of Mo.
  • V is added, grains are refined up to a certain added amount thereof, resulting in an increase in the impact value.
  • V When V is excessively added, coarse crystallized materials mainly composed of V, C or N are generated at the time of coagulation in steel ingot production. These materials act as starting points, so that the impact value is decreased. Further, in the steel excessively containing V, VC is precipitated in ⁇ grain boundaries at the time of cooling of quenching, which also contributes to a decrease in the impact value.
  • the minimal amount thereof may be the amount in any one of the inventive steels as summarized in Table 3.
  • the maximum amount thereof may be the amount in any one of the inventive steels as summarized in Table 3.
  • the minimal value thereof may be the value in any one of the inventive steels as summarized in Table 3.
  • the maximum value thereof may be the value in any one of the inventive steels as summarized in Table 3.
  • an injection molding die for plastic products is provided with many water cooling holes for the purpose of a reduction in production time (molding in high cycles).
  • the insides of the water cooling holes are under a corrosion environment due to water, and in addition, tensile stress acts thereon.
  • a source of tensile stress is thermal stress at the time when a resin is injected or mechanical stress due to deflection of the die at the time of mold cramping or injection.
  • Fig. 9 shows a method for testing whether a steel material is easily cracked or not, when the tensile stress acts under the corrosion environment.
  • a test specimen is cylindrical and has a diameter of 6 mm, and a notch is formed near the center thereof.
  • a notch part has a diameter of 4 mm.
  • Materials have the same alloy components as inventive steel 1, comparative steel 2 and comparative steel 3, which are described later.
  • the test specimen is supported in a cantilever form, and thereafter, a weight is hung from an end opposite to a fixed side, thereby adding bending force to the test specimen.
  • the tensile stress always acts on an upper side of the notch part.
  • water is continuously dropped to the notch part.
  • the time from hanging of the weight to breakage of the test specimen is evaluated.
  • the time to the breakage is longer, it can be judged to be a more excellent die material in which the water cooling cracking is difficult to occur.
  • test specimens are set one by one on 5 testing devices, and evaluation of the same steel grade is performed on all the 5 testing devices in parallel. Then, the time when one of the 5 specimens is broken is recorded as the "breaking time", and the test is finished (even when the remaining 4 specimens are not broken).
  • Fig. 10 shows the breaking time in the case where a load of 44 [N] was put on each of 3 steel grades refined to 39 HRC.
  • Inventive steel 1 had a breaking time of about 1.5 times that of comparative steel 2 and about 300 times that of comparative steel 3. That is to say, when the tensile stress acts thereon under the corrosion environment, inventive steel 1 is difficult to be broken, and therefore can be judged as an excellent die material in which the water cooling cracking is difficult to occur.
  • steel of the invention is characterized by that the water cooling cracking is difficult to occur. This is because the corrosion resistance is high, which makes it difficult to generate a corroded part, and the toughness is high, which makes it difficult to rapidly develop a crack. Further, the steel material is embrittled by hydrogen entering from water to promote breakage. The main reason for the difficulty of the steel of the invention to be broken is also that the kind and amount of precipitates (the intermetallic compound composed of Ni and Al, aging precipitated Cu and MnS, and the like) which trap hydrogen to render it harmless are proper.
  • the steel of the invention is characterized by that the heat treatment hardness is easily adjustable and difficult to depart from a severe hardness standard. Description will be made herein taking as an example the case where a hardness standard within the narrow range of 39 to 41 HRC is required.
  • Materials have the same alloy components as inventive steel 1 and comparative steel 1, which are described later.
  • Fig. 11 shows changes in hardness to the tempering temperature of inventive steel 1 and comparative steel 1.
  • comparative steel 1 in order to satisfy the standard of 39 to 41 HRC, it is necessary to soak the steel material within the range of 10°C from 550 to 560°C. Accordingly, tempering conditions to be set are 555°C ⁇ 5 hr.
  • the temperature fluctuation range during soaking in a heat treating furnace is generally from 5 to 15°C. Further, even when the temperature fluctuation range during soaking is extremely small, a difference in temperature of 5 to 15°C is generated between positions in the furnace. Addition of both the differences in temperature results in generation of a difference in temperature of up to about 30°C.
  • comparative steel 1 is actually heated at 540 to 570°C even when soaking at 555°C is intended.
  • this heating condition corresponds to a condition for giving 37 to 42 HRC. That is to say, it is extremely difficult to refine steel 1 for comparison to the narrow range of 39 to 41 HRC, and the hardness in cross-section becomes 37 to 42 HRC.
  • inventive steel 1 may be heated in a temperature region of 527°C or less, in order to satisfy the standard of 39 to 41 HRC.
  • Tempering conditions to be set are, for example, 510°C ⁇ 5 hr. From the problem of the variation in furnace temperature described above, the steel of the invention is actually heated at 495 to 525°C. Nevertheless, a hardness of approximately 40 HRC is obtained.
  • the steel of the invention is characterized by that the hardness is easily controllable within the narrow range. This is an effect of making proper the amounts of the carbide containing Cr, Mo or V, the intermetallic compound composed of Ni and Al, and Cu precipitated by adjusting the balance of C-Cr-Mo-V-Cu-Ni-Al, thereby reducing changes in hardness to the tempering temperature.
  • This block was reheated at 900°C. After keeping for 3 hours, the block was immersed in oil of 40 to 100°C to perform quenching. Further, the block was kept in a temperature region of 350 to 560°C for 5 hours to adjust the hardness to 35 to 43 HRC by refining. Using a material cut out from near the center of the block after refining, there were evaluated the machinability, the impact value, the thermal conductivity, the mirror surface properties, the weldability, the corrosion resistance, the sensitivity of water cooling hole cracking and variations in hardness. Further, production cost was also evaluated.
  • the thermal conductivity is a value measured by a laser flash method at 200°C.
  • the larger number is preferred because the die formed is more excellent in cooling performance.
  • the mirror polishing properties mean the upper limit grain size which generates no defect (such as undulation, tarnish and pin holes) on a surface of the steel material, when polished with an abrasive with changing the grain size thereof.
  • the larger this number the smaller the abrasive grain of the abrasive, which means that the steel material can be finely polished.
  • Such a steel material is preferred because of being usable for the higher-grade die.
  • the machinability was judged by a wear state of a cutting tool at the time when a cutting distance of 1,000 mm was cut, standardizing the cut amount and the feed rate.
  • the case where the wear amount of the cutting tool was small ( ⁇ 150 ⁇ m) and the wear was normal was indicated as , the case where the wear amount was large ( ⁇ 300 ⁇ m) was indicated as ⁇ , the case where the wear amount was further increased ( ⁇ 300 ⁇ m) and the abnormal wear was observed was indicated as ⁇ , and the case where in addition to the abnormal wear, the tool was chipped was indicated as ⁇ .
  • the impact value was judged by the value of a 2 mm U-notch test specimen (JIS No. 3) at room temperature. That is to say, the case where the impact value was 40 J/cm 2 or more was indicated as , the case where the impact value was from 30 to less than 40 J/cm 2 was indicated as ⁇ , the case where the impact value was from 20 to less than 30 J/cm 2 was indicated as ⁇ , and the case where the impact value was less than 20 J/cm 2 was indicated as ⁇ .
  • the weldability was judged from the results obtained by performing multi-pass welding using a proper welding rod appropriate for the C amount, cutting a welded part, and examining hardness distribution and cracks. That is to say, the case where there were no cracks and no site in which the hardness was significantly decreased was indicated as , the case where there were no cracks but a site in which the hardness was decreased was indicated as ⁇ , the case where there were no cracks but a site in which the hardness was largely decreased was indicated as ⁇ , and the case where cracks occurred was indicated as ⁇ .
  • the corrosion resistance (weather resistance) was judged from the degree of rust at the time when the mirror-polished material was allowed to stand on the shore in an environment exposed to rain for 1 month. That is to say, the case where the material was hardly rusted or point-like corroded parts were slightly observed was indicated as , the case where point-like corroded parts were remarkable was indicated as ⁇ , the case where corroded parts were connected together to form rust widely spread was indicated as ⁇ , and the case where a rust region was further spread to decrease a metallic luster part was indicated as ⁇ .
  • the sensitivity of water cooling hole cracking was evaluated by the test method described above. The test was performed putting a load of 90% of the bending breaking strength on all the materials. The breaking time in this case was evaluated as the sensitivity of water cooling hole cracking.
  • the variation in hardness is a difference between the maximum value and the minimum value of the HRC hardness measured at 5 places (near 4 corners and the center) on a surface of a block material.
  • the respective sites of the block material do not have the same hardness under the influence of the variation in furnace temperature.
  • the variation in hardness was evaluated.
  • the smaller variation in hardness means that the hardness falls in a narrower range even when the furnace temperature fluctuates, so that such a material is a steel material which is easily controllable in hardness.
  • inventive steels of particular note is the high hardness of the thermal conductivity, which is stably 26 W/(m ⁇ K) or more.
  • the steels other than inventive steels 19 to 22 secure a hardness of 28 W/(m ⁇ K) or more. That is to say, deficiency in cooling performance of the die is difficult to occur.
  • grain size #8,000 or more is satisfied, so that the steels of the invention can be used for the die having a high surface quality level.
  • the steels of the invention has no " ⁇ " for the other characteristics, which are qualitatively evaluated by symbols, and it is obvious at a glance that they are good in balance of the various characteristics.
  • the steels of the invention have high thermal conductivity and mirror polishing properties as basic performances, and are also excellent in the other characteristics and cost performance. Further, the average hardness at room temperature is also within the range of 35 to 45 HRC.
  • the breaking time in the test which simulates the water cooling hole cracking exceeds 100 hours. There are no steels of the invention which are broken within several hours or tens of hours, so that it is considered that the water cooling hole cracking is difficult to occur.
  • the variation in hardness falls within 3.
  • the variation in hardness is within 2. That is to say, even when a narrow hardness standard is required, the steels of the invention can comply therewith.
  • Comparative steel 1 is excellent in mirror polishing properties, and also high in thermal conductivity and machinability. On the other hand, it has defects in impact value and corrosion resistance, which causes problems of cracking and rust. Comparative steel 2 is excellent in mirror polishing properties and also good in weldability. On the other hand, it has defects in thermal conductivity and impact value, which causes problems of deficiency in cooling performance of the die and cracking. Comparative steel 3 is a steel material fairly well balanced. However, the cooling performance of the die is deficient because of its low thermal conductivity. In nowadays in which molding in high cycles has been demanded, this is a fetal defect. Further, the cost is not cheap, and expensive for the steel material characteristics.
  • Comparative steel 4 is high in thermal conductivity and also good in machinability. On the other hand, it has defects in corrosion resistance and mirror polishing properties, so that the range of application thereof is considerably limited. Comparative steel 5 is excellent in mirror polishing properties and also good in corrosion resistance. On the other hand, it has defects in machinability and thermal conductivity, which causes problems of difficulty of die machining and deficiency in cooling performance of the die. Comparative steel 6 is excellent in mirror polishing properties and also good in corrosion resistance. On the other hand, it has defects in machinability, impact value, weldability and thermal conductivity, which causes problems of difficulty of die machining or repairs and further deficiency in cooling performance of the die.
  • the breaking time in the test which simulates the water cooling hole cracking is as extremely low as less than 40 hours. Such steels are considered to be at high risk of occurrence of the water cooling hole cracking.
  • comparative steels have problems in characteristics and cost.
  • Inventive steels have high thermal conductivity and mirror polishing properties while securing a hardness of 35 HRC or more, and are also excellent in the other characteristics and cost performance.
  • the 3 types of dispersion strengthening mechanisms are (1) the secondary precipitation of the carbide mainly composed of Mo or V, (2) the aging precipitation of Cu and (3) the aging precipitation of the intermetallic compound composed of Ni and Al. Moreover, the invention is also characterized by achievement of (2) and (3) in a state where the alloy element amount is smaller than that of the conventional steels, thereby balancing the strength with the other characteristics.

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Claims (10)

  1. Acier pour moule de moulage, ledit acier contenant, en % en poids,
    0,040 < C < 0,100,
    0,03 < Si < 0,28,
    1,11 < Mn < 1,45,
    0,30 < Cu < 0,77,
    0,30 < Ni < 1,78,
    3,23 < Cr < 9,00,
    0,10 < Al < 0,50,
    0,04 < Mo < 1,00, et
    0,02 < V < 0,50,
    et comprenant optionnellement :
    W ≤ 4,00,
    Co ≤ 3,00,
    Nb ≤ 0,100,
    Ta ≤ 0,100,
    Ti ≤ 0,100,
    Zr ≤ 0,100,
    B ≤ 0,0050,
    S ≤ 0,050,
    Ca ≤ 0,2000,
    Se ≤ 0,50,
    Te ≤ 0,100,
    Bi ≤ 0,30, et
    Pb ≤ 0,50,
    le reste étant Fe et des impuretés inévitables,
    ledit acier satisfaisant, en % en poids, à
    5,00 < Mn + Cr + 0,5 Ni < 6,20.
  2. Acier pour moule de moulage, ledit acier contenant, en % en poids, 0,040 < C < 0,100,
    0,03 < Si < 0,28,
    1,11 < Mn < 1,45,
    0,30 < Cu < 0,77,
    0,30 < Ni < 1,78,
    3,23 < Cr < 9,00,
    0,10 < Al < 0,50 ; et
    0,04 < Mo < 1,00, et
    0,02 < V < 0,50,
    et comprenant optionnellement :
    W ≤ 4,00,
    Co ≤ 3,00,
    Nb ≤ 0,100,
    Ta ≤ 0,100,
    Ti ≤ 0,100,
    Zr ≤ 0,100,
    B ≤ 0,0050,
    S ≤ 0,050,
    Ca ≤ 0,2000,
    Se ≤ 0,50,
    Te ≤ 0,100,
    Bi ≤ 0,30, et
    Pb ≤ 0,50,
    le reste étant Fe et des impuretés inévitables,
    ledit acier satisfaisant, en % en poids, à
    0,19 < 0,5 Mo + V < 0,45.
  3. Acier pour moule de moulage selon la revendication 2, ledit acier satisfaisant à, en % en poids, 5,00 < Mn + Cr + 0,5 Ni < 6,20.
  4. Acier pour moule de moulage selon la revendication 1, 2, ou 3, comprenant, en % en poids, au moins un élément parmi :
    0,30 < W ≤ 4,00, et
    0,30 < Co ≤ 3,00.
  5. Acier pour moule de moulage selon l'une quelconque des revendications 1 à 4, comprenant, en % en poids, au moins un élément parmi :
    0,003 < S ≤ 0,050,
    0,0005 < Ca ≤ 0,2000,
    0,03 < Se ≤ 0,50,
    0,005 < Te ≤ 0,100,
    0,01 < Bi ≤ 0,30, et
    0,03 < Pb ≤ 0,50.
  6. Acier pour moule de moulage selon l'une quelconque des revendications 1 à 5, comprenant, en % en poids, 0,0001 < B ≤ 0,0050.
  7. Acier pour moule de moulage selon l'une quelconque des revendications 1 à 6, comprenant, en % en poids, au moins un élément parmi :
    0,003 < S ≤ 0,050,
    0,0005 < Ca ≤ 0,2000,
    0,03 < Se ≤ 0,50,
    0,005 < Te ≤ 0,100,
    0,01 < Bi ≤ 0,30, et
    0,03 < Pb ≤ 0,50.
  8. Acier pour moule de moulage selon l'une quelconque des revendications 1 à 7, ayant une dureté moyenne à température ambiante dans la plage de 35 à 45 HRC.
  9. Acier pour moule de moulage selon l'une quelconque des revendications 1 à 8, ayant une conductivité thermique mesurée par une méthode d'éclair laser à 200°C de 26 W/(m.K) ou plus.
  10. Utilisation de l'acier selon l'une quelconque des revendications 1 à 9, pour la fabrication d'un moule de moulage.
EP13166415.3A 2012-10-20 2013-05-03 Acier pour filière de moulage présentant une excellente conductivité thermique, des propriétés de polissage en miroir et une excellente ténacité Not-in-force EP2722406B1 (fr)

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JP6859623B2 (ja) 2015-09-11 2021-04-14 大同特殊鋼株式会社 金型用鋼及び成形具
US11482355B2 (en) 2016-07-11 2022-10-25 Daido Steel Co., Ltd. Soft magnetic alloy
JP6859862B2 (ja) * 2016-07-11 2021-04-14 大同特殊鋼株式会社 軟磁性合金
JP7392330B2 (ja) * 2018-10-12 2023-12-06 大同特殊鋼株式会社 金型用鋼及び金型
EP3636791B1 (fr) * 2018-10-12 2021-05-05 Daido Steel Co., Ltd. Acier pour moule
CN110230009B (zh) * 2019-05-14 2020-09-29 鞍钢股份有限公司 一种具有良好切削性能的热作模具钢及其制备方法
CN110195186B (zh) * 2019-05-14 2021-02-23 鞍钢股份有限公司 一种特厚热轧高合金热作模具钢及其制备方法
CN111809114B (zh) * 2020-07-07 2021-09-14 鞍钢股份有限公司 具有优异高温强度的塑料模具钢及其制备方法
CN113061801A (zh) * 2021-02-08 2021-07-02 中航上大高温合金材料股份有限公司 一种耐蚀镜面模具钢及制造方法
CN113373380B (zh) * 2021-06-30 2022-07-01 宝武集团鄂城钢铁有限公司 一种锆处理的经济型塑料模具钢及其生产方法
CN113664200B (zh) * 2021-07-28 2023-03-24 深圳市泛海统联精密制造股份有限公司 一种金属粉末注射成型工艺制备镜面抛光产品的方法
CN114000063A (zh) * 2021-11-05 2022-02-01 安徽工程大学 一种增材制造高导热模具钢材料及其制备方法
CN114250422B (zh) * 2021-12-31 2022-09-30 安徽哈特三维科技有限公司 一种韧性好热导率高的模具钢及其制备方法
CN114807774B (zh) * 2022-06-21 2023-05-30 育材堂（苏州）材料科技有限公司 热作模具钢、其热处理方法及热作模具

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CN103774047B (zh) 2017-03-01
TWI576441B (zh) 2017-04-01
KR20140051039A (ko) 2014-04-30
CN103774047A (zh) 2014-05-07
KR101928106B1 (ko) 2018-12-11
TW201416462A (zh) 2014-05-01

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