EP2714957A1 - Procédé d'application d'une couche de protection, élément revêtu d'une couche de protection et turbine à gaz dotée d'un tel élément - Google Patents
Procédé d'application d'une couche de protection, élément revêtu d'une couche de protection et turbine à gaz dotée d'un tel élémentInfo
- Publication number
- EP2714957A1 EP2714957A1 EP12725000.9A EP12725000A EP2714957A1 EP 2714957 A1 EP2714957 A1 EP 2714957A1 EP 12725000 A EP12725000 A EP 12725000A EP 2714957 A1 EP2714957 A1 EP 2714957A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- diffusion layer
- component
- diffusion
- protective layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims abstract description 35
- 239000011241 protective layer Substances 0.000 title claims abstract description 20
- 239000010410 layer Substances 0.000 claims abstract description 69
- 238000009792 diffusion process Methods 0.000 claims abstract description 49
- 239000012790 adhesive layer Substances 0.000 claims abstract description 25
- 239000010953 base metal Substances 0.000 claims abstract description 17
- 239000000919 ceramic Substances 0.000 claims abstract description 14
- 238000005260 corrosion Methods 0.000 claims abstract description 8
- 230000007797 corrosion Effects 0.000 claims abstract description 7
- 230000003628 erosive effect Effects 0.000 claims abstract description 7
- 238000007750 plasma spraying Methods 0.000 claims abstract description 6
- 239000012720 thermal barrier coating Substances 0.000 claims description 18
- 238000009499 grossing Methods 0.000 claims description 9
- 230000003746 surface roughness Effects 0.000 claims description 6
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000007751 thermal spraying Methods 0.000 claims description 3
- 229910002077 partially stabilized zirconia Inorganic materials 0.000 claims description 2
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 abstract 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 abstract 1
- 229910001928 zirconium oxide Inorganic materials 0.000 abstract 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 8
- 239000012071 phase Substances 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 238000010285 flame spraying Methods 0.000 description 4
- 229910000943 NiAl Inorganic materials 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000007749 high velocity oxygen fuel spraying Methods 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000010290 vacuum plasma spraying Methods 0.000 description 2
- 208000035874 Excoriation Diseases 0.000 description 1
- 229910006020 NiCoAl Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 238000001947 vapour-phase growth Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/10—Oxides, borides, carbides, nitrides or silicides; Mixtures thereof
- C23C4/11—Oxides
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
- F01D5/28—Selecting particular materials; Particular measures relating thereto; Measures against erosion or corrosion
- F01D5/288—Protective coatings for blades
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/02—Pretreatment of the material to be coated
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/28—Solid state diffusion of only metal elements or silicon into metallic material surfaces using solids, e.g. powders, pastes
- C23C10/34—Embedding in a powder mixture, i.e. pack cementation
- C23C10/36—Embedding in a powder mixture, i.e. pack cementation only one element being diffused
- C23C10/48—Aluminising
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/60—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
- C23C4/073—Metallic material containing MCrAl or MCrAlY alloys, where M is nickel, cobalt or iron, with or without non-metal elements
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/10—Oxides, borides, carbides, nitrides or silicides; Mixtures thereof
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
- C23C4/134—Plasma spraying
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/18—After-treatment
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12611—Oxide-containing component
Definitions
- the invention relates to a method for applying a protective layer on a base metal detail with the features of the preamble of claim 1 and a coated with such a protective layer component for use in a
- a method of the type mentioned in the introduction is e.g. from EP 1 637 622 A1.
- Thermal barrier coatings serve to lower the material temperature of cooled components. As a result, their life can be extended, cooling air saved or the gas turbine can be operated with higher inlet temperatures.
- Thermal barrier coating systems always consist of a metallic adhesive layer connected by diffusion to the base metal ⁇ base metal) and an overlying ceramic layer with poor thermal conductivity, which represents the actual barrier against heat flow and protects the base metal detail against high temperature corrosion and high temperature erosion.
- Ceramic material for the thermal barrier coating has zirconia
- thermal insulation layers are classified according to the respective application method into two main classes.
- a first class are thermal barrier coatings by physical
- thermal barrier coating is chemically bonded by formation of an Al, Zr mixed oxide on a pure alumina (TGO) film formed by the bond coat during application and then in service.
- TGO pure alumina
- thermal barrier coatings which are sprayed thermally (usually with atmospheric plasma, APS).
- Thermal barrier coatings depending on the desired layer thickness and stress distribution, a porosity between about 10 and 25 vol .-% set. Since the bonding of the ceramic layer to the adhesive layer should take place here by mechanical clamping, the adhesive layer is sprayed in a targeted rough manner in order to maximize the interface and thus the adhesion forces. A certain amount of chemical bonding due to TGO formation only occurs during long-term operation. This application process is relatively simple, resulting in relatively cheap coating costs.
- the invention has the object of developing a method according to the preamble of claim 1 so that it achieves a good thermal fatigue resistance of the protective layer, but nevertheless can be carried out in a simple manner. This is achieved with the features in the characterizing part of claim 1 reached
- the invention is also based on the object, one with a against
- Protective layer on the component can be produced in a simple manner and has a good thermal fatigue resistance. This is achieved with a component according to claim 7 or with a gas turbine according to claim 8.
- M Ni, Co
- MCrAlY layers contain the intermetallic ß phase NiCoAl as an aluminum supply, but this also has a
- the MCrAlY layers are overly aluminized with an Al diffusion layer. Because of the risk of embrittlement, this is largely due to aluminum arms (AI ⁇ 8%)
- the structure of an aluminized MCrAlY layer consists of an inner, largely unchanged y, ß mixed phase, ie a diffusion zone in which the Al content increases to about 20%, and an outer ß-NiAl phase with a proportion of about 30% AI.
- This outer ß-NiAi phase represents a certain weak point of the layer system in terms of brittleness and crack sensitivity. It therefore becomes subjected the overaligned layer to an abrasive treatment so that the outer ⁇ -NiAl phase is removed down to the diffusion zone.
- the aluminum activity is favorably influenced, so that the ability to TGO formation is favored.
- a good bonding of the ceramic layer can be achieved without the need for a rough adhesion layer, which makes it possible, inter alia, for the MC rAI Y layer by means of low-pressure plasma spraying (LPPS) or by thermal spraying, for example high-speed flame spraying (HVOF ) or vacuum plasma spraying.
- LPPS low-pressure plasma spraying
- HVOF high-speed flame spraying
- vacuum plasma spraying for example high-speed flame spraying (HVOF ) or vacuum plasma spraying.
- High-speed fluid injection is less expensive and tends to produce smoother surfaces.
- a method of applying a high temperature corrosion and high temperature erosion resistant protective layer to a base metal wherein an MCrAlY based adhesive layer is applied to the base metal, the adhesive layer
- Overalumination is coated with an Al diffusion layer, the Al diffusion layer is subjected to an abrasive treatment, so that an outer build-up layer of the Al diffusion layer is removed, and on the remaining Al diffusion layer, a ceramic thermal barrier layer of yttria partially stabilized zirconia is applied.
- the method is characterized in that the ceramic thermal barrier coating is applied to the remaining AL diffusion layer by atmospheric plasma spraying.
- the applied adhesive layer is subjected to a smoothing treatment prior to its over-alkalization.
- a smoothing treatment Preferably, in the smoothing treatment, a surface roughness of Ra ⁇ 2 ⁇ m is generated on the adhesive layer.
- the adhesive layer is applied to the base metal by means of thermal spraying, for example high-speed flame spraying (HVOF) or vacuum plasma spraying of high-velocity flame spraying or vapor phase deposition.
- HVOF high-speed flame spraying
- vapor phase deposition for example high-speed flame spraying (HVOF) or vacuum plasma spraying of high-velocity flame spraying or vapor phase deposition.
- the AL diffusion layer is subjected to a smoothing treatment, such that a smoothing treatment takes place on the remaining AL diffusion layer
- the outer build-up layer of the AL diffusion layer is removed so far that the content of Al in a surface of the remaining Al diffusion layer exceeds 18 wt%. and less than 30% by weight.
- a component for use in a hot gas region of a gas turbine having a surface which is at least partially applied in any conceivable combination by a method according to one, several or all of the previously described embodiments of the invention
- High temperature corrosion and high temperature erosion resistant protective coating is provided.
- a gas turbine having a hot gas area and a component arranged therein according to the second aspect of the invention.
- the protective layer has a good thermal endurance, but can nevertheless be produced in a simple manner.
- the invention provides a thermal barrier coating concept that combines the low cost of the APS process with the advantages of chemical bonding between the adhesive and ceramic layers.
- the TCF behavior compared to the classic APS layers can be improved.
- thermal barrier coatings with improved thermal endurance can be produced more easily and thus at lower cost than with EB-PVD processes.
- FIG. 1 shows in a sectional view a region provided with a protective layer of a component of a component arranged in a hot gas region Gas turbine according to an embodiment of the invention.
- FIG. 1 shows a sectional view of a region of a component 10, which is provided in a hot gas region, provided with a protective layer 12-14
- Gas turbine 1 according to an embodiment of the invention.
- the component 10 ' which for example can be designed as a turbine blade or as another hot gas to come into contact component of the gas turbine 1 "has a base metal 11 (base material) having a surface on" the protection against high-temperature corrosion and high-temperature erosion completely or partially with a
- resistant ceramic thermal barrier coating 13 is provided.
- the ceramic thermal barrier coating 13 consists of
- Zirconia partially stabilized with about 7% by weight of yttria International Abbreviation: "YPSZ" by Ytfria Partially Stabiiised Zirconia.
- the adhesive layer 12 is made of a MCrAlY based special alloy (e.g., LCO 22).
- LPPS Low-pressure plasma spraying
- High speed flame spraying HVOF
- the applied adhesive layer 12 is subjected to a smoothing treatment (e.g., fine flattening), to which an adhesive layer 12 is applied
- the overbalancing can be realized by a treatment in which a reactive Al-containing gas, which may be an Al halide (AIX2), at higher temperature
- the outer make coat 14.2 is subjected to abrasive treatment such as abrasion treatment.
- abrasive treatment such as abrasion treatment.
- Hard particle blasting e.g., corundum, silicon carbide, reduced metal wires, etc.
- machining with other known grinding or grinding techniques
- polishing down to the inner diffusion zone 14.1 of the Al diffusion layer 14 removed.
- the abrasive treatment is driven so far that the surface of the remaining Al diffusion layer 14 (diffusion zone 14.1) has an Al content of more than about 18% by weight and less than about 30% by weight.
- the AL diffusion layer 14 is subjected to a smoothing treatment (e.g., fine flattening), so that a surface roughness of .mu.m is applied to the remaining AL diffusion layer 14 (diffusion zone 14.1)
- a smoothing treatment e.g., fine flattening
- the ceramic thermal barrier coating (YPSZ ceramic layer) 13 is then applied to the thus prepared surface of the remaining aluminum diffusion layer 14 by atmospheric plasma spraying (APS), wherein the same parameters can be used for the APS process as in the conventional one Adhesive layers.
- APS atmospheric plasma spraying
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Plasma & Fusion (AREA)
- Physics & Mathematics (AREA)
- General Engineering & Computer Science (AREA)
- Coating By Spraying Or Casting (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
Abstract
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102011103731A DE102011103731A1 (de) | 2011-05-31 | 2011-05-31 | Verfahren zum Aufbringen einer Schutzschicht, mit einer Schutzschicht beschichtetes Bauteil und Gasturbine mit einem solchen Bauteil |
PCT/EP2012/060195 WO2012163991A1 (fr) | 2011-05-31 | 2012-05-31 | Procédé d'application d'une couche de protection, élément revêtu d'une couche de protection et turbine à gaz dotée d'un tel élément |
Publications (1)
Publication Number | Publication Date |
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EP2714957A1 true EP2714957A1 (fr) | 2014-04-09 |
Family
ID=46201638
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12725000.9A Withdrawn EP2714957A1 (fr) | 2011-05-31 | 2012-05-31 | Procédé d'application d'une couche de protection, élément revêtu d'une couche de protection et turbine à gaz dotée d'un tel élément |
Country Status (6)
Country | Link |
---|---|
US (1) | US20140141276A1 (fr) |
EP (1) | EP2714957A1 (fr) |
JP (1) | JP5878629B2 (fr) |
CA (1) | CA2837415C (fr) |
DE (1) | DE102011103731A1 (fr) |
WO (1) | WO2012163991A1 (fr) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3002239B1 (fr) * | 2013-02-15 | 2015-04-10 | Messier Bugatti Dowty | Procede de fabrication d'une piece d'aeronef comportant un substrat et une couche de revetement du substrat |
US9518325B2 (en) * | 2013-03-19 | 2016-12-13 | General Electric Company | Treated coated article and process of treating a coated article |
CN104404436B (zh) * | 2014-11-25 | 2017-02-22 | 西安交通大学 | 基于液相过滤的低压等离子喷涂制备柱状陶瓷涂层的方法 |
DE102016103664A1 (de) | 2016-03-01 | 2017-09-07 | Lufthansa Technik Ag | Strömungselement und Verfahren zum Beschichten eines Strömungselements |
GB201903484D0 (en) * | 2019-03-14 | 2019-05-01 | Rolls Royce Plc | A method of removing a ceramic coating from a ceramic coated metallic article |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5236745A (en) * | 1991-09-13 | 1993-08-17 | General Electric Company | Method for increasing the cyclic spallation life of a thermal barrier coating |
JP3219594B2 (ja) * | 1994-04-27 | 2001-10-15 | 三菱重工業株式会社 | 高温酸化防止用遮熱コーティング方法 |
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DE19801424B4 (de) * | 1998-01-16 | 2004-08-05 | Forschungszentrum Jülich GmbH | Wärmedämmstoff für hohe Temperaturen und seine Verwendung |
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DE102004045049A1 (de) * | 2004-09-15 | 2006-03-16 | Man Turbo Ag | Verfahren zum Aufbringen einer Schutzschicht |
DE102005053531A1 (de) * | 2005-11-08 | 2007-05-10 | Man Turbo Ag | Wärmedämmende Schutzschicht für ein Bauteil innerhalb des Heißgasbereiches einer Gasturbine |
DE102005060243A1 (de) * | 2005-12-14 | 2007-06-21 | Man Turbo Ag | Verfahren zum Beschichten einer Schaufel und Schaufel einer Gasturbine |
WO2007112783A1 (fr) * | 2006-04-06 | 2007-10-11 | Siemens Aktiengesellschaft | Revetement stratifie formant une barriere thermique a porosite elevee et composant |
US20090162692A1 (en) * | 2007-12-24 | 2009-06-25 | Bangalore Aswatha Nagaraj | Coated Superalloy Articles |
DE102008007870A1 (de) * | 2008-02-06 | 2009-08-13 | Forschungszentrum Jülich GmbH | Wärmedämmschichtsystem sowie Verfahren zu seiner Herstellung |
-
2011
- 2011-05-31 DE DE102011103731A patent/DE102011103731A1/de not_active Withdrawn
-
2012
- 2012-05-31 WO PCT/EP2012/060195 patent/WO2012163991A1/fr active Application Filing
- 2012-05-31 US US14/122,495 patent/US20140141276A1/en not_active Abandoned
- 2012-05-31 JP JP2014513181A patent/JP5878629B2/ja not_active Expired - Fee Related
- 2012-05-31 CA CA2837415A patent/CA2837415C/fr not_active Expired - Fee Related
- 2012-05-31 EP EP12725000.9A patent/EP2714957A1/fr not_active Withdrawn
Non-Patent Citations (2)
Title |
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None * |
See also references of WO2012163991A1 * |
Also Published As
Publication number | Publication date |
---|---|
CA2837415A1 (fr) | 2012-12-06 |
JP5878629B2 (ja) | 2016-03-08 |
CA2837415C (fr) | 2016-11-08 |
US20140141276A1 (en) | 2014-05-22 |
JP2014520205A (ja) | 2014-08-21 |
WO2012163991A1 (fr) | 2012-12-06 |
DE102011103731A1 (de) | 2012-12-06 |
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