EP1945834B1 - Couche de protection calorifuge destinée à un composant situé dans la zone des gaz chauds d'une turbine à gaz - Google Patents

Couche de protection calorifuge destinée à un composant situé dans la zone des gaz chauds d'une turbine à gaz Download PDF

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Publication number
EP1945834B1
EP1945834B1 EP06818401.9A EP06818401A EP1945834B1 EP 1945834 B1 EP1945834 B1 EP 1945834B1 EP 06818401 A EP06818401 A EP 06818401A EP 1945834 B1 EP1945834 B1 EP 1945834B1
Authority
EP
European Patent Office
Prior art keywords
layer
heat
insulating protective
bonding layer
protective layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP06818401.9A
Other languages
German (de)
English (en)
Other versions
EP1945834A2 (fr
Inventor
Sharad Chandra
Norbert Czech
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MAN Energy Solutions SE
Original Assignee
MAN Diesel and Turbo SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by MAN Diesel and Turbo SE filed Critical MAN Diesel and Turbo SE
Publication of EP1945834A2 publication Critical patent/EP1945834A2/fr
Application granted granted Critical
Publication of EP1945834B1 publication Critical patent/EP1945834B1/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
    • C23C10/02—Pretreatment of the material to be coated
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/32—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
    • C23C28/321—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer with at least one metal alloy layer
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/32—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
    • C23C28/321—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer with at least one metal alloy layer
    • C23C28/3215—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer with at least one metal alloy layer at least one MCrAlX layer
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/32—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
    • C23C28/325—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer with layers graded in composition or in physical properties
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
    • C23C28/345—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
    • C23C28/345—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
    • C23C28/3455—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer with a refractory ceramic layer, e.g. refractory metal oxide, ZrO2, rare earth oxides or a thermal barrier system comprising at least one refractory oxide layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal

Definitions

  • MCrAlY-based adhesive or overlay layers offer the best possibilities for meeting the chemical and mechanical requirements mechanical requirements.
  • M Ni, Co
  • MCrAlY layers contain the intermetallic ß-phase NiCoAl as an aluminum supply.
  • the ⁇ -phase NiCoAl also has a brittle effect, so that the practically realizable Al content is ⁇ 12 wt .-%.
  • the structure of an aluminized MCrAlY layer consists of the inner, largely unchanged y, ßß mixed phase, a diffusion zone in which the Al content increases to ⁇ 20% and an outer ß-NiAl phase in a proportion of about 30% Al ,
  • the NiAl phase is the weak point of the coating system in terms of brittleness and crack sensitivity.
  • the (inter-) diffusion phenomena between the base material and the MCrAlY layer - in the special case also between the MCrAlY layer and the alitization - become lifetime-determining with increasing application temperature.
  • the diffusion-induced loss of the oxidation-active aluminum in the MCrAlY layer may exceed the oxide-induced loss.
  • the invention has for its object to avoid the disadvantages described above and to slow the diffusion in a generic heat-insulating protective layer without the oxidation properties of the alit Being layer and the ductility, and creep resistance of the layer system are adversely affected.
  • the powder used has the following chemical composition: Co 25 wt%, Cr 21 wt%, Al 8 wt%, Y 0.5 wt%, Re 1.5 wt%, balance Ni.
  • the adhesive layer has the chemical composition of the powder used.
  • the adhesion layer is coated or over-alloyed with an Al diffusion layer to increase its Al content.
  • the overcoating is done by overbalancing, that is, by a treatment in which a reactive Al-containing gas, which is usually an Al-halide (AlX 2 ), becomes an inward diffusion of Al at higher temperature, combined with an outward diffusion of Ni , causes.
  • a reactive Al-containing gas which is usually an Al-halide (AlX 2 )
  • AlX 2 Al-halide
  • the ceramic layer of zirconia partially stabilized by yttrium oxide is applied by one of the methods mentioned at the outset.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Ceramic Engineering (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Coating By Spraying Or Casting (AREA)
  • Turbine Rotor Nozzle Sealing (AREA)
  • Powder Metallurgy (AREA)

Claims (2)

  1. Couche de protection calorifique destinée à un composant situé dans la zone des gaz chauds d'une turbine à gaz, dans lequel la couche de protection calorifique est constituée d'une couche adhérente, une couche d'aluminisation et une couche de céramique, qui est appliquée sur le métal de base du composant, résistant aux températures élevées, dans laquelle la couche adhérente est constituée d'un alliage métallique contenant du Ni, Co, CR, Al, Y [MCrAlY (M=Ni, Co)], dans laquelle la couche d'aluminisation est produite par diffusion entrante d'Al sur la couche adhérente et la couche de céramique est constituée de Zr02, qui est partiellement stabilisé par l'oxyde d'yttrium,
    caractérisée en ce que une perte induite par la durée de vie de la teneur en Al dans la couche adhérente est diminuée de telle sorte que le matériau de la couche adhérente forme un alliage avec un ou plusieurs éléments métalliques avec un grand diamètre d'atome du groupe Re, W, Si, Hf et/ou Ta et en ce que la couche adhérente présente après l'application la composition chimique suivante :
    Ni résiduel
    Co 15 à 30 %
    Cr 15 à 25 %
    Al 6 à 13 %
    Y 0,2 à 0,7 %
    Re jusqu'à 5 %
    W jusqu'à 5 %
    Si jusqu'à 3 %
    Hf jusqu'à 3 %
    Ta jusqu'à 5 %.
  2. Couche de protection calorifique selon la revendication 1,
    caractérisé en ce que le matériau de la couche adhérente forme un alliage avec Re et en ce que la couche adhérente présente après l'application la composition chimique suivante :
    Ni résiduel
    Co 25 %
    Cr 21 %
    Al 8 %
    Y 0,5 %
    Re 1,5 %.
EP06818401.9A 2005-11-08 2006-11-07 Couche de protection calorifuge destinée à un composant situé dans la zone des gaz chauds d'une turbine à gaz Not-in-force EP1945834B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE200510053531 DE102005053531A1 (de) 2005-11-08 2005-11-08 Wärmedämmende Schutzschicht für ein Bauteil innerhalb des Heißgasbereiches einer Gasturbine
PCT/EP2006/010655 WO2007054265A2 (fr) 2005-11-08 2006-11-07 Couche de protection calorifuge destinee a un composant situe dans la zone des gaz chauds d'une turbine a gaz

Publications (2)

Publication Number Publication Date
EP1945834A2 EP1945834A2 (fr) 2008-07-23
EP1945834B1 true EP1945834B1 (fr) 2017-01-04

Family

ID=37691010

Family Applications (1)

Application Number Title Priority Date Filing Date
EP06818401.9A Not-in-force EP1945834B1 (fr) 2005-11-08 2006-11-07 Couche de protection calorifuge destinée à un composant situé dans la zone des gaz chauds d'une turbine à gaz

Country Status (8)

Country Link
US (1) US9139896B2 (fr)
EP (1) EP1945834B1 (fr)
JP (1) JP2009515048A (fr)
CN (1) CN101351576A (fr)
CA (1) CA2629066A1 (fr)
DE (1) DE102005053531A1 (fr)
RU (1) RU2008118065A (fr)
WO (1) WO2007054265A2 (fr)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008018539A1 (de) * 2008-04-12 2009-10-15 Berthold, Jürgen Metallkörper mit metallischer Schutzschicht
EP2216421A1 (fr) * 2009-01-29 2010-08-11 Siemens Aktiengesellschaft Alliage, couche de protection et composant
DE102010010595A1 (de) * 2010-03-08 2011-09-08 Lufthansa Technik Ag Verfahren zur Reparatur von Dichtsegmenten in der Rotor-/Statordichtung einer Gasturbine
FR2960970B1 (fr) * 2010-06-03 2015-02-20 Snecma Mesure de l'endommagement d'une barriere thermique d'aube de turbine
DE102011103731A1 (de) * 2011-05-31 2012-12-06 Man Diesel & Turbo Se Verfahren zum Aufbringen einer Schutzschicht, mit einer Schutzschicht beschichtetes Bauteil und Gasturbine mit einem solchen Bauteil
CN103060747B (zh) * 2012-12-13 2014-10-15 北京航空航天大学 一种采用包埋渗工艺在Ni基高温合金上制备Y改性CoAlNi涂层的方法
EP2971243B1 (fr) 2013-03-13 2020-02-26 General Electric Company Revêtements pour substrats métalliques
US9289917B2 (en) * 2013-10-01 2016-03-22 General Electric Company Method for 3-D printing a pattern for the surface of a turbine shroud
KR102179506B1 (ko) * 2013-12-23 2020-11-17 삼성전자 주식회사 전자장치 및 그 제어방법
US10578014B2 (en) * 2015-11-20 2020-03-03 Tenneco Inc. Combustion engine components with dynamic thermal insulation coating and method of making and using such a coating
CN105463453B (zh) * 2015-11-25 2018-09-14 沈阳黎明航空发动机(集团)有限责任公司 一种界面稳定的热障涂层及其制备方法
CN109844149A (zh) * 2016-09-12 2019-06-04 西门子股份公司 NiCoCrAlY合金、粉末和层体系
US10605785B2 (en) * 2017-06-07 2020-03-31 General Electric Company Sensor system and method
CN108754386A (zh) * 2018-07-27 2018-11-06 北方工业大学 耐热冲击MCrAlY涂层及其制备方法
CN109735798B (zh) * 2019-01-17 2020-08-07 长沙理工大学 抗高温蠕变性优良的改性奥氏体不锈钢及其制备方法
CN111893363B (zh) * 2020-07-31 2021-11-19 西安交通大学 一种具有优异强度塑性匹配的NiCoCr基中熵合金及制备方法
CN112458351B (zh) * 2020-10-22 2021-10-15 中国人民解放军陆军装甲兵学院 高抗压强度的镍钴基高温合金
CN114086101A (zh) * 2021-11-19 2022-02-25 华能国际电力股份有限公司 一种抗高温氧化和热腐蚀热障涂层及制备方法
CN114262859B (zh) * 2021-12-29 2023-01-31 矿冶科技集团有限公司 一种双界面性能强化的MCrAlYX粘结层和热障涂层及其制备方法

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US32121A (en) * 1861-04-23 Francis comtesse
DE1758010A1 (de) * 1968-03-20 1970-12-10 Dr Dietrich Merz Hochwarmfeste Legierungen mit Anteilen an Rhenium und Hafnium
US4034142A (en) * 1975-12-31 1977-07-05 United Technologies Corporation Superalloy base having a coating containing silicon for corrosion/oxidation protection
US4447503A (en) * 1980-05-01 1984-05-08 Howmet Turbine Components Corporation Superalloy coating composition with high temperature oxidation resistance
USRE32121E (en) * 1981-08-05 1986-04-22 United Technologies Corporation Overlay coatings for superalloys
CA1209827A (fr) * 1981-08-05 1986-08-19 David S. Duvall Enduits de surcouche a forte teneur d'yttrium
US4419416A (en) * 1981-08-05 1983-12-06 United Technologies Corporation Overlay coatings for superalloys
US4933239A (en) * 1989-03-06 1990-06-12 United Technologies Corporation Aluminide coating for superalloys
US5268238A (en) * 1989-08-10 1993-12-07 Siemens Aktiengesellschaft Highly corrosion and/or oxidation-resistant protective coating containing rhenium applied to gas turbine component surface and method thereof
DE58908611D1 (de) * 1989-08-10 1994-12-08 Siemens Ag Hochtemperaturfeste korrosionsschutzbeschichtung, insbesondere für gasturbinenbauteile.
US5273712A (en) * 1989-08-10 1993-12-28 Siemens Aktiengesellschaft Highly corrosion and/or oxidation-resistant protective coating containing rhenium
DE3926479A1 (de) * 1989-08-10 1991-02-14 Siemens Ag Rheniumhaltige schutzbeschichtung, mit grosser korrosions- und/oder oxidationsbestaendigkeit
US5087477A (en) * 1990-02-05 1992-02-11 United Technologies Corporation Eb-pvd method for applying ceramic coatings
US5401307A (en) * 1990-08-10 1995-03-28 Siemens Aktiengesellschaft High temperature-resistant corrosion protection coating on a component, in particular a gas turbine component
US5582635A (en) * 1990-08-10 1996-12-10 Siemens Aktiengesellschaft High temperature-resistant corrosion protection coating for a component in particular a gas turbine component
RU2147624C1 (ru) * 1994-10-14 2000-04-20 Сименс АГ Защитный слой для защиты детали от коррозии, окисления и термической перегрузки, а также способ его изготовления
DE19615012A1 (de) * 1995-08-16 1997-02-20 Siemens Ag Erzeugnis zur Führung eines heißen, oxidierenden Gases
JP3258599B2 (ja) * 1996-06-27 2002-02-18 ユナイテッド テクノロジーズ コーポレイション 断熱バリヤコーティングシステム
GB9724844D0 (en) * 1997-11-26 1998-01-21 Rolls Royce Plc A coated superalloy article and a method of coating a superalloy article
DE19807359A1 (de) * 1998-02-21 1999-08-26 Deutsch Zentr Luft & Raumfahrt Wärmedämmschichtsystem mit integrierter Aluminiumoxidschicht
CZ300909B6 (cs) * 1998-02-28 2009-09-09 General Electric Company Vícevrstvový vazební povlak pro povlakový systém tepelné ochranné bariéry a zpusob jeho vytvorení
US20040180233A1 (en) * 1998-04-29 2004-09-16 Siemens Aktiengesellschaft Product having a layer which protects against corrosion. and process for producing a layer which protects against corrosion
AU4505399A (en) * 1999-06-02 2000-12-28 Abb Research Ltd Coating composition for high temperature protection
DE10347363A1 (de) * 2003-10-11 2005-05-12 Mtu Aero Engines Gmbh Verfahren zur lokalen Alitierung, Silizierung oder Chromierung von metallischen Bauteilen
DE102004045049A1 (de) * 2004-09-15 2006-03-16 Man Turbo Ag Verfahren zum Aufbringen einer Schutzschicht

Also Published As

Publication number Publication date
US20090011260A1 (en) 2009-01-08
RU2008118065A (ru) 2009-12-20
WO2007054265A2 (fr) 2007-05-18
DE102005053531A1 (de) 2007-05-10
CN101351576A (zh) 2009-01-21
WO2007054265A3 (fr) 2007-11-01
JP2009515048A (ja) 2009-04-09
CA2629066A1 (fr) 2007-05-18
US9139896B2 (en) 2015-09-22
EP1945834A2 (fr) 2008-07-23

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