Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
  • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
  • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
  • B29C48/05—Filamentary, e.g. strands
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
  • C09J153/02—Vinyl aromatic monomers and conjugated dienes
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
  • B29B9/00—Making granules
  • B29B9/12—Making granules characterised by structure or composition
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J3/00—Processes of treating or compounding macromolecular substances
  • C08J3/12—Powdering or granulating
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J3/00—Processes of treating or compounding macromolecular substances
  • C08J3/12—Powdering or granulating
  • C08J3/124—Treatment for improving the free-flowing characteristics
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J3/00—Processes of treating or compounding macromolecular substances
  • C08J3/12—Powdering or granulating
  • C08J3/126—Polymer particles coated by polymer, e.g. core shell structures
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
  • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
  • C08L23/04—Homopolymers or copolymers of ethene
  • C08L23/06—Polyethene
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
  • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
  • C08L23/04—Homopolymers or copolymers of ethene
  • C08L23/08—Copolymers of ethene
  • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
  • C08L23/0853—Ethene vinyl acetate copolymers
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
  • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
  • C09J11/02—Non-macromolecular additives
  • C09J11/06—Non-macromolecular additives organic
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J191/00—Adhesives based on oils, fats or waxes; Adhesives based on derivatives thereof
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J9/00—Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
  • B29B9/00—Making granules
  • B29B9/02—Making granules by dividing preformed material
  • B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
  • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
  • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
  • B29C48/04—Particle-shaped
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
  • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
  • B29C48/16—Articles comprising two or more components, e.g. co-extruded layers
  • B29C48/18—Articles comprising two or more components, e.g. co-extruded layers the components being layers
  • B29C48/21—Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their surfaces
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
  • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
  • B29C48/25—Component parts, details or accessories; Auxiliary operations
  • B29C48/30—Extrusion nozzles or dies
  • B29C48/345—Extrusion nozzles comprising two or more adjacently arranged ports, for simultaneously extruding multiple strands, e.g. for pelletising
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
  • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
  • B29K2105/0097—Glues or adhesives, e.g. hot melts or thermofusible adhesives
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
  • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
  • C08J2423/04—Homopolymers or copolymers of ethene
  • C08J2423/06—Polyethene
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
  • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
  • C08J2423/04—Homopolymers or copolymers of ethene
  • C08J2423/08—Copolymers of ethene
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J2453/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
  • C08J2453/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J2491/00—Characterised by the use of oils, fats or waxes; Derivatives thereof
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L2555/00—Characteristics of bituminous mixtures
  • C08L2555/40—Mixtures based upon bitumen or asphalt containing functional additives
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
  • C08L91/06—Waxes
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J2453/00—Presence of block copolymer
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J2491/00—Presence of oils, fats or waxes

Definitions

• the invention relates to granulated block-resistant hot melt adhesives, wherein the granules are individually surrounded by a shell.
• This shell should be compatible with the hot melt pressure sensitive adhesive and lead to a homogeneous adhesive in the common melting.
• EP 1812297 describes a process for packaging hot melt adhesives wherein the adhesive is packaged by a shell containing at least 25% by weight of a wax.
• Other constituents described are certain polyethylenes and elastic block copolymers.
• EP 0469564 processes for the packaging of hot melt adhesives are described.
• the sheath material should be compatible with the adhesive.
• the adhesive units are described in amounts of 100 g to 4 kg. Therefore, the proportion of shell material in the adhesive is low.
• polyolefins are described as preferred shell material.
• Object of the present invention is therefore to provide a hot melt adhesive as granules, which can be transported in automatic conveyor systems.
• it has a blocking resistance during storage, and the shell material is chosen so that the adhesive properties are not impaired in the homogeneous melting of the granules.
• a hotmelt adhesive in the form of a granulate wherein the granules comprise a core of the hot melt pressure-sensitive adhesive and a surrounding outer layer of a non-sticky composition, characterized in that the outer layer 5 to 30 wt .-% of a hydrogenated Stryrolblockco- polymers, 20 to 65 wt .-% of at least one oil, and 0 to 15 wt .-% additives.
• the hot melt adhesive according to the invention must be present as granules.
• Granules are particles that are small in size and can still flow. Such granules of solids are known in principle. They may have a size of 1 to 20 mm, preferably the particles are from 2 to 10 mm.
• the weight of granulate particles according to the invention is, for example, less than 20 g, in particular less than 10 g.
• the shape can vary widely, it is influenced by the manufacturing process.
• the grain has a pillow, cylinder-shaped or spherical shape, this may also differ from ideal shapes and be deformed. It is according to the invention necessary that the particles have a non-sticky surface, so that a flowing property of the granules can be ensured.
• Flowable for the invention means that the granules due to its own weight at temperatures of -10 to +40 ° C at an autogenous pressure of 50 cm filling level still "flows" through an opening of 5 cm diameter. If the granules do not stick together, the surface is block-resistant.
• the material of the granule core corresponds to the type and amount of the individual components of a conventional hot melt adhesive composition, in particular one Hot melt pressure sensitive adhesive composition (PSA).
• PSA Hot melt pressure sensitive adhesive composition
• the hot melt adhesives comprise a variety of base polymers which are blended with other ingredients such as plasticizers, tackifiers, and additives to form the adhesive.
• the base polymers essentially determine the adhesive properties with respect to adhesion, strength and temperature behavior. It is also possible to use mixtures as long as they are compatible with one another.
• Suitable base polymers are, for example, elastic block copolymers such as styrene-butadiene, styrene-butadiene-styrene, styrene-isoprene-styrene, styrene-ethylene-butylene-styrene, styrene-ethylene-propylene-styrene; Olefin copolymers, such as ethylene-vinyl acetate polymers, ethylene-methacrylate, ethylene-n-butyl acrylate or ethylene-acrylic acid polymers; Polyolefins such as polyethylene, polypropylene and copolymers; polyacrylates; polyamides; Polyester; Polyvinyl alcohols and copolymers; Polyurethanes.
• elastic block copolymers such as styrene-butadiene, styrene-butadiene-styrene, styrene-is
• EVA ethylene vinyl acetate copolymers
• APAO amorphous polyolefins
• polyethylene and copolymers polyethylene and copolymers
• polyolefins as random, block copolymers or star polymers
• styrene block copolymers such as styrene-butadiene-styrene (SBS), styrene-isoprene-styrene (SIS), polybutenes, poly (meth) acrylates, for example containing C4 to C16 alkyl (meth) acrylic esters.
• SBS styrene-butadiene-styrene
• SIS styrene-isoprene-styrene
• polybutenes poly (meth) acrylates, for example containing C4 to C16 alkyl (meth) acrylic esters.
• polymers prepared by condensation are suitable, such as, for example, thermoplastic non-reactive polyurethanes, in particular diisocyanates and polyols.
• An embodiment of the invention employs inert base polymers, another embodiment employs polymers which contain crosslinkable functional groups which can be subjected to a crosslinking reaction after application.
• the above-mentioned base polymers and additives are included, which may affect certain properties of the adhesive, such. Cohesive strength, adhesion, softening point or processing viscosity. These include, for example, plasticizers, stabilizers, waxes, adhesion promoters, antioxidants, light stabilizers, pigments, fillers or similar additives. The amount can be up to 70% by weight. It is also possible to use several additives as a mixture.
• the hot-melt adhesive suitable according to the invention contains at least one tackifying resin.
• the resin causes additional stickiness of the Adhesive. It is used in an amount of 5 to 50% by weight, preferably 10 to 40% by weight.
• Resins can be selected from aromatic, aliphatic or cycloaliphatic hydrocarbon resins, as well as modified or hydrogenated derivatives.
• resins which can be used in the context of the invention are polyterpene resins, phenolic or aromatic modified polyterpene resins, modified natural resins such as resin acids from gum rosin, tall resin or wood rosin, optionally also hydroabietyl alcohol and its esters, acrylic acid copolymers such as styrene-acrylic acid copolymers and resins based on functional resins hydrocarbon resins. According to the invention, these resins should have a softening point between 50 and 130 ° C (ring-ball method).
• Plasticizers are preferably used to adjust viscosity or flexibility and are generally contained in a concentration of 0-30% by weight, preferably 2-20% by weight.
• Suitable plasticizers are, for example, medicinal white oils, naphthenic mineral oils, polypropylene, polybutene, polyisoprene oligomers, hydrogenated polyisoprene and / or polybutadiene oligomers, paraffinic hydrocarbon oils, benzoate esters, phthalate esters, adipate esters, glycerol esters, vegetable or animal oils and derivatives thereof, polypropylene glycol , Polybutylene glycol, polymethylene glycol.
• the plasticizers also increase the tack of the adhesive composition.
• waxes in amounts of 0 to 20 wt .-% may be added to the hot melt adhesive.
• the amount is dimensioned so that on the one hand, the viscosity is lowered to the desired range, on the other hand, the adhesion is not adversely affected.
• the wax can be of natural or synthetic origin. Vegetable waxes, animal waxes, mineral waxes or petrochemical waxes can be used as natural waxes. Hard waxes such as montan ester waxes, sarsol waxes, etc. can be used as the chemically modified waxes. As synthetic waxes find polyalkylene waxes and polyethylene glycol waxes use.
• petrochemical waxes such as petrolatum, microwaxes and synthetic waxes, in particular polyethylene waxes, polypropylene waxes, Fischer-Tropsch resins, paraffin waxes or microcrystalline waxes.
• antioxidants Another group of additives are stabilizers. Their task is to protect the polymers from degradation during processing. Here are in particular the antioxidants to call. They are usually added in amounts of up to 3 wt .-%, preferably in amounts of about 0.1 to 1, 0 wt .-% of the hot melt pressure sensitive adhesive. Such additives and such hotmelt adhesives are known in the art in principle. He can make a selection of the desired properties of the hot melt adhesive.
• hotmelt adhesive of the core material those having a high pressure-sensitive tackiness, for example, pressure-sensitive adhesive (PSA), are particularly selected. These are understood as adhesives which, applied as a layer, bond to the surface by light pressure with various substrates. However, it is also possible to coat other hotmelt adhesives accordingly.
• PSA pressure-sensitive adhesive
• One embodiment of the invention employs inert hot melt adhesives as the core.
• Another embodiment uses reactive pressure-sensitive hot-melt adhesives, these can still be crosslinked after application. Examples include hot melt adhesives which still have radiation-crosslinkable groups which can crosslink by radical polymerization or which can crosslink by condensation reactions.
• hot melt adhesives are suitable which have a low softening point, for example from 60 to 130 ° C., in particular from 70 to 120 ° C. (softening temperature measured using Ring / Ball, ISO 4625-1).
• the layer surrounding the core of, for example, pressure sensitive hotmelt adhesive does not have to have sticky properties.
• the composition of the surrounding outer shell layer should be compatible with the hotmelt adhesive of the core. By this is meant that melting of both components gives a homogeneous molten composition. This should give no phase separation in the molten state during production and processing. This can be achieved that in principle conventional and known components are used, which are compatible with the hotmelt adhesive of the core.
• the cladding layer according to the invention should contain styrene block copolymers. These are copolymers based on olefins and styrene. These are dioder multiblock polymers that also have elastic properties. It is also possible to use hydrogenated block copolymers. These are known to the person skilled in the art and are commercially available. For example, these may be SIS, SBS, SIBS, SIPS, SEBS, SEPS. The amount should be from 5 to 35 wt .-% based on the composition of the shell, in particular 10 to 25 wt%. Furthermore, a coating layer according to the invention must contain 20 to 65% by weight of at least one oil. As oils, the above-enumerated softening oils can in principle be used.
• hydrogenated plasticizers are suitable, such as mineral oils, hydrocarbons or polyolefin oligomers.
• the oils are selected from hydrocarbon oils, paraffinic oils, naphthenic oils or medicinal white oils. These have a high compatibility with the styrene block copolymers. Exudation, that is an accumulation on the surface of a corresponding layer, is not observed.
• the amount of oils in the cladding layer should be from 30 to 50% by weight.
• the amount of the oils of the coating layer is greater than the amount of plasticizers or oils in the composition of the hot melt pressure sensitive adhesive.
• the outer layer may contain from 0 to 15% by weight of additives, in particular up to 5% by weight.
• additives are meant, for example, stabilizers, light stabilizers, oxidizing agents and similar substances.
• a polyolefin copolymer can furthermore be contained in the coating layer.
• a polyolefin copolymer which have a softening point of 90 to 130 ° C.
• Such polyolefins are known; they are selected in particular on the basis of polyethylenes or polypropylenes or copolymers, particularly preferably as LDPE or EVA.
• the copolymers differ from waxes in that they usually have a higher molecular weight, for example from 15,000 to 150000 g / mol.
• a composition according to the invention of the cladding layer can still have 0 to 25% by weight of waxes.
• wax the waxes listed above as part of the adhesive can be used.
• the amount should be between 5 and 20% by weight.
• the amount of waxes should be selected so that the tackiness of the entire molten shell and core mixture is substantially unaffected.
• the individual components of the composition of the shell can be selected individually in the amounts mentioned, as far as the mixture has the required properties.
• the sum of the components of the shell should be 100%.
• the outer layer consists of a mixture of - 5 to 30 wt .-% of a styrene block copolymer, - 5 to 30 wt .-% of a Polyolefincopo- polymers, 0 to 20% by weight of wax, 0 to 15% by weight of additives and 20 to 65% by weight of at least one oil selected from paraffinic, naphthenic oils or medical white oils.
• the cladding layer has a softening point of less than 135 ° C, preferably less than 125 ° C, and more preferably less than 115 ° C. However, this is generally above 80 ° C., preferably above 90 ° C., in particular above 100 ° C.
• the cladding layer is block-resistant, i. it is not sticky as granules at temperatures up to 40 ° C by its own weight. The blocking resistance is also given during storage. In particular, after a storage of 2, in particular of 4 months, an inventive granules should still be fluid.
• the weight fraction of the outer shell layer to the total weight of the adhesive is between 5 to 20 wt .-%, in particular between 7 to 12 wt .-%.
• the outer layer of granules should have a thickness of 10 to 300 ⁇ , in particular from 30 to 150 ⁇ .
• the shell is stable enough to have a stable surface in the usual operations of the granules, such as transport, storage, filling and not stick together.
• the invention furthermore relates to a process for the production of granules from fully coated hot-melt adhesive particles.
• the methods of making hot melt adhesive compositions and shell particle compositions of the granule particles are known.
• the ingredients are melted and mixed in the melt. This can be done batchwise in boilers, but it is also possible that the production is carried out continuously in an extruder.
• the blends of the core material and the shell material are individually solid at room temperature. They are usually free of organic solvents.
• the melted components (core, shell) of the granules are processed in a preferred preparation by coextrusion.
• the hot melt adhesive is applied in strand form through a central nozzle, the shell material is extruded parallel to the shell material and placed around the strand. It is known to perform the extrusion under water or to cool the extruded strand immediately thereafter in water or other liquids.
• the strand of core and shell is separated together. The separation takes place at a time when the material is still plastic, that is, it can still take place a deformation of the core and shell.
• the resulting adhesive granules according to the invention are small.
• the size may be about 10 ⁇ 10 ⁇ 15 mm
• the weight of a particle is less than 20 g, preferably 0, 1 to 10 g, in particular 0.3 to 5 g.
• the granules according to the invention are cooled after their preparation. So they are dimensionally stable, they no longer stick together. These granules can then be filled into known packaging materials, such as barrels, hobbocks, cartons, sacks or containers. In these containers, the granules of the invention can be stored. It has been shown that they do not block at a temperature up to 40 ° C, that is, even after prolonged storage or transport at a corresponding temperature, the granules are free flowing and can be removed from the containers.
• the hot melt adhesive granules according to the invention should then be melted before application. For this purpose, they are removed from the containers and brought, for example via a mechanical transport device to a melting tank. There, these granules are melted and optionally conveyed with mixing to the application stations.
• the granules have only a low weight, it is possible to melt only small amounts of the hot melt adhesive and apply. In this case, the thermal load of the hot melt adhesive granules according to the invention is reduced. Furthermore, it is possible to transport these granules with automatic conveyors, for example of compressed air or vacuum conveyors. This is an increased automation of the adhesive application possible. Furthermore, customers can be supplied with larger amounts of the adhesive, but an application is possible in small quantities only according to the actual consumption. This improves the storage and logistics of adhesives.
• Hotmelt adhesive manufacturing method is intended to illustrate the invention.
• the polymers were melted and mixed in a laboratory stirrer. Then the other recipe ingredients were added and completely homogenized and optionally degassed. The molten mixture was bottled and then cooled to solidify.
• Hotmelt adhesive 4
• a hot melt adhesive according to Example 1 to 4 is melted.
• a shell mixture 1 or 2 is melted.
• the adhesive was discharged under water through a central nozzle and the shell material through an annular die. The result was a wrapped tube (diameter about 5 mm), which was cooled immediately. The strand was continued and then separated by squeezing into short pillow-shaped pieces. These were in the cooling bath Room temperature cooled. They were then no longer sticky, are storage-stable and could be dried.
• the size of the individual particles was about 8 x 8 x 5 mm, the weight ca 1, 5 g.
• the amount of shell was determined by the discharged melts, it was about
• a flowable pressure-sensitive adhesive was prepared by melting. This was applied with the usual pumps and metering devices and resulted in a pressure-sensitive adhesive layer after cooling.

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• Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Health & Medical Sciences (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• Engineering & Computer Science (AREA)
• Mechanical Engineering (AREA)
• Oil, Petroleum & Natural Gas (AREA)
• Crystallography & Structural Chemistry (AREA)
• Adhesives Or Adhesive Processes (AREA)
• Processes Of Treating Macromolecular Substances (AREA)

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• 2012
  • 2012-03-06 CN CN2012800133888A patent/CN103443235A/zh active Pending
  • 2012-03-06 WO PCT/EP2012/053789 patent/WO2012123282A1/de active Application Filing
  • 2012-03-06 BR BR112013023488A patent/BR112013023488A2/pt not_active IP Right Cessation
  • 2012-03-06 MX MX2013010491A patent/MX2013010491A/es unknown
  • 2012-03-06 KR KR1020137024257A patent/KR20140012666A/ko not_active Withdrawn
  • 2012-03-06 JP JP2013558359A patent/JP2014512427A/ja active Pending
  • 2012-03-06 RU RU2013146244/05A patent/RU2013146244A/ru not_active Application Discontinuation
  • 2012-03-06 CA CA2829846A patent/CA2829846A1/en not_active Abandoned
  • 2012-03-06 EP EP12708296.4A patent/EP2686398A1/de not_active Withdrawn
• 2013
  • 2013-09-17 US US14/028,580 patent/US20140011912A1/en not_active Abandoned

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