EP2655584A1 - Zusammensetzungen enthaltend sekundäres paraffinsulfonat und tetrahydroxypropylethylendiamin - Google Patents

Zusammensetzungen enthaltend sekundäres paraffinsulfonat und tetrahydroxypropylethylendiamin

Info

Publication number
EP2655584A1
EP2655584A1 EP11799634.8A EP11799634A EP2655584A1 EP 2655584 A1 EP2655584 A1 EP 2655584A1 EP 11799634 A EP11799634 A EP 11799634A EP 2655584 A1 EP2655584 A1 EP 2655584A1
Authority
EP
European Patent Office
Prior art keywords
weight
composition according
paraffin
component
carbon atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP11799634.8A
Other languages
German (de)
English (en)
French (fr)
Inventor
Johannes Himmrich
Wolfgang Walther
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Weylchem Switzerland AG
Original Assignee
Clariant International Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Clariant International Ltd filed Critical Clariant International Ltd
Publication of EP2655584A1 publication Critical patent/EP2655584A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/143—Sulfonic acid esters

Definitions

  • compositions containing secondary paraffin sulphonate Compositions containing secondary paraffin sulphonate
  • the invention relates to aqueous compositions containing 45-65% by weight of secondary paraffin sulphonate, 1-10% by weight
  • Tetrahydroxypropylethylenediamine and water Tetrahydroxypropylethylenediamine and water.
  • Secondary paraffin sulfonates have long been known as base surfactants, especially for detergent applications, dishwashing detergents and industrial cleaners.
  • Secondary paraffin sulfonates are surfactants which, statistically distributed, predominantly contain an SO 3 X group in the secondary position on the paraffin hydrocarbon chain and to a lesser extent two or more SO 8 X groups in the secondary position on the paraffin hydrocarbon chain.
  • the paraffin hydrocarbon chains are predominantly linear and only a minor proportion of 5% by weight or less branched paraffin chains having 8 to 22 carbon atoms.
  • the group X can stand for Li + , Na + , K ⁇ Mg ++ , Ca ++ , Al +++ , NH 4 + and quaternary ammonium ions [HNR 1 R 2 R 3 ] + , where R 1 , R 2 and R 3 is independently hydrogen, a linear or branched alkyl group having 1 to 22 carbon atoms, a linear or branched, mono- or polyunsaturated alkenyl group having 2 to
  • 10 carbon atoms preferably a mono-hydroxyethyl or mono-hydroxypropyl group, as well as a linear or branched di-hydroxyalkyl group having 3 to 10 carbon atoms, may be.
  • This class of surfactants can be obtained by sulfoxidation of paraffins
  • Photochemical conditions are produced and is, for example, in the market under the trade name Hostapur ® SAS in the concentrations
  • aqueous secondary paraffin sulfonate is pasty and tends to phase separate. To prevent the separation, it must be constantly stirred or circulated in a circle. Therefore, additives are sought which suppress a phase separation and thereby the
  • Phase separation is omitted.
  • the disadvantage is that the preparation is flammable and appropriate protective measures must be taken.
  • Object of the present invention was therefore to provide compositions with a high proportion of secondary Paraffinsulfonat, even with longer storage times and greater temperature fluctuations no
  • compositions according to the invention have good phase stability. They remain phase stable over periods of 6 months and more,
  • the compositions of the invention have a viscosity at 20 ° C 1000-100000 ⁇ mPa s, particularly preferably from 2000 to 70,000 mPa ⁇ s and particularly preferably 5000 to 60,000 mPa ⁇ s.
  • the viscosities are measured on the compositions according to the invention even under the following conditions: equipment Brookfield RVT; Spindle No. 3 for the viscosity range of 1,000 to 5,000 mPa ⁇ s; Spindle No. 4 for the
  • compositions according to the invention are advantageously pumpable.
  • compositions of the invention contain
  • compositions each based on the total weight of the compositions.
  • compositions according to the invention particularly preferably comprise a) 45 to 65% by weight of one or more secondary paraffin sulfonates having 8 to 22 carbon atoms,
  • compositions each based on the total weight of the compositions.
  • compositions according to the invention preferably contain, in addition to the components a) to c)
  • compositions those which are d) the sodium sulfate in amounts of from 1 to 5% by weight and, in turn, are preferred
  • compositions each based on the total weight of the compositions.
  • compositions according to the invention from the components a) to e).
  • at least 95% by weight, more preferably at least 97% by weight, of the one or more secondary paraffin sulfonates of component a) contain from 14 to 17 carbon atoms.
  • Paraffin sulfonates of component a) a branched paraffin part.
  • the counterions of the one or more secondary paraffin sulfonates of component a) are selected from the group consisting of Na + , K + , Mg 2+ and Ca 2+ . Particularly preferred is the counterion of the one or more secondary paraffin sulfonates of component a) Na + .
  • the one or more secondary paraffin sulfonates of component a) comprises a saturated paraffin portion and from 0 to 0.5% by weight of the one or more secondary paraffin sulfonates of component a) an unsaturated paraffin portion.
  • 100% by weight of the one or more secondary paraffin sulfonates of component a) contains a saturated paraffin part and no unsaturated parts.
  • second paraffin sulfonate means that the sulfonate groups are attached to the non-terminal paraffin moiety.
  • the sulfonate groups are randomly distributed throughout the non-terminal paraffin portion of the one or more secondary paraffin sulfonates of component a) and further preferably carry from 75 to 95 weight percent of the one or more secondary paraffin sulfonates, a sulfonate group and from 5 to 25 weight percent % of the one or more secondary paraffin sulphonates two or more sulphonate groups.
  • compositions of the invention have a pH of from 6.0 to 9.0, and more preferably from 7.0 to 8.5.
  • compositions according to the invention can be prepared in such a way that components a) to c) and optionally d) and e) (and optionally other components) at room temperature or at elevated temperatures, preferably at temperatures up to 80 ° C, are mixed with stirring.
  • component a) is optionally presented together with components d) and e) in water, which is component c), and component b) is added with stirring.
  • Tetrahydroxypropylethylenediamine is added directly after the preparation and workup of the secondary Paraffinsulfonats, which is usually prepared in water.
  • compositions according to the invention are advantageously suitable for the production of detergents and cleaners.
  • Another object of the invention is therefore the use of a composition according to the invention for the production of detergents and cleaners.
  • dishwashing detergents preferably hand dishwashing detergents, liquid detergents, hard surface cleaners, for example for cleaning ceramic, metal or glass surfaces, neutral cleaners, all-purpose cleaners, sanitary cleaners, floor cleaners, industrial cleaners but Also to call detergents and cleaning agents in powder form.
  • compositions according to the invention are preferably present in amounts of from 0.5 to 60.0% by weight, particularly preferably from 2.0 to 50.0% by weight, in the detergents and cleaners prepared therefrom.
  • compositions according to the invention can be used both in acidic and in basic formulations, preferably in formulations having a pH of from 2 to 13.
  • the compositions according to the invention have the advantage that they are stable at these pH values.
  • the compositions according to the invention are advantageously suitable for the production of cosmetic cleansing compositions such as. As shampoos, shower gels, bubble baths, soaps and toothpastes.
  • compositions according to the invention are suitable in
  • antistatic agents for plastics as auxiliaries for emulsion polymerizations, as textile and leather auxiliaries, for use in fire-extinguishing agents and for use as oil field chemicals.
  • Hostapur ® SAS 60 is introduced and tetrahydroxypropylethylenediamine added with stirring at room temperature and stirred for 5 minutes.
  • Hostapur ® SAS 60 is a composition of
  • the secondary paraffin sulfonate used contains about 97% by weight of paraffin sulfonates having 14 to 17 carbon atoms.
  • the n-paraffin content of the secondary paraffin sulfonate is> 98% by weight.
  • the secondary paraffin sulfonate is 100% saturated. It consists of about 90 wt .-% of monosulfonated and about 10 wt .-% of disulfonated and higher sulfonated Paraffinsulfonaten.
  • the phase stability of compositions 1-5 and V-6 was assessed after the compositions over a period of 6 months
  • phase separation does not mean that it will take 6 months to complete
  • Examples 1 to 5 according to the invention represent phase-stable compositions.
  • phase separation occurred in the composition of Comparative Example V-6 with a small amount of tetrahydroxypropylethylenediamine.
  • the viscosity of the Hostapur ® SAS 60 is in the compositions of the invention by addition of tetrahydroxypropylethylenediamine
  • tetrahydroxypropylethylenediamine When tetrahydroxypropylethylenediamine is added in amounts greater than 10% by weight, the viscosities of the compositions increase significantly so that they become more viscous. This showed z. B. to a comparative composition that has been prepared from 89.0 wt .-% Hostapur ® SAS 60 and 11 0 wt .-% tetrahydroxypropylethylenediamine. Such compositions are much more difficult than the
  • compositions of the invention were prepared.
  • a Genapol ® LRO paste (Clariant) 25.0 wt .-%
  • Active ingredient lauryl ether sulfate, 2EO (EO: ethylene oxide
  • a water, dist. ad 100% by weight coconut fatty acid 2.0% by weight
  • Active ingredient undecyl alcohol polyglycol ether, 8EO
  • Active ingredient lauryl ether sulfate, 2EO, Na salt
  • Active ingredient C C -is-oxoalcohol polyglycol ether, 7EO
  • Genagen CAB ® 818 (Clariant)
  • Active ingredient Cr / Ci7-Alkylamidopropylbetaine
  • Active ingredient C Cis oxo alcohol polyglycol ether, 8EO
  • Example 4 Composition of Example 4 17.0 wt% Dequest 2066 (Monsanto) 4.0 wt% Active: organophosphonate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
EP11799634.8A 2010-12-22 2011-12-15 Zusammensetzungen enthaltend sekundäres paraffinsulfonat und tetrahydroxypropylethylendiamin Withdrawn EP2655584A1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102010055741A DE102010055741A1 (de) 2010-12-22 2010-12-22 Zusammensetzungen enthaltend sekundäres Paraffinsulfonat und Tetrahydroxypropylethylendiamin
PCT/EP2011/006331 WO2012084149A1 (de) 2010-12-22 2011-12-15 Zusammensetzungen enthaltend sekundäres paraffinsulfonat und tetrahydroxypropylethylendiamin

Publications (1)

Publication Number Publication Date
EP2655584A1 true EP2655584A1 (de) 2013-10-30

Family

ID=45401029

Family Applications (1)

Application Number Title Priority Date Filing Date
EP11799634.8A Withdrawn EP2655584A1 (de) 2010-12-22 2011-12-15 Zusammensetzungen enthaltend sekundäres paraffinsulfonat und tetrahydroxypropylethylendiamin

Country Status (5)

Country Link
US (1) US20130310299A1 (enrdf_load_stackoverflow)
EP (1) EP2655584A1 (enrdf_load_stackoverflow)
JP (1) JP5806330B2 (enrdf_load_stackoverflow)
DE (1) DE102010055741A1 (enrdf_load_stackoverflow)
WO (1) WO2012084149A1 (enrdf_load_stackoverflow)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014064152A1 (de) * 2012-10-26 2014-05-01 Basf Se Verfahren zur erdölförderung unter verwendung von tensiden mindestens enthaltend ein sekundäres alkansulfonat sowie ein alkylethersulfat/sulfonat/carboxylat/phosphat
US10358625B2 (en) * 2015-07-17 2019-07-23 S. C. Johnson & Son, Inc. Non-corrosive cleaning composition

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ZA807664B (en) * 1979-12-14 1982-07-28 Unilever Ltd Process for making detergent compositions
DE3711776A1 (de) * 1987-04-08 1988-10-27 Huels Chemische Werke Ag Verwendung von n-polyhydroxyalkylfettsaeureamiden als verdickungsmittel fuer fluessige waessrige tensidsysteme
DE19701896A1 (de) * 1997-01-21 1998-07-23 Clariant Gmbh Granulares sekundäres Alkansulfonat
US5827813A (en) * 1997-02-28 1998-10-27 Procter & Gamble Company Detergent compositions having color care agents
JP2003521563A (ja) * 1999-01-20 2003-07-15 ザ、プロクター、エンド、ギャンブル、カンパニー 変性アルキルベンゼンスルホネートを含んでなる水性ヘビーデューティー液体洗剤組成物
US6462008B1 (en) * 1999-03-05 2002-10-08 Case Western Reserve University Detergent compositions comprising photobleaching delivery systems
DE10041211A1 (de) * 2000-08-22 2002-03-07 Basf Ag Verwendung hydrophiler Pfropfcopolymere mit N-Vinylamin-und /oder offenkettigen n-Vinylamdeinheiten in kosmetischen Formulierungen
JP2004196987A (ja) * 2002-12-19 2004-07-15 Lion Corp 液体洗浄剤組成物
US6851544B2 (en) * 2003-05-19 2005-02-08 Graphic Management Associates, Inc. Transfer device
DE10338070A1 (de) * 2003-08-19 2005-03-17 Henkel Kgaa Auf Substratoberflächen aufziehende Mittel
DE102005045002A1 (de) * 2005-09-21 2007-03-29 Clariant Produkte (Deutschland) Gmbh Biozide Zusammensetzungen
DE102005054565A1 (de) * 2005-11-14 2007-05-16 Henkel Kgaa Oxidationsmittel enthaltende,wohlriechende Verbrauchsprodukte
US8318654B2 (en) * 2006-11-30 2012-11-27 Kimberly-Clark Worldwide, Inc. Cleansing composition incorporating a biocide, heating agent and thermochromic substance
CN101657530A (zh) * 2007-04-02 2010-02-24 宝洁公司 织物护理组合物
DE102007028310A1 (de) * 2007-06-20 2008-12-24 Clariant International Ltd. Tensidmischungen mit synergistischen Eigenschaften
US20100234269A1 (en) * 2007-08-17 2010-09-16 Reckitt Benckiser Inc. Environmentally Acceptable Hard Surface Treatment Compositions
DE102010055743A1 (de) * 2010-12-22 2012-06-28 Clariant International Ltd. Zusammensetzungen enthaltend sekundäres Paraffinsulfonat und Alkoholalkoxylat
DE102010055742A1 (de) * 2010-12-22 2012-06-28 Clariant International Ltd. Zusammensetzungen enthaltend sekundäres Paraffinsulfonat und Alkoholalkoxylat
US10016354B2 (en) * 2011-03-23 2018-07-10 Basf Se Compositions containing polymeric, ionic compounds comprising imidazolium groups

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Also Published As

Publication number Publication date
DE102010055741A1 (de) 2012-06-28
WO2012084149A1 (de) 2012-06-28
JP5806330B2 (ja) 2015-11-10
JP2014501297A (ja) 2014-01-20
US20130310299A1 (en) 2013-11-21

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