EP2651330A1 - Instrument endodontique pour l'alésage de canaux radiculaires d'une dent - Google Patents
Instrument endodontique pour l'alésage de canaux radiculaires d'une dentInfo
- Publication number
- EP2651330A1 EP2651330A1 EP11808132.2A EP11808132A EP2651330A1 EP 2651330 A1 EP2651330 A1 EP 2651330A1 EP 11808132 A EP11808132 A EP 11808132A EP 2651330 A1 EP2651330 A1 EP 2651330A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- instrument
- temperature
- endodontic
- root canal
- instrument according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 210000004262 dental pulp cavity Anatomy 0.000 title claims abstract description 49
- 238000005553 drilling Methods 0.000 title abstract 2
- 238000005520 cutting process Methods 0.000 claims abstract description 9
- 229910001092 metal group alloy Inorganic materials 0.000 claims abstract description 9
- 229910000734 martensite Inorganic materials 0.000 claims description 13
- 229910045601 alloy Inorganic materials 0.000 claims description 10
- 239000000956 alloy Substances 0.000 claims description 10
- -1 copper-zinc-aluminum-nickel Chemical compound 0.000 claims description 6
- 230000008859 change Effects 0.000 claims description 4
- 229910001000 nickel titanium Inorganic materials 0.000 claims description 4
- HZEWFHLRYVTOIW-UHFFFAOYSA-N [Ti].[Ni] Chemical compound [Ti].[Ni] HZEWFHLRYVTOIW-UHFFFAOYSA-N 0.000 claims description 3
- 230000009471 action Effects 0.000 claims description 3
- 238000009499 grossing Methods 0.000 claims description 3
- 230000009466 transformation Effects 0.000 claims description 3
- PVLPPJSAQOKEPF-UHFFFAOYSA-N [Fe].[Au].[Cu].[Zn] Chemical compound [Fe].[Au].[Cu].[Zn] PVLPPJSAQOKEPF-UHFFFAOYSA-N 0.000 claims description 2
- 238000007493 shaping process Methods 0.000 abstract description 3
- 230000007704 transition Effects 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 3
- 238000003754 machining Methods 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 208000015181 infectious disease Diseases 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000003566 sealing material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 240000006909 Tilia x europaea Species 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- SXKZZFLSYPUIAN-UHFFFAOYSA-N [Cu].[Zn].[Au] Chemical compound [Cu].[Zn].[Au] SXKZZFLSYPUIAN-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011325 microbead Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000012781 shape memory material Substances 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21F—WORKING OR PROCESSING OF METAL WIRE
- B21F45/00—Wire-working in the manufacture of other particular articles
- B21F45/008—Wire-working in the manufacture of other particular articles of medical instruments, e.g. stents, corneal rings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61C—DENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
- A61C5/00—Filling or capping teeth
- A61C5/40—Implements for surgical treatment of the roots or nerves of the teeth; Nerve needles; Methods or instruments for medication of the roots
- A61C5/42—Files for root canals; Handgrips or guiding means therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21F—WORKING OR PROCESSING OF METAL WIRE
- B21F1/00—Bending wire other than coiling; Straightening wire
- B21F1/004—Bending wire other than coiling; Straightening wire by means of press-type tooling
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/10—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of nickel or cobalt or alloys based thereon
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61C—DENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
- A61C2201/00—Material properties
- A61C2201/007—Material properties using shape memory effect
Definitions
- the present invention relates to an endodontic instrument, in particular an instrument for boring a root canal of a tooth of a patient, said instrument having a longitudinal axis and comprising a working zone arranged to form and / or shape and / or or cutting and / or cleaning the wall of the root canal of the tooth, this working area being provided with a holding tip arranged to be fixed on a support.
- the cleaning and shaping of the root canals of a tooth for receiving the filling substances is carried out by the use of boring instruments having an active part, called a working part, which has the purpose of to shape and clean the root canal to prepare it for receiving treatment and sealing materials.
- the root canals often have particular geometries with complex curvatures and reduced sections, such as constrictions or oval areas, which are not well suited to the introduction of preparation and shaping instruments. This is why instruments called limes must have sometimes contradictory characteristics: These files must be thin but resistant while being flexible enough to follow the curvatures of the root canal and reach its end while remaining hard enough to cut and cut the walls of the root canal. this channel.
- the US publication US 2010/0233648 discloses an endodontic instrument which is made of a superelastic material which has a first shape at the time of its introduction into the root canal and which takes a second shape when it is inside this channel.
- This shape modification 5 is related to the property of superelasticity of the material, which allows the instrument to undergo deformations due to mechanical constraints imposed by the profile of the channel.
- the present invention proposes to overcome all of the above disadvantages and to provide means for ensuring effective preparation of the root canal, by providing the practitioner with an adaptable instrument that is easily introduced to the patient. interior of the root canal and which may nevertheless have a suitable shape to ensure the preparation for the root treatment and the closure of this channel.
- the instrument according to the invention as defined in the preamble and characterized in that said at least one working zone is arranged to have a retracted shape with at least partially straight geometry when the instrument is in the rest position.
- the instrument being in the so-called martensitic phase and an expanded structured form adapted to the profile of said root canal when the instrument is in the working position, the instrument then being in a so-called austenitic phase, the transition from the martensitic phase to the the austenitic phase being caused by a first predetermined change in the temperature of the instrument and the return of the instrument from its austenitic phase to its martensitic phase being caused by a second predetermined variation of the temperature of this instrument.
- At least said first predetermined variation of the temperature of the instrument is caused during the use of said instrument after its introduction into said root canal.
- said first predetermined temperature variation of the instrument is a rise in temperature.
- Said temperature rise which causes said passage of the martensitic phase to the austenitic phase, is advantageously in a range of temperatures between 0 ° and 60 ° C and preferably between 25 ° and 40 ° C.
- said second predetermined variation of the temperature of this instrument is a lowering of the temperature.
- Said lowering of temperature, to a value called transformation temperature which advantageously causes the passage of the austenitic phase to the martensitic phase, is in a range of temperatures between 60 ° and 0 ° C and preferably between 40 ° and 40 ° C. 25 ° C.
- said at least one working zone may be made of a metal alloy having shape memory properties enabling it to take a retracted form at room temperature and a structured form expanded to a higher temperature at the time of or after its introduction into said root canal.
- said metal alloy having shape memory properties is an alloy chosen from the following alloys: nickel-titanium, copper-zinc-aluminum-nickel, copper-aluminum-nickel, or zinc-copper-gold -fer or a combination of at least two of these alloys.
- said expanded structured form may have a twisted appearance, a substantially flat twist shape or a twisted twisted form of substantially circular section.
- the working area of the instrument may comprise parts having cutting edges or smoothing edges or an abrasive surface or at least one end sector forming an angle with the axis of the instrument.
- the working zone of the instrument may be tubular and comprise two end sectors forming an angle with respect to the axis of the instrument, these two sectors being arranged to describe a cone during the axial rotation of the instrument.
- FIG. 1A shows an instrument according to the invention in the form of a flat tendril, at the moment of its introduction into a root canal of a tooth
- FIGS. 1B to 1D show the instrument of FIG. 1A after its introduction into the root canal of the tooth
- FIGS. 1C and 1D respectively representing sections in this tooth along the axes AA and BB
- Figures 2A and 2C show another embodiment of the instrument according to the invention at the time of its introduction into a root canal of a root of a tooth
- Figure 2C showing a section in the root of this tooth along the axis AA
- FIGS. 2B and 2D represent the instrument of FIG. 2A, after its introduction into the root canal of a root of the tooth
- FIG. 2D representing a section in this root along axis AA
- FIGS. 3A and 3C show another variant embodiment of an instrument according to the invention which is expandable, in a first working state in a root of a tooth, FIG. 3C showing a section in this root along the axis AA
- FIGS. 3B and 3D represent the so-called expandable instrument of FIG. 3A, in a second working state, FIG. 3D showing a section in the treated root of the tooth along the AA axis
- FIGS. 4A and 4B. represent an expansible instrument similar to that of FIGS. 3A to 3D, in a different working configuration in a root of a tooth, FIG. 4B showing a section in this root along the AA axis
- FIG. 5A illustrates a variant, tubular, of the instrument according to the invention, introduced into the root of a tooth but in a rest position
- FIG 5B is an enlarged view of the end of the working area of the instrument of the FIG. 5A in the rest position
- FIG. 6A illustrates the instrument of FIGS. 5A and 5B in the working position in the root of the tooth
- Figure 6B is an enlarged view of the end of the working area of the instrument of Figure 5A in the working position.
- the instrument shown in Figs. 1A-1D is a manual-type instrument for attachment to the end of a handle to allow the practitioner to scrape the substantially oval root canal of a patient's tooth. essentially by back and forth movements and pivoting movements about the longitudinal axis of the instrument.
- This instrument 10 comprises a working zone 11, made of a wire comprising one or more strands, extended by a holding tip 13 which is carried by a support 14, in this case a handle allowing the practitioner to manipulate the instrument.
- FIG. 1A shows the instrument 10 in its insertion position in the root canal 21 of a tooth 20.
- the working zone 11 of the instrument 10 is in the retracted position, in this case, substantially rectilinear, which facilitates its introduction into the root canal 21 and allows easy passage through an apparent constriction 16 in this channel.
- the working zone 11 retains its retracted form, substantially rectilinear because the metal alloy in which it is made has a characteristic called "shape memory".
- shape memory This characteristic, known per se, allows a suitable metal alloy to have a first geometric shape in a given temperature range and take a different geometric shape after switching to another temperature.
- the working zone 11 of the instrument made of a nickel-titanium-based alloy, has a substantially rectilinear shape at an ambient temperature, for example between 0 and 35.degree.
- a first temperature variation such as an elevation, is applied, which is in the range of temperatures between 0 ° and 60 ° C.
- a second variation in temperature is applied, such as a lowering to a a value called transformation temperature, which is in a temperature range between 60 ° and 0 ° C, and preferably 40 ° and 25 ° C for some nickel alloys.
- transformation temperature a value that is in a temperature range between 60 ° and 0 ° C, and preferably 40 ° and 25 ° C for some nickel alloys.
- the alloys usable for their shape memory properties are mainly copper-zinc-aluminum-nickel, copper-aluminum-nickel and zinc-copper-gold-iron alloys. Other alloys with similar properties could of course be used.
- the rise in temperature can be accelerated by means of heating incorporated in the support of the instrument or by external means such as for example sodium hypochlorite (NaOCI) which is used for the disinfection of the root canal.
- NaOCI sodium hypochlorite
- This compound can be injected by a heating syringe, commonly used in the field by practitioners.
- FIGS. 1B to 1 D The expanded structured shape taken by the working zone 11 of the instrument 10 is represented by FIGS. 1B to 1 D.
- the working zone 11 has, in this embodiment, taken the form of a flat tendril which substantially fills the entire width of the root canal 21 as illustrated by Figures 1C and 1D.
- This auger has great flexibility, so that it adapts to the shape of the channel 21.
- the loops 17 of the tendril are less accentuated than in widened sectors 18 and 19 respectively corresponding to the bottom and the inlet of the channel 21 ' .
- FIGS. 2A to 2D show an instrument 10 according to the invention, of the motorized type, engaged in one of the channels 21 of a molar tooth 20 with two root canals.
- FIGS. 1B to 1 D The expanded structured shape taken by the working zone 11 of the instrument 10 is represented by FIGS. 1B to 1 D.
- the working zone 11 has, in this embodiment, taken the form of a flat tendril which substantially fills the entire
- the working area 1 1 in its retracted form, is substantially rectilinear, which allows easy insertion into the root canal 21.
- the work area 1 1 has taken its expanded structural form, following an increase in temperature obtained either by contact with the body of the patient, or by means of a heating resistor (not shown) present in the support 14 which In the example shown, the instrument is mechanically rotated and has, in its structured state, a form of corkscrew.
- the working zone 11 of the instrument 10 has, moreover, a sufficiently flexible consistency so that its section can adapt to the section of the root canal 21 which is more or less conical.
- the working zone 11 is made with a shape memory metal alloy wire which takes its expanded structural form following a rise in temperature or a change in temperature.
- the section of the wire may be substantially circular or possibly angular so that the function of the instrument is rather smooth or rather sharp or abrasive depending on the desired result.
- Figures 3A to 3D show another embodiment of an instrument according to the invention of the motorized type.
- This instrument 10 said expandable, has specific characteristics that allow it to adapt to the profile and dimensions of a root canal or "machine" this canal to give it the desired profile and dimensions for further processing of root.
- the instrument in its state represented by FIGS.
- 3A and 3C is introduced into one of the root canals 21 of the tooth 20.
- This channel comprises a slight bulge 21a in its central part, followed by a narrowing 21b. .
- the working area 11 of the instrument 10 adapts to this configuration.
- this instrument is rotated by its support 14 and, depending on the section of the wire of metal with which it is constituted, its action produces either machining, cutting, abrasion or In this case, the aim is to widen the upper part of the channel by eliminating the constriction 21b in order to facilitate the introduction of the sealing paste.
- the instrument 0 expands, takes a form of corkscrew of substantially circular section and acts on the walls by cutting or eroding the material of the body of the tooth, as shown in Figures 3B and 3D.
- the expansion of the instrument 10 is essentially in the upper part of the working zone 11 and the aim is to cone the root canal 21
- the working zone 11 can be cutting, abrasive or smoothing according to the envisaged machining of the channel 21.
- FIGS. 5A and 5B illustrate another embodiment of the instrument 10, in which the working zone 11 is substantially tubular and has a twisted appearance.
- the lower end 12 of this working zone 11 is slotted axially over a certain length and comprises two sectors 12a and 12b which are visible in FIG. 5B.
- the two sectors 12a and 12b are juxtaposed in the axial extension of the remainder of the zone of
- the present invention is not limited to the embodiments described, but may undergo various modifications or variations.
- the described variants are manual and motorized, it is possible to also consider vibrating the instrument by ultrasound.
- the preparation of the root canal may vary.
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- General Health & Medical Sciences (AREA)
- Neurology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Surgery (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Crystallography & Structural Chemistry (AREA)
- Thermal Sciences (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- Neurosurgery (AREA)
- Dentistry (AREA)
- Biomedical Technology (AREA)
- Physics & Mathematics (AREA)
- Heart & Thoracic Surgery (AREA)
- Vascular Medicine (AREA)
- Dental Tools And Instruments Or Auxiliary Dental Instruments (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH02100/10A CH704235B1 (fr) | 2010-12-16 | 2010-12-16 | Instrument endodontique pour l’alésage de canaux radiculaires d’une dent. |
PCT/CH2011/000296 WO2012079183A1 (fr) | 2010-12-16 | 2011-12-12 | Instrument endodontique pour l'alésage de canaux radiculaires d'une dent |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2651330A1 true EP2651330A1 (fr) | 2013-10-23 |
Family
ID=44509769
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP11808132.2A Withdrawn EP2651330A1 (fr) | 2010-12-16 | 2011-12-12 | Instrument endodontique pour l'alésage de canaux radiculaires d'une dent |
Country Status (16)
Country | Link |
---|---|
US (3) | US20140004479A1 (es) |
EP (1) | EP2651330A1 (es) |
JP (2) | JP2014505507A (es) |
KR (1) | KR102705112B1 (es) |
CN (2) | CN117731422A (es) |
AU (1) | AU2016348753B2 (es) |
BR (1) | BR112018008424B1 (es) |
CA (1) | CA2819204A1 (es) |
CH (1) | CH704235B1 (es) |
CL (1) | CL2018001170A1 (es) |
ES (1) | ES2858756T3 (es) |
MX (1) | MX2018005582A (es) |
MY (1) | MY190220A (es) |
SG (1) | SG11201803658YA (es) |
WO (1) | WO2012079183A1 (es) |
ZA (1) | ZA201803177B (es) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH704235B1 (fr) * | 2010-12-16 | 2015-09-30 | Fkg Dentaire Sa | Instrument endodontique pour l’alésage de canaux radiculaires d’une dent. |
CH709851B1 (fr) | 2014-07-07 | 2020-01-31 | Fkg Dentaire Sa | Instrument endodontique pour l'alésage de canaux radiculaires. |
WO2016012236A1 (en) * | 2014-07-24 | 2016-01-28 | Nv Bekaert Sa | High fatigue resistant wire |
WO2016040416A1 (en) * | 2014-09-09 | 2016-03-17 | Gold Standard Instruments, LLC | Method for forming an endodontic instrument or device |
CA3003301C (en) * | 2015-11-03 | 2024-02-13 | Fkg Dentaire Sa | Endodontic instrument for drilling the root canals of a tooth |
EP3178439B1 (en) | 2015-12-03 | 2021-10-13 | Ormco Corporation | Fluted endodontic file |
ES2906636T3 (es) | 2016-10-22 | 2022-04-19 | Ormco Corp | Tratamiento térmico variable y fabricación de limas de endodoncia |
KR20180064937A (ko) * | 2016-12-06 | 2018-06-15 | 주식회사 마루치 | 초음파 근관 세정용 Ni-Ti 합금 파일 |
USD837376S1 (en) * | 2016-12-15 | 2019-01-01 | Moji Bagheri | Endodontic tool |
USD842474S1 (en) | 2017-10-20 | 2019-03-05 | Ormco Corporation | Endodontic file |
US11191616B1 (en) * | 2017-10-21 | 2021-12-07 | David W. Kelliny | Access guide and drill kit to be used with same for endodontic access cavity preparation and method of use |
US11432906B2 (en) | 2018-06-18 | 2022-09-06 | Hu-Friedy Mfg. Co., Llc | Dental instrument with a flexible tip end and method of manufacture |
KR20210137130A (ko) * | 2019-03-08 | 2021-11-17 | 스트라우만 홀딩 에이쥐 | 치과용 드릴 표면 처리 |
KR20210014914A (ko) | 2019-07-31 | 2021-02-10 | 주식회사 엘지화학 | 곡면 유리에 인쇄 가능한 자외선 경화형 블랙 잉크 조성물 및 베젤 패턴 인쇄 방법 |
KR20210014913A (ko) | 2019-07-31 | 2021-02-10 | 주식회사 엘지화학 | 곡면 유리에 인쇄 가능한 자외선 경화형 블랙 잉크 조성물 및 베젤 패턴 인쇄 방법 |
US20210212799A1 (en) * | 2020-01-09 | 2021-07-15 | Clifford J. Ruddle | Endoactivator tips for cleaning dental root canal system |
MX2022011230A (es) | 2020-03-12 | 2022-10-07 | Mdt Micro Diamond Tech Ltd | Corte de extremo de cepillo endodontico. |
JP7411248B2 (ja) * | 2021-08-02 | 2024-01-11 | 藤栄電気株式会社 | 根管拡大用切削具、根管長測定器及び根管拡大装置 |
WO2024115953A1 (en) | 2022-12-02 | 2024-06-06 | FKG Dentaire Sàrl | Endodontic instrument having improved fit of the tooth canal geometry |
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2010
- 2010-12-16 CH CH02100/10A patent/CH704235B1/fr unknown
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2011
- 2011-12-12 CA CA2819204A patent/CA2819204A1/fr not_active Abandoned
- 2011-12-12 WO PCT/CH2011/000296 patent/WO2012079183A1/fr active Application Filing
- 2011-12-12 EP EP11808132.2A patent/EP2651330A1/fr not_active Withdrawn
- 2011-12-12 US US13/994,162 patent/US20140004479A1/en not_active Abandoned
- 2011-12-12 JP JP2013543481A patent/JP2014505507A/ja active Pending
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2015
- 2015-11-03 US US14/930,844 patent/US9931179B2/en active Active
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2016
- 2016-11-02 BR BR112018008424-7A patent/BR112018008424B1/pt active IP Right Grant
- 2016-11-02 ES ES16808553T patent/ES2858756T3/es active Active
- 2016-11-02 KR KR1020187015715A patent/KR102705112B1/ko active IP Right Grant
- 2016-11-02 AU AU2016348753A patent/AU2016348753B2/en active Active
- 2016-11-02 MY MYPI2018701617A patent/MY190220A/en unknown
- 2016-11-02 MX MX2018005582A patent/MX2018005582A/es unknown
- 2016-11-02 CN CN202311326125.9A patent/CN117731422A/zh active Pending
- 2016-11-02 SG SG11201803658YA patent/SG11201803658YA/en unknown
- 2016-11-02 CN CN201680064194.9A patent/CN108350532A/zh active Pending
- 2016-11-02 JP JP2018520111A patent/JP7133218B2/ja active Active
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2017
- 2017-12-04 US US15/830,601 patent/US11571275B2/en active Active
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2018
- 2018-05-02 CL CL2018001170A patent/CL2018001170A1/es unknown
- 2018-05-14 ZA ZA2018/03177A patent/ZA201803177B/en unknown
Non-Patent Citations (2)
Title |
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None * |
See also references of WO2012079183A1 * |
Also Published As
Publication number | Publication date |
---|---|
US20140004479A1 (en) | 2014-01-02 |
WO2012079183A1 (fr) | 2012-06-21 |
JP7133218B2 (ja) | 2022-09-08 |
BR112018008424A2 (pt) | 2018-11-06 |
AU2016348753B2 (en) | 2022-03-17 |
MX2018005582A (es) | 2018-09-21 |
US20180085195A1 (en) | 2018-03-29 |
BR112018008424B1 (pt) | 2021-09-14 |
US20160051339A1 (en) | 2016-02-25 |
US11571275B2 (en) | 2023-02-07 |
JP2018531709A (ja) | 2018-11-01 |
KR102705112B1 (ko) | 2024-09-09 |
CN108350532A (zh) | 2018-07-31 |
CA2819204A1 (fr) | 2012-06-21 |
JP2014505507A (ja) | 2014-03-06 |
KR20180095806A (ko) | 2018-08-28 |
ZA201803177B (en) | 2019-07-31 |
MY190220A (en) | 2022-04-06 |
CH704235A1 (fr) | 2012-06-29 |
AU2016348753A1 (en) | 2018-06-21 |
ES2858756T3 (es) | 2021-09-30 |
SG11201803658YA (en) | 2018-05-30 |
CH704235B1 (fr) | 2015-09-30 |
CN117731422A (zh) | 2024-03-22 |
CL2018001170A1 (es) | 2018-12-14 |
US9931179B2 (en) | 2018-04-03 |
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