EP2620422B1 - Ionische, monergole Treibstoffe auf N2O-Basis für den Raumantreib - Google Patents
Ionische, monergole Treibstoffe auf N2O-Basis für den Raumantreib Download PDFInfo
- Publication number
- EP2620422B1 EP2620422B1 EP13152595.8A EP13152595A EP2620422B1 EP 2620422 B1 EP2620422 B1 EP 2620422B1 EP 13152595 A EP13152595 A EP 13152595A EP 2620422 B1 EP2620422 B1 EP 2620422B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- triazolium
- nitrate
- dicyanamide
- fuel
- ammonium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Inorganic materials [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 claims description 75
- 150000003839 salts Chemical class 0.000 claims description 57
- 239000000203 mixture Substances 0.000 claims description 39
- 239000000446 fuel Substances 0.000 claims description 38
- 239000007788 liquid Substances 0.000 claims description 37
- -1 hydrazinium ions Chemical class 0.000 claims description 35
- MJVUDZGNBKFOBF-UHFFFAOYSA-N n-nitronitramide Chemical compound [O-][N+](=O)N[N+]([O-])=O MJVUDZGNBKFOBF-UHFFFAOYSA-N 0.000 claims description 31
- 239000007789 gas Substances 0.000 claims description 28
- 239000001272 nitrous oxide Substances 0.000 claims description 25
- 238000002485 combustion reaction Methods 0.000 claims description 24
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 21
- 229910002651 NO3 Inorganic materials 0.000 claims description 21
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 21
- 238000002156 mixing Methods 0.000 claims description 20
- 239000007791 liquid phase Substances 0.000 claims description 19
- 150000001450 anions Chemical class 0.000 claims description 18
- 150000001768 cations Chemical class 0.000 claims description 18
- 239000002904 solvent Substances 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 17
- 239000012071 phase Substances 0.000 claims description 17
- 125000001425 triazolyl group Chemical group 0.000 claims description 15
- 150000001540 azides Chemical class 0.000 claims description 12
- SFLZICZHQSFYOR-UHFFFAOYSA-N 1-nitrotetrazole-5-carboxylic acid Chemical compound OC(=O)C1=NN=NN1[N+]([O-])=O SFLZICZHQSFYOR-UHFFFAOYSA-N 0.000 claims description 11
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 10
- UAZDIGCOBKKMPU-UHFFFAOYSA-O azanium;azide Chemical compound [NH4+].[N-]=[N+]=[N-] UAZDIGCOBKKMPU-UHFFFAOYSA-O 0.000 claims description 10
- RBLWMQWAHONKNC-UHFFFAOYSA-N hydroxyazanium Chemical compound O[NH3+] RBLWMQWAHONKNC-UHFFFAOYSA-N 0.000 claims description 10
- 150000002500 ions Chemical class 0.000 claims description 10
- 239000007800 oxidant agent Substances 0.000 claims description 10
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 claims description 9
- NQRYJNQNLNOLGT-UHFFFAOYSA-O Piperidinium(1+) Chemical compound C1CC[NH2+]CC1 NQRYJNQNLNOLGT-UHFFFAOYSA-O 0.000 claims description 9
- XYODKMYYACGWBN-UHFFFAOYSA-N aminoazanium;nitroformate Chemical compound [NH3+]N.[O-]C(=O)[N+]([O-])=O XYODKMYYACGWBN-UHFFFAOYSA-N 0.000 claims description 9
- CRJZNQFRBUFHTE-UHFFFAOYSA-N hydroxylammonium nitrate Chemical compound O[NH3+].[O-][N+]([O-])=O CRJZNQFRBUFHTE-UHFFFAOYSA-N 0.000 claims description 9
- NSPMIYGKQJPBQR-UHFFFAOYSA-N 4H-1,2,4-triazole Chemical compound C=1N=CNN=1 NSPMIYGKQJPBQR-UHFFFAOYSA-N 0.000 claims description 8
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 7
- BRUFJXUJQKYQHA-UHFFFAOYSA-O ammonium dinitramide Chemical compound [NH4+].[O-][N+](=O)[N-][N+]([O-])=O BRUFJXUJQKYQHA-UHFFFAOYSA-O 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- VMPIHZLTNJDKEN-UHFFFAOYSA-O triethanolammonium nitrate Chemical compound [O-][N+]([O-])=O.OCC[NH+](CCO)CCO VMPIHZLTNJDKEN-UHFFFAOYSA-O 0.000 claims description 7
- WTKZEGDFNFYCGP-UHFFFAOYSA-O Pyrazolium Chemical compound C1=CN[NH+]=C1 WTKZEGDFNFYCGP-UHFFFAOYSA-O 0.000 claims description 6
- JBFYUZGYRGXSFL-UHFFFAOYSA-N imidazolide Chemical compound C1=C[N-]C=N1 JBFYUZGYRGXSFL-UHFFFAOYSA-N 0.000 claims description 6
- WRHZVMBBRYBTKZ-UHFFFAOYSA-N pyrrole-2-carboxylic acid Chemical class OC(=O)C1=CC=CN1 WRHZVMBBRYBTKZ-UHFFFAOYSA-N 0.000 claims description 6
- 125000003831 tetrazolyl group Chemical group 0.000 claims description 6
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims description 5
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 claims description 5
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims description 5
- LJVQHXICFCZRJN-UHFFFAOYSA-N 1h-1,2,4-triazole-5-carboxylic acid Chemical compound OC(=O)C1=NC=NN1 LJVQHXICFCZRJN-UHFFFAOYSA-N 0.000 claims description 4
- 125000005235 azinium group Chemical group 0.000 claims description 4
- SFDJOSRHYKHMOK-UHFFFAOYSA-N nitramide Chemical compound N[N+]([O-])=O SFDJOSRHYKHMOK-UHFFFAOYSA-N 0.000 claims description 4
- KOPFEFZSAMLEHK-UHFFFAOYSA-N 1h-pyrazole-5-carboxylic acid Chemical compound OC(=O)C=1C=CNN=1 KOPFEFZSAMLEHK-UHFFFAOYSA-N 0.000 claims description 3
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims description 3
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- CTAPFRYPJLPFDF-UHFFFAOYSA-O hydron;1,2-oxazole Chemical compound C=1C=[NH+]OC=1 CTAPFRYPJLPFDF-UHFFFAOYSA-O 0.000 claims description 3
- ZCQWOFVYLHDMMC-UHFFFAOYSA-O hydron;1,3-oxazole Chemical compound C1=COC=[NH+]1 ZCQWOFVYLHDMMC-UHFFFAOYSA-O 0.000 claims description 3
- KAESVJOAVNADME-UHFFFAOYSA-O hydron;1h-pyrrole Chemical compound [NH2+]1C=CC=C1 KAESVJOAVNADME-UHFFFAOYSA-O 0.000 claims description 3
- CZPWVGJYEJSRLH-UHFFFAOYSA-O hydron;pyrimidine Chemical compound C1=CN=C[NH+]=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-O 0.000 claims description 3
- WCPAKWJPBJAGKN-UHFFFAOYSA-N oxadiazole Chemical compound C1=CON=N1 WCPAKWJPBJAGKN-UHFFFAOYSA-N 0.000 claims description 3
- CQDAMYNQINDRQC-UHFFFAOYSA-N oxatriazole Chemical compound C1=NN=NO1 CQDAMYNQINDRQC-UHFFFAOYSA-N 0.000 claims description 3
- ASRAWSBMDXVNLX-UHFFFAOYSA-N pyrazolynate Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(=O)C=1C(C)=NN(C)C=1OS(=O)(=O)C1=CC=C(C)C=C1 ASRAWSBMDXVNLX-UHFFFAOYSA-N 0.000 claims description 3
- PBMFSQRYOILNGV-UHFFFAOYSA-N pyridazine Chemical compound C1=CC=NN=C1 PBMFSQRYOILNGV-UHFFFAOYSA-N 0.000 claims description 3
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 claims description 3
- LAZVTKQYCZFNSZ-UHFFFAOYSA-N nitro formate Chemical compound [O-][N+](=O)OC=O LAZVTKQYCZFNSZ-UHFFFAOYSA-N 0.000 claims description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 2
- 150000002894 organic compounds Chemical class 0.000 claims 1
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 24
- 239000003380 propellant Substances 0.000 description 20
- CCRNCEKMSVYFLU-UHFFFAOYSA-N 4,5-dinitro-1h-imidazole Chemical compound [O-][N+](=O)C=1N=CNC=1[N+]([O-])=O CCRNCEKMSVYFLU-UHFFFAOYSA-N 0.000 description 16
- 239000000243 solution Substances 0.000 description 15
- IVRMZWNICZWHMI-UHFFFAOYSA-N Azide Chemical compound [N-]=[N+]=[N-] IVRMZWNICZWHMI-UHFFFAOYSA-N 0.000 description 14
- 150000001875 compounds Chemical class 0.000 description 14
- 230000001590 oxidative effect Effects 0.000 description 13
- 125000000217 alkyl group Chemical group 0.000 description 12
- WVVQNTCHJACXPP-UHFFFAOYSA-O 4-methyltetrazol-4-ium-1,5-diamine Chemical compound C[N+]=1N=NN(N)C=1N WVVQNTCHJACXPP-UHFFFAOYSA-O 0.000 description 11
- 238000003860 storage Methods 0.000 description 11
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- OAKJQQAXSVQMHS-UHFFFAOYSA-O hydrazinium(1+) Chemical compound [NH3+]N OAKJQQAXSVQMHS-UHFFFAOYSA-O 0.000 description 9
- IQQRAVYLUAZUGX-UHFFFAOYSA-N 1-butyl-3-methylimidazolium Chemical compound CCCCN1C=C[N+](C)=C1 IQQRAVYLUAZUGX-UHFFFAOYSA-N 0.000 description 8
- FMCUPJKTGNBGEC-UHFFFAOYSA-N 1,2,4-triazol-4-amine Chemical compound NN1C=NN=C1 FMCUPJKTGNBGEC-UHFFFAOYSA-N 0.000 description 7
- MWZDIEIXRBWPLG-UHFFFAOYSA-O 2-methyl-1h-1,2,4-triazol-2-ium Chemical compound C[N+]1=CN=CN1 MWZDIEIXRBWPLG-UHFFFAOYSA-O 0.000 description 7
- OKHTZNLRYCWACF-UHFFFAOYSA-N 5-azido-1h-1,2,4-triazole Chemical compound [N-]=[N+]=NC1=NC=NN1 OKHTZNLRYCWACF-UHFFFAOYSA-N 0.000 description 7
- IGNDAXMAFOVNIC-UHFFFAOYSA-O 5-azido-2-methyl-1H-1,2,4-triazol-2-ium Chemical compound C[NH+]1C=NC(N=[N+]=[N-])=N1 IGNDAXMAFOVNIC-UHFFFAOYSA-O 0.000 description 7
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical class C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 7
- UZXHZRFWCCZBDW-UHFFFAOYSA-O aminoazanium;azide Chemical compound [NH3+]N.[N-]=[N+]=[N-] UZXHZRFWCCZBDW-UHFFFAOYSA-O 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000002347 injection Methods 0.000 description 7
- 239000007924 injection Substances 0.000 description 7
- 239000002608 ionic liquid Substances 0.000 description 7
- 230000004913 activation Effects 0.000 description 6
- 239000003638 chemical reducing agent Substances 0.000 description 6
- 238000006053 organic reaction Methods 0.000 description 6
- MXLZUALXSYVAIV-UHFFFAOYSA-N 1,2-dimethyl-3-propylimidazol-1-ium Chemical compound CCCN1C=C[N+](C)=C1C MXLZUALXSYVAIV-UHFFFAOYSA-N 0.000 description 5
- BSAYKWAKQFDCPG-UHFFFAOYSA-N 1-but-2-ynyl-3-methylimidazol-3-ium Chemical compound CC#CCN1C=C[N+](C)=C1 BSAYKWAKQFDCPG-UHFFFAOYSA-N 0.000 description 5
- PXELHGDYRQLRQO-UHFFFAOYSA-N 1-butyl-1-methylpyrrolidin-1-ium Chemical compound CCCC[N+]1(C)CCCC1 PXELHGDYRQLRQO-UHFFFAOYSA-N 0.000 description 5
- ICIVTHOGIQHZRY-UHFFFAOYSA-N 1-butyl-3-methylimidazol-3-ium;cyanoiminomethylideneazanide Chemical compound [N-]=C=NC#N.CCCCN1C=C[N+](C)=C1 ICIVTHOGIQHZRY-UHFFFAOYSA-N 0.000 description 5
- NJMWOUFKYKNWDW-UHFFFAOYSA-N 1-ethyl-3-methylimidazolium Chemical compound CCN1C=C[N+](C)=C1 NJMWOUFKYKNWDW-UHFFFAOYSA-N 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 230000003197 catalytic effect Effects 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 238000005649 metathesis reaction Methods 0.000 description 5
- 238000005457 optimization Methods 0.000 description 5
- HVVRUQBMAZRKPJ-UHFFFAOYSA-N 1,3-dimethylimidazolium Chemical compound CN1C=C[N+](C)=C1 HVVRUQBMAZRKPJ-UHFFFAOYSA-N 0.000 description 4
- UFDAQRCLFHCJEQ-UHFFFAOYSA-N 1,5-dimethyl-2H-tetrazol-3-amine Chemical compound CN1NN(N)N=C1C UFDAQRCLFHCJEQ-UHFFFAOYSA-N 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- IZBOAZUNIFCNBE-UHFFFAOYSA-N ethanol;1-methylimidazole Chemical compound CCO.CN1C=CN=C1 IZBOAZUNIFCNBE-UHFFFAOYSA-N 0.000 description 4
- 238000011049 filling Methods 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- 241000894007 species Species 0.000 description 4
- OIEWJYPMDZYRBG-UHFFFAOYSA-N 1-azido-1h-triazol-1-ium;1-nitrotetrazole-5-carboxylate Chemical compound [N-]=[N+]=N[NH+]1C=CN=N1.[O-]C(=O)C1=NN=NN1[N+]([O-])=O OIEWJYPMDZYRBG-UHFFFAOYSA-N 0.000 description 3
- NIHOUJYFWMURBG-UHFFFAOYSA-N 1-ethyl-1-methylpyrrolidin-1-ium Chemical compound CC[N+]1(C)CCCC1 NIHOUJYFWMURBG-UHFFFAOYSA-N 0.000 description 3
- RVEJOWGVUQQIIZ-UHFFFAOYSA-N 1-hexyl-3-methylimidazolium Chemical compound CCCCCCN1C=C[N+](C)=C1 RVEJOWGVUQQIIZ-UHFFFAOYSA-N 0.000 description 3
- OGLIVJFAKNJZRE-UHFFFAOYSA-N 1-methyl-1-propylpiperidin-1-ium Chemical compound CCC[N+]1(C)CCCCC1 OGLIVJFAKNJZRE-UHFFFAOYSA-N 0.000 description 3
- YQFWGCSKGJMGHE-UHFFFAOYSA-N 1-methyl-1-propylpyrrolidin-1-ium Chemical compound CCC[N+]1(C)CCCC1 YQFWGCSKGJMGHE-UHFFFAOYSA-N 0.000 description 3
- MCTWTZJPVLRJOU-UHFFFAOYSA-O 1-methylimidazole Chemical compound CN1C=C[NH+]=C1 MCTWTZJPVLRJOU-UHFFFAOYSA-O 0.000 description 3
- RSEBUVRVKCANEP-UHFFFAOYSA-N 2-pyrroline Chemical compound C1CC=CN1 RSEBUVRVKCANEP-UHFFFAOYSA-N 0.000 description 3
- MIFXNTWNZOVEFV-UHFFFAOYSA-N 3-azido-1h-1,2,4-triazol-1-ium;5-nitrotetrazole-5-carboxylate Chemical compound [N-]=[N+]=NC1=N[NH2+]C=N1.[O-]C(=O)C1([N+]([O-])=O)N=NN=N1 MIFXNTWNZOVEFV-UHFFFAOYSA-N 0.000 description 3
- WXMVWUBWIHZLMQ-UHFFFAOYSA-N 3-methyl-1-octylimidazolium Chemical compound CCCCCCCCN1C=C[N+](C)=C1 WXMVWUBWIHZLMQ-UHFFFAOYSA-N 0.000 description 3
- XAGXLODJENLEBR-UHFFFAOYSA-N 4,5-dimethyltetrazol-4-ium-1-amine Chemical compound CC=1N(N)N=N[N+]=1C XAGXLODJENLEBR-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- GCMIVBDGXCCOEP-UHFFFAOYSA-N N#CNC#N.N Chemical compound N#CNC#N.N GCMIVBDGXCCOEP-UHFFFAOYSA-N 0.000 description 3
- GRWCKIFVULPUSU-UHFFFAOYSA-O N[N+]([O-])=O.N[N+]([O-])=O.CN1N=N[N+](N)=C1N Chemical compound N[N+]([O-])=O.N[N+]([O-])=O.CN1N=N[N+](N)=C1N GRWCKIFVULPUSU-UHFFFAOYSA-O 0.000 description 3
- RWRDLPDLKQPQOW-UHFFFAOYSA-O Pyrrolidinium ion Chemical compound C1CC[NH2+]C1 RWRDLPDLKQPQOW-UHFFFAOYSA-O 0.000 description 3
- 230000029936 alkylation Effects 0.000 description 3
- 238000005804 alkylation reaction Methods 0.000 description 3
- 125000000852 azido group Chemical group *N=[N+]=[N-] 0.000 description 3
- 230000033228 biological regulation Effects 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000005474 detonation Methods 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- GATNOFPXSDHULC-UHFFFAOYSA-N ethylphosphonic acid Chemical compound CCP(O)(O)=O GATNOFPXSDHULC-UHFFFAOYSA-N 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 150000008040 ionic compounds Chemical class 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- YACKEPLHDIMKIO-UHFFFAOYSA-N methylphosphonic acid Chemical compound CP(O)(O)=O YACKEPLHDIMKIO-UHFFFAOYSA-N 0.000 description 3
- HDZGCSFEDULWCS-UHFFFAOYSA-N monomethylhydrazine Chemical compound CNN HDZGCSFEDULWCS-UHFFFAOYSA-N 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- JKANAVGODYYCQF-UHFFFAOYSA-N prop-2-yn-1-amine Chemical compound NCC#C JKANAVGODYYCQF-UHFFFAOYSA-N 0.000 description 3
- WGYKZJWCGVVSQN-UHFFFAOYSA-O propan-1-aminium Chemical compound CCC[NH3+] WGYKZJWCGVVSQN-UHFFFAOYSA-O 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- 239000012808 vapor phase Substances 0.000 description 3
- 0 **1C(*)=*(*)C(*)=*1 Chemical compound **1C(*)=*(*)C(*)=*1 0.000 description 2
- AOCVWHNJJSAWLY-UHFFFAOYSA-O 1,5-dimethyl-1,2-dihydrotetrazol-1-ium-3-amine;nitrate Chemical compound [O-][N+]([O-])=O.CN1NN(N)[NH+]=C1C AOCVWHNJJSAWLY-UHFFFAOYSA-O 0.000 description 2
- FDWZAOGDOVQOLD-UHFFFAOYSA-N 1-methylpyrrolinium Chemical compound C[N+]1=CCCC1 FDWZAOGDOVQOLD-UHFFFAOYSA-N 0.000 description 2
- 125000001494 2-propynyl group Chemical group [H]C#CC([H])([H])* 0.000 description 2
- UTYHRWFPLVSEEY-UHFFFAOYSA-N 3-azido-1-methyl-1h-1,2,4-triazol-1-ium;5-nitrotetrazole-5-carboxylate Chemical compound C[NH+]1C=NC(N=[N+]=[N-])=N1.[O-]C(=O)C1([N+]([O-])=O)N=NN=N1 UTYHRWFPLVSEEY-UHFFFAOYSA-N 0.000 description 2
- MIGFTZZNPSSSAV-UHFFFAOYSA-N 4,5-dimethyltetrazol-4-ium-1-amine;nitrate Chemical compound [O-][N+]([O-])=O.CC=1N(N)N=N[N+]=1C MIGFTZZNPSSSAV-UHFFFAOYSA-N 0.000 description 2
- FSGREQVUKVWGDV-UHFFFAOYSA-O 4-methyltetrazol-4-ium-1,5-diamine;nitrate Chemical compound [O-][N+]([O-])=O.C[N+]=1N=NN(N)C=1N FSGREQVUKVWGDV-UHFFFAOYSA-O 0.000 description 2
- HBVOEKFVEUNBRJ-UHFFFAOYSA-N 5-nitrotetrazole-5-carboxylate;1h-1,2,4-triazol-1-ium Chemical compound [NH2+]1C=NC=N1.[O-]C(=O)C1([N+]([O-])=O)N=NN=N1 HBVOEKFVEUNBRJ-UHFFFAOYSA-N 0.000 description 2
- HTJFMHFDZWNRLO-UHFFFAOYSA-N 5-nitrotetrazole-5-carboxylate;1h-1,2,4-triazol-4-ium-4-amine Chemical compound N[N+]=1C=NNC=1.[O-]C(=O)C1([N+]([O-])=O)N=NN=N1 HTJFMHFDZWNRLO-UHFFFAOYSA-N 0.000 description 2
- NKGQFSOOECRNTM-UHFFFAOYSA-N 5-nitrotetrazole-5-carboxylic acid Chemical compound OC(=O)C1([N+]([O-])=O)N=NN=N1 NKGQFSOOECRNTM-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- AJPXOOXHHFMBQS-UHFFFAOYSA-N N[N+]([O-])=O.N[N+]([O-])=O.NO Chemical compound N[N+]([O-])=O.N[N+]([O-])=O.NO AJPXOOXHHFMBQS-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- FTPMPYVSRHETHX-UHFFFAOYSA-N [NH3+]O.[N-]=[N+]=[N-] Chemical compound [NH3+]O.[N-]=[N+]=[N-] FTPMPYVSRHETHX-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- RAESLDWEUUSRLO-UHFFFAOYSA-O aminoazanium;nitrate Chemical compound [NH3+]N.[O-][N+]([O-])=O RAESLDWEUUSRLO-UHFFFAOYSA-O 0.000 description 2
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- IWMOUXZYHULGCL-UHFFFAOYSA-N nitro 2H-tetrazole-5-carboxylate Chemical compound [O-][N+](=O)OC(=O)C1=NN=NN1 IWMOUXZYHULGCL-UHFFFAOYSA-N 0.000 description 2
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- CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical compound CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 description 2
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- YUQWYOKVPSTRNH-UHFFFAOYSA-L 1,3-dimethylimidazol-1-ium;methyl-dioxido-oxo-$l^{5}-phosphane Chemical compound CP([O-])([O-])=O.CN1C=C[N+](C)=C1.CN1C=C[N+](C)=C1 YUQWYOKVPSTRNH-UHFFFAOYSA-L 0.000 description 1
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- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 241000321453 Paranthias colonus Species 0.000 description 1
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical class C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 1
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- 230000000740 bleeding effect Effects 0.000 description 1
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- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 238000005859 coupling reaction Methods 0.000 description 1
- MXTUDRWETHDXHP-UHFFFAOYSA-N cyanocyanamide 1H-imidazole Chemical compound C1=CNC=N1.N#CNC#N MXTUDRWETHDXHP-UHFFFAOYSA-N 0.000 description 1
- FMYCKRQZPVZFLW-UHFFFAOYSA-N cyanoiminomethylideneazanide tributyl(methyl)azanium Chemical compound [N-]=C=NC#N.CCCC[N+](C)(CCCC)CCCC FMYCKRQZPVZFLW-UHFFFAOYSA-N 0.000 description 1
- UBQLCZUQCFNAGM-UHFFFAOYSA-N cyanoiminomethylideneazanide;2-(3-methylimidazol-3-ium-1-yl)ethanol Chemical compound N#C[N-]C#N.CN1C=C[N+](CCO)=C1 UBQLCZUQCFNAGM-UHFFFAOYSA-N 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
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- 230000005484 gravity Effects 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- GLUUGHFHXGJENI-UHFFFAOYSA-O hydron piperazine Chemical compound [H+].C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-O 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 150000004693 imidazolium salts Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000012073 inactive phase Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
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- 238000011068 loading method Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 231100000219 mutagenic Toxicity 0.000 description 1
- 230000003505 mutagenic effect Effects 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
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- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
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- 230000001141 propulsive effect Effects 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000005588 protonation Effects 0.000 description 1
- 238000005956 quaternization reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
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- 230000009467 reduction Effects 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- JSFMCJBSPUHNHS-UHFFFAOYSA-N silver;cyanoiminomethylideneazanide Chemical compound [Ag+].N#C[N-]C#N JSFMCJBSPUHNHS-UHFFFAOYSA-N 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- IXBPPZBJIFNGJJ-UHFFFAOYSA-N sodium;cyanoiminomethylideneazanide Chemical compound [Na+].N#C[N-]C#N IXBPPZBJIFNGJJ-UHFFFAOYSA-N 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
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- 125000001424 substituent group Chemical group 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical compound CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
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Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B43/00—Compositions characterised by explosive or thermic constituents not provided for in groups C06B25/00 - C06B41/00
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06D—MEANS FOR GENERATING SMOKE OR MIST; GAS-ATTACK COMPOSITIONS; GENERATION OF GAS FOR BLASTING OR PROPULSION (CHEMICAL PART)
- C06D5/00—Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets
- C06D5/08—Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets by reaction of two or more liquids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Fuel Cell (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Inert Electrodes (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Claims (14)
- Monergol, eine Mischung umfassend, die enthält:- Distickstoffmonoxid (N2O) als Oxidans, mindestens teilweise in flüssiger Form und- einen Brennstoff in Form eines Salzes in der flüssigen Phase des N2O.
- Monergol nach Anspruch 1, derart, dass das Distickstoffmonoxid teilweise gasförmig ist.
- Monergol nach einem beliebigen der vorhergehenden Ansprüche, derart, dass seine flüssige Phase besteht aus:(i) einem Brennstoff in Form eines festen Salzes, wenn es bei Umgebungstemperatur isoliert ist und in dem N2O, das mindestens teilweise in flüssiger Form vorliegt, gelöst ist oder(ii) einem geschmolzenen Salz des Brennstoffs in binärer Mischung mit dem N2O, das mindestens teilweise in flüssiger Form vorliegt, oder(iii) einer ionischen Lösung des Brennstoffs, gelöst in einem organischen oder ionischen energetischen Lösungsmittel, in binärer Mischung mit dem N2O, das mindestens in flüssiger Form vorliegt.
- Monergol nach einem beliebigen der vorhergehenden Ansprüche, derart, dass der Brennstoff ein Salz einer energetischen organischen Verbindung ist.
- Monergol nach einem beliebigen der vorhergehenden Ansprüche, derart, dass der Brennstoff ein Salz eines Stickstoffderivats ist.
- Monergol nach einem beliebigen der vorhergehenden Ansprüche, derart, dass das Kation des Salzes ausgewählt ist aus:- den linearen Kationen, wie die Ammonium-Ionen, Hydroxylammonium-lonen, Hydrazinium-Ionen und ihren Derivaten;- den gesättigten heterozyklischen Kationen, wie Piperidinium, Piperazinium und ihren Derivaten; und- den aromatischen oder nichtaromatischen heterozyklischen Kationen, wie dem Azinium, Azolium, Diazolium, Triazolium und Tetrazolium, insbesondere Pyridinium, Pyrrolium, Isoxazolium, Pyrazolium, Oxazolium, Imidazolium, Oxadiazolium, Triazolium, Oxatriazolium, Tetrazolium, Pyrrolidium, Triazinium, Pyridazinium, Pyrimidinium, Pyrazinium, Piperidinium, 1,2,3- oder 1,2,4-Triazolium, 1,4,5-oder 2,4,5-Tetrazolium, sowie ihren -inium und -idinium Analoga und ihren Derivaten.
- Monergol nach Anspruch 6, derart, dass das Kation ausgewählt ist aus den Ammonium-, Imidazolium-, Triazolium-, Tetrazolium-Ionen und ihren Derivaten.
- Monergol nach einem beliebigen der vorhergehenden Ansprüche, derart, dass das Anion des Salzes ausgewählt ist aus:- den linearen Anionen, wie den Azid-, Nitrat-, Nitrylamid-, Dinitramid-, Nitroformiat-, Nitrit-, Acetat-, Cyanamid-, Dicyanamid-Ionen; und- den nichtgesättigten heterozyklischen Anionen, wie den Azolaten, wie Pyrrolat, Diazolat, wie Pyrazolat, Imidazolat, Triazolat, wie 1,2,3- und 1,2,4-Triazolat und Tetrazolat, wie Nitrotetrazolat und ihren Derivaten.
- Monergol nach Anspruch 8, derart, dass das Gegenion (Anion) ausgewählt ist aus den Azid-, Nitrat-, Dinitramid-, Dicyanamid-, Imidazolat-und Tetrazolat-Ionen und ihren Derivaten.
- Monergol nach einem beliebigen der vorhergehenden Ansprüche, derart, dass der Brennstoff ausgewählt ist aus:- Ammoniumacid (AA),- Tetrabutylammoniumacid,- Triazoliumnitrotetrazolat,- Azidotriazoliumnitrotetrazolat,- Ammoniumdinitramid (ADN),- Hydroxylammoniumacid (HAA),- Hydraziniumacid (HA),- 1-(2-Butynyl)-3-methylimidazoliumacid- Hydroxylammoniumnitrat (HAN),- Hydraziniumnitroformiat (HNF),- Ammoniumnitrat (AN),- Hydraziniumnitrat (HN),- Triethanolammoniumnitrat (TEAN),- Hydroxylammoniumdinitramid (HAON),- Ammoniumdicyanamid,- Imidazoliumdicyanamid,- 1-Butyl-3-methylimidazoliumdicyanamid,- 1-Butyl-2,3-dimethylamidazoliumacetat,- 1-Butyl-1-methylpyrrolidiniumacetat, 1-Butyl-1-methylpyrrolidiniumdicyanamid- 1-Ethanol-3-methylimidazoliumdicyanamid,- N-Tributyl-N-methylammoniumdicyanamid,- 1-Butyl-3-methylimidazoliumdicyanamide,- 1,2,4-Triazolium-4,5-dinitroimidazolat,- 1-Methyl-1,2,4-triazolium-4,5-dinitroimidazolat,- 3-Azido-1,2,4-triazolium-4,5-dinitroimidazolat,- 1-Methyl-3-azido-1,2,4-triazolium-4,5-dinitroimidazolat,- 4-Amino-1,2,4-triazolium-4,5-dinitroimidazolat,- 1,2,4-Triazolium-5-nitrotetrazolat,- 1-Methyl-1,2,4-triazolium-5-nitrotetrazolat,- 3-Azido-1,2,4-triazofium-5-nitrotetrazolat,- 1-Methyl-3-azido-1,2,4-triazolium-5-nitrotetrazolat,- 4-Amino-1,2,4-triazolium-5-nitrotetrazolat,- 1-Amino-4,5-dimethyltetrazoliumnitrat,- 2-Amino-4,5-dimethyltetrazoliumnitrat,- 1,5-Diamino-4-methyltetrazoliumnitrat- 1,5-Diamino-4-methyltetrazoliumdinitramid- 1,5-Diamino-4-methyltetrazoliumacid- 1,5-Diamino-4-methyltetrazoliumdinitramid.
- Verfahren zur Herstellung eines Monergols nach einem beliebigen der vorhergehenden Ansprüche, den Schritt der Mischung des Brennstoffs und des N2O in einer geschlossenen Umhüllung umfassend.
- Verfahren für den Raumantrieb mittels eines Monergols nach einem beliebigen der Ansprüche 1 bis 10.
- Verfahren für den Raumantrieb nach Anspruch 12, die Verbrennung des Monergols durch gesteuertes Zünden umfassend.
- Verfahren nach Anspruch 12 oder 13, das Mittel zur Druckbeaufschlagung des Monergols in dem Behälter umfassend.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1250794A FR2986229B1 (fr) | 2012-01-27 | 2012-01-27 | Nouveaux monergols ioniques a base de n2o pour la propulsion spatiale |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP2620422A1 EP2620422A1 (de) | 2013-07-31 |
| EP2620422B1 true EP2620422B1 (de) | 2014-04-23 |
Family
ID=47559353
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP13152595.8A Active EP2620422B1 (de) | 2012-01-27 | 2013-01-24 | Ionische, monergole Treibstoffe auf N2O-Basis für den Raumantreib |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US20130305685A1 (de) |
| EP (1) | EP2620422B1 (de) |
| JP (1) | JP6154142B2 (de) |
| FR (1) | FR2986229B1 (de) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6484224B2 (ja) | 2013-05-20 | 2019-03-13 | イーシーエイピーエス・アクチボラグ | デュアルモード化学ロケットエンジンおよびデュアルモード化学ロケットエンジンを備えるデュアルモード推進システム |
| JP6240940B2 (ja) * | 2014-02-06 | 2017-12-06 | 株式会社Adeka | エポキシ樹脂組成物 |
| WO2015118952A1 (ja) * | 2014-02-06 | 2015-08-13 | 株式会社Adeka | 新規化合物及びそれを含有してなるエポキシ樹脂組成物 |
| CN106370301A (zh) * | 2016-08-24 | 2017-02-01 | 中国科学院合肥物质科学研究院 | 用于星载大气环境探测仪的防潮防污染导流吹氮保护系统 |
| CN108981162A (zh) * | 2018-06-06 | 2018-12-11 | 朱焕旺 | 一种熔盐循环运行工艺 |
| CN111925262B (zh) * | 2020-08-19 | 2021-08-27 | 中国工程物理研究院化工材料研究所 | 基于金属氯化物的多组分低共融液体的制备方法 |
| DE102020122337A1 (de) * | 2020-08-26 | 2022-03-03 | LabOrbital GmbH | Heißgaserzeugungsvorrichtung mit monergolem ionischen Treibstoff und Niederspannungsanzündung |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8006A (en) * | 1851-04-01 | Horseshoe-nail machine | ||
| DE4303169C1 (de) * | 1993-02-04 | 1994-04-28 | Dynamit Nobel Ag | Gasentwickelndes Material sowie Verwendung des Materials zur Erzeugung von Nutz- oder Druckgas |
| US6045638A (en) * | 1998-10-09 | 2000-04-04 | Atlantic Research Corporation | Monopropellant and propellant compositions including mono and polyaminoguanidine dinitrate |
| SE513930C2 (sv) | 1999-02-26 | 2000-11-27 | Svenska Rymdaktiebolaget | Flytande drivmedel |
| AU5695001A (en) * | 1999-11-11 | 2001-07-24 | Kelly Space & Technology, Inc. | Nitrous oxide/fuel monopropellants |
| US7771549B1 (en) * | 2002-10-07 | 2010-08-10 | United States Of America As Represented By The Secretary Of The Air Force | Energetic ionic liquids |
| JP4333943B2 (ja) * | 2003-05-01 | 2009-09-16 | 株式会社Ｉｈｉ | Ｈａｎ／ｈｎベースモノプロペラントを用いた高温ガス発生方法 |
| US6931832B2 (en) * | 2003-05-13 | 2005-08-23 | United Technologies Corporation | Monopropellant combustion system |
| US7745635B1 (en) * | 2003-06-16 | 2010-06-29 | Drake Greg W | Energetic ionic salts |
| US20050269001A1 (en) * | 2004-04-22 | 2005-12-08 | Liotta Charles L | Ionic liquid energetic materials |
| EP2084394A4 (de) * | 2006-11-13 | 2013-06-19 | Space Propulsion Group Inc | Mischungen aus stickstoffoxiden und sauerstoff als oxidationsmittel für antriebs-, treibstoff und energieerzeugungsanwendungen |
| US8034202B1 (en) * | 2007-10-04 | 2011-10-11 | The United States Of America As Represented By The Secretary Of The Air Force | Hypergolic fuels |
| CN101855325A (zh) * | 2007-11-09 | 2010-10-06 | 火星工程有限公司 | 氧化亚氮燃料掺混物单元推进剂 |
| US20120304620A1 (en) * | 2011-06-01 | 2012-12-06 | Aerojet-General Corporation | Catalyst, gas generator, and thruster with improved thermal capability and corrosion resistance |
-
2012
- 2012-01-27 FR FR1250794A patent/FR2986229B1/fr not_active Expired - Fee Related
-
2013
- 2013-01-24 EP EP13152595.8A patent/EP2620422B1/de active Active
- 2013-01-25 JP JP2013012051A patent/JP6154142B2/ja active Active
- 2013-01-28 US US13/751,774 patent/US20130305685A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| JP6154142B2 (ja) | 2017-06-28 |
| FR2986229B1 (fr) | 2014-03-21 |
| JP2013155105A (ja) | 2013-08-15 |
| US20130305685A1 (en) | 2013-11-21 |
| EP2620422A1 (de) | 2013-07-31 |
| FR2986229A1 (fr) | 2013-08-02 |
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