EP2609229A1 - Réduction catalytique sélective par électrolyse d'urée - Google Patents

Réduction catalytique sélective par électrolyse d'urée

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Publication number
EP2609229A1
EP2609229A1 EP11754960.0A EP11754960A EP2609229A1 EP 2609229 A1 EP2609229 A1 EP 2609229A1 EP 11754960 A EP11754960 A EP 11754960A EP 2609229 A1 EP2609229 A1 EP 2609229A1
Authority
EP
European Patent Office
Prior art keywords
urea
electrolytic
electrolyte composition
anode
alkaline electrolyte
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP11754960.0A
Other languages
German (de)
English (en)
Inventor
Gerardine G. Botte
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ohio University
Ohio State University
Original Assignee
Ohio University
Ohio State University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/077,277 external-priority patent/US8388920B2/en
Application filed by Ohio University, Ohio State University filed Critical Ohio University
Publication of EP2609229A1 publication Critical patent/EP2609229A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/27—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F01N3/2066—Selective catalytic reduction [SCR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2067—Urea
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2240/00—Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being
    • F01N2240/25—Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being an ammonia generator
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2240/00—Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being
    • F01N2240/34—Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being an electrolyser
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2240/00—Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being
    • F01N2240/40—Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being a hydrolysis catalyst
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2610/00—Adding substances to exhaust gases
    • F01N2610/02—Adding substances to exhaust gases the substance being ammonia or urea
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

Definitions

  • the present invention relates to methods and devices for treating exhaust gases.
  • the exhaust gas of vehicles powered with diesel fuel contains chemical pollutants such as nitrogen oxides (“NOx”) and sulfur oxides (“SOx”), as well as particulates.
  • Selective catalytic reduction (SCR) and selective non-catalytic reduction (SNCR) are means for converting nitrogen oxides (NO .* ) into diatomic nitrogen, N 2 , and water, H 2 0.
  • SCR selective catalytic reduction
  • SNCR selective non-catalytic reduction
  • a catalyst is used in combination with a gaseous reductant, which is added to a stream of flue or exhaust gas and is absorbed onto the catalyst.
  • the reductant is injected into the flue gas in a furnace within an appropriate temperature window.
  • flue gas conditioning with a gaseous reductant can also enhance electrostatic precipitator performance for removing fly ash.
  • the reductant is typically ammonia or urea.
  • ammonia is more reactive, is more easily dispersed uniformly into the flue gas stream, and is active over a broader temperature range, as well as being more efficient.
  • Urea as such, while also an effective reductant, forms unwanted byproducts, such as carbon monoxide (CO) and nitrous oxide (N 2 0), both of which are now under critical scrutiny by environmental authorities.
  • CO carbon monoxide
  • N 2 0 nitrous oxide
  • Commonly urea is thermally hydrolyzed to form ammonia for exhaust gas treatment applications. The hydrolysis of urea to form ammonia can be broken down into two distinct reactions. The first reaction is a mildly exothermic reaction, wherein heat is given off as urea hydrolyzes to form ammonium carbamate.
  • the second reaction in which the ammonium carbamate is converted to ammonia and carbon dioxide, is strongly endothermic, which overall dominates the thermodynamics of the conversion of urea to ammonia and carbon dioxide, i.e., the overall reaction is endothermic. Therefore, the hydrolysis of urea requires a substantial amount of heat and quickly stops when the supply of heat is withdrawn. For example, the liberation of ammonia commences at around 110°C and becomes rapid at around 150°C to 160°C, with or without catalytic assistance.
  • the water quality is important.
  • a conventional thermal hydrolysis of urea to ammonia for an SCR system an aqueous solution of urea is atomized through a spray nozzle into a heated vaporization chamber.
  • the excess water is also vaporized during the hydrolysis of urea to ammonia, thereby leaving behind any non- volatile substances such as minerals.
  • Minerals and other non-volatile substances can adhere to equipment surfaces, such as spray nozzles and the vaporization chamber walls, and build up over time, which may lead to blockage of the spray nozzle or reduced heat transfer efficiency to the vaporization chamber.
  • the water used in thermal hydrolysis systems needs to be demineralized.
  • the thermal hydrolysis of urea method is also sensitive to the quality of the urea. For example, formaldehyde present in urea can negatively affect the performance of an SCR system in a way similar to that of using demineralized water.
  • the hydrolysis of urea requires an external heat source to initiate the reaction, even when coupled with combustion engines, and also is sensitive to the extent of demineralization of the water, and the quality of urea used in the hydrolysis.
  • the present invention is premised on the realization that ammonia can be produced from the electrolysis of urea to supply exhaust gas treatment applications, such as selective catalytic reduction (SCR) systems, selective non-catalytic reduction (SNCR) systems, and/or flue gas conditioning systems.
  • SCR selective catalytic reduction
  • SNCR selective non-catalytic reduction
  • flue gas conditioning systems such as flue gas conditioning systems.
  • a method for supplying N3 ⁇ 4 to an exhaust gas treatment system includes supplying urea to an electrolytic flow cell that includes an inlet, an outlet, a cathode having a first conducting component, an anode having a second conducting component, an alkaline electrolyte composition in electrical communication with the anode and the cathode, and a recirculation system operatively coupled to the inlet and the outlet of the electrolytic cell; producing ammonia by the electrolytic hydrolysis of urea by applying a voltage difference to the electrolytic flow cell, wherein the voltage difference is applied across a cathode and an anode, wherein the voltage difference is sufficient to effect the electrolytic hydrolysis of urea to produce at least N3 ⁇ 4; recovering at least a portion of the N3 ⁇ 4; transferring the at least a portion of the NH 3 to the exhaust gas treatment system; and recirculating at least a portion of the alkaline electrolyte composition.
  • an exhaust gas treatment system for a combustion engine includes at least one of a selective catalytic reduction system, a selective non-catalytic reduction system, or a flue gas conditioning system; and an ammonia generator.
  • the ammonia generator includes an electrolytic flow cell having an inlet, at least one outlet, a cathode having a first conducting component, an anode having a second conducting component, an alkaline electrolyte composition in electrical communication with the anode and the cathode, where the alkaline electrolyte composition has a hydroxide concentration of at least 0.01 M or a pH of at least 8, and a recirculation system operatively coupled to the inlet and the at least one outlet of the electrolytic cell.
  • the at least one outlet from the ammonia generator is further in communication with the at least one of the selective catalytic reduction system, the selective non-catalytic reduction system, or the flue gas conditioning system.
  • FIG. 1 is a schematic representation of a method to produce ammonia from urea
  • FIG 2 is a diagrammatical view of a simplified electrolytic cell coupled to exhausted combustion gases
  • FIG. 3 is a diagrammatical view of a method to purify exhaust gases from a combustion engine
  • FIG. 4 is a plot of current density at a constant voltage (1.4 V) in the
  • FIG. 5 is a plot of current density at a constant voltage (1.33 V) in the electrochemical cell over time
  • FIG. 6 is a diagrammatic depiction of an electrolytic ammonia generator system according to an embodiment of the present invention.
  • FIG. 7 is exploded view of an electrolytic flow cell according to an embodiment of the present invention.
  • FIG. 8 is a diagrammatic depiction of an electrolytic ammonia generator system according to another embodiment of the present invention.
  • FIG. 9 is a diagrammatic depiction of an electrolytic ammonia generator system according to yet another embodiment of the present invention.
  • urea may be subjected to electrolysis-induced hydrolysis in an electrolytic device.
  • the electrolytic device may comprise a cell or multiple cells that each contains an anode and a cathode.
  • the electrolytic cell can operate in batch mode, continuous mode, semi-continuous, and with recirculation, as needed to provide on demand and controlled injection of ammonia into a process gas stream such as a combustion gas exhaust.
  • the working electrode of the cell urea is hydrolyzed to ammonia.
  • Equation 8 The overall hydrolysis reaction is provided in Equation 8 below.
  • An electrode assembly comprising two electrodes, an anode 3 and a cathode 4, is suspended within an alkaline electrolyte composition 6 contained in tank 2.
  • a separator 5 may be positioned between the anode and cathode.
  • the alkaline electrolyte composition 6 includes an effective amount of urea as described below.
  • the anode 3 and cathode 4 are electrically connected to a voltage source 7, which provides the electrical energy for the electrolysis of urea contained in the alkaline electrolyte composition 6.
  • a voltage source 7 which provides the electrical energy for the electrolysis of urea contained in the alkaline electrolyte composition 6.
  • the alkaline electrolyte composition may be stirred to facilitate mass transfer. It will be readily apparent to one of ordinary skill in the art that the above cell is readily adaptable to a continuous flow cell configuration, semi- continuous, and with recirculation of the alkaline electrolyte composition, as discussed in detail below.
  • the electrodes comprise a conductor or a support which can be coated with one or more active conducting components.
  • Exemplary conductors include, but are not limited to, metals such as nickel and platinum, alloys such as carbon steel or stainless steel, or other materials capable of conducting electricity such as carbon or graphite.
  • Exemplary electrode support materials may be chosen from many known supports, such as foils, meshes, sponges, and beads, for example.
  • the support materials may include, but are not limited to, Ni foils, Ti foils, graphite, carbon fibers, carbon paper, glassy carbon, carbon nanofibers, and carbon nanotubes. Aside from these specific support materials listed, other suitable supports will be recognized by those of ordinary skill in the art.
  • the cathode may comprise a conductor that is inert to an alkaline electrolyte composition. Additionally, the cathode may further include a support material that is inert to the alkaline electrolyte compositions and coated with one or more active conducting components.
  • the conducting component of the cathode may include carbon, cobalt, copper, iridium, iron, nickel, palladium, platinum, rhodium, ruthenium, or mixtures or alloys thereof.
  • Exemplary conducting components include carbon steel and stainless steel.
  • the anode may comprise a conductor that is inert to the alkaline electrolyte composition. Additionally, the anode may further include a support material that is inert to the alkaline electrolyte compositions and coated with one or more active conducting components. According to embodiments of the present invention, the reaction of urea hydrolysis occurs at the conducting component of the anode. Therefore, the conductor and/or the conducting component at the anode is one or more metals active toward electrolytic hydrolysis of urea. Active metals may include cobalt, copper, iridium, iron, platinum, nickel, rhodium, ruthenium, or mixtures or alloys thereof, for example, and in particular, nickel. The active metals may be in an oxidized form, such as nickel oxyhydroxide.
  • the structure of the anode is not limited to any specific shape or form.
  • the active metal may be formed as foil, wire, gauze, bead, or coated onto a support.
  • Exemplary working electrodes include, nickel electrodeposited on a carbon support, such as carbon fibers, carbon paper, glassy carbon, carbon nanofibers, or carbon nanotubes, and nickel formed into beads and suspended in a nickel gauze.
  • a carbon support such as carbon fibers, carbon paper, glassy carbon, carbon nanofibers, or carbon nanotubes
  • Ni oxyhydroxide modified nickel electrode on different 4 cm 2 - metallic substrates (Ni foil, Ni gauze, Ti foil and Ti gauze) that have been electroplated with 10 ⁇ 0.1 mg of Ni using a Watts bath.
  • the plated nickel electrode is activated by immersed in a solution containing nickel sulfate, sodium acetate, and sodium hydroxide at 33°C.
  • Stainless steel is used as counter electrode.
  • the plated nickel electrode may be used as the anode and cathode by manual polarity switching at 6.25 A/m 2 for four 1 -minute cycles and two 2-minute cycles.
  • the separator 5 compartmentalizes the anode and cathode. Separators should be constructed from materials chemically resistant to the alkaline electrolyte composition. Many polymers are suitable for constructing separators, such as Teflon® and polypropylene.
  • Separators are not required for simple batch-type arrangements, but may be advantageous for continuous flow electrochemical cells or fuel cells.
  • Separators may include ion exchange membranes, solid electrolytes or electrolytic gels, for example. Separators may be permeable, semi-permeable or impermeable to gases or liquids.
  • the electrolyte composition is alkaline and has a hydroxide ion concentration of at least 0.01 M or a pH of at least 8.
  • the alkaline electrolyte composition has a hydroxide concentration of at least 0.01 M and a pH of at least 8.
  • the alkaline electrolyte composition may include a sufficient quantity of any suitable hydroxide salt, carbonate salt or bicarbonate salt to provide an electrolyte composition with a hydroxide ion concentration of at least 0.01M and/or a pH of at least 8.
  • alkali metal hydroxide or alkaline earth metal hydroxide salt such as lithium hydroxide, rubidium hydroxide, cesium hydroxide, barium hydroxide, strontium hydroxide, potassium hydroxide, sodium hydroxide, magnesium hydroxide, calcium hydroxide, and mixtures thereof may be used.
  • the alkaline electrolyte composition includes potassium hydroxide.
  • the sequestration of CO 2 gas, shown in Equation 1 may be realized by the reaction of C0 2 with hydroxide to form carbonate, which may be retained in the alkaline electrolyte composition.
  • alkali metal carbonates or bicarbonate salts or alkaline earth metal carbonates or bicarbonate salts are also suitable electrolytes.
  • the concentration of the hydroxide, carbonate, or bicarbonate salts may vary according to embodiments of the invention.
  • the concentration of the hydroxide, carbonate, or bicarbonate salts may be from about 0.01 M to about 8 M.
  • the concentrations of potassium hydroxide, potassium carbonate, potassium bicarbonate, sodium hydroxide, sodium carbonate, or sodium bicarbonate from about 2 M to about 8 M and from about 4 M to about 8 M, are particularly effective.
  • the alkaline electrolyte composition may comprise a gel, such as a solid polymer electrolyte.
  • Suitable gels include, but are not limited to, those containing polyacrylic acid, polyacrylates, polymethacrylates, polyacrylamides and similar polymers and copolymers.
  • the electrolytic gel may be prepared using any suitable method. One method includes forming a polymer and then injecting a hydroxide, a carbonate or a bicarbonate salt electrolyte into the polymer to form a polymeric mixture. In another method, the monomer may be polymerized in the presence of a hydroxide, a carbonate, or bicarbonate salt electrolyte.
  • the electrodes are separated by the electrolyte gel which contains an effective hydroxide, carbonate, or bicarbonate ion concentration.
  • the anode is contacted with a urea solution as the feed stock.
  • the cathode is then contacted with a suitable aqueous solution, such as water or a hydroxide, carbonate, or bicarbonate solution, for example.
  • the gel electrolyte is not fixed and can flow through an electrolytic cell.
  • urea may be contained within the gel or an aqueous solution comprising urea may flow within the gel electrolyte.
  • the electrolyte composition 6 includes urea, which may vary from trace amounts up to about a saturated solution, which is approximately 12 M at standard temperature and pressure.
  • urea which may vary from trace amounts up to about a saturated solution, which is approximately 12 M at standard temperature and pressure.
  • the specific source and purity of the urea is not particularly limited.
  • aqueous solutions of urea the specific source and purity of the water used in making the aqueous solution is not particularly limited or critical.
  • the entire aqueous solution comprising urea is not volatilized to thereby leave behind trace minerals and other non- volatile materials. Instead, the majority of the water remains in the liquid form, which substantially maintains the trace minerals in solution.
  • the aqueous solution or the alkaline electrolyte composition being discharged from the electrochemical cell may be recirculated.
  • Voltage source 7 may be any available source, such as batteries, fuel cells, power from the grid, and renewable energy sources, such as a solar cell or a wind-turbine generator, for example.
  • the electric source may be from an alternator.
  • a voltage sufficient to initiate the electrolytic hydrolysis of urea is required. But it is preferable that the voltage not be so high as to significantly electrolyze water. Generally, the minimum voltage required to electrolyze or electrolytically-hydrolyze urea is about 0.85 volts.
  • the voltage required to electrolyze water is greater than 1.7 volts with a platinum electrode at standard conditions, but the rate of electrolysis and/or electrolysis -induced hydrolysis depends on other factors, such as temperature and ionic strength/conductivity.
  • the voltage range applied to the electrolytic cell to electrolytically-hydrolyze urea may be from about 0.85 volts to less than about 1.7 volts.
  • the voltage range may be from about 1.2 volts to about 1.6 volts.
  • the electrolytic cell will be operated at a constant voltage within these ranges.
  • the rate of producing ammonia and/or hydrogen from urea may be controlled by varying the voltage within different regions of the electrolytic cell.
  • the voltage within the packed-bed of an anodic catalyst material can be adjusted along the catalyst bed to control the rate of ammonia production and/or injection into an SCR or SNCR device.
  • different regions in the catalyst bed may have different potentials to control the rate of ammonia production.
  • a packed bed column configuration may include a plurality of anodes with each being electrically insulated from the other anodes and capable of having voltage controlled separately thereto, such as that represented in FIG. 6.
  • the totality of the anodes may be polarized. However, when a lower amount of ammonia is desired, then less than all of the anodes are polarized.
  • Amperage or current density may affect the performance of an electrolytic cell, as well. Pure water has poor electrical conductivity and, as such, electrolysis in pure water is very slow and essentially occurs due to the self-ionization of water. Generally, the rate of electrolysis increases by adding an electrolyte, such as a salt, an acid or a base. Therefore, the presence of an added hydroxide ion, a carbonate ion or a bicarbonate ion and its respective counter ion in the alkaline electrolyte composition enhances the conduction of electrical current.
  • the current density of the electrolytic cell described herein ranges from about 1 mA/cm 2 to about 500 mA/cm 2 .
  • the current density range may be from about 50 mA/cm 2 to about 400 mA/cm 2 .
  • the current density range may be from about 200 mA/cm 2 to about 300 mA/cm 2 .
  • the electrical current may also be used to control the production of ammonia from the electrolytic hydrolysis of urea and therefore control the rate of injecting ammonia into an exhaust gas treatment system. For example, a given electrical current may be required to induce the active form of the active metal in all the regions of the anode to maximize the production of ammonia.
  • the applied current may be lowered when the need for ammonia decreases.
  • Electrolytic cells may operate over varying ranges of pressure and temperature.
  • the operating pressure may be about atmospheric pressure or ambient pressure with no upper pressure limit other than the physical limits of the reaction vessel. If desired, the operating pressure of the electrolytic cell may be varied to control the rate of ammonia that is injected into an exhaust gas.
  • the operating temperature range may be from about 0°C to about 100°C.
  • An acceptable operating temperature range may be from about 40°C to about 80°C. More specifically, an operating temperature range from about 60°C to about 70°C is particularly useful.
  • the temperature in the electrolytic cell may be controlled with any available source.
  • the electrolytic cell may further include a heater apparatus operatively coupled to electrolytic cell, and/or a recirculation system operatively coupled to the electrolytic cell, wherein the recirculation system contains at least a portion of the alkaline electrolyte composition.
  • Exemplary heating apparatus include heating jackets that surround the electrolytic cell, from which heat may be supplied by external sources, such as steam, heated water, or other heated fluids.
  • Other possible heating sources can include, but are not limited to, electric heaters or combustion gases.
  • the electrolytic cell may further include a heater apparatus operatively coupled to electrolytic cell, and/or a recirculation system operatively coupled to the electrolytic cell, wherein the recirculation system contains at least a portion of the alkaline electrolyte composition.
  • Exemplary heating apparatus include heating jackets that surround the electrolytic cell, from which heat may be supplied by external sources, such as steam, heated water, or other heated fluids.
  • recirculation system may also include a heating apparatus for increasing the temperature of the alkaline electrolyte composition at a point external to the electrolytic cell.
  • the desired heating source may depend on the availability and/or compatibility with the system. For example, electric heat may be the most convenient way to provide the heat to achieve a desired operating temperature for the use of the electrolytic cell in an automobile SCR system, especially during cold start and during extreme weather conditions. Accordingly, the electrolytic cell may have temperature control that is independent of the temperature of the engine.
  • FIG. 6 An exemplary system for the continuous generation of sufficient quantities of ammonia to adequately supply the needs of a coal fired power plant on a continuous basis is shown in FIG. 6.
  • urea prill is supplied via a rotary feed valve 12 to a mix tank 14 where the urea prill is mixed with water from a water supply 16 to form a urea solution.
  • the mix tank 14 includes a discharge line 18, which supplies the urea solution to a urea solution feed pump 20 to transfer the urea solution to a urea electrolyte tank 24 through the urea electrolyte tank inlet 22.
  • a urea solution recirculation line 26 permits continuous operation of the urea solution feed pump 20.
  • the urea electrolyte composition is formed by mixing the urea solution from the mix tank 14 with an alkaline electrolyte composition including hydroxide, carbonate, or bicarbonate salts of alkali metals or alkaline earth metal, or combinations thereof.
  • the urea electrolyte tank 24 includes a discharge line 28, which supplies the urea electrolyte solution to a urea electrolyte solution feed pump 30 to transfer the urea electrolyte solution through an electrolytic cell inlet 32 to an electrolytic cell 34.
  • a urea electrolyte solution recirculation line 36 permits continuous operation of the urea electrolyte solution feed pump 30, and may also participate in control of the volume or level of urea electrolyte solution within the electrolytic cell 34.
  • the electrolytic cell 34 includes a heating jacket 38 having an inlet line 40 and an outlet line 42 for recirculating heating fluids therethrough.
  • One typical flow cell design is that of a packed-bed type of electrolytic flow cell, which enables the voltage and/or the current within the packed bed of anodic catalyst material to be varied along the catalyst bed and thereby control the rate of ammonia evolution.
  • a packed-bed type flow cell is depicted in FIG. 6 with VI -V6 representing the variable voltage capability of the electrolytic cell 34, where the insulating materials between the electrically insulated regions of the packed anodic catalyst bed are not shown.
  • This configuration is also adaptable for controlling the amount of urea being hydrolyzed based on the level or volume of urea electrolyte solution covering the catalyst bed.
  • varying an area percentage of a total area of the anodic catalyst bed in contact with a urea solution will vary the rate of ammonia production.
  • increasing the amount of urea electrolyte solution covering the available catalyst bed will increase the rate of ammonia production.
  • the urea electrolyte solution flows through the electrolytic cell 34 and thereby contacting the electrodes. Accordingly, the generated ammonia from the electrolytic hydrolysis of urea is supplied to an exhaust gas treatment system through an ammonia discharge line 44. Depending on the electrolytic cell operating conditions, hydrogen may also be produced and supplied to auxiliary systems through a hydrogen gas discharge line 46.
  • the urea electrolyte solution after having been depleted of at least a portion of its urea, is returned to the urea electrolyte tank 24 though urea electrolyte return line 48.
  • the alkaline electrolyte composition is concentrated to a desired level prior to being returned to the urea electrolyte tank 24.
  • the urea electrolyte return line 48 delivers the discharge of the electrolytic cell 34 to an evaporator 50 wherein excess water is removed via a water discharge line 52 to achieve a desired concentration.
  • any non-hydrolyzed urea is principally retained in solution and is therefore also concentrated therein.
  • the concentrated electrolyte solution is then transferred to the urea electrolyte tank 24 through a concentrated electrolyte discharge line 54.
  • the rate of excess water removal can be controlled by modifying various parameters, such as temperature and pressure.
  • the operating temperature of the evaporator 50 may range from about 120°C to about 90 °C, depending on the relative operating pressure of the evaporator.
  • the evaporator 50 may be operated at about 110°C and near or below atmospheric pressure.
  • the source of heat for the evaporator 50 is not particularly constrained to any source.
  • a flow cell 60 may include a jacketed containment vessel 62 having a tubular cathode 64, a tubular anode 66 and a vessel lid 68.
  • the jacketed containment vessel 62 may be thermally controlled by any suitable method.
  • the jacketed vessel 62 further includes inlet 70.
  • a tubular separator 72 compartmentalizes the tubular cathode 64 and the tubular anode 66, which permits separation of the effluents therefrom.
  • each electrode chamber may have its own discharge port, whereby the vessel lid 68 is configured to accommodate a cathode connector tubing 74 and an anode connector tubing 76.
  • the cathode connector tubing 74 may be hollow and include a conductor to thereby provide both a discharge flow path from the proximity of the tubular cathode 64 and an electrical connection.
  • the anode connector tubing 76 may be hollow and include a conductor to thereby provide both a discharge flow path from the proximity of the tubular anode 66 and an electrical connection.
  • the urea may be supplied to the electrolytic flow cell 90 as a pre-dissolved, concentrated aqueous solution.
  • Many conventional SCR systems use to treat diesel exhaust utilize diesel exhaust fluid (DEF), which can be, for example, about 32 wt% urea dissolved in deionized water.
  • DEF diesel exhaust fluid
  • the exhaust gas treatment systems in accord with the principles of the present invention can include an ammonia generator 80, which further includes a DEF tank 82.
  • the DEF tank 82 transfers the DEF from the DEF tank 82 to a three way feed valve 86, which mixes the DEF and alkaline electrolyte composition in the desired portions to achieve a target urea concentration therein. If the DEF tank 82 is kept pressurized, for example, about 20 psig, a pump 20 will not be needed for the system. This may allow a more compact system for transportation applications.
  • the alkaline electrolyte composition is supplied via recirculating alkaline electrolyte composition supply line 87. The urea electrolyte solution is transferred through an electrolytic cell inlet 88 to the electrolytic cell 90.
  • the generated ammonia from the electrolytic hydrolysis of urea is supplied to an exhaust gas treatment system through an ammonia discharge line 92 through valve 93.
  • hydrogen may also be produced and supplied to auxiliary systems through a hydrogen gas discharge line 94 through valve 95.
  • the discharge of the electrolytic cell is directed to an evaporator 96 via pump 20, wherein the alkaline electrolyte composition is concentrated via removal of water via water discharge line 98.
  • the alkaline electrolyte composition may be concentrated near to the saturation point for the given alkaline electrolyte(s), which elevates the freezing point of the solution.
  • the ammonia generator 110 may include an electrolytic cell 130 having a supply of solid urea in a urea cartridge 120.
  • the urea may be transferred from the cartridge 120 via supply line 122 and mixed with water in a rotary mixing valve 12 prior to being added to the electrolytic cell 130 via inlet 128.
  • water need only be introduced into the system from water supply tank 124 via water supply line 126 over time to make up for the water consumed during the hydrolysis of urea (see Equation 8).
  • the water may be introduced at regularly scheduled time intervals and/or based on one or more operating parameter.
  • the water can be added directly in the electrolytic cell 130 at regularly schedule time intervals to decrease freezing point due its mixture with the electrolyte.
  • the ammonia and/or hydrogen which can be transported via discharge lines 132, 136 and valves 133, 137, respectively, are utilized for the treatment of exhaust combustion gas as described above.
  • the urea cartridge 120 may be contained within the electrolytic cell 130.
  • the electrolyte may be contained within the electrolytic cell and may be stored in gel form. Although not shown, the electrolyte can be recirculated within the electrolytic cell 130 to facilitate improved mixing with the urea cartridge 120.
  • Electrolytic Hydrolysis of Urea A cell containing 7 M KOH/0.33 M urea solution at atmospheric pressure was subjected to electrolysis-induced hydrolysis. A cell voltage of 1.4 volts was applied to a 2x2.5 cm 2 carbon-paper anode deposited with Ni, and a 5x5 cm 2 Pt foil cathode. Under these conditions, the presence of ammonia was detected from the conversion of urea into ammonia and carbon dioxide. The hydrolysis pathway becomes favorable with increasing hydroxide salt concentration and increasing temperatures. For example, urea samples contained in 0 M, 1 M, 5 M and 7 M KOH at 50°C for 89 hours produced 0.7%, 4.2%, 27.4% and 36.7% hydrolysis, respectively. A 7 M KOH sample of urea at 70°C for 24 hours provided over 95% hydrolysis.
  • Flow Cell Hydrolysis of Urea In a sandwich-style urea electrolytic cell that compartmentalized the anode and cathode, a polypropylene membrane was used as a separator.
  • the anode was constructed of a 5 cm 2 carbon-paper support, on which was electrodeposited Ni.
  • the cathode was constructed of a 5 cm 2 carbon paper support, on which was electrodeposited Pt.
  • the electrodes were immersed in 5M KOH/0.33 M urea at 70°C. A cell voltage of 1.33 volts was applied and ammonia evolved from the anode. It was noted that a small amount of hydrogen was produced from the cathode.
  • Electrolysis of Urea A cell containing 5 M KOH/0.33 M urea solution at 25°C and atmospheric pressure was subjected to electrolysis. A cell voltage of 1.4 volts was applied to a 2x2.5 cm 2 carbon-paper anode deposited with Ni, and a 5x5 cm 2 Pt foil cathode. It was determined by gas chromatography that the electrolysis of urea produced nitrogen at the anode of this electrolytic cell, whereas hydrogen was produced at the cathode. Ammonia, which is presumably derived from the electrolysis-induced hydrolysis of urea, was detected in the electrolyzed solution using an Orion ammonia selective electrode (ISE). No carbon species were detected in the gas phase. It is postulated that the generated CO2 was quickly transformed into potassium carbonate by reacting with potassium hydroxide in the alkaline electrolyte composition.
  • ISE Orion ammonia selective electrode
  • urea may be oxidized to nitrogen and carbon dioxide.
  • hydrogen may be produced, as shown in the following reaction:
  • the foregoing electrolysis of urea may provide hydrogen, which may be injected into a combustion chamber that is attached to the exhaust gas treatment system, as shown in FIG. 3.
  • adding hydrogen to the combustion chamber may facilitate improved fuel combustion efficiency, as well as reducing unwanted emission by-products.
  • the model system in accordance with the embodiment represented in FIG. 6 has been designed with an electrolytic cell having a total volume of 825 liter, with 660 liters of an anodic bed providing 1 ,247 m 2 of active metal surface.
  • operation mass transfer parameters were calculated for the foregoing system.
  • a comparison was made between the inventive electrolytic hydrolysis method (EU2A) and the commonly-used chemical hydrolysis.
  • EU2A inventive electrolytic hydrolysis method
  • Table 4 the electrolytic urea to ammonia (EU2A) hydrolysis method provides an ammonia stream which is predominantly (e.g., 64 molar %) comprised of ammonia.
  • the calculated parameters and comparison data are shown in Tables 3 and 4, respectively.
  • the model system in accordance with the embodiment represented in FIG. 8 was calculated for an electrolytic cell having a volume of 2 liters.
  • a comparison was made between the inventive electrolytic hydrolysis method (EU2A) and the commonly-used DEF- SCR systems used on diesel trucks (which are based on chemical hydrolysis).
  • EU2A inventive electrolytic hydrolysis method
  • DEF- SCR systems used on diesel trucks (which are based on chemical hydrolysis).
  • Table 5 the electrolytic urea to ammonia (EU2A) hydrolysis method provides an ammonia source that is substantially more volume and weight efficient compared to that of DEF-SCR chemical hydrolysis systems.
  • the model system in accordance with the embodiment represented in FIG. 9 was calculated for an electrolytic cell having a volume of 2 liters.
  • a comparison was made between the inventive electrolytic hydrolysis method (EU2A) using solid urea versus the conventional DEF-SCR system.
  • EU2A inventive electrolytic hydrolysis method
  • Table 6 the electrolytic urea to ammonia (EU2A) hydrolysis method provides an ammonia source that is substantially more volume efficient that chemical hydrolysis systems.
  • the deactivation may be attributed to the attachment of an oxidized film on the anode and/or the attachment of scale on the surface of the cathode.
  • This deactivation process deteriorates the electrolytic efficiency of the cell.
  • the current density can, in some instances, decrease for a constant applied voltage, thereby reducing the rate of electro-oxidation.
  • the current density sometimes can be sustained by increasing the applied voltage. In either instance, energy is wasted and the overall efficiency of the cell is diminished.
  • the reversed voltage may be the same or different as the operating voltage.
  • the reversal voltage may range from about 0.5 volts to about 2.0 volts.
  • Another suitable reversal voltage may range from about 1.4 volts to about 1.6 volts.
  • the period of time for applying a reversed voltage may vary from just a few minutes to tens of hours.
  • the first and second conducting components may both include one or more metals active toward electrochemical oxidation of urea, therefore either electrode may function as a cathode and produce hydrogen.
  • reversing the voltage is effectively an uninterrupted process, thereby allowing the reversed voltage to be applied for an indefinite period of time or until deactivation is again encountered.
  • electrodes may be operated for about 5 hours to about 20 hours before losing activity and requiring activation.
  • the anode's conducting component is comprised of a metal inactive toward electrochemical oxidation of urea
  • the regeneration may be achieved in about 1 minute to about 20 minutes at about 1.4 volts. In some instances, reactivation can be achieved in about 6 minutes at 1.4 volts.
  • the SCR unit is not particularly limited to any specific configuration or catalyst.
  • the catalyst is not limited to any species or form.
  • traditional catalysts based on vanadium, titanium, or iron or copper- promoted zeolite catalysts are suitable for use.
  • newer SCR catalysts such as those disclosed in U.S. Patent No. 7,527,776 by Golden et al. may be used.
  • the SNCR unit and /or the particle precipitator are not particularly limited to any specific design.
  • the electrolytic cells according to embodiments of the present invention may be adapted to couple with commercially available SCR or SNCR units or flue gas conditioning systems.
  • the electrolytic cell may be adapted to work with existing ammonia generators that thermally hydrolyze urea, or the electrolytic cell may be designed to be the lone source of ammonia for the exhaust gas treatment systems.
  • the cell and the exhaust gas treatment system such as an SCR or an SNCR system, may be designed as a combined unit.
  • the ammonia may normally be introduced into the exhaust gas prior to an electrostatic precipitator, an SNCR unit, or prior to contacting a catalyst within an SCR unit.
  • the exhaust gas and the ammonia as a reducing agent may be contacted with the catalyst, thereby reducing the nitrogen oxides in the exhaust gas.
  • the optimization of temperatures, pressures, flow rates and the like can readily be achieved by one having ordinary skill in the art of exhaust gas treatment technology.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Toxicology (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Treating Waste Gases (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
  • Catalysts (AREA)

Abstract

L'invention concerne un procédé de production d'ammoniac approprié pour une utilisation comme réducteur dans un système de traitement de gaz d'échappement de combustion, comprenant l'hydrolyse électrolytique d'urée dans des conditions douces. Le générateur d'ammoniac, qui comprend une cellule électrolytique 1 comprenant une anode 3, une cathode 4 et une composition électrolytique alcaline 6 d'urée, un appareil d'électrolyse comprenant une cellule électrolytique à circulation, une composition électrolytique alcaline et un système de recirculation, peut être couplé de manière fonctionnelle à un système de traitement de gaz d'échappement pour former un appareil destiné à la réduction des oxydes d'azote (NOx) et/ou des particules dans les gaz d'échappement.
EP11754960.0A 2010-08-23 2011-08-23 Réduction catalytique sélective par électrolyse d'urée Withdrawn EP2609229A1 (fr)

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US37610810P 2010-08-23 2010-08-23
US13/077,277 US8388920B2 (en) 2010-04-02 2011-03-31 Selective catalytic reduction via electrolysis of urea
PCT/US2011/048809 WO2012027368A1 (fr) 2010-08-23 2011-08-23 Réduction catalytique sélective par électrolyse d'urée

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KR (1) KR20130108309A (fr)
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JP6797685B2 (ja) * 2013-10-25 2020-12-09 オハイオ・ユニバーシティ グラフェンで覆われた電極を含む電気化学セル
FR3013381B1 (fr) 2013-11-15 2016-01-01 IFP Energies Nouvelles Procede de depollution des gaz d'echappement, notamment de moteur a combustion interne, en particulier pour vehicule automobile, et installation utilisant un tel procede.
CN104074577B (zh) * 2014-06-25 2016-04-06 同济大学 一种提高柴油机scr系统尿素热解水解效率的方法
US10036291B2 (en) * 2016-01-20 2018-07-31 Tenneco Automotive Operating Company Inc. Exhaust after-treatment system including ammonia and hydrogen generation
US10267196B1 (en) 2016-09-14 2019-04-23 Southwest Research Institute Treatment of reductant urea solutions with catalyst precursors to assist selective catalytic reduction
GB2552040B (en) * 2016-12-01 2018-08-01 Univ Loughborough Process for reducing nitrogen oxides
CN108033518B (zh) * 2017-11-27 2024-04-12 山西大学 一种降解含氯游泳池水中尿素的方法和装置
US10378411B1 (en) 2018-01-03 2019-08-13 Southwest Research Institute Dosing method and apparatus for reductant urea solutions with catalyst precursors to assist selective catalytic reduction
US10774715B1 (en) 2018-03-27 2020-09-15 Southwest Research Institute Stabilization of aqueous urea solutions containing organometallic catalyst precursors
CN109046188A (zh) * 2018-09-07 2018-12-21 唐勇 气液闭合回路离子反应方法
WO2020204393A1 (fr) * 2019-03-29 2020-10-08 울산과학기술원 Système d'épuration de gaz d'échappement permettant la réduction de poussière fine
CN110224165A (zh) * 2019-06-24 2019-09-10 云南省能源研究院有限公司 一种三元电解质凝胶聚合物电解液的制备方法及其应用
CN110273163A (zh) * 2019-07-23 2019-09-24 闫巍 一种可再生能源直接电解含尿素废水制氢的系统及方法
CN110512224A (zh) * 2019-08-30 2019-11-29 济南大学 一种电化学氧化生氮并同时还原固氮成氨的方法
CN113184953A (zh) * 2021-04-28 2021-07-30 中山大学 一种用于小便池的原位降解尿液装置
CN115305492B (zh) * 2022-07-01 2023-11-07 中国华能集团清洁能源技术研究院有限公司 交替进行尿素电解制氢和碳还原的系统及方法和应用系统
CN115094454B (zh) * 2022-07-01 2023-08-25 中国华能集团清洁能源技术研究院有限公司 用于尿素电解制氢和碳还原的电解池及方法
CN115305477A (zh) * 2022-07-01 2022-11-08 中国华能集团清洁能源技术研究院有限公司 电解尿素-二氧化碳还原制取合成气的系统和方法

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CA2809092A1 (fr) 2012-03-01
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CN103201411A (zh) 2013-07-10
BR112013003925A2 (pt) 2016-06-07

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