EP2566943A1 - Système de dosage conçu pour libérer des préparations contenant un agent de blanchiment au cours d'un programme de lavage d'un lave-linge - Google Patents

Système de dosage conçu pour libérer des préparations contenant un agent de blanchiment au cours d'un programme de lavage d'un lave-linge

Info

Publication number
EP2566943A1
EP2566943A1 EP11718007A EP11718007A EP2566943A1 EP 2566943 A1 EP2566943 A1 EP 2566943A1 EP 11718007 A EP11718007 A EP 11718007A EP 11718007 A EP11718007 A EP 11718007A EP 2566943 A1 EP2566943 A1 EP 2566943A1
Authority
EP
European Patent Office
Prior art keywords
chamber
cartridge
acid
dosing
washing machine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP11718007A
Other languages
German (de)
English (en)
Other versions
EP2566943B1 (fr
Inventor
Erik BRÜCKNER
Slavoljub Barackov
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to PL11718007T priority Critical patent/PL2566943T3/pl
Publication of EP2566943A1 publication Critical patent/EP2566943A1/fr
Application granted granted Critical
Publication of EP2566943B1 publication Critical patent/EP2566943B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/046—Insoluble free body dispenser
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3947—Liquid compositions
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F39/00—Details of washing machines not specific to a single type of machines covered by groups D06F9/00 - D06F27/00 
    • D06F39/02—Devices for adding soap or other washing agents
    • D06F39/022—Devices for adding soap or other washing agents in a liquid state

Definitions

  • the invention relates to a metering system for the release of at least one bleach-containing preparation during a washing program of a washing machine.
  • Machine detergents are available to consumers in a variety of forms. These mechanical detergents are typically offered to the consumer in solid form, for example as a powder or as tablets, but increasingly also in liquid or gel form. While the separation of incompatible ingredients with solid agents is usually relatively easy and can be done by wrapping the packaged in solid form individual substances come in liquid, especially aqueous preparations, the individual ingredients in close contact, so that in particular after storage an unreasonable decrease in the amount individual ingredients as a result of chemical reactions with other ingredients. Another main focus of the
  • one of the main objectives of the machine washing machine manufacturers is to improve the washing performance of these detergents, with a recent focus on the
  • Devices can be differentiated between integrated in the textile washing machine metering chambers on the one hand and stand-alone, independent of the textile washing machine devices on the other. By means of these devices multiplying the for the
  • the object of the present invention is to provide a metering system for a washing machine, which provides an improved dosage of a bleach-containing preparation in the treatment room of the washing machine.
  • the metering system according to the invention for releasing preparations inside a washing machine which achieves this object comprises at least one metering device and at least one cartridge which can be coupled to the metering device, wherein the cartridge comprises at least one chamber containing a flowable peroxocarboxylic acid-containing preparation.
  • the cartridge which can be coupled to the metering device comprises, in addition to the chamber containing the peroxycarboxylic acid-containing preparation, a further chamber or a total of at least three chambers which contain different flowable preparations, the further or first chamber storing at least one enzyme and one surfactant, the second chamber at least one preparation containing peroxycarboxylic acid is stored, and the optionally present third chamber stores at least one fragrance and / or one optical brightener and / or one conditioning agent.
  • the first chamber contains no bleaching agent, in particular no peroxycarboxylic acid, and / or no perfume.
  • the second chamber containing the peroxycarboxylic acid-containing preparation contains no enzyme and / or fragrance.
  • the third chamber if present, contains no bleach, especially no peroxycarboxylic acid, and / or no enzyme; It is very particularly preferred that the third chamber also contains no complexing agent and / or no surfactant.
  • the dosing device comprises at least one sensor which is suitable for detecting the presence of water inside the washing machine.
  • the dosing device comprises a conductivity sensor and / or
  • Washing machine represents a dosage from the chamber of the cartridge takes place. It is preferred that the dosage from the containing the peroxycarboxylic acid containing preparation chamber is triggered after a predefined time between 1 min and 45 min, preferably between 5 minutes and 20 minutes after the start of the washing process defined by the aforesaid sensor signal. This can be ensured in a simple manner that the ingredients of a already present at the beginning of the washing process, for example, with the hot water scavenging detergent over the predefined period can act on the laundry to be washed before the release of the peroxycarboxylic acid takes place.
  • an enzyme- and surfactant-containing liquid detergent can be used with the aid of
  • the dosing device is therefore configured in the presence of at least two chambers in the cartridge that after a predefined time, which is between 1 min and 30 min, preferably between 5 min and 15 min after the dosage of the enzyme - And surfactant-containing preparation from the first chamber of the cartridge is done, a dosage of the second peroxocarboxylic acid-containing
  • Preparation containing chamber is triggered.
  • the dosage from the first chamber of the cartridge is preferably carried out after a predefined time, which is between 0, 1 sec and 10 min, preferably between 0.5 min and 5 min after the start of the washing process.
  • the invention further comprises a method for releasing preparations inside a washing machine comprising at least one metering device with at least one sensor which is suitable for detecting the presence of water in the interior of the washing machine and at least one cartridge which can be coupled to the metering device, the cartridge being at least two, in particular at least three chambers comprising different flowable preparations from each other, wherein the first chamber at least one enzyme and a surfactant, preferably at a pH of 5 to 10, in particular 6-8 stored, the second chamber at least one peroxycarboxylic acid, preferably stored at a pH of from 2 to 7, in particular from 3 to 6, the third chamber, if present, at least one perfume and / or an optical brightener and / or a conditioner, preferably at a pH of 6-8, stored, wherein in the presence of at least one sensor signal, the presence of Wa Sser represents inside the washing machine, a dosage from the first chamber of the cartridge takes place and after a predefined time, which is between 1 min and 30 min, preferably between 5 min and
  • the washing performance of the abovementioned process can be markedly increased, especially at temperatures below 30 ° C., for example 10 ° C. to 30 ° C. and preferably at 15 ° C. to 25 ° C., provided the water feed is preceded by an ion exchanger, for example based on levatite , which acts to exchange the polyvalent cations for Na ions.
  • an ion exchanger for example based on levatite , which acts to exchange the polyvalent cations for Na ions.
  • an ion exchanger for example based on levatite
  • flowable detergent preparations can be supplied in a time-optimized manner to a washing process, so that an excellent washing performance with minimum use of raw materials, in particular in the area of enzymatically degradable and bleachable
  • the peroxocarboxylic acid-containing preparation is released at the beginning of the last fifth of the main wash, in particular in the last 5 to 10 minutes of the main wash.
  • the present invention with the time lag of the introduction of the active ingredients, it is possible to improve the washing performance of a liquid detergent bleachable stains under at least constant performance of enzyme-sensitive stains.
  • the overall performance of a liquid detergent can thus be increased to the performance of a powdered universal detergent.
  • Another advantage is that bad odors, as they can conventionally occur after repeated washing at low Temepraturen be avoided.
  • the improved hygiene of the washing machine and the laundry should be mentioned.
  • the controlled release of the peroxycarboxylic acid reduces its corrosion potential within the washing machine, which can particularly affect the heating element or in the area between the holding down device and the heating element. Likewise, the occurrence of yellowing of the textiles, especially based on polyamide, is avoided.
  • a cartridge is understood to mean a packaging material which is suitable for enveloping or holding together at least one flowable preparation and which can be coupled to a metering device for dispensing at least one preparation.
  • the cartridge is in particular designed so that it is provided for storing a plurality of dosing portions of the preparations to be stored in it.
  • the cartridge for storing 10 to 50, more preferably 15 to 30, most preferably 20 to 25 Dosierportionen formed.
  • the cartridge preferably has at least two, in particular at least three, preferably dimensionally stable chambers for storing preparations which are different from one another.
  • each of the chambers is designed to store from 10 to 50, particularly preferably 15 to 30, very particularly preferably 20 to 25 metering portions.
  • the cartridge has at least one outlet opening, which is arranged such that a gravity-induced release of preparation from the cartridge in the position of use of the dosing device can be effected.
  • the cartridge is integrally formed.
  • the cartridges in particular by suitable blow molding, cost-effectively trained in a manufacturing step.
  • the chambers of a cartridge can be separated from one another, for example, by webs or material bridges which are formed during or after the blow molding process.
  • the cartridge may also be formed in several pieces, for example by injection molded components and subsequently assembled components.
  • the cartridge is formed in several pieces so that at least one chamber, preferably all chambers, can be removed individually from the dosing device or inserted into the dosing device.
  • the chamber walls can in particular be shaped such that they can be positively connected to one another.
  • the cartridges are shaped in such a way that the chambers can be positively connected to one another only in a specific defined position.
  • the chambers of a cartridge can be fixed to one another by suitable connection methods, so that a container unit is formed.
  • the chambers can by means of a suitable form-fitting, non-positive or cohesive connection detachable or insoluble
  • connection can also be formed by a shrink sleeve (so-called sleeve), which is pulled in a heated state over the entire or sections of the cartridge and firmly encloses the chambers or the cartridge in the cooled state.
  • a shrink sleeve so-called sleeve
  • the cartridge may also be asymmetrical. It is particularly preferred to mold the asymmetry of the cartridge in such a way that the cartridge can only be coupled to the dosing device in a predefined position, thereby preventing an otherwise possible incorrect operation by the user.
  • a metering chamber may be formed.
  • the preparation amount that is to be released in the release of preparation from the chamber to the environment set.
  • the closure element of the dosing device which causes the preparation output from a chamber to the environment, can only be put into a dispensing and a closure state without measurement or control of the dispensing quantity. It is then ensured by the metering chamber that a predefined amount of preparation is released without an immediate feedback of the currently discharged, outflowing preparation amount.
  • the metering chambers can be formed in one piece or in several pieces. Furthermore, it is possible to firmly connect the metering chambers with the cartridge or detachably.
  • one or more chambers in addition to a, preferably bottom-side outlet opening each have a liquid-tight sealable, preferably head-side second chamber opening. Through this Chamber opening, it is possible, for example, to refill stored in this chamber preparation.
  • the cartridge can take on any spatial form. It can for example be cube-shaped, spherical or plate-like. To provide an immediate optical level control, it is advantageous, the cartridge at least partially from a
  • the cartridge is formed in particular dimensionally stable.
  • the cartridge is also conceivable to design the cartridge as a flexible packaging such as a tube.
  • flexible containers such as bags, in particular if they are inserted into a substantially dimensionally stable receptacle in accordance with the bag-in-bottle principle dimensionally stable cartridge designs described - the need to provide a ventilation system for pressure equalization.
  • the cartridge has an RFID tag that contains at least information about the contents of the cartridge and that can be read by a sensor unit, which may be provided in particular in the metering device or the washing machine. This information can be used, for example, to select a dosing program stored in the dosing unit control unit. In this way it can be ensured that an optimal dosing program is always used for a particular preparation. It can also be provided that in the absence of an RFID tag or an RFID tag with a false or faulty identifier, no metering is done by the metering device and instead an optical or acoustic signal is generated that the user to the present Error indicates.
  • the cartridges may also have structural elements that correspond to corresponding elements of the dispenser after the cartridge
  • the container coordinated control of the metering device can be done.
  • All preparations stored in the cartridge are free-flowing, since this ensures rapid dissolution of the preparations in the wash liquor, as a result of which these preparations have a rapid effect to achieve immediate cleaning or disinfecting and / or scenting effect, especially on the walls of the washroom and in the wash water lines.
  • the cartridge usually has a total filling volume of ⁇ 5,000 ml, in particular ⁇ 1,000 ml, preferably ⁇ 500 ml, more preferably ⁇ 250 ml, most preferably ⁇ 50 ml. If it has several chambers, the chambers of a cartridge may have the same or different filling volumes. In a configuration with two or three
  • Chambers the volume ratio is preferably 4: 1 or 4: 1: 1, wherein the enzyme-containing detergent preparation containing chamber preferably has the largest filling volume of the existing chambers.
  • the chambers which store a peroxycarbonic acid-containing preparation or a fragrance-containing preparation, have approximately the same filling volumes.
  • the cartridge comprises a cartridge bottom, which is directed in the position of use in the direction of gravity down and at the preferred for each chamber at least one in
  • Gravity direction is provided on the bottom side outlet opening.
  • the outlet openings arranged on the bottom side are in particular designed such that at least one, preferably all, outlet openings can communicate with the inlet openings of the dosing device, ie preparation via the outlet openings from the cartridge into the dosing device, preferably gravitationally effected, can flow in.
  • one or more chambers have a not arranged in the direction of gravity bottom outlet opening. This is particularly advantageous if, for example, a perfume should be delivered not only to the inside of the washing machine, but also to the environment of the cartridge.
  • the outlet openings of the cartridge are closed by closure means at least in the filled, unopened state of the cartridge.
  • the closure means may be designed such that they allow a single opening of the outlet opening by destruction of the closure means.
  • Such closure means are, for example, sealing foils or caps.
  • the outlet openings are each provided with a closure that allows in the coupled state with a dispenser outflow of preparation from the respective chambers and in the uncoupled state of the cartridge outflow of preparation in the
  • Ventilation opening for venting comprises at least one chamber, wherein the ventilation opening is separated from the discharge opening and the ventilation opening communicating with at least one chamber of the cartridge is connected. It is advantageous if, with multi-chamber cartridges, one ventilation opening and one discharge opening are provided for each chamber. It is further preferred that the bottom-side ventilation opening is communicatively connected to a ventilation channel, whose end facing away from the ventilation opening in the
  • the ventilation duct is completely or partially formed in or on the walls and / or webs of the cartridge.
  • the ventilation channel can be integrally formed in or on the walls and / or webs of the cartridge.
  • vent opening of a chamber is communicatively connected to the metering device side mandrel before the closed outlet opening of the corresponding chamber is opened, for example by the communicating connection with the inlet opening of the dosing device.
  • the cartridge may be designed so that it can be detachably or firmly arranged in or on the dosing device and / or the washing machine.
  • the metering system comprises a metering device and a cartridge which can be coupled to the metering device and contains flowable preparations, in particular a cartridge Multi-chamber cartridge.
  • the dosing device is configured in such a way that it can dose at least one, preferably a plurality of preparations from the chamber or the chambers of the cartridge into the interior of a washing machine.
  • at least one actuator and / or at least one closure element and / or at least one control unit and / or at least one sensor and / or at least one energy source can be provided in the dosing device.
  • the dosing device can be permanently installed with a washing machine.
  • a washing machine In a preferred embodiment
  • the metering device is not permanently installed with the washing machine, but freely movable in, on or on a washing machine can be positioned by a user.
  • the metering device is detachably or fixedly arranged within the Ein Togetherschublade the washing machine.
  • the dosing device comprises at least a first interface which cooperates in or on a washing machine formed corresponding interface in such a way that realizes a transfer of electrical energy and / or signals from the washing machine to the dosing and / or from the dosing to the washing machine is.
  • the interfaces are formed by connectors.
  • the interface cells can be designed in such a way that a wireless transmission of electrical energy and / or electrical and / or optical signals is effected.
  • the interfaces provided for the transmission of electrical energy are inductive transmitters or receivers
  • electromagnetic waves are.
  • Dosing be designed as a receiver coil with iron core.
  • the transmission of electrical energy can also be provided by means of an interface, the washing machine side, an electrically operated light source and dosierettifact a light sensor, such as a photodiode or a solar cell comprises.
  • the light emitted by the light source is converted by the light sensor into electrical energy, which in turn feeds, for example, a metering device side accumulator.
  • an interface on the dosing device and the washing machine for the transmission (that is, transmission and reception) of electromagnetic and / or optical signals, which in particular operating state, measuring and / or
  • an interface for the transmission of signals or an interface for the transmission of electrical energy or in each case an interface to provide for transmission of signals and an interface for the transmission of electrical energy or to provide an interface that is both suitable to provide a transmission of electrical energy and signals.
  • such an interface can be designed such that a wireless transmission of electrical energy and / or electromagnetic and / or optical signals is effected.
  • the interface is configured to transmit and / or receive optical signals. It is very particularly preferred for the interface to be configured to emit or receive light in the visible range. It has proven particularly advantageous to use wavelengths between 600 nm and 800 nm in the visible spectrum. Alternatively or additionally, it is advantageous that the interface for transmitting or receiving
  • Infrared signals is configured.
  • the interface comprises at least one LED.
  • the interface comprises at least two LEDs.
  • at least one LED is an RGB LED whose wavelength is adjustable.
  • an LED can be used to define different signal bands that emit signals at different wavelengths.
  • an optical signal is designed as a signal pulse with a pulse duration between 1 ms and 10 seconds, preferably between 5 ms and 100 ms seconds.
  • the signal transmitted and / or received by the interface is in particular a carrier of information, in particular a control signal or a signal representing an operating state of the dosing device and / or the washing machine.
  • the dosing device may comprise at least one optical receiving unit.
  • the dosing device can receive signals from an optical transmission unit arranged in the washing machine.
  • This can be realized by any suitable optical receiving unit, such as photocells, photomultipliers, semiconductor detectors, photodiodes, photoresistors, solar cells, phototransistors, CCD and / or CMOS image sensors. It is particularly preferred that the optical receiving unit is suitable for receiving light in the wavelength range of 600-800 nm.
  • the optical receiving unit on the dosing device can also be designed in such a way that the one coupled by the transmitting unit into a dosing device coupled to the dosing Cartridge einkoppelbaren signals from the cartridge and can be detected by the optical receiving unit of the dosing device are detectable.
  • the signals emitted by the transmitting unit into the surroundings of the metering device may preferably represent information regarding operating conditions or control commands.
  • the dosing device is arranged outside the washing machine in a preferred embodiment.
  • the metering device can be designed such that it can be coupled to a cartridge and is provided for positioning outside the treatment chamber of the water-conducting household appliance and has no connection to a water-carrying line of the water-conducting household appliance.
  • the dosing device comprises at least one sensor which detects at least the presence of water in the water-conducting domestic appliance, at least one pump which effects a delivery of preparation from the cartridge or dosing device, provided that the preparation does not escape from the cartridge or the dosing device due to gravity, at least one Control unit, which interacts with the sensor and optionally the pump in such a way that in the presence of a defined
  • Sensor signal at least one preparation from the cartridge or the dosing device is promoted or flowed out, and at least one fluid line that connects the cartridge or dosing with the treatment room of the water-bearing household appliance, so that a preparation from the outside of the treatment room of the water-conducting household appliance positioned dosing via a with the
  • Treatment room in connection opening of the water-conducting household appliance in the treatment room of the water-conducting household appliance can be fed.
  • the dosing device is arranged within the rotating treatment chamber of the washing machine. Another embodiment of this
  • Embodiment consists of a plurality of movable, in the treatment room of the
  • washing machine positionable dispensers for dispensing each of at least one flowable preparation provided, the preparations which are dispensed by the dispensers, as described above are different from each other and the dosing devices comprise means for releasing the preparations, which are configured in such a way that the dispensing the preparations at different times during a
  • an actuator is a device that converts an input variable into a different output quantity and with which an object is moved or whose movement is generated.
  • the actuator is preferably coupled to at least one closure element in such a way that the release of preparation from at least one cartridge chamber can be effected.
  • the actuator can be selected by means of drives selected from the group of gravity drives, ion drives, electric drives, motor drives, hydraulic drives, pneumatic drives, gear drives, threaded spindle drives, ball screws, linear drives, roller screws, tooth worm drives, piezoelectric drives,
  • the actuator is designed as a pump or compressor.
  • the actuator is a bistable solenoid which, together with an engaging in the bistable solenoid, designed as a plunger core
  • Closing element forms a pulse-controlled, bi-stable valve.
  • Bistable lifting magnets are electromechanical magnets with linear direction of movement, wherein the plunger locked in each end position without current.
  • Bistable lifting magnets or valves are known in the art. A bistable valve is needed to change valve positions
  • pulse-controlled valves do not consume energy to dwell in the valve end positions, the closed position and dispensing position, but only need an energy pulse to change the valve layers, thus the valve end positions are to be considered stable.
  • a bistable valve remains in that switching position, which last received a control signal.
  • a closure element is a component on which the actuator acts and which, as a result of this action, causes the opening or the closure of an outlet opening.
  • the closure element can be valves which can be brought into a product delivery position or closure position by the actuator.
  • the embodiment of the closure element and the actuator in the form of a solenoid valve, in which the dispenser is configured by the valve and the actuator by the electromagnetic or piezoelectric drive of the solenoid valve, in particular when using a plurality of containers and thus to dosing preparations leaves through the use of solenoid valves, the amount as well as the
  • a sensor is a measuring sensor or measuring sensor which can quantitatively record certain physical or chemical properties and / or the material quality of its environment qualitatively or as a measured variable.
  • the dosing system preferably has at least one sensor which is suitable for detecting a temperature.
  • the temperature sensor is designed in particular for detecting a water temperature.
  • the dosing system comprises a sensor for detecting the conductivity, whereby in particular the presence, the flushing and / or the spraying of water in a water-conducting domestic appliance is / are recorded.
  • Conduct resistance measurements on the conductivity sensor each with a different polarity, ie with an exchange of positive and negative pole, so that no charge surpluses can form on the contacts.
  • a sensor from the group of timers, temperature sensors, infrared sensors, brightness sensors, motion sensors,
  • Strain sensors speed sensors, proximity sensors, flow sensors, color sensors, gas sensors, vibration sensors, pressure sensors, conductivity sensors, turbidity sensors, sound pressure sensors, "lab-on-a-chip” sensors, force sensors,
  • Hydrogen sulfide sensors position sensors, gyroscopes, optical, electrical and / or mechanical displacement sensors, and / or MEMS sensors to be selected.
  • sensors can preferably be selected from the group of temperature sensors, motion sensors, rotational speed sensors, vibration sensors, conductivity sensors, turbidity sensors,
  • Rinse program to detect.
  • the conductivity sensor can be detected, for example, whether the conductivity sensor is wetted by water, so that, for example. determine whether water is in the water-bearing household appliance or flushed.
  • Treatment programs in water-bearing household appliances such as washing and rinsing programs, generally have a characteristic temperature profile, which is determined inter alia by the heating of the washing or rinsing water, which can be detected by a temperature sensor.
  • a vibration sensor By means of a vibration sensor, it is for example possible to detect natural oscillations or the resonance of a household appliance with a rotating treatment room, for example, if the washing drum is accelerated to spin the laundry to correspondingly high numbers of revolutions. Thus, it is conceivable to detect by means of a vibration sensor the beginning or the end of a spin cycle.
  • a motion sensor can - especially if the metering device is provided in the rotating Treatment room of a household appliance to be positioned as the washing drum of a washing machine - to detect the movement of the dosing in the treatment room.
  • the rotation of the washing drum can be detected in the washing program or spinning.
  • a turbidity sensor can also be provided. From this it is also possible, for example, to select a dosing program in the dosing system which is appropriate for the identified contamination situation. It is also conceivable to detect the course of a treatment program of a washing machine with the aid of at least one sound sensor by detecting specific sound and / or vibration emissions, for example during pumping or pumping out of water.
  • the data line between the sensor and the control unit can be realized via an electrically conductive cable or wirelessly.
  • at least one sensor outside the metering system in the interior of the washing machine such as in the treatment room, in or on the washing drum and / or in or on the Ein effetschublade, positioned or positioned and a data line - especially wireless - for transmission the measurement data from the sensor to the dosing system is formed.
  • a wirelessly formed data line is formed in particular by the transmission of electromagnetic waves or light. It is preferable to form a wireless data line according to standardized standards such as Bluetooth, IrDA, IEEE 802, GSM, UMTS, etc.
  • At least one sensor on the projecting into the treatment space distal end of a fluid line, the dosing with the treatment room is preferred.
  • the Ein istschublade, the washing drum, etc. connects is arranged.
  • the sensor is in particular configured such that it is suitable for detecting the operation of the washing machine and / or the flushing of water into the washing machine.
  • the sensor on the distal end of the fluid line projecting into the treatment space is a conductance and / or a temperature sensor and / or a sound or vibration sensor.
  • a control unit in the sense of this application is a device that is suitable, the
  • the control unit influences at least one actuator with the aid of information, in particular of measuring signals of the sensor unit, which processes it in the sense of the control target.
  • at least one sensor is connected to the control unit, wherein it is particularly preferred that the sensor sends a signal to the control unit representing the presence of water in the washing machine and / or the operation of the washing machine.
  • control unit may be a programmable microprocessor.
  • control unit may be a programmable microprocessor.
  • control unit is on the
  • Microprocessor stored a plurality of dosing programs, which are selectable and executable in a particularly preferred embodiment according to the container coupled to the dosing device.
  • the control unit has in a preferred embodiment no
  • control unit is coupled to the existing control of the household appliance.
  • this coupling is wireless.
  • a transmitter on or in a washing machine, preferably on or on the dosing chamber, which wirelessly transmits a signal to the dosing unit when the controller of the washing machine effects the dosing of, for example, a detergent or softener from the corresponding dosing chamber.
  • the energy source a component of the dosing, which is expedient to provide a suitable for the operation of the dosing or the dosing energy.
  • the energy source is designed such that the dosing system is self-sufficient.
  • the energy source provides electrical energy.
  • the energy source may be, for example, a battery, an accumulator, a power supply, solar cells or the like. It is particularly advantageous to make the energy source replaceable, for example in the form of a replaceable battery.
  • a battery may be selected from the group consisting of alkaline manganese batteries, zinc carbon batteries, nickel oxyhydroxide batteries, lithium batteries, lithium iron sulfide batteries, zinc air batteries, zinc chloride batteries, Mercury oxide zinc batteries and / or silver oxide zinc batteries.
  • Lead accumulators (lead dioxide / lead), nickel-cadmium batteries, nickel-metal hydride batteries, lithium-ion batteries, lithium-polymer batteries, alkaline manganese batteries, silver-zinc batteries, nickel Hydrogen batteries, zinc bromine batteries, sodium nickel chloride batteries and / or nickel-iron batteries.
  • the accumulator can in particular be designed in such a way that it can be recharged by induction.
  • the energy source is preferably dimensioned such that the dosing device can run through about 1000 dosing cycles before the energy source is exhausted. It is special preferred that the energy source between 1 and 1000 dosing cycles, most preferably between 10 and 500, more preferably between 100 and 300 can pass through before the energy source is exhausted.
  • the preparations stored in the cartridge or the cartridge chambers are free-flowing and preferably have a viscosity between 10 mPas and 10000 mPas, in particular 100 mPas to 2000 mPas at a shear rate of 30 s " and a temperature of 25 ° C.
  • the viscosity of the preparations can can be measured by conventional standard methods (for example Brookfield RVD-VII viscometer at 20 rpm and 20 ° C., spindle 3).
  • a peroxocarboxylic acid is contained in the cartridge or the second chamber of a multi-chamber cartridge.
  • Suitable peroxycarboxylic acids are, in particular, mono- and diperoxocarboxylic acids, such as performic acid, peracetic acid, decanediperoxoic acid,
  • Dodecanediperoxoic acid mono- and di-perphthalic acid, mono- and di-perterephthalic acid, imidoperoxycarboxylic acids such as 6-phthalimidoperoxocaproic acid (PAP), and mixtures thereof. It is also possible to use aqueous mixtures of the corresponding acid anhydride and / or the corresponding acid with hydrogen peroxide, in which form the peroxycarboxylic acids.
  • the peroxycarboxylic acid is solid at room temperature and atmospheric pressure; In this case, the peroxycarboxylic acid is used as a preferably aqueous suspension or dispersion.
  • Multi-compartment cartridge containing an enzyme-containing liquid formulation which preferably contains no bleach, in particular no peroxocarboxylic acid, but otherwise may contain all customary in liquid detergents ingredients that do not interact in an unreasonably negative manner with the enzyme, such as surfactants, builders, complexing agents, enzyme stabilizers, foam regulators, Soil release agents, optical brighteners, dyes, and fragrances.
  • ingredients may also be present in the preparation containing the peroxycarboxylic acid, but this is preferably free of optical brighteners and / or fragrances.
  • Suitable enzymes are, in particular, those from the classes of the hydrolases, such as the proteases, esterases, lipases or lipolytic enzymes, amylases, cellulases or other glycosyl hydrolases and mixtures of said enzymes. All of these hydrolases in the wash contribute to the removal of stains such as proteinaceous, greasy or starchy stains and graying. Cellulases and other glycosyl hydrolases can be further improved by removing pilling and microfibrils for color retention and to increase the softness of the skin Textile contribute. Oxireductases may also be used to inhibit color transfer.
  • subtilisin-type proteases and in particular proteases derived from Bacillus lentus are used.
  • Enzyme mixtures for example from protease and amylase or protease and lipase or lipolytic enzymes or protease and cellulase or from cellulase and Lipase.
  • lipolytic enzymes or from protease, amylase and lipase or lipolytic enzymes or protease, lipase or lipolytic enzymes and cellulase, but in particular protease and / or lipase-containing mixtures or mixtures with lipolytic enzymes of particular interest.
  • lipolytic enzymes are the known cutinases.
  • Peroxidases or oxidases have also proved suitable in some cases.
  • Suitable amylases include in particular ⁇ -amylases, iso-amylases, pullulanases and pectinases.
  • cellulases are preferably cellobiohydrolases, endoglucanases and ß-glucosidases, which are also called cellobiases, or mixtures thereof used. Since different cellulase types differ by their CMCase and avicelase activities, the desired activities can be set by targeted mixtures of the cellulases.
  • an agent according to the invention or used in the process according to the invention contains nonionic surfactant selected from fatty alkyl polyglycosides, fatty alkyl polyalkoxylates, in particular ethoxylates and / or propoxylates, fatty acid polyhydroxyamides and / or ethoxylation and / or propoxylation products of fatty alkylamines, vicinal diols , Fatty acid alkyl esters and / or fatty acid amides and mixtures thereof, in particular in an amount in the range of 0.5 wt .-% to 25 wt .-%, in particular 2 wt .-% to 20 wt .-%.
  • Suitable nonionic surfactants include the alkoxylates, in particular the ethoxylates and / or propoxylates of saturated or mono- to polyunsaturated linear or branched-chain alcohols having 10 to 22 C atoms, preferably 12 to 18 C atoms.
  • the degree of alkoxylation of the alcohols is generally between 1 and 20, preferably between 3 and 10. They can be prepared in a known manner by reacting the corresponding alcohols with the corresponding alkylene oxides.
  • Particularly suitable are the derivatives of fatty alcohols, although their branched-chain isomers, in particular so-called oxo alcohols, can be used for the preparation of usable alkoxylates.
  • alkoxylates in particular the ethoxylates, primary alcohols with linear, in particular dodecyl, tetradecyl, hexadecyl or octadecyl radicals and mixtures thereof.
  • corresponding alkoxylation products of alkylamines are vicinal Diols and carboxylic acid amides, which correspond to the said alcohols with respect to the alkyl part, usable.
  • the ethylene oxide and / or propylene oxide inser- tion products of fatty acid alkyl esters and Fettklarepolyhydroxyamide into consideration. to
  • alkyl polyglycosides are compounds of general formula (G) n -OR 12 in which R 2 is an alkyl or alkenyl radical having 8 to 22 carbon atoms, G is a glycose unit and n is a number between 1 and 10 ,
  • the glycoside component (G) n are oligomers or polymers of naturally occurring aldose or ketose monomers, in particular glucose, mannose, fructose, galactose, talose, gulose, altrose, allose, idose, ribose, Include arabinose, xylose and lyxose.
  • the oligomers consisting of such glycosidically linked monomers are characterized not only by the nature of the sugars contained in them by their number, the so-called Oligomermaschinesgrad.
  • the degree of oligomerization n assumes as the value to be determined analytically generally broken numerical values; it is between 1 and 10, with the glycosides preferably used below a value of 1, 5, in particular between 1, 2 and 1, 4.
  • Preferred monomer building block is glucose because of its good availability.
  • the alkyl or alkenyl moiety R 2 of the glycosides preferably also originates from readily available derivatives of renewable raw materials, in particular from fatty alcohols, although their branched-chain isomers, in particular so-called oxoalcohols, can be used to prepare useful glycosides.
  • the primary alcohols having linear octyl, decyl, dodecyl, tetradecyl, hexadecyl or octadecyl radicals and mixtures thereof are particularly suitable.
  • Another embodiment of such agents comprises the presence of synthetic anionic surfactant of the sulfate and / or sulfonate type, in particular fatty alkyl sulfate, fatty alkyl ether sulfate,
  • the anionic surfactant is preferably selected from the alkyl or alkenyl sulfates and / or the alkyl or alkenyl ether sulfates in which the alkyl or alkenyl group has 8 to 22, in particular 12 to 18, carbon atoms. These are usually not individual substances, but cuts or mixtures. Of these, those are preferred whose proportion of compounds with
  • Suitable synthetic anionic surfactants which are particularly suitable for use in such compositions are the alkyl and / or alkenyl sulfates having 8 to 22 C atoms which carry an alkali, ammonium or alkyl or hydroxyalkyl-substituted ammonium ion as counter cation. Preference is given to the derivatives of the fatty alcohols having in particular 12 to 18 carbon atoms and their branched-chain analogs, the so-called oxo alcohols.
  • the alkyl and alkenyl sulfates can be in known
  • the reaction mixture can be prepared by reacting the corresponding alcohol component with a customary sulfating reagent, in particular sulfur trioxide or chlorosulfonic acid, and then neutralizing with alkali, ammonium or alkyl or hydroxyalkyl-substituted ammonium bases.
  • Sulfur-type surfactants which can be used also include the sulfated alkoxylation products of the alcohols mentioned, known as ether sulfates.
  • Such ether sulfates preferably contain from 2 to 30, in particular from 4 to 10, ethylene glycol groups per molecule.
  • Suitable anionic surfactants of the sulfonate type include the ⁇ -sulfoesters obtainable by reaction of fatty acid esters with sulfur trioxide and subsequent neutralization, in particular those of fatty acids having 8 to 22 C atoms, preferably 12 to 18 C atoms, and linear alcohols having 1 to 6 C-atoms, preferably 1 to 4 C-atoms, derivative sulfonation products, as well as those resulting from formal saponification thereof
  • soaps suitable being saturated fatty acid soaps, such as the salts of lauric acid, myristic acid, palmitic acid or stearic acid, and soaps derived from natural fatty acid mixtures, for example coconut, palm kernel or tallow fatty acids.
  • Soap mixtures are preferred which are composed of 50 wt .-% to 100 wt .-% of saturated C 2 -C 8 fatty acid soaps and 50 wt .-% to oleic acid soap.
  • soap is contained in amounts of 0.1 to 10% by weight, in particular 0.5 to 5% by weight.
  • one of the formulations contains complexing agents, e.g. Nitrilotriacetic acid, ethylenediaminetetraacetic acid or phosphonate etc., preferably in amounts of up to 30% by weight or up to 20% by weight, in particular 0 to 10% by weight, advantageously from 0.1 to 5% by weight , Based on the total agent, so is a further preferred embodiment of the invention.
  • complexing agents can be used to preferably bind heavy metal ions and thus inactivate, which can act in particular as catalysts of oxidation processes and thus can lead to a degradation of oxidants such as peroxycarboxylic acids and, for example, via water pipes or metallic components of the production or raw or Ingredients can be registered in the agent according to the invention.
  • the preparation contained in the first chamber and / or preferably in the third chamber of the multi-chamber cartridge contains at least one fragrance or fragrance, the embodiment of the presence of this component in the third chamber also comprising preparations which have a fragrance composition of at least 50% by weight. %, at least 60 wt .-%, at least 70 wt .-%, at least 80 wt .-%, at least 90 wt .-% or at least 91% by weight, preferably at least 92% by weight, advantageously at least 94% by weight, more preferably at least 96% by weight, more preferably at least 98% by weight, most preferably at least 99% Wt .-%, in particular even contain 100 wt .-% of fragrances.
  • the peroxocarboxylic acid-containing preparation is free of fragrance or odoriferous substances.
  • the fragrances or fragrances are preferably selected from the group of citronitrile, ortho-tert-butylcyclohexyl acetate, cyclohexyl salicylate, (+) - (1 'R, 3S, 6'S) -1 - (2', 2 ', 6'-trimethyl -1'-cyclohexyl) -3-hexanol, (-) - (1 'S, 3R, 6'R) -1- (2', 2 ', 6'-trimethyl-r-cyclohexyl) -3- hexanol, (+) - (1'R, 3R, 6'S) -1- (2 ', 2', 6'-trimethyl-1'-cyclohexyl) -3-hexanol, (-) - (1 'S, 3S , 6'R) -1- (2 ', 2', 6'-trimethyl-r-cyclohexyl) -3-hexanol,
  • allyl (cyclohexyloxy) acetate 2,4-dimethyl-1,3-dioxolane-2-acetic acid ethyl ester, 3,12-tridecadienitrile, amyl acetate, isoamyl acetate, ethyl phenylacetate, 2-propenyl phenoxyacetate, isobornyl acetate, Dimethylbenzylcarbinylacetate, hexylacetate, cresylacetate (para), isobutylphenylacetate, butylcyclohexylacetate-cis-para-tert., Butylcyclohexylacetate-trans-para-tert., Hydrocinnamalcohol, 2,6-dimethylheptan-2-ol, decanol, octanol, 2 , 6-dimethylbicyclo- [4.4.0] decan-1-ol (0.1% in di-propylene glycol),
  • At least one preparation contains certain
  • fragrance namely at least 0.01% by weight or 0.05% by weight
  • At least one contains However, larger amounts of fragrances, namely at least 1 wt .-%, advantageously at least 2 wt .-%, in a considerably advantageous manner at least 5 wt .-%, more preferably at least 10 wt .-%, in a further advantageous manner at least 13 Wt .-%, more preferably at least 14 wt .-%, in a very advantageous manner at least 15 wt .-%, in a particularly advantageous manner at least 16 wt .-%, most preferably at least 17 wt .-% , in a significantly advantageous manner at least 18 wt .-%, in a very advantageous manner at least 19 wt .-%, in particular at least 20 wt .-% of fragrances, based on the total preparation.
  • fragrance within the meaning of the invention is in accordance with the usual definition, i. they are usually substances that are perceptible by their smell, especially pleasant smell. These preferably also include the flavorings.
  • Essential oils, flower oils, extracts from plant and animal drugs, from natural products, isolated components (isolates) as well as semi-synthetic and fully synthetic uniform fragrances are used today as fragrances.
  • Optical brighteners can be added to detergents to
  • Suitable compounds originate from the substance classes of the 4,4 '2,2 -Diamino- stilbenedisulfonic acids (flavonic), 4,4'-biphenylene -Distyryl, Methylumbelliferone, coumarins, dihydroquinolinones, 1, 3-diaryl pyrazolines, naphthalimides, benzoxazole , Benzisoxazole and benzimidazole systems as well as heterocyclic substituted pyrene derivatives.
  • optical brighteners are included in the third preparation described above;
  • the peroxocarboxylic acid-containing preparation is free of them.
  • Grayness inhibitors in textile cleaners have the task to keep suspended from the fiber debris suspended in the fleet and so the reassembly of the
  • Water-soluble colloids of mostly organic nature are suitable for this purpose, for example the water-soluble salts of polymeric carboxylic acids, glue, gelatin, salts of ether sulfonic acids or cellulose or salts of acidic sulfuric acid esters of cellulose or starch.
  • water-soluble polyamides containing acidic groups are suitable for this purpose.
  • soluble starch preparations and other than the above starch products can be used, eg degraded starch, aldehyde starches, etc.
  • Polyvinylpyrrolidone is useful.
  • Cellulosic ethers such as carboxymethylcellulose (Na salt), methylcellulose, can also be used as graying inhibitors in the particulate agents.
  • Hydroxyalkylcellulose and mixed ethers such as methylhydroxyethylcellulose,
  • Methylhydroxypropylcellulose methylcarboxymethylcellulose and mixtures thereof.
  • Suitable foam regulators are, for example, soaps, paraffins or silicone oils, which may optionally be applied to support materials.
  • Suitable anti-redeposition agents which are also referred to as soil repellents, are, for example, nonionic cellulose ethers such as methylcellulose and methylhydroxypropylcellulose with a proportion of methoxy groups of 15 to 30% by weight and of hydroxypropyl groups of 1 to 15% by weight, based in each case on the nonionic cellulose ether as well as the known from the prior art polymers of phthalic acid and / or terephthalic acid or derivatives thereof, in particular polymers of ethylene terephthalates and / or polyethylene glycol terephthalates or anionic and / or nonionic modified derivatives thereof.
  • Especially preferred of these are the sulfonated derivatives of the phthalic and terephthalic acid polymers.
  • a preparation preferably the above-mentioned third preparation and not the peroxycarboxylic acid-containing preparation, may contain a conditioning agent.
  • conditioning is preferably to be understood as meaning the avivating treatment of textiles, fabrics and fabrics. Conditioning gives the textiles positive properties, such as improved softness, increased gloss and color brilliance, improved scent impression, reduction in felt formation,
  • the preparations according to the invention may comprise plasticizer components, so-called softening agents.
  • softening agents are quaternary ammonium compounds, cationic polymers and
  • Emulsifiers such as those used in hair care products and also in textile auxiliaries.
  • Suitable examples are quaternary ammonium compounds of the formulas (III) and (IV),
  • R and R is an acyclic alkyl radical having 12 to 24 carbon atoms
  • R 2 is a saturated C 1 -C 4 alkyl or hydroxyalkyl radical
  • R 3 is either R, R or R 2 or is an aromatic radical.
  • X ⁇ represents either a halide, methosulfate, methophosphate or phosphate ion and mixtures of these.
  • Examples of cationic compounds of the formula (III) are didecyldimethylammonium chloride, ditallowdimethylammonium chloride or dihexadecylammonium chloride.
  • Compounds of formula (IV) are so-called ester quats. Esterquats are characterized by excellent biodegradability.
  • R 4 is an aliphatic alkyl radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds;
  • R 5 is H, OH or O (CO) R 7 ,
  • R 6 is, independently of R 5, H, OH or O (CO) R 8 , where R 7 and R 8 are each independently an aliphatic alk (ene) ylrest with 12 to 22
  • Carbon atoms having 0, 1, 2 or 3 double bonds, m, n and p may each independently of one another have the value 1, 2 or 3.
  • X ⁇ may be either a halide, methosulfate, methophosphate or phosphate ion as well as mixtures of these.
  • Particularly preferred are compounds in which R 6 is also OH.
  • Examples of compounds of the formula (IV) are methyl N- (2-hydroxyethyl) -N, N-di (tallow acyl-oxyethyl) ammonium methosulfate, bis (palmitoyl) -ethyl-hydroxyethyl-methyl-ammonium metho - Sulfate or methyl-N, N-bis (acyl-oxyethyl) -N- (2-hydroxyethyl) ammonium methosulfate.
  • acyl groups whose corresponding fatty acids have an iodine number between 5 and 80, preferably between 10 and 60 and in particular between 15 and 45 and which have a cis / trans isomer ratio (in wt .-%) of greater than 30: 70, preferably greater than 50: 50 and in particular greater than 70: 30 have.
  • Stepan methosulfates marketed by Stepan under the tradename Stepantex ® Methylhydroxyalkyldi-alkoyloxyalkylammonium- or those known under Dehyquart ® Cognis products known under or Rewoquat ® manufactured by Goldschmidt-Witco.
  • Stepantex Methylhydroxyalkyldi-alkoyloxyalkylammonium- or those known under Dehyquart ® Cognis products known under or Rewoquat ® manufactured by Goldschmidt-Witco.
  • Other preferred compounds are
  • R and R independently of one another each represent an aliphatic radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds.
  • R and R independently of one another each represent an aliphatic radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds.
  • R 9 is H or a saturated alkyl radical having 1 to 4 carbon atoms
  • R 0 and R independently of one another may each be an aliphatic, saturated or unsaturated alkyl radical having 12 to 18 carbon atoms
  • R 0 may alternatively also be 0 (CO) R 20
  • R 20 is an aliphatic, saturated or unsaturated alkyl radical having 12 to 18 carbon atoms
  • Z is an NH group or oxygen
  • X ⁇ is an anion.
  • q can take integer values between 1 and 4.
  • R, R and R independently represent a C 1-4 alkyl, alkenyl or hydroxyalkyl group
  • R 5 and R 6 each independently represent a C 1-4 alkyl group
  • r is a number between 0 and 5.
  • short-chain, water-soluble, quaternary ammonium compounds are used, such as trihydroxyethylmethylammonium methosulfate or the alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, for example cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, distearyldimethylammonium chloride, lauryldimethylammonium chloride, lauryldimethylbenzylammonium chloride and tricetylmethylammonium chloride.
  • trihydroxyethylmethylammonium methosulfate or the alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, for example cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, distearyldimethylammonium chloride, lauryldimethylammonium chloride, la
  • Suitable cationic polymers include the polyquaternium polymers as described in the CTFA Cosmetic Ingredient Dictionary (The Cosmetic, Toiletry and Fragrance, Inc., 1997), in particular the polyquaternium-6, polyquaternium-7, polyquaternium-10 polymers (Ucare polymer IR 400, Amerchol), also referred to as merquats, polyquaternium-4 copolymers, such as grafting agents.
  • copolymers having a cellulose backbone and quaternary ammonium groups bonded via allyldimethylammonium chloride, cationic cellulose derivatives such as cationic guar such as guar hydroxypropyl triammonium chloride, and similar quaternized guar derivatives (eg Cosmedia Guar, manufacturer: Cognis GmbH), cationic quaternary sugar derivatives (cationic alkyl polyglucosides) , z.
  • cationic cellulose derivatives such as cationic guar such as guar hydroxypropyl triammonium chloride
  • similar quaternized guar derivatives eg Cosmedia Guar, manufacturer: Cognis GmbH
  • cationic quaternary sugar derivatives cationic alkyl polyglucosides
  • Glucquat ® 100 for example, the commercial product Glucquat ® 100, according to CTFA nomenclature a "Lauryl Methyl Gluceth-10 hydroxypropyl Dimonium Chloride", copolymers of PVP and dimethylaminomethacrylate, copolymers of vinylimidazole and
  • Vinyl pyrrolidone, aminosilicone polymers and copolymers Polyquaternized polymers (for example Luviquat Care from BASF) and also cationic biopolymers based on chitin and derivatives thereof, for example, under the trade designation chitosan ® (manufacturer: Cognis) polymer obtainable.
  • cationic silicone oils such as the commercially available Q2-7224 (manufactured by Dow Corning, a stabilized trimethylsilylamodimeth-icon), Dow Corning 929 emulsion (containing a hydroxylamino-modified silicone, also referred to as amodimethicones).
  • SM-2059 (manufacturer: General Electric), SLM-55067 (manufacturer: Wacker) Abil ® -Quat 3270 and 3272 (manufacturer: Goldschmidt Rewo; diquaternary polydimethylsiloxanes, quaternium-80), and Silicone quat Rewoquat ® SQ 1 (Tegopren ® 6922, manufacturer: Goldschmidt-Rewo).
  • the alkylamidoamines may be in their quaternized or, as shown, their quaternized form.
  • R 7 can be an aliphatic alk (en) yl radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds, s can assume values between 0 and 5.
  • R 8 and R 9 are each independently H, d ⁇ alkyl or hydroxyalkyl.
  • Preferred compounds are fatty acid amidoamines, such as the Stearylamido- obtainable under the name Tego Amid ® S 18 propyldimethylamine or obtainable under the name Stepantex ® X 9124 3-propyl-Talgamido- trimethylammo-nium methosulfate, which by a good conditioning effect by dye transfer-inhibiting Effect as well as specially characterized by their good biodegradability.
  • Particular preference is given to alkylated quaternary ammonium compounds, of which at least one alkyl chain is protected by an ester group and / or amido group. in particular N-methyl-N (2-hydroxyethyl) -N, N- (ditalgacyloxyethyl) ammonium methosulfate.
  • Suitable nonionic plasticizers are, in particular, polyoxyalkylene glycol alkanoates, polybutylenes, long-chain fatty acids, ethoxylated fatty acid ethanolamides, alkyl polyglycosides, in particular sorbitan mono-, di- and triester and fatty acid esters of polycarboxylic acids.
  • conditioning agents in amounts of 0, 1 to
  • 80 wt .-% usually 0.1 to 70 wt .-%, preferably 0.2 to 60 wt .-% and in particular
  • the preparations according to the invention are in liquid form. To achieve a liquid consistency, the use of both liquid organic solvents and water may be indicated.
  • the agents according to the invention therefore contain water, for example in amounts of up to 90% by weight, based on the preparation, and optionally nonaqueous solvent.
  • Solvents which can be used in the preparations according to the invention are derived, for example, from the group of monohydric or polyhydric alcohols, alkanolamines or glycol ethers, provided they are miscible with water in the concentration range indicated.
  • the solvents are selected from ethanol, n- or i-propanol, butanols, glycol, propane or butanediol, glycerol, diglycol, propyl or butyldiglycol, hexylene glycol,
  • glycol ethers are among the following glycol ethers:
  • Arcosolv ® Arco Chemical Co.
  • Cellosolve ® Cellosolve ®
  • Carbitol ® Propasol ® (Union Carbide Corp.); this includes for example ButylCarbitol® ®, hexyl carbitol ®, MethylCarbitol® ®, and carbitol ® itself, (2- (2-ethoxy) ethoxy) ethanol.
  • glycol ether can be readily made by one skilled in the art on the basis of its volatility, water solubility, weight percent of total dispersion, and the like.
  • Pyrrolidone solvent such as N-alkyl pyrrolidones, for example N-methyl-2-pyrrolidone or NC 8 -C 2 alkyl-pyrrolidone or 2-pyrrolidone, may also be employed.
  • N-alkyl pyrrolidones for example N-methyl-2-pyrrolidone or NC 8 -C 2 alkyl-pyrrolidone or 2-pyrrolidone
  • solvent mixture may also be employed.
  • glycerol derivatives are further preferred as sole solvent or as a constituent of a solvent mixture.
  • Glycerol carbonate is preferably used in the present invention as
  • Cosolvents include low molecular weight liquid polyethylene glycols, for example, polyethylene glycols having a molecular weight of 200, 300, 400 or 600. Further suitable cosolvents are other alcohols, for example (a) lower alcohols such as ethanol, propanol, isopropanol and n-butanol, (b) ketones such as acetone and
  • Methyl ethyl ketone (c) C 2 -C 4 polyols such as a diol or a triol, for example ethylene glycol, propylene glycol, glycerol or mixtures thereof. Particularly preferred is from the class of diols 1, 2-octanediol.
  • the compositions contain agents of the invention, one or more solvents from the group consisting of d- to C 4 --hole Monoalko, C 2 - to C 6 glycols, C 3 - to C 2 glycol ethers and glycerol, in particular ethanol ,
  • the C 3 - to C 12 glycol ethers according to the invention contain alkyl or alkenyl groups having less than 10 carbon atoms, preferably up to 8, in particular up to 6, more preferably 1 to 4 and most preferably 2 to 3 carbon atoms.
  • Preferred C 1 to C 4 monoalcohols are ethanol, n-propanol, isopropanol and tert-butanol.
  • Preferred C 2 to C 6 glycols are
  • Ethylene glycol 1,2-propylene glycol, 1,3-propylene glycol, 1,5-pentanediol, neopentyl glycol and 1,6-hexanediol, in particular ethylene glycol and 1,2-propylene glycol.
  • Preferred C 3 - to C 2 glycol ethers are di-, tri-, tetra- and pentaethylene glycol, di-, tri- and tetrapropylene glycol, propylene glycol and propylene glycol monoethyl ether and the solvent monotertiärbutylether designated under INCI Butoxydiglycol, butoxyethanol, butoxyisopropanol, butoxypropanol, butyl octanol, Ethoxydiglycol, ethoxyethanol, ethyl hexanediol, isobutoxypropanol, isopentyldiol, 3-methoxybutanol, methoxyethanol, methoxyisopropanol and methoxymethylbutanol.
  • a preparation according to the invention one or more solvents in an amount of preferably up to 40 wt .-%, more preferably 0.1 to 30 wt .-%, in particular 2 to 20 wt .-%, particularly preferably 3 to 15 wt. -%, most preferably 5 to 12 wt .-%, for example, 5.3 or 10.6 wt .-%, each based on the total agent included.
  • the preparations according to the invention may optionally contain ironing assistants for improving the water absorption capacity, the rewettability of the treated textiles and for ease of ironing the treated textiles.
  • ironing assistants for improving the water absorption capacity, the rewettability of the treated textiles and for ease of ironing the treated textiles.
  • silicone derivatives can be used in the formulations. These additionally improve the rinsing behavior of the detergent-active formulations by their foam-inhibiting
  • Preferred silicone derivatives are, for example, polydialkyl or alkylaryl siloxanes in which the alkyl groups have one to five carbon atoms and are completely or partially fluorinated.
  • Preferred silicones are polydimethylsiloxanes, which may optionally be derivatized and are then amino-functional or quaternized or have Si-OH, Si-H and / or Si-Cl bonds.
  • the viscosities of the preferred silicones are in the range between 100 and 100,000 mPas at 25 ° C., it being possible to use the silicones in amounts of between 0.2 and 5% by weight, based on the preparation. Examples
  • Example 1 was repeated several times at 20 ° C and at 60 ° C to check the damage to machine and laundry.
  • Fig. 3 metering system for a washing machine with a plurality of dosing
  • Fig. 4 adapter for coupling the dosing with a Ein Actuallyschublade a
  • Fig. 5 metering system for a washing machine with a fluid line through the
  • Washing machine door is guided into the treatment room
  • Fig. 6 washing machine with an interface for the metering system according to the invention 1 shows a first possible embodiment of the metering system 1 according to the invention.
  • the metering system 1 consists of a metering device 5 which is detachably coupled to a cartridge which comprises three chambers 3a, 3b, 3c.
  • the cartridge chambers 3a, 3b, 3c can be removed individually from the dosing device 5 in the embodiment shown.
  • a control unit for controlling the dosing device 5, an energy source, preferably as a battery, accumulator or power plug and a pump that promotes the preparations from the cartridge chambers 3a, 3b, 3c.
  • an energy source preferably as a battery, accumulator or power plug and a pump that promotes the preparations from the cartridge chambers 3a, 3b, 3c.
  • a fluid line 7 is arranged, through which the pumped by the pump preparation to Ein effetschublade 8 of the washing machine 2 are passed.
  • the free, distal end of the fluid line 7 is positioned in the dispenser drawer 8. It is also possible to couple the fluid line 7 by means of an adapter provided with the Ein effetschublade 8. This will be discussed in more detail elsewhere.
  • About the Ein Hughesschublade 8 then passes a dosed by the dosing device 5 preparation in the treatment room 6 of the washing machine. 2
  • a conductivity sensor At the free, distal end of the fluid line 7 is a conductivity sensor, through which the presence or the flushing of water is detected in the Ein Togetherschublade 8 of the washing machine 2.
  • the dosage of at least one of the preparation from the dosing device 5 is determined according to a dosing program stored in the control unit
  • Cartridge chambers 3a, 3b, 3c made.
  • the fluid line 7 may in particular be formed of a flexible hose, preferably of plastic.
  • the fluid conduit 7 can be positioned in the Ein effetschublade 8 in a manner that is simple for a user.
  • the fluid conduit 7 may be configured to be pinch-proof, i. the conduit cross-section is substantially maintained, even if the fluid conduit 7 is e.g. is squeezed through the Ein effetschublade 8 of an object standing on the line. It is also conceivable to form the fluid line 7 as a rigid channel.
  • Fig. 2 shows the known from Fig. 1 dosing system 1, wherein for each of the
  • Cartridge chambers 3a, 3b, 3c preparation to be released a separate fluid line 7a, 7b, 7c is provided.
  • the free distal ends of the fluid lines 7a, 7b, 7c can be positioned in a dispensing chamber of the dispensing drawer 8 or in different dispensing chambers of the dispensing drawer 8.
  • each of the dosing devices 5a, 5b, 5c has in each case a fluid line 7a, 7b, 7c whose free, distal end open into in each case different dispensing chambers 8a, 8b, 8c of the dispensing drawer 8.
  • interfaces 10a, 10b, 10c are provided on the washing machine 2, which allow a coupling with the dosing device 5 in such a way that a fluid connection via the interfaces 10, 10b, 10c between a preferably rigid fluid line 7a, 7b, 7c of the metering device 5 and the treatment chamber 6 of the washing machine can be produced.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Washing And Drying Of Tableware (AREA)
  • Detail Structures Of Washing Machines And Dryers (AREA)

Abstract

La performance de lessives liquides devait être améliorée. Cet objectif est atteint grâce à un système de dosage conçu pour libérer des préparations à l'intérieur d'un lave-linge, lequel système comprend au moins un appareil doseur et au moins une cartouche qui peut être couplée à l'appareil doseur. Ladite cartouche présente au moins une chambre qui renferme une préparation liquide contenant de l'acide peroxocarboxylique.
EP11718007.5A 2010-05-03 2011-04-28 Procédé pour libérer des préparations contenant un agent de blanchiment au cours d'un programme de lavage d'un lave-linge par le biais du système de dosage Active EP2566943B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL11718007T PL2566943T3 (pl) 2010-05-03 2011-04-28 Sposób uwalniania preparatów zawierających środek wybielający podczas programu prania pralki za pomocą układu dozującego

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102010028483A DE102010028483A1 (de) 2010-05-03 2010-05-03 Dosiersystem zur Freisetzung von bleichmittelhaltigen Zubereitungen während eines Waschprogramms einer Waschmaschine
PCT/EP2011/056722 WO2011138218A1 (fr) 2010-05-03 2011-04-28 Système de dosage conçu pour libérer des préparations contenant un agent de blanchiment au cours d'un programme de lavage d'un lave-linge

Publications (2)

Publication Number Publication Date
EP2566943A1 true EP2566943A1 (fr) 2013-03-13
EP2566943B1 EP2566943B1 (fr) 2017-09-06

Family

ID=44118936

Family Applications (1)

Application Number Title Priority Date Filing Date
EP11718007.5A Active EP2566943B1 (fr) 2010-05-03 2011-04-28 Procédé pour libérer des préparations contenant un agent de blanchiment au cours d'un programme de lavage d'un lave-linge par le biais du système de dosage

Country Status (5)

Country Link
EP (1) EP2566943B1 (fr)
DE (1) DE102010028483A1 (fr)
ES (1) ES2643129T3 (fr)
PL (1) PL2566943T3 (fr)
WO (1) WO2011138218A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10358622B2 (en) 2012-09-13 2019-07-23 Ecolab Usa Inc. Two step method of cleaning, sanitizing, and rinsing a surface
US10433547B2 (en) 2014-12-18 2019-10-08 Ecolab Usa Inc. Generation of peroxyformic acid through polyhydric alcohol formate
IT201900022392A1 (it) 2019-11-28 2021-05-28 Salros S R L Composizione di lavaggio liquida a componenti separati, per bucato in macchine lavatrici automatiche
US11180385B2 (en) 2012-10-05 2021-11-23 Ecolab USA, Inc. Stable percarboxylic acid compositions and uses thereof

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102011119021B3 (de) * 2011-11-22 2013-05-16 Beatrice Saier Vorrichtung und Verfahren zum schaltbaren Verbinden
US10165774B2 (en) 2013-03-05 2019-01-01 Ecolab Usa Inc. Defoamer useful in a peracid composition with anionic surfactants
US20140256811A1 (en) 2013-03-05 2014-09-11 Ecolab Usa Inc. Efficient stabilizer in controlling self accelerated decomposition temperature of peroxycarboxylic acid compositions with mineral acids
US8822719B1 (en) 2013-03-05 2014-09-02 Ecolab Usa Inc. Peroxycarboxylic acid compositions suitable for inline optical or conductivity monitoring
AT514640B1 (de) * 2013-07-22 2015-05-15 Hagleitner Hans Georg Messvorrichtung zur Erfassung wenigstens eines Parameters einer Flüssigkeit
DE102013113636A1 (de) * 2013-12-06 2015-06-11 Winterhalter Gastronom Gmbh Vorrichtung und Verfahren für eine automatisierte Wartung
DE102014109623B4 (de) * 2014-07-09 2023-01-05 Miele & Cie. Kg Verfahren zum Betreiben eines wasserführenden elektrischen Gerät sowie wasserführendes elektrisches Gerät
US11389843B2 (en) 2014-10-27 2022-07-19 Michael Saier Apparatus and method for connecting in a switchable manner
BR112017013210B1 (pt) 2014-12-18 2021-12-14 Ecolab Usa Inc Métodos para formar ácido peroxifórmico
US10172351B2 (en) 2015-09-04 2019-01-08 Ecolab Usa Inc. Performic acid on-site generator and formulator
WO2017044806A1 (fr) 2015-09-10 2017-03-16 Ecolab Usa Inc. Produit chimique antimicrobien auto-indicateur
DE102016106777A1 (de) * 2016-04-13 2017-10-19 Miele & Cie. Kg Waschautomat zum Waschen von Wäsche und Verfahren zum Bleichen von Wäsche in einem Waschautomaten
EP3469132A1 (fr) 2016-06-09 2019-04-17 Unilever PLC Appareil de mélange de liquides de lessive
DE102016122902B3 (de) 2016-11-28 2018-04-26 Miele & Cie. Kg Behältervorrichtung zur Anordnung in einem Dosiersystem eines Haushaltgeräts, Dosiersystem, Verfahren zum Betreiben eines Dosiersystems und Verfahren zum Herstellen einer Behältervorrichtung
EP3551971B1 (fr) * 2016-12-12 2022-04-20 Illinois Tool Works, Inc. Capteur optique de niveau de récipient amovible d'aide au lavage
DE102016225887A1 (de) 2016-12-21 2018-06-21 Henkel Ag & Co. Kgaa Dosierverfahren für ein Ausgabemodul
CN106758015B (zh) * 2017-01-03 2023-04-18 珠海格力电器股份有限公司 洗衣机衣物增香装置、洗衣机及洗衣机控制方法
WO2019019078A1 (fr) * 2017-07-27 2019-01-31 The Procter & Gamble Company Procédé et système de réduction de fluctuation d'auto-dosage d'une machine de nettoyage automatique
DE102017213671B3 (de) 2017-08-07 2018-10-11 BSH Hausgeräte GmbH Wäschepflegegerät mit einer Steuerung sowie Verfahren zur Pflege von Wäsche
TR202004710U5 (tr) 2017-10-05 2021-01-21 Unilever Nv Özelleştirilmiş çamaşır yıkama için usuller ve aygıtlar.
GB2571336A (en) 2018-02-26 2019-08-28 Unilever Plc Methods and system for monitoring and replenishing one or more laundry components
CA3103876C (fr) 2018-06-15 2024-02-27 Ecolab Usa Inc. Compositions d'acide performique generees sur place pour le traitement de trayons
WO2020243382A1 (fr) 2019-05-31 2020-12-03 Ecolab Usa Inc. Procédé de surveillance de concentrations en peracide par mesures de conductivité et composition de peracide
CN114630934A (zh) 2019-11-01 2022-06-14 联合利华知识产权控股有限公司 可回收自动定量配给容器
EP3839124B1 (fr) * 2019-12-19 2023-11-15 Henkel AG & Co. KGaA Procédé et dispositif pour distribuer une composition de parfum pendant un cycle de nettoyage d'un appareil ménager
EP4194536A1 (fr) * 2021-12-08 2023-06-14 The Procter & Gamble Company Cartouche de traitement du linge
EP4194537A1 (fr) * 2021-12-08 2023-06-14 The Procter & Gamble Company Cartouche de traitement du linge
DE102022204754A1 (de) 2022-05-16 2023-11-16 Henkel Ag & Co. Kgaa Textilwaschverfahren
EP4335914A1 (fr) 2022-09-07 2024-03-13 Henkel AG & Co. KGaA Procédé de lavage de textiles
WO2024056332A1 (fr) * 2022-09-13 2024-03-21 Unilever Ip Holdings B.V. Machine à laver et procédé de lavage
WO2024056333A1 (fr) * 2022-09-13 2024-03-21 Unilever Ip Holdings B.V. Machine à laver et procédé de lavage
WO2024056278A1 (fr) * 2022-09-13 2024-03-21 Unilever Ip Holdings B.V. Machine à laver et procédé de lavage
WO2024056334A1 (fr) * 2022-09-13 2024-03-21 Unilever Ip Holdings B.V. Machine à laver et procédé de lavage

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0490436A1 (fr) * 1990-12-10 1992-06-17 Unilever N.V. Utilisation des compositions detergentes non-aqueuses
DE10114256A1 (de) * 2001-03-22 2002-10-02 Henkel Kgaa Dosiersystem für Waschsubstanzen
GB2386129B (en) 2002-03-06 2004-12-01 Reckitt Benckiser Nv Detergent dosing device
DE502006000627D1 (de) * 2005-04-27 2008-05-29 Mifa Ag Frenkendorf Flüssigwaschmittel mit Bleichmittelzusatz
DE102005062479A1 (de) 2005-12-27 2007-07-05 BSH Bosch und Siemens Hausgeräte GmbH Dosiervorrichtung für die Zugabe eines Zuschlagmittels in einen Behandlungsraum und Geschirrspülmaschine mit einer Dosiervorrichtung
DE102006009807A1 (de) * 2006-03-01 2007-09-06 Lothar Ernst Wilhelm Weber Waschmaschine, Reinigungseinrichtung, Verfahren zum Waschen und Spülmaschine
DE102007014425A1 (de) * 2007-03-22 2008-09-25 Henkel Ag & Co. Kgaa Bewegliches Dosiersystem zur Abgabe von fließ- oder streufähigen Zubereitungen
WO2010094430A2 (fr) * 2009-02-18 2010-08-26 Henkel Ag & Co. Kgaa Doseur à chambre de dosage
WO2011051415A1 (fr) * 2009-10-30 2011-05-05 Henkel Ag & Co. Kgaa Procédé de lavage en machine

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2011138218A1 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10358622B2 (en) 2012-09-13 2019-07-23 Ecolab Usa Inc. Two step method of cleaning, sanitizing, and rinsing a surface
US11180385B2 (en) 2012-10-05 2021-11-23 Ecolab USA, Inc. Stable percarboxylic acid compositions and uses thereof
US10433547B2 (en) 2014-12-18 2019-10-08 Ecolab Usa Inc. Generation of peroxyformic acid through polyhydric alcohol formate
IT201900022392A1 (it) 2019-11-28 2021-05-28 Salros S R L Composizione di lavaggio liquida a componenti separati, per bucato in macchine lavatrici automatiche
WO2021105919A1 (fr) * 2019-11-28 2021-06-03 Salros S.R.L. Composition de lavage liquide à composants séparés pour le linge et kit associé, et procédé de lavage pour machines à laver automatiques
CN114761529A (zh) * 2019-11-28 2022-07-15 萨尔罗斯公司 具有分开组分的洗衣用液体洗涤组合物及其套件、以及用于自动洗衣机的洗涤方法
EP4386072A2 (fr) 2019-11-28 2024-06-19 Salros S.R.L. Composition de lavage liquide avec composants séparés pour le linge et kit associé et procédé de lavage pour machines à laver automatiques

Also Published As

Publication number Publication date
ES2643129T3 (es) 2017-11-21
WO2011138218A1 (fr) 2011-11-10
PL2566943T3 (pl) 2018-02-28
EP2566943B1 (fr) 2017-09-06
DE102010028483A1 (de) 2011-11-03

Similar Documents

Publication Publication Date Title
EP2566943B1 (fr) Procédé pour libérer des préparations contenant un agent de blanchiment au cours d'un programme de lavage d'un lave-linge par le biais du système de dosage
EP2521810B1 (fr) Système de dosage pour libérer au moins trois préparations différentes pendant un programme de lavage d'un lave-linge
WO2011131256A1 (fr) Système de dosage pour un appareil ménager à circulation d'eau
DE102010027992A1 (de) Dosiersystem zur Freisetzung von wenigstens drei unterschiedlichen Zubereitungen während eines Waschprogramms einer Waschmaschine
DE102010027991A1 (de) Dosiersystem zur Verwendung in Verbindung mit einem wasserführenden Haushaltsgerät wie eine Waschmaschine, Spülmaschine, Wäschetrockner oder dergleichen
DE102010028354A1 (de) Dosiersystem zur Verwendung in Verbindung mit einem wasserführenden Haushaltsgerät wie eine Waschmaschine, Spülmaschine, Wäschetrockner oder dergleichen
EP2956534B1 (fr) Détergent inhibant le grisonnement
WO2006102978A1 (fr) Produit nettoyant ou detergent transparent a limite d'ecoulement
EP2291504A1 (fr) Additif de détergents se présentant sous forme de particules
DE10153551A1 (de) Im wesentlichen sedimentfrei dispergierbares Wasch- oder Reinigungsmittel
WO2007098862A1 (fr) Agent nettoyant liquide inhibant le grisonnement
CA2974200A1 (fr) Compositions de nettoyage et/ou de traitement
DE102007021793A1 (de) Wasch- oder Reinigungsmittel mit Polysaccharid
DE102008047361A1 (de) Textilspülmittel
DE112018004365T5 (de) Waschprodukte
DE102009027162A1 (de) Maschinelles Geschirrspülmittel
WO2009019136A1 (fr) Produit de lavage ou de nettoyage respectant les couleurs avec agent de blanchiment optique
DE102007047433A1 (de) Flüssigwasch- und Flüssigreinigungsmittel
DE10066036B4 (de) Kompartiment-Hohlkörper
WO2008155160A1 (fr) Lessives ou détergents liquides hautement moussants, présentant une viscosité stable
EP2328457A1 (fr) Produit de nettoyage contenant un agent de blanchiment
DE102007005419A1 (de) Enzym-haltiges Wasch- oder Reinigungsmittel mit verbesserter Stabilität
EP2032681A1 (fr) Portion de détergent ou de produit traitant i
DE10062585A1 (de) Teilchenförmiges Additiv für Wasch- und Reinigungsmittel
WO2017050821A1 (fr) Composition contenant des tensioactifs pour le traitement de textiles avec un colorant

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20121010

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

DAX Request for extension of the european patent (deleted)
17Q First examination report despatched

Effective date: 20160226

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

INTG Intention to grant announced

Effective date: 20170517

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

Ref country code: AT

Ref legal event code: REF

Ref document number: 925931

Country of ref document: AT

Kind code of ref document: T

Effective date: 20170915

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: LANGUAGE OF EP DOCUMENT: GERMAN

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 502011012955

Country of ref document: DE

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2643129

Country of ref document: ES

Kind code of ref document: T3

Effective date: 20171121

REG Reference to a national code

Ref country code: NL

Ref legal event code: MP

Effective date: 20170906

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171206

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170906

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170906

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170906

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170906

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170906

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170906

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171206

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171207

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170906

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 8

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170906

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170906

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170906

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180106

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170906

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170906

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 502011012955

Country of ref document: DE

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170906

26N No opposition filed

Effective date: 20180607

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170906

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170906

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170906

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

REG Reference to a national code

Ref country code: BE

Ref legal event code: MM

Effective date: 20180430

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180428

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180430

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180430

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180430

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180428

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 925931

Country of ref document: AT

Kind code of ref document: T

Effective date: 20180428

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180428

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170906

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20110428

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170906

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170906

Ref country code: MK

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170906

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170906

P01 Opt-out of the competence of the unified patent court (upc) registered

Effective date: 20230530

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20230426

Year of fee payment: 13

Ref country code: FR

Payment date: 20230420

Year of fee payment: 13

Ref country code: ES

Payment date: 20230627

Year of fee payment: 13

Ref country code: DE

Payment date: 20230420

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: PL

Payment date: 20230421

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20230419

Year of fee payment: 13