EP2561919B1 - Système de traitement des gaz d'échappement muni d'un équipement d'absorption chimique du dioxyde de carbone - Google Patents

Système de traitement des gaz d'échappement muni d'un équipement d'absorption chimique du dioxyde de carbone Download PDF

Info

Publication number
EP2561919B1
EP2561919B1 EP11771994.8A EP11771994A EP2561919B1 EP 2561919 B1 EP2561919 B1 EP 2561919B1 EP 11771994 A EP11771994 A EP 11771994A EP 2561919 B1 EP2561919 B1 EP 2561919B1
Authority
EP
European Patent Office
Prior art keywords
absorbing solution
heat
reboiler
regeneration column
exhaust gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP11771994.8A
Other languages
German (de)
English (en)
Other versions
EP2561919A4 (fr
EP2561919A1 (fr
Inventor
Tomoyuki Konishi
Takanori Nakamoto
Naoki Oda
Nobuo Morimoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Power Ltd
Original Assignee
Mitsubishi Hitachi Power Systems Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Hitachi Power Systems Ltd filed Critical Mitsubishi Hitachi Power Systems Ltd
Priority to PL11771994T priority Critical patent/PL2561919T3/pl
Publication of EP2561919A1 publication Critical patent/EP2561919A1/fr
Publication of EP2561919A4 publication Critical patent/EP2561919A4/fr
Application granted granted Critical
Publication of EP2561919B1 publication Critical patent/EP2561919B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/62—Carbon oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1425—Regeneration of liquid absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1475—Removing carbon dioxide
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00—Arrangements of devices for treating smoke or fumes
    • F23J15/006—Layout of treatment plant
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00—Arrangements of devices for treating smoke or fumes
    • F23J15/02—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00—Arrangements of devices for treating smoke or fumes
    • F23J15/06—Arrangements of devices for treating smoke or fumes of coolers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/65—Employing advanced heat integration, e.g. Pinch technology
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00—Preventing emissions
    • F23J2215/10—Nitrogen; Compounds thereof
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00—Preventing emissions
    • F23J2215/30—Halogen; Compounds thereof
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00—Preventing emissions
    • F23J2215/50—Carbon dioxide
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2219/00—Treatment devices
    • F23J2219/40—Sorption with wet devices, e.g. scrubbers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/30—Technologies for a more efficient combustion or heat usage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/32—Direct CO2 mitigation

Definitions

  • the present invention relates to an exhaust gas treatment system with a carbon dioxide chemical absorption equipment, and particularly to an exhaust gas treatment system in which heat recovered from an exhaust gas is effectively used in a carbon dioxide (CO 2 ) chemical absorption equipment.
  • CO 2 carbon dioxide
  • a smoke exhaust treatment device is disposed on a downstream side of the coal-fired boiler or the like. After removing a toxic substance in the exhaust gas, the thus obtained clean gas is released into the atmosphere.
  • US 2009/0151566 discloses a system and method for regeneration of an absorbent solution.
  • the system for regenerating a rich absorbent solution includes: an absorber facilitating interaction between a process stream and an absorbent solution, wherein the process stream comprises an acidic component, and interaction of the process stream with the absorbent solution produces a reduced acidic component stream and a rich absorbent solution; at least one heat exchanger accepting at least one of said reduced acidic component stream and the process stream to transfer heat to a heat transfer fluid; and at least one mechanism to transfer the heat transfer fluid from said at least one heat exchanger to a regenerator regenerating the rich absorbent solution, wherein each of the at least one mechanisms is fluidly coupled to each of the at least one heat exchangers.
  • JP 2010-85078 describes a carbon dioxide recovery type steam power generation system.
  • US 2008/0317651 describes a plant and process for recovering carbon dioxide from gas streams, in particular in which the carbon dioxide component of industrial gas streams also containing steam, such as flue gases produced by power stations, can be processed so to utilize either as latent and/or sensible heat the heat available from the steam component to assist in separating carbon dioxide from the remainder of the gas stream, and nitrogen and sulphur constituents such as SOx and NOx, H 2 S and other nitrogen containing compounds may also be removed from the gas stream through direct contact with the absorbing medium and used to produce by-products such as fertiliser material.
  • US 4,514,379 discloses catalytic processes for converting 2-oxazolidones to their corresponding alkanolamines.
  • JP 2009-247932 discloses a method for removing carbon dioxide of combustion exhaust gas.
  • EP 1 688 173 describes a carbon dioxide recovery and power generation.
  • FIG. 4 is an explanatory drawing showing an example of a conventional smoke exhaust treatment system.
  • a combustion exhaust gas discharged from a boiler 1 is heat-exchanged by an air preheater 3 after removing nitrogen oxide by a denitration device 2, and then cooled to, for example, 120°C to 170°C.
  • Heat of the exhaust gas passed through the air preheater 3 is taken by a heating medium in a heat recovery device 4 and, after cooled to, for example, 75°C to 110°C, smoke dust in the exhaust gas are removed by a precipitator 5.
  • the pressure is further increased by an induced draft fan 6, and then sulfur oxide is removed by a wet-type desulfurization device 7.
  • the temperature of the exhaust gas passed through the wet-type smoke exhaust desulfurization device usually decreases to about 40°C to 60°C, resulting in a moisture saturation state.
  • a heating medium circulation line 12 using a heat transfer tube is provided between the heat recovery device 4 and the reheater 18, and thus a heating medium is circulated between the heat recovery device 4 and the reheater 18 by a heating medium circulation pump 13 via the heat transfer tube.
  • the temperature of the exhaust gas is decreased by the heat recovery device 4 thereby allowing ash in the exhaust gas to adsorb SO 3 and heavy metals, and thus enabling the removal of them together with ash by the precipitator 5. It is also possible to use heat recovered by the heat recovery device 4 for reheating of a moisture saturated gas of an outlet of the wet-type desulfurization device 7, for the purpose of preventing the generation of a white smoke through the funnel 11 (Patent Document 1).
  • a CO 2 recovery equipment For the purpose of reducing emissions of CO 2 , it has recently been planned to provide a smoke exhaust treatment system with a CO 2 recovery equipment, and progress has been made in the research and development.
  • CO 2 recovery equipment of a CO 2 chemical absorption equipment in which CO 2 is recovered using an aqueous solution of an amine compound such as alkanolamine and the like as an absorbing solution (for example, Patent Document 2).
  • Fig. 5 is an explanatory drawing showing an example of a conventional CO 2 chemical absorption equipment by an amine absorbing solution.
  • the exhaust gas having a pressure raised by a blower 8 is introduced into the lower portion of an absorption column 25.
  • the amine absorbing solution containing CO 2 absorbed therein is stored in the bottom portion of the absorption column 25, introduced into an amine heat exchanger 46 by an absorbing solution circulation pump 28a, heated, for example, from 40°C to 100°C, and then introduced into a regeneration column 26 through a regeneration column amine feed piping 47.
  • the CO 2 -rich amine absorbing solution fed through the regeneration column amine feed piping 47 is fed to a regeneration column packed bed 48.
  • vapor is fed to the lower portion of the packed bed 48 from a reboiler 30 through a regeneration column vapor feed piping 33.
  • a regeneration column outlet gas 51 is cooled to 40°C by a regeneration column cooler 52 and condensed water drains are separated by a drum 53, followed by feeding to the regeneration column 26 as washing water 50 of the regeneration column water washing portion by means of a regeneration column wash water pump 54.
  • a CO 2 -lean absorbing solution from which CO 2 has been eliminated, is once stored in a tray 55 of the regeneration column lower portion, and then fed into a reboiler 30 from the lower portion of the reboiler through a reboiler solution feed piping 35.
  • the reboiler 30 is provided with a heat transfer tube (not shown), and the absorbing solution is heated to, for example, 120°C to 140°C by passing of a steam 32 through the heat transfer tube.
  • the heated absorbing solution generates vapor and the vapor is fed to the regeneration column 26 through the regeneration column vapor piping 33.
  • the reboiler 30 is provided with a partition plate 56 and a solution, that has overflown the partition plate 56, is stored in the bottom portion of the regeneration column 26 through a regeneration column solution feed piping 57 and extracted by an amine absorbing solution circulation pump 28b. After decreasing the temperature to, for example, about 40°C by the amine heat exchanger 46, the solution is fed to the absorption column packed bed 40 through the absorption column amine feed piping 41.
  • An object of the present invention is to provide an exhaust gas treatment system that effectively use heat recovered from an exhaust gas without any limitation in a CO 2 chemical absorption equipment that requires enormous heat energy, and thus enabling reduction in running cost of the CO 2 chemical absorption equipment.
  • the present invention provides an exhaust gas treatment system with a CO 2 chemical absorption equipment, in which the system comprises:
  • a heat recovery device that recovers heat of an exhaust gas discharged from a boiler is provided, and the heat is fed to a CO 2 chemical absorption equipment by an amine absorbing solution and used as a heat source for preheating a regenerating amine absorbing solution to be fed to the reboiler from a regeneration column, thereby raising the temperature of the regenerating amine absorbing solution, and thus enabling a decrease in amount of steam to be fed to the reboiler. Since the above heat source is not used for heating an amine absorbing solution extracted from a CO 2 absorption column, such a problem does not arise: the absorbing solution does not drop in a regeneration column and thus it becomes difficult to circulate the solution. Since the reboiler requires energy that is remarkably more than heat energy recovered from the exhaust gas, limitation on feed of recovered heat for preheating does not arise. Thereby, it becomes possible to configure an exhaust gas treatment system with higher heat efficiency as compared with the prior art.
  • a smoke exhaust treatment system comprising a denitration device 2, an air preheater 3, a precipitator 5, an induced draft fan 6, a wet-type desulfurization device 7 and a blower 8 is shown.
  • all these devices and arrangements are not necessarily indispensable, and addition and deletion of the fan and blower may be made on an exhaust gas passage, or some devices may comprise a system to be by-passed.
  • type of the device and the wet-type desulfurization device may be replaced by other type of devices, for example a dry-type desulfurization device and the like.
  • Fig. 1 is an explanatory drawing showing an Example of an exhaust gas treatment system of the present invention.
  • the exhaust gas treatment system of the present invention and conventional systems shown in Figs. 4 and 5 are different in that a solution feed piping 35 of a reboiler 30 is provided with a heating medium heater 36, and a heating medium circulation line (high temperature side) 12a and a heating medium circulation line (low temperature side) 12b, that configure the heat transfer tube through which a heating medium passes, and a heating medium circulation pump 13 are provided between a heat recovery device 4 at an outlet of an air preheater 3 of a boiler 1 and the above-mentioned heating medium heater 36, thereby circulating the heating medium between the heat recovery device 4 and the heating medium heater 36 via the heat transfer tube.
  • a solution feed piping 35 of a reboiler 30 is provided with a heating medium heater 36, and a heating medium circulation line (high temperature side) 12a and a heating medium circulation line (low temperature side) 12b, that configure the heat
  • an exhaust gas from a boiler 1 is introduced into a denitration device 2 and, after removing nitrogen oxide, combustion air to be used in the boiler 1 is heated by the exhaust gas in an air preheater 3.
  • the exhaust gas discharged from the air preheater 3 is introduced into a heat recovery device 4 and heat is recovered by a heating medium circulating in the heat recovery device, and thus the exhaust gas is cooled.
  • Soot dust in the exhaust gas discharged from the heat recovery device 4 are precipitated by a precipitator 5, and the exhaust gas discharged from the precipitator 5 are introduced into a wet-type desulfurization device 7 after raising the pressure by an induced draft fan 6.
  • Sulfur oxide is removed by the wet-type desulfurization device 7 and the exhaust gas is delivered to a CO 2 chemical absorption equipment after raising the pressure by a blower 8. Namely, the exhaust gas having a pressure raised by the blower 8 is introduced into the lower portion of an absorption column 25 of the CO 2 chemical absorption equipment.
  • the exhaust gas is washed with wash water to be fed through a wash water circulation line 45 in an absorption column water washing portion 42 and, furthermore, mist of the absorbing solution accompanied with the gas is removed and the gas is discharged as a CO 2 -removed gas 27 through a funnel 11 by a fan 10.
  • wash water is circulated by an absorption column water washing pump 43.
  • the amine absorbing solution containing CO 2 absorbed therein is stored in the bottom portion of an absorption column 25, introduced into an amine heat exchanger 46 by an absorbing solution circulation pump 28a, heated, for example, from 40°C to 100°C, and then introduced into a regeneration column 26 through a regeneration column amine feed piping 47.
  • a CO 2 -rich amine absorbing solution to be fed through the regeneration column amine feed piping 47 is fed to the regeneration column packed bed 48.
  • vapor is fed to the lower portion of the packed bed 48 from a reboiler 30 through a regeneration column vapor feed piping 33.
  • a regeneration column outlet gas 51 is cooled, for example, to 40°C by a regeneration column cooler 52 and condensed drain water are separated by a drum 53, followed by feeding as wash water of the regeneration column water washing portion 49 by means of a regeneration column wash water pump 54.
  • a CO 2 -lean absorbing solution from which CO 2 has been eliminated, is once stored in a tray 55 of the regeneration column lower portion, and then fed into a reboiler 30 from the lower portion of the reboiler 30 through a reboiler solution feed piping 35.
  • the reboiler 30 is provided with a heat transfer tube (not shown), and the absorbing solution is heated to, for example, 120°C to 140°C by passing of a steam 32 through the heat transfer tube. The heated absorbing solution generates vapor and the vapor is fed to the regeneration column through the regeneration column vapor piping 33.
  • the reboiler 30 is provided with a partition plate 56 and a solution that has overflown the partition plate is stored in the bottom portion of the regeneration column 26 through a regeneration column solution feed piping 57 and extracted by an amine absorbing solution circulation pump 28b. After decreasing the temperature to, for example, about 40°C by the amine heat exchanger 46, the solution is fed to the absorption column packed bed 40 through the absorption column amine feed piping 41.
  • a heating medium is circulated between a heating medium heater 36 provided in a reboiler solution feed piping 35 and a heat recovery device 4 through heating medium circulation lines 12a, 12b by a heating medium circulation pump 13, and a regenerated amine solution passing through the reboiler solution feed piping 35 is heated by a heating medium having a temperature raised due to heat-changing by a heat recovery device 4.
  • a heating medium having a temperature raised due to heat-changing by a heat recovery device 4.
  • FIG. 2 Another Example of the present invention is shown in Fig. 2 .
  • a basic configuration of Fig. 2 is the same as that of Fig. 1 , except for the following configuration of Fig. 2 in which an absorbing solution stored in a tray 55 provided at the lower portion of a regeneration column 26 is delivered to a heat recovery device 4 that recovers heat by an exhaust gas from a boiler 1 by a regenerating amine absorbing solution circulation pump 15 provided in a heating medium circulation line (low temperature side) 12b, and the absorbing solution heated to high temperature by heat recovery is delivered to a reboiler 30 through a heating medium circulation line 12a.
  • FIG. 3 Comparative Example to Examples shown in Figs. 1 and 2 is shown in Fig. 3 .
  • a basic configuration of the system of Fig. 3 is the same as those of Fig. 1 and Fig. 2 , except for the following configuration of Fig. 3 in which an amine absorbing solution extracted from the bottom of a regeneration column 26 is delivered to an amine solution heat exchanger 46 by a circulation pump 28b after passing through a heat recovery device 4 that recovers heat by an exhaust gas from a boiler 1, and thus the amine absorbing solution to be fed to an absorption column 25 is preheated.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Gas Separation By Absorption (AREA)
  • Treating Waste Gases (AREA)
  • Chimneys And Flues (AREA)

Claims (2)

  1. Système de traitement de gaz d'échappement avec un équipement d'absorption chimique de CO2, dans lequel le système comprend :
    une unité de récupération de chaleur comprenant :
    un dispositif de récupération de chaleur (4) pour récupérer une chaleur d'échappement à partir d'un gaz d'échappement évacué à partir d'une chaudière (1) et fournir la chaleur récupérée à un milieu chauffant, et un dispositif d'échange de chaleur (36) pour transférer la chaleur récupérée du milieu chauffant à une solution absorbante distribuée d'une colonne de régénération de CO2 (26), possédant un lit à garnissage (48), à un bouilleur (30) par l'intermédiaire du dispositif d'échange de chaleur (36), dans lequel le milieu chauffant est en circulation entre le dispositif d'échange de chaleur (36) et le dispositif de récupération de chaleur (4) ; ou
    un dispositif de récupération de chaleur (4) pour récupérer une chaleur d'échappement à partir d'un gaz d'échappement évacué à partir d'une chaudière (1) et fournir la chaleur récupérée à une solution absorbante distribuée à partir d'une colonne de régénération de CO2 (26), possédant un lit à garnissage (48), à un bouilleur (30) par l'intermédiaire du dispositif de récupération de chaleur (4) ; et
    l'équipement d'absorption chimique de CO2 comprenant :
    une colonne d'absorption de CO2 (25) pour mettre une solution absorbante s'écoulant dans la colonne d'absorption de CO2 (25) en contact avec le gaz d'échappement qui est passé à travers le dispositif de récupération (4) pour que la solution absorbante absorbe le CO2 contenu dans le gaz d'échappement,
    le lit à garnissage (48) de la colonne de régénération de CO2 (26) pour chauffer la solution absorbante qui a absorbé le CO2 pour libérer le CO2 à partir de la solution absorbante à CO2 absorbé,
    un plateau (55) dans une portion inférieure de la colonne de régénération de CO2 (26) pour stocker la solution absorbante à CO2 libéré ;
    une tuyauterie (47) pour distribuer la solution absorbante à CO2 absorbé de la colonne d'absorption de CO2 (25) à la colonne de régénération de CO2 (26),
    une tuyauterie (41) pour distribuer la solution absorbante à CO2 libéré d'une portion inférieure de la colonne de régénération de CO2 (26) à la colonne d'absorption de CO2 (25),
    le bouilleur (30) pour chauffer la solution absorbante, qui est passé à travers l'unité de récupération de chaleur, en utilisant de la vapeur, et
    une tuyauterie (35, 33, 57) pour mettre en circulation la solution absorbante entre la colonne de régénération de CO2 (26) et le bouilleur (30), la tuyauterie (35, 33, 57) comprenant (i) une tuyauterie d'alimentation en solution de bouilleur (35) pour fournir la solution absorbante à CO2 libéré du plateau (55) au bouilleur (30), le dispositif de récupération de chaleur (4) étant agencé pour chauffer la solution absorbante à CO2 libéré entre le plateau (55) et le bouilleur (30), (ii) une tuyauterie de vapeur de colonne de régénération (33) agencée pour fournir de la vapeur, générée à partir de la solution absorbante à CO2 libéré chauffée, du bouilleur (30) à la colonne de régénération de CO2 (26) en dessous du lit à garnissage (48), et (iii) une tuyauterie d'alimentation de solution de colonne de régénération (57) pour fournir la solution absorbante à CO2 libéré du bouilleur (30) à la portion inférieure de la colonne de régénération de CO2 (26) ; dans lequel la solution absorbante contient une amine.
  2. Système selon la revendication 1, dans lequel le bouilleur (30) comprend un tube à transfert de chaleur et la vapeur passe à travers le tube à transfert de chaleur.
EP11771994.8A 2010-04-20 2011-04-19 Système de traitement des gaz d'échappement muni d'un équipement d'absorption chimique du dioxyde de carbone Active EP2561919B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL11771994T PL2561919T3 (pl) 2010-04-20 2011-04-19 Układ do obróbki gazów spalinowych zaopatrzony w urządzenie do chemisorpcji dwutlenku węgla

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2010096844A JP5686987B2 (ja) 2010-04-20 2010-04-20 二酸化炭素化学吸収設備を備えた排ガス処理システム
PCT/JP2011/059597 WO2011132659A1 (fr) 2010-04-20 2011-04-19 Système de traitement des gaz d'échappement muni d'un équipement d'absorption chimique du dioxyde de carbone

Publications (3)

Publication Number Publication Date
EP2561919A1 EP2561919A1 (fr) 2013-02-27
EP2561919A4 EP2561919A4 (fr) 2014-08-27
EP2561919B1 true EP2561919B1 (fr) 2017-07-19

Family

ID=44834178

Family Applications (1)

Application Number Title Priority Date Filing Date
EP11771994.8A Active EP2561919B1 (fr) 2010-04-20 2011-04-19 Système de traitement des gaz d'échappement muni d'un équipement d'absorption chimique du dioxyde de carbone

Country Status (8)

Country Link
US (1) US8741034B2 (fr)
EP (1) EP2561919B1 (fr)
JP (1) JP5686987B2 (fr)
CN (1) CN102933284A (fr)
CA (1) CA2796745C (fr)
ES (1) ES2642797T3 (fr)
PL (1) PL2561919T3 (fr)
WO (1) WO2011132659A1 (fr)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2481466A1 (fr) * 2011-01-31 2012-08-01 Siemens Aktiengesellschaft Dispositif et procédé de nettoyage d'un produit d'une installation de processus contaminé par de la nitrosamine
JP5632787B2 (ja) * 2011-04-05 2014-11-26 株式会社日立製作所 超臨界水を用いた反応プロセス
KR101292084B1 (ko) 2013-03-11 2013-08-01 제동일 생체 아민을 포함하는 이산화탄소 흡수제 및 이를 이용한 배가스 중의 이산화탄소 제거방법
US10375901B2 (en) 2014-12-09 2019-08-13 Mtd Products Inc Blower/vacuum
JP6576288B2 (ja) * 2016-04-01 2019-09-18 日鉄エンジニアリング株式会社 二酸化炭素ガスの回収装置、及び、二酸化炭素ガスの製造方法
CN106076114B (zh) * 2016-08-12 2019-06-14 王涛 一种烟气处理系统及方法
CN107042054A (zh) * 2017-03-27 2017-08-15 南京工业大学 一种醛类废气的处理方法
KR102631336B1 (ko) * 2021-08-27 2024-02-01 한국에너지기술연구원 수소 및 이산화탄소의 분리회수 시스템
JP2023062584A (ja) * 2021-10-21 2023-05-08 三菱重工業株式会社 Ｃｏ２回収システム及びｃｏ２回収方法
US12030013B2 (en) 2021-10-22 2024-07-09 Saudi Arabian Oil Company Process for capturing CO2 from a mobile source using exhaust heat
CN113828120A (zh) * 2021-11-01 2021-12-24 中国船舶重工集团公司第七一一研究所 一种低能耗船舶柴油机烟气co2捕集系统
CN114712990B (zh) * 2022-03-17 2023-08-08 中国华能集团清洁能源技术研究院有限公司 一种co2再生装置及工艺方法
WO2024023509A1 (fr) * 2022-07-29 2024-02-01 Carbon Clean Solutions Limited Procédé et système pour l'élimination de dioxyde de carbone à partir de solvants de capture de carbone à l'aide de chaleur provenant d'un gaz
JP7309983B1 (ja) 2022-08-08 2023-07-18 株式会社タクマ 二酸化炭素回収装置、及び二酸化炭素回収方法
EP4353676A1 (fr) * 2022-10-14 2024-04-17 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Installation et procédé de production d'un produit de gaz de synthèse appauvri en dioxyde de carbone par reformage à la vapeur

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4514379A (en) * 1983-06-28 1985-04-30 Union Oil Company Of California Catalytic process for converting 2-oxazolidinones to their corresponding alkanolamines
JPH0731834A (ja) * 1993-06-28 1995-02-03 Mitsubishi Heavy Ind Ltd 吸収液の再生方法
NO180520C (no) * 1994-02-15 1997-05-07 Kvaerner Asa Fremgangsmåte til fjerning av karbondioksid fra forbrenningsgasser
JP3486220B2 (ja) 1994-03-08 2004-01-13 バブコック日立株式会社 燃焼排ガス浄化方法および装置
US6174506B1 (en) * 1999-06-10 2001-01-16 Praxair Technology, Inc. Carbon dioxide recovery from an oxygen containing mixture
JP3969949B2 (ja) 2000-10-25 2007-09-05 関西電力株式会社 アミン回収方法及び装置並びにこれを備えた脱炭酸ガス装置
CN1137753C (zh) * 2000-12-19 2004-02-11 中国冶金建设集团鞍山焦化耐火材料设计研究总院 生物气中co2、h2s的净化工艺
JP4231735B2 (ja) 2003-02-04 2009-03-04 新日本製鐵株式会社 二酸化炭素の分離回収方法および装置
JP4875303B2 (ja) * 2005-02-07 2012-02-15 三菱重工業株式会社 二酸化炭素回収システム、これを用いた発電システムおよびこれら方法
NO326645B1 (no) * 2005-06-28 2009-01-26 Ntnu Technology Transfer As Fremgangsmate og apparatur for a fjerne og gjenvinne sure gasser, CO2 og/eller H2S.
US7976803B2 (en) * 2005-08-16 2011-07-12 Co2Crc Technologies Pty Ltd. Plant and process for removing carbon dioxide from gas streams
JP4795991B2 (ja) * 2007-02-27 2011-10-19 三菱重工業株式会社 Ｃｏ２回収装置及びｃｏ２回収装置における固形分取出し方法
US8192530B2 (en) * 2007-12-13 2012-06-05 Alstom Technology Ltd System and method for regeneration of an absorbent solution
JP2009247932A (ja) * 2008-04-02 2009-10-29 Chiyoda Kako Kensetsu Kk 排ガス熱源を利用した二酸化炭素の除去方法
JP5558036B2 (ja) * 2008-09-04 2014-07-23 株式会社東芝 二酸化炭素回収型汽力発電システム

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None *

Also Published As

Publication number Publication date
EP2561919A4 (fr) 2014-08-27
CA2796745A1 (fr) 2011-10-27
PL2561919T3 (pl) 2018-01-31
ES2642797T3 (es) 2017-11-20
JP5686987B2 (ja) 2015-03-18
JP2011224472A (ja) 2011-11-10
WO2011132659A1 (fr) 2011-10-27
US8741034B2 (en) 2014-06-03
EP2561919A1 (fr) 2013-02-27
CN102933284A (zh) 2013-02-13
US20130052096A1 (en) 2013-02-28
CA2796745C (fr) 2017-11-21

Similar Documents

Publication Publication Date Title
EP2561919B1 (fr) Système de traitement des gaz d'échappement muni d'un équipement d'absorption chimique du dioxyde de carbone
JP6072055B2 (ja) 排ガス処理システム及び方法
EP2722097B1 (fr) Système de traitement de gaz d'échappement de combustion et procédé de traitement de gaz d'échappement de combustion
JP5416679B2 (ja) 排ガス処理方法と装置
US8623314B2 (en) Chilled ammonia based CO2 capture system with ammonia recovery and processes of use
US8828130B2 (en) Exhaust gas treatment system equipped with carbon dioxide removal device
US9216380B1 (en) Ammonia stripper for a carbon capture system for reduction of energy consumption
WO2011132660A1 (fr) Système de traitement de gaz d'échappement ayant un dispositif d'élimination de dioxyde de carbone
WO2011152552A1 (fr) Système et procédé de traitement de gaz d'échappement
WO2014024791A1 (fr) Système de traitement de gaz d'échappement
JP5738137B2 (ja) Ｃｏ２回収装置およびｃｏ２回収方法
JP2011194292A (ja) 排ガス処理方法および装置
JP2010227742A (ja) 排煙処理装置と方法
CN102980198A (zh) 水洗凝结式烟气三回收装置
JP6173734B2 (ja) 排ガス処理システム
Tsujiuchi et al. CO 2 recovery unit and CO 2 recovery method

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20121114

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

DAX Request for extension of the european patent (deleted)
A4 Supplementary search report drawn up and despatched

Effective date: 20140728

RIC1 Information provided on ipc code assigned before grant

Ipc: F23J 15/00 20060101ALI20140722BHEP

Ipc: B01D 53/62 20060101AFI20140722BHEP

Ipc: B01D 53/14 20060101ALI20140722BHEP

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: MITSUBISHI HITACHI POWER SYSTEMS, LTD.

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: MITSUBISHI HITACHI POWER SYSTEMS, LTD.

17Q First examination report despatched

Effective date: 20150819

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: GRANT OF PATENT IS INTENDED

INTG Intention to grant announced

Effective date: 20170130

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE PATENT HAS BEEN GRANTED

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 909843

Country of ref document: AT

Kind code of ref document: T

Effective date: 20170815

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602011039751

Country of ref document: DE

REG Reference to a national code

Ref country code: SE

Ref legal event code: TRGR

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2642797

Country of ref document: ES

Kind code of ref document: T3

Effective date: 20171120

REG Reference to a national code

Ref country code: NL

Ref legal event code: MP

Effective date: 20170719

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK05

Ref document number: 909843

Country of ref document: AT

Kind code of ref document: T

Effective date: 20170719

REG Reference to a national code

Ref country code: NO

Ref legal event code: T2

Effective date: 20170719

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170719

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170719

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170719

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170719

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170719

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171020

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170719

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170719

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171119

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171019

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 8

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602011039751

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170719

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170719

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170719

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170719

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170719

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170719

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170719

26N No opposition filed

Effective date: 20180420

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170719

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170719

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

REG Reference to a national code

Ref country code: BE

Ref legal event code: MM

Effective date: 20180430

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180419

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180430

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180430

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180430

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180419

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180419

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170719

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20110419

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170719

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170719

Ref country code: MK

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170719

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170719

REG Reference to a national code

Ref country code: DE

Ref legal event code: R082

Ref document number: 602011039751

Country of ref document: DE

Representative=s name: PAGE, WHITE & FARRER GERMANY LLP, DE

Ref country code: DE

Ref legal event code: R081

Ref document number: 602011039751

Country of ref document: DE

Owner name: MITSUBISHI POWER, LTD., JP

Free format text: FORMER OWNER: MITSUBISHI HITACHI POWER SYSTEMS, LTD., YOKOHAMA, JP

REG Reference to a national code

Ref country code: NO

Ref legal event code: CHAD

Owner name: MITSUBISHI POWER, JP

REG Reference to a national code

Ref country code: ES

Ref legal event code: PC2A

Owner name: MITSUBISHI POWER, LTD.

Effective date: 20210421

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20240229

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 20240312

Year of fee payment: 14

Ref country code: PL

Payment date: 20240312

Year of fee payment: 14

Ref country code: FR

Payment date: 20240308

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20240227

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20240507

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NO

Payment date: 20240409

Year of fee payment: 14