EP2542399A1 - Procédé d'isolation de la cabine d'un véhicule - Google Patents

Procédé d'isolation de la cabine d'un véhicule

Info

Publication number
EP2542399A1
EP2542399A1 EP11709825A EP11709825A EP2542399A1 EP 2542399 A1 EP2542399 A1 EP 2542399A1 EP 11709825 A EP11709825 A EP 11709825A EP 11709825 A EP11709825 A EP 11709825A EP 2542399 A1 EP2542399 A1 EP 2542399A1
Authority
EP
European Patent Office
Prior art keywords
foam
vehicle cabin
foam formulation
curable
formulation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP11709825A
Other languages
German (de)
English (en)
Inventor
Adrian J. Birch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Dow Global Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies LLC filed Critical Dow Global Technologies LLC
Publication of EP2542399A1 publication Critical patent/EP2542399A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34—Auxiliary operations
    • B29C44/36—Feeding the material to be shaped
    • B29C44/46—Feeding the material to be shaped into an open space or onto moving surfaces, i.e. to make articles of indefinite length
    • B29C44/468—Feeding the material to be shaped into an open space or onto moving surfaces, i.e. to make articles of indefinite length in a plurality of parallel streams which unite during the foaming

Definitions

  • This invention relates to a process for insulating vehicle cabins.
  • Vehicles contain cabins or passenger compartments that enclose the operator and other passengers. For reasons of passenger comfort, portions of these cabins are often thermally and/or acoustically insulated. Large truck cabins are prominent examples. Large truck cabins often have an area behind the seats where the driver can set up a bed and store personal belongings. In the United States, truck cabins of these types are sometimes known as "sleeper cabs". In some cases, this area can even be large enough to include a small kitchen or sitting area. Sleeper cabs allow the driver to park overnight and sleep at any convenient place along the road.
  • Thermal and acoustical insulation is very important in these sleeper cabs, if the driver is to be comfortable. Therefore, this insulation is routinely installed when sleeper cabs are manufactured.
  • This insulation is currently installed by manually applying pre-cut sections of polymeric foam and felt to the interior walls of the cabin.
  • the foam and felt pieces must be cut in advance to fit between and around structural features such as struts, windows and doors, as well as other features.
  • This installation process is time-consuming, as the pieces must be pre-cut to size and then manually installed. The installation process takes so much time that it is often the rate-limiting step in the trim shop assembly lines where the installation takes place.
  • the foam and felt pieces must be inventoried, which leads to still more costs.
  • This invention is a process for insulating a vehicle cabin, comprising robotically spraying a curable foam formulation through a flat cone airless sprayhead onto at least one interior surface of a vehicle cabin in a series of substantially non-overlapping parallel strips from a distance of from 6 to 40 cm from the interior surface, and curing the curable foam formulation to form an insulating foam adherent to the interior surface.
  • the process produces a good quality insulation layer on interior surfaces of the vehicle cabin.
  • the process is rapid, thereby reducing installation time and enabling the
  • Figure 1A is an isometric view of a simulated roof section of a vehicle, prior to application of foam insulation in accordance with this invention.
  • Figure IB is an isometric view of the simulated roof section shown in Figure 1A, after a first application of a first parallel strip of curable foam insulation.
  • Figure 1C is an isometric view of the simulated roof section shown in Figure 1A, during an application of a second parallel strip of curable foam insulation.
  • Figure ID is an isometric view of the simulated roof section shown in Figure 1A, during application of a third parallel strip of curable foam insulation.
  • Figure IE is an isometric view of the simulated roof section shown in Figure 1A, after application of a third parallel strip of curable foam insulation.
  • Figure IF is an isometric view of the simulated roof section shown in Figure 1A, during application of a fourth parallel strip of curable foam insulation.
  • Figure 1G is an isometric view of the simulated roof section shown in Figure 1A, after application of a fourth parallel strip of curable foam insulation.
  • Figure 1H is an isometric view of the simulated roof section shown in Figure 1A, during application of a fifth parallel strip of curable foam insulation.
  • Figure II is an isometric view of the simulated roof section shown in Figure 1A, during application of a sixth parallel strip of curable foam insulation.
  • Figure 1 J is an isometric view of the simulated roof section shown in Figure 1A, after application of a sixth parallel strip of curable foam insulation.
  • Figure IK is an isometric view of the simulated roof section shown in Figure 1A, after application of a seventh parallel strip of curable foam insulation.
  • Figure 2A is an isometric view of an integrated vehicular roof and wall panel of a vehicle, prior to application of foam insulation in accordance with this invention.
  • Figure 2B is an isometric view of the integrated vehicular roof and wall panel shown in Figure 2A, after application of three parallel strips of curable foam insulation.
  • Figure 2 C is an isometric view of the integrated vehicular roof and wall panel shown in Figure 2A, after application of four parallel strips of curable foam insulation in one section, and another strip of curable foam insulation in a second section.
  • Figure 2D is an isometric view of the integrated vehicular roof and wall panel shown in Figure 2A, after application of foam insulation in accordance with this invention.
  • FIGS. 1A through IK illustrate sequential steps in the insulating process of the invention.
  • FIG. 1A shows simulated roof section 1 of a vehicle cabin.
  • Struts 2 define surfaces 5 and 5A, to which foam insulation is to be applied.
  • simulated roof section 1 is not assembled onto other surfaces that represent other parts (sides, bottom) of a vehicle cabin.
  • the vehicle cabin may be painted prior to applying foam insulation in accordance with this invention, although the foam insulation may instead be applied to an uncoated surface or onto e- coated surfaces.
  • surfaces 5 and 5 A face downwardly during the spraying process, necessitating an overhead or upward spray direction (upside-down spraying). Because, in a manufacturing environment, the vehicle cabin typically will be assembled prior to applying the foam insulation, it is expected that at least one surface of the cabin often will be facing downwardly when the foam insulation is applied to it in the manner shown in Figures 1A- 1K.
  • the curable foam formulation can be applied to multiple and/or non-coplanar surfaces of a vehicle cabin, in accordance with the invention, including one or more downwardly-facing surfaces, without repositioning the vehicle cabin during the spraying process.
  • surface 15 is planar, but one or more surfaces of a vehicle cabin may be have non-planar surfaces.
  • the process of the invention is easily used to apply a foam insulation layer to a three-dimensional surface of a vehicle cabin.
  • a curable foam formulation is applied surfaces 5 and 5A of simulated roof section I .
  • Mix/sprayhead 6 is affixed to robotic arm 7, which controls the movement of mix/spray head 6.
  • Robotic arm 7 and mix/spray head 6 are operated via computerized controls (not shown) which (a) control the placement and movement of mix/spray head 6 relative to surfaces 5 and 5A and (b) control the timing of the mix/spray head operation.
  • the computerized controls may also control other operating parameters such as pressure and/or temperatures at mix/spray head 6.
  • mix/spray head 6 is held in a starting position, from which it will begin the spraying process.
  • Robotic arm 7 is controlled to move mix/spray head 6 over the surfaces 5 and 5A in a series of parallel lines.
  • Mix/spray head 6 is operated to dispense a curable foam formulation onto surfaces 5 and 5A as it moves along those parallel lines, on each pass laying down a strip of the curable foam formulation.
  • Figures IB through 1J demonstrate the movement of robotic arm 7 and mix/sprayhead 6 through the process of applying an insulating layer onto surfaces 5 and 15 of simulated roof sections 5 and 5A.
  • Robotic arm 7 first moves upwardly and downwardly over surface 5, moving a predetermined distance to the left after each pass. During each pass, a strip of curable foam formulation is applied to surface 5.
  • Robotic arm 7 and mix/sprayhead 6 move transversely across surface 5 in three passes to apply three strips of the curable foam formulation to surface 5.
  • Figure IB shows the position of mix/spray head 6 and robotic arm 7 at the end of the first pass.
  • a strip 8A of the curable foam formulation is applied to surface 5.
  • Robotic arm 7 is operated such that mix/spray head 6 is maintained within a predetermined range of distances from surface 5 as mix/spray head
  • robotic arm 7 moves mix/sprayhead 6 to the left by a predetermined distance, and applies a second strip 8B of curable foam formulation while moving back upwardly across surface 5.
  • Figure 1C shows the position of robotic arm 7 and mix/sprayhead 6 at the beginning of this second pass.
  • Adjacent strips abut "substantially without overlapping” if they (1) abut but do not overlap at all, (2) overlap to the extent of 10% or less of their respective widths and/or (3) are separated by a distance which becomes filled as the curable foam formulation expands.
  • Other spraying parameters including the distance from mix/sprayhead 6 to surface 5, the spray pattern produced by the mix/sprayhead and operating pressures, are taken into account in determining the amount of leftward movement between the application of adjacent strips 8A and 8B, so there is essentially no overlap between the first strip 8A and second strip 8B of the curable foam formulation.
  • 69233 mix/sprayhead 6 and surfaces 5 and 5A is at least 6 cm and not more than 40 cm.
  • a preferred distance is at least 8 cm up to 35 cm.
  • Figure ID shows the position of mix/sprayhead 6 and robotic arm 7 during the application of third strip 8C of the curable foam formulation to surface 5.
  • This third strip is again laid essentially parallel to the previously applied strip 8B, with substantially no overlap, again through robotic control of the position and path of mix/sprayhead 6.
  • first and second strips 8A and 8B of the curable foam formulation are seen to be visibly expanding and curing, whereas third strip 8C exhibits minimal rise and cure.
  • Figure IE shows the position of mix/sprayhead 6 and robotic arm 7 after the application of third strip 8C of the curable foam formulation to surface 5.
  • first, second and third strips 8A, 8B and 8C of the curable foam formulation are seen to be visibly expanding and curing.
  • Total elapsed time from the start of the process (Figure 1A) to the position shown in Figure IE is on the order of about 1 to 20 secones, preferably from 2 to 10 seconds and more preferably from 4 to 5 seconds.
  • Figures IF through IJ illustrate the movement of mix/sprayhead 6 and robotic arm 7 during the application of four substantially parallel, non-overlapping strips 8D, 8E, 8F and 8G to surface 5A of simulated roof section I .
  • Figure IK shows the insulated simulated roof section 1 after the application of the curable foam formulation to surfaces 5 and 5A has been completed.
  • the applied curable foam formulation rises and cures after it is applied.
  • strips 8A-8C have merged as a result of the rising and curing process to form insulation layer 9, which adheres to surface 5 of insulated roof/sidewall I.
  • Strips 8D-8G being the last to have been applied, have in Figure IK only partially risen and cured. Upon further reaction, strips 8D-8G will merge to form an insulation layer which adheres to surface 5A of insulated roof/sidewall 1. Struts 2 remain exposed.
  • Insulation layers 5 and 5A are of highly uniform thickness, although some thickening can be present at the junctions between adjacent strips of curable foam formulation. This thickening can be reduced or eliminated through more careful control of the movement of mix/sprayhead 6, by changing application rates (such as by adjusting operating pressures) and/or by modifying the distance from the mix/sprayhead 6 and surfaces 5 and 5A.
  • a fully assembled vehicle cabin body typically will include multiple (two or more) non-coplanar surfaces which need insulating. One or more of those surfaces is often oriented downwardly when the foam formulation is applied in accordance with the invention, so that the curable foam formulation must be sprayed upwardly onto those surfaces ("upside-down" spraying).
  • the process of the invention is useful to apply a foam insulating layer to as few as one and as many as all of the various surfaces of the vehicle cabin body.
  • the foam insulation can be applied to multiple surfaces using a single robotically controlled mix/sprayhead, or multiple robotically controlled mix/sprayheads.
  • the vehicle cabin may be a passenger compartment for an automobile, truck, boat, personal water craft, train or other land or marine vehicle.
  • truck sleeper cabs are of particular interest.
  • the sprayhead used in this invention is a flat cone airless type.
  • airless it is mean that no propelling gas is ejected through the sprayhead as the foam formulation is sprayed onto the interior surface of the vehicle body. Gasses may be passed through the sprayhead between shots, such as for cleaning purposes.
  • “Flat cone” refers to the spatial distribution of the sprayed foam formulation. Viewed from the side, the sprayed foam formulation forms a fan-like shape. If the sprayhead were to be held stationary with respect to the target as the foam formulation is dispensed, the sprayed foam formulation would contact the target to form a straight-line pattern or a highly elongated ellipse.
  • the sprayhead is oriented so that the width of the spray is perpendicular to its direction of movement as the foam formulation is sprayed, so that the width of the applied strips of foam formulation is defined by the width of the spray.
  • Flat cone sprayheads are available commercially from manufacturers such as Spraying Systems Company, Wheaton, Illinois US.
  • the sprayhead may be affixed to a mixhead. This will usually be the case when the curable foam formulation consists of two or more constituent components which are to be mixed immediately before spraying. In such a case, the various constituent components are brought together under pressure at the mixhead, where they are mechanically mixed together and then passed through the sprayhead for application onto the vehicle cabin. Impingement mixers are a preferred type of mixhead, but other types of mixheads, including static mixers, can be used instead of or in conjunction with an impingement mixer. Suitable mixheads are available commercially from manufacturers such as Canon and Krauss-Maffei.
  • the flow of materials to the mixhead is preferably automated and controlled in conjunction with other operating parameters, such as the rate of movement of the sprayhead across the surface of the vehicle cabin and the distance of the sprayhead to the surface, to obtain the desired spray pattern, width of spray, and thickness of the applied layer. It is generally preferable to apply a layer which, after expansion, is from 10 to 75 mm thick, although it is possible to apply thinner or thicker layers.
  • the output of curable foam formulation from the sprayhead may be from 1 to 200 grams/second (g/s), preferably from 5 to 100 g/s and more preferably from 10 to 50 g/s.
  • Traversing speeds are selected to provide the desired layer thickness. Suitable traversing speeds are typically from 100 to 2000 mm/second. A preferred range is from 200 to 1200 mm/second.
  • Robotic control is provided by an automated mechanical device to which the sprayhead is affixed. Movement of the mechanical device is controlled by one or more computers, by which is meant simply a programmed electronic device which generates signals that directly or indirectly produce the desired movement of the mechanical device.
  • the program may exist in software or firmware, or some combination thereof.
  • the mechanical device includes or is connected to various actuators, such as motors, piezoelectric or hydraulic systems, which respond to signals produced by the computer(s) to effect a predetermined movement in response to specific signals.
  • the specific design of the robotic control system is not considered to be critical to the invention, provided that the robotic control system is capable of manipulating the sprayhead through the movements as are needed to apply the curable foam formulation. Suitable robotic control systems are available from various commercial sources, including ABB Robotics, Zurich, Switzerland.
  • the preferred multipart polyurethane formulations can be formulated so that they react exothermically at temperatures ranging from slightly below room temperature to a slightly elevated (up to 50°C) temperature. In such a case, all that is required is to bring the components to the mixhead at a temperature sufficient for the components to react, and to maintain a temperature of from about 15°C to about 50°C during the spraying step and curing steps. Expansion and initial curing to
  • a tack-free state in this case is generally completed within about 1 minute. If necessary, the components can be heated to higher temperatures or cooled to lower temperatures before performing the mixing and spraying steps, and heat can be applied to the sprayed foam to help promote expansion and curing.
  • the process of the invention can be easily practiced in an assembly line environment, in which the vehicle cabin is mounted on a movable production line as the foam insulation is applied.
  • a movable production line which may take any form, for transporting it sequentially through multiple assembly stations at which various assembly steps are performed.
  • the movable line may be brought to a stop at one or more assembly stations at which the foam insulation layer is applied in accordance with this invention.
  • foam insulation layer it is generally desirable to apply the foam insulation layer to the vehicle cabin before interior components are assembled inside of the vehicle cabin.
  • these interior components are assembled onto or inside of the vehicle cabin in a "trim shop", which is located after a preceding painting or e-coating step is completed.
  • a "trim shop” which is located after a preceding painting or e-coating step is completed.
  • the foam insulation layer is applied between the paint and trim shops of an assembly plant, or in the trim shop after painting but before additional trim features are assembled onto the vehicle cabin.
  • foam insulation layer it is also possible to apply the foam insulation layer to the vehicle cabin prior to painting, or at least prior to the application of the final paint coat.
  • one or more paint layers can be applied overtop the foam insulation layer.
  • a paint layer covering the foam insulation layer can provide stiffening and/or a non-porous surface layer.
  • the curable foam formulation can be any material which, when sprayed onto the vehicle cabin surface, (1) adheres to the surface and (2) expands and cures to form a cellular insulation.
  • the cured insulation suitably has a foam density of from 16 to 240 kg/m 3 .
  • a preferred density is from 24 to 96 kg/m 3 and a more preferred density is from 24 to 64 kg/m 3 .
  • the insulation may be open or closed-celled, although it is preferred
  • the curable foam formulation may be, for example, an expandable epoxy resin or an expandable polyurethane.
  • the curable foam formulation preferably expands and cures to a tack-free state in less than one minute, preferably in less than 30 seconds, after application.
  • a preferred type of curable foam formulation is a multi-part polyurethane, as these systems can be formulated to expand and cure very rapidly.
  • the multi-part polyurethane consists of at least a polyol component and a polyisocyanate component. These components are formulated separately, the polyol component containing at least one polyol and other isocyanate-reactive materials as may be present, and the polyisocyanate containing at least one polyisocyanate compound. It is possible to formulate all of the isocyanate-reactive materials into a single, formulated polyol component, and to formulate all of the polyisocyanate compounds into a single polyisocyanate component, and to bring exactly two streams into the mixhead. It is also possible to bring the ingredients to the mixhead in a greater number of streams.
  • Auxiliary materials such as blowing agents, surfactants, catalysts, fillers, reinforcing fibers, and the like can be formulated into either or both of the polyol component or the polyisocyanate component. Reinforcing fibers can also or alternatively be brought separately into the mixhead and combined with the curable foam formulation in the mixhead, in the spray head or in the spray.
  • the curable foam formulation will contain at least one blowing agent.
  • blowing agents are those which release carbon dioxide or react to form carbon dioxide under the conditions of the curing step.
  • Water is a preferred blowing agent, although compounds such as certain carbamates and bicarbonate/citric acid mixtures are also useful.
  • the selection of particular polyols, polyisocyanates and other components of the polyurethane foam formulation are selected to provide the desired foam density, curing characteristics, insulating properties and physical properties.
  • the cured insulation may be a highly rigid, friable material, may be a highly compressible and flexible material, or may be a so-called "viscoelastic" material which exhibits a time- delayed and rate- dependent response to an applied stress. These viscoelastic foams have low resiliency and recover slowly when compressed.
  • Foam formulations useful for preparing these various types of insulating foams are well known and described, for example, in US 5,817,860, US 6,423,755, US 6,541,534, WO 02/079340, WO 03/037948, WO 05/069273, WO 07/040617 and WO 08/021034, all incorporated herein by reference.
  • the polyol component generally will contain at least one polyol that has at least three hydroxyl, primary amino and/or secondary amino groups per molecule. Two or more such polyols may be present. In addition, one or more polyol(s) having a lower (1 to 2) functionality or higher (4 to 8) functionality may be present.
  • the polyol(s) preferably have an equivalent weight of from 31 to about 2000 per hydroxyl and/or primary or secondary amino group. When the insulation is a rigid type, the average equivalent weight of the polyols tends to be in the range of from about 50 to 200. Viscoelastic foams tend to be produced when the predominant (i.e., that present in the largest quantity by weight) polyol has an equivalent weight of 200 to 400. More flexible materials tend to be produced when the predominate polyol has an equivalent weight of greater than 400.
  • Suitable polyols include glycerine, trimethylolpropane, trimethylolethane, pentaerythritol, sorbitol, sucrose, diethanolamine, monoethanolamine, triethanolamine, pentaerythritol, neopentyl glycol, dipropylene glycol, tripropylene glycol, diethylene glycol, alkoxylates (especially ethoxylates and/or propoxylates) of any of the foregoing as well as other polyether polyols and triethylene glycol polyester polyols.
  • Polyether polyols are preferred; such a polyether polyol may be a homopolymer of propylene oxide, a random copolymer of propylene oxide and optionally up to 30% by weight ethylene oxide, or an ethylene oxide-capped poly(propylene oxide).
  • Each polyisocyanate compound is an organic polyisocyanate or mixture. These compounds suitably have, in the aggregate, an isocyanate content of from 8 to 45 weight percent, preferably from 15 to 40 weight percent, and an average functionality of from 2.0 to 3.5 isocyanate groups per molecule.
  • Suitable polyisocyanates include aromatic, aliphatic and cycloaliphatic polyisocyanates. Aromatic polyisocyanates are generally preferred based on cost, availability and properties imparted to the product polyurethane.
  • Exemplary polyisocyanates include, for example, m-phenylene diisocyanate, 2,4- and/or 2,6-toluene diisocyanate (TDI), the various isomers of diphenylmethanediisocyanate (MDI), hexamethylene-l,6-diisocyanate, tetramethylene- 1,4-diisocyanate, cyclohexane-l,4-diisocyanate, hexahydrotoluene diisocyanate, hydrogenated MDI (H 12 MDI), naphthylene-l,5-diisocyanate, methoxyphenyl-2,4- diisocyanate, 4,4'-biphenylene diisocyanate, 3,3'-dimethoxy-4,4'-biphenyl diisocyanate, 3,3'-dimethyldiphenylmethane-4,4'-diisocyanate, 4,4',4"-
  • polyisocyanates include MDI and derivatives of MDI such as carbodiimide-modified or uretonimine-modified "liquid" MDI products and polymeric MDI, as well as mixtures of the 2,4- and 2,6- isomers of TDI. Any of the foregoing polyisocyanates may be modified with carbodiimide, biuret, urethane, urea or similar groups.
  • Either or both of the polyol and the isocyanate components may contain various optional ingredients. These include an organosilicone surfactant, one or more reaction catalysts, a diluent, a plasticizer, a flame retardant, fillers, reinforcing fibers, and the like.
  • the silicone surfactant if present, is suitably an organosilicone type.
  • organosilicone surfactants are useful, including those sold by Momentive Performance Materials under the NiaxTM trade name or those sold by Th. Goldschmidt AG under the trade name TegostabTM, or those sold by Air Products under the DabcoTM tradename. Specific examples include NiaxTM L-6900 surfactant, TegostabTM B 1048 B- 8462, B8427, B8433 and B-8404 surfactants and DabcoTM DC-193, DC-198, DC-5000, DC-5043 and DC-5098 surfactants.
  • the surfactant suitably constitutes from 0.25 to 5 percent, preferably from 0.5 to 2.5 percent, of the total weight of the polyisocyanate component.
  • Suitable catalysts include tertiary amine compounds and organometallic compounds, especially tin carboxylates and tetravalent tin compounds.
  • Representative tertiary amine catalysts include trimethylamine, triethylamine, dimethylethanolamine, N-methylmorpholine, N-ethylmorpholine, ⁇ , ⁇ -dimethylbenzylamine, N,N- dimethylethanolamine, N,N,N',N'-tetramethyl-l,4-butanediamine, N,N- dimethylpiperazine, l,4-diazobicyclo-2,2,2-octane, bis(dimethylaminoethyl)ether, bis(2- dimethylaminoethyl) ether, morpholine,4,4'-(oxydi-2, l-ethanediyl)bis, triethylenediamine, pentamethyl diethylene triamine, dimethyl cyclohexyl amine, N- cetyl
  • tin catalysts examples include stannous octoate, dibutyl tin diacetate, dibutyl tin dilaurate, dibutyl tin dimercaptide, dialkyl tin dialkylmercapto acids, dibutyl tin oxide, dimethyl tin dimercaptide, dimethyl tin diisooctylmercaptoacetate, and the like.
  • Catalysts are typically used in small amounts.
  • the total amount of catalyst used may be 0.0015 to 10, preferably from 0.5 to 10 parts by weight per 100 parts by weight of polyol or polyol mixture.
  • Catalyst concentrations tend to be somewhat high in this invention to promote a fast cure, so that the sprayed foam formulation does not run off of the surfaces to which it is applied, and so the vehicle cabin can be taken to downstream manufacturing processes quickly after the foam insulation layer is applied.
  • Diluents are materials which are added to reduce component viscosities or to balance mixing ratios. They may be of the reactive or non-reactive types. Plasticizers tend to make the cured polymer more flexible, and may also be present to balance mixing ratios. Various phthalate esters are useful for this purpose.
  • Flame retardants are commonly halogenated and/or phosphorus-containing compounds. A wide number of these materials are useful herein.
  • Fillers include particulate solids which are thermally and chemically stable at the temperatures encountered in the curing reaction. They may be inorganic materials such as various clays, ground glass, boron nitride, calcium carbonate, mica, titanium dioxide, diatomaceous earth, carbon black and the like, or may be high-melting or non- melting organic polymers. Fibers include materials such as glass fibers, carbon fibers and various types of ceramic fibers. High melting polymeric fibers also are useful.
  • Fibers can be introduced into the foam layer in several ways.
  • a mat or scrim of fibers can be applied to the vehicle surface, and the curable foam formulation sprayed on top of the mat or scrim.
  • fibers can be sprayed together with the curable foam formulation onto the vehicle surface.
  • fibers can be introduced into the mixhead, where they are mixed with the curable foam formulation and transferred together to the flat cone airless sprayhead, from which they are sprayed onto the vehicle surface. It is also possible to spray the fibers and curable foam formulation separately onto the vehicle surface.
  • the curable foam formulation in such a
  • fibers may be supplied in the form of continuous rovings which are chopped into the desired lengths immediately before being sprayed.
  • Krauss-Maffei manufactures spray equipment which is capable of chopping the rovings into short (6 to 30 cm) lengths and mixing the chopped fibers with a foam formulation.
  • a wetting agent may be present if a filler or fiber is present.
  • Suitable wetting agents include certain acidic polyester and ammonium salts of acidic copolymers, as sold by BykUSA under the trade names BYK W985 and BYK W969.
  • the polyisocyanate and polyol components can be reacted at an isocyanate index of from 70 to 500 or more, although a more typical isocyanate index is from 80 to 130.
  • Isocyanate index is calculated as the number of reactive isocyanate groups provided by the polyisocyanate component divided by the number of isocyanate-reactive groups in the foam formulation (including isocyanate-reactive blowing agents such as water) and multiplying by 100. Water is considered to have two isocyanate-reactive groups per molecule for purposes of calculating isocyanate index.
  • a preferred isocyanate index is from 80 to 125.
  • foam insulation layer Various additional coatings or other layers can be applied on top of the foam insulation layer that is applied in accordance with this invention.
  • These include paint layers, other color layers, various show surfaces which, depending on their particular composition, can be sprayed onto the foam layer or attached thereto via various adhesives or through mechanical means, and the like.
  • the foam layer can also function as an adhesive layer, if a layer of another material is laid onto the foam layer before it has fully cured. Show surfaces may include woven or nonwoven fabrics, thermoplastic films, various multilayer composite materials and the like.
  • roof-sidewall panel 11 includes peripheral members 12 which define sections 15 and 15 A, to which foam insulation is applied.
  • Section 15 is 120 cm long X 80 cm wide and bends through an angle of nearly
  • Section 15A is 80 cm wide and about 40 cm from top to bottom.
  • a Krauss-Maffei RimstarTM Compact minidose 3/3 reaction injection molding apparatus is equipped with a MK2.0-2K mixhead (reference numeral 16 in Figures 2B-2D) which feeds a Wheaton ROBTC 8003 flat cone airless spray nozzle.
  • Mix/sprayhead 16 is manipulated with an ABB 5-joint robotic arm (reference numeral 17 in Figures 2B-2D) under computerized control.
  • the foam formulation is a two-part polyurethane.
  • the components are heated to a temperature of 30-40°C and brought to the mixhead under a pressure of 160 bar (16 MPa).
  • the weight ratio of polyol component to polyisocyanate is 1:1.18.
  • Spray output is from 20-30 g/second.
  • the polyol and polyisocyanate components are as follows:
  • This formulation has a cream time of approximately 2 seconds under the test conditions, and expands and cures to a tack-free state in less than one minute after being dispensed.
  • the computer is programmed to spray the foam formulation onto section 15 in an up-and-down pattern, making four passes starting in the top left-hand corner (as shown) and finishing at the bottom right hand corner of section 15. While applying foam to section 15, mix/sprayhead 16 moves in three dimensions, maintaining a nearly constant distance from the surface of section 15 as mix/sprayhead 16 traversed the bend in section 15. Foam formulation is then sprayed into Section 15A in two left-to-right passes starting at the top left-hand corner (as shown), with mix/sprayhead 16 in this case moving first from left-to-right and then from right-to-left to apply the foam formulation.
  • the spray distance is set at 6-10 cm, the traversing speed set at 200mm/second and the spray output is set at 25 g/second. This produces (after curing and expansion) a foam insulation layer mm thick, with minimal drift and overspray.
  • the average time needed to fill both sections 15 and 15A with the foam formulation is less than 14 seconds.
  • FIG. 69233 Figure 2B illustrates roof-sidewall panel 11 after the foam formulation has been applied to part of section 15. Strips 18A, 18B and 18C of foam formulation have been applied, and are in various stages of expansion and curing. Robotic arm 17 and mix/sprayhead 16 is shown at the completion of a downward movement to apply a third strip of foam insulation to section 15.
  • FIG 2C illustrates roof-sidewall panel 11 after section 15 has been completely covered with the foam formulation, and a first strip 18E of the foam formulation has been applied to section 15A.
  • the foam formulation applied to section 15 has expanded and partially cured to form foam insulation layer 19.
  • Figure 2D illustrates roof-sidewall panel 11 upon completion of the insulating process.
  • foam insulation layer 19 covers section 15 and foam insulation layer 19A covers section 15A.
  • the foam insulation layers 19 and 19A are generally uniformly thick, although small discrepencies are visible at the bond lines that form between adjacent strips of the foam formulation.

Landscapes

  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

Selon l'invention, de la mousse acoustique et isolante est appliquée sur les surfaces intérieures de la cabine d'un véhicule par pulvérisation robotisée à des distances de pulvérisation contrôlées. Une formulation de mousse durcissable est appliquée par pulvérisation par le biais d'une tête de pulvérisation de conception spécifique. La formulation de mousse est appliquée sous la forme d'une série de deux bandes parallèles ou plus, (18A, 18B, 18C).
EP11709825A 2010-03-03 2011-03-01 Procédé d'isolation de la cabine d'un véhicule Withdrawn EP2542399A1 (fr)

Applications Claiming Priority (2)

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US31001510P 2010-03-03 2010-03-03
PCT/US2011/026593 WO2011109335A1 (fr) 2010-03-03 2011-03-01 Procédé d'isolation de la cabine d'un véhicule

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EP2542399A1 true EP2542399A1 (fr) 2013-01-09

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CN109366841A (zh) * 2018-11-15 2019-02-22 陕西宏象房车科技发展有限公司 房车保温层的成型工艺

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