EP2532769A1 - Procédé de production dune couche de conversion sur une surface dune bande d'aluminium ou d'alliage d'aluminium - Google Patents

Procédé de production dune couche de conversion sur une surface dune bande d'aluminium ou d'alliage d'aluminium Download PDF

Info

Publication number
EP2532769A1
EP2532769A1 EP11004742A EP11004742A EP2532769A1 EP 2532769 A1 EP2532769 A1 EP 2532769A1 EP 11004742 A EP11004742 A EP 11004742A EP 11004742 A EP11004742 A EP 11004742A EP 2532769 A1 EP2532769 A1 EP 2532769A1
Authority
EP
European Patent Office
Prior art keywords
strip
acid
solution
treatment
conversion coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP11004742A
Other languages
German (de)
English (en)
Inventor
Jürg Lutz
René Segerer
Hans Schlager
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Amcor Flexibles Kreuzlingen AG
Original Assignee
Amcor Flexibles Kreuzlingen AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Amcor Flexibles Kreuzlingen AG filed Critical Amcor Flexibles Kreuzlingen AG
Priority to EP11004742A priority Critical patent/EP2532769A1/fr
Priority to ES12725321.9T priority patent/ES2668270T3/es
Priority to PCT/EP2012/002324 priority patent/WO2012167889A1/fr
Priority to PL12725321T priority patent/PL2718479T3/pl
Priority to EP12725321.9A priority patent/EP2718479B1/fr
Publication of EP2532769A1 publication Critical patent/EP2532769A1/fr
Priority to HRP20180845TT priority patent/HRP20180845T1/hr
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/82After-treatment
    • C23C22/83Chemical after-treatment
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/02Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using non-aqueous solutions
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/34Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/40Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates
    • C23C22/44Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates containing also fluorides or complex fluorides
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/73Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/73Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
    • C23C22/74Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process for obtaining burned-in conversion coatings
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/73Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
    • C23C22/76Applying the liquid by spraying

Definitions

  • the invention relates to a method of producing an aluminium or aluminium alloy strip with a heat-seal lacquer on a first surface and an epoxide based stove lacquer on the second surface.
  • the invention relates to the preparation of cleaned surfaces with good adhesion properties of the aforementioned organic coatings on aluminium or aluminium alloy strips intended for the manufacturing of lacquered and deep-drawn capsules closed with a heat-sealed membrane lid for packaging portions of coffee.
  • rinse and no-rinse processes are generally known in the chemical treatment of metal surfaces, for example for the subsequent application of paints, adhesives and/or plastics.
  • the metal surfaces are freed from oil, dirt and other residues in a first stage. Any residues of chemicals from this first stage are removed by rinsing with water.
  • the clean metal surface is wetted with an aqueous bath solution which is rinsed off.
  • the non-rinse process the clean metal surface is wetted with an aqueous bath solution which is not rinsed off, but instead is dried in situ on the metal surface and, in the process, is converted into a solid film of the bath ingredients.
  • Coatings such as these can significantly improve the surface quality of covering layers subsequently applied, particularly with respect to corrosion control and adhesion.
  • treatment solutions containing hexavalent chromium (“yellow chromating") were often proposed in the extensive relevant prior art literature.
  • hexavalent chromium yellow chromating
  • these processes or rather the rinsing waters accumulating therein require expensive wastewater treatment.
  • Even processes which only use trivalent chromium were not entirely satisfactory on account of increasing demands for the complete absence of chromium.
  • EP-A-0 008 942 discloses treatment solutions, preferably for aluminum cans, containing:
  • DE-C-24 33 704 describes treatment baths for increasing paint adhesion and permanent protection against corrosion inter alia on aluminum which may contain from 0.1 to 5 g/I of polyacrylic acid or salts or esters thereof and 0.1 to 3.5 g/I of ammonium fluorozirconate, expressed as ZrO 2 .
  • US-A-4,992,116 describes treatment baths for the conversion treatment of aluminum with pH values of around 2.5 to 5 which contain at least three components, namely:
  • WO-A-92/07973 describes a chromium-free treatment process for aluminum which uses 0.01 to around 18% by weight of H 2 ZrF 6 and 0.01 to around 10% by weight of a 3-(N-C 1-4 -alkyl-N-2-hydroxyethylaminomethyl)-4-hydroxystyrene polymer as essential components in the form of an acidic aqueous solution.
  • DE-A-43 17 217 describes a process for the pretreatment of surfaces of aluminum or its alloys before a second conversion treatment for permanent corrosion control, in which the surfaces are contacted with acidic aqueous treatment solutions which contain complex fluorides of the elements boron, silicon, titanium, zirconium or hafnium either individually or in admixture with one another in concentrations of the fluoroanions of, in total, 100 to 4,000 and preferably 200 to 2,000 mg/l and which have a pH value of 0.3 to 3.5 and preferably in the range from 1 to 3.
  • the treatment solutions may additionally contain polymers of the polyacrylate type and/or in the form of reaction products of poly(vinylphenol) with aldehydes and organic hydroxyfunctional amines in concentrations below 500 mg/l and preferably below 200 mg/l.
  • Phosphoric acid is another optional constituent of these baths.
  • US-A-4,136,073 claims a chromium-free treatment process for aluminum surfaces, in which the surfaces are contacted with acidic (pH 1.2 to 5.5) aqueous solutions containing an organic film former and a soluble titanium compound in a ratio by weight of polymer to titanium of 100:1 to 1 :10.
  • the preferred titanium concentration is between 0.01 and 5% by weight.
  • US-A-5,868872 discloses a chromium-free process for the no-rinse treatment of aluminium and its alloys and aqueous bath solutions suitable for this process. The surfaces are contacted with solutions containing:
  • An object of the present invention is to provide a method of the type mentioned at the beginning with a good adhesion of the aluminium or aluminium alloy strip with a heat-seal lacquer on a first surface and an epoxide based stove lacquer on the second surface and the epoxide based stove lacquer without the need of a Cr(III) conversion coating.
  • the aluminium or aluminium alloy strip manufactured with the method according to the present invention shall be qualified for the manufacture of deep-drawn capsules for packaging portions of coffee, the capsules having a heat-seal lacquer on the inner surface of the capsule and an epoxide based coloured stove lacquer on the outer surface of the capsule.
  • a further object is to provide a method of producing a chromium-free conversion coating on a surface of an aluminium or aluminium alloy strip in a continuous production line, the chromium-free conversion coating having good adhesion properties of a heat-seal lacquer on a first surface and an epoxide based stove lacquer on the second surface of the aluminium or aluminium alloy strip intended for the manufacturing of lacquered and deep-drawn capsules closed with a heat-sealed membrane lid for packaging portions of coffee.
  • the first of the aforementioned objectives is achieved by way of the invention in that a chromium-free conversion coating is produced on the first and second surface of the aluminium or aluminium alloy strip in a continuous production line before applying the heat-seal lacquer and the stove lacquer, the chromium-free conversion coating is produced by
  • the method comprises the steps of continuous uncoiling of a rolled aluminium or aluminium alloy strip from a first coil; continuous annealing of the uncoiled strip; continuous cleaning and degreasing of the surface of the annealed strip; continuous washing of the cleaned and degreased surface of the strip; continuous pickling of the surface of the washed strip; continuous washing of the surface of the pickled strip; drying of the surface of the washed strip; continuous production of a chromium-free conversion coating on the surface of the dried conversion coated strip by
  • Cleaning and degreasing is preferably made by spraying the strip with an aqueous solution of 5 to 50 g/I, preferably 15 to 25 g/I, of an initial solution comprising 0.10 to 1.0 wt.% bisoctyl dimethyl ammonium chloride, 5 to 10 wt.-% potassium hydroxide, 5 to 10 wt.-% phosphate (P) and ⁇ 5 wt.-% cationic tenside.
  • pickling is preferably made by spraying the strip with an aqueous solution of 5 to 50 g/I, preferably 15 to 25 g/I, of an initial solution comprising 65 to 80 wt.-% ortho phosphoric acid.
  • pickling is preferably made by spraying the strip with an aqueous solution of 5 to 30 g/l, preferably 8 to 15 g/I, of a first initial solution comprising 25 to 50 wt.-% sulphuric acid and 5 to 15 wt.-% non ionic tenside, and 0.1 to 10 g/l, preferably 1 to 3 g/I, of a second initial solution comprising 5 to 7 wt.-% hydrofluoric acid.
  • the conversion coating is preferably made by spraying the strip with a solution of 50 to 200 g/l, preferably 80 to 120 g/l, of an initial solution comprising silane and 10 to 25 wt.-% ethanol.
  • the conversion coating is preferably made by spraying the strip with an aqueous solution of 10 to 160 g/l, preferably 30 to 50 g/I, of a first initial solution comprising 5 to 10 wt.-% hexafluorotitanic acid and 2.5 to 5 wt.-% hexafluorozirconic acid, and 1 to 10 g/l, preferably 7 to 9 g/I, of a second initial solution comprising 20 to 21 wt.-% silica.
  • the conversion coating is preferably made by spraying the strip with an aqueous solution of 5 to 50 g/l, preferably 15 to 25 g/I, of a first initial solution comprising ⁇ 1 wt.-% diammonium dimolybdate and 5 to 10 wt.-% hexafluorozirconic acid, and 0.01 to 0.3 g/l, preferably 0.1 to 0.3 g/I, of a second initial solution comprising 10 to 25 wt.-% ammonium fluoride and 10 to 25 wt.-% ammonium hydrogen difluoride.
  • the conversion coating is preferably made by spraying the strip with an aqueous solution of 5 to 50 g/l, preferably 15 to 25 g/I, of a first initial solution comprising ⁇ 1 wt.-% diammonium dimolybdate and 5 to 10 wt.-% hexafluorozirconic acid, and 0.01 to 0.3 g/l, preferably 0.1 to 0.3 g/l, of a second initial solution comprising 10 to 25 wt.-% ammonium fluoride and 10 to 25 wt.-% ammonium hydrogen difluoride, and 0 to 2 g/I, preferably 0.05 to 0.2 g/I, of a third initial solution comprising 25 wt.-% polycarboxylic acid in water.
  • a conventionally cleaned and rinsed metal surface after rinsing with deionized water and drying and/or removal of the water film by squeegees, is wetted in any manner with the solution of silanes in the polar organic solvent aqueous treatment solution in such a quantity that around 2 to 20 ml and preferably around 5 to 10 ml of the polar organic treatment solution are applied per square meter of surface area.
  • the treatment solutions in the preferred no rinse process according to the invention may be applied to the precleaned metal strips by any method which is capable of producing a uniform, defined liquid film on the metal surface in the quantity ranges indicated.
  • the roller application process using two to four rollers (“chemcoater”) has proved to be particularly effective, although wetting of the strip by spraying or immersion and subsequent removal of the excess liquid film, for example by plastic-coated equalizing rollers or an adjustable air knife, is also suitable.
  • the temperature of the treatment solution may be in the range from 15°C to 30°C and is preferably in the range from 20°C to 25°C.
  • the liquid film applied to the metal surface is allowed to react thereon for about 1 to 40 seconds, after which the film is dried and heat-treated at elevated temperature.
  • the process steps of contact with the metal surface and drying may also be combined.
  • a formable, water-insoluble solid film with a weight per unit area of around 5 to 50 mg Si/m 2 and preferably around 10 to 30 mg Si/m 2 is left on the metal surface.
  • the drying and/or heat treatment of the liquid film applied to the metal surface, or rather of the chemicals applied with it, may be carried out at temperatures of around 80°C to 140°C, temperatures in the range from 110°C to 120°C being preferred.
  • Both acidic and alkaline cleaners are suitable for the cleaning pretreatment of the metal surfaces to be wetted in accordance with the invention.
  • the layers obtained with the treatment solution according to the invention provide a uniform finish of the substrate. In combination with suitable organic coatings subsequently applied, they satisfy the requirements of the food packaging industry.
  • the following example relates to a no-rinse process with a conversion coating by treatment with a solution of silanes in ethanol.

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Cookers (AREA)
EP11004742A 2011-06-10 2011-06-10 Procédé de production dune couche de conversion sur une surface dune bande d'aluminium ou d'alliage d'aluminium Withdrawn EP2532769A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP11004742A EP2532769A1 (fr) 2011-06-10 2011-06-10 Procédé de production dune couche de conversion sur une surface dune bande d'aluminium ou d'alliage d'aluminium
ES12725321.9T ES2668270T3 (es) 2011-06-10 2012-06-01 Método para producir una tira de aluminio o aleación de aluminio con una laca de termosellado sobre una primera superficie y una laca al horno sobre la segunda superficie previamente revestida con un revestimiento de conversión libre de cromo
PCT/EP2012/002324 WO2012167889A1 (fr) 2011-06-10 2012-06-01 Procédé de production d'une bande d'aluminium ou d'alliage d'aluminium dotée d'une laque de thermoscellage sur une première surface et d'une laque cuite au four à base d'époxyde sur la seconde surface préalablement revêtue d'une couche de conversion exempte de chrome
PL12725321T PL2718479T3 (pl) 2011-06-10 2012-06-01 Sposób wytwarzania pasków z aluminium lub stopów aluminium, z lakierem termoutwardzalnym na pierwszej powierzchni i lakierem piecowym na bazie epoksydowej na drugiej powierzchni, uprzednio pokrytymi bezchromową powłoką modyfikującą
EP12725321.9A EP2718479B1 (fr) 2011-06-10 2012-06-01 Procédé de production d'une bande d'aluminium ou d'alliage d'aluminium dotée d'une laque de thermoscellage sur une première surface et d'une laque cuite au four à base d'époxyde sur la seconde surface préalablement revêtue d'une couche de conversion exempte de chrome
HRP20180845TT HRP20180845T1 (hr) 2011-06-10 2018-05-28 Postupak proizvodnje aluminijskih traka ili traka od aluminijskih legura s vruće lijepljenim lakom na prvoj površini te s paljenim lakom na bazi epoksida na drugoj površini, koje su prethodno obložene konverzijskim slojem bez kroma

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP11004742A EP2532769A1 (fr) 2011-06-10 2011-06-10 Procédé de production dune couche de conversion sur une surface dune bande d'aluminium ou d'alliage d'aluminium

Publications (1)

Publication Number Publication Date
EP2532769A1 true EP2532769A1 (fr) 2012-12-12

Family

ID=44904600

Family Applications (2)

Application Number Title Priority Date Filing Date
EP11004742A Withdrawn EP2532769A1 (fr) 2011-06-10 2011-06-10 Procédé de production dune couche de conversion sur une surface dune bande d'aluminium ou d'alliage d'aluminium
EP12725321.9A Active EP2718479B1 (fr) 2011-06-10 2012-06-01 Procédé de production d'une bande d'aluminium ou d'alliage d'aluminium dotée d'une laque de thermoscellage sur une première surface et d'une laque cuite au four à base d'époxyde sur la seconde surface préalablement revêtue d'une couche de conversion exempte de chrome

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP12725321.9A Active EP2718479B1 (fr) 2011-06-10 2012-06-01 Procédé de production d'une bande d'aluminium ou d'alliage d'aluminium dotée d'une laque de thermoscellage sur une première surface et d'une laque cuite au four à base d'époxyde sur la seconde surface préalablement revêtue d'une couche de conversion exempte de chrome

Country Status (5)

Country Link
EP (2) EP2532769A1 (fr)
ES (1) ES2668270T3 (fr)
HR (1) HRP20180845T1 (fr)
PL (1) PL2718479T3 (fr)
WO (1) WO2012167889A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103230347A (zh) * 2013-05-03 2013-08-07 杨松涛 多效免冲洗浴液及其制备方法
EP2826569A1 (fr) 2013-07-16 2015-01-21 ThyssenKrupp Rasselstein GmbH Procédé de passivation de tôle noire en forme de bande
EP3133187A1 (fr) 2015-08-21 2017-02-22 ThyssenKrupp Rasselstein GmbH Procede de traitement thermique d'une tole noire revetue d'une couche de conversion
WO2017046139A1 (fr) * 2015-09-15 2017-03-23 Chemetall Gmbh Prétraitement de surfaces en aluminium avec des compositions contenant du zircon et du molybdène

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2611610C2 (ru) * 2012-08-29 2017-02-28 Ппг Индастриз Огайо, Инк. Циркониевые композиции предварительной обработки, содержащие молибден, соответствующие способы обработки металлических субстратов и соответствующие металлические субстраты с покрытиями
US20170081569A1 (en) 2014-05-27 2017-03-23 Amcor Flexibles Rorschach Ag Heat-Sealable Structure for Aluminum Disposable Beverage-Brewing Containers
CA3034712C (fr) 2016-08-24 2021-10-12 Ppg Industries Ohio, Inc. Composition alcaline destine au traitement de substrats metalliques
US20200164403A1 (en) 2017-06-26 2020-05-28 Actega Rhenania Gmbh Process for applying a multicolour coating on a metal or metal alloy foil
EP3898857B1 (fr) 2018-12-21 2022-10-19 ACTEGA Rhenania GmbH Composition pour l'application d'un revêtement multicouche sur un substrat
CN110373661B (zh) * 2019-07-31 2021-05-28 首钢京唐钢铁联合有限责任公司 一种镀锡板钝化液及钝化工艺

Citations (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4136073A (en) 1974-12-25 1979-01-23 Oxy Metal Industries Corporation Process for treating an aluminum surface
EP0008942A1 (fr) 1978-09-06 1980-03-19 Amchem Products, Inc. a Corporation organised under the Laws of the State of Delaware United States of America Compositions et procédés pour revêtir de l'aluminium
DE2433704C3 (de) 1973-07-13 1981-05-21 Amchem Products, Inc.,(n.d.Ges.d. Staates Delaware), Ambler, Pa. Verwendung von Zirkonverbindungen und Polyacrylsäure enthaltenden wäßrigen Dispersionen zur Behandlung von Metallflächen
US4921552A (en) 1988-05-03 1990-05-01 Betz Laboratories, Inc. Composition and method for non-chromate coating of aluminum
US4992116A (en) 1989-04-21 1991-02-12 Henkel Corporation Method and composition for coating aluminum
WO1992007973A1 (fr) 1990-11-02 1992-05-14 Henkel Corporation Composition amelioree exempte de chrome et procede pour traitements resistants a la corrosion appliques a des surfaces d'aluminium
US5129967A (en) 1988-05-03 1992-07-14 Betz Laboratories, Inc. Composition and method for non-chromate coating of aluminum
DE4317217A1 (de) 1993-05-24 1994-12-01 Henkel Kgaa Chromfreie Konversionsbehandlung von Aluminium
US5868872A (en) 1994-04-08 1999-02-09 Henkel Kommanditgesellschaft Auf Aktien Chromium-free process for the no-rinse treatment of aluminum and its alloys and aqueous bath solutions suitable for this process
US6346295B1 (en) * 1997-08-06 2002-02-12 Henkel Kommanditgesellschaft Auf Aktien Alkaline strip passivation
US20040062873A1 (en) * 2000-10-11 2004-04-01 Christian Jung Method for pretreating and/or coating metallic surfaces with a paint-like coating prior to forming and use of substrates coated in this way
EP1859926A1 (fr) * 2006-05-26 2007-11-28 Borealis Technology Oy Tyau revétu avec une couche comprenant un polyoféfine avec adhérence améliorée
EP2048203A1 (fr) * 2007-10-12 2009-04-15 Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. Revêtement d'inhibition de corrosion pour protection de corrosion active des surfaces métalliques comportant un complexe d'inhibiteur de type sandwich
US20090214883A1 (en) * 2006-08-24 2009-08-27 Ard De Zeeuw Chromium-free, thermally curable corrosion protection composition
US20100055327A1 (en) * 2006-11-22 2010-03-04 Bs Coatings Sas Method for Applying an Anti-Corrosion Coating on Parts of a Duct Including the Use of a Silane Aqueous Solution and an Epoxy Powdery Paint

Patent Citations (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2433704C3 (de) 1973-07-13 1981-05-21 Amchem Products, Inc.,(n.d.Ges.d. Staates Delaware), Ambler, Pa. Verwendung von Zirkonverbindungen und Polyacrylsäure enthaltenden wäßrigen Dispersionen zur Behandlung von Metallflächen
US4136073A (en) 1974-12-25 1979-01-23 Oxy Metal Industries Corporation Process for treating an aluminum surface
EP0008942A1 (fr) 1978-09-06 1980-03-19 Amchem Products, Inc. a Corporation organised under the Laws of the State of Delaware United States of America Compositions et procédés pour revêtir de l'aluminium
US5129967A (en) 1988-05-03 1992-07-14 Betz Laboratories, Inc. Composition and method for non-chromate coating of aluminum
US4921552A (en) 1988-05-03 1990-05-01 Betz Laboratories, Inc. Composition and method for non-chromate coating of aluminum
US4992116A (en) 1989-04-21 1991-02-12 Henkel Corporation Method and composition for coating aluminum
WO1992007973A1 (fr) 1990-11-02 1992-05-14 Henkel Corporation Composition amelioree exempte de chrome et procede pour traitements resistants a la corrosion appliques a des surfaces d'aluminium
DE4317217A1 (de) 1993-05-24 1994-12-01 Henkel Kgaa Chromfreie Konversionsbehandlung von Aluminium
US5868872A (en) 1994-04-08 1999-02-09 Henkel Kommanditgesellschaft Auf Aktien Chromium-free process for the no-rinse treatment of aluminum and its alloys and aqueous bath solutions suitable for this process
US6346295B1 (en) * 1997-08-06 2002-02-12 Henkel Kommanditgesellschaft Auf Aktien Alkaline strip passivation
US20040062873A1 (en) * 2000-10-11 2004-04-01 Christian Jung Method for pretreating and/or coating metallic surfaces with a paint-like coating prior to forming and use of substrates coated in this way
EP1859926A1 (fr) * 2006-05-26 2007-11-28 Borealis Technology Oy Tyau revétu avec une couche comprenant un polyoféfine avec adhérence améliorée
US20090214883A1 (en) * 2006-08-24 2009-08-27 Ard De Zeeuw Chromium-free, thermally curable corrosion protection composition
US20100055327A1 (en) * 2006-11-22 2010-03-04 Bs Coatings Sas Method for Applying an Anti-Corrosion Coating on Parts of a Duct Including the Use of a Silane Aqueous Solution and an Epoxy Powdery Paint
EP2048203A1 (fr) * 2007-10-12 2009-04-15 Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. Revêtement d'inhibition de corrosion pour protection de corrosion active des surfaces métalliques comportant un complexe d'inhibiteur de type sandwich

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103230347A (zh) * 2013-05-03 2013-08-07 杨松涛 多效免冲洗浴液及其制备方法
EP2826569A1 (fr) 2013-07-16 2015-01-21 ThyssenKrupp Rasselstein GmbH Procédé de passivation de tôle noire en forme de bande
DE102013107506A1 (de) 2013-07-16 2015-01-22 Thyssenkrupp Rasselstein Gmbh Verfahren zur Passivierung von bandförmigem Schwarzblech
EP3133187A1 (fr) 2015-08-21 2017-02-22 ThyssenKrupp Rasselstein GmbH Procede de traitement thermique d'une tole noire revetue d'une couche de conversion
DE102015113878A1 (de) 2015-08-21 2017-02-23 Thyssenkrupp Ag Verfahren zur thermischen Behandlung eines mit einer Konversionsschicht beschichteten Schwarzblechs
US10550479B2 (en) 2015-08-21 2020-02-04 Thyssenkrupp Rasselstein Gmbh Method of thermally treating black plate coated with a conversion coating
DE102015113878B4 (de) 2015-08-21 2023-03-16 Thyssenkrupp Ag Verfahren zur thermischen Behandlung eines mit einer Konversionsschicht beschichteten Schwarzblechs
WO2017046139A1 (fr) * 2015-09-15 2017-03-23 Chemetall Gmbh Prétraitement de surfaces en aluminium avec des compositions contenant du zircon et du molybdène

Also Published As

Publication number Publication date
EP2718479B1 (fr) 2018-03-14
PL2718479T3 (pl) 2018-10-31
ES2668270T3 (es) 2018-05-17
HRP20180845T1 (hr) 2018-09-07
WO2012167889A1 (fr) 2012-12-13
EP2718479A1 (fr) 2014-04-16

Similar Documents

Publication Publication Date Title
EP2718479B1 (fr) Procédé de production d'une bande d'aluminium ou d'alliage d'aluminium dotée d'une laque de thermoscellage sur une première surface et d'une laque cuite au four à base d'époxyde sur la seconde surface préalablement revêtue d'une couche de conversion exempte de chrome
EP1440186B1 (fr) Post-traitement d'aluminium anodise
US5868872A (en) Chromium-free process for the no-rinse treatment of aluminum and its alloys and aqueous bath solutions suitable for this process
US6203854B1 (en) Methods of and compositions for preventing corrosion of metal substrates
AU2008248694B2 (en) Preliminary metallizing treatment of zinc surfaces
EP1404894B1 (fr) Revetement anti-corrosion pour aluminium et alliages d'aluminium
US20070017602A1 (en) Two-stage conversion treatment
US9738790B2 (en) Process for forming corrosion protection layers on metal surfaces
EP1368507B1 (fr) Procede de traitement d'articles polymetalliques
US5801217A (en) Chromium-free conversation coating and methods of use
US6521029B1 (en) Pretreatment for aluminum and aluminum alloys
US8557096B2 (en) Multistage method for treating metal surfaces prior to dip painting
EP3301205B1 (fr) Composition aqueuse acide pour préparer un revêtement résistant à la corrosion sur un substrat métallique, procédé de traitement d'un substart métallique en utilisant la composition
CA2373089A1 (fr) Traitement prealable de surfaces d'aluminium a l'aide de solutions exemptes de chrome
JP2018035445A (ja) 金属基体用の洗浄組成物
KR20180053306A (ko) 지르코늄- 및 몰리브데넘-함유 조성물로의 알루미늄 표면의 전처리
JPH07126859A (ja) アルミニウム及びアルミニウム合金用6価クロムフリーの化成表面処理剤
JP2000144444A (ja) 耐食性に優れた表面処理鋼板の製造方法
US6200693B1 (en) Water-based liquid treatment for aluminum and its alloys
JPH11335863A (ja) 耐食性に優れた表面処理鋼板の製造方法
AU744557B2 (en) Water-based liquid treatment for aluminum and its alloys
KR102278974B1 (ko) 다단계 전착 방법
JPH11335862A (ja) 耐食性に優れた表面処理鋼板の製造方法
AU724978C (en) Method and compositions for preventing corrosion of metal substrates
JP2002220678A (ja) 熱間圧延鋼板又は鋼材の処理方法及び熱間圧延鋼板又は鋼材

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 20130613