EP2414106B1 - Chromfreie metallische beschichtung, verfahren zu deren herstellung und verbunddraht - Google Patents

Chromfreie metallische beschichtung, verfahren zu deren herstellung und verbunddraht Download PDF

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Publication number
EP2414106B1
EP2414106B1 EP10756469.2A EP10756469A EP2414106B1 EP 2414106 B1 EP2414106 B1 EP 2414106B1 EP 10756469 A EP10756469 A EP 10756469A EP 2414106 B1 EP2414106 B1 EP 2414106B1
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weight
range
aluminum
silicon
nickel
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French (fr)
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EP2414106A1 (de
EP2414106A4 (de
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Michael W. Seitz
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General Electric Technology GmbH
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General Electric Technology GmbH
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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06—Metallic material
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06—Metallic material
    • C23C4/067—Metallic material containing free particles of non-metal elements, e.g. carbon, silicon, boron, phosphorus or arsenic
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
    • C23C4/131—Wire arc spraying

Definitions

  • This invention relates to chrome-free metal coating compositions and thermal spray wires for producing same.
  • CH 311 869 discloses an alloy composition for use as a magnet.
  • DE 102 59 141 discloses material systems for coating.
  • DE 43 28 732 discloses a process and material for producing a thermally sprayed layer.
  • GB 2 250 030 discloses wire compositions for use in metal spraying.
  • US 2009/0032501 discloses abrasion-resistant weld overlay compositions.
  • US 2008/0098926 discloses composite wires for coating substrates.
  • US 2006/0078749 discloses composite materials.
  • a chromium-free metallic coating precursor in one embodiment of the invention, according to claim 1, there is provided a chromium-free metallic coating precursor.
  • the precursor is provided in the form of a composite wire.
  • a chromium-free metallic coating as can be made from the wire.
  • the chromium-free metallic coating precursor comprises a base metal constituent, a silicon constituent, a titanium constituent, and a boron constituent.
  • the base metal constituent is present in amount of at least 54% by weight.
  • the base metal constituent comprises at least one base metal selected from the group consisting of iron, nickel, cobalt, lead, zinc, copper, tin, and aluminum and always comprises at least 1 % by weight of aluminum, based on mass of the coating precursor.
  • the silicon, titanium and boron constituents are each present in amount between 1 % and 15% by weight.
  • the above constituents are provided in a composite wire in accordance with another embodiment of the invention.
  • the composite wire comprises a metallic outer sheath in the range of 70 to 95% by weight and an inner core of particles in the range of 5 to 30% by weight.
  • the metallic outer sheath comprises at least 70 weight percent of a base metal readily capable of being rolled and drawn into the sheath and comprising at least one of nickel, iron and cobalt, and at least 2 weight percent alloyed aluminum and/or silicon.
  • the inner core of particles comprises, by weight percent, in the range of 15% to 30% titanium, in the range of 15% to 35% silicon, in the range of 20% to 50% boron, and in the range of 0% to 15% carbon.
  • the composite wire is applied by thermal spray technique to produce the metallic chrome-free coating of the invention on a substrate.
  • the chrome-free coating composition usually comprises, in bulk on a weight basis, 70% to 90% of base metal, at least 2% aluminum, 2 to 10% titanium, 2 to 10% silicon, and 2 to 10% boron.
  • the coating is high temperature wear and corrosion resistant.
  • the drawing illustrates pictorially a composite wire in accordance with an embodiment of the invention.
  • the chromium-free metallic coating precursor comprises a base metal constituent, a silicon constituent, a titanium constituent, and a boron constituent, in alloy, mixture or composite form.
  • the base metal constituent is present in amount of at least 54% by weight.
  • the base metal constituent comprises at least one base metal selected the group consisting of iron, nickel, cobalt, lead, zinc, copper, tin, and aluminum and always comprises at least about 1% by weight of aluminum, based on mass of the coating precursor.
  • the silicon, titanium and boron constituents are each present in amount between about 1% and about 15% by weight.
  • the base metal is present in an amount of at least 68% by weight and contains an aluminum and/or silicon component alloyed therein in an amount of at least 2% by weight, based on mass of coating precursor.
  • the silicon, titanium and boron are preferably each present in amount between 2% and 10 percent by weight.
  • the base metal constituent is present in an amount of at least 76% by weight and is selected from at least one of iron, nickel, cobalt, and aluminum.
  • the base metal constituent is a mixture or an alloy, preferably an alloy, and always preferably comprises at least 3% by weight of aluminum, based on mass of coating precursor.
  • the silicon, titanium and boron may be present, preferably as a mass in particle form, in amount between 4% and 7%, preferably as the inside of a composite wire formed from the base metal constituent.
  • the coatings of the present invention can be formed from composite wires as described herein by feeding the wires through a conventional arc spraying apparatus.
  • the composite wire 10 comprises a metallic outer sheath 20 in the range of 70 to 95% by weight and an inner core 30 in the range of 5 to 30% by weight.
  • the composite wire comprises a metallic outer sheath in the range of 75 to 85% by weight and an inner core in the range of 15 to 25% by weight.
  • the metallic outer sheath comprises at least 70 weight percent of a base metal readily capable of being rolled and drawn into the sheath and at least 2 weight percent alloyed aluminum and/or silicon.
  • Aluminum can also be employed exclusively as the base metal.
  • the inner core comprises in the range of 15% to 30% titanium, in the range of 15% to 35% silicon, in the range of 20% to 50% boron, and in the range of 0% to 15% carbon, all in particle, preferably powdered, mixture form.
  • the titanium, silicon and boron may be present as a mixture of compounds containing additional elements.
  • the base metal is a relatively soft elemental metal or alloy, comprising at least one of nickel, iron, or cobalt.
  • Nickel is preferred, and the outer sheath most preferably comprises an alloy of nickel and aluminum.
  • Exemplary materials may comprise in the range of 70 to 98 percent by weight of nickel and in the range of 2 to 30 percent by weight of alloyed aluminum and/or silicon, preferably in the range of 85 to 98 percent by weight of nickel and in the range of 2 to 15 percent by weight alloyed aluminum and/or silicon, and most preferably 90 to 97 percent by weight of nickel and in the range of 3 to 10 percent by weight of alloyed aluminum.
  • the inner core preferably comprises in the range of 20% to 30% titanium, in the range of 20% to 30% silicon, in the range of 30% to 40% boron, and in the range of 0% to 15% carbon.
  • Carbon generally in the form of carbides, can be present if desired in the inner core, but since it is probably not present in the coating composition, at least in amounts which contribute properties, it is not considered material to the coating invention.
  • the titanium and silicon can be provided by a suitable amount of a TiSi source, for example, in the range of 50 to 60% of a TiSi source such as TiSiFe in admixture with a source of boron and optional carbon, for example, B 4 C in an amount of 40 to 50%.
  • the inner core may also contain additional materials.
  • the additional materials may include: carbides, such as tungsten carbide, titanium carbide, vanadium carbide, and the like; oxides, such as aluminum oxide, zirconium oxide, and the like; and borides, such as nickel boride, iron boride, and the like.
  • the inner core may also include additional metal powders, such as aluminum, nickel, or alloy powder, or composite powders, such as tungsten carbide nickel.
  • the inner core can include in the range of 0.1 to 10% molybdenum, 0.1 to 10% tungsten, 0.1 to 10% neodymium, and 0.1 to 10% carbon.
  • metal or metal alloy powders comprising magnesium, phosphorus, vanadium, manganese, iron, cobalt, nickel, copper, zirconium, niobium, molybdenum, tantalum and/or tungsten may be present in the inner core, for example, in the range of 0.1 to 10%.
  • the core components listed above can be alloyed into the sheath, and where this is done, the constituent need not be present in the inner core, or it can be present in a reduced amount.
  • the constituent need not be present in the inner core, or it can be present in a reduced amount.
  • titanium, silicon and boron can be alloyed in the sheath in the amount of 2 to 10% by weight, based on weight of the composite wire.
  • the aluminum component may be present in the inner core, rather than the sheath.
  • the grain size of the powdered inner core will have an effect on the physical properties of the applied coating. Generally, the finer the grains of the powder, the more homogenous the coating will be and generally the better the wear and corrosion properties. However, acquisition costs and manufacturing constraints will limit the lower end of the grain size range.
  • the cored wires may be formed in a conventional manner by placing the mix for forming the inner core, which need not be an agglomerated mix, onto the strip to be made into the outer metallic sheath.
  • the strip can be drawn continuously through a plurality of wire drawing dies to form an outer wire sheath around an inner core.
  • the final outer diameter of the cored wire will depend upon the application for which it is used. For most applications, the cored wire final diameter ranges between about 0.8 mm and about 6.4 mm.
  • Conventional cored wire manufacturing techniques are disclosed in U.S. Patent Nos. 6,156,443 (Dallaire et al. ) and 6,513,728 (Hughes et al. ), both being hereby incorporated by reference.
  • a method of forming a wear resistant and corrosion resistant coating on a substrate is also provided.
  • the method generally includes the steps of providing a composite wire according to an embodiment of the invention and coating a substrate by employing the composite wire in conjunction with thermal spraying techniques to form a fused metallic coating.
  • the inventive wire is not weldable by commonly available techniques, so non-welding methods must be used to form the fused coating.
  • the resulting fused metallic chrome-free coating composition comprises, in bulk on a weight basis, 70% to 90% of base metal, at least 2% aluminum, 2 to 10% titanium, 2 to 10% silicon, and 2 to 10% boron.
  • the base metal is preferably selected from the group consisting of at least one of nickel, iron and cobalt, most preferably nickel.
  • the coating can contain additional constituents if desired, for example, additional constituents selected from the group consisting of 0.1 to 10% iron, 0.1 to 10% molybdenum, 0.1 to 10% tungsten, and 0 to 10% carbon.
  • the coatings according to the present invention are specifically designed for articles subjected to wear and/or corrosion.
  • Such articles include, for example, boiler tubes, hydraulic piston rods, pump casings, rollers in the paper and steel industry, wear plates, journals and shafts, and turbine blades and casings.
  • the coatings are designed to protect boiler tubes against erosion-corrosion related wastage and are applied to the boiler tubes by means of a conventional arc spraying apparatus.
  • arc spraying apparatus employing wires as the feed material.
  • Arc spraying methods and apparatus are well documented in the art, see for example, U.S. Pat. Nos. 6,156,443 (Dallaire, et al. ); 5,837,326 (Dallaire, et al. ); and European Patent No. EP 0 522 438 (Zurecki et al. ) the disclosures of which are incorporated by reference.
  • a composite wire was formed according to the following composition.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Coating By Spraying Or Casting (AREA)
  • Nonmetallic Welding Materials (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Claims (17)

  1. Chromfreier metallischer Beschichtungsvorläufer, umfassend
    zu mindestens 54 Gew.-% mindestens ein Grundmetall, ausgewählt aus der Gruppe bestehend aus Eisen, Nickel, Kobalt, Blei, Zink, Kupfer, Zinn und Aluminium, wobei der Beschichtungsvorläufer immer zu mindestens 1 Gew.-% Aluminium, zu zwischen 1 Gew.-% und 15 Gew.-% Silicium, zu zwischen 1 Gew.-% und 15 Gew.-% Titan und zu zwischen 1 Gew.-% und 15 Gew.-% Bor umfasst.
  2. Chromfreier metallischer Beschichtungsvorläufer nach Anspruch 1, umfassend zu mindestens 68 Gew.-% mindestens ein Grundmetall, ausgewählt aus der Gruppe bestehend aus Eisen, Nickel, Kobalt, Blei, Zink, Kupfer, Zinn und Aluminium, wobei das Grundmetall immer zu mindestens 2 Gew.-% legiertes Aluminium und/oder Silicium, zu zwischen 2 Gew.-% und 10 Gew.-% Silicium, zu zwischen 2 Gew.-% und 10 Gew.-% Titan und zu zwischen 2 Gew.-% und 10 Gew.-% Bor umfasst.
  3. Chromfreier metallischer Beschichtungsvorläufer nach Anspruch 1, umfassend zu mindestens 76 Gew.-% von mindestens ein Grundmetall, ausgewählt aus der Gruppe bestehend aus Eisen, Nickel, Kobalt und Aluminium, wobei das Grundmetall immer zu mindestens 3 Gew.-% legiertes Aluminium, zu zwischen 3 Gew.-% und 7 Gew.-% Silicium, zu zwischen 3 Gew.-% und 7 Gew.-% Titan und zu zwischen 3 Gew.-% und 7 Gew.-% Bor umfasst.
  4. Chromfreier metallischer Beschichtungsvorläufer nach Anspruch 1, umfassend eine Legierung aus Nickel, Eisen und/oder Kobalt mit Aluminium und eine Masse aus silicium-, titan- und borhaltigen Teilchen.
  5. Geschmolzene chromfreie metallische Beschichtungszusammensetzung, umfassend in Masse auf Gewichtsbasis zu 70 Gew.-% bis 90 Gew.-% mindestens ein Grundmetall, ausgewählt aus der Gruppe bestehend aus Eisen, Nickel, Kobalt, Blei, Zink, Zinn und Aluminium, wobei die metallische Beschichtungszusammensetzung immer zu mindestens 2 Gew.-% Aluminium, zu 2 Gew.-% bis 10 Gew.-% Titan, zu 2 Gew.-% bis 10 Gew.-% Silicium und zu 2 Gew.-% bis 10 Gew.-% Bor umfasst.
  6. Geschmolzene chromfreie metallische Beschichtungszusammensetzung nach Anspruch 5, umfassend Aluminium in dem Bereich von 2 Gew.-% bis 10 Gew.-%.
  7. Geschmolzene chromfreie metallische Beschichtungszusammensetzung nach Anspruch 6, wobei das mindestens eine Grundmetall aus der Gruppe bestehend aus Nickel, Eisen und Kobalt ausgewählt ist.
  8. Geschmolzene chromfreie metallische Beschichtungszusammensetzung nach Anspruch 7, wobei das Grundmetall Nickel umfasst, wobei die Zusammensetzung ferner in Masse auf Gewichtsbasis mindestens einen zusätzlichen Bestandteil umfasst, ausgewählt aus der Gruppe bestehend aus 0,1 Gew.-% bis 10 Gew.-% Eisen, 0,1 Gew.-% bis 10 Gew.-% Molybdän und 0,1 Gew.-% bis 10 Gew.-% Wolfram.
  9. Verbunddraht, der kein Chrom enthält, zum Herstellen einer verschleiß- und korrosionsbeständigen Beschichtung auf einem Substrat, wobei der Verbunddraht einen metallischen Außenmantel in dem Bereich von 70 bis 95 Gew.-% und einen Innenkern aus Teilchen in dem Bereich von 5 bis 30 Gew.-% umfasst, wobei der metallische Außenmantel zu mindestens 70 Gew.-% ein Grundmetall und zu mindestens 2 Gew.-% legiertes Aluminium und/oder Silicium umfasst, wobei das Grundmetall mindestens eines von Nickel, Eisen und Kobalt umfasst, und wobei der Innenkern aus Teilchen Kohlenstoff in dem Bereich von 15 Gew.-% bis 30 Gew.-% Titan, in dem Bereich von 15 Gew.-% bis 30 Gew.-% Silicium, in dem Bereich von 20 Gew.-% bis 50 Gew.-% Bor und in dem Bereich von 0 Gew.-% bis 15 Gew.-% umfasst.
  10. Verbunddraht nach Anspruch 9, wobei der Außenmantel eine Legierung aus Nickel und Aluminium und/oder Silicium umfasst.
  11. Verbunddraht nach Anspruch 9, wobei der Außenmantel Nickel in dem Bereich von 85 bis 98 Gew.-% und legiertes Aluminium und/oder Silicium in dem Bereich von 2 bis 15 Gew.-% umfasst.
  12. Verbunddraht nach Anspruch 11, wobei der Außenmantel Nickel in dem Bereich von 90 bis 97 Gew.-% und legiertes Aluminium in dem Bereich von 3 bis 10 Gew.-% umfasst.
  13. Verbunddraht nach Anspruch 9, wobei der Innenkern aus Teilchen Titan in dem Bereich von 20 Gew.-% bis 30 Gew.-%, Silicium in dem Bereich von 20 Gew.-% bis 30 Gew.-%, Bor in dem Bereich von 30 Gew.-% bis 40 Gew.-% und Kohlenstoff in dem Bereich von 0 Gew.-% bis 15 Gew.-% umfasst.
  14. Verbunddraht nach Anspruch 13, wobei der Innenkern aus Teilchen eine Mischung aus einer TiSi -Quelle in dem Bereich von 50 Gew.-% bis 60 Gew.-% und B4Cin dem Bereich von 40 Gew.-% bis 50 Gew.-% umfasst.
  15. Verbunddraht nach Anspruch 9, umfassend einen metallischen Außenmantel in dem Bereich von 80 bis 90 Gew.-% und einen Innenkern aus Teilchen in dem Bereich von 10 bis 20 Gew.-%.
  16. Verbunddraht nach Anspruch 9, ferner umfassend Molybdän in dem Bereich von 0,1 Gew.-% bis 10 Gew.-%, zu 0,1 Gew.-% bis 10 Gew.-% Wolfram und zu 0,1 Gew.-% bis 10 Gew.-% Kohlenstoff.
  17. Verfahren zum Bilden einer verschleißbeständigen und korrosionsbeständigen Beschichtung auf einem Substrat, umfassend die Schritte: Bereitstellen eines Verbunddrahts nach Anspruch 9 und Einsetzen des Drahts zum Bilden der Beschichtung, wobei der Schritt eines Einsetzens des Drahts zum Bilden der Beschichtung ein thermisches Spritzen des Drahts auf das Substrat umfasst.
EP10756469.2A 2009-03-24 2010-03-24 Chromfreie metallische beschichtung, verfahren zu deren herstellung und verbunddraht Active EP2414106B1 (de)

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Application Number Priority Date Filing Date Title
PL10756469T PL2414106T3 (pl) 2009-03-24 2010-03-24 Bezchromowa powłoka metaliczna, sposób formowania takiej powłoki i drutu kompozytowego

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Application Number Priority Date Filing Date Title
US21090309P 2009-03-24 2009-03-24
PCT/US2010/000858 WO2010110873A1 (en) 2009-03-24 2010-03-24 Chrome-free coating for substrate

Publications (3)

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EP2414106A1 EP2414106A1 (de) 2012-02-08
EP2414106A4 EP2414106A4 (de) 2014-05-14
EP2414106B1 true EP2414106B1 (de) 2020-12-30

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EP (1) EP2414106B1 (de)
JP (1) JP5275509B2 (de)
KR (1) KR101548553B1 (de)
CN (1) CN102387870B (de)
AU (1) AU2010229319B2 (de)
CA (1) CA2756033C (de)
MX (1) MX2011009089A (de)
PL (1) PL2414106T3 (de)
WO (1) WO2010110873A1 (de)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9475154B2 (en) 2013-05-30 2016-10-25 Lincoln Global, Inc. High boron hardfacing electrode
CN109989999A (zh) * 2017-12-29 2019-07-09 圣戈班性能塑料帕姆普斯有限公司 轴承部件及其制备和使用方法

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH311869A (de) 1951-08-06 1955-12-15 Deutsche Edelstahlwerke Ag Verfahren zur Herstellung einer Dauermagnetlegierung.
US4039318A (en) * 1976-07-19 1977-08-02 Eutectic Corporation Metaliferous flame spray material for producing machinable coatings
US4741974A (en) * 1986-05-20 1988-05-03 The Perkin-Elmer Corporation Composite wire for wear resistant coatings
AU6390790A (en) * 1989-10-30 1991-05-02 Lanxide Corporation Anti-ballistic materials and methods of making the same
FR2669645A1 (fr) 1990-11-22 1992-05-29 Castolin Sa Procede de preparation de couches de forte adherence.
DE4328732C1 (de) 1993-08-26 1995-02-16 Castolin Sa Verfahren zum Herstellen einer thermisch gespritzten metallhaltigen Schicht sowie Werkstoff dafür
US6156443A (en) 1998-03-24 2000-12-05 National Research Council Of Canada Method of producing improved erosion resistant coatings and the coatings produced thereby
US6258185B1 (en) * 1999-05-25 2001-07-10 Bechtel Bwxt Idaho, Llc Methods of forming steel
DE10036262B4 (de) * 2000-07-26 2004-09-16 Daimlerchrysler Ag Verfahren zur Herstellung einer Oberflächenschicht und Oberflächenschicht
US6513728B1 (en) 2000-11-13 2003-02-04 Concept Alloys, L.L.C. Thermal spray apparatus and method having a wire electrode with core of multiplex composite powder its method of manufacture and use
DE10259141A1 (de) 2002-12-18 2004-07-08 Corodur Verschleiss-Schutz Gmbh Werkstoffsystem zum thermischen Beschichten
DE10306919B4 (de) * 2003-02-19 2006-08-17 Daimlerchrysler Ag Verbundwerkstoff aus intermetallischen Phasen und Keramik, Herstellungsverfahren und Verwendung
WO2004111290A1 (en) * 2003-06-06 2004-12-23 Michael Walter Seitz Composite wiress for coating substrates and methods of use
US7482061B2 (en) * 2004-11-30 2009-01-27 Momentive Performance Materials Inc. Chromium free corrosion resistant surface treatments using siliconized barrier coatings
FR2886182B1 (fr) * 2005-05-26 2009-01-30 Snecma Services Sa Poudre de superalliage
US9422616B2 (en) * 2005-08-12 2016-08-23 Kennametal Inc. Abrasion-resistant weld overlay

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
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KR101548553B1 (ko) 2015-09-01
CN102387870A (zh) 2012-03-21
EP2414106A1 (de) 2012-02-08
PL2414106T3 (pl) 2021-05-31
MX2011009089A (es) 2011-09-27
CA2756033A1 (en) 2010-09-30
JP2012521496A (ja) 2012-09-13
CN102387870B (zh) 2015-05-20
WO2010110873A1 (en) 2010-09-30
CA2756033C (en) 2014-01-28
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JP5275509B2 (ja) 2013-08-28
EP2414106A4 (de) 2014-05-14

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