EP2409103B1 - Unité d'échange de chaleur et installation thermotechnique - Google Patents
Unité d'échange de chaleur et installation thermotechnique Download PDFInfo
- Publication number
- EP2409103B1 EP2409103B1 EP10719231.2A EP10719231A EP2409103B1 EP 2409103 B1 EP2409103 B1 EP 2409103B1 EP 10719231 A EP10719231 A EP 10719231A EP 2409103 B1 EP2409103 B1 EP 2409103B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- heat exchanger
- unit
- exchanger units
- condenser
- evaporator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000007788 liquid Substances 0.000 claims description 7
- 238000010327 methods by industry Methods 0.000 claims description 3
- 238000010612 desalination reaction Methods 0.000 claims description 2
- 238000005057 refrigeration Methods 0.000 description 11
- 238000010276 construction Methods 0.000 description 6
- 238000013461 design Methods 0.000 description 6
- 238000001816 cooling Methods 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- 239000006096 absorbing agent Substances 0.000 description 3
- 238000004378 air conditioning Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D1/00—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators
- F28D1/02—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid
- F28D1/04—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits
- F28D1/0408—Multi-circuit heat exchangers, e.g. integrating different heat exchange sections in the same unit or heat exchangers for more than two fluids
- F28D1/0426—Multi-circuit heat exchangers, e.g. integrating different heat exchange sections in the same unit or heat exchangers for more than two fluids with units having particular arrangement relative to the large body of fluid, e.g. with interleaved units or with adjacent heat exchange units in common air flow or with units extending at an angle to each other or with units arranged around a central element
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B39/00—Evaporators; Condensers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D1/00—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators
- F28D1/02—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid
- F28D1/04—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits
- F28D1/0408—Multi-circuit heat exchangers, e.g. integrating different heat exchange sections in the same unit or heat exchangers for more than two fluids
- F28D1/0426—Multi-circuit heat exchangers, e.g. integrating different heat exchange sections in the same unit or heat exchangers for more than two fluids with units having particular arrangement relative to the large body of fluid, e.g. with interleaved units or with adjacent heat exchange units in common air flow or with units extending at an angle to each other or with units arranged around a central element
- F28D1/0443—Combination of units extending one beside or one above the other
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D1/00—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators
- F28D1/02—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid
- F28D1/04—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits
- F28D1/047—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits the conduits being bent, e.g. in a serpentine or zig-zag
- F28D1/0477—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits the conduits being bent, e.g. in a serpentine or zig-zag the conduits being bent in a serpentine or zig-zag
- F28D1/0478—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits the conduits being bent, e.g. in a serpentine or zig-zag the conduits being bent in a serpentine or zig-zag the conduits having a non-circular cross-section
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D21/00—Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
- F28D2021/0019—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for
- F28D2021/0068—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for for refrigerant cycles
- F28D2021/007—Condensers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D21/00—Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
- F28D2021/0019—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for
- F28D2021/0068—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for for refrigerant cycles
- F28D2021/0071—Evaporators
Definitions
- the invention relates to a thermal system, in particular a refrigeration system.
- the main components of refrigeration systems such as evaporators, absorbers, expellers and condensers are heat exchangers, which all transport between media heat. These heat exchangers are responsible for 50% of the costs and 75% of the volume of the refrigeration system.
- WO 2007/006289 A1 discloses the functional principle of a heat pump designed as an absorption refrigeration system.
- the mode of operation of the heat pump which has several heat exchanger components, is explained in detail using a schematic circuit diagram.
- heat exchanger components are then also combined to form heat exchanger units which have an evaporator device , which is configured to evaporate a heat exchanger operating or heat exchanger working fluid, and having a liquefier device which is configured to liquefy the heat exchanger operating or heat exchanger working medium.
- Known types of construction and construction for heat exchanger units provide for a pronounced spatial separation of the functional units, which are optionally arranged in a common shell or a common housing.
- the evaporator device and the condenser device are arranged side by side.
- One version of this is the so-called hamster-jaw construction, in which an evaporator device is arranged between two partial condenser devices and the entire structure is integrated in a tubular housing.
- Known units of heat exchanger components have a drip separator or steam blinds in order to make it more difficult for liquid splashes to make the transition to other heat exchanger units or to prevent them completely.
- the object of the invention is to provide a thermal system with an improved structural design that supports the flexible use of the thermal system in applications with different requirements.
- thermodynamic unit consists of one or more pairs of evaporator device and condenser device, which form a thermodynamic and process engineering unit.
- This thermodynamic unit is characterized in particular in that both the length of the steam path and the specific steam mass flow are independent of the absolute power or capacity of the entire heat exchanger unit. The once optimized ratio of the capacities of the heat exchangers to one another, which form a higher-level unit, is retained even when the output is scaled.
- Modular heat exchanger units can be produced, which can be assembled in an overall system, which enables improved scalability of thermal engineering systems or heat pumps, in particular refrigeration systems and desalination systems.
- the front-side configuration also enables a structural design with optimized space utilization and makes a decisive contribution to the thermal separation of the different functional units, steam generators and condensers, which minimizes thermal losses despite spatial optimization.
- the evaporator device can be, for example, a generator or an evaporator.
- the liquefier device is designed, for example, as an absorber or a condenser.
- the frontal arrangement of the evaporator device and the condenser device leads to a changed steam flow behavior between the devices compared to known heat exchanger units, which implies a kind of wave formation, whereby an increased heat and mass transfer is achieved.
- the performance-related heat exchanger area is reduced.
- the scalability achieved with the invention makes it possible to individually adapt thermal engineering systems, in particular refrigeration systems, with regard to the system size and output for different applications.
- a compact design is made possible to advance into small performance ranges that were unattractive for known types of possible assembly of heat exchanger components due to poor power density and large space requirements.
- the invention provides that the evaporator device and the condenser device are arranged opposite one another on the end face.
- end faces of the evaporator device and the condenser device are arranged opposite one another, either at a distance from one another or essentially lying on top of one another.
- the evaporator device and the liquefier device are arranged at least in sections interlocking at the end.
- line sections of the evaporator device and the condenser device engage in sections, with an overlap formed thereby preferably being greater or less than half the longitudinal extent of the respective pipelines.
- An advantageous embodiment of the invention provides that pipes of the evaporator device and pipes of the condenser device alternately interlock.
- a pipe of the evaporator device and a pipe of the condenser device are arranged alternately.
- a further development of the invention preferably provides that an end face of the evaporator device facing the condenser device is arranged substantially completely overlapping with an end face of the condenser device facing the evaporator device and / or vice versa.
- the end faces are arranged essentially congruently.
- An advantageous embodiment of the invention provides a drip separator-free design. In contrast to known heat exchanger units, the effort and provisions for a droplet separator can be saved.
- a further development of the invention provides a vapor barrier-free and / or a drip barrier-free training. This creates a further simplification, which supports a material and cost-saving structure.
- the invention provides a module structure.
- the proposed design principle with regard to the arrangement of the evaporator device and the condenser device makes it possible, in one embodiment, to design independent flow properties for the heat exchanger operating means in the respective module, which essentially do not change even if several heat exchanger units constructed as modules are assembled in one system.
- the evaporator device and the condenser device are formed in a thermal compressor.
- the thermal compressor is integrated in a refrigeration system.
- Fig. 1 shows a perspective view of a thermal system with a heat exchanger unit 10, which is formed with a steam generator 11 and a condenser 12.
- the steam generator 11 and the condenser 12 each have associated pipelines 13, 14.
- a further heat exchanger unit 20 is arranged, which is formed with a condenser 21 and a steam generator 22.
- the two heat exchanger units 10, 20 form a refrigeration system.
- the steam generator 11 and the condenser 12 are positioned in an end configuration or arrangement, with end surfaces arranged opposite each other.
- the same construction is provided for the further heat exchanger unit 20 with the condenser 21 and the steam generator 22.
- evaporated operating fluid which is also referred to as working fluid, flows from the steam generator 11 to the condenser 12 in order to at least partially condense there.
- the liquid condensate is then transferred to the steam generator 22 in order to evaporate there and then to flow as steam to the condenser 21, where condensation takes place again.
- the liquid produced here is then fed back to the steam generator 11.
- Fig. 2 shows a schematic representation of a heat exchanger unit with condenser device 30 and evaporator device 31 in which end faces 32, 33 are arranged opposite one another.
- Fig. 3 shows a schematic representation of a heat exchanger unit with condenser device 40 and evaporator device 41, in which end faces 42, 43 are also arranged opposite one another.
- Fig. 4 shows a schematic representation of a heat exchanger unit with a condenser device 50 and an evaporator device 51 in a configuration at the end, the evaporator device 50 and the condenser device 51 being partially interlocking, so that an overlap area 52 is created.
- the respective evaporator device can be an evaporator, a desorber or a generator.
- the respective condenser device (condenser) is preferably designed as an absorber or condenser.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
- Details Of Heat-Exchange And Heat-Transfer (AREA)
Claims (8)
- Installation thermique, pourvue de plusieurs unités d'échangeurs thermiques (10, 20), qui sont assemblées conformément à une structure modulaire :- les plusieurs unités d'échangeurs thermiques (10, 20) étant formées chacune avec un système d'évaporateur, qui est configuré pour faire évaporer un fluide de fonctionnement d'échangeur thermique, et avec un système de condenseur, qui est configuré pour liquéfier le fluide de fonctionnement d'échangeur thermique, pour une submersion du fluide de fonctionnement d'échangeur thermique, le système d'évaporateur et le système de condenseur étant en liaison fluidique et placés l'un par rapport à l'autre selon une configuration frontale, et- les plusieurs unités d'échangeurs thermiques (10, 20) formant une unité thermodynamique et relevant de la technique de processus, de telle sorte qu'en fonctionnement- du fluide de fonctionnement évaporé du système d'évaporateur (11) vers un système de condenseur (12) submerge l'une des unités d'échangeurs thermiques (10), pour s'y liquéfier au moins partiellement,- le liquide généré dans le système de condenseur (12) soit alors transféré vers un système d'évaporateur (22) d'une autre des unités d'échangeurs thermiques (20) pour s'y évaporer sous forme de vapeur, et- la vapeur submerge un système de condenseur (21) de l'autre unité d'échangeurs thermiques (20), où une fois encore a lieu une liquéfaction, et le liquide généré à cet effet est ramené vers le système d'évaporateur (11).
- Installation thermique selon la revendication 1, caractérisée en ce que sur les plusieurs unités d'échangeurs thermiques (10, 20), le système d'évaporateur (51) et le système de condenseur (50) sont placés en s'imbriquant au moins en partie en face frontale.
- Installation thermique selon la revendication 2, caractérisée en ce que sur les plusieurs unités d'échangeurs thermiques (10, 20), des tuyauteries du système d'évaporateur et des tuyauteries du système de condenseur s'imbriquent en alternance.
- Installation thermique selon au moins l'une quelconque des revendications précédentes, caractérisée en ce que sur les plusieurs unités d'échangeurs thermiques (10, 20), une face frontale du système d'évaporateur qui est dirigée vers le système de condenseur est placée en chevauchement sensiblement complet avec une face frontale du système de condenseur qui est dirigée vers le système d'évaporateur et / ou inversement.
- Installation thermique selon au moins l'une quelconque des revendications précédentes, caractérisée par une réalisation sans séparateur de gouttes des plusieurs unités d'échangeurs thermiques (10, 20).
- Installation thermique selon au moins l'une quelconque des revendications précédentes, caractérisée par une réalisation sans pare-vapeur et / ou une réalisation sans paregouttes des plusieurs unités d'échangeurs thermiques (10, 20).
- Installation thermique selon au moins l'une quelconque des revendications précédentes, caractérisée en ce que sur les plusieurs unités d'échangeurs thermiques (10, 20), le système d'évaporateur et le système de condenseur sont formés dans un compresseur.
- Installation thermique selon au moins l'une quelconque des revendications précédentes, réalisée sous la forme d'une pompe à chaleur, d'une installation frigorifique ou d'une installation de dessalement.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102009013684A DE102009013684A1 (de) | 2009-03-20 | 2009-03-20 | Wärmetauschereinheit und wärmetechnische Anlage |
PCT/DE2010/000309 WO2010105613A2 (fr) | 2009-03-20 | 2010-03-19 | Unité d'échange de chaleur et installation thermotechnique |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2409103A2 EP2409103A2 (fr) | 2012-01-25 |
EP2409103B1 true EP2409103B1 (fr) | 2020-05-06 |
Family
ID=42674761
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10719231.2A Active EP2409103B1 (fr) | 2009-03-20 | 2010-03-19 | Unité d'échange de chaleur et installation thermotechnique |
Country Status (4)
Country | Link |
---|---|
US (1) | US10801782B2 (fr) |
EP (1) | EP2409103B1 (fr) |
DE (1) | DE102009013684A1 (fr) |
WO (1) | WO2010105613A2 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3686714A1 (fr) * | 2019-01-25 | 2020-07-29 | Asetek Danmark A/S | Système de refroidissement comprenant une unité d'échange de chaleur |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5916251A (en) * | 1997-10-29 | 1999-06-29 | Gas Research Institute | Steam flow regulation in an absorption chiller |
EP1160530A1 (fr) * | 1999-03-04 | 2001-12-05 | Ebara Corporation | Echangeur de chaleur a plaques |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1401713B2 (de) | 1958-10-14 | 1971-09-23 | Waermeaustauscher | |
DE1551523A1 (de) | 1967-01-05 | 1970-03-19 | Willy Scheller Maschb Kg Fa | Waermeaustauscher |
US3817708A (en) | 1970-02-25 | 1974-06-18 | Phillips Petroleum Co | Alkylation apparatus |
DE2343463A1 (de) | 1973-08-29 | 1975-03-13 | Ver Kesselwerke Ag | Verfahren zur erzeugung von reindestillat mittels mehrstufenverdampfung durch entspannungsverdampfung und die anlage hierzu |
US5626102A (en) | 1996-03-14 | 1997-05-06 | Nir; Ari | Heat recovery system for a boiler and a boiler provided therewith |
DE19902695B4 (de) * | 1998-01-21 | 2016-01-07 | Vaillant Gmbh | Sorptionswärmepumpe mit einem Ad-/Desorber-Wärmetauscher |
JP2000111212A (ja) | 1998-10-09 | 2000-04-18 | Sanyo Electric Co Ltd | 吸収冷凍機界面活性剤循環回路 |
DE19858686A1 (de) * | 1998-12-18 | 2000-06-21 | Linde Ag | Absorptionsmaschine |
EP1139041B1 (fr) * | 2000-03-31 | 2013-06-19 | Panasonic Healthcare Co., Ltd. | Entrepôt et système de surveillance s'y rapportant |
NZ533996A (en) * | 2001-12-17 | 2005-11-25 | Showa Denko K | Heat exchanger formed by bending finned hairpin tube |
DE102005032266A1 (de) * | 2005-07-11 | 2007-02-15 | Technische Universität Berlin | Verfahren zum Abführen eines Gases aus einer Wärmepumpe und Wärmepumpe |
JP2007113801A (ja) * | 2005-10-18 | 2007-05-10 | Denso Corp | 熱交換器 |
US8506839B2 (en) * | 2005-12-14 | 2013-08-13 | E I Du Pont De Nemours And Company | Absorption cycle utilizing ionic liquids and water as working fluids |
CA2530621A1 (fr) * | 2006-01-03 | 2007-07-03 | Free Energy Solutions Inc. | Systeme frigorifique thermique supraconducteur |
GB2451848A (en) | 2007-08-14 | 2009-02-18 | Arctic Circle Ltd | Multiple circuit heat exchanger comprising tube bundles |
-
2009
- 2009-03-20 DE DE102009013684A patent/DE102009013684A1/de not_active Withdrawn
-
2010
- 2010-03-19 WO PCT/DE2010/000309 patent/WO2010105613A2/fr active Application Filing
- 2010-03-19 US US13/257,929 patent/US10801782B2/en active Active
- 2010-03-19 EP EP10719231.2A patent/EP2409103B1/fr active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5916251A (en) * | 1997-10-29 | 1999-06-29 | Gas Research Institute | Steam flow regulation in an absorption chiller |
EP1160530A1 (fr) * | 1999-03-04 | 2001-12-05 | Ebara Corporation | Echangeur de chaleur a plaques |
Also Published As
Publication number | Publication date |
---|---|
WO2010105613A2 (fr) | 2010-09-23 |
WO2010105613A3 (fr) | 2011-03-10 |
EP2409103A2 (fr) | 2012-01-25 |
US20120067713A1 (en) | 2012-03-22 |
DE102009013684A1 (de) | 2010-10-07 |
US10801782B2 (en) | 2020-10-13 |
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