EP2368081B1 - Heat pump/air conditioning apparatus with sequential operation - Google Patents

Heat pump/air conditioning apparatus with sequential operation Download PDF

Info

Publication number
EP2368081B1
EP2368081B1 EP09830629.3A EP09830629A EP2368081B1 EP 2368081 B1 EP2368081 B1 EP 2368081B1 EP 09830629 A EP09830629 A EP 09830629A EP 2368081 B1 EP2368081 B1 EP 2368081B1
Authority
EP
European Patent Office
Prior art keywords
heat exchanger
heat
refrigerant
heating
temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP09830629.3A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP2368081A4 (en
EP2368081A1 (en
Inventor
Per Erik Holm
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Isolve As
Original Assignee
Varmepumpen As
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Varmepumpen As filed Critical Varmepumpen As
Publication of EP2368081A1 publication Critical patent/EP2368081A1/en
Publication of EP2368081A4 publication Critical patent/EP2368081A4/en
Application granted granted Critical
Publication of EP2368081B1 publication Critical patent/EP2368081B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B30/00—Heat pumps
    • F25B30/02—Heat pumps of the compression type
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24D—DOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D17/00—Domestic hot-water supply systems
    • F24D17/02—Domestic hot-water supply systems using heat pumps
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B41/00—Fluid-circulation arrangements
    • F25B41/30—Expansion means; Dispositions thereof
    • F25B41/39—Dispositions with two or more expansion means arranged in series, i.e. multi-stage expansion, on a refrigerant line leading to the same evaporator
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B5/00—Compression machines, plants or systems, with several evaporator circuits, e.g. for varying refrigerating capacity
    • F25B5/04—Compression machines, plants or systems, with several evaporator circuits, e.g. for varying refrigerating capacity arranged in series
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B6/00—Compression machines, plants or systems, with several condenser circuits
    • F25B6/04—Compression machines, plants or systems, with several condenser circuits arranged in series
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B13/00—Compression machines, plants or systems, with reversible cycle
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2309/00—Gas cycle refrigeration machines
    • F25B2309/06—Compression machines, plants or systems characterised by the refrigerant being carbon dioxide
    • F25B2309/061—Compression machines, plants or systems characterised by the refrigerant being carbon dioxide with cycle highest pressure above the supercritical pressure
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2339/00—Details of evaporators; Details of condensers
    • F25B2339/04—Details of condensers
    • F25B2339/047—Water-cooled condensers
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2400/00—General features or devices for refrigeration machines, plants or systems, combined heating and refrigeration systems or heat-pump systems, i.e. not limited to a particular subgroup of F25B
    • F25B2400/04—Refrigeration circuit bypassing means
    • F25B2400/0409—Refrigeration circuit bypassing means for the evaporator
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2600/00—Control issues
    • F25B2600/25—Control of valves
    • F25B2600/2501—Bypass valves
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2600/00—Control issues
    • F25B2600/25—Control of valves
    • F25B2600/2513—Expansion valves
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B9/00—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
    • F25B9/002—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant
    • F25B9/008—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant the refrigerant being carbon dioxide

Definitions

  • the invention relates to a system for providing a vapour compression cycle as for example an air-conditioning unit or a heat pump, with a thermal energy reservoir or storage that has a dual function, working either as an evaporator or as a gas cooler (condenser), and where the mode of operation depends on the temperature level of recurring temperatures of the energy source, the temperature of the energy storage, and the heat demand, all regulated to optimize heat production and to minimize power consumption. Furthermore the invention relates to a method for operating the system.
  • FIG. 1 A conventional vapour compression cycle system for refrigeration, air-conditioning or heat pump purposes is shown in principle in Fig. 1 .
  • the system consists of a compressor 1, a condensing heat exchanger 2, a throttling valve or pressure reducing device 3 and an evaporating heat exchanger 4. These components are connected in a closed flow circuit 11, in which a refrigerant is circulated.
  • the operating principle of a vapour compression cycle device is as follows: The pressure and temperature of the refrigerant is increased by the compressor 1, before it enters the gas cooler/condenser 2 where it is cooled and/or condensed, giving off heat. The high-pressure liquid is then throttled to the evaporator pressure by means of the pressure reduction device 3. In the evaporator 4, the refrigerant boils and absorbs heat from its surroundings. The vapour at the evaporator is drawn into the compressor 1, completing the cycle.
  • refrigerants as for instance R134A,
  • R134A refrigerant
  • a number of different substances or mixtures of substances may be used as a refrigerant.
  • the choice of refrigerant is among other factors influenced by the condensation temperature, as the critical temperature of the fluid sets the upper limit for the condensation to occur. In order to maintain a reasonable efficiency it is normally desirable to use a refrigerant with critical temperature at 20-30°C above the condensation temperature. Near critical temperatures are avoided in design and operation of conventional systems, although some new systems operate near supercritical temperatures. This is for example the case for the heat pump described in UK patent application GB 2414289 A and in the patent application WO2005/106346 A1 . Both of these applications describe the use of R410A as a refrigerant.
  • a regulation method for transcritical heat pumping with R744 (CO2) is described in patent EP 0 424 474 B2 .
  • the COP for a heatpump that uses R744 is poor in a typical house-heating mode because of its low critical point of 31.2°C . This is thoroughly described in a Doctoral Thesis by J ⁇ rn Stene; Residential CO2 heatpump systems for combined space heating and hot water heating (ISBN 82-471-6316-0 ). The increased CO2 emissions from the energy source that powers the R744 refrigerant heat pump may outweigh the reduced green house gas effect from the potential release of HFC refrigerant to atmosphere. According to the Doctoral Thesis by Stene, the high-pressure hot R744 gas should reject usable heat well below the critical temperature of CO2 (31,2°C) in order to achieve a good COP.
  • US 4,012,920 discloses a reversible heat pump that that has three coils to operate as either an evaporator or a condenser and for connecting either one of the other two coils to operate as a condenser or evaporator, respectively, so that heat can be exchanged in any combination between inside air, outside air and a storage fluid.
  • the three coil arrangement can only work together two and two in cooling or heating mode, and never work with two of the coils performing as gas cooler/condenser simultaneously, which is essential for the principle of this invention when the heat storage is prepared for the next phase of operation.
  • US 3,523,575 disclose a reversible heat pump with a heat storage reservoir that can act both as help in cooling and in heating mode.
  • the heat pump has only two coils and the stored energy is only aimed at assisting in the evaporation/condensing process, not acting as the sole heat source for the heat pump.
  • the module includes a refrigerant compressor, a heat exchange/storage block located on a delivery side of the compressor, a heat exchange/storage medium-temperature block, another heat exchanger, or preferably a heat exchange/storage low-temperature block.
  • the present invention is especially designed for a vapour compression cycle that uses CO2 (R744) as working fluid in transcritical refrigeration.
  • Still other objects of the present invention is to reduce noise from heat pumping by eliminating air and fan noises at certain times, to reduce time for de-icing of the evaporator that uses air as energy source and to increase longevity of compressor through more stable compressor load.
  • the current invention improves the efficiency of thermal solar collectors when they are heating a heat reservoir or storage, because they can feed usable heat to the system at low water temperatures.
  • Still another object of the invention is to increase the heat pump work by heating a bigger portion of the warm water that is consumed.
  • a two tank system with different temperature levels in the tanks should preferably be incorporated in the system, although it is also possible to use other tank arrangements.
  • the dual temperature tank system provides an option to preheat parts of sanitary hot water at times when it is beneficial for the overall compression cycle in one of the tanks, and to blend this water with hot water from the other tank when consumption of warm sanitary water takes place.
  • a system according to claim 1 and a method according to claim 4 are provided.
  • the present invention involves the control or regulation of energy flow between the heat storage and the refrigerant, the time for heating sanitary hot water, the room heating and for controlling when the evaporation heat is taken from the environment.
  • This regulation is typically performed by valve regulation by actuation of valve positions, and by regulation of warm water production.
  • a control unit for controlling or regulating the system may include common control circuits and sensors.
  • the present invention concerns a system for providing a vapour compression cycle.
  • the system includes a flow loop or circuit with a compressor, a first heat exchanger downstream of the compressor, a second heat exchanger downstream of the first heat exchanger, a third heat exchanger downstream of the second heat exchanger and a first pressure reduction device downstream of the third heat exchanger, a fourth heat exchanger with a heat storage device or reservoir downstream of the first pressure reduction device, a second pressure reduction device downstream of the fourth heat exchanger, a fifth heat exchanger downstream of the second pressure reduction device and the flow loop is then connected back to the compressor completing the loop.
  • the pressure reduction devices are common devices for throttling frequently used within the field of heat pumps and refrigeration circuit and may include expansion valves that are fixed or adjustable. Expansion valves may include thermodynamic energy expansion valves such as diaphragm electromagnetism valves, straight close valves and right angle close valves.
  • a bypass line with a shutoff valve bypasses the fifth heat exchanger, and is connected at a first end between the fourth heat exchanger and the second pressure reduction device, and at a second end between the fifth heat exchanger and the compressor.
  • a control unit controls at least the shutoff valve and the pressure reduction devices.
  • the first heat exchanger may be in heat exchange relationship with a high temperature water tank
  • the second heat exchanger may be in heat exchange relationship with a space (room) heating device
  • the third heat exchanger may be in heat exchange relationship with a water tank for preheating sanitary water.
  • a four way valve may be placed over the inlet and outlet of the compressor for switching between heating modes and cooling modes.
  • a thermal solar panel may be connected to the heat storage tank and to one or both of the sanitary hot water tanks.
  • the refrigerant may be CO2.
  • the invention includes a method for controlling the vapour compression cycle with the system defined above wherein opening the first pressure reduction device, closing the shutoff valve, and regulating the second pressure reduction device prepares a first heating mode, and where regulating the first pressure reduction device, with the second pressure reduction device or the bypass valve closed, prepares a second heating mode.
  • the system allows switching between first and second heating modes.
  • the two modes are generally governed by outdoor temperature and the time of the day.
  • the heat exchanger connected to the heat storage may act as an evaporator when the ambient temperature of the fifth heat exchanger is at a low level, and it may act as gas cooler when the ambient temperature is at a high level.
  • the preheating of the sanitary water in a low temperature water tank should correspond with the use of the heat storage as an evaporator.
  • the closed working fluid circuit consists of a refrigerant flow loop (11) where five heat exchangers are connected in series.
  • the five heat exchangers are numbered (2h), (2r), (2p), (4) and (6).
  • Heat exchangers (6) and (4) have a pressure reducing device upstream, numbered (5) and (3) respectively, enabling control of the pressure and temperature at the various sections of the flow loop.
  • the flow loop has a bypass line with a shutoff valve (8) and a compressor (1).
  • the fourth heat exchanger (6) allows the refrigerant to exchange heat with the heat storage medium in tank/closed compartment (7) at temperature (T1).
  • a regulator (14) governs the shown flow loop with its two modes of heating operation. Adjustment of the pressure reducing devices (5) and (3), and the position (shut or open) of the valve (8) in the bypass line determines if the operating mode one heating or operating mode two heating is to be used.
  • Operating mode one heating and operating mode two heating of the present invention is used when the purpose of the apparatus is to heat an environment /building/water etc.
  • Operating mode one heating is used when the temperature (T2) of the external environment of fifth heat exchanger (4) is at a high level in its cycle. If outdoor ambient air is the external environment (air is used as heat source), then it is likely that operating mode one heating would be during daytime, because the outdoor air temperature (T2) is systematically (but not always) higher during daytime than at night. ( Fig. 3 shows the temperature measured each hour during a typical winter period in Oslo.)
  • the pressure reduction device (5) upstream the fourth heat exchanger (6) can be set fully open, and the bypass line shutoff valve (8) is then closed.
  • the second pressure reduction device (3) regulates the pressure level in the first heat exchanger (2h) and the second heat exchanger (2r) and the third heat exchanger (2p) and the fourth heat exchanger (6).
  • the refrigerant boils off in the fifth heat exchanger (4).
  • a compressor (1) increases the pressure and temperature of the refrigerant gas. Downstream the compressor (1), the refrigerant rejects heat in the first heat exchanger (2h) to the hot water tank and second heat exchanger (2r) to a heat distribution medium.
  • the medium could be water or air.
  • the refrigerant then passes the fully open the first pressure reduction device (5) and flows into the fourth heat exchanger (6) where heat in the refrigerant is rejected to a heat storage medium that could be water (or ice) in the heat storage (7)
  • the high-pressure refrigerant is then throttled in the second pressure reduction device (3) before it flows to the fifth heat exchanger (4) and the flow circuit is complete.
  • Operating mode two heating is used when the temperature (T2) of the external environment of the fifth heat exchanger (4) is a low point in its cycle. If outdoor air is used as heat source for the fifth heat exchanger (4), then it is likely that operating mode-two heating is at night time ref. Fig 3 .
  • the second pressure reduction device (5) is now shut and the bypass line shutoff valve (8) is open. (The shutoff valve (8) could be closed and the second pressure reduction device (5) could be set fully open if outdoor temperature (T2) is high enough to contribute to the evaporation.)
  • the first pressure reduction device (5) is regulating pressure level in heat exchangers upstream of it. These valve positions make the media in heat storage (7) to the heat source for evaporation of the refrigerant.
  • the fourth heat exchanger (6) enables the heat storage media to be the heat source that boils off the refrigerant.
  • Compressor (1) sucks the vapour from the fourth heat exchanger (6) via the bypass line and raises the pressure and temperature of the refrigerant gas as it pumps the refrigerant in the refrigerant cycle. Downstream of the compressor (1), the refrigerant rejects heat in the second heat exchanger (2r) and (2p). Refrigerant pressure and temperature is throttled in the first pressure reduction device (5) to condensate in the fourth heat exchanger (6) where evaporation takes place and the cycle is complete.
  • the gain of the arrangement described is that the nighttime evaporation temperature is increased by (T1) minus (T2).
  • the media in the heat storage is water it can be designed to have a lower temperature limit of approximately zero deg C. That is because the water in the heat storage has a temperature of zero deg. C until all of the water is frozen to ice.
  • T1 the nighttime evaporation temperature
  • T2 the media in the heat storage
  • the fourth heat exchanger (6) used at nighttime is virtually noiseless compared to the fifth heat exchanger (4) that uses forced air flow as heat source. Silence through the night is important for the use of any apparatuses in densely populated areas.
  • Ice build up at fins of the heat exchanger is a problem, because it reduces the efficiency of the heat transfer and de-icing is required when ice build-up become too severe.
  • De-icing consumes energy, it produces water and it may affect longevity of the equipment as it implies temperature fluctuations in piping and increased valve switching.
  • the present invention reduces problems related to de-icing to daytime.
  • Fig 4 The preferred embodiment of the invention is shown in Fig 4 .
  • This embodiment includes two hot water tanks, (9h) (hot water 27-65°C) and (9p) (preheating 7 - 27°C), in addition to a room heating device (Rhd) and the three flow adjustable circulation pumps (Ph) (hot water), (Pr) (room heating), (Pp) (preheating).
  • the purpose of using two hot water tanks is to be able to separate the production of hot water at two different temperature levels, one temperature level for each operating mode. Heating of hot water can then take place at times when the physical state of other elements in the refrigerant flow circuit is benign for this purpose.
  • Another benefit of using two tanks is that more water is heated by the heat pump compared with a traditional tank solution.
  • Fig. 7 shows water volumes heated with a traditional one tank solution compared with a two tank dual temperature solution where warm sanitary tap water consists of hot water from the hot water tank tempered with preheated water from the low temperature water tank.
  • hot refrigerant gas from the compressor (1) is in heat exchange relationship with water, being circulated from the bottom of water tank (9h) - through the first heat exchanger (2h) and back to the top of water to tank 9h.
  • the water is heated from app. 27°C to 65-90°C depending on refrigerant pressure and hot water temperatures and circulation rate.
  • the heating capacity is regulated by means of the hot water circulation flow rate, the compressor (1) discharge pressure and flow rate.
  • hot refrigerant gas Downstream of the first heat exchanger (2h), hot refrigerant gas is in heat exchange relationship with a conditioning fluid for room heating in the second heat exchanger (2r). Temperature levels of the conditioning fluid will in most cases vary between 27 and 45°C depending on local room heating systems. The heating capacity is regulated by the conditioning fluid flow rate, and the temperature and flow rate of the refrigerant hot gas.
  • the high-pressure refrigerant gas then flows through a third heat exchanger (2p) where no heat is rejected (there is no circulation of water in the heat exchanger (2p) in this mode).
  • the refrigerant gas then flows further through the fully open pressure reduction device (5) before the hot refrigerant gas rejects heat to the media in heat storage (7) by means of the fourth heat exchanger (6).
  • Bypass line shut off valve (8) is kept closed. Downstream the fourth heat exchanger (6) the refrigerant gas is flowing through the second pressure reduction device (3) where pressure is throttled whereafter liquid refrigerant flows to the fifth heat exchanger (4) where evaporation takes place before the refrigerant gas is sucked into the compressor (1) completing the cycle.
  • shutoff valve (8) opens, the second pressure reduction device (5) closes and pressure reduction device (5) is operational.
  • heat storage fluid in tank (7) serves as heat source to evaporate the refrigerant.
  • the latent heat of the heat storage fluid is transferred to the refrigerant by the fourth heat exchanger (6) where liquid refrigerant boils off to form vapour.
  • the vapour is sucked into the compressor (1).
  • Compressor (1) raises pressure and temperature in the circulating refrigerant gas.
  • the refrigerant passes through the first heat exchanger (2h) without rejecting heat as (Ph) is off in this mode of operation.
  • the first heat exchanger (2h) hot refrigerant gas Downstream the first heat exchanger (2h) hot refrigerant gas is in heat exchange relationship with a conditioning fluid for room heating in the second heat exchanger (2r). Temperature levels of the conditioning fluid will in most cases vary between 25 and 45°C depending on local room heating systems.
  • the heating capacity is regulated by means of the conditioning fluid flow rate ((Pr) running speed) and flow and temperature of the refrigerant hot gas.
  • the refrigerant gas then passes a third heat exchanger (2p) in which water to tank (9p) is circulated by means of (Pp). Water circulates from the bottom of the tank, via the heat exchanger (2p) where water is in heat exchange relationship with the refrigerant gas, and back to the top of the tank (9p).
  • the temperature of heat storage medium in heat storage (7) will be lowered to a level where ice may have been formed given the heat storage medium was water. With a good heat transfer mechanism in the fourth heat exchanger (6) the whole tank may freeze.
  • This preferred embodiment of the invention shows that a controlled running of flow from the circulation device Ph, Pr and Pp in the different operating modes can provide gas cooling in operating mode two heating. Proper dimensioning of the hot water tanks (9h) and (9p) will assure enough daily hot water to a normal family dwelling.
  • the media that is used to boil off the refrigerant in operating mode two heating could be water or another phase change material.
  • the phase change from liquid to solid should be facilitated in the energy storage (7) in order to increase the amount of energy that can be stored in a limited volume and also to get a stable evaporation temperature. Melting point for water is 0°C and freezing energy is 334 kJ/kg.
  • a 300 litre tank contains app. 28 kWh for evaporation, which should be sufficient for a normal apartment. However, other tanks could be used and phase change may then be unnecessary.
  • a 3000 litres tank (normal size for an indoor/outdoor oil storage tank) contains 52,5 kWh when water is cooled from 15°C to zero.
  • the heat storage media in heat storage (7) provides for gas cooling in operating mode one heating. This is usable heat as long as T1 >T2 in operating mode two.
  • Fig. 5 shows a pressure enthalpy diagram of a transcritical vapour compression cycle.
  • the pressure and enthalpy of the hot gas from the discharge of compressor (1) ( Fig. 1 ) is at state a ( Fig 5 ).
  • a cooling agent e.g. hot water in (2) at constant pressure the refrigerant is cooled to state b.
  • Throttling valve (3) ( Fig. 1 ) takes the refrigerant to a two-phase gas/liquid mixture shown as state c ( fig. 5 ).
  • the throttling is a constant enthalpy process.
  • the refrigerant absorbs heat in the fifth heat exchanger (4) ( Fig.
  • the state of the refrigerant at outlet of compressor (1) ( Fig. 2 ) is at a.
  • the refrigerant is giving off heat to hot water in the first heat exchanger (2h) and to room heating media in the second heat exchanger (2r) ( Fig. 2 ), bringing the refrigerant to state b at the inlet of the fourth heat exchanger (6) ( Fig. 2 ).
  • the refrigerant is further cooled, giving off heat to a suitable medium in heat storage (7) ( Fig. 2 ), taking the refrigerant to state b' at the fourth heat exchanger (6) ( Fig. 2 ) outlet.
  • the state of the refrigerant in the heat rejection phase before throttling is then moved from b to b'.
  • the enthalpy difference b-b' represents the energy per unit of refrigerant flow that is available for storage in heat storage (7) ( Fig. 2 ). From b' the refrigerant is throttled to point c'. The point c' represents evaporation pressure and temperature at the actual temperature (T2). The enthalpy c'-c is equivalent to b-b' and shows how the stored energy is harvested from the environment.
  • the refrigerant absorbs heat in fifth heat exchanger (4) ( Fig. 2 ), and moves from state c' to state d before it enters the compressor (1) and the cycle is complete.
  • Fig. 6 shows a log pressure enthalpy diagram of a transcritical vapour compression cycle.
  • Operating mode two heating is represented by points a, b", c", d.
  • Operating mode two heating is run when the temperature (T2) ( Fig. 2 ) is at a low point and the temperature of the heat storage media (T1) is high (after a period where the media in heat storage (7) has been used to cool the gas).
  • Temperature (T1) could be between 0 and 20°C given the heat storage media is water and T1 should be greater than T2.
  • the refrigerant status at outlet of compressor (1) ( fig. 2 ) is at state a.
  • the first pressure reduction device (5) ( fig. 2 ) lets the pressure of the refrigerant down to point c" at constant enthalpy.
  • Heat from the media in heat storage (7) ( fig. 2 ) is used to boil off the refrigerant in the fourth heat exchanger (6) ( fig. 2 ) bringing the refrigerant to state d.
  • the fifth heat exchanger (4) ( fig.
  • Point c' shows the evaporation pressure if the heat source were at (T2) ( fig. 2 ) assuming that T1 > T2 and that no preheating of hot water in (2p) took place.
  • Point d' is the corresponding state of refrigerant gas at compressor inlet.
  • the gain of this operating mode is that the evaporation temperature is lifted from c' to c , thus reducing the compressor work with (a-d') - (a-d) and the energy taken from the heat storage is increased by the enthalpy (d-c") - (d-c').
  • Fig. 7 shows differences in the amounts of water being heated by the heat pump when heating 100 litres of water for use at 40°C, when using two tanks at two temperatures for sanitary warm water supply compared to a conventional one tank system.
  • the hot refrigerant gas in the first heat exchanger (2h) rejects heat at temperatures up to 90°C to a separate hot water tank (9h).
  • Pump speed of circulation pump (Ph) governs the energy transfer and temperature approach of hot water in the first heat exchanger (2h).
  • circulation pump (Pp) is off, and no preheating of hot water is done in heat exchanger (2p).
  • the hot refrigerant gas flows right through the heat exchanger (2p) before it goes to the fourth heat exchanger (6), where remaining heat is given off to thaw/heat the medium in the heat storage (7).
  • the hot water circulation pump (Ph) is off and the hot refrigerant gas flows right through the first heat exchanger (2h) without giving of any heat, before it enters the second heat exchanger (2r) and gives off heat to a room heating media.
  • the hot refrigerant gas flows to heat exchanger (2p) where heat is given off to water circulating from tank (9p). Energy outtake is regulated by means of circulation pump (Pp).
  • Tempered water from tank (9p) should be used to blend with hot water from tank (9h) before use. More of the sanitary water can then be heated by the heat pump at lower temperature than what is the case for traditional system. This is shown in fig. 7 .
  • a flow loop from a solar thermal collector may be connected to the heat storage tank (7).
  • the fluid from the solar thermal collector in heat exchange relationship with the media in the heat storage (7) will then help thaw and heat the heat storage medium.
  • the differential temperature between ambient temperature and heat transfer fluid is relatively high in the winter season.
  • a typical temperature differential of 50 - 60°C is common.
  • a high temperature differential reduces the efficiency of the heat absorber because of radiation losses and convection losses in the absorber. Because of the low temperature requirement for thawing ice and raising temperature above zero degrees in the heat storage, wintertime efficiency of thermal collector increases with up to 50 percent compared to traditional systems.
  • the solar thermal collector can produce hot water for sanitary use directly to the water tanks.
  • a four way valve 12 is introduced downstream of compressor (1).
  • refrigerant heat may be dumped in the fifth heat exchanger (4) or in the fourth heat exchanger (6) depending on ambient temperature and actual temperature in the heat storage media in the heat storage tank (7).
  • shutoff valve (8) When shutoff valve (8) is closed, heat is first dumped to ambient air through heat exchanger (4).
  • the second pressure reduction device (3) or the first pressure reduction device (5) may be used to reduce the pressure to condensate the refrigerant to the second heat exchanger (2r) where room cooling media is in heat exchange relationship with the refrigerant. Circulation pumps (Pp) and (Ph) are normally stopped in this mode of operation.

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Heat-Pump Type And Storage Water Heaters (AREA)
  • Compression-Type Refrigeration Machines With Reversible Cycles (AREA)
EP09830629.3A 2008-12-02 2009-12-02 Heat pump/air conditioning apparatus with sequential operation Active EP2368081B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NO20085016A NO331155B1 (no) 2008-12-02 2008-12-02 Varmepumpe/luftkondisjoneringsapparat med sekvensiell drift
PCT/NO2009/000414 WO2010064923A1 (en) 2008-12-02 2009-12-02 Heat pump/air conditioning apparatus with sequential operation

Publications (3)

Publication Number Publication Date
EP2368081A1 EP2368081A1 (en) 2011-09-28
EP2368081A4 EP2368081A4 (en) 2013-10-09
EP2368081B1 true EP2368081B1 (en) 2018-07-18

Family

ID=42233424

Family Applications (1)

Application Number Title Priority Date Filing Date
EP09830629.3A Active EP2368081B1 (en) 2008-12-02 2009-12-02 Heat pump/air conditioning apparatus with sequential operation

Country Status (6)

Country Link
EP (1) EP2368081B1 (zh)
JP (1) JP5860700B2 (zh)
CN (1) CN102239372B (zh)
CA (1) CA2745109C (zh)
NO (1) NO331155B1 (zh)
WO (1) WO2010064923A1 (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022093669A3 (en) * 2020-08-24 2022-08-04 Alley Tony Multiple channel heat exchanger

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2489944A1 (en) * 2011-02-18 2012-08-22 Thermocold Costruzioni SrL Thermal generator with CO2 operating vapor compression cycle
DE102012208174B4 (de) 2012-05-16 2016-09-01 Efficient Energy Gmbh Wärmepumpe und verfahren zum pumpen von wärme im freikühlungsmodus
CN103574960A (zh) * 2012-08-08 2014-02-12 昆山赤子坊国际贸易有限公司 一种新型的制冷装置
CN103075843A (zh) * 2013-01-21 2013-05-01 深圳市庄合地能产业科技有限公司 一种冷热内平衡机组
CN103090591A (zh) * 2013-01-21 2013-05-08 深圳市庄合地能产业科技有限公司 一种溴化锂机组与冷库结合使用的冷热内平衡系统
FR3003936A3 (fr) * 2013-03-27 2014-10-03 Nextherm Installation de pompe a chaleur fonctionnant a partir d'une source froide
CN103727696A (zh) * 2013-11-26 2014-04-16 中山市蓝水能源科技发展有限公司 一种自调节空调系统
LU92502B1 (fr) * 2014-07-22 2016-01-25 Regandsy & Hates Sarl Installation de production de froid comprenant desmoyens de condensation à la fois par air et par e au, ainsi que son procédé de mise en oeuvre
CN106568111A (zh) * 2015-10-09 2017-04-19 上海日立电器有限公司 二氧化碳热泵采暖系统
ITUB20154857A1 (it) * 2015-10-27 2017-04-27 Thermocold Costr Srl Macchina a pompa di calore a doppio evaporatore in serie
FR3050018A1 (fr) * 2016-04-11 2017-10-13 Antoine Zalcman Climatiseur a narguiles
CN107525296A (zh) * 2017-08-15 2017-12-29 东北电力大学 一种蓄热式空气源热泵系统及其控制方法
IL260159B (en) * 2018-06-19 2022-02-01 N A M Tech Ltd A cooling system consisting of multiple cascades
DE102021002899A1 (de) * 2021-06-08 2022-12-08 Gea Refrigeration Netherlands N.V. Wärmetauscher-Anordnung für Wärmepumpe und Wärmepumpe mit derselben
GB202112604D0 (en) * 2021-09-03 2021-10-20 Kensa Heat Pumps Ltd Improvements in or relating to heat pumps

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3523575A (en) 1968-06-12 1970-08-11 American Standard Inc Air-conditioning system having heat storage reservoir
US4012920A (en) 1976-02-18 1977-03-22 Westinghouse Electric Corporation Heating and cooling system with heat pump and storage
JPS61149759A (ja) * 1984-12-21 1986-07-08 Mitsubishi Electric Corp ヒ−トポンプ式給湯装置
NO890076D0 (no) 1989-01-09 1989-01-09 Sinvent As Luftkondisjonering.
JPH0534033A (ja) * 1991-07-30 1993-02-09 Mitsubishi Electric Corp ヒートポンプ装置
JP3598604B2 (ja) * 1995-09-08 2004-12-08 ダイキン工業株式会社 熱搬送装置
JP3557918B2 (ja) * 1998-10-05 2004-08-25 トヨタ自動車株式会社 冷暖房及び給湯システム
JP2002106963A (ja) * 2000-09-29 2002-04-10 Sanyo Electric Co Ltd ヒートポンプ給湯機
JP4378900B2 (ja) * 2001-08-03 2009-12-09 株式会社デンソー ヒートポンプ式給湯装置
DE10213339A1 (de) * 2002-03-26 2003-10-16 Gea Happel Klimatechnik Wärmepumpe zum gleichzeitigen Kühlen und Heizen
JP2003287294A (ja) * 2002-03-27 2003-10-10 Matsushita Electric Ind Co Ltd 冷凍サイクル装置の運転方法
JP2004257586A (ja) * 2003-02-24 2004-09-16 Matsushita Electric Ind Co Ltd 二酸化炭素を冷媒として用いた冷凍装置
JPWO2005106346A1 (ja) 2004-04-28 2007-12-13 東芝キヤリア株式会社 ヒートポンプ式給湯装置
GB2414289A (en) 2004-05-19 2005-11-23 Asker Barum Kuldeteknikk A S A heat pump installation
WO2006051617A1 (ja) * 2004-11-12 2006-05-18 Mayekawa Mfg.Co.,Ltd. Ｃｏ２を冷媒としたヒートポンプ及びその運転方法
DE102006003096B4 (de) 2006-01-20 2012-05-31 Hydro Aluminium Deutschland Gmbh Modularer Sonnenkollektor
CN1825017A (zh) * 2006-03-29 2006-08-30 南京航空航天大学 户式中央热泵采暖空调热水器
JP2007327671A (ja) * 2006-06-06 2007-12-20 Daiwa House Ind Co Ltd ソーラーヒートポンプシステム
FR2906604A1 (fr) 2006-09-28 2008-04-04 Heliotrans Sarl Module utilisable pour le stockage et le transfert thermique.

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022093669A3 (en) * 2020-08-24 2022-08-04 Alley Tony Multiple channel heat exchanger

Also Published As

Publication number Publication date
CA2745109C (en) 2016-07-26
EP2368081A4 (en) 2013-10-09
EP2368081A1 (en) 2011-09-28
CN102239372A (zh) 2011-11-09
CN102239372B (zh) 2014-03-26
JP2012510605A (ja) 2012-05-10
JP5860700B2 (ja) 2016-02-16
WO2010064923A1 (en) 2010-06-10
CA2745109A1 (en) 2010-06-10
NO20085016L (no) 2010-06-03
NO331155B1 (no) 2011-10-24

Similar Documents

Publication Publication Date Title
EP2368081B1 (en) Heat pump/air conditioning apparatus with sequential operation
US5678626A (en) Air conditioning system with thermal energy storage and load leveling capacity
JP5380226B2 (ja) 空調給湯システム及びヒートポンプユニット
US5467812A (en) Air conditioning system with thermal energy storage and load leveling capacity
JP5121922B2 (ja) 空調給湯複合システム
US4693089A (en) Three function heat pump system
JP5084903B2 (ja) 空調給湯複合システム
EP2527751B1 (en) Air conditioning-hot water supply combined system
JP5455521B2 (ja) 空調給湯システム
JP5121747B2 (ja) 地中熱ヒートポンプ装置
US20100038441A1 (en) Energy system with a heat pump
CN102753916B (zh) 空气调节热水供给系统
KR100430238B1 (ko) 고온 급탕 열펌프 유닛
WO2021231619A1 (en) Switching flow water source heater/chiller
WO2007043952A1 (en) Heat exchanger device
CN111928338A (zh) 空调余热回收系统及空调系统
CN212566000U (zh) 空调余热回收系统及空调系统
KR20100013010A (ko) 공중목욕탕용 에너지절약형 물공급장치
KR200257232Y1 (ko) 히트펌프식 폐열회수장치
WO2004010060A1 (ja) 冷凍サイクル

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20110622

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR

DAX Request for extension of the european patent (deleted)
A4 Supplementary search report drawn up and despatched

Effective date: 20130910

RIC1 Information provided on ipc code assigned before grant

Ipc: F25B 30/00 20060101AFI20130904BHEP

Ipc: F25B 5/04 20060101ALI20130904BHEP

Ipc: F25B 6/04 20060101ALI20130904BHEP

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

INTG Intention to grant announced

Effective date: 20180309

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 1019804

Country of ref document: AT

Kind code of ref document: T

Effective date: 20180815

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602009053379

Country of ref document: DE

REG Reference to a national code

Ref country code: CH

Ref legal event code: NV

Representative=s name: RENTSCH PARTNER AG, CH

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 10

REG Reference to a national code

Ref country code: SE

Ref legal event code: TRGR

RAP2 Party data changed (patent owner data changed or rights of a patent transferred)

Owner name: ISOLVE AS

REG Reference to a national code

Ref country code: NL

Ref legal event code: MP

Effective date: 20180718

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK05

Ref document number: 1019804

Country of ref document: AT

Kind code of ref document: T

Effective date: 20180718

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180718

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180718

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180718

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181118

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181018

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180718

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180718

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181018

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181019

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180718

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180718

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180718

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602009053379

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180718

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180718

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180718

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180718

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180718

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180718

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180718

26N No opposition filed

Effective date: 20190423

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20181202

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180718

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180718

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20181202

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20181202

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180718

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180718

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MK

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180718

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180718

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20091202

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20231215

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 20231220

Year of fee payment: 15

Ref country code: FR

Payment date: 20231221

Year of fee payment: 15

Ref country code: DE

Payment date: 20231218

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20231220

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 20240102

Year of fee payment: 15