EP2340299B1 - Copolymer zur oberflächenverarbeitung oder modifizierung - Google Patents
Copolymer zur oberflächenverarbeitung oder modifizierung Download PDFInfo
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- EP2340299B1 EP2340299B1 EP09809323.0A EP09809323A EP2340299B1 EP 2340299 B1 EP2340299 B1 EP 2340299B1 EP 09809323 A EP09809323 A EP 09809323A EP 2340299 B1 EP2340299 B1 EP 2340299B1
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- 229920001577 copolymer Polymers 0.000 title claims description 95
- 230000004048 modification Effects 0.000 title claims description 12
- 238000012986 modification Methods 0.000 title claims description 12
- 239000000203 mixture Substances 0.000 claims description 332
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 84
- 238000004140 cleaning Methods 0.000 claims description 74
- -1 vinyl lactam Chemical class 0.000 claims description 64
- 125000000217 alkyl group Chemical group 0.000 claims description 41
- 239000004094 surface-active agent Substances 0.000 claims description 40
- 239000000178 monomer Substances 0.000 claims description 38
- 125000002091 cationic group Chemical group 0.000 claims description 30
- 238000004851 dishwashing Methods 0.000 claims description 28
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 17
- 238000011282 treatment Methods 0.000 claims description 16
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 15
- 125000000129 anionic group Chemical group 0.000 claims description 15
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 13
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 claims description 13
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 11
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 11
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 9
- 150000001450 anions Chemical class 0.000 claims description 8
- 230000002209 hydrophobic effect Effects 0.000 claims description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
- UZNHKBFIBYXPDV-UHFFFAOYSA-N trimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)NCCC[N+](C)(C)C UZNHKBFIBYXPDV-UHFFFAOYSA-N 0.000 claims description 4
- 229920002554 vinyl polymer Polymers 0.000 claims description 4
- SYPXNWGMHMNKMW-UHFFFAOYSA-N 2-ethenyl-1-ethylpyridin-1-ium Chemical compound CC[N+]1=CC=CC=C1C=C SYPXNWGMHMNKMW-UHFFFAOYSA-N 0.000 claims description 3
- YORNOYIKCMVNMD-UHFFFAOYSA-N 4-ethenyl-1-ethylpyridin-1-ium Chemical compound CC[N+]1=CC=C(C=C)C=C1 YORNOYIKCMVNMD-UHFFFAOYSA-N 0.000 claims description 3
- 239000005630 Diquat Substances 0.000 claims description 3
- SYJFEGQWDCRVNX-UHFFFAOYSA-N diquat Chemical compound C1=CC=[N+]2CC[N+]3=CC=CC=C3C2=C1 SYJFEGQWDCRVNX-UHFFFAOYSA-N 0.000 claims description 3
- XIUCEANTZSXBQQ-UHFFFAOYSA-N (3-chloro-2-hydroxypropyl)-trimethylazanium Chemical compound C[N+](C)(C)CC(O)CCl XIUCEANTZSXBQQ-UHFFFAOYSA-N 0.000 claims description 2
- AIUAMYPYEUQVEM-UHFFFAOYSA-N trimethyl(2-prop-2-enoyloxyethyl)azanium Chemical compound C[N+](C)(C)CCOC(=O)C=C AIUAMYPYEUQVEM-UHFFFAOYSA-N 0.000 claims description 2
- WCCVMVPVUAVUFI-UHFFFAOYSA-N 2-methylprop-2-enamide;hydrochloride Chemical compound Cl.CC(=C)C(N)=O WCCVMVPVUAVUFI-UHFFFAOYSA-N 0.000 claims 1
- 230000001476 alcoholic effect Effects 0.000 claims 1
- SCVMAXDVEVNLCQ-UHFFFAOYSA-N methyl hydrogen sulfate;2-methylprop-2-enamide Chemical compound COS(O)(=O)=O.CC(=C)C(N)=O SCVMAXDVEVNLCQ-UHFFFAOYSA-N 0.000 claims 1
- 229920006301 statistical copolymer Polymers 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 description 84
- 239000011521 glass Substances 0.000 description 37
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 34
- 238000001035 drying Methods 0.000 description 31
- 238000009472 formulation Methods 0.000 description 30
- 229910052708 sodium Inorganic materials 0.000 description 30
- 239000011734 sodium Substances 0.000 description 30
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 29
- LXEKPEMOWBOYRF-UHFFFAOYSA-N [2-[(1-azaniumyl-1-imino-2-methylpropan-2-yl)diazenyl]-2-methylpropanimidoyl]azanium;dichloride Chemical compound Cl.Cl.NC(=N)C(C)(C)N=NC(C)(C)C(N)=N LXEKPEMOWBOYRF-UHFFFAOYSA-N 0.000 description 29
- 235000002639 sodium chloride Nutrition 0.000 description 25
- 239000003999 initiator Substances 0.000 description 23
- 235000013350 formula milk Nutrition 0.000 description 22
- 150000003254 radicals Chemical class 0.000 description 22
- 239000002904 solvent Substances 0.000 description 21
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 19
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 19
- 239000003139 biocide Substances 0.000 description 19
- 150000003839 salts Chemical class 0.000 description 19
- 229910052757 nitrogen Inorganic materials 0.000 description 18
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 17
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 17
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 16
- 239000002736 nonionic surfactant Substances 0.000 description 16
- 229910052700 potassium Inorganic materials 0.000 description 16
- 239000011591 potassium Substances 0.000 description 16
- 125000004432 carbon atom Chemical group C* 0.000 description 15
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 15
- 239000006260 foam Substances 0.000 description 15
- 239000002253 acid Substances 0.000 description 14
- 239000000654 additive Substances 0.000 description 14
- QYZFTMMPKCOTAN-UHFFFAOYSA-N n-[2-(2-hydroxyethylamino)ethyl]-2-[[1-[2-(2-hydroxyethylamino)ethylamino]-2-methyl-1-oxopropan-2-yl]diazenyl]-2-methylpropanamide Chemical compound OCCNCCNC(=O)C(C)(C)N=NC(C)(C)C(=O)NCCNCCO QYZFTMMPKCOTAN-UHFFFAOYSA-N 0.000 description 14
- 229920000642 polymer Polymers 0.000 description 14
- KFZMGEQAYNKOFK-UHFFFAOYSA-N 2-propanol Substances CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 13
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 12
- 229920002125 Sokalan® Polymers 0.000 description 12
- 229910052783 alkali metal Inorganic materials 0.000 description 12
- 239000003599 detergent Substances 0.000 description 12
- 235000014113 dietary fatty acids Nutrition 0.000 description 12
- 150000002009 diols Chemical class 0.000 description 12
- 239000000194 fatty acid Substances 0.000 description 12
- 229930195729 fatty acid Natural products 0.000 description 12
- 239000011541 reaction mixture Substances 0.000 description 12
- 150000004760 silicates Chemical class 0.000 description 12
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 11
- 125000004429 atom Chemical group 0.000 description 11
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 11
- 239000002243 precursor Substances 0.000 description 11
- 230000008569 process Effects 0.000 description 11
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 244000303965 Cyamopsis psoralioides Species 0.000 description 10
- 239000007844 bleaching agent Substances 0.000 description 10
- 150000001768 cations Chemical class 0.000 description 10
- 238000006116 polymerization reaction Methods 0.000 description 10
- ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 10
- 239000000344 soap Substances 0.000 description 10
- 239000004471 Glycine Substances 0.000 description 9
- 241000243142 Porifera Species 0.000 description 9
- 150000001412 amines Chemical class 0.000 description 9
- 239000003093 cationic surfactant Substances 0.000 description 9
- 238000000151 deposition Methods 0.000 description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 9
- 238000010790 dilution Methods 0.000 description 9
- 239000012895 dilution Substances 0.000 description 9
- 150000004665 fatty acids Chemical class 0.000 description 9
- 239000002304 perfume Substances 0.000 description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 8
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 8
- 241000282372 Panthera onca Species 0.000 description 8
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 8
- 150000007513 acids Chemical class 0.000 description 8
- 150000001340 alkali metals Chemical class 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- 239000012429 reaction media Substances 0.000 description 8
- 239000002689 soil Substances 0.000 description 8
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 7
- 229910019142 PO4 Inorganic materials 0.000 description 7
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 7
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 7
- 239000003945 anionic surfactant Substances 0.000 description 7
- 125000003118 aryl group Chemical group 0.000 description 7
- 230000008901 benefit Effects 0.000 description 7
- 229910052500 inorganic mineral Inorganic materials 0.000 description 7
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 7
- 239000011707 mineral Substances 0.000 description 7
- 235000021317 phosphate Nutrition 0.000 description 7
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 7
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Natural products NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 6
- 239000002280 amphoteric surfactant Substances 0.000 description 6
- 239000001913 cellulose Substances 0.000 description 6
- 229920002678 cellulose Polymers 0.000 description 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 6
- 229910052744 lithium Inorganic materials 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
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- 239000000377 silicon dioxide Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- CUVLMZNMSPJDON-UHFFFAOYSA-N 1-(1-butoxypropan-2-yloxy)propan-2-ol Chemical compound CCCCOCC(C)OCC(C)O CUVLMZNMSPJDON-UHFFFAOYSA-N 0.000 description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 5
- MHRRTVVGLQIJHH-UHFFFAOYSA-N C(=C)P(=O)(O)OP(=O)O Chemical class C(=C)P(=O)(O)OP(=O)O MHRRTVVGLQIJHH-UHFFFAOYSA-N 0.000 description 5
- 238000007792 addition Methods 0.000 description 5
- 239000002671 adjuvant Substances 0.000 description 5
- 150000001298 alcohols Chemical class 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 235000015165 citric acid Nutrition 0.000 description 5
- 230000003165 hydrotropic effect Effects 0.000 description 5
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 239000003755 preservative agent Substances 0.000 description 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 5
- 235000000346 sugar Nutrition 0.000 description 5
- 239000002888 zwitterionic surfactant Substances 0.000 description 5
- JGVZJRHAZOBPMW-UHFFFAOYSA-N 1,3-bis(dimethylamino)propan-2-ol Chemical compound CN(C)CC(O)CN(C)C JGVZJRHAZOBPMW-UHFFFAOYSA-N 0.000 description 4
- IDQBJILTOGBZCR-UHFFFAOYSA-N 1-butoxypropan-1-ol Chemical compound CCCCOC(O)CC IDQBJILTOGBZCR-UHFFFAOYSA-N 0.000 description 4
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 4
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- JCTXKRPTIMZBJT-UHFFFAOYSA-N 2,2,4-trimethylpentane-1,3-diol Chemical compound CC(C)C(O)C(C)(C)CO JCTXKRPTIMZBJT-UHFFFAOYSA-N 0.000 description 4
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 4
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- SMBRHGJEDJVDOB-UHFFFAOYSA-N 2-methylpropanimidamide;dihydrochloride Chemical compound Cl.Cl.CC(C)C(N)=N SMBRHGJEDJVDOB-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 4
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- 102000004190 Enzymes Human genes 0.000 description 4
- 108090000790 Enzymes Proteins 0.000 description 4
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- 102220549062 Low molecular weight phosphotyrosine protein phosphatase_C13S_mutation Human genes 0.000 description 4
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 4
- 229920002257 Plurafac® Polymers 0.000 description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 4
- 241001080024 Telles Species 0.000 description 4
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 4
- 150000008051 alkyl sulfates Chemical class 0.000 description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
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- 150000001642 boronic acid derivatives Chemical class 0.000 description 4
- 150000007942 carboxylates Chemical class 0.000 description 4
- 238000007334 copolymerization reaction Methods 0.000 description 4
- 238000005238 degreasing Methods 0.000 description 4
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- 239000000945 filler Substances 0.000 description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical group C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 4
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- 150000002334 glycols Chemical class 0.000 description 4
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 4
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- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 4
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- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 3
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- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 3
- CFKMVGJGLGKFKI-UHFFFAOYSA-N 4-chloro-m-cresol Chemical compound CC1=CC(O)=CC=C1Cl CFKMVGJGLGKFKI-UHFFFAOYSA-N 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 3
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- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical class ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
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- 229940035535 iodophors Drugs 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 159000000014 iron salts Chemical class 0.000 description 1
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical class OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 1
- 150000003951 lactams Chemical group 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229940102859 methylene diphosphonate Drugs 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 238000000569 multi-angle light scattering Methods 0.000 description 1
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
- WTNTZFRNCHEDOS-UHFFFAOYSA-N n-(2-hydroxyethyl)-2-methylpropanamide Chemical compound CC(C)C(=O)NCCO WTNTZFRNCHEDOS-UHFFFAOYSA-N 0.000 description 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 1
- CDKDZKXSXLNROY-UHFFFAOYSA-N octylbenzene Chemical compound CCCCCCCCC1=CC=CC=C1 CDKDZKXSXLNROY-UHFFFAOYSA-N 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000011146 organic particle Substances 0.000 description 1
- 235000010292 orthophenyl phenol Nutrition 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229960003330 pentetic acid Drugs 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 235000020030 perry Nutrition 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 239000010665 pine oil Substances 0.000 description 1
- 239000008389 polyethoxylated castor oil Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002643 polyglutamic acid Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920000137 polyphosphoric acid Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- ZZPKZRHERLGEKA-UHFFFAOYSA-N resorcinol monoacetate Chemical compound CC(=O)OC1=CC=CC(O)=C1 ZZPKZRHERLGEKA-UHFFFAOYSA-N 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000003009 skin protective agent Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 239000004296 sodium metabisulphite Substances 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000019351 sodium silicates Nutrition 0.000 description 1
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- JNYAEWCLZODPBN-CTQIIAAMSA-N sorbitan Polymers OCC(O)C1OCC(O)[C@@H]1O JNYAEWCLZODPBN-CTQIIAAMSA-N 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 235000011044 succinic acid Nutrition 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 238000010408 sweeping Methods 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 150000003608 titanium Chemical class 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- RRHXZLALVWBDKH-UHFFFAOYSA-M trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)OCC[N+](C)(C)C RRHXZLALVWBDKH-UHFFFAOYSA-M 0.000 description 1
- OEIXGLMQZVLOQX-UHFFFAOYSA-N trimethyl-[3-(prop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCNC(=O)C=C OEIXGLMQZVLOQX-UHFFFAOYSA-N 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical group CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- HXWNEEZPMZTSBJ-UHFFFAOYSA-N triphenyl(tetradecyl)phosphanium Chemical compound C=1C=CC=CC=1[P+](C=1C=CC=CC=1)(CCCCCCCCCCCCCC)C1=CC=CC=C1 HXWNEEZPMZTSBJ-UHFFFAOYSA-N 0.000 description 1
- FUMBGFNGBMYHGH-UHFFFAOYSA-M triphenyl(tetradecyl)phosphanium;bromide Chemical compound [Br-].C=1C=CC=CC=1[P+](C=1C=CC=CC=1)(CCCCCCCCCCCCCC)C1=CC=CC=C1 FUMBGFNGBMYHGH-UHFFFAOYSA-M 0.000 description 1
- RIOQSEWOXXDEQQ-UHFFFAOYSA-O triphenylphosphanium Chemical compound C1=CC=CC=C1[PH+](C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-O 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 238000012800 visualization Methods 0.000 description 1
- 239000008170 walnut oil Substances 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- CAAIULQYGCAMCD-UHFFFAOYSA-L zinc;hydroxymethanesulfinate Chemical compound [Zn+2].OCS([O-])=O.OCS([O-])=O CAAIULQYGCAMCD-UHFFFAOYSA-L 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Claims (17)
- Verwendung einer Zusammensetzung zur Behandlung und/oder zur Veränderung von harten Oberflächen, wobei die Zusammensetzung ein Copolymer enthält, das kationische Einheiten A und andere Einheiten B enthält, dadurch gekennzeichnet, dass- die Einheiten A mindestens eine quartäre Ammoniumgruppe oder eine Iniumgruppe enthalten und- die Einheiten B Einheiten sind, die Derivate eines Monomers der folgenden Formel sind:
CH2=CR1-CO-X-R2-OH
wobei- R1 ein Wasserstoffatom oder eine Methylgruppe ist- X = -O- oder -NH-- R2 eine zweiwertige Alkylgruppe mit 1 bis 4 Kohlenstoffatomen, vorzugsweise mit 2 Kohlenstoffatomen, ist- und die Einheiten A und B 50 bis 100 Mol-% der Einheiten des Copolymers darstellen. - Verwendung nach dem vorangehenden Anspruch, dadurch gekennzeichnet, dass das Copolymer ein lineares statistisches Copolymer ist.
- Verwendung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die Einheiten A und B 75 bis 100 Mol-% der Einheiten des Copolymers darstellen.
- Verwendung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass das Copolymer Folgendes enthält:- 1 bis 25 Mol-% der Einheiten A, vorzugsweise 3 bis 13 %,- 50 bis 99 Mol-% der Einheiten B, vorzugsweise 87 bis 97 % und- gegebenenfalls weitere Einheiten, wobei die Summe aller Einheiten gleich 100 Mol-% ist.
- Verwendung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass das Molverhältnis zwischen den Einheiten A und den Einheiten B zwischen 1/99 und 25/75, vorzugsweise zwischen 5/95 und 15/85 beträgt.
- Verwendung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass das Copolymer ferner Folgendes enthält:- nicht-ionische, hydrophile oder hydrophobe CN-Einheiten, und/oder- anionische oder potentiell anionische CA-Einheiten, und/oder- kationische oder potentiell kationische CC-Einheiten, die von den Einheiten A verschieden sind, und/oder- zwitterionische CZ-Einheiten.
- Verwendung nach Anspruch 6, dadurch gekennzeichnet, dass das Copolymer ferner CN-Einheiten enthält, die aus den Einheiten ausgewählt sind, die Derivate von einem Vinyllactam, vorzugsweise dem Vinylpyrrolidon, sind.
- Verwendung nach Anspruch 7, dadurch gekennzeichnet, dass das Copolymer Folgendes enthält:- 1 bis 25 Mol-% der Einheiten A, vorzugsweise 3 bis 13 %,- 50 bis 98 Mol-% der Einheiten B, vorzugsweise 55 bis 96 % und- 1 bis 49 Mol-% von Einheiten, die Derivate von einem Vinyllactam sind, vorzugsweise 5 bis 35 %, wobei die Summe aller Einheiten gleich 100 Mol-% ist.
- Verwendung nach einem der Ansprüche 1 bis 8, dadurch gekennzeichnet, dass- das Copolymer im Wesentlichen frei von zwitterionischen Einheiten ist und- das Copolymer im Wesentlichen frei von anionischen oder potentiell anionischen Einheiten ist.
- Verwendung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass- R1 ein Wasserstoffatom ist- X = -O-- R2 eine zweiwertige Alkylgruppe mit 1 bis 4 Kohlenstoffatomen, vorzugsweise mit 2 Kohlenstoffatomen, ist.
- Verwendung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die Einheiten A aus den Einheiten ausgewählt sind, die Derivate der folgenden kationischen Monomere A sind:- dem Trimethylammoniumpropylmethacrylatchlorid,- dem Trimethylammoniumethylacrylamid- oder -methacrylamidchlorid oder -bromid,- dem Trimethylammoniumbutylacrylamid- oder -methacrylamidmethylsulfat,- dem Trimethylammoniumpropylmethacrylamidmethylsulfat (MAPTA MeS),- dem (3-Methacrylamidpropyl)trimethylammoniumchlorid (MAPTAC),- dem (3-Acrylamidpropyl)trimethylammoniumchlorid (APTAC),- dem Methacryloyloxyethyltrimethylammoniumchlorid oder -methylsulfat,- den Acryloyloxyethyltrimethylammoniumsalzen (ADAMQUAT),- dem 1-Ethyl 2-vinylpyridinium-, 1-Ethyl 4-vinylpyridiniumbromid, -chlorid oder -methylsulfat,- dem N,N-Dimethyldiallylammoniumchlorid (DADMAC),- dem Dimethylaminopropylmethacrylamide,N-(3-chloro-2-hydroxypropyl) trimethylammoniumchlorid (DIQUAT),- dem Monomer der Formel
- dem 1-Ethyl 2-vinylpyridinium- oder 1-Ethyl 4-vinylpyridiniumbromid, -chlorid oder -methylsulfat und- deren Gemischen oder Verbindungen. - Verwendung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die Einheiten A Derivate von N,N-Dimethyldiallylammoniumchlorid (DADMAC) sind und die Einheiten B Derivate von Hydroxyethylacrylat (HEA) sind.
- Verwendung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die Zusammensetzung mindestens ein Tensid enthält.
- Verwendung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die Zusammensetzung mindestens einen flüssigen Träger, vorzugsweise einen wässrigen, alkoholischen oder hydro-alkoholischen Träger enthält.
- Verwendung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die Behandlung eine Reinigung einer harten Oberfläche ist.
- Verwendung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die Behandlung eine Reinigung von Geschirr, automatisch oder von Hand, ist.
- Verfahren zur Behandlung und/oder Veränderung von harten Oberflächen, umfassend einen Schritt des Auftragens einer Zusammensetzung nach einem der Ansprüche 1 bis 14 auf der Oberfläche, wobei die Zusammensetzung gegebenenfalls zuvor in Wasser verdünnt wird.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0804708A FR2935390B1 (fr) | 2008-08-26 | 2008-08-26 | Copolymere pour le traitement ou la modification de surfaces |
| PCT/EP2009/060825 WO2010023163A1 (fr) | 2008-08-26 | 2009-08-21 | Copolymere pour le traitement ou la modification de surfaces |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP2340299A1 EP2340299A1 (de) | 2011-07-06 |
| EP2340299B1 true EP2340299B1 (de) | 2016-03-30 |
Family
ID=40427228
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP09809323.0A Active EP2340299B1 (de) | 2008-08-26 | 2009-08-21 | Copolymer zur oberflächenverarbeitung oder modifizierung |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US8658586B2 (de) |
| EP (1) | EP2340299B1 (de) |
| FR (1) | FR2935390B1 (de) |
| WO (1) | WO2010023163A1 (de) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| EP3119837A1 (de) * | 2014-03-19 | 2017-01-25 | The Procter & Gamble Company | Flüssige reinigungsmittelzusammensetzung |
| WO2015139221A1 (en) * | 2014-03-19 | 2015-09-24 | Rhodia Operations | New copolymers useful in liquid detergent compositions |
| WO2015143644A1 (en) * | 2014-03-26 | 2015-10-01 | The Procter & Gamble Company | Cleaning compositions containing cationic polymers, and methods of making and using same |
| CN106459842B (zh) * | 2014-03-26 | 2020-05-12 | 巴斯夫欧洲公司 | 包含阳离子聚合物的清洁组合物及其制备和使用方法 |
| US9956153B2 (en) | 2014-08-01 | 2018-05-01 | Ecolab Usa Inc. | Antimicrobial foaming compositions containing cationic active ingredients |
| US11052431B2 (en) * | 2017-03-27 | 2021-07-06 | Clear Solutions USA, LLC | Compositions and methods for GRAS compliant cleaners for ethanol production equipment |
| BR112020026213A8 (pt) * | 2018-07-05 | 2021-04-06 | Chemetall Gmbh | método para tratar uma superfície metálica, composição aquosa ácida, mistura padrão, uso da composição aquosa ácida, e, substrato |
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| US4287280A (en) * | 1979-06-27 | 1981-09-01 | Xerox Corporation | Release agent applicators and method of applying release agent emulsions upon fusers in electrostatic copiers |
| GR74545B (de) * | 1980-11-28 | 1984-06-29 | Procter & Gamble | |
| US4557853A (en) * | 1984-08-24 | 1985-12-10 | The Procter & Gamble Company | Skin cleansing compositions containing alkaline earth metal carbonates as skin feel agents |
| US4728455A (en) * | 1986-03-07 | 1988-03-01 | Lever Brothers Company | Detergent bleach compositions, bleaching agents and bleach activators |
| US5108660A (en) * | 1990-01-29 | 1992-04-28 | The Procter & Gamble Company | Hard surface liquid detergent compositions containing hydrocarbyl amidoalkylenesulfobetaine |
| GB9003741D0 (en) * | 1990-02-19 | 1990-04-18 | Unilever Plc | Bleach activation |
| DE488868T1 (de) | 1990-11-30 | 1994-02-03 | Rhone Poulenc Chimie | Gerüststoff auf Basis von Alkalimetallsilikaten für Reinigungsmittelzusammensetzungen. |
| US5308532A (en) * | 1992-03-10 | 1994-05-03 | Rohm And Haas Company | Aminoacryloyl-containing terpolymers |
| FR2688798B1 (fr) | 1992-03-20 | 1994-10-14 | Rhobb Poulenc Chimie | Agent "builder" a base de silicate et d'un produit mineral. |
| US5280117A (en) * | 1992-09-09 | 1994-01-18 | Lever Brothers Company, A Division Of Conopco, Inc. | Process for the preparation of manganese bleach catalyst |
| US5536452A (en) * | 1993-12-07 | 1996-07-16 | Black; Robert H. | Aqueous shower rinsing composition and a method for keeping showers clean |
| BR9607019A (pt) | 1995-02-02 | 1997-10-28 | Procter & Gamble | Composições para lavadora automática de louça compreendendo catalisadores de cobalto |
| EP0807159B1 (de) | 1995-02-02 | 2000-05-24 | The Procter & Gamble Company | Maschinengeschirrspülmittel zusammensetzungen mit kobalt chelatkatalysatoren |
| DE69617209T2 (de) | 1995-02-02 | 2002-07-25 | Procter & Gamble | Verfahren zur entfernung von teeflecken in geschirrspülern mit zusammensetzungen enthaltend kobalt (iii)- katalysator |
| US5559261A (en) * | 1995-07-27 | 1996-09-24 | The Procter & Gamble Company | Method for manufacturing cobalt catalysts |
| CA2248476A1 (en) | 1997-10-01 | 1999-04-01 | Unilever Plc | Bleach activation |
| JP2001524586A (ja) | 1997-11-21 | 2001-12-04 | ザ、プロクター、エンド、ギャンブル、カンパニー | 泡安定剤を含有する液体皿洗洗剤 |
| BR9812789A (pt) | 1997-11-21 | 2000-10-17 | Procter & Gamble | Composições detergentes compreendendo realçadores de água de sabão poliméricos e seu uso |
| BR9812788A (pt) | 1997-11-21 | 2000-10-17 | Procter & Gamble | Composições lìquidas detergentes compreendendo intensificadores poliméricos de espuma |
| EP1032632A1 (de) | 1997-11-21 | 2000-09-06 | The Procter & Gamble Company | Schaumstabile flüssige geschirrspülmittel |
| EP1180130A1 (de) | 1999-05-26 | 2002-02-20 | The Procter & Gamble Company | Flüssige waschmittelzusammensetzungen enthaltend polymere schaumbilder |
| BR0010926B1 (pt) | 1999-05-26 | 2012-11-27 | polìmeros, composições e processos de uso para espumas, detergentes para lavagem de roupa, enxaguantes de banho e coagulantes. | |
| WO2000071652A2 (en) | 1999-05-26 | 2000-11-30 | The Procter & Gamble Company | Detergent compositions comprising polymeric suds volume and suds duration enhancers |
| DE60032597T2 (de) | 1999-05-26 | 2007-10-04 | The Procter & Gamble Company, Cincinnati | Verwendungsverfahren von zwitterionischen polymeren schaumbildern |
| EP1180132A1 (de) | 1999-05-26 | 2002-02-20 | The Procter & Gamble Company | Waschmittelzusammensetzungen enthaltend polymere schaumbilder mit verbesserten hautsanftheit und hautgefühl |
| MXPA01012191A (es) | 1999-05-26 | 2003-06-30 | Procter & Gamble | Composiciones y metodos para el uso de mejoradores de espuma de jabon poolimericos. |
| EP1194461B1 (de) | 1999-05-26 | 2008-10-08 | Rhodia Inc. | Blockpolymere, zusammensetzungen und verfahren zur verwendung in schäumen, waschmitteln, duschreinigern und koagulierungsmitteln |
| WO2000071660A1 (en) | 1999-05-26 | 2000-11-30 | The Procter & Gamble Company | Liquid detergent compositions comprising block polymeric suds enhancers |
| US6924260B2 (en) * | 1999-07-15 | 2005-08-02 | Rhodia Chimie | Method of reducing and preventing soil redeposition in an automatic dishwashing machine |
| FR2796391B1 (fr) | 1999-07-15 | 2003-09-19 | Rhodia Chimie Sa | Composition nettoyante pour surfaces dures |
| FR2796390B1 (fr) * | 1999-07-15 | 2001-10-26 | Rhodia Chimie Sa | Utilisation d'un polymere amphotere pour traiter une surface dure |
| FR2796392B1 (fr) | 1999-07-15 | 2003-09-19 | Rhodia Chimie Sa | Composition nettoyante comprenant un polymere hydrosoluble ou hydrodispersable |
| CA2398156A1 (en) * | 2000-02-02 | 2001-08-09 | Kenneth Wong | Polymers for laundry applications |
| JP2003003197A (ja) | 2001-01-05 | 2003-01-08 | Procter & Gamble Co:The | アミンオキシドモノマー単位含有高分子石鹸泡増進剤を使用する組成物および方法 |
| EP1404792B1 (de) * | 2001-07-11 | 2009-08-26 | The Procter and Gamble Company | Verfahren zur oberflächenreinigung mittels eines dispergierten polymers |
| CA2464692A1 (en) * | 2001-11-02 | 2003-05-15 | The Procter & Gamble Company | Composition containing a cationic polymer and water insoluble solid material |
| US6675093B1 (en) * | 2001-12-21 | 2004-01-06 | Garmin Ltd. | Systems, functional data, and methods for generating a route |
| FR2839977B1 (fr) * | 2002-05-27 | 2005-08-12 | Rhodia Chimie Sa | Utilisation, dans une composition lavante et rincante de la vaisselle en machine, d'un copolymere amphotere comme agent anti-redeposition des salissures |
| DE10257279A1 (de) * | 2002-12-07 | 2004-06-24 | Clariant Gmbh | Flüssige Bleichmittelkomponenten enthaltend amphiphile Polymere |
| US20070060488A9 (en) * | 2004-01-07 | 2007-03-15 | Henri Samain | Detergent cosmetic compositions comprising at least one polymer chosen from cationic and amphoteric polymers, at least one detergent surfactant, and at least one drawing polymer, and process of use |
| US20060025318A1 (en) * | 2004-04-22 | 2006-02-02 | Mireille Maubru | Composition for washing and conditioning keratin materials, comprising a carboxyalkyl starch, and process for the use thereof |
| FR2875811B1 (fr) | 2004-09-29 | 2008-08-22 | Rhodia Chimie Sa | Utilisation d'un alcool gras aliphatique dans les compositions moussantes detergentes pour l'entretien de surfaces dures ou textiles |
| DE602006014275D1 (de) * | 2005-08-04 | 2010-06-24 | Mitsubishi Chem Corp | Copolymer und reinigungsmittelzusammensetzungen damit |
| DE102005041349A1 (de) * | 2005-08-31 | 2007-03-01 | Basf Ag | Reinigungsformulierungen für die maschinelle Geschirrreinigung enthaltend hydrophil modifizierte Polycarboxylate |
| US7867969B2 (en) * | 2005-10-28 | 2011-01-11 | L'oreal S.A. | Composition for washing keratin materials comprising a magnesium salt anionic surfactant |
| EP2051780A1 (de) * | 2006-08-11 | 2009-04-29 | Basf Se | Verwendung von kationischen copolymerisaten aus aminhaltigen acrylaten und n-vinylimidazoliumsalzen in haarkosmetischen zubereitungen |
| EP1967545A1 (de) * | 2007-03-09 | 2008-09-10 | Rohm and Haas France SAS | Kationisches Polymer-Latex |
| FR2917968B1 (fr) * | 2007-06-29 | 2010-02-26 | Oreal | Compositions cosmetiques detergentes comprenant quatre tensioactifs, un polymere cationique et un agent benefique et utilisation |
-
2008
- 2008-08-26 FR FR0804708A patent/FR2935390B1/fr not_active Expired - Fee Related
-
2009
- 2009-08-21 US US13/061,120 patent/US8658586B2/en active Active
- 2009-08-21 EP EP09809323.0A patent/EP2340299B1/de active Active
- 2009-08-21 WO PCT/EP2009/060825 patent/WO2010023163A1/fr active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| US8658586B2 (en) | 2014-02-25 |
| WO2010023163A1 (fr) | 2010-03-04 |
| FR2935390B1 (fr) | 2012-07-06 |
| FR2935390A1 (fr) | 2010-03-05 |
| EP2340299A1 (de) | 2011-07-06 |
| US20110195889A1 (en) | 2011-08-11 |
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