EP2329503B1 - Mit geschäumtem polyurethan ummantelte elektrische leitung - Google Patents

Mit geschäumtem polyurethan ummantelte elektrische leitung Download PDF

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Publication number
EP2329503B1
EP2329503B1 EP09778913.5A EP09778913A EP2329503B1 EP 2329503 B1 EP2329503 B1 EP 2329503B1 EP 09778913 A EP09778913 A EP 09778913A EP 2329503 B1 EP2329503 B1 EP 2329503B1
Authority
EP
European Patent Office
Prior art keywords
layer
foamed
insulation
layers
polyurethane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP09778913.5A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP2329503A1 (de
Inventor
Frank Zappe
Oliver Brambach
Helmut Wichmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Coroplast Fritz Mueller GmbH and Co KG
Original Assignee
Coroplast Fritz Mueller GmbH and Co KG
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Publication date
Application filed by Coroplast Fritz Mueller GmbH and Co KG filed Critical Coroplast Fritz Mueller GmbH and Co KG
Publication of EP2329503A1 publication Critical patent/EP2329503A1/de
Application granted granted Critical
Publication of EP2329503B1 publication Critical patent/EP2329503B1/de
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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/18—Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
    • H01B7/185—Sheaths comprising internal cavities or channels
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/302—Polyurethanes or polythiourethanes; Polyurea or polythiourea
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
    • H01B3/445—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds from vinylfluorides or other fluoroethylenic compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/448—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from other vinyl compounds

Definitions

  • the invention relates to a sheathed electrical line, comprising at least one electrical conductor with an insulation, which consists of a thermoplastic elastomer (TPE), and a jacket consisting of a plastic.
  • TPE thermoplastic elastomer
  • a sheathed electrical lead comprising at least one electrical conductor with insulation and a sheath made of a plastic material is disclosed in US Pat DE 202 15 523 U1 described.
  • This line can be used in particular for anti-lock braking systems and sensors of speed measuring systems of motor vehicles and has proven itself in practice.
  • the line has a jacket made of polyurethane.
  • the sheath consists in particular of polyether polyurethane, which may preferably have a hardness in the range of 75 to 95 Shore A.
  • EVA ethylene-vinyl acetate copolymer
  • said utility model also provides for the insulation of the polyurethane conductor, this having a hardness in the range of 55 to 64 Shore D.
  • this polyurethane material is a thermoplastic material which is reflowable and therefore can easily be subjected to recycling.
  • the DE 34 44 500 A1 describes an electrical or optical cable, in particular a multi-core electrical power cable whose head whose soul consists of the wires is surrounded by a sheath of insulating materials. At least one outer layer of this envelope consists entirely or partially of a radiation-crosslinked polyurethane. In one embodiment described two-layer structure of the envelope, this consists in the region of an inner jacket made of silicone rubber, which is surrounded by an outer sheath, which forms a protective cover of the radiation-crosslinked polyurethane.
  • the protective cover can consist of a foamed and crosslinked polyurethane.
  • the DE 30 05 615 A1 describes an electric flexible cable with special buoyancy, in which a flexible base cable coaxially with a foamed plastic tape with a large pore volume, preferably on polyethylene or polyurethane-based, is wrapped in a spiral.
  • the boundary of the outer contour formed by the enveloping band is effected by a likewise coaxially arranged above plastic sheath, preferably based on polyurethane.
  • the DE 202 15 523 U1 refers to the technical requirements placed on such pipelines Bosch regulation VS 18296-NKA (October 2001 ) and, in addition to its recyclability, refers in particular to the technical parameters of heat distortion resistance and fatigue strength according to VDE 0472-603 / J.
  • the WO 01/61711 discloses a conduit of the initially mentioned type with a polymer-based shell with inorganic, flame-retardant additives.
  • the jacket in this case comprises an outer, an intermediate and an inner layer, wherein the intermediate layer is foamed.
  • the WO 01/61711 A1 refers to a generic cable WO 98/52197 A1 whose flame retardance is to be improved.
  • the prior art cable already had a layer of a foamed polymeric material having predetermined mechanical strength properties and a predetermined degree of foaming, whereby a high impact strength could be set.
  • the present invention has for its object to provide an electrical line of the type mentioned, which has an improved quality in view of the aforementioned mechanical and processing properties.
  • the jacket consists of a thermoplastic polyurethane elastomer and comprises an inner, an intermediate and an outer layer, wherein the outer layer and / or the inner layer is a foamed layer, and wherein the intermediate layer is a non-foamed layer , It can be provided in detail that the sheath consists of several sub-layers, of which at least one is foamed.
  • a foamed layer which may be in particular a gas-filled closed-cell material, advantageously reduced by the invention, the specific mass of the line, the stripping over large and oversized cable lengths is facilitated, and improve the torsional behavior as well by a damping effect of the foamed layer, the mechanical pressure resistance and bending fatigue strength.
  • Thermoplastic polyurethane elastomers are semi-crystalline materials and belong to the class of thermoplastic elastomers. They are high performance materials, which in their characteristic image dynamic load capacity, high flexibility in a wide temperature range, high wear resistance and buckling and breaking strength (tear and tear resistance) with good resistance to the influence of oil, grease and solvents, the weather, ozone and Combine UV radiation, as well as hydrolytic substances and microbes. They are reflowable and can therefore easily be subjected to recycling.
  • thermoplastic polyurethanes with blowing agents for the production of shoe soles.
  • the hard segments are formed by diisocyanates used in the preparation and short-chain diols, and the soft segments by diisocyanates and long-chain diols.
  • a sheathed electrical line consists of at least one electrical conductor 1, which is surrounded by an insulation 2, and a plastic sheath 3.
  • electrical conductors 1 are shown with their insulation 2 by way of example ,
  • the conductor 1 may consist of an electrically conductive material in the form of strands or in the form of a wire, which may preferably have a diameter in the range of 0.03 mm to 3.0 mm.
  • a wire used for the conductor 1 can also be formed from a plurality of individual wires 1 a.
  • the insulation 2 of the conductor 1 consists of a thermoplastic elastomer (TPE), in particular styrene-containing TPE, a polyolefin such as polypropylene (PP), an ethylene-vinyl acetate copolymer (EVA) or a fluoropolymer, such as FEP (tetrafluoroethylene-hexafluoropropylene copolymer ).
  • TPE thermoplastic elastomer
  • PP polypropylene
  • EVA ethylene-vinyl acetate copolymer
  • FEP tetrafluoroethylene-hexafluoropropylene copolymer
  • the jacket 3 comprises a foamed layer 4.
  • the jacket 3 consists of a thermoplastic polyurethane (TPU), which may in particular be a polyether polyurethane.
  • TPU thermoplastic polyurethane
  • the use of a polyester-polyurethane is due to its higher thermal stability possible with advantage.
  • an intermediate layer 7 is also disposed in the shell 3 between the outer layer 5 and the inner layer 6.
  • this intermediate layer 7 is a non-foamed layer
  • the outer layer 5 and the inner layer 6 are foamed layers 4.
  • the inner layer 6 is the foamed layer 4
  • the outer layer 5 is unfoamed.
  • the number of conductors 1 or the geometric dimensions of an electrical line according to the invention such as a thickness of the individual layers 3, 4, 5, 6, 7, vary within wide limits, without departing from the scope of the invention.
  • a degree of foaming of the foamed layer 4 can also be varied. Foaming degree is understood as meaning a volume fraction of gas in the total volume of the foamed layer.
  • the degree of foaming within the material-related limits in combination with the optimum thickness ratios of the individual layers 3, 4, 5, 6, 7 can be decisive for the quality of a particularly high torsional and flexural fatigue-resistant electrical line according to the invention.
  • the layers 4, 5, 6, 7 can be connected to each other in particular by co-or tandem extrusion.
  • the strength of the adhesion of the individual layers 4, 5, 6, 7 to one another is determined both by the production method and the nature of the layer materials.
  • a structure of the shell 3 with more than three, such as four or five layers, of which at least two layers are foamed layers 4, falls within the scope of the invention.
  • the outer layer 5, the inner layer 6 and / or one or two intermediate layers 7 may be foamed layers 4.
  • a fluorine-containing polymer layer lying above a TPU layer is considered to be particularly suitable for reducing swelling of the TPU layer in various media.
  • isolation 2 may preferably from the aforementioned DE 202 15 523 U1 known material can be used, with which the further advantage is connected, that the conductor 1 can be used in bare, untinned version.
  • the applications of a line according to the invention are not limited to applications for anti-lock braking systems and sensors of speed measuring systems of motor vehicles. They are preferably wherever high torsional and / or bending fatigue resistance is required, such as in certain sensor and drag chain lines.

Landscapes

  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Insulated Conductors (AREA)
  • Organic Insulating Materials (AREA)
  • Polyurethanes Or Polyureas (AREA)
EP09778913.5A 2008-09-03 2009-01-05 Mit geschäumtem polyurethan ummantelte elektrische leitung Active EP2329503B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE200820011737 DE202008011737U1 (de) 2008-09-03 2008-09-03 Ummantelte elektrische Leitung
PCT/EP2009/050035 WO2010025963A1 (de) 2008-09-03 2009-01-05 Mit geschäumten polyurethan ummantelte elektrische leitung

Publications (2)

Publication Number Publication Date
EP2329503A1 EP2329503A1 (de) 2011-06-08
EP2329503B1 true EP2329503B1 (de) 2016-04-13

Family

ID=40601438

Family Applications (1)

Application Number Title Priority Date Filing Date
EP09778913.5A Active EP2329503B1 (de) 2008-09-03 2009-01-05 Mit geschäumtem polyurethan ummantelte elektrische leitung

Country Status (8)

Country Link
EP (1) EP2329503B1 (hu)
CN (1) CN101667472B (hu)
DE (1) DE202008011737U1 (hu)
ES (1) ES2573264T3 (hu)
HK (1) HK1142166A1 (hu)
HU (1) HUE027761T2 (hu)
PL (1) PL2329503T3 (hu)
WO (1) WO2010025963A1 (hu)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2584567B1 (de) * 2011-10-20 2016-02-10 Nexans Leicht abzumantelndes elektrisches kabel
CN102496415A (zh) * 2011-12-26 2012-06-13 宝胜科技创新股份有限公司 一种热塑性弹性体发泡绝缘电缆及其制作工艺
CN103903788A (zh) * 2014-03-04 2014-07-02 成都科创佳思科技有限公司 高压交联聚乙烯绝缘电力电缆
CN105006298A (zh) * 2015-06-26 2015-10-28 张家港金海港电线电缆有限公司 一种电缆制作工艺
US20180261355A1 (en) 2015-09-03 2018-09-13 Solvay Specialty Polymers Italy S.P.A. Cable jackets
CN106558368B (zh) * 2015-09-24 2018-11-20 深圳市联嘉祥科技股份有限公司 一种电动汽车充电电缆及其制备方法
CN109494002A (zh) * 2018-12-26 2019-03-19 江苏永鼎电气有限公司 一种智能装备控制电缆
EP4113541A1 (de) 2021-07-01 2023-01-04 Coroplast Fritz Müller GmbH & Co. KG Ladeleitung mit optimierter handhabbarkeit
DE202021103508U1 (de) 2021-07-01 2022-10-11 Coroplast Fritz Müller GmbH & Co. K. G. Ladeleitung mit optimierter Handhabbarkeit

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001061711A1 (en) * 2000-02-21 2001-08-23 Pirelli Cavi E Sistemi S.P.A. Impact-resistant self-extinguishing cable

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3005615A1 (de) * 1980-02-15 1981-08-20 U.I. Lapp Kg, 7000 Stuttgart Elektrisches, flexibles kabel mit besonderer schwimmfaehigkeit
DE3444500A1 (de) * 1984-05-24 1985-11-28 kabelmetal electro GmbH, 3000 Hannover Schwer entflammbares elektrisches oder optisches kabel
CN1162822A (zh) * 1997-02-14 1997-10-22 吴江市盛泽通信电缆厂 皮/泡沫/皮物理发泡电缆及其制作工艺
CN2456271Y (zh) * 2000-12-31 2001-10-24 天水铁路电缆工厂 铁路数字信号电缆
DE20215523U1 (de) * 2002-10-09 2004-03-11 Coroplast Fritz Müller Gmbh & Co. Kg Ummantelte elektrische Leitung, insbesondere für Antiblockiersysteme und Fühler von Drehzahlmeßsystemen von Kraftfahrzeugen
CN1545102A (zh) * 2003-11-24 2004-11-10 珠海宇讯同轴电缆有限公司 同轴电缆
CN1822245A (zh) * 2005-12-29 2006-08-23 江苏亨鑫科技有限公司 信号传输用同轴电缆及物理发泡绝缘层制备和模具

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001061711A1 (en) * 2000-02-21 2001-08-23 Pirelli Cavi E Sistemi S.P.A. Impact-resistant self-extinguishing cable

Also Published As

Publication number Publication date
EP2329503A1 (de) 2011-06-08
CN101667472A (zh) 2010-03-10
PL2329503T3 (pl) 2016-10-31
DE202008011737U1 (de) 2010-01-14
ES2573264T3 (es) 2016-06-06
HK1142166A1 (en) 2010-11-26
HUE027761T2 (hu) 2016-10-28
CN101667472B (zh) 2012-02-29
WO2010025963A1 (de) 2010-03-11

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