EP2313614A2 - Verfahren zum bau eines unterirdischen tunnels oder eines lochs zur herstellung eines undurchdringlichen pfropfens zur lagerung von gefährlichem, insbesondere radioaktivem abfall - Google Patents
Verfahren zum bau eines unterirdischen tunnels oder eines lochs zur herstellung eines undurchdringlichen pfropfens zur lagerung von gefährlichem, insbesondere radioaktivem abfallInfo
- Publication number
- EP2313614A2 EP2313614A2 EP09737050A EP09737050A EP2313614A2 EP 2313614 A2 EP2313614 A2 EP 2313614A2 EP 09737050 A EP09737050 A EP 09737050A EP 09737050 A EP09737050 A EP 09737050A EP 2313614 A2 EP2313614 A2 EP 2313614A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- gallery
- face
- prior
- digging
- plug
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims abstract description 52
- 238000003860 storage Methods 0.000 title claims abstract description 20
- 239000002699 waste material Substances 0.000 title abstract description 9
- 231100001261 hazardous Toxicity 0.000 title abstract description 4
- 230000002285 radioactive effect Effects 0.000 title abstract description 3
- 239000000463 material Substances 0.000 claims abstract description 26
- 238000007789 sealing Methods 0.000 claims abstract description 12
- 238000009434 installation Methods 0.000 claims abstract description 10
- 230000008014 freezing Effects 0.000 claims abstract description 5
- 238000007710 freezing Methods 0.000 claims abstract description 5
- 230000003014 reinforcing effect Effects 0.000 claims abstract 2
- 238000002360 preparation method Methods 0.000 claims description 14
- 230000002787 reinforcement Effects 0.000 claims description 10
- 238000009412 basement excavation Methods 0.000 claims description 9
- 238000011144 upstream manufacturing Methods 0.000 claims description 9
- 238000002513 implantation Methods 0.000 claims description 7
- 238000012360 testing method Methods 0.000 claims description 6
- 238000004873 anchoring Methods 0.000 claims description 5
- 239000002920 hazardous waste Substances 0.000 claims description 5
- 230000007774 longterm Effects 0.000 claims description 5
- 239000007789 gas Substances 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- 230000002250 progressing effect Effects 0.000 claims 2
- 238000010276 construction Methods 0.000 description 8
- 230000035882 stress Effects 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000005553 drilling Methods 0.000 description 5
- 239000010438 granite Substances 0.000 description 5
- 239000002901 radioactive waste Substances 0.000 description 5
- 239000000440 bentonite Substances 0.000 description 4
- 229910000278 bentonite Inorganic materials 0.000 description 4
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 4
- 238000006073 displacement reaction Methods 0.000 description 4
- 210000004027 cell Anatomy 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 239000011435 rock Substances 0.000 description 3
- RYXPMWYHEBGTRV-UHFFFAOYSA-N Omeprazole sodium Chemical compound [Na+].N=1C2=CC(OC)=CC=C2[N-]C=1S(=O)CC1=NC=C(C)C(OC)=C1C RYXPMWYHEBGTRV-UHFFFAOYSA-N 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 235000015076 Shorea robusta Nutrition 0.000 description 1
- 244000166071 Shorea robusta Species 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 210000002287 horizontal cell Anatomy 0.000 description 1
- 238000012613 in situ experiment Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 230000000803 paradoxical effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000002915 spent fuel radioactive waste Substances 0.000 description 1
- 210000000352 storage cell Anatomy 0.000 description 1
- 238000013517 stratification Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21D—SHAFTS; TUNNELS; GALLERIES; LARGE UNDERGROUND CHAMBERS
- E21D9/00—Tunnels or galleries, with or without linings; Methods or apparatus for making thereof; Layout of tunnels or galleries
- E21D9/001—Improving soil or rock, e.g. by freezing; Injections
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21D—SHAFTS; TUNNELS; GALLERIES; LARGE UNDERGROUND CHAMBERS
- E21D9/00—Tunnels or galleries, with or without linings; Methods or apparatus for making thereof; Layout of tunnels or galleries
- E21D9/10—Making by using boring or cutting machines
- E21D9/1053—Making by using boring or cutting machines for making a slit along the perimeter of the tunnel profile, the remaining core being removed subsequently, e.g. by blasting
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21F—SAFETY DEVICES, TRANSPORT, FILLING-UP, RESCUE, VENTILATION, OR DRAINING IN OR OF MINES OR TUNNELS
- E21F17/00—Methods or devices for use in mines or tunnels, not covered elsewhere
- E21F17/16—Modification of mine passages or chambers for storage purposes, especially for liquids or gases
Definitions
- the present invention relates to a method for producing an underground gallery, or a well, for a deep installation in a geological medium intended to receive hazardous and especially radioactive waste. This process will make it possible to construct a waterproof cap during the closure of the storage.
- the future of hazardous waste has long been a problem, particularly for radioactive waste from nuclear power plants or spent fuel reprocessing plants.
- nuclear waste particularly high-level and long-lived waste
- long-term storage in a "geological" layer that is to say in deep layers of a material selected for its purpose, is envisaged. very high mechanical and chemical stability.
- the choice of these layers may vary according to the country and the site, for example to a depth of the order of 300 to 500m and in materials such as argillites, shales or granite.
- some of these wastes can create additional constraints, for example by producing heat during the first stages of storage, for a few hundred years.
- the methods envisaged for sealing are based on the filling of access tunnels with bentonite, and the sealing of tunnels by injecting a suspension of bentonite into the walls so that they resist hydraulic pressure in the case water circulation ducts.
- the stability and sealing performance for this type of storage is an important point, to prevent water infiltrations from entering the storage cells, at the risk of damaging the containers, and do not come out at the risk of contaminating the surrounding subsoil and groundwater in their underground route.
- EDZ Excavated Damaged Zone
- EDZ Excavated Damaged Zone
- These cracked areas do not always occur immediately, but develop over a period of time, depending on the nature of the environment and the depth of storage.
- Their extension can be signaled by audible crunches. For example, in the Mont-Blanc tunnel, in granite and under heavy cover, this period lasted more than a week.
- EP 1 760 256 Another solution proposed by EP 1 760 256 is to use an automated machine provided with a tool carrying arm to resize the walls to a certain thickness, to eliminate the damaged part and thus achieve a specific profile before the pouring of a concrete plug.
- this new excavation itself causes a damaged area because of the tools used, or even simply that there is a new relaxation of internal pressures that still remain behind the new surfaces exposed.
- An object of the invention is to allow a good seal to gases or liquids in good conditions of reliability and stability over time, around the galleries or wells once the plugs are sealed.
- the invention proposes a method of producing a gallery or wells in particular according to the claims below.
- the invention proposes to provide this plug in a gallery that has not been disturbed by a face size. For this, as paradoxical as it may seem, it is proposed to make part of the gallery (or well) in an area far from the face of size, that is to say, in front of the face of size.
- One principle of this method is to remove the face of size, which is the main source of damage and cracking of the host mass, the area where we must provide for the installation of a plug, or less of
- the invention proposes a method of producing a gallery leading to an underground installation intended for the medium or long term storage of hazardous waste.
- this method comprises an excavation of at least a predetermined length of this gallery by employing a method of preparation prior to digging.
- any method of prior preparation is considered unnecessary in very stable materials such as those excavated during the digging of such storage facilities.
- no reinforcement can be obtained with respect to this type of material, or only to a small extent.
- the stable and often strong nature of such materials for example granite or argillite, makes any further processing of the material before excavation difficult and expensive, in time as well as in work and equipment.
- the invention proposes to use such a method of preparation (protection and / or reinforcement), not to facilitate the construction of the gallery but to obtain a better subsequent seal of this gallery, despite the additional efforts that may represent and despite this prejudice of uselessness.
- the invention proposes to minimize as much as possible the dimensions of the holes or boreholes used to perform this prior preparation, which allows to minimize the risk of damage caused by these preliminary drilling or to avoid them completely.
- several small boreholes may be used rather than a single bore of larger dimensions, for example to excavate the volume necessary for the establishment of a prior protection in front of the face or to allow the implementation place of tie rods.
- the protective structures implanted prior to the main excavation will preferably have compact dimensions. Preferably, they will be full and it will avoid making a posteriori empty spaces or compressible inside to limit the risk of damage that could create future crash. It should be noted that this choice goes rather against the methods often used to obtain a better mechanical resistance by limiting the contribution of material, in which it is common to use or to realize hollow structures having large external dimensions
- FIG. 1 is a schematic perspective view of a multi-storage level cavities within an underground radioactive waste storage facility
- FIG. 2 is a diagrammatic view of a horizontal tunnel in the course of digging according to the prior art and of the damaged zone surrounding it, respectively in cross-section, in horizontal section, and in vertical longitudinal section in the region; the face of the waist
- - FIGURE 3 is a schematic vertical half-sectional view of a gallery portion made according to the first embodiment with prior implantation of retaining elements;
- FIGURE 4 is a schematic view of a frustoconical shell 324 constructed around a portion of the gallery of FIGURE 3;
- FIGURE 5 is a schematic horizontal sectional view of the gallery of FIGURE 3;
- FIGURE 6 is a schematic horizontal sectional view of a tunnel being excavated according to the second embodiment of the invention using consumable anchor bolts implanted alternately in three successive groups;
- FIG. 7 is a schematic view in horizontal section of a gallery being excavated according to an embodiment combining prior implantations of retaining elements a prior reinforcement of the working face by means of consumable anchor bolts;
- FIGURE 8 is a schematic view in longitudinal section of a gallery comprising a sealing plug during leak test.
- gallery is used here to indicate indifferently a horizontal gallery, or also a vertical shaft, or a descent, or also pipes at all intermediate inclinations.
- FIG. 3 illustrates a first embodiment of the invention using an implementation of retaining elements 321 to 324 before the digging of the gallery and as and when progession 219 (see FIGURE 2).
- the part 301 has already been hollowed in the conventional manner.
- the intermediate portion 302 is being excavated and is intended to subsequently receive a sealing plug.
- Part 303 is not yet dug, and will be conventionally after completion of the intermediate portion 302.
- the portion 302 is constructed sheltered frustoconical hulls 321 to 324 of horizontal axis and nested one inside the other.
- the shells already constructed 321 to 323, as well as the hull 324 under construction, are made by means of a series of boreholes 32410 made in the periphery of the face of size 309. These drillings are contiguous to each other and inclined so as to move away from the axis of the gallery to dig. They are for example dug by means of a chain mechanism, comparable to a chainsaw, but working end.
- These holes 32410 are then filled 32419 concrete to form a segment 3241 forming part of a truncated cone 324 (shown separately in FIGURE 4) surrounding an area 3240 of the future gallery.
- FIGURE 5 thus illustrates the result of the operation in a long sectional cut: the parts 301 and 303 normally excavated each have a damaged zone 391 and 393, in contrast to the portion 302 intended to receive the plug.
- the digging of the housing 3241 to receive the concrete to form the hull portion 324 creates only negligible damage, perhaps a hundred times smaller than that of the zones 391 and 393 generated by the conventional digging of the gallery.
- each of the holes 32410 made has a very small dimension which therefore causes only a very small damaged area, or none at all.
- These holes are for example of a maximum diameter of 10cm to 15cm, or even 15cm to 20cm in the case of chain drilling equipment.
- the frustoconical hulls 322, 323 and 324 have thus been entirely made in areas undisturbed by a face of size, and do not have the disadvantages of the damaged zone (EDZ) known in the current state of the art.
- EDZ damaged zone
- FIG. 6 illustrates a second embodiment of the invention using consumable anchor bolts implanted in the material in front of the face of the face and / or on its periphery, and as the progression progresses.
- the first part 601 has already been dug, in a conventional manner.
- the second part 602 is being excavated and is intended to subsequently receive a sealing plug.
- the pre-build method of preparation used herein includes the implantation of tie rods 621 to 623 consumable and sealed onto full length, to arm the front of size 609.
- These tie rods are embedded in narrow holes drilled in the front of the tail 609 and / or its periphery.
- These tie rods are for example fiberglass with a length of the order of three times the diameter of the gallery, for example between 2.5 and 4 times this diameter. They are sealed in the material of the face of size; they are distributed substantially uniformly over the surface of the face and / or its periphery.
- This armed volume may correspond to the substantially cylindrical volume of the future duct, but may also be provided to occupy a slightly conical volume widening in the direction of progression 609, at an angle of, for example, between 0 ° and 10 °.
- These tie rods strengthen the area of the face. They are of different lengths 621, 622 and 623 and implanted by successive thirds. They are destroyed during the advanced digging along the entire length of the area where we try to avoid deformation of the medium, so its cracking. New long rods are implanted by a third of the total number of tie rods each time the digging advances one-third of the length of these rods.
- a third embodiment which does not require any particular representation here, comprises the use of a method of freezing the solid mass beyond the face of the face, which allows an increase in the resistance of the medium when the interstitial water is turned into ice over ten meters in length.
- the material is then excavated in its frozen form, which prevents the formation of a damaged area around the excavated gallery.
- This freezing can be carried out with means and according to methods used in extreme cases for the crossing of an unstable zone by a tunnel. It can be done on all or part of the tunnel volume in the location of the future cap.
- the method according to the invention preferably comprises a preliminary thermo-hydro-mechanical study of the material to be digged.
- FIGURE 7 illustrates an embodiment combining prior implementations of support elements and means for anchoring the face, for example as described above.
- the anchoring means may be combined without departing from the scope of the invention.
- FIGURE 7 illustrates an embodiment combining prior implementations of support elements and means for anchoring the face, for example as described above.
- the anchoring means may be combined without departing from the scope of the invention.
- FIGURE 7 illustrates an embodiment combining prior implementations of support elements and means for anchoring the face, for example as described above.
- the anchoring means for example as described above.
- 621 to 623 may be arranged to exceed EA thickness outside the 600 series, for example to still imin the damage caused by the frustoconical hulls of drilling 321 to 323
- the invention may then include the specific use of a prior reinforcement method in certain areas of the gallery or the face when there is a greater risk of creating an EDZ.
- the invention also proposes a method for verifying the tightness of a plug, for example installed in an excavated tunnel according to the invention.
- FIG. 8 thus illustrates how to test a gallery produced according to the invention on a part 802 and comprising a plug 805 and the device for checking the tightness around the gallery.
- the tested gallery comprises the treated part 802, which has been produced according to the invention. It is located between a part 803 called upstream on one side, for example on the storage side, and a part 801 called downstream on the other side.
- a central plug 805 is made according to known methods within the treated portion 802.
- an upstream annular chamber 831 is created by installing a plug 832 d it upstream.
- an annular chamber 811 called downstream is created by installing a plug 812 called downstream.
- the upstream plugs 832 and downstream 812 may also be an integral part of the central plug 805, which then has a shape releasing an annular space forming the upstream 831 and downstream 811 chambers.
- a pressure pi is imposed in the upstream chamber 831 and the evolution of the pressure p2 prevailing in the downstream chamber 811 is recorded to evaluate the leakage rate and the leaktightness of the gallery around the central plug 805.
- Wileveau Y., Bernier F. Similarities in the hydraulic-mechanical response of Callovo-Oxfordian clay and clay boom during excavation gallery. Clays in Natural & Engineered Barriers for Radioactive Waste Confinement. 3 rd International Meeting. Lille, September 17 to 20, 2007. page 149.
Landscapes
- Engineering & Computer Science (AREA)
- Mining & Mineral Resources (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Environmental & Geological Engineering (AREA)
- Soil Sciences (AREA)
- Lining And Supports For Tunnels (AREA)
- Processing Of Solid Wastes (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0854876A FR2934007B1 (fr) | 2008-07-17 | 2008-07-17 | Procede de construction d'une galerie souterraine ou d'un puits permettant de realiser un bouchon etanche pour un stockage de dechets dangereux et notamment radioactifs. |
PCT/FR2009/051394 WO2010007305A2 (fr) | 2008-07-17 | 2009-07-13 | Procede de construction d'une galerie souterraine ou d'un puits permettant de realiser un bouchon etanche pour un stockage de dechets dangereux et notamment radioactifs |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2313614A2 true EP2313614A2 (de) | 2011-04-27 |
Family
ID=40303757
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09737050A Withdrawn EP2313614A2 (de) | 2008-07-17 | 2009-07-13 | Verfahren zum bau eines unterirdischen tunnels oder eines lochs zur herstellung eines undurchdringlichen pfropfens zur lagerung von gefährlichem, insbesondere radioaktivem abfall |
Country Status (5)
Country | Link |
---|---|
US (1) | US20110116868A1 (de) |
EP (1) | EP2313614A2 (de) |
JP (1) | JP2011528119A (de) |
FR (1) | FR2934007B1 (de) |
WO (1) | WO2010007305A2 (de) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102102536B (zh) * | 2010-12-15 | 2013-02-13 | 中国神华能源股份有限公司 | 一种利用废弃巷道贮存瓦斯的方法 |
CN102071945B (zh) * | 2010-12-29 | 2012-11-28 | 上海隧道工程股份有限公司 | 三面封闭已建结构下盾构进出洞施工方法 |
FR2974141B1 (fr) * | 2011-04-14 | 2013-05-03 | Irsn | Procede et dispositif de forage non destructif |
TWI789397B (zh) * | 2017-06-05 | 2023-01-11 | 美商深絕公司 | 於地下岩層中儲存危險材料 |
CN110685697A (zh) * | 2019-09-28 | 2020-01-14 | 中铁九局集团第四工程有限公司 | 联络通道的冻结施工方法及冻结系统 |
CN111119929B (zh) * | 2019-12-29 | 2024-08-27 | 中铁二院工程集团有限责任公司 | 一种大型超高岩溶空洞隧道格构式防落石结构及构筑方法 |
CN113153344B (zh) * | 2021-04-08 | 2024-05-28 | 江苏锐成机械有限公司 | 真空密闭排渣的高放废物处置坑掘进系统 |
CN113515840B (zh) * | 2021-04-14 | 2022-04-15 | 中国科学院武汉岩土力学研究所 | 一种岩体开挖扰动区的预测方法以及相关设备 |
CN114060038B (zh) * | 2021-10-29 | 2024-02-13 | 五邑大学 | 一种冻结加固装置及其盾构对接加固方法 |
CN115545561A (zh) * | 2022-11-09 | 2022-12-30 | 交通运输部公路科学研究所 | 一种公路隧道设施安全可靠服役风险评估方法 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
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US3332244A (en) * | 1964-10-28 | 1967-07-25 | American Cyanamid Co | Reinforcing bolts |
US3597929A (en) * | 1968-08-02 | 1971-08-10 | Albert G Bodine | Method and device for tunneling |
US3968655A (en) * | 1973-07-13 | 1976-07-13 | Mcglothlin William K | Method of reinforcing tunnels before excavation |
SE448194B (sv) * | 1985-04-02 | 1987-01-26 | Boliden Ab | Forfarande for tillredning av en anleggning for forvaring av radioaktivt avfall i berg |
JPH07107359B2 (ja) * | 1988-06-15 | 1995-11-15 | 株式会社小松製作所 | 地下空洞施工法及びトンネル掘削機 |
IT1234069B (it) * | 1989-04-28 | 1992-04-29 | Trevi Spa | Procedimento per l'esecuzione del rivestimento di una galleria ed apparecchiatura per l'attivazione di tale procedimento |
JP3071252B2 (ja) * | 1991-08-28 | 2000-07-31 | 前田建設工業株式会社 | 軟弱地盤トンネル掘削工法 |
IT1256533B (it) * | 1992-02-28 | 1995-12-07 | Trevi Spa | Attrezzatura per lo scavo di gallerie. |
JPH1018755A (ja) * | 1996-06-28 | 1998-01-20 | Ohbayashi Corp | トンネル掘削工法 |
US6238138B1 (en) * | 1997-07-14 | 2001-05-29 | Henry Crichlow | Method for temporary or permanent disposal of nuclear waste using multilateral and horizontal boreholes in deep islolated geologic basins |
US6409650B2 (en) * | 1999-08-25 | 2002-06-25 | Terralog Technologies Usa, Inc. | Method for biosolid disposal and methane generation |
JP3769721B2 (ja) * | 2000-09-06 | 2006-04-26 | 清水建設株式会社 | 廃棄物の地下処分方法及び地下処分施設 |
ITGE20030005A1 (it) * | 2003-01-24 | 2004-07-25 | Ferrari De Nobili S R L | Metodo continuo di realizzazione di opere in sotterraneo, |
JP2005048404A (ja) * | 2003-07-31 | 2005-02-24 | Shimizu Corp | 放射性廃棄物処分場の遮水構造とその施工法 |
EP1760256A1 (de) * | 2005-08-18 | 2007-03-07 | Welldone EDS GmbH | Seitliche Schneidevorrichtung zum Bohren von Löchern |
JP4803429B2 (ja) * | 2006-02-15 | 2011-10-26 | 清水建設株式会社 | 地中空洞の施工方法 |
-
2008
- 2008-07-17 FR FR0854876A patent/FR2934007B1/fr not_active Expired - Fee Related
-
2009
- 2009-07-13 EP EP09737050A patent/EP2313614A2/de not_active Withdrawn
- 2009-07-13 WO PCT/FR2009/051394 patent/WO2010007305A2/fr active Application Filing
- 2009-07-13 US US13/054,243 patent/US20110116868A1/en not_active Abandoned
- 2009-07-13 JP JP2011517970A patent/JP2011528119A/ja active Pending
Non-Patent Citations (1)
Title |
---|
See references of WO2010007305A3 * |
Also Published As
Publication number | Publication date |
---|---|
WO2010007305A3 (fr) | 2010-03-18 |
US20110116868A1 (en) | 2011-05-19 |
WO2010007305A2 (fr) | 2010-01-21 |
FR2934007B1 (fr) | 2010-09-10 |
JP2011528119A (ja) | 2011-11-10 |
FR2934007A1 (fr) | 2010-01-22 |
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