EP2304316A2 - Unité brûleur et dispositif brûleur pour combustible solide pulvérulent - Google Patents

Unité brûleur et dispositif brûleur pour combustible solide pulvérulent

Info

Publication number
EP2304316A2
EP2304316A2 EP09780392A EP09780392A EP2304316A2 EP 2304316 A2 EP2304316 A2 EP 2304316A2 EP 09780392 A EP09780392 A EP 09780392A EP 09780392 A EP09780392 A EP 09780392A EP 2304316 A2 EP2304316 A2 EP 2304316A2
Authority
EP
European Patent Office
Prior art keywords
tube
burner
solid fuel
fuel
burner unit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP09780392A
Other languages
German (de)
English (en)
Inventor
Per Wasner
Frank WINKELRÄT
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rheinkalk GmbH
Original Assignee
Rheinkalk GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rheinkalk GmbH filed Critical Rheinkalk GmbH
Publication of EP2304316A2 publication Critical patent/EP2304316A2/fr
Ceased legal-status Critical Current

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23D—BURNERS
    • F23D1/00—Burners for combustion of pulverulent fuel
    • F23D1/02—Vortex burners, e.g. for cyclone-type combustion apparatus
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B1/00—Shaft or like vertical or substantially vertical furnaces
    • F27B1/005—Shaft or like vertical or substantially vertical furnaces wherein no smelting of the charge occurs, e.g. calcining or sintering furnaces
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B1/00—Shaft or like vertical or substantially vertical furnaces
    • F27B1/10—Details, accessories, or equipment peculiar to furnaces of these types
    • F27B1/16—Arrangements of tuyeres
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D99/00—Subject matter not provided for in other groups of this subclass
    • F27D99/0001—Heating elements or systems
    • F27D99/0033—Heating elements or systems using burners
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C2900/00—Special features of, or arrangements for combustion apparatus using fluid fuels or solid fuels suspended in air; Combustion processes therefor
    • F23C2900/03006—Reverse flow combustion chambers
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C2900/00—Special features of, or arrangements for combustion apparatus using fluid fuels or solid fuels suspended in air; Combustion processes therefor
    • F23C2900/99004—Combustion process using petroleum coke or any other fuel with a very low content in volatile matters
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23D—BURNERS
    • F23D2201/00—Burners adapted for particulate solid or pulverulent fuels
    • F23D2201/20—Fuel flow guiding devices
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23D—BURNERS
    • F23D2201/00—Burners adapted for particulate solid or pulverulent fuels
    • F23D2201/30—Wear protection
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23D—BURNERS
    • F23D2900/00—Special features of, or arrangements for burners using fluid fuels or solid fuels suspended in a carrier gas
    • F23D2900/00016—Preventing or reducing deposit build-up on burner parts, e.g. from carbon

Definitions

  • the invention relates to a burner unit for Staubtorraigen solid fuel. Furthermore, the invention relates to a burner assembly for an oven, in particular for a ring-shaft furnace for burning limestone, and such a furnace.
  • Burner units of the type mentioned are known from the prior art. Among other things, they will be in
  • Shaft kilns for example, used in ring shaft furnace for burning limestone.
  • the particular procedural challenge is to achieve the fullest possible implementation of the dusty fuel, for example petcoke dust r in hot gases in order to use the energy content of the dusty solid fuel as completely as possible.
  • Petrolkoksstaub known, in which the injected via a lance m a combustion chamber dusty solid fuel after exiting the lance first encounters a arranged in extension of the lance Umlenkkorper, whereby it is deflected at about 180 ° in the opposite direction, which is so generated reverse flow mixed with tangentially injected into the combustion chamber secondary air.
  • the resulting mixture is m in the direction of the output of the Transports combustion chamber, where it is implemented under optimal conditions completely m hot gases.
  • the present invention seeks to provide a Burner unit of the type mentioned, which allows a stable and efficient Brennerbetrieo even with different operating conditions, especially different combustion air temperatures, and the use of different composite solid fuels, so that the injected dust-like solid fuel to ⁇ eder Time completely m hot gases is converted. Furthermore, a corresponding burner arrangement is to be specified.
  • the object is achieved with a burner unit for dust-shaped fuel Fes ⁇ brennstoff having a first tube for demanding the solid fuel in a first Forderides and surrounding the first tube second pipe to demand
  • Combustion air and a third tube surrounding the first tube to request an additional fuel unkraftt.
  • the erfmdungsgedorfe burner unit m in various respects over the known from the prior art burner units advantageous.
  • the dust-like solid fuel which is initially encased in a cone or funnel shape of the combustion air, controlled in Brennra ⁇ m, in which the burner unit is installed, is guided and thus optimal in terms of stromungsischen aspects and under your aspect of a spatially uniform combustion Way spreads.
  • the combustion air cone also makes it possible to directly control the length of the flame, so that it can be adapted to the spatial conditions in a furnace.
  • the additional fuel is therefore preferably an easily flammable gaseous auxiliary fuel, for example natural gas. Accordingly, the third tube is preferably designed for the delivery of a gaseous additional fuel.
  • the third tube is arranged in the radial direction between the first and the second tube. This ensures that the combustion air flow emerging from the second and corresponding outer tube both from the first tube emerging dust-like solid fuel as well as the emerging from the third tube additional fuel cone or funnel-shaped wrapped.
  • the free end of the third tube is set back relative to the free end of the first tube. Furthermore, the free end of the second tube is preferably arranged substantially at the height of the free end of the third tube.
  • the first tube is axially displaceable in the surrounding second tube and third tube.
  • the optimal axial exit point for the dusty solid fuel can be defined from the point of view of flow engineering. If the first tube in continuous operation of the burner unit: shorten due to the strong thermal load, so the first tube can be adjusted accordingly due to the axial adjustability.
  • the burner according to the invention is used, for example, for firing a ring-shaft furnace, it is to be ensured that the axial extent of the burner flame is limited so that a permanent loading of the inner cylinder of the annular shaft furnace, which would be associated with a long-term damage to the refractory material, is avoided.
  • the axial extent of the burner flame is limited so that a permanent loading of the inner cylinder of the annular shaft furnace, which would be associated with a long-term damage to the refractory material, is avoided.
  • the pulse Ström I P is defined as follows:
  • a swirl body is arranged in the second tube near its mouth for generating a swirl flow in the combustion air emerging from the second tube.
  • the twisting body in turn can take various forms.
  • it is annular, in particular as a vane ring with over the circumference of an annular
  • Base body distributed, to the symmetry axis of the body twisted vanes formed.
  • a further improved mixing between combustion air and pulverulent solid fuel can be achieved if a deflecting body for deflecting the solid fuel jet emerging from the first pipe is arranged in extension of the first pipe, as known in principle from the prior art.
  • a deflecting body for deflecting the solid fuel jet emerging from the first pipe is arranged in extension of the first pipe, as known in principle from the prior art.
  • first a 180 ° deflection of the solid fuel jet is achieved immediately after exiting the first tube, which requires intensive mixing with the combustion air.
  • the mechanical stability of the thermally heavily loaded in the operation of the burner deflecting body has been found in studies by the applicant as problematic.
  • a further aspect of the present invention relates to a burner arrangement for an oven, in particular for a ring-shaft furnace for burning limestone, with a burner housing defining a combustion space and a burner unit according to one of claims 1 to 11.
  • the combustion chamber is formed substantially cylindrical, wherein the burner unit projects substantially coaxially into the combustion chamber.
  • the burner housing comprises a spiral housing into which a further combustion air duct tangentially opens. This makes it possible that further combustion air enters the burner housing with a combustion air that is significantly higher in comparison to the combustion air emerging from the second tube and due to the tangential flow
  • the spiral housing is strongly twisted.
  • the correspondingly twisted from the volute casing into the combustion chamber combustion air can be intensively mixed with the emerging from the second tube combustion air and dusty solid fuel and with the exiting from a third tube additional fuel, so that a complete combustion of the dusty solid fuel even at substoichiometric Zubowung from the second tube exiting combustion air is ensured.
  • the spiral housing is preferably arranged in the flow direction of the dust-like solid fuel in front of the combustion chamber.
  • the twist directions of the two air streams are preferably in the same direction, in order to achieve a particularly intensive mixing,
  • That combustion air is blown from a second tube surrounding the first tube in the combustion chamber and
  • auxiliary fuel a gaseous auxiliary fuel, in particular natural gas, is preferably used.
  • This is highly flammable and capable of providing the thermal energy necessary for complete combustion, particularly of high solids fumed solid fuels.
  • dust-like solid fuels are preferably Kohlesta ⁇ be used.
  • Particularly preferred is the use of petroleum coke dust or brown coal dust. Brown coal dust is characterized by a comparatively low
  • Ignition temperature of about 700 0 C, so that here the use of the additional fuel is necessary to bridge the temperature difference between the temperature of the combustion air and the ignition temperature of the petroleum coke dust.
  • Solid fuel also without additional fuel for the purpose of raising the temperature level in the combustion chamber ensures.
  • the exit velocity of the Forder Kunststoff for the dust-like solid fuel v FL ⁇ about 15 m / sec.
  • the pulse current of the Forderluft / fuel mixture is limited upwards.
  • the length of the flame can be limited and thus damage to the refractory lining of the furnace fired by the firing unit can be avoided.
  • FIG. 1 shows a burner arrangement known from the prior art
  • Fig. 2 shows an improved burner assembly in particular for a ring shaft furnace for burning limestone
  • Fig. 3 shows the burner assembly of FIG. 2 in a modified embodiment
  • Fig. 1 a known from the prior art burner assembly is shown.
  • the burner assembly comprises a burner housing 100 with a rotationally symmetrical combustion chamber 200, which initially widens conically in the transport direction of the fuel or in the propagation direction of the flame and then conically rejuvenated dusenformig conical up to the burner output.
  • a central tube 300 disposed coaxially with the combustion chamber 200, dust-like solid fuel is pneumatically, i. in a so-called. Primarluftstrom, required and exits at the free end 300 a of the central tube 300 from this.
  • Zubuchung 500 in the Brennraur ⁇ 200 at its closed end injected secondary combustion air is in Combustion chamber 200 twisted, as indicated by the spiral line S.
  • An intensive mixing of the dusty solid fuel with the twisted secondary air is achieved in that the dust-like solid fuel at exnem arranged in extension of the central tube 300
  • Stromungsumscher 400 is deflected by about 180 ° from its original Str ⁇ mungsrichtu ⁇ g. This return flow thus mixes with the twisted secondary air, so that a dust mass enriched with air flows through the combustion chamber 200 in the direction of its output and passes into the burner flame B.
  • tertiary combustion air is still stepped through several tangentially arranged nozzles introduced into the combustion chamber 200 to support the swirl flow in the combustion chamber 200.
  • FIG. 2 shows an improved burner arrangement A compared to FIG. 1.
  • the burner assembly A comprises a housing 1 which encloses a presently cylindrical combustion chamber 2.
  • a volute 3 is arranged, via soft combustion air or a mixture of so-called.
  • Propellant and Weggebowtem Umwalzgas (a partial flow of the kiln exhaust gases, see Fig. 4) can be introduced tangentially with very high volume flow into the combustion chamber 2.
  • side of Schneckengehauses 3 of the burner block 4 is arranged with conically widening inner cross-section, in which the Brenneremheii described below is arranged substantially coaxially.
  • the burner unit comprises a first tube 5 for the demand of dusty solid fuel, in this case petroleum coke dust P, in a Forderluftstrom. This is fed to the first tube 5 via a conveyor tube 5b.
  • the inner diameter of the first tube 5 and that of the conveyor tube 5b are identical. This ensures that the mass flow of the solid fuel / Forderiuft mixture proportional to the pulse flow of solid fuel / Forderiuft mixture through the first tube 5 is not too large, so that the length of the flame forming in the combustion chamber 2 is limited.
  • the first tube 5 is designed to be axially displaceable, so that the optimal axial exit point for the dust-like solid fuel can be determined from the point of view of flow engineering. Furthermore, the free end of the pipe can be nachgeschreibx in a possible burn-off of the tip due to ongoing high thermal stress during operation of the burner unit.
  • a stuffing box 5a is provided for sealing the first tube 5 with respect to the other construction.
  • a second tube 6 Coaxially to the first tube 5, a second tube 6 is arranged, in which the first tube 5 is received.
  • the second tube 6 serves to promote secondary combustion air S in the combustion chamber 2, which can be supplied to the second tube 6 via a radial line 6a.
  • a third tube 7 is received, which serves to promote an additional fuel, in this case natural gas E. This is in turn fed to the third tube via a radial line 7a.
  • the third tube 7 has a conical section 7b at its free end.
  • each air or fuel / conveying air flows conically divergent along the longitudinal axis of the combustion chamber 2 propagate.
  • the second tube 6 also has, near its free end, a swirl body 8, which in the present case is annularly designed as a vane ring with guide vanes which are distributed over the circumference of an annular base body and rotated with respect to the axis of symmetry of the base body.
  • a swirl body 8 which in the present case is annularly designed as a vane ring with guide vanes which are distributed over the circumference of an annular base body and rotated with respect to the axis of symmetry of the base body.
  • the operation of the burner assembly A according to FIG. 2 is the following:
  • a mixture of the dust-like solid fuel (petcoke dust P) and a transport air flow (so-called primary air) is introduced via the Forderrohr 5b and required by the first tube 5 in the combustion chamber 2, wherein the solid fuel jet in the region of the burner block 4 from the first tube 5 exits.
  • the exit velocity ⁇ er Forderluft for dust-based solid fuel amounts to preferably ⁇ about 15 m / sec, in order to limit the momentum flow of the fuel-air mixture against the background of a limitation of the flame length total.
  • Solid fuel P and the additional gaseous fuel E is achieved in that on the Spiralgehause 3 more preheated combustion air or a mixture of preheated combustion air and recirculating exhaust gas (so-called injection air 1 ⁇ tangential and high
  • volumetric flow is introduced into the combustion chamber 2. Due to the geometric design of the Spiralgehauses 3 and the tangential introduction, this air flow is also strongly twisted, as indicated by the spiral line D. With increasing distance from the burner unit then the swirled injection air I, the emerging from the second tube 6 preferably co-twisted secondary combustion air S, the emerging from the third tube 1 natural gas stream E and exiting from the first tube 5 dusty solid fuel P for not shown open end of the combustion chamber towards intensively mixed and completely converted to hot gases.
  • the burner arrangement A 'modified with respect to the burner arrangement A from Fig. 2 differs from the former in that the first pipe 5 "has, in extension of its free end, a deflection body 9 for deflecting the solid fuel jet P emerging from the first pipe a further improved mixing between solid fuel P, additional gaseous fuel (natural gas E) and secondary combustion air S.
  • the mechanical stability of the deflecting body 9 has proved to be problematic if the thermal load continues.
  • FIG. 4 The integration of a burner arrangement A according to FIG. 2 or a burner arrangement A 'according to FIG. 3 into a ring-shaft furnace for burning limestone is shown in FIG. 4 shown.
  • the annular shaft furnace of Fig. 4 is of the type
  • the oven has a cylindrical outer shell, which is divided into a top shaft 20 and a main shaft 10.
  • the inner shaft wall of the main shaft 10 is formed by a lower inner cylinder 30, which is the
  • Oberschachtes 20 by an upper inner cylinder 40 by an upper inner cylinder 40.
  • a plurality of burner assemblies A of the type described in connection with FIG. 2 are arranged in a lower burner level, of which m is the present sectional view visible.
  • the Brennereinhej th the upper burner level can also be formed in the inventive manner.
  • the granular material G (limestone) to be fired is placed in the annular shaft kiln and, owing to gravity, first moves through the preheating zone VZ, where it is heated in countercurrent by exhaust gases rising from the combustion zone BZ. As soon as the firing material G has passed the upper inner cylinder 40, it enters the combustion zone BZ and is burned there in countercurrent and below the lower burner level with the burner arrangements A in DC. Subsequently, the now fired Good G * enters the Kuhlzone KZ, where it is again cooled in countercurrent. Finally, the product G * is discharged from the annular shaft furnace.
  • m of the preheating zone VZ of the upper shaft 20 flows into an exhaust part ⁇ : rom in the upper inner cylinder 40 and from there into a recuperator unit 70, where it heats a three-air flow path.
  • the injection air provided by the injectors 50 often does not have those for the ignition of the
  • Another advantage of the presented burner concept is that existing burners can be easily converted in such a way that they also allow the use of an additional fuel such as natural gas.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)

Abstract

La présente invention concerne une unité brûleur pour combustible solide pulvérulent (P), laquelle unité comprend un premier tube (5, 5') permettant de transporter le combustible solide (P) dans une première direction de transport et un deuxième tube (6) entourant le premier tube (5) et permettant de transporter de l'air de combustion (S). Selon l'invention, l'unité brûleur est caractérisée en ce qu'un troisième tube (7) entourant le premier tube (5, 5') est utilisé pour transporter un combustible supplémentaire (E). L'invention concerne également un dispositif brûleur (A, A') comprenant une unité brûleur du type susmentionné, un procédé permettant de brûler du combustible solide pulvérulent, ainsi qu'un four.
EP09780392A 2008-07-11 2009-07-09 Unité brûleur et dispositif brûleur pour combustible solide pulvérulent Ceased EP2304316A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102008032589 2008-07-11
PCT/EP2009/058770 WO2010004009A2 (fr) 2008-07-11 2009-07-09 Unité brûleur et dispositif brûleur pour combustible solide pulvérulent

Publications (1)

Publication Number Publication Date
EP2304316A2 true EP2304316A2 (fr) 2011-04-06

Family

ID=41129217

Family Applications (2)

Application Number Title Priority Date Filing Date
EP09780392A Ceased EP2304316A2 (fr) 2008-07-11 2009-07-09 Unité brûleur et dispositif brûleur pour combustible solide pulvérulent
EP09165089A Active EP2143998B1 (fr) 2008-07-11 2009-07-09 Unité de brûleur pour combustible pulvérulent

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP09165089A Active EP2143998B1 (fr) 2008-07-11 2009-07-09 Unité de brûleur pour combustible pulvérulent

Country Status (6)

Country Link
EP (2) EP2304316A2 (fr)
ES (1) ES2394539T3 (fr)
PL (1) PL2143998T3 (fr)
PT (1) PT2143998E (fr)
SI (1) SI2143998T1 (fr)
WO (1) WO2010004009A2 (fr)

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CA2881760C (fr) 2005-11-10 2017-06-13 Arshad Quadri Stent de raccordement de prothese vasculaire, a deploiement automatique, pouvant etre deploye par ballonnet
EP3001978B2 (fr) 2010-09-23 2023-03-01 Edwards Lifesciences CardiAQ LLC Valvules prothétiques, dispositifs de pose et procédés afférents
DE102015005416B4 (de) * 2015-04-29 2023-11-30 Khd Humboldt Wedag Gmbh Verfahren zum Betrieb eines Calcinators mit einem Gasbrenner
BE1023896B1 (fr) 2016-06-28 2017-09-06 Lhoist Rech Et Developpement Sa Procede de combustion de combustible dans une chambre de combustion tubulaire
US10350062B2 (en) 2016-07-21 2019-07-16 Edwards Lifesciences Corporation Replacement heart valve prosthesis
CN106247338B (zh) * 2016-08-29 2018-05-25 煤科院节能技术有限公司 一种快速互换的多燃料燃烧器

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DE504546C (de) * 1927-03-08 1930-08-05 Steitz & Co G M B H Staubfeuerungsflachbrenner
EP0171788A1 (fr) * 1984-08-16 1986-02-19 STEIN INDUSTRIE Société Anonyme dite: Bruleur d'allumage et de soutien de combustion pour combustible solide fossilé pulverisé, et chambre de combustion comportant de tels bruleurs

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GB207062A (en) * 1922-12-28 1923-11-22 Babcock & Wilcox Hampfkessel W Improvements in and relating to furnaces
GB704901A (en) * 1951-08-07 1954-03-03 Pollopas Patents Ltd Improvements in or relating to pulverised fuel burners, more particularly for cementkilns and similarly constructed furnaces
US4387654A (en) * 1980-05-05 1983-06-14 Coen Company, Inc. Method for firing a rotary kiln with pulverized solid fuel
US5441546A (en) * 1993-11-08 1995-08-15 Moard; David Apparatus and method for decreasing nitrogen oxide emissions from internal combustion power sources
DE19527083A1 (de) * 1995-07-25 1997-01-30 Lentjes Kraftwerkstechnik Verfahren und Brenner zur Verminderung der Bildung von NO¶x¶ bei der Verbrennung von Kohlenstaub
DE10232373B4 (de) * 2002-07-17 2009-04-02 Schoppe, Fritz, Dr.-Ing. Verfahren zur Erhöhung der Flammstabilität bei Kohlenstaubfeuerungen und Vorrichtung zur Ausführung des Verfahrens
US6986311B2 (en) * 2003-01-22 2006-01-17 Joel Vatsky Burner system and method for mixing a plurality of solid fuels
DE112004000319T5 (de) * 2003-02-24 2006-02-02 Posco, Pohang City Brennervorrichtung zum Injizieren von pulverförmiger Kohle in drehbaren Brennöfen und zugehöriges Verfahren und zugehörige Vorrichtung zur Herstellung von CaO
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EP0171788A1 (fr) * 1984-08-16 1986-02-19 STEIN INDUSTRIE Société Anonyme dite: Bruleur d'allumage et de soutien de combustion pour combustible solide fossilé pulverisé, et chambre de combustion comportant de tels bruleurs

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Also Published As

Publication number Publication date
PT2143998E (pt) 2012-12-10
WO2010004009A3 (fr) 2011-04-28
EP2143998A3 (fr) 2011-04-13
SI2143998T1 (sl) 2013-01-31
EP2143998B1 (fr) 2012-08-29
WO2010004009A2 (fr) 2010-01-14
ES2394539T3 (es) 2013-02-01
PL2143998T3 (pl) 2013-03-29
EP2143998A2 (fr) 2010-01-13

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