EP2283272B1 - Leimbefestigung eines isolationsblocks für einen flüssiggasspeichertank unter verwendung wellender kügelchen - Google Patents

Leimbefestigung eines isolationsblocks für einen flüssiggasspeichertank unter verwendung wellender kügelchen Download PDF

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Publication number
EP2283272B1
EP2283272B1 EP09761917A EP09761917A EP2283272B1 EP 2283272 B1 EP2283272 B1 EP 2283272B1 EP 09761917 A EP09761917 A EP 09761917A EP 09761917 A EP09761917 A EP 09761917A EP 2283272 B1 EP2283272 B1 EP 2283272B1
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EP
European Patent Office
Prior art keywords
insulating
cords
tank
insulating blocks
mastic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP09761917A
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English (en)
French (fr)
Other versions
EP2283272A1 (de
Inventor
Gery Canler
Adnan Ezzarhouni
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gaztransport et Technigaz SA
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Gaztransport et Technigaz SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
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Publication of EP2283272A1 publication Critical patent/EP2283272A1/de
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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C3/00—Vessels not under pressure
    • F17C3/02—Vessels not under pressure with provision for thermal insulation
    • F17C3/025—Bulk storage in barges or on ships
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00—Vessel construction, in particular walls or details thereof
    • F17C2203/03—Thermal insulations
    • F17C2203/0304—Thermal insulations by solid means
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00—Vessel construction, in particular walls or details thereof
    • F17C2203/03—Thermal insulations
    • F17C2203/0304—Thermal insulations by solid means
    • F17C2203/0329—Foam
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00—Vessel construction, in particular walls or details thereof
    • F17C2203/03—Thermal insulations
    • F17C2203/0304—Thermal insulations by solid means
    • F17C2203/0354—Wood
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00—Vessel construction, in particular walls or details thereof
    • F17C2203/03—Thermal insulations
    • F17C2203/0304—Thermal insulations by solid means
    • F17C2203/0358—Thermal insulations by solid means in form of panels
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00—Vessel construction, in particular walls or details thereof
    • F17C2203/06—Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634—Materials for walls or layers thereof
    • F17C2203/0636—Metals
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00—Vessel construction, in particular walls or details thereof
    • F17C2203/06—Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634—Materials for walls or layers thereof
    • F17C2203/0678—Concrete
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
    • F17C2205/01—Mounting arrangements
    • F17C2205/0153—Details of mounting arrangements
    • F17C2205/018—Supporting feet
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2209/00—Vessel construction, in particular methods of manufacturing
    • F17C2209/22—Assembling processes
    • F17C2209/227—Assembling processes by adhesive means
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2221/00—Handled fluid, in particular type of fluid
    • F17C2221/03—Mixtures
    • F17C2221/032—Hydrocarbons
    • F17C2221/033—Methane, e.g. natural gas, CNG, LNG, GNL, GNC, PLNG
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2260/00—Purposes of gas storage and gas handling
    • F17C2260/01—Improving mechanical properties or manufacturing
    • F17C2260/011—Improving strength
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2260/00—Purposes of gas storage and gas handling
    • F17C2260/03—Dealing with losses
    • F17C2260/035—Dealing with losses of fluid
    • F17C2260/036—Avoiding leaks
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00—Applications
    • F17C2270/01—Applications for fluid transport or storage
    • F17C2270/0102—Applications for fluid transport or storage on or in the water
    • F17C2270/0105—Ships
    • F17C2270/0107—Wall panels

Definitions

  • the present invention relates to a sealed and thermally insulated tank and its manufacturing process.
  • the present invention relates to a tank for liquefied gas storage and, in particular, liquefied natural gas with a high methane content.
  • Terrestrial tanks are also known for the storage of liquefied gas, also having two successive sealing barriers alternating with two layers of thermal insulation.
  • the supporting structure is generally made of concrete.
  • the primary and secondary insulating barriers consist of a succession of insulating blocks which are either closed parallelepiped boxes filled with a heat insulator, or consist of blocks of insulating foam bonded to a load-bearing panel.
  • the material used to make the panels of boxes or load-bearing panels is generally plywood, for a question of cost and its insulating qualities.
  • One of the disadvantages of plywood however is that it is anisotropic and that its mechanical properties are different depending on whether one exerts a stress in the direction or transversely to the fibers of its outer plies.
  • the insulating blocks of the secondary barrier are fixed on the supporting structure, in the first case by assembling with studs taken in the supporting structure and in the second case simply glued, via their external panel, on said structure.
  • the material used for bonding is generally an epoxy resin putty, which is deposited in the form of cords on the face of the insulating block placed opposite the carrier structure.
  • the cords are arranged rectilinearly on the panels of the insulating blocks, parallel to each other.
  • mastic cords have the function, besides that of maintaining the insulating block on the carrier structure, to compensate for the inevitable irregularities by adapting to the shape thereof.
  • the insulating block is positioned on the supporting structure using known means so that the cords of mastic are compressed, before polymerization, against the support structure and perfectly fit its shape. We are sure to get a good quality collage. With curing, mastic cords harden and behave like perfectly rigid materials.
  • the multiplicity of cords has, moreover, the disadvantage of significantly increase the cost of realization of the tank, because of the large amount of mastic necessary.
  • the cords must on the one hand be of a section high enough to compensate for the irregularities of the supporting structure and, on the other hand, the total length of the cords, if they were put end to end, would reach several tens or even one hundred, kilometers for a medium-sized ship or medium-sized tank.
  • the present invention aims to overcome these disadvantages by providing a less expensive method of bonding insulating blocks on the carrier structure using cords of mastic, while maintaining a good resistance of the panels of said insulating blocks to the compressive or tensile forces exerted on them, or even improving it.
  • the distance between two consecutive wavy lines is greater than or equal to 100 mm.
  • the wavy lines are sinusoids.
  • the sinusoid has a ratio substantially equal to 8 between its period and its amplitude.
  • the subject of the invention is also a sealed and thermally insulated earth tank integrated in a supporting structure, comprising a thermally insulating barrier comprising a plurality of insulating blocks, each insulating block comprising a plywood panel and containing or carrying thermally insulating material, said insulating blocks being fixed directly against the supporting structure by means of cords of mastic positioned on the panels of said insulating blocks along lines parallel to each other,
  • the carrier structure 1 of a tank for the storage of liquefied gas is made of concrete.
  • "land tank” means a vessel built on fixed foundations on the ground, whether it is the land surface, the shore or an underwater soil.
  • the tank can be built above ground level, or be partially or completely buried.
  • the primary insulating barrier 2, the secondary sealed barrier 6 and the secondary insulating barrier 4 are made using prefabricated panels assembled on the supporting structure 1.
  • the primary insulating barrier 2 is completed by insulating elements 12 placed between the prefabricated panels.
  • the secondary watertight barrier 6 is not represented on the figure 1 but its position is indicated by the bottom of the insulating elements 12.
  • the side wall of the vessel also comprises, in a lower part, a primary watertight barrier, a primary insulating barrier, a secondary watertight barrier and a secondary insulating barrier, and in an upper part, a single barrier waterproof and a single insulating barrier.
  • the side wall of the tank comprises over its entire height a primary waterproof barrier, a primary insulating barrier, a secondary sealed barrier and a secondary insulating barrier.
  • an "insulating block 14" is an element of the secondary watertight barrier, which may comprise, according to the technique used, a layer of foam and a plywood panel (in the case of figures 1 and 3 ), a box filled with insulating material (case not shown). In both cases, the insulating block 14 comprises, at its face facing the supporting structure, a plywood panel.
  • the insulating blocks 14 are fixed on the support structure using cords of putty 3. It can be seen on the figure 3 two cords of 3 corrugated putty.
  • the figure 2 represents a tank according to the prior art, in which the caulk beads 3 are rectilinear. On the figure 2 , we used the same reference numbers as on the figure 3 to designate corresponding elements.
  • FIG 4 we see a bottom view of a panel of an insulating block 14, on which cords of putty 3 have been placed, transversely to the largest dimension. Because of the method of construction of plywood panels, the folds are always in odd number and on the outer folds the wood fibers are oriented in the axis of the smallest dimension of the panel. This orientation is represented by the axis AA on the figure 4 .
  • mastic cords are rectilinear and regularly spaced a length that varies depending on where the second insulating block corresponding to be placed in the tank, in other words according to the pressure to which it will be subjected.
  • a spacing of 100 mm is generally retained between two consecutive cords on the same insulating block. In areas where the pressure to be supported will be lower (upper sidewall and ceiling sections) looser spacing is acceptable. The spacing generally retained is then 140 mm.
  • the wood panels constituting the faces of the insulating blocks 14 are subjected in use to compressive forces due to the weight of the liquid contained in the tank.
  • the invention solves this problem by replacing the rectilinear cords previously used by cords 3 having corrugations, which may, for example, be sinusoidal as shown by Figures 4 and 5 .
  • Tests were carried out on panels which were equipped with sinusoidal cords, with various spacings, whose period L is 372 mm and the amplitude is 46.5 mm.
  • the length of such a sinusoid which is characterized by a ratio L / a equal to 8, is 14% greater than that of the line segment of corresponding length L.
  • the inter-flexural breaking strength and the delamination of the panels were evaluated and compared to those of panels equipped with rectilinear cords spaced 100 or 140 mm apart. We find the same bending rupture pressure with these sinusoidal cords, with a spacing between them greater than 35% that found with straight cords.
  • the delamination resistance tests have shown that with such a sinusoidal shape (ratio L / a equal to 8) the delamination resistance is increased by 48% compared to straight cords also placed parallel to the plywood fibers. This means that a shortening of 35% of the length of putty deposited on the panel of a second insulating block is possible, without placing itself more unfavorably vis-à-vis the delamination with rectilinear cords.

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Standing Axle, Rod, Or Tube Structures Coupled By Welding, Adhesion, Or Deposition (AREA)

Claims (8)

  1. Verklebungsverfahren von Isolationsblöcken auf einer Trägerstruktur eines Erdblocks mithilfe von Abdichtungsschnüren (3) für die Realisierung eines abgedichteten und thermisch isolierten Erdbeckens für die Lagerung von Flüssiggas auf dem Boden, wobei das genannte Becken eine thermisch isolierende Barriere mit einer Vielzahl von Isolationsblöcken (14) umfasst, wobei jeder Isolationsblock eine Sperrholzplatte umfasst und thermisch isolierendes Materials enthält oder trägt, wobei das genannte Verfahren umfasst
    a) die Anbringung von Abdichtungsschnüren (3) auf der Platte der genannten Isolationsblöcke (14) oder auf der Trägerstruktur entlang von untereinander parallelen Linien,
    b) die Positionierung der genannten Isolationsblöcke (14) gegen die Trägerstruktur des Beckens (15) und
    c) ihre Unter-Drucksetzung gegen die genannte Trägerstruktur bis zur Polymerisation der genannten Abdichtung,
    dadurch gekennzeichnet, dass zwischen der Platte wenigstens einer der genannten Isolationsblöcke (14) und der Trägerstruktur wenigstens zwei der genannten Schnüre (3) entlang gewellten parallelen Linien angeordnet sind.
  2. Verklebungsverfahren gemäß Anspruch 1, in dem die Entfernung zwischen zwei aufeinander folgenden gewellten Linien größer als oder gleich 100 mm ist.
  3. Verklebungsverfahren gemäß einem der vorherigen Ansprüche, in dem die gewellten Linien Sinuskurven sind.
  4. Verklebungsverfahren gemäß Anspruch 3, in dem die Sinuskurve zwischen ihrer Periode und ihrer Amplitude ein Verhältnis von deutlich gleich 8 aufweist.
  5. Abgedichtetes und thermisch isoliertes, in eine Trägerstruktur (1) integriertes Erdbecken mit einer thermisch isolierenden Barriere mit einer Vielzahl von Isolationsblöcken (14), wobei jeder Isolationsblock eine Sperrholzplatte umfasst und thermisch isolierendes Material enthält oder trägt, wobei die genannten Isolationsblöcke (14) mittels auf den Platten der genannten Isolationsblöcke entlang untereinander parallelen Linien positionierten Abdichtungsschnüren (3) direkt gegen die Trägerstruktur (1) befestigt sind,
    dadurch gekennzeichnet, dass auf der Platte wenigstens eines der genannten Isolationsblöcke (14) wenigstens zwei der genannten Schnüre (3) entlang gewellten, parallelen Linien angeordnet sind.
  6. Abgedichtetes und thermisch isolierendes Becken gemäß Anspruch 5, in dem die Entfernung zwischen zwei aufeinander folgenden, gewellten, parallelen Linien größer als oder gleich 100 mm ist.
  7. Abgedichtetes und thermisch isolierendes Becken gemäß Anspruch 5 oder 6, in dem die gewellten Linien Sinuskurven sind.
  8. Abgedichtetes und thermisch isolierendes gemäß Anspruch 7, in dem die Sinuskurve ein Verhältnis zwischen ihrer Periode und ihrer Amplitude von deutlich gleich 8 aufweist.
EP09761917A 2008-05-21 2009-05-19 Leimbefestigung eines isolationsblocks für einen flüssiggasspeichertank unter verwendung wellender kügelchen Active EP2283272B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0853288A FR2931535B1 (fr) 2008-05-21 2008-05-21 Fixation par collage de blocs isolants pour cuve de stockage de gaz liquefies a l'aide de cordons ondules
PCT/FR2009/050932 WO2009150366A1 (fr) 2008-05-21 2009-05-19 Fixation par collage de blocs isolants pour cuve de stockage de gaz liquefies a l'aide de cordons ondules

Publications (2)

Publication Number Publication Date
EP2283272A1 EP2283272A1 (de) 2011-02-16
EP2283272B1 true EP2283272B1 (de) 2011-11-02

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EP09761917A Active EP2283272B1 (de) 2008-05-21 2009-05-19 Leimbefestigung eines isolationsblocks für einen flüssiggasspeichertank unter verwendung wellender kügelchen

Country Status (19)

Country Link
US (1) US20110062164A1 (de)
EP (1) EP2283272B1 (de)
JP (1) JP2011521186A (de)
KR (1) KR101274064B1 (de)
CN (1) CN102037270B (de)
AP (2) AP2010005503A0 (de)
AT (1) ATE531998T1 (de)
AU (1) AU2009259099B2 (de)
BR (1) BRPI0913065A2 (de)
CA (1) CA2724520A1 (de)
CO (1) CO6331386A2 (de)
ES (1) ES2371737T3 (de)
FR (1) FR2931535B1 (de)
MX (1) MX2010012660A (de)
RU (1) RU2493476C2 (de)
SA (1) SA109300307B1 (de)
TW (1) TW201007049A (de)
UA (1) UA99359C2 (de)
WO (1) WO2009150366A1 (de)

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FR2978748B1 (fr) * 2011-08-01 2014-10-24 Gaztransp Et Technigaz Cuve etanche et thermiquement isolante
FR3000042B1 (fr) 2012-12-21 2015-01-23 Gaztransp Et Technigaz Cuve etanche et thermiquement isolante
FR3001945B1 (fr) * 2013-02-14 2017-04-28 Gaztransport Et Technigaz Paroi etanche et thermiquement isolante pour cuve de stockage de fluide
FR3004507B1 (fr) * 2013-04-11 2019-04-26 Gaztransport Et Technigaz Decouplage des ondulations d'une barriere etanche
FR3038690B1 (fr) * 2015-07-06 2018-01-05 Gaztransport Et Technigaz Cuve etanche et thermiquement isolante ayant une membrane d'etancheite secondaire equipee d'un arrangement d'angle a toles metalliques ondulees
FR3039248B1 (fr) * 2015-07-24 2017-08-18 Gaztransport Et Technigaz Cuve etanche et thermiquement isolante munie d'une piece de renfort
CN110332456B (zh) * 2019-05-13 2021-05-28 江苏华兴压力容器有限公司 一种粘合密封装置
FR3111178B1 (fr) 2020-06-03 2022-05-06 Gaztransport Et Technigaz Cuve étanche et thermiquement isolante intégrée dans une structure porteuse
CN112498581A (zh) * 2020-10-30 2021-03-16 沪东中华造船(集团)有限公司 一种薄膜型围护系统及应用该系统的lng船

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EP1819588A4 (de) * 2004-12-08 2016-12-21 Korea Gas Corp Lng-speichertank und herstellungsverfahren dafür
JP2006214458A (ja) * 2005-02-01 2006-08-17 Foomutekku:Kk メンブレン型液化天然ガスタンク用断熱性複合パネルおよびその製造方法
FR2909356B1 (fr) * 2006-11-30 2009-01-16 Gaztransp Et Technigaz Soc Par Fixation par collage de blocs isolants pour cuve de transport de gaz liquefies a l'aide de cordons ondules

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JP2011521186A (ja) 2011-07-21
KR20110015638A (ko) 2011-02-16
AU2009259099A1 (en) 2009-12-17
FR2931535A1 (fr) 2009-11-27
MX2010012660A (es) 2010-12-21
RU2010150879A (ru) 2012-06-20
TW201007049A (en) 2010-02-16
FR2931535B1 (fr) 2010-08-20
ES2371737T3 (es) 2012-01-09
SA109300307B1 (ar) 2013-12-08
AP2010005503A0 (en) 2010-12-31
UA99359C2 (ru) 2012-08-10
CN102037270B (zh) 2013-01-09
ATE531998T1 (de) 2011-11-15
CN102037270A (zh) 2011-04-27
RU2493476C2 (ru) 2013-09-20
US20110062164A1 (en) 2011-03-17
AU2009259099B2 (en) 2011-12-08
CA2724520A1 (fr) 2009-12-17
KR101274064B1 (ko) 2013-06-12
AP2010005510A0 (en) 2010-12-31
CO6331386A2 (es) 2011-10-20
EP2283272A1 (de) 2011-02-16
BRPI0913065A2 (pt) 2015-10-13
WO2009150366A1 (fr) 2009-12-17
ES2371737T8 (es) 2012-02-17

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