EP2281948A1 - Construction de voie de circulation dotée de propriétés améliorées - Google Patents

Construction de voie de circulation dotée de propriétés améliorées Download PDF

Info

Publication number
EP2281948A1
EP2281948A1 EP09164780A EP09164780A EP2281948A1 EP 2281948 A1 EP2281948 A1 EP 2281948A1 EP 09164780 A EP09164780 A EP 09164780A EP 09164780 A EP09164780 A EP 09164780A EP 2281948 A1 EP2281948 A1 EP 2281948A1
Authority
EP
European Patent Office
Prior art keywords
adhesive composition
plastic film
solid
primer
room temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP09164780A
Other languages
German (de)
English (en)
Other versions
EP2281948B1 (fr
Inventor
Hans Gantner
Raphael Teysseire
Herbert Ackermann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sika Technology AG
Original Assignee
Sika Technology AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to ES09164780T priority Critical patent/ES2394757T3/es
Application filed by Sika Technology AG filed Critical Sika Technology AG
Priority to EP09164780A priority patent/EP2281948B1/fr
Priority to AU2010270243A priority patent/AU2010270243B2/en
Priority to RU2012104030/03A priority patent/RU2532113C2/ru
Priority to CN201080030796.5A priority patent/CN102472024B/zh
Priority to PCT/EP2010/059682 priority patent/WO2011003927A1/fr
Priority to JP2012518976A priority patent/JP5782028B2/ja
Publication of EP2281948A1 publication Critical patent/EP2281948A1/fr
Priority to US13/346,003 priority patent/US8534953B2/en
Application granted granted Critical
Publication of EP2281948B1 publication Critical patent/EP2281948B1/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01DCONSTRUCTION OF BRIDGES, ELEVATED ROADWAYS OR VIADUCTS; ASSEMBLY OF BRIDGES
    • E01D19/00Structural or constructional details of bridges
    • E01D19/08Damp-proof or other insulating layers; Drainage arrangements or devices ; Bridge deck surfacings
    • E01D19/083Waterproofing of bridge decks; Other insulations for bridges, e.g. thermal ; Bridge deck surfacings

Definitions

  • the invention relates to the field of roadway sealing on a support structure.
  • a starting point for solving this problem lies in the use of mastic asphalt as an adhesive between plastic layer and bituminous base course.
  • these systems had the great disadvantage that first the mastic asphalt must be applied at high temperature and the bituminous base course can be applied only after cooling, which on the one hand extended and more expensive because of this additional step, the creation of the sealing or creation process of the road.
  • WO 2008/095215 avoids the problem by using a concrete pavement. It discloses a concrete carriageway on a concrete support structure with an interposed plastic film and an adhesive layer between the plastic film and concrete carriageway. In order to ensure the adhesion of the concrete pavement with the adhesive layer in this case the spreading of quartz sand is proposed in the adhesive layer before its hardening.
  • AT 413 990 B proposes, in order to improve the bond between the plastic film and the bituminous base layer, the use of a polyurethane-based adhesive primer onto which loose granules of synthetic resin are sprinkled.
  • the scattering of granules involves some problems, in particular it can lead during or after the spreading of the granules, especially on wind-exposed concrete support structures, for example, that large amounts of granules are weggewindet, resulting in unwanted loss of material or uncontrolled adhesive losses.
  • such systems tend to shear bond strongly to adhesive fracture between granules and asphalt. The occurrence of adhesive fracture is always a sign of lack of adhesion and can lead to delamination or leakage especially after prolonged environmental exposure.
  • the object of the present invention is therefore to provide a roadway structure available, which can be easily and efficiently created and leads to a high adhesion between plastic film and bituminous base layer to a good bond and adhesion test under shear stress to high content of cohesive fracture in the Asphalt leads.
  • the core of the present invention is the combination of a solid epoxy resin and a solid at room temperature thermoplastic polymer as an essential constituent of the necessary adhesive composition.
  • the present invention makes it possible to massively increase the proportion of cohesive fracture in the asphalt.
  • the critical point is the inherent strength of the asphalt rather than adhesion.
  • the adhesive bond also remains intact over the long term and that the formation of delamination of the bitumen-based support layer, and thus the formation of cracks and leaks, can be massively reduced.
  • Such a support structure is preferably a building of civil engineering.
  • this may be a bridge, a gallery, a tunnel, a ramp or departure ramp or a parking deck.
  • a preferred example of such a support structure is a bridge.
  • This required for the roadway supporting structure is a structure of a material which may have a supporting function.
  • this material is a metal or a metal alloy or a concrete, in particular a reinforced concrete, preferably a reinforced concrete.
  • the most preferred example of such a support structure is a concrete bridge.
  • a primer in particular a concrete primer, is applied to the support structure in step (i).
  • a “primer” in this document is generally understood to mean a thin layer of a polymer applied to a substrate, which improves the adhesion between this substrate and another substrate.
  • a primer has a flowable consistency at room temperature and is applied to the substrate by brushing, painting, rolling, spraying, casting or brushing. It should be noted that the term “flowable” here will refer not only to liquid, but also to higher viscosity honey-like to pasty materials whose shape is adjusted under the influence of gravity.
  • room temperature in this document means a temperature of 23 ° C.
  • concrete primer a thin layer of a polymer applied to the concrete, which the adhesion of Improved concrete to another substrate.
  • concrete primer apply primer based on epoxy resin.
  • the concrete primers are highly fluid, in particular having a viscosity of less than 10,000 mPas, preferably between 10 and 1,000 mPas, so that they can penetrate into the concrete surface.
  • Particularly preferred concrete primers are two-component, low-viscosity, epoxy resin primers, such as those sold under the trade name Sikafloor® or Sikagard® by Sika Deutschland GmbH, or Sika Buch AG.
  • Particularly preferred concrete primers are Sikafloor®-156 Primer and Sikagard®-186.
  • plastic primer in this document is meant a thin layer of a polymer applied to the plastic film, which improves the adhesion of plastic film to another substrate.
  • plastic primer apply primer based on epoxy resin.
  • step (i) and step (ii) in the primer preferably in the concrete primer, inorganic bedding agents, in particular sand, preferably quartz sand, are interspersed.
  • inorganic bedding agents in particular sand, preferably quartz sand
  • this inorganic bedding agent has a maximum particle size of less than 1 mm, in particular between 0.1 and 1 mm, preferably between 0.3 and 0.8 mm.
  • the amount of such bedding agents should be such that the primer is not completely covered, but that there are always places in the structure where the primer is in direct contact with the plastic film.
  • the use of bedding agent is advantageous for the bond between plastic film and primer, or the support structure.
  • the primer at least partially flows around the grain surface and thus a larger contact surface between the plastic film and primer is created, and / or that is strongly locally reinforced by the inorganic spreading means, the primer layer, so that be transmitted and / or that are made by the Einstreusch a purely mechanical anchoring between the plastic film and primer by the integrated into the matrix of the primer grains lead to a roughened primer surface and these grains in the Embed the surface of the preferably elastic plastic film.
  • the plastic film receives a significantly larger contact surface, since it is applied to a primer surface, which has a significantly larger surface area due to the roughening caused by the roasting agent.
  • the average layer thickness of the primer is typically between 100 micrometers and 10 millimeters, advantageously the average layer thickness of the primer layer is less than 3 mm, preferably between 0.3 and 2 mm.
  • step (ii) a plastic film is applied to the support structure primed after step (i).
  • the plastic film should be as waterproof as possible and even under prolonged influence of water or moisture, do not decompose or be mechanically damaged.
  • plastic films in particular such films are suitable, as they are used for sealing purposes, especially for the roof construction or for the bridge sealing purpose in the prior art.
  • the plastic films are made of a material having a softening point of about 140 ° C, preferably between 160 ° C and 300 ° C.
  • the plastic film should advantageously have at least a low degree of elasticity, for example, can bridge caused by temperature expansion differences between asphalt and support structure or caused by cracks in the support structure or the support layer voltages without the plastic film is damaged or cracked and would affect the sealing function of the plastic film .
  • the plastic film can be used as a prefabricated web.
  • the plastic film is preferably produced by an industrial process in a film factory and arrives at the construction site preferably in the form of plastic film from a roll used. It is advantageous if, in this case, the plastic film is brought into contact with the primer before its complete hardening or hardening.
  • the plastic film can also be produced on site, for example by a crosslinking reaction of reactive components which are mixed and applied on site. Particularly advantageous have sprayed plastic films proven.
  • the plastic film advantageously has a layer thickness in the millimeter range, typically between 0.5 and 15 mm, preferably between 1 and 4 mm.
  • plastic film are polyurethane films, in particular sprayed films of two-component polyurethanes.
  • Plastic primers used are, in particular, primers based on two-component polyurethanes or epoxides, preferably epoxides.
  • the core of the present invention is the guarantee of the bond between the plastic film and the bituminous base layer by means of the application of a specific adhesive composition.
  • solid epoxy resin is well known to the person skilled in the art and is used in contrast to "liquid epoxy resins".
  • the glass transition temperature of solid resins is above room temperature, i. they can be ground at room temperature to give pourable powders.
  • Preferred solid epoxy resins have the formula (I)
  • substituents R 'and R are independently of one another either H or CH 3. Furthermore, the subscript s stands for a value of> 1.5, in particular from 2 to 12.
  • Such solid epoxy resins are commercially available for example under the trade name D.E.R. TM or Araldite® or Epikote from Dow or Huntsman or Hexion and accordingly the person skilled in the best known.
  • thermoplastic polymer which is solid at room temperature is a polymeric material at room temperature which softens at a temperature above one of the softening point and finally becomes fluid.
  • softening temperatures or softening points are understood in particular as measured by the Ring & Ball method according to DIN ISO 4625.
  • thermoplastic polymer which is solid at room temperature has a softening point in the range from 80 ° C. to 150 ° C., in particular from 90 ° C. to 130 ° C.
  • thermoplastic polymers which have a softening point which is at least 25 ° C. below the temperature of the bituminous base layer measured in step (iv) during application are particularly advantageous.
  • monomers which are selected from the group consisting of ethylene, propylene, butylene, butadiene, isoprene, acrylonitrile, vinyl esters, in particular vinyl acetate, vinyl ethers, allyl ethers , (Meth) acrylic acid, (meth) acrylic acid esters, maleic acid, maleic anhydride, maleic acid esters, fumaric
  • copolymers which are prepared only from the monomers of the group just mentioned.
  • graft-modified copolymers of olefinically unsaturated monomers in particular the graft-modified copolymers of the preceding section.
  • APAO atactic poly- ⁇ -olefins
  • thermoplastic polymers are ethylene / vinyl acetate copolymers (EVA), in particular those having a vinyl acetate content of less than 50% by weight, in particular having a vinyl acetate content of between 10 and 40% by weight, preferably between 20 and 35 Wt .-%, most preferably between 27 and 32 wt .-%.
  • EVA ethylene / vinyl acetate copolymers
  • thermoplastic polymers which are solid at room temperature are used, which preferably have a different chemical composition.
  • one of these two different thermoplastic polymers is an ethylene / vinyl acetate copolymer.
  • thermoplastic polymer is a copolymer in whose preparation maleic acid or maleic anhydride has been used as monomer or as grafting reagent.
  • the weight ratio of solid epoxy resin to thermoplastic polymer which is solid at room temperature is preferably between 1: 2 and 1:10, preferably between 1: 4 and 1: 8.
  • the adhesive composition comprises a tackifier resin, in particular based on hydrocarbon resins, preferably aliphatic hydrocarbon resins, in particular as sold for example by the company Exxon Mobil under the trade name Escorez TM.
  • the adhesive composition further contains a chemical or physical blowing agent.
  • exothermic blowing agents such as azo compounds, hydrazine derivatives, semicarbazides or tetrazoles.
  • exothermic blowing agents such as azo compounds, hydrazine derivatives, semicarbazides or tetrazoles.
  • azodicarbonamide and oxy-bis (benzenesulfonyl hydrazide) which release energy during decomposition.
  • endothermic blowing agents such as, for example, sodium bicarbonate / citric acid mixtures.
  • Such chemical blowing agents are available, for example, under the name Celogen TM from Chemtura.
  • physical blowing agents such as those sold under the trade name Expancel TM by Akzo Nobel.
  • blowing agents are those available under the trade name Expancel TM from Akzo Nobel or Celogen TM from Chemtura.
  • Preferred blowing agents are chemical blowing agents which release a gas on heating, in particular to a temperature of 100 to 160 ° C.
  • the amount of the physical or chemical blowing agent is in particular in the range of 0.1 to 3% by weight, based on the weight of the adhesive composition.
  • the adhesive composition may in particular contain epoxide crosslinking catalysts and / or curing agents for epoxy resins, which is activated by elevated temperature.
  • epoxide crosslinking catalysts and / or curing agents for epoxy resins which is activated by elevated temperature.
  • these are selected from the group consisting of dicyandiamide, guanamines, guanidines, aminoguanidines and their derivatives; substituted ureas, in particular 3- (3-chloro-4-methylphenyl) -1,1-dimethylurea (chlorotoluron), or phenyl-dimethylureas, in particular p-chlorophenyl-N, N-dimethylurea (monuron), 3-phenyl-1, 1-dimethylurea (fenuron), 3,4-dichlorophenyl-N, N-dimethylurea (diuron), N, N-dimethylurea, N-iso-butyl-N '
  • heat-activatable hardeners are preferably activatable at a temperature of 80-160.degree. C., in particular of 85.degree. C. to 150.degree. C., preferably of 90-140.degree.
  • dicyandiamide is used in combination with a substituted urea.
  • the adhesive composition may additionally contain other constituents already in addition to the constituents mentioned, for example biocides, stabilizers, in particular heat stabilizers, plasticizers, pigments, adhesion promoters, in particular organosilanes, reactive binders, solvents, rheology modifiers, fillers or fibers, in particular glass, carbon, Cellulose, cotton or synthetic synthetic fibers, preferably fibers of polyester or of a homo- or copolymers of ethylene and / or propylene or of viscose.
  • the fibers can be used as short fibers or long fibers, or in the form of spun, woven or non-woven fiber materials.
  • the use of fibers is particularly advantageous for improving the mechanical reinforcement, in particular if at least some of the fibers consist of tensile or high-tensile fibers, in particular glass, carbon or aramids.
  • the adhesive composition is advantageously used in the form of granules, preferably with a granule diameter of 1 to 10 mm, in particular of 3 to 6 mm.
  • this adhesive composition is used in combination with a plastic film produced locally as described above, and applied within the open time of this plastic film produced, for example, by a crosslinking reaction of reactive components.
  • the application of the adhesive composition is preferably carried out by sprinkling in the not yet fully reacted and at least slightly tacky plastic film. This has the great advantage that the spread adhesive composition remains stuck to the surface of the plastic film and unwanted removal, for example by wind, of the adhesive composition can be largely prevented.
  • a plastic primer is applied to the plastic film applied in step (ii) in step (ii a), in which the adhesive composition is applied within the open time of the plastic primer.
  • the application of the adhesive composition is preferably carried out by sprinkling in the not yet reacted and at least slightly sticky plastic primer. This has the great advantage that the spread adhesive composition remains stuck to the surface of the adhering to the plastic film plastic primer and unwanted removal, for example by wind, the adhesive composition can be largely prevented.
  • the adhesive composition is used in the form of a film. This is done in the form of applying the adhesive composition in the form of a thin film.
  • Such an adhesive composition film can be produced, for example, in a film factory by at least partial melting of the adhesive composition and subsequent extrusion or calendering. At most, it may also be advantageous if this adhesive composition film contains a fiber fabric or fleece or connected to a fiber fabric or fleece, z. B. an-extruidert, is. After cooling, this film can be easily rolled and thus easily stored or transported. Thus, the adhesive composition is simply on the site and can be unrolled and cut to the required dimensions. This is a very cost and time efficient work step. Basically, the surface of such an adhesive composition film is tack-free.
  • an adhesive composition film has the great advantage that the adhesive composition is distributed over a large area and homogeneously and that the unwanted removal, for example by wind, of the adhesive composition can be largely prevented. It may also be helpful if a pressure sensitive adhesive is applied to one surface of such an adhesive composition film to achieve better fixation of the adhesive composition film to the plastic film during pavement fabrication. In this case, the use of a release paper is particularly recommended to prevent accidental sticking of the individual layers with each other, especially when they are rolled.
  • the adhesive composition is applied in a molten state to the plastic film applied in step (ii). This is typically done by melting the adhesive composition in place by means of a warm-up device and, for example, sprayed or whisked in the molten state. Upon cooling, the adhesive composition solidifies into a thin film adhered to the plastic film.
  • the adhesive composition is a dispersion in which at least solid epoxy resin and thermoplastic polymer are present as a solid phase in a liquid phase.
  • the adhesive composition in step (iii) is applied directly to the plastic film.
  • the liquid phase is formed in particular by a liquid reactive binder, preferably a binder based on two-component epoxides, which at most still have solvents or plasticizers.
  • a film is formed which binds the solid parts of the dispersion. This has the great advantage that these solids content of the adhesive composition remain stuck to the surface of the plastic film and an unwanted removal, for example by wind, the adhesive composition can be largely prevented.
  • step (iv) a bituminous base support layer is applied.
  • this bituminous base support layer is applied directly to the adhesive composition.
  • This base layer represents the road surface, which is in direct contact with vehicles.
  • the bituminous base layer is heated prior to application to a temperature of typically 140 ° C to 160 ° C and preferably rolled by means of a roll.
  • the application of the bituminous support layer is well known to the person skilled in the art and will therefore not be discussed further here.
  • the base layer can have the other possible components known to those skilled in the art.
  • One skilled in the art will be well aware of the nature and amount of the constituents of bitumen-based compositions used in pavement construction. Of particular importance here is the fact that the support layer usually to a significant extent mineral fillers, especially sand or grit have.
  • the thermoplastic polymer which is solid at room temperature, and any other fusible components of the adhesive composition will melt or melt depending on their melting point. If it melts, they can form a largely homogeneous thermoplastic layer or dissolve in the bitumen near the surface and form a thermoplastic-containing boundary phase layer. Thus, it is well within the spirit of the present invention that the adhesive composition need not necessarily form a discrete and individual layer. If the adhesive composition comprises a chemical or physical blowing agent, upon contacting the molten bitumen with the adhesive composition the propellant is activated and in particular a gas is released. It was found that the adhesion improvement is thereby further improved by observing the proportion of cohesive breakage during testing. The reason for this detention improvement is not yet clear. Gas evolution is believed to modify the bitumen structure at the interface, which in particular achieves better mechanical entanglement of bitumen and adhesive composition.
  • the roadway construction produced in this way has the significant advantage that a long-lasting bond between the individual layers is ensured among each other, that it remains dimensionally stable for a long time even under heavy axle loads.
  • the bond between the plastic film and the bitumen has been greatly improved over the prior art. This results in significantly less fatigue cracks that could affect the Abdichtfunktion the roadway structure.
  • This method presented here thus not only saves time in the manufacture of the roadway structure, but brings further savings in maintenance, since the repair or renewal intervals means can be extended.
  • Another aspect of the present invention relates to the use of the adhesive composition described above in detail for increasing the adhesion of bitumen to plastic.
  • the adhesive layer is in this case based on at least one solid epoxy resin and at least one solid at room temperature thermoplastic polymer.
  • the modified region of the plastic film and / or base layer in the interface region between the plastic film and the base layer is modified here with at least one solid epoxy resin and at least one thermoplastic polymer which is solid at room temperature.
  • either a discrete intermediate layer of the adhesive composition is formed during manufacture and forms the adhesive layer or the plastic film and / or backing layer are modified by the adhesive composition so that the composition of the near-surface region of plastic film and / or backing layer is chemically different from the composition the area remote from the plastic film and / or base layer differs.
  • the thickness of the modified region is highly dependent on the migration ability of the ingredients contained in the adhesive composition and the temperature of the bitumen in the application and its cooling behavior duration. For example, the migration ability is also dependent on the molecular weight and polarity of these constituents. Usually, the boundary of this modified area is not sharp but gradually formed.
  • FIG. 1 shows a schematic cross section through a concrete support structure 2 with applied concrete primer 3 and plastic film 4.
  • a two-component epoxy resin concrete primer 3 was applied to the concrete support structure 2 in a first step (i).
  • a quartz sand in Fig. 1 not shown
  • a two-component polyurethane plastic film 4 was sprayed in a layer thickness of 4 mm.
  • FIG. 1 shows the situation of the roadway structure after step (ii).
  • FIG. 2 shows a preferred embodiment of the application of the adhesive composition 5.
  • the plastic film 4 was produced on site, in particular as a sprayable 2-component polyurethane film.
  • the adhesive composition 5 is interspersed as a form of granules 5 'within, in particular towards the end, the open time of the plastic film 5 on the surface thereof. Since the plastic film is not yet fully reacted, they stick to the surface of the still sticky plastic film, or the granules 5 'sink easily into the plastic films and are thus integrated and fixed during the Ausreagieren of the plastic film in the plastic film surface.
  • FIG. 3 shows another preferred embodiment of applying the adhesive composition 5.
  • a plastic primer 6 is applied to the plastic film 4.
  • the plastic primer in this case preferably has a reactive binder, so that a crosslinking reaction occurs by a chemical reaction.
  • the adhesive composition 5 is interspersed as a form of granules 5 'within, in particular towards the end, the open-time plastic primer 6 on its surface. Since the plastic primer is not yet completely reacted, sticking to the surface of the still sticky plastic primer, or the granules 5 'sink slightly into the plastic primer and are so incorporated and fixed during the Ausreagieren the plastic primer in the plastic primer.
  • FIG. 4 shows another preferred embodiment of applying the adhesive composition 5.
  • the adhesive composition is applied in the form of a film 5 "The film was prepared by melting and extruding the adhesive composition in a film factory then a pressure sensitive adhesive 9 (pressure sensitive adhesive) applied and covered with a release film 10 and then rolled up. Such a role is now brought to the construction site if necessary, the film is unrolled and cut in the correct length and width and placed on the plastic film 4. When this laying the release film 10 is now deducted. In the FIG. 4 the deduction direction is indicated by a gray arrow. By removing the film, the pressure-sensitive adhesive 9 comes into contact with the plastic film 4, as a result of which the film 5 "is at least temporarily fixed with the plastic film 4, and the unwanted removal of adhesive composition 5 is largely prevented even in the case of larger wind movements.
  • FIG. 5 shows another preferred embodiment of applying the adhesive composition 5.
  • the adhesive composition 5 is applied in the form of a dispersion 5 '.
  • the dispersion 5' comprises solids phases of solid epoxy resin and thermoplastic polymer and a continuous liquid phase which is penetrated by liquid binder based on two-component epoxides and solvent or plasticizer is formed on.
  • the dispersion 5 '" is applied homogeneously to the surface of the plastic film 4 by means of a brush, for example ,
  • FIG. 6 shows a schematic cross-section through an embodiment of a roadway structure 1.
  • a bituminous base support layer 8 was applied in step (iv).
  • the adhesive composition 5, in particular in the form of interspersed granules 5 ' were heated by the contact with the molten bitumen and are melted so that an adhesive layer 7' is formed.
  • the adhesive composition 5 shown here was shown as a full-surface layer. After cooling down the Applied bituminous layer, the support layer 8 is stable and firmly connected to the plastic film 4.
  • FIG. 6 shows a schematic cross-section through a further embodiment of a roadway structure 1.
  • a bituminous base support layer 8 was applied in step (iv).
  • the adhesive composition 5, in particular in the form of interspersed granules 5 ' were heated by contact with the molten bitumen and melted.
  • the adhesive composition 5 penetrates into both the plastic film 4 and the base layer 8.
  • a modified region forms near the surface, namely a modified region 7 "in the plastic film 4, or a modified region 7 '" in the base layer 8.
  • compositions were prepared according to parts by weight in Table 1, in which the ingredients were mixed together in a twin-screw extruder at a temperature of 80 ° C. By subsequent strand granulation, a granule having a granule diameter of 1 to 3 mm was obtained.
  • Table 1 Compositions in parts by weight.
  • Sikafloor®-161 (available from Sika für AG) was applied as a plastic primer in a quantity of 0.3 to 0.4 kg / m 2 using a felt roller.
  • granules of the compositions according to Table 1 were then sprinkled in an amount of 0.8 to 1.0 kg / m 2 onto the still sticky plastic primer.
  • an asphalt asphalt AC T 16 N 70/100 heated to 160 ° C. was applied in two passes in an amount of 0.8 to 1.0 kg / m 2 , so that in each case a layer thickness of 4 cm resulted, and rolled.
  • Comparative Examples Ref. 1 and Ref. 2 have a very high proportion of adhesive fracture, whereas the examples according to the invention have a very high proportion of cohesive fracture.
  • the measured shear strength values of the examples according to the invention are noticeably, or sometimes greatly increased, compared to the comparative examples.

Landscapes

  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Road Paving Structures (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Bridges Or Land Bridges (AREA)
  • Laminated Bodies (AREA)
EP09164780A 2009-07-07 2009-07-07 Construction de voie de circulation dotée de propriétés améliorées Not-in-force EP2281948B1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
EP09164780A EP2281948B1 (fr) 2009-07-07 2009-07-07 Construction de voie de circulation dotée de propriétés améliorées
ES09164780T ES2394757T3 (es) 2009-07-07 2009-07-07 Construcción de calzada con propiedades de adherencia mejoradas
RU2012104030/03A RU2532113C2 (ru) 2009-07-07 2010-07-07 Конструкция дорожного полотна с улучшенными свойствами сцепления
CN201080030796.5A CN102472024B (zh) 2009-07-07 2010-07-07 具有增强的粘结特性的路面结构
AU2010270243A AU2010270243B2 (en) 2009-07-07 2010-07-07 Roadway structure having improved adhesive properties
PCT/EP2010/059682 WO2011003927A1 (fr) 2009-07-07 2010-07-07 Structure de chaussée à propriétés de cohésion améliorées
JP2012518976A JP5782028B2 (ja) 2009-07-07 2010-07-07 改善された接着特性を伴う道路構造物
US13/346,003 US8534953B2 (en) 2009-07-07 2012-01-09 Roadway structure having improved adhesive properties

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP09164780A EP2281948B1 (fr) 2009-07-07 2009-07-07 Construction de voie de circulation dotée de propriétés améliorées

Publications (2)

Publication Number Publication Date
EP2281948A1 true EP2281948A1 (fr) 2011-02-09
EP2281948B1 EP2281948B1 (fr) 2012-11-07

Family

ID=41367639

Family Applications (1)

Application Number Title Priority Date Filing Date
EP09164780A Not-in-force EP2281948B1 (fr) 2009-07-07 2009-07-07 Construction de voie de circulation dotée de propriétés améliorées

Country Status (7)

Country Link
US (1) US8534953B2 (fr)
EP (1) EP2281948B1 (fr)
JP (1) JP5782028B2 (fr)
CN (1) CN102472024B (fr)
ES (1) ES2394757T3 (fr)
RU (1) RU2532113C2 (fr)
WO (1) WO2011003927A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT513000A1 (de) * 2012-06-12 2013-12-15 Rojek Verfahren zur Herstellung einer Abdichtung von Fahrbahnen
EP2685001A1 (fr) * 2012-07-11 2014-01-15 Sika Technology AG Rêvetement de chaussée et procédé pour son obtention
EP3095914A1 (fr) * 2015-05-20 2016-11-23 Sika Technology AG Application simple d'une matière adhésive sur un sous-sol ayant une excellente adhérence à l'asphalte
EP3095915A1 (fr) * 2015-05-20 2016-11-23 Sika Technology AG Application d'un treillis pour construction de bande de roulement dotée de propriétés améliorées

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2192233A1 (fr) * 2008-11-27 2010-06-02 Sika Technology AG Methode pour rendre étanche une voie de circulation
CN103924495A (zh) * 2013-01-15 2014-07-16 上海市政工程设计研究总院(集团)有限公司 一种中小钢桥桥面铺装系统及实施方法
CN103243626B (zh) * 2013-05-23 2015-07-29 交通运输部公路科学研究所 一种适用于重载交通的半刚性基层沥青路面耐久性结构
RU2582685C1 (ru) * 2015-03-23 2016-04-27 Лев Петрович Петренко Способ формирования транспортной дороги (варианты)
CN107386109B (zh) * 2016-11-03 2023-08-01 江西省交通科学研究院 一种桥面铺装结构
RU176728U1 (ru) * 2017-08-18 2018-01-25 Акционерное общество "ОргСинтезРесурс" Конструкция дорожного покрытия

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2539333A1 (de) * 1975-09-04 1977-03-17 Hoechst Ag Verfahren zur herstellung von epoxidfestharzen
EP0199371A2 (fr) * 1985-04-16 1986-10-29 Rütgerswerke Aktiengesellschaft Procédé de construction de revêtements de tabliers de ponts
EP0212429A2 (fr) * 1985-08-08 1987-03-04 Gebr. von der Wettern GmbH Procédé de fabrication de systèmes d'enduction rigide aux efforts de cisaillement pour tabliers d'acier à revêtements en asphalte
AT413990B (de) 2003-09-05 2006-08-15 Toro Bausanierungs Und Handels Verfahren zur herstellung einer abdichtung von fahrbahnen z.b. auf brücken sowie zur aufbringung eines erneuerbaren verschleissbelages
WO2008095215A1 (fr) 2007-02-09 2008-08-14 Toro Bausanierungs- Und Handelsges.M.B.H. Chaussée utilisée sur des ponts présentant une structure porteuse de pont en béton

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1955421A (en) * 1934-04-17 Concrete structure and method of
BE793133A (fr) * 1972-07-26 1973-04-16 Villadsens Fab As Jens Materiau plastique en feuille et articles contenant un tel materiau
US4319854A (en) * 1977-12-19 1982-03-16 Owens-Corning Fiberglas Corporation Moisture control method and means for pavements and bridge deck constructions
US4556338A (en) * 1983-07-11 1985-12-03 Tar Heel Technologies, Inc. Method for reinforcing pavement
US4909662A (en) * 1989-01-13 1990-03-20 Baker Robert L Roadway and method of construction
RU2134330C1 (ru) * 1997-09-15 1999-08-10 Худайбердин Равиль Абдуллович Рулонный кровельный и гидроизоляционный материал "бикрост"
JP2000170111A (ja) * 1998-12-02 2000-06-20 Daito Sangyo Kk 舗装の防水接着方法及びその構造
WO2001044579A1 (fr) * 1999-12-17 2001-06-21 Mitsui Chemicals, Incorporated Couche de renfort pour routes, structure d'une chaussee asphaltee renforcee et son procede de realisation
RU20657U1 (ru) * 2001-08-06 2001-11-20 Общество с ограниченной ответственностью "ПРАС" Дорожная одежда
JP3956757B2 (ja) * 2002-04-24 2007-08-08 三菱化学産資株式会社 床版防水構造
JP4110002B2 (ja) * 2002-07-11 2008-07-02 大都産業株式会社 床版の防水舗装施工法及びその構造
JP4225796B2 (ja) * 2002-07-11 2009-02-18 大都産業株式会社 床版の防水舗装施工法及びその構造
WO2004076553A1 (fr) * 2003-02-25 2004-09-10 Toda Kogyo Corporation Composition de resine destinee au revetement
JP4909493B2 (ja) * 2003-09-19 2012-04-04 三和化工株式会社 接着剤用樹脂発泡シートおよびその製造方法並びに道路防水工法
CN100419165C (zh) * 2004-05-14 2008-09-17 深圳市海川实业股份有限公司 一种桥面用防水结构及其施工方法
US8186117B2 (en) * 2008-05-27 2012-05-29 Eren Tumer H System for creating a decking/flooring and a method for installing same
CN101314936A (zh) * 2008-07-07 2008-12-03 重庆市智翔铺道技术工程有限公司 桥面铺装中聚脲防水粘结层及其施工方法
EP2192233A1 (fr) * 2008-11-27 2010-06-02 Sika Technology AG Methode pour rendre étanche une voie de circulation

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2539333A1 (de) * 1975-09-04 1977-03-17 Hoechst Ag Verfahren zur herstellung von epoxidfestharzen
EP0199371A2 (fr) * 1985-04-16 1986-10-29 Rütgerswerke Aktiengesellschaft Procédé de construction de revêtements de tabliers de ponts
EP0212429A2 (fr) * 1985-08-08 1987-03-04 Gebr. von der Wettern GmbH Procédé de fabrication de systèmes d'enduction rigide aux efforts de cisaillement pour tabliers d'acier à revêtements en asphalte
AT413990B (de) 2003-09-05 2006-08-15 Toro Bausanierungs Und Handels Verfahren zur herstellung einer abdichtung von fahrbahnen z.b. auf brücken sowie zur aufbringung eines erneuerbaren verschleissbelages
WO2008095215A1 (fr) 2007-02-09 2008-08-14 Toro Bausanierungs- Und Handelsges.M.B.H. Chaussée utilisée sur des ponts présentant une structure porteuse de pont en béton

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT513000A1 (de) * 2012-06-12 2013-12-15 Rojek Verfahren zur Herstellung einer Abdichtung von Fahrbahnen
WO2013185156A1 (fr) * 2012-06-12 2013-12-19 Rojek Helmut Procédé pour réaliser une étanchéité de chaussées
AT513000B1 (de) * 2012-06-12 2014-08-15 Rojek Helmut Verfahren zur Herstellung einer Abdichtung von Fahrbahnen
EP2685001A1 (fr) * 2012-07-11 2014-01-15 Sika Technology AG Rêvetement de chaussée et procédé pour son obtention
WO2014009132A1 (fr) * 2012-07-11 2014-01-16 Sika Technology Ag Structure de chaussée et son procédé de fabrication
EP3095914A1 (fr) * 2015-05-20 2016-11-23 Sika Technology AG Application simple d'une matière adhésive sur un sous-sol ayant une excellente adhérence à l'asphalte
EP3095915A1 (fr) * 2015-05-20 2016-11-23 Sika Technology AG Application d'un treillis pour construction de bande de roulement dotée de propriétés améliorées
US9915037B2 (en) 2015-05-20 2018-03-13 Sika Technology Ag Simple application of an adhesive material to a substrate with excellent adhesion to asphalt

Also Published As

Publication number Publication date
CN102472024B (zh) 2014-08-13
US8534953B2 (en) 2013-09-17
RU2532113C2 (ru) 2014-10-27
AU2010270243A1 (en) 2012-02-23
ES2394757T3 (es) 2013-02-05
WO2011003927A1 (fr) 2011-01-13
JP2012533007A (ja) 2012-12-20
CN102472024A (zh) 2012-05-23
EP2281948B1 (fr) 2012-11-07
JP5782028B2 (ja) 2015-09-24
RU2012104030A (ru) 2013-08-20
US20120170977A1 (en) 2012-07-05

Similar Documents

Publication Publication Date Title
EP2281948B1 (fr) Construction de voie de circulation dotée de propriétés améliorées
EP2616518B1 (fr) Membrane d'étanchéité à adhérence améliorée
CH669955A5 (fr)
JP2012533007A5 (fr)
EP2652224B1 (fr) Utilisation de films de revêtement en polyoléfine revêtus d'adhésif thermofusible non réactif à des fins d'étanchéification
DE60015754T2 (de) Gefertigte verbundene struktur
EP2665791A1 (fr) Matière d'étanchéité et élément d'étanchéité pour l'étanchéification des ouvrages
DE2259660A1 (de) Verfahren und vorrichtung zur verlegung und verankerung von elastoplastischen streifen auf dem boden als waagerechte verkehrszeichen
EP2370638A1 (fr) Structure d'étanchéification d'une chaussée et son procédé de production
WO2014009132A1 (fr) Structure de chaussée et son procédé de fabrication
EP3095915B1 (fr) Application d'un treillis pour construction de bande de roulement dotée de propriétés adhésives améliorées
EP3095914B1 (fr) Procédé de production d'une structure routière
DE202011000107U1 (de) Dichtungsmasse und Dichtungselement zur Bauwerksabdichtung
GB2056458A (en) Epoxy resin compositions for use in seal coats
DE3513487A1 (de) Verfahren zur herstellung von fahrbahndecken auf bruecken
EP2859049B1 (fr) Procédé pour réaliser une étanchéité de chaussées
EP0212429B1 (fr) Procédé de fabrication de systèmes d'enduction rigide aux efforts de cisaillement pour tabliers d'acier à revêtements en asphalte
WO2009127448A1 (fr) Procédé de collage de granulats
WO2009024402A1 (fr) Revêtement de sol collé
DE1100213B (de) Biegsamer Verklebungsfilm in Folien- oder Bahnform

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20100115

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR

AX Request for extension of the european patent

Extension state: AL BA RS

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

RIC1 Information provided on ipc code assigned before grant

Ipc: E01C 7/32 20060101ALI20120625BHEP

Ipc: E01D 19/08 20060101AFI20120625BHEP

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

Ref country code: AT

Ref legal event code: REF

Ref document number: 583077

Country of ref document: AT

Kind code of ref document: T

Effective date: 20121115

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: LANGUAGE OF EP DOCUMENT: GERMAN

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 502009005309

Country of ref document: DE

Effective date: 20130103

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2394757

Country of ref document: ES

Kind code of ref document: T3

Effective date: 20130205

REG Reference to a national code

Ref country code: NL

Ref legal event code: VDEP

Effective date: 20121107

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121107

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130307

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121107

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121107

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121107

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130207

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121107

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121107

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121107

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130208

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130307

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121107

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130207

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121107

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121107

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121107

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121107

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121107

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121107

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20130808

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121107

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 502009005309

Country of ref document: DE

Effective date: 20130808

BERE Be: lapsed

Owner name: SIKA TECHNOLOGY A.G.

Effective date: 20130731

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121107

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20130731

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20130731

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20130731

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20130707

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121107

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121107

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121107

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20090707

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121107

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20130707

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 583077

Country of ref document: AT

Kind code of ref document: T

Effective date: 20140707

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20140707

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 8

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 9

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20200623

Year of fee payment: 12

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20200624

Year of fee payment: 12

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20200622

Year of fee payment: 12

Ref country code: ES

Payment date: 20200803

Year of fee payment: 12

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 502009005309

Country of ref document: DE

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20210707

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210707

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20220201

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210731

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20220930

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210708