EP2268784B2 - Granulat mit reduzierter fleckenbildung - Google Patents

Granulat mit reduzierter fleckenbildung Download PDF

Info

Publication number
EP2268784B2
EP2268784B2 EP09737914.3A EP09737914A EP2268784B2 EP 2268784 B2 EP2268784 B2 EP 2268784B2 EP 09737914 A EP09737914 A EP 09737914A EP 2268784 B2 EP2268784 B2 EP 2268784B2
Authority
EP
European Patent Office
Prior art keywords
dyes
dye
granule
sokalan
violet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP09737914.3A
Other languages
English (en)
French (fr)
Other versions
EP2268784B1 (de
EP2268784A1 (de
Inventor
Stephen Norman Batchelor
Jayne Michelle Bird
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Unilever NV
Original Assignee
Unilever PLC
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=39797974&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP2268784(B2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Unilever PLC, Unilever NV filed Critical Unilever PLC
Priority to EP09737914.3A priority Critical patent/EP2268784B2/de
Publication of EP2268784A1 publication Critical patent/EP2268784A1/de
Application granted granted Critical
Publication of EP2268784B1 publication Critical patent/EP2268784B1/de
Publication of EP2268784B2 publication Critical patent/EP2268784B2/de
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3776—Heterocyclic compounds, e.g. lactam
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3792—Amine oxide containing polymers

Definitions

  • the present invention relates to the delivery of shading dyes to fabrics.
  • WO 2005/003274 discloses that shading dyes are added to laundry detergents to increase whiteness.
  • One drawback with these powders is that under certain conditions localised spotting occurs on fabric treated with the detergent powder.
  • WO 2006 /020162 and WO 2006/053598 disclose laundry compositions comprising granules containing a dye.
  • a shading dye granule present in a laundry detergent formulation is susceptible to providing unwanted spotting of fabrics.
  • the present invention provides a shading dye granule comprising:
  • the present invention provides a granular laundry detergent composition
  • a granular laundry detergent composition comprising:
  • the surfactant that comes from the base powder may be a mixture of different types of surfactants but the total concentration of anionic surfactant in the granulate laundry detergent is in the range from 10 to 50 wt %.
  • the surfactant that comes from the base powder is preferably greater than 70% anionic surfactant.
  • the shading dye granule is visually distinct (VD) from a granular background powder in order to provide a visual cue.
  • the shading dye granule is for adding to a base powder (main detergent powder).
  • the shading dye granule does not contain an anionic surfactant.
  • the shading dye granule is admixed with the base powder, which must contain an anionic surfactant, there may be some migration of anionic surfactant to the shading dye granule.
  • the ratio of the dye transfer polymer:the charged surfactant prevents spotting whilst permitting dye deposition of substantive dyes from the wash liquors.
  • the shading dye is blue or violet. It is preferred that the shading dye(s) have a peak absorption wavelength of from 550nm to 650nm, preferably from 570nm to 630nm.
  • Dyes are coloured organic molecules which are soluble in aqueous media that contain surfactants. Dyes are described in 'Industrial Dyes', Wiley VCH 2002, K.Hunger (edit or).
  • Dyes are listed in the Color Index International published by Society of Dyers and Colourists and the American Association of Textile Chemists and Colorists . Dyes are preferably selected from the classes of basic, acid and direct dyes.
  • Direct violet and direct blue dyes are preferred.
  • the dyes are bis- azo or tris -azo dyes.
  • the carcinogenic benzidene based dyes are not preferred.
  • Bis-azo copper containing dyes such as direct violet 66 may be used.
  • the direct dye is a direct violet of the following structures: or wherein:
  • Preferred dyes are direct violet 7, direct violet 9, direct violet 11, direct violet 26, direct violet 31, direct violet 35, direct violet 40, direct violet 41, direct violet 51, and direct violet 99.
  • Cotton substantive acid dyes give benefits to cotton containing garments.
  • Preferred acid dyes are:
  • Preferred azine dyes are: acid violet 50 and acid blue 98.
  • acid dyes are acid violet 17, acid black 1, acid red 17 and acid blue 29.
  • the acid dye is present at 0.001 wt% to 0.006 wt% of the formulation.
  • the composition may comprise one or more hydrophobic dyes selected from benzodifuranes, methine, triphenylmethanes, napthalimides, pyrazole, napthoquinone, anthraquinone and mono-azo or di-azo dye chromophores.
  • Hydrophobic dyes are dyes which do not contain any charged water solubilising group. Hydrophobic dyes may be selected from the groups of disperse and solvent dyes. Blue and violet anthraquinone and mono-azo dye are preferred.
  • Preferred dyes include solvent violet 13, disperse violet 27 disperse violet 26, disperse violet 28, disperse violet 63 and disperse violet 77.
  • the hydrophobic dye is present at 0.0005 wt% to 0.004 wt% of the formulation.
  • Basic dyes are organic dyes which carry a net positive charge. They deposit onto cotton. They are of particular utility for used in composition that contain predominantly cationic surfactants. Dyes may be selected from the basic violet and basic blue dyes listed in the Colour Index International.
  • Preferred examples include triarylmethane basic dyes, azo basic dye, methane basic dye, anthraquinone basic dyes, basic blue 16, basic blue 65, basic blue 66, basic blue 67, basic blue 71, basic blue 159, basic violet 19, basic violet 35, basic violet 38, basic violet 48; basic blue 3, basic blue 75, basic blue 95, basic blue 122, basic blue 124, basic blue 141 and thiazolium dyes.
  • Reactive dyes are dyes which contain an organic group capable of reacting with cellulose and linking the dye to cellulose with a covalent bond. They deposit onto cotton.
  • the reactive group is hydrolysed or reactive group of the dyes has been reacted with an organic species such as a polymer, so as to the link the dye to this species.
  • Dyes may be selected from the reactive violet and reactive blue dyes listed in the Colour Index International.
  • Preferred examples include reactive blue 19, reactive blue 163, reactive blue 182 and reactive blue, reactive blue 96.
  • the shading dye granule according to the present invention comprising from 0.1 to 99.999 wt%, preferably from 0.5 to 18 wt%, more preferably from 0.5 to 2 wt% by weight of an anti-dye transfer polymer (ADTP) selected from: polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, polyvinylpyrrolidone polymers, polyvinyloxazolidones and polyvinylimidazoles.
  • ADTP anti-dye transfer polymer
  • ADTPs anti-dye transfer polymers
  • the preferred anti-dye transfer polymer is PVP.
  • the shading dye granule preferably contains a carrier preferred examples of carrier are bentonite, sodium chloride, zeolite, and sodium sulphate.
  • a binder is a material used to bind together two or more other materials in mixtures. Its two principal properties are adhesion and cohesion.
  • the binder is other than a non-ionic surfactant. Binders are standard in the art of laundry detergent granules, examples of which are: Sokalan® CP45, Sokalan® CP5, ethylene glycol, surfactants, anionic surfactants, polyethylene glycol, polyvinyl pyrrolidone, polyacrylates, citric acid and mixtures thereof.
  • the binder has a melting point above 30 °C.
  • the binder is selected from the group consisting of a polyacrylate, polyethylene glycol, and polyacrylate/maleate copolymer.
  • Suitable polymers for use herein are water-soluble.
  • water-soluble it is meant herein that the polymers have a solubility greater than 5 g/l at 20 °C in demineralised water.
  • the binder is preferably an acidic polymer.
  • an acidic polymer it is meant herein that a 1% solution of said polymers has a pH of less than 7, preferably less than 5.5.
  • Suitable polymers for use herein have a molecular weight in the range of from 1000 to 280,000, preferably from 1500 to 150,000.
  • Suitable polymers which meet the above criteria and are therefore particularly useful in the present invention include those having the following empirical formula I wherein X is 0 or CH2; Y is a comonomer or comonomer mixture; R1 and R2 are bleach-stable polymer-end groups; R3 is H, OH or C1-4 alkyl; M is H, and mixtures thereof with alkali metal, alkaline earth metal, ammonium or substituted ammonium; p is from 0 to 2; and n is at least 10, and mixtures thereof.
  • the proportion of M being H in such polymers is preferably such as to ensure that the polymer is sufficiently acidic to meet the acidity criteria as hereinbefore defined.
  • Polymers according to formula I are known in the field of laundry detergents, and are typically used as chelating agents, as for instance in GB-A-1,597,756 .
  • Preferred polycarboxylate polymers fall into several categories.
  • a first category belongs to the class of copolymeric polycarboxylate polymers which, formally at least, are formed from an unsaturated polycarboxylic acid such as maleic acid, citraconic acid, itaconic acid and mesaconic acid as first monomer, and an unsaturated monocarboxylic acid such as acrylic acid or an alpha -C1-C4 alkyl acrylic acid as second monomer.
  • preferred polycarboxylate polymers of this type are those in which X is CHO, R3 is H or C1-4 alkyl, especially methyl, p is from about 0.1 to about 1.9, preferably from about 0.2 to about 1.5, n averages from about 10 to about 1500, preferably from about 50 to about 1000, more preferably from 100 to 800, especially from 120 to 400 and Y comprises monomer units of formula II
  • Such polymers are available from BASF under the trade name Sokalan® CP5 (neutralised form) and Sokajan® CP45 (acidic form).
  • Binder materials are commercially readily available.
  • the water soluble polymers of the Sokalan® type sold by BASF® are preferred.
  • the granules are preferably of the size from 50 to 1800 microns.
  • the granule size is as determined by passing through a mesh sieve.
  • Preferably the size is in the range 100 to 800 microns.
  • the dye solvent violet 13 was mixed in non-ionic surfactant (7EO) to form a 0.5 wt% solution. To this was added the [nitrolotris(2,1-ethanediyloxy)] tris[propanol] salt of direct violet 9, DV9, (Ex Ciba Speciality Chemicals). The non-ionic was added to the carrier in a high shear mixer. Following this the binder, Sokalam CP5 (ex BASF) was added. Where appropriate polyvinylpyrrolidone, PVP, was added to the starting non-ionic solution.
  • the resultant granules were dried in an oven at 353K finally sieved to give granules in the size range 500 to 1400 microns.
  • the granules had the following composition. All percentages refer to dry weight%.
  • Granule bentonite 7EO DV9 PVP CP5 1* 69.93 20.56 0.20 0.00 9.41 2 69.71 20.68 0.20 0.21 9.51 3 69.41 20.65 0.08 0.21 9.83 4* 69.38 20.93 0.08 0.00 9.58 * comparative examples
  • the granules of example 1 were separately added to a detergent powder (20% linear alkyl benzene sulphonate, 30% sodium carbonate, 40% sodium chloride, remainder minors including fluorescer and moisture), at 2 wt%. 10 g of the powder was sprinkled onto a 25 by 25 cm piece of white cotton sheeting, immersed in 1 cm of demineralised water. The cloth was soaked for 90 minutes, then thoroughly rinsed and dried. Each experiment was repeated four times. Cloths soaked with Granule 1 and 2 were compared, and Granule 3 and 4 were compared, as they had equivalent levels of DV9. The eight clothes from each comparison were ranked in terms of the degree of dye staining/spotting. The cloth with the least staining/spotting received a score of 1, that with the second lowest level of staining a score of 2, and so on, so that the most stained/spotted cloth had a score of 8.
  • the granules containing the dye transfer inhibition polymer show reduced levels of spotting/staining.
  • the granules of example 1 were added to the base washing powder of example 2, such that when the washing powder was dissolved at 2g/L the wash liquor contained 200ppb of SV13.
  • Granule 2 and granule 3 were individually added to exemplary powder formulations A, B, C and D at 1 wt % to generate final formulations for use in washing and shading textiles.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
  • Coloring (AREA)

Claims (4)

  1. Nuancierfarbstoffgranulat, das Folgendes aufweist:
    (i) 0,001 bis 95 Gew.-% eines Nuancierfarbstoffs;
    (ii) 0,1 bis 99,999 Gew.-% eines Farbstoffübertragungspolymers, das ausgewählt ist aus: Polyamin-N-oxid-Polymeren, Copolymeren von N-Vinylpyrrolidon und N-Vinylimidazol, Polyvinylpyrrolidonpolymeren, Polyvinyloxazolidonen und Polyvinylimidazolen;
    (iii) 0 bis 80 Gew.-% eines nicht-ionischenTensides;
    (iv) 0 bis 20 Gew.-% eines anionischen oder kationischen Tensides;
    (v) 0 bis 99,5 Gew.-% eines Trägers;
    (vi) 0 bis 50 Gew.-% eines Bindemittels, wobei das Gewichtsverhältnis von Farbstoffübertragungspolymer zu geladenem Tensid 1:0 bis 1:1 beträgt und wobei der Nuancierfarbstoff blau oder violett ist.
  2. Nuancierfarbstoffgranulat gemäß Anspruch 1, wobei das geladene Tensid ein anionisches Tensid ist.
  3. Nuancierfarbstoffgranulat gemäß irgendeinem vorhergehenden Anspruch, wobei der Nuancierfarbstoff ausgewählt ist aus: sauren Farbstoffen, basischen Farbstoffen und Direktfarbstoffen.
  4. Körnige Waschmittelzusammensetzung umfassend:
    (a) 0,00005 bis 10 Gew.-% eines visuell unterschiedlichen Waschmittelgranulats gemäß einem der Ansprüche 1 bis 3;
    (b) 99,99995 bis 90 Gew.-% eines körnigen Grundpulvers, wobei die körnige Waschmittelzusammensetzung 10 bis 50 Gew.-% eines anionischen Tensides aufweist.
EP09737914.3A 2008-05-02 2009-02-18 Granulat mit reduzierter fleckenbildung Active EP2268784B2 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP09737914.3A EP2268784B2 (de) 2008-05-02 2009-02-18 Granulat mit reduzierter fleckenbildung

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP08155571 2008-05-02
EP09737914.3A EP2268784B2 (de) 2008-05-02 2009-02-18 Granulat mit reduzierter fleckenbildung
PCT/EP2009/051893 WO2009132870A1 (en) 2008-05-02 2009-02-18 Reduced spotting granules

Publications (3)

Publication Number Publication Date
EP2268784A1 EP2268784A1 (de) 2011-01-05
EP2268784B1 EP2268784B1 (de) 2012-11-21
EP2268784B2 true EP2268784B2 (de) 2015-10-28

Family

ID=39797974

Family Applications (1)

Application Number Title Priority Date Filing Date
EP09737914.3A Active EP2268784B2 (de) 2008-05-02 2009-02-18 Granulat mit reduzierter fleckenbildung

Country Status (9)

Country Link
EP (1) EP2268784B2 (de)
CN (1) CN102015989B (de)
AR (1) AR071603A1 (de)
BR (1) BRPI0910682B1 (de)
CL (1) CL2009001053A1 (de)
ES (1) ES2400204T5 (de)
MY (1) MY153627A (de)
WO (1) WO2009132870A1 (de)
ZA (1) ZA201007320B (de)

Families Citing this family (125)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0823344D0 (en) * 2008-12-22 2009-01-28 Reckitt Benckiser Nv Composition
AU2011246662B2 (en) 2010-04-26 2014-09-25 Novozymes A/S Enzyme granules
WO2012107405A1 (en) * 2011-02-07 2012-08-16 Punch Industries Dye scavenging substrate
US8946139B2 (en) 2011-05-26 2015-02-03 Conopco Inc. Liquid laundry composition
US20140371435A9 (en) 2011-06-03 2014-12-18 Eduardo Torres Laundry Care Compositions Containing Thiophene Azo Dyes
WO2012175401A2 (en) 2011-06-20 2012-12-27 Novozymes A/S Particulate composition
WO2012175708A2 (en) 2011-06-24 2012-12-27 Novozymes A/S Polypeptides having protease activity and polynucleotides encoding same
US20140206026A1 (en) 2011-06-30 2014-07-24 Novozymes A/S Method for Screening Alpha-Amylases
EP2732018B1 (de) 2011-07-12 2017-01-04 Novozymes A/S Lagerstabile enzymgranulate
CN103857781A (zh) 2011-07-21 2014-06-11 荷兰联合利华有限公司 液体洗衣组合物
US9000138B2 (en) 2011-08-15 2015-04-07 Novozymes A/S Expression constructs comprising a Terebella lapidaria nucleic acid encoding a cellulase, host cells, and methods of making the cellulase
CN104204200B (zh) 2011-09-22 2017-06-09 诺维信公司 具有蛋白酶活性的多肽和编码它们的多核苷酸
WO2013076269A1 (en) 2011-11-25 2013-05-30 Novozymes A/S Subtilase variants and polynucleotides encoding same
WO2013092635A1 (en) 2011-12-20 2013-06-27 Novozymes A/S Subtilase variants and polynucleotides encoding same
WO2013110766A1 (en) 2012-01-26 2013-08-01 Novozymes A/S Use of polypeptides having protease activity in animal feed and detergents
JP2015509364A (ja) 2012-02-17 2015-03-30 ノボザイムス アクティーゼルスカブ サブチリシン変異体およびそれをコードするポリヌクレオチド
EP2823026A1 (de) 2012-03-07 2015-01-14 Novozymes A/S Waschmittelzusammensetzung und substitution von optischen aufhellern in waschmittelzusammensetzungen
CN104220535B (zh) 2012-03-19 2017-03-22 美利肯公司 羧酸盐染料
CN113201519A (zh) 2012-05-07 2021-08-03 诺维信公司 具有黄原胶降解活性的多肽以及编码其的核苷酸
US9540600B2 (en) 2012-05-09 2017-01-10 The Procter & Gamble Company Laundry detergent composition comprising a particle having hueing agent and clay
US9540599B2 (en) 2012-05-09 2017-01-10 Milliken & Company Laundry detergent composition comprising a particle having hueing agent and clay
US20150140165A1 (en) 2012-06-20 2015-05-21 Novozymes A/S Use of polypeptides having protease activity in animal feed and detergents
ES2655032T3 (es) 2012-12-21 2018-02-16 Novozymes A/S Polipéptidos que poseen actividad proteasa y polinucleótidos que los codifican
CN112458069A (zh) 2013-01-03 2021-03-09 诺维信公司 α-淀粉酶变体以及对其进行编码的多核苷酸
WO2014183921A1 (en) 2013-05-17 2014-11-20 Novozymes A/S Polypeptides having alpha amylase activity
WO2014193859A1 (en) 2013-05-28 2014-12-04 The Procter & Gamble Company Surface treatment compositions comprising photochromic dyes
WO2014195356A2 (en) 2013-06-06 2014-12-11 Novozymes A/S Alpha-amylase variants and polynucleotides encoding same
RU2016102045A (ru) 2013-06-27 2017-08-01 Новозимс А/С Варианты субтилаз и кодирующие их полинуклеотиды
EP3013955A1 (de) 2013-06-27 2016-05-04 Novozymes A/S Subtilasevarianten und polynukleotide zur codierung davon
US20160152925A1 (en) 2013-07-04 2016-06-02 Novozymes A/S Polypeptides Having Anti-Redeposition Effect and Polynucleotides Encoding Same
CN105358686A (zh) 2013-07-29 2016-02-24 诺维信公司 蛋白酶变体以及对其进行编码的多核苷酸
US9926550B2 (en) 2013-07-29 2018-03-27 Novozymes A/S Protease variants and polynucleotides encoding same
EP3339436B1 (de) 2013-07-29 2021-03-31 Henkel AG & Co. KGaA Waschmittelzusammensetzung mit proteasevarianten
CA2920901A1 (en) 2013-09-18 2015-03-26 The Procter & Gamble Company Laundry care compositions containing thiophene azo carboxylate dyes
WO2015042086A1 (en) 2013-09-18 2015-03-26 The Procter & Gamble Company Laundry care composition comprising carboxylate dye
US9834682B2 (en) 2013-09-18 2017-12-05 Milliken & Company Laundry care composition comprising carboxylate dye
EP3047009B1 (de) 2013-09-18 2018-05-16 The Procter and Gamble Company Wäschepflegezusammensetzungen mit carboxylatfarbstoff
WO2015049370A1 (en) 2013-10-03 2015-04-09 Novozymes A/S Detergent composition and use of detergent composition
CN105814200A (zh) 2013-12-20 2016-07-27 诺维信公司 具有蛋白酶活性的多肽以及编码它们的多核苷酸
WO2015112339A1 (en) 2014-01-22 2015-07-30 The Procter & Gamble Company Fabric treatment composition
EP3097174A1 (de) 2014-01-22 2016-11-30 The Procter & Gamble Company Verfahren zur behandlung von textilstoffen
WO2015112341A1 (en) 2014-01-22 2015-07-30 The Procter & Gamble Company Fabric treatment composition
WO2015112338A1 (en) 2014-01-22 2015-07-30 The Procter & Gamble Company Method of treating textile fabrics
EP2899260A1 (de) 2014-01-22 2015-07-29 Unilever PLC Verfahren zur Herstellung einer Flüssigreinigungsmittelformulierung
US20160348035A1 (en) 2014-03-05 2016-12-01 Novozymes A/S Compositions and Methods for Improving Properties of Non-Cellulosic Textile Materials with Xyloglucan Endotransglycosylase
WO2015134737A1 (en) 2014-03-05 2015-09-11 Novozymes A/S Compositions and methods for improving properties of cellulosic textile materials with xyloglucan endotransglycosylase
EP3126479A1 (de) 2014-04-01 2017-02-08 Novozymes A/S Polypeptide mit alpha-amylase-aktivität
JP2017518407A (ja) 2014-05-06 2017-07-06 ミリケン・アンド・カンパニーＭｉｌｌｉｋｅｎ ＆ Ｃｏｍｐａｎｙ ランドリーケア組成物
EP3155097A1 (de) 2014-06-12 2017-04-19 Novozymes A/S Alpha-amylase-varianten und polynukleotide zur codierung davon
WO2016001449A1 (en) 2014-07-04 2016-01-07 Novozymes A/S Subtilase variants and polynucleotides encoding same
EP3739029A1 (de) 2014-07-04 2020-11-18 Novozymes A/S Subtilasevarianten und polynukleotide zur codierung davon
US10017716B2 (en) * 2014-08-22 2018-07-10 Rohm And Haas Company Imidazole-modified carbohydrate polymers as laundry dye transfer inhibitors
EP3221447A1 (de) 2014-11-20 2017-09-27 Novozymes A/S Alicyclobacillus-varianten und dafür codierende polynukleotide
RU2710720C2 (ru) 2014-12-04 2020-01-10 Новозимс А/С Варианты субтилазы и кодирующие их полинуклеотиды
EP3608403A3 (de) 2014-12-15 2020-03-25 Henkel AG & Co. KGaA Reinigungsmittelzusammensetzung mit subtilasevarianten
EP3292173A1 (de) 2015-05-04 2018-03-14 Milliken & Company Leuko-triphenylmethanfarbstoffe als vergrauungshemmer in wäschepflegezusammensetzungen
WO2016188693A1 (en) 2015-05-27 2016-12-01 Unilever Plc Laundry detergent composition
TR201906836T4 (tr) 2015-06-02 2019-05-21 Unilever Nv Çamaşır deterjan bileşimi.
WO2016202839A2 (en) 2015-06-18 2016-12-22 Novozymes A/S Subtilase variants and polynucleotides encoding same
EP3106508B1 (de) 2015-06-18 2019-11-20 Henkel AG & Co. KGaA Reinigungsmittelzusammensetzung mit subtilasevarianten
CN108138083B (zh) 2015-10-01 2021-06-11 荷兰联合利华有限公司 粉末洗衣洗涤剂组合物
US20180171318A1 (en) 2015-10-14 2018-06-21 Novozymes A/S Polypeptides Having Protease Activity and Polynucleotides Encoding Same
EP4324919A3 (de) 2015-10-14 2024-05-29 Novozymes A/S Polypeptidvarianten
EP3417040B1 (de) 2016-02-17 2019-09-04 Unilever PLC Bleichungszusammensetzung
WO2017140391A1 (en) 2016-02-17 2017-08-24 Unilever Plc Whitening composition
US10947480B2 (en) 2016-05-17 2021-03-16 Conopeo, Inc. Liquid laundry detergent compositions
BR112018073598B1 (pt) 2016-05-17 2022-09-27 Unilever Ip Holdings B.V Composição líquida para lavagem de roupas e uso de uma composição líquida detergente para lavagem de roupas
WO2017207762A1 (en) 2016-06-03 2017-12-07 Novozymes A/S Subtilase variants and polynucleotides encoding same
CN109642222A (zh) 2016-07-13 2019-04-16 诺维信公司 食物芽孢杆菌dna酶变体
WO2018060139A1 (en) 2016-09-27 2018-04-05 Unilever Plc Domestic laundering method
CN109844083B (zh) 2016-10-18 2021-11-09 联合利华知识产权控股有限公司 增白组合物
US20180119056A1 (en) 2016-11-03 2018-05-03 Milliken & Company Leuco Triphenylmethane Colorants As Bluing Agents in Laundry Care Compositions
CN110869480B (zh) 2017-07-07 2021-08-13 联合利华知识产权控股有限公司 增白组合物
CN110892053A (zh) 2017-07-07 2020-03-17 荷兰联合利华有限公司 洗衣清洁组合物
DK3476936T3 (da) 2017-10-27 2022-03-14 Procter & Gamble Vaskemiddelsammensætninger, der omfatter polypeptidvarianter
MX2020004145A (es) 2017-10-27 2020-08-03 Novozymes As Variantes de desoxirribonucleasa (dnasa).
CN111479912B (zh) 2017-11-30 2021-08-10 联合利华知识产权控股有限公司 包含蛋白酶的洗涤剂组合物
EP3755774B1 (de) 2018-02-23 2024-05-08 Unilever Global IP Limited Geformtes waschmittelprodukt mit aminopolycarboxylat
CN111971372B (zh) * 2018-04-03 2022-03-11 联合利华知识产权控股有限公司 染料颗粒
US20210009927A1 (en) 2018-04-17 2021-01-14 Novozymes A/S Polypeptides Comprising Carbohydrate Binding Activity in Detergent Compositions And Their use in Reducing Wrinkles in Textile or Fabrics
WO2019219531A1 (en) 2018-05-17 2019-11-21 Unilever Plc Cleaning composition
BR112020023123A2 (pt) 2018-05-17 2021-02-02 Unilever N.V. composição de limpeza e método doméstico para tratar um tecido
EP3824057B1 (de) 2018-07-17 2023-10-18 Unilever Global IP Limited Verwendung eines rhamnolipids in einem tensidsystem
WO2020058024A1 (en) 2018-09-17 2020-03-26 Unilever Plc Detergent composition
CN113166689A (zh) 2018-11-20 2021-07-23 联合利华知识产权控股有限公司 洗涤剂组合物
EP3884026B1 (de) 2018-11-20 2024-06-26 Unilever Global Ip Limited Reinigungsmittelzusammensetzung
BR112021009807A2 (pt) 2018-11-20 2021-08-17 Unilever Ip Holdings B.V. composição detergente, método de tratamento de um substrato de tecido e uso de uma enzima isomerase
BR112021009789A2 (pt) 2018-11-20 2021-08-17 Unilever Ip Holdings B.V. composição detergente, método de tratamento de um substrato de tecido e uso de uma enzima esterase
CN113056550B (zh) 2018-11-20 2022-10-28 联合利华知识产权控股有限公司 洗涤剂组合物
US20220235341A1 (en) 2019-03-21 2022-07-28 Novozymes A/S Alpha-amylase variants and polynucleotides encoding same
WO2020207944A1 (en) 2019-04-10 2020-10-15 Novozymes A/S Polypeptide variants
EP3750978A1 (de) 2019-06-12 2020-12-16 Unilever N.V. Wäschewaschmittelzusammensetzung
EP3750979A1 (de) 2019-06-12 2020-12-16 Unilever N.V. Verwendung einer waschmittelzusammensetzung
WO2020260006A1 (en) 2019-06-28 2020-12-30 Unilever Plc Detergent compositions
BR112021022423A2 (pt) 2019-06-28 2022-01-04 Unilever Ip Holdings B V Composição detergente e método doméstico de tratamento de tecidos
CN113906124B (zh) 2019-06-28 2024-08-02 联合利华知识产权控股有限公司 洗涤剂组合物
US20220372397A1 (en) 2019-06-28 2022-11-24 Conopco, Inc., D/B/A Unilever Detergent composition
US20220364022A1 (en) 2019-06-28 2022-11-17 Conopco, Inc., D/B/A Unilever Detergent composition
CN114008183A (zh) 2019-06-28 2022-02-01 联合利华知识产权控股有限公司 洗涤剂组合物
WO2021032833A1 (en) 2019-08-21 2021-02-25 Unilever Ip Holdings B.V. Detergent solid composition
CN114787329A (zh) 2019-08-27 2022-07-22 诺维信公司 洗涤剂组合物
AR119874A1 (es) 2019-09-02 2022-01-19 Unilever Nv Composición detergente con un derivado de éster de ácido cítrico de un monoglicérido
CN114616312A (zh) 2019-09-19 2022-06-10 诺维信公司 洗涤剂组合物
US20220340843A1 (en) 2019-10-03 2022-10-27 Novozymes A/S Polypeptides comprising at least two carbohydrate binding domains
AR120142A1 (es) 2019-10-07 2022-02-02 Unilever Nv Composición detergente
WO2021185956A1 (en) 2020-03-19 2021-09-23 Unilever Ip Holdings B.V. Detergent composition
EP4121502A1 (de) 2020-03-19 2023-01-25 Unilever IP Holdings B.V. Reinigungsmittelzusammensetzung
EP3892708A1 (de) 2020-04-06 2021-10-13 Henkel AG & Co. KGaA Reinigungszusammensetzungen mit dispersinvarianten
WO2021249927A1 (en) 2020-06-08 2021-12-16 Unilever Ip Holdings B.V. Method of improving protease activity
WO2022023250A1 (en) 2020-07-27 2022-02-03 Unilever Ip Holdings B.V. Use of an enzyme and surfactant for inhibiting microorganisms
US20230287300A1 (en) 2020-08-28 2023-09-14 Conopco, Inc., D/B/A Unilever Surfactant and detergent composition
BR112023002979A2 (pt) 2020-08-28 2023-04-04 Unilever Ip Holdings B V Composição detergente e método de tratamento de um artigo têxtil
EP4204526B1 (de) 2020-08-28 2024-04-24 Unilever IP Holdings B.V. Tensid und waschmittelzusammensetzung
EP4204530B1 (de) 2020-08-28 2024-07-17 Unilever IP Holdings B.V. Reinigungsmittelzusammensetzung
WO2022043042A1 (en) 2020-08-28 2022-03-03 Unilever Ip Holdings B.V. Detergent composition
EP4225905A2 (de) 2020-10-07 2023-08-16 Novozymes A/S Alpha-amylase-varianten
EP4263771A1 (de) 2020-12-17 2023-10-25 Unilever IP Holdings B.V. Verwendung und reinigungsmittel
WO2022128781A1 (en) 2020-12-17 2022-06-23 Unilever Ip Holdings B.V. Cleaning composition
CN116829709A (zh) 2021-02-12 2023-09-29 诺维信公司 α-淀粉酶变体
WO2022268885A1 (en) 2021-06-23 2022-12-29 Novozymes A/S Alpha-amylase polypeptides
BR112023026713A2 (pt) 2021-06-24 2024-03-12 Unilever Ip Holdings B V Composição de limpeza em dose unitária
CN117957300A (zh) 2021-09-20 2024-04-30 联合利华知识产权控股有限公司 洗涤剂组合物
EP4433567A1 (de) 2021-10-21 2024-09-25 Unilever IP Holdings B.V. Waschmittelzusammensetzungen
WO2023144071A1 (en) 2022-01-28 2023-08-03 Unilever Ip Holdings B.V. Laundry composition
WO2024131880A2 (en) 2022-12-23 2024-06-27 Novozymes A/S Detergent composition comprising catalase and amylase

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5073295A (en) † 1987-12-29 1991-12-17 Ciba-Geigy Corporation Encapsulated fluorescent whitening agent, photoativator or anti-microbial agent
US6291412B1 (en) † 1998-05-18 2001-09-18 Ciba Specialty Chemicals Corporation Water-soluble granules of phthalocyanine compounds
WO2005014769A1 (en) † 2003-08-06 2005-02-17 Ciba Specialty Chemicals Holding Inc. Shading composition
WO2007006357A1 (en) † 2005-07-11 2007-01-18 Unilever Plc Dye delivery granules

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2360293A (en) * 2000-03-14 2001-09-19 Procter & Gamble Detergent compositions
GB0314210D0 (en) * 2003-06-18 2003-07-23 Unilever Plc Laundry treatment compositions
EP2248884A1 (de) * 2004-07-22 2010-11-10 The Procter & Gamble Company Waschmittelzusammensetzungen enthaltend Farbpartikel
CA2588068A1 (en) * 2004-11-22 2006-05-26 Unilever Plc Laundry treatment compositions

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5073295A (en) † 1987-12-29 1991-12-17 Ciba-Geigy Corporation Encapsulated fluorescent whitening agent, photoativator or anti-microbial agent
US6291412B1 (en) † 1998-05-18 2001-09-18 Ciba Specialty Chemicals Corporation Water-soluble granules of phthalocyanine compounds
WO2005014769A1 (en) † 2003-08-06 2005-02-17 Ciba Specialty Chemicals Holding Inc. Shading composition
WO2007006357A1 (en) † 2005-07-11 2007-01-18 Unilever Plc Dye delivery granules

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
M. S. SHOWELL: "Powdered Detergents", 1998, MARCEL DEKKER, NEW YORK, pages: 14 †

Also Published As

Publication number Publication date
EP2268784B1 (de) 2012-11-21
CL2009001053A1 (es) 2010-01-15
MY153627A (en) 2015-02-27
ZA201007320B (en) 2012-01-25
BRPI0910682A2 (pt) 2015-09-29
ES2400204T3 (es) 2013-04-08
EP2268784A1 (de) 2011-01-05
CN102015989B (zh) 2012-07-04
BRPI0910682B1 (pt) 2020-09-24
ES2400204T5 (es) 2015-11-26
WO2009132870A1 (en) 2009-11-05
CN102015989A (zh) 2011-04-13
AR071603A1 (es) 2010-06-30

Similar Documents

Publication Publication Date Title
EP2268784B2 (de) Granulat mit reduzierter fleckenbildung
EP2288686B1 (de) Nuancierungsmittel
EP2118256B2 (de) Nuancierungsmittel
EP2297288B1 (de) Waschmittelzusammensetzungen
EP1627909B1 (de) Waschmittelzusammensetzungen enthaltend Farbpartikel
WO2007006357A1 (en) Dye delivery granules
JP2022547846A (ja) コポリマーを含む布地ケア組成物及び関連する方法
CN104302752A (zh) 包含含调色剂和粘土的颗粒的衣物洗涤剂组合物
EP0753566B1 (de) Waschmittelzusammensetzung und Verfahren zur Verhinderung der Absetzung von Farbstoff
EP1023430B1 (de) Wasserlösliche farbstoff komplexierende polymere als farbstoffübertragungsinhibitoren in wäschewasch- und weichspülerzusammensetzungen
EP3250666B1 (de) Verdickte wässrige reinigungsmittelzusammensetzungen
EP2787066A1 (de) Waschmittelzusammensetzung mit Abtönungsfarbstoffen und Lipase
DE60108510T2 (de) Gefärbte teilchenzusammensetzung sowie diese enthaltende teilchenförmige waschmittel
US20070203052A1 (en) Laundry Composition
CN112760176B (zh) 一种低碱性护色洗衣粉组合物及其制备方法
EP0584736B1 (de) Verwendung von Polyvinylalkoholen als Waschmittelzusatz
EP3775121B1 (de) Farbstoffgranulat
EP2085461A1 (de) Waschzusammensetzung
CA3199892A1 (en) Colour care detergent composition
EP2331670B1 (de) Kationische isothiazolium-farbstoffe

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20101012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: AL BA RS

DAX Request for extension of the european patent (deleted)
GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 585100

Country of ref document: AT

Kind code of ref document: T

Effective date: 20121215

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602009011374

Country of ref document: DE

Effective date: 20130117

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2400204

Country of ref document: ES

Kind code of ref document: T3

Effective date: 20130408

REG Reference to a national code

Ref country code: NL

Ref legal event code: VDEP

Effective date: 20121121

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK05

Ref document number: 585100

Country of ref document: AT

Kind code of ref document: T

Effective date: 20121121

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130221

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130321

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130222

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

Ref country code: BE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130221

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

26 Opposition filed

Opponent name: THE PROCTER & GAMBLE COMPANY

Effective date: 20130820

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20130228

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PLAX Notice of opposition and request to file observation + time limit sent

Free format text: ORIGINAL CODE: EPIDOSNOBS2

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20130228

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20130228

REG Reference to a national code

Ref country code: DE

Ref legal event code: R026

Ref document number: 602009011374

Country of ref document: DE

Effective date: 20130820

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20130218

PLBB Reply of patent proprietor to notice(s) of opposition received

Free format text: ORIGINAL CODE: EPIDOSNOBS3

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 7

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20130218

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20090218

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

PUAH Patent maintained in amended form

Free format text: ORIGINAL CODE: 0009272

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: PATENT MAINTAINED AS AMENDED

27A Patent maintained in amended form

Effective date: 20151028

AK Designated contracting states

Kind code of ref document: B2

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: DE

Ref legal event code: R102

Ref document number: 602009011374

Country of ref document: DE

REG Reference to a national code

Ref country code: ES

Ref legal event code: DC2A

Ref document number: 2400204

Country of ref document: ES

Kind code of ref document: T5

Effective date: 20151126

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 8

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 9

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20170217

Year of fee payment: 9

Ref country code: DE

Payment date: 20170217

Year of fee payment: 9

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20170213

Year of fee payment: 9

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 602009011374

Country of ref document: DE

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20181031

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180901

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180228

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20190801

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180219

REG Reference to a national code

Ref country code: GB

Ref legal event code: 732E

Free format text: REGISTERED BETWEEN 20220203 AND 20220209

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20240219

Year of fee payment: 16

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: TR

Payment date: 20240210

Year of fee payment: 16