EP2247770A1 - Procédé pour le revêtement sol-gel d'un objet traité thermiquement - Google Patents
Procédé pour le revêtement sol-gel d'un objet traité thermiquementInfo
- Publication number
- EP2247770A1 EP2247770A1 EP09706898A EP09706898A EP2247770A1 EP 2247770 A1 EP2247770 A1 EP 2247770A1 EP 09706898 A EP09706898 A EP 09706898A EP 09706898 A EP09706898 A EP 09706898A EP 2247770 A1 EP2247770 A1 EP 2247770A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- sol
- gel coating
- heat treatment
- heat
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 60
- 239000011248 coating agent Substances 0.000 title claims abstract description 58
- 238000000034 method Methods 0.000 title claims abstract description 33
- 238000010438 heat treatment Methods 0.000 claims abstract description 23
- 238000005507 spraying Methods 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 2
- 238000001723 curing Methods 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000005536 corrosion prevention Methods 0.000 description 2
- 238000013007 heat curing Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
- C23C18/04—Pretreatment of the material to be coated
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
- C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
- C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
- C23C18/125—Process of deposition of the inorganic material
- C23C18/1254—Sol or sol-gel processing
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
- C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
- C23C18/125—Process of deposition of the inorganic material
- C23C18/1291—Process of deposition of the inorganic material by heating of the substrate
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/18—After-treatment
Definitions
- the invention relates to a method defined in the preamble of claim 1 for the sol-gel coating of a heat-treated object.
- Sol-gel coating is usually provided as a separate manufacturing step in the production process of the product.
- One process step in providing a sol-gel coating normally comprises curing the coating, which is usually carried out e.g. in a furnace at a temperature of about 100 to 150 2 C as a separate process step.
- the heat treatment / curing step which is part of forming a sol-gel coating easily causes problems, in particular when applying the proc- ess in the already existing production plants. There may not necessarily be the required heat treatment apparatus or capacity it requires, one is not willing to make the investment required for acquiring one, or there is simply not enough room for the new equipment in the production area.
- heat treatment / curing of a sol-gel coating and the preceding and following work steps take time, which is why this particular work step may form a bottleneck for the production process.
- the objective of the invention is to eliminate the drawbacks referred to above and to disclose a new type of method for providing a sol-gel coating.
- the method according to the invention is characterized by what has been presented in the claims .
- the invention is based on a method for sol- gel coating a heat-treated object, wherein the object is heat-treated e.g. by hot galvanization or hot spraying, and the sol-gel coating is formed onto the object.
- the heat energy transferred and stored in the object in conjunction with the heat treatment is applied for curing the sol- gel coating in the formation of the sol-gel coating.
- an object refers to any kind of two- or three-dimensional object.
- the object may have been formed from any material which is suitable for the purpose, e.g. metal or alloy.
- the basic idea of the invention is that the heat energy transferred and stored in the object during a heat treatment process, e.g. hot galvanization process or hot spray coating performed before the sol- gel coating, is utilized in the sol-gel coating provided after the heat treatment, whereby the sol-gel coating cures and acquires its final properties without any separate heat treatment to provide the curing. Further, the basic idea of the invention encompasses the utilization of residual heat energy in the sol-gel coating, whereby the sol-gel coating is cured by utilizing residual heat energy generated e.g. during hot galvanization or hot spraying.
- the heat treatment is hot galvanization, preferably hot galvanization of piece articles.
- the heat treatment is hot spraying.
- the temperature of the object after hot galvanization e.g. as lifted from the hot galvanization kettle after immersion coating, is 430 to 470 °C, preferably about 450 2 C.
- the tem- perature of the object after hot spraying is 180 to 220 0 C, preferably about 200 2 C.
- the object is cooled to a desired temperature after the heat treatment by air . In one embodiment of the invention, the object is cooled to a desired temperature after the heat treatment by water cooling.
- the object is cooled before sol-gel coating to a temperature of 100 to 200°C.
- the object is cooled before sol-gel coating to a temperature of 80 to 100 0 C.
- the ob- ject is cooled before sol-gel coating to a temperature of 50 to 8O 0 C, which are lower temperatures of the material than what is usual.
- the sol- gel coating is provided onto the object substantially directly after heat treatment. Between heat treatment and sol-gel coating, the object can be cooled to a desired temperature.
- the invention provides the advantage that a sol-gel coating provided after heat treatment, e.g. galvanization or hot spraying, does not require a separate heat treatment step to cure the coating, or any pretreatment step.
- Use of the method according to the invention saves both energy and processing costs in the formation of a sol-gel coating.
- sol-gel coating onto hot-galvanized objects and cure the coating by the method according to the invention.
- the objects were let cool after hot galvanization to dif- ferent temperatures which were 250, 200, 150, 100 and 50 2 C, after which the objects were coated with sol-gel coating and let cool further to room temperature. It was discovered that the sol-gel coating of the objects and curing of the coating were successfully accom- pushed by the method according to the invention.
- the preliminary tests comprised testing test samples coated by WC10Co4Cr coating and their corresponding coating by the sol-gel coating, the applied temperatures of the coated material being 170, 140 and HO 2 C.
- the tests revealed that it is possible to use even lower temperatures of the material that is to be sol-gel coated, even temperatures between 50 and 80 a C. It was discovered that the sol-gel coating of objects that were treated by hot spraying, and curing of the coating were successfully accomplished by the method according to the invention.
- sol-gel coating of various products e.g. metal products
- curing the coating are possible without a separate heat treatment step by utilizing the heat energy stored during some other process step or remaining from that step in the material that is to be coated.
- this method provides equal properties in terms of corrosion prevention or water-repelling ability of the sol-gel coating, if the temperature of the substrate at the time of coating is suitable for the applied coating. At its best, the corrosion prevention ability is equal to a coating cured in optimum conditions, as is also the water contact angle, i.e. water repelling ability.
- the method according to the invention is suitable in different embodiments for use in the most different kinds of sol-gel coating processes.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Plasma & Fusion (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI20085073A FI20085073A0 (fi) | 2008-01-30 | 2008-01-30 | Menetelmä kuumasinkittyjen ja termisesti ruiskutettujen tuotteiden sooli-geelipinnoitukseen |
PCT/FI2009/050024 WO2009095530A1 (fr) | 2008-01-30 | 2009-01-15 | Procédé pour le revêtement sol-gel d'un objet traité thermiquement |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2247770A1 true EP2247770A1 (fr) | 2010-11-10 |
EP2247770A4 EP2247770A4 (fr) | 2011-02-16 |
Family
ID=39004373
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09706898A Withdrawn EP2247770A4 (fr) | 2008-01-30 | 2009-01-15 | Procédé pour le revêtement sol-gel d'un objet traité thermiquement |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP2247770A4 (fr) |
FI (1) | FI20085073A0 (fr) |
WO (1) | WO2009095530A1 (fr) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000226691A (ja) * | 1999-02-05 | 2000-08-15 | Toyo Kohan Co Ltd | 表面処理鋼板の製造方法および表面処理鋼板 |
JP2001064782A (ja) * | 1999-06-23 | 2001-03-13 | Tanaka Galvanizing Co Ltd | 鋼材に高耐候性を付与する表面処理方法及び高耐候性鋼材 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5106828A (en) | 1987-07-20 | 1992-04-21 | North American Philips Corporation | Method for fabricating superconductors by sol-gel process |
US5262204A (en) | 1989-11-03 | 1993-11-16 | Schott Glaswerke | Glass-ceramic article decorated with ceramic color and process for its production |
CZ293670B6 (cs) | 2002-03-25 | 2004-06-16 | Ornela A. S. | Způsob získání barevného povlaku na drobných skleněných předmětech |
-
2008
- 2008-01-30 FI FI20085073A patent/FI20085073A0/fi not_active Application Discontinuation
-
2009
- 2009-01-15 EP EP09706898A patent/EP2247770A4/fr not_active Withdrawn
- 2009-01-15 WO PCT/FI2009/050024 patent/WO2009095530A1/fr active Application Filing
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000226691A (ja) * | 1999-02-05 | 2000-08-15 | Toyo Kohan Co Ltd | 表面処理鋼板の製造方法および表面処理鋼板 |
JP2001064782A (ja) * | 1999-06-23 | 2001-03-13 | Tanaka Galvanizing Co Ltd | 鋼材に高耐候性を付与する表面処理方法及び高耐候性鋼材 |
Non-Patent Citations (1)
Title |
---|
See also references of WO2009095530A1 * |
Also Published As
Publication number | Publication date |
---|---|
EP2247770A4 (fr) | 2011-02-16 |
WO2009095530A1 (fr) | 2009-08-06 |
FI20085073A0 (fi) | 2008-01-30 |
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Extension state: AL BA RS |
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A4 | Supplementary search report drawn up and despatched |
Effective date: 20110119 |
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DAX | Request for extension of the european patent (deleted) | ||
17Q | First examination report despatched |
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STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
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18D | Application deemed to be withdrawn |
Effective date: 20160802 |