EP2210457A2 - Procédé de fabrication d'un composant à fonction électronique - Google Patents
Procédé de fabrication d'un composant à fonction électroniqueInfo
- Publication number
- EP2210457A2 EP2210457A2 EP08871932A EP08871932A EP2210457A2 EP 2210457 A2 EP2210457 A2 EP 2210457A2 EP 08871932 A EP08871932 A EP 08871932A EP 08871932 A EP08871932 A EP 08871932A EP 2210457 A2 EP2210457 A2 EP 2210457A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- printing
- mixed
- homogeneous
- layers
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 42
- 239000000463 material Substances 0.000 claims abstract description 97
- 238000007639 printing Methods 0.000 claims abstract description 97
- 230000008021 deposition Effects 0.000 claims abstract description 10
- 230000000295 complement effect Effects 0.000 claims description 21
- 239000010409 thin film Substances 0.000 claims description 21
- 238000004519 manufacturing process Methods 0.000 claims description 18
- 230000001939 inductive effect Effects 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 9
- 230000008569 process Effects 0.000 claims description 9
- 239000003990 capacitor Substances 0.000 claims description 8
- 229910010293 ceramic material Inorganic materials 0.000 claims description 7
- 239000007790 solid phase Substances 0.000 claims description 5
- 239000007791 liquid phase Substances 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims 1
- 239000000976 ink Substances 0.000 description 14
- 238000000151 deposition Methods 0.000 description 9
- 238000001540 jet deposition Methods 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 238000005266 casting Methods 0.000 description 1
- 239000011231 conductive filler Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/16—Printed circuits incorporating printed electric components, e.g. printed resistor, capacitor, inductor
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/002—Details
- H01G4/005—Electrodes
- H01G4/008—Selection of materials
- H01G4/0085—Fried electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/002—Details
- H01G4/005—Electrodes
- H01G4/012—Form of non-self-supporting electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/30—Stacked capacitors
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/16—Printed circuits incorporating printed electric components, e.g. printed resistor, capacitor, inductor
- H05K1/162—Printed circuits incorporating printed electric components, e.g. printed resistor, capacitor, inductor incorporating printed capacitors
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/16—Printed circuits incorporating printed electric components, e.g. printed resistor, capacitor, inductor
- H05K1/165—Printed circuits incorporating printed electric components, e.g. printed resistor, capacitor, inductor incorporating printed inductors
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/16—Printed circuits incorporating printed electric components, e.g. printed resistor, capacitor, inductor
- H05K1/167—Printed circuits incorporating printed electric components, e.g. printed resistor, capacitor, inductor incorporating printed resistors
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
- H05K2203/01—Tools for processing; Objects used during processing
- H05K2203/0104—Tools for processing; Objects used during processing for patterning or coating
- H05K2203/013—Inkjet printing, e.g. for printing insulating material or resist
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/10—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern
- H05K3/12—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern using thick film techniques, e.g. printing techniques to apply the conductive material or similar techniques for applying conductive paste or ink patterns
- H05K3/1241—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern using thick film techniques, e.g. printing techniques to apply the conductive material or similar techniques for applying conductive paste or ink patterns by ink-jet printing or drawing by dispensing
- H05K3/125—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern using thick film techniques, e.g. printing techniques to apply the conductive material or similar techniques for applying conductive paste or ink patterns by ink-jet printing or drawing by dispensing by ink-jet printing
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/46—Manufacturing multilayer circuits
- H05K3/4644—Manufacturing multilayer circuits by building the multilayer layer by layer, i.e. build-up multilayer circuits
- H05K3/4664—Adding a circuit layer by thick film methods, e.g. printing techniques or by other techniques for making conductive patterns by using pastes, inks or powders
Definitions
- the present invention relates to the field of electronic component manufacturing processes.
- the invention relates to a method of manufacturing capacitors.
- This document describes a method of depositing successive printing layers of ceramics and metallic materials. This The method further introduces, as indicated on page 16, lines 22 to 26, for a given layer, a surface condition of a certain roughness, so as to influence the arrangement, in terms of spreading and dispersion, of the material which will then be deposited on this layer.
- An object of the present invention is to provide a method for producing three-dimensional multi-material components meeting the disadvantages of the prior art mentioned above.
- the invention provides a method of producing a three-dimensional multi-material component composed of at least a first and a second material.
- the method consists in producing at least two superimposed printing layers along discrete spatial pathways of printing paths, the printing layers being executed by non-contact deposition of localized impacts of printing drops, and:
- a homogeneous printing layer N A is constituted by at least the first material excluding the second material, and
- At least one mixed printing layer Ni consists of the first material and at least the second material.
- At least one other mixed printing layer Ni + i is superimposed on the preceding mixed printing layer Ni.
- the first material of the mixed printing layer Ni + i is substantially superimposed on the first material of the preceding mixed printing layer Ni.
- a plurality of mixed printing layers are deposited successively, forming a first mixed thin layer Mi having complementary reliefs of first and second materials.
- a plurality of homogeneous printing layers N A constituted by at least the first material excluding the second material and forming a thin layer homogeneous M A are deposited successively on the first mixed thin layer Mi.
- a plurality of homogeneous printing layers N B consisting of at least the second material excluding the first material and forming a homogeneous thin film M B are successively deposited on the first mixed thin layer Mi.
- At least two other thin films, mixed Mi then homogeneous M A , M B are deposited successively on the homogeneous thin film M A ; M B previous.
- At least one of the complementary reliefs of first and second materials has a dome shape
- the complementary reliefs forms a crossing between two homogeneous thin layers;
- the projected printing drops have at least one component in the liquid phase and at least one component in the solid phase so as to form a liquid mixture;
- the volume proportion of solid phase element in the liquid mixture is between 1% and 50%;
- the viscosity of the liquid mixture sprayed is between 1 and 40 mPa.s;
- the surface tension of the liquid mixture sprayed is between 20 and 70 mN / m; the deposits are operated on a support made of evanescent material, for example based on graphite or paper, which can be destroyed at high temperature;
- At least one of the deposited materials is based on ceramic material.
- the method can be applied to the fabrication of capacitors, capacitive resistive, capacitive inductive and capacitive inductive resistive multi-functional components.
- the invention also relates to a three-dimensional multi-material component that can be obtained by implementing the method according to any one of the abovementioned embodiments.
- the component comprises at least two printing layers produced by non-contact deposition of localized impacts of printing drops, and:
- a homogeneous printing layer N A comprises at least one first material excluding a second material
- At least one mixed printing layer Ni comprises the first and at least one second material.
- the component further comprises at least one mixed printing layer Ni + i superimposed on the printing layer Ni.
- the first material of the printing layer Ni + i is substantially superimposed on the first material of the preceding printing layer Ni.
- the component comprises a plurality of mixed printing layers forming a mixed thin layer Mi having complementary reliefs of first and second material.
- it comprises a plurality of homogeneous printing layers N A , constituted by at least the first material excluding the second material and forming a homogeneous thin film M A , deposited successively on the first mixed thin layer Mi.
- it comprises a plurality of homogeneous printing layers N B , constituted by at least the second material excluding the first material and forming a homogeneous thin film M B , deposited successively on the first mixed thin layer Mi.
- it comprises at least two other thin films, mixed Mi then homogeneous M A , M B , deposited successively on the homogeneous thin film M A ; M B previous.
- At least one of the complementary reliefs has a dome shape
- At least one of the complementary reliefs forms a crossing between two homogeneous thin layers (M A , M B ).
- the invention finally relates to a capacitive resistive, capacitive inductive and resistive capacitive inductive resistive component according to any one of the abovementioned embodiments.
- the method of embodiment and the component according to the invention can improve the strength, or bond, mechanical between the various thin layers forming the component.
- complementary reliefs of first and second materials having a dome shape makes it possible to bond several homogeneous thin layers without altering the conductivity of the component. Moreover, the complementary reliefs forming a crossing between two homogeneous thin layers substantially improves the mechanical strength between these two homogeneous thin layers.
- printing layer is meant here an elementary thickness of a localized deposit of printing drops made in a discrete spatial trajectory and forming a continuum. As a result, two printing drops forming the same printing layer are not considered superimposed as long as they overlap only partially.
- superimposed printing layers is meant the successive deposition of at least two layers printing in a constant direction substantially perpendicular to the deposition surface.
- homogeneous printing layer is understood to mean a printing layer formed by the deposition of at least one first material excluding a second material or the deposition of at least one second material to the second material. exclusion of the first material.
- mixed printing layer is meant a printing layer having at least the first and second materials.
- homogeneous thin film is understood to mean the superposition of at least two homogeneous printing layers and by mixed thin film, the superposition of at least two mixed printing layers.
- FIG. 1 shows a schematic cross-sectional view of two homogeneous and mixed printing layers superimposed according to an embodiment of the invention
- FIGS. 2a and 2b show three superimposed printing layers according to an embodiment method according to the invention
- - Figures 3, 4, 5 and 6 show cross-sectional views of five superimposed thin layers according to an embodiment of the invention and for which several complementary reliefs of first and second materials have a dome shape.
- FIG. 7 shows a cross-sectional view of three superimposed thin layers according to an embodiment of the invention and for which several complementary reliefs of first and second materials form a crossing between two homogeneous thin layers.
- the multi-material three-dimensional component 2 is produced by non-contact impact deposition.
- localized printing drops along a discrete spatial trajectory of printing path.
- the localized impacts of printing drops initially form a homogeneous printing layer N A constituted by a first material A.
- the localized impacts of printing drops form a mixed printing layer Ni consisting of first material A and a second material B different.
- Figures 2a and 2b schematically show two embodiments of components 2 according to the present invention.
- the component 2 comprises a first homogeneous printing layer N A on which is superimposed a mixed printing layer Ni, then a second homogeneous printing layer N A '.
- the component 2 comprises a first mixed printing layer Ni on which is superimposed a homogeneous printing layer N A / and then a second mixed printing layer Ni + i.
- the final component 2 obtained according to the invention preferably comprises a larger number of printing layers N A , N B , Ni, Ni + i formed in accordance with the production method according to the invention.
- the production method according to the invention makes it possible to produce a component 2 having at least two thin layers M A , M B , M 1, M n each composed of a plurality of superimposed printing layers N A , N B , Ni, Ni +1 .
- a thin layer formed by the superposition of a plurality of homogeneous printing layers N A , N B is called homogeneous thin film M A , M B.
- a thin layer formed by the superposition of a plurality of mixed printing layers Ni, Ni + i is called mixed thin film Mi; Min.
- the first material A of a mixed printing layer Ni +1 is substantially superposed on the first material A of the preceding mixed printing layer Ni so as to form a mixed thin film Mi; Mi +1 , presenting complementary reliefs of first and second materials (A, B).
- These complementary reliefs provide a connection between the various thin layers of the component 2. It is therefore here not a surface state provided with a certain roughness for increasing the mechanical strength of the component 2, but real reliefs preventing the relative displacement of two homogeneous superimposed thin layers.
- a first homogeneous thin film M A is produced by successively depositing a plurality of homogeneous printing layers.
- a first mixed thin film Mj is then superimposed on the first homogeneous thin film M A.
- the first thin layer Mi has complementary reliefs 4 of first and second materials (A, B).
- a second homogeneous thin layer M B is then superimposed on the previous thin mixed layer Mi.
- the reliefs thus formed between the first homogeneous thin layer M A and the second homogeneous thin layer M B to improve the mechanical cohesion between these homogeneous thin films M A , M B and consequently the cohesion of the final component 2.
- a second thin mixed film Mn also having complementary reliefs 4, then a third homogeneous thin film M A 'are successively superimposed on the second homogeneous thin film M B.
- the aforementioned reliefs 4 may be the subject of numerous variants. It may be protruding reliefs 4a as shown in FIG. 3, or recessed reliefs 4b as shown in FIG. 4. It may also be a combination of protruding reliefs 4a and 4b hollow reliefs, as illustrated in Figures 5 and 6.
- the component 2 has a first homogeneous thin layer M A on which is superimposed a mixed thin layer
- first and second homogeneous thin films M A , M A ' are both formed from at least one first material A and excluding a second material B.
- the complementary reliefs 4 form crossings 4c of first material A between the first and second homogeneous thin layers M A , M A '.
- these bushings 4c made of material A are formed locally in a mixed thin film also comprising a different material B, so as to connect at least two printing layers N A , N A 'consisting of at least the same material A , excluding the second material B.
- the successive deposits of printing layers in the context of the present invention may be carried out according to any technique known to those skilled in the art.
- This is preferably ink jet deposition.
- the Applicant has determined that various deposited ink parameters are critical to obtain a functional and reliable component 2.
- the projected drops consist of at least one solid phase component and a liquid phase component so as to form a liquid mixture.
- the volume content of inorganic filler in the deposited inks is substantially between 1 and 50%.
- the viscosity of the inks deposited is between about 1 and about 40 mPa.s.
- the Applicant has determined that, preferably, the surface tension of the inks deposited is between about 20 and about 70 mN / m.
- the ink jet deposition of the layers forming the component 2 according to the present invention can be operated on any suitable support.
- said support is formed of an evanescent material. That is, the material is intended to be removed by any suitable technique once the component 2, or at least the first printing layer N A , N B , Ni, is produced. More specifically still in the context of the present invention, for this purpose, the support layer receiving the ink jet deposits is formed of a material that can be destroyed at high temperature, for example based on graphite or paper. any appropriate composition.
- the mixed printing layers Ni, Ni + i integrate electrically conductive fillers while the homogeneous printing layers N A , N A 'are layers of electrically insulating.
- the mixed printing layers Ni, Ni + i form, for example, the capacitor plates.
- the present invention is not limited to the production of components 2 of the capacitor type. It encompasses the production of any type of component 2 with an electronic function, for example components 2 incorporating resistive and / or inductive functions by using resistive or inductive ink on localized areas.
- the present invention thus makes it possible to make multifunctional components 2 as variants.
- RC resistive and capacitive
- LC inductive and capacitive
- RLC resistive and capacitive
- the present invention is not limited to the embodiments presented above, but extends to any variant that can be made by those skilled in the art. Therefore, the present invention is not limited to the particular embodiment of capacitors, but on the contrary covers the manufacture of many other components 2 with electronic function, such as for example components 2 incorporating resistive and / or inductive elements.
- some mixed thin layers may be formed from randomly superimposed mixed printing layers so that materials A and B are mixed within these mixed thin layers.
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Ceramic Capacitors (AREA)
- Electroluminescent Light Sources (AREA)
- Printing Methods (AREA)
- Manufacturing Of Printed Wiring (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0707976A FR2923671B1 (fr) | 2007-11-13 | 2007-11-13 | Procede de fabrication d'un composant a fonction electronique. |
PCT/FR2008/001590 WO2009095559A2 (fr) | 2007-11-13 | 2008-11-12 | Procédé de fabrication d'un composant à fonction électronique |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2210457A2 true EP2210457A2 (fr) | 2010-07-28 |
EP2210457B1 EP2210457B1 (fr) | 2014-06-04 |
Family
ID=39530162
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP08871932.3A Not-in-force EP2210457B1 (fr) | 2007-11-13 | 2008-11-12 | Procédé de fabrication d'un composant à fonction électronique |
Country Status (5)
Country | Link |
---|---|
US (1) | US20100294549A1 (fr) |
EP (1) | EP2210457B1 (fr) |
ES (1) | ES2490166T3 (fr) |
FR (1) | FR2923671B1 (fr) |
WO (1) | WO2009095559A2 (fr) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2381451B1 (fr) | 2010-04-22 | 2018-08-01 | Epcos AG | Procédé de production d'un composant électrique multicouches et composant électrique multicouches |
US8883064B2 (en) | 2011-06-02 | 2014-11-11 | A. Raymond & Cie | Method of making printed fastener |
US8916085B2 (en) | 2011-06-02 | 2014-12-23 | A. Raymond Et Cie | Process of making a component with a passageway |
EP2714375A1 (fr) | 2011-06-02 | 2014-04-09 | A. Raymond et Cie | Dispositifs de fixation fabriqués par impression en trois dimensions |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060159838A1 (en) * | 2005-01-14 | 2006-07-20 | Cabot Corporation | Controlling ink migration during the formation of printable electronic features |
US6835473B2 (en) * | 2001-12-06 | 2004-12-28 | Konica Corporation | Organic electroluminescence element and display |
JP3805273B2 (ja) * | 2002-03-29 | 2006-08-02 | Uht株式会社 | 積層型電子部品の製造装置 |
JP2003318133A (ja) * | 2002-04-22 | 2003-11-07 | Seiko Epson Corp | 膜パターンの形成方法、膜パターン形成装置、導電膜配線、半導体チップの実装構造、半導体装置、発光装置、電気光学装置、電子機器、並びに非接触型カード媒体 |
FR2859128B1 (fr) * | 2003-08-29 | 2006-03-10 | Centre Nat Rech Scient | Procede et dispositif de fabrication d'un composant multimateriaux tridimensionnel par impression du type jet d'encre |
JP2005081335A (ja) * | 2003-09-11 | 2005-03-31 | Seiko Epson Corp | パターン形成方法、導電性薄膜、電気光学装置、電子機器 |
US7229936B2 (en) * | 2004-05-03 | 2007-06-12 | International Business Machines Corporation | Method to reduce photoresist pattern collapse by controlled surface microroughening |
KR100663941B1 (ko) * | 2005-03-30 | 2007-01-02 | 삼성전기주식회사 | 어레이형 적층 세라믹 콘덴서 및 그 제조 방법 |
TWI270901B (en) * | 2005-09-16 | 2007-01-11 | Ctech Technology Corp | Solid capacitor and fabrication method thereof |
-
2007
- 2007-11-13 FR FR0707976A patent/FR2923671B1/fr not_active Expired - Fee Related
-
2008
- 2008-11-12 EP EP08871932.3A patent/EP2210457B1/fr not_active Not-in-force
- 2008-11-12 ES ES08871932.3T patent/ES2490166T3/es active Active
- 2008-11-12 US US12/742,565 patent/US20100294549A1/en not_active Abandoned
- 2008-11-12 WO PCT/FR2008/001590 patent/WO2009095559A2/fr active Application Filing
Non-Patent Citations (1)
Title |
---|
See references of WO2009095559A2 * |
Also Published As
Publication number | Publication date |
---|---|
ES2490166T3 (es) | 2014-09-03 |
FR2923671A1 (fr) | 2009-05-15 |
US20100294549A1 (en) | 2010-11-25 |
FR2923671B1 (fr) | 2010-08-27 |
EP2210457B1 (fr) | 2014-06-04 |
WO2009095559A2 (fr) | 2009-08-06 |
WO2009095559A3 (fr) | 2009-11-05 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20100507 |
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