EP2175494B1 - Dispositif semi-conducteur en matériau composite et son procédé de fabrication - Google Patents

Dispositif semi-conducteur en matériau composite et son procédé de fabrication Download PDF

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EP2175494B1
EP2175494B1 EP09178269.8A EP09178269A EP2175494B1 EP 2175494 B1 EP2175494 B1 EP 2175494B1 EP 09178269 A EP09178269 A EP 09178269A EP 2175494 B1 EP2175494 B1 EP 2175494B1
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layer
compound semiconductor
semiconductor device
gate electrode
forming
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EP2175494A2 (fr
EP2175494A3 (fr
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Toshihide Kikkawa
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Fujitsu Ltd
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Fujitsu Ltd
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Priority to EP13164123.5A priority patent/EP2657976B1/fr
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    • H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76—Unipolar devices, e.g. field effect transistors
    • H01L29/772—Field effect transistors
    • H01L29/778—Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/12—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
    • H01L29/20—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only AIIIBV compounds
    • H01L29/201—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only AIIIBV compounds including two or more compounds, e.g. alloys
    • H01L29/205—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only AIIIBV compounds including two or more compounds, e.g. alloys in different semiconductor regions, e.g. heterojunctions
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/12—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
    • H01L29/26—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, elements provided for in two or more of the groups H01L29/16, H01L29/18, H01L29/20, H01L29/22, H01L29/24, e.g. alloys
    • H01L29/267—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, elements provided for in two or more of the groups H01L29/16, H01L29/18, H01L29/20, H01L29/22, H01L29/24, e.g. alloys in different semiconductor regions, e.g. heterojunctions
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007—Multistep manufacturing processes
    • H01L29/66075—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409—Unipolar field-effect transistors
    • H01L29/66446—Unipolar field-effect transistors with an active layer made of a group 13/15 material, e.g. group 13/15 velocity modulation transistor [VMT], group 13/15 negative resistance FET [NERFET]
    • H01L29/66462—Unipolar field-effect transistors with an active layer made of a group 13/15 material, e.g. group 13/15 velocity modulation transistor [VMT], group 13/15 negative resistance FET [NERFET] with a heterojunction interface channel or gate, e.g. HFET, HIGFET, SISFET, HJFET, HEMT
    • H—ELECTRICITY
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    • H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76—Unipolar devices, e.g. field effect transistors
    • H01L29/772—Field effect transistors
    • H01L29/778—Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface
    • H01L29/7786—Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface with direct single heterostructure, i.e. with wide bandgap layer formed on top of active layer, e.g. direct single heterostructure MIS-like HEMT
    • H01L29/7787—Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface with direct single heterostructure, i.e. with wide bandgap layer formed on top of active layer, e.g. direct single heterostructure MIS-like HEMT with wide bandgap charge-carrier supplying layer, e.g. direct single heterostructure MODFET
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/12—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
    • H01L29/20—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only AIIIBV compounds
    • H01L29/2003—Nitride compounds
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    • H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/40—Electrodes ; Multistep manufacturing processes therefor
    • H01L29/43—Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
    • H01L29/49—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET
    • H01L29/51—Insulating materials associated therewith
    • H01L29/518—Insulating materials associated therewith the insulating material containing nitrogen, e.g. nitride, oxynitride, nitrogen-doped material

Definitions

  • the present invention relates to a compound semiconductor device suitable for a high electron mobility transistor (HEMT) and so on and a manufacturing method thereof.
  • HEMT high electron mobility transistor
  • an electronic device (a compound semiconductor device) is vigorous in which a GaN layer and an AlGaN layer are formed sequentially on a substrate composed of sapphire, SiC, GaN, Si, or the like, and the GaN layer is used as an electron transit layer.
  • a bandgap of GaN is 3.4 eV, and it is larger than that of GaAs of 1.4 eV. Accordingly, an operation in high withstand voltage is expected for the compound semiconductor device.
  • a high-voltage operation is required for a base station amplifier of a cellular phone system, and a high withstand voltage is essential requirement thereof. At present, a value over 300 V is reported as a withstand voltage when current is turned off. There is a case when a change in on-resistance during operation called as a current collapse occurs in the above-stated compound semiconductor device. This phenomenon can be avoided by disposing a GaN protective layer on an AlGaN electron supply layer, and further forming an SiN protective film. The structure as stated above is described in, for example, Patent Document 1.
  • Fig. 16 is a sectional view showing a structure of a conventional compound semiconductor device.
  • An AlN layer 102, a GaN layer 103, an n-type AlGaN layer 104a, an n-type AlGaN layer 104b and an n-type GaN layer 105 are sequentially formed on an SiC substrate 101.
  • a thickness of the AlN layer 102 is 150 ⁇ m.
  • a total thickness of the n-type AlGaN layer 104b and the n-type GaN layer 105 is approximately 30 nm.
  • an SiN layer 107 is formed on the n-type GaN layer 105.
  • Plural openings are formed at the SiN layer 107, and a source electrode 108a, a drain electrode 108b and a gate electrode 109 are evaporated in these openings.
  • this compound semiconductor device is a normally-on type.
  • a compound semiconductor device is used for automobile parts. Current continues to flow in the automobile parts when a car goes out of order resulting from a traffic accident and so on when the compound semiconductor device is the normally-on type. Accordingly, a demand for a normally-off type compound semiconductor device becomes high in recent times.
  • a positive gate leakage current flows in a saturation region as input power is made large. This is because the gate electrode 109 and the n-type GaN layer 105 are in contact directly. It is difficult to continue to use in a saturation power state if the gate leak current as stated above flows, and it is hard to say that it is suitable for the base station amplifier of the cellular phone.
  • Patent Document 3 discloses a compound semiconductor device comprising an InGaN carrier transit layer formed over a semiconductor substrate, an AlGaN carrier supply layer formed on the carrier transit layer, GaN based protective layers formed on the carrier supply layer, a source electrode, a drain electrode and a gate electrode formed on the protective layer, an AlN layer formed on the protective layer between the gate electrode and the source electrode, and between the gate electrode and the drain electrode, and an insulator layer formed on the AlN layer.
  • An object of the present invention is to provide a compound semiconductor device and a manufacturing method thereof capable of suppressing current flowing when a gate voltage is set to be "0" (zero), and manufacturing with high reproducibility.
  • a compound semiconductor device comprising: a GaN based carrier transit layer formed over a semiconductor substrate; a GaN based carrier supply layer formed on said carrier transit layer; a GaN based protective layer formed on said carrier supply layer; a source electrode, a drain electrode and a gate electrode formed on said protective layer; a non-doped AlN layer formed on said protective layer, and positioned between said gate electrode and said source electrode, and between said gate electrode and said drain electrode; and an insulator layer formed on said AlN layer; wherein a GaN based compound semiconductor layer is formed between said AlN layer and said insulator layer.
  • a manufacturing method of a compound semiconductor device comprising: forming a GaN based carrier transit layer over a semiconductor substrate; forming a GaN based carrier supply layer on the carrier transit layer; forming a GaN based protective layer on the carrier supply layer; forming a non-doped AlN layer on said protective layer; forming an insulator layer on the AlN layer; forming an opening for a source electrode, an opening for a drain electrode and an opening for a gate electrode in the insulator layer and the AlN layer; forming electrodes in the three openings, wherein said forming the opening for the gate electrode has performing wet etching of the AlN layer until the protective layer exposes; and forming a GaN based compound semiconductor layer on the AlN layer, between said forming the AlN layer and said forming the insulator layer.
  • FIG. 1 is a sectional view showing a structure of a compound semiconductor device according to the first example of the present invention.
  • an AlN layer 2 with a thickness of approximately 150 nm to 300 nm is formed on an SiC substrate 1.
  • a GaN buffer layer 3 (a carrier transit layer) with a thickness of approximately 3 ⁇ m is formed on the AlN layer 2.
  • a non-doped AlGaN layer 4a with a thickness of approximately 5 nm is formed on the GaN buffer layer 3.
  • An n-type AlGaN layer 4b (a carrier supply layer) with a thickness of approximately 15 nm to 20 nm is formed on the non-doped AlGaN layer 4a.
  • the n-type AlGaN layer 4b is doped with Si at approximately 4 ⁇ 10 18 cm -3 .
  • an n-type GaN layer 5 (a protective layer) with a thickness of approximately 7 nm is formed on the n-type AlGaN layer 4b.
  • the n-type GaN layer 5 is doped with Si at approximately 5 ⁇ 10 18 cm -3 .
  • a non-doped AlN layer 6 with a thickness of approximately 3 nm and an SiN layer 7 with a thickness of approximately 20 nm are sequentially formed on the n-type GaN layer 5.
  • a semiconductor-insulator junction exists between the non-doped AlN layer 6 and the SiN layer 7.
  • At least three openings are formed in the non-doped AlN layer 6 and the SiN layer 7, and a source electrode 8a, a drain electrode 8b and a gate electrode 19 are evaporated in these openings.
  • a semiconductor-metal junction exists between the non-doped AlN layer 6 and the gate electrode 19.
  • a metal-semiconductor junction exists between the gate electrode 19 and the n-type GaN layer 5.
  • the source electrode 8a and the drain electrode 8b may be composed of, for example, a Ta film with a thickness of approximately 10 nm and an Al film with a thickness of approximately 300 nm formed thereon.
  • the gate electrode 19 may be composed of, for example, an Ni film and an Au film formed thereon.
  • a piezoelectric effect resulting from a lattice mismatch occurs in a vicinity of an interface of the non-doped AlGaN layer 4a with the GaN buffer layer 3. Accordingly, positive polarization charges appear, and electrons are induced in the vicinity of the interface of the GaN buffer layer 3 with the non-doped AlGaN layer 4a. As a result, a two-dimensional electron gas (2DEG) appears.
  • 2DEG two-dimensional electron gas
  • the SiN layer 7 exists at a periphery of the gate electrode 19 as an insulator layer, and therefore, it is possible to prevent a gate leak current from a side surface. Accordingly, a high withstand voltage is realized.
  • the non-doped AlN layer 6 exists between the SiN layer 7 and the n-type GaN layer 5, and therefore, electrons exist at an interface between the non-doped AlN layer 6 and the n-type GaN layer 5. Accordingly, a lot of two-dimensional electron gas exists at an electron transit region between the gate electrode 19 and the source electrode 8a and the drain electrode 8b. Consequently, a transconductance (Gm) improves, and on-resistance is suppressed to be low. Besides, a threshold voltage approximates to "0" (zero) V more closely because a gate recess structure is adopted. Namely, it becomes possible to secure the enough current while approximating the threshold voltage to "0" (zero) V owing to these interactions.
  • FIG. 2A to Fig. 2G are sectional views showing the manufacturing method of the compound semiconductor device according to the first example in process sequence.
  • the AlN layer 2 is formed on the SiC substrate 1, as shown in Fig. 2A .
  • the GaN buffer layer 3 is formed on the AlN layer 2.
  • the non-doped AlGaN layer 4a is formed on the GaN buffer layer 3.
  • the n-type AlGaN layer 4b is formed on the non-doped AlGaN layer 4a.
  • the n-type GaN layer 5 is formed on the n-type AlGaN layer 4b.
  • the non-doped AlN layer 6 is formed on the n-type GaN layer 5.
  • the SiN layer 7 is formed on the non-doped AlN layer 6.
  • the formations of the AIN layer 2, the GaN buffer layer 3, the non-doped AlGaN layer 4a, the n-type AlGaN layer 4b, the n-type GaN layer 5 and the non-doped AlN layer 6 may be performed by, for example, a crystal growth method such as an MOCVD method.
  • the formation of the SiN layer 7 may be performed by, for example, a plasma CVD method.
  • a resist pattern 21 having openings at regions where the source electrode 8a and the drain electrode 8b are to be formed is formed on the SiN layer 7, as shown in Fig. 2B .
  • wet etching of the SiN layer 7 and the non-doped AlN layer 6 is performed by using the resist pattern 21 as a mask, and thereby, the opening for the source electrode and the opening for the drain electrode are formed in the SiN layer 7 and the non-doped AlN layer 6, as shown in Fig. 2C .
  • the n-type GaN layer 5 positioning under the non-doped AlN layer 6 is not removed by the wet etching, and therefore, the etching is stopped at a surface of the n-type GaN layer 5.
  • the resist pattern 21 is removed after the openings are formed.
  • the source electrode 8a and the drain electrode 8b are evaporated in the openings in the SiN layer 7 and the non-doped AlN layer 6, as shown in Fig. 2D .
  • a resist pattern 22 having an opening at a region where the gate electrode 19 is to be formed is formed on the SiN layer 7, the source electrode 8a and the drain electrode 8b, as shown in Fig. 2E .
  • wet etching etching using acid
  • wet etching using acid of the SiN layer 7 and the non-doped AlN layer 6 is performed by using the resist pattern 22 as a mask, and thereby, the opening for the gate electrode is formed in the SiN layer 7 and the non-doped AlN layer 6, as shown in Fig. 2F .
  • the n-type GaN layer 5 positioning under the non-doped AlN layer 6 is not removed by the wet etching, and therefore, the etching is stopped at the surface of the n-type GaN layer 5.
  • the resist pattern 22 is removed after the opening is formed.
  • the gate electrode 19 (an embedded gate electrode) is evaporated in the opening in the SiN layer 7 and the non-doped AlN layer 6, as shown in Fig. 2G .
  • element isolation can be performed by, for example, ion-implantation, though it is not shown.
  • a selection ratio between the non-doped AlN layer 6 and the n-type GaN layer 5 at the wet etching is high, and therefore, it is possible to process the non-doped AlN layer 6 with high accuracy.
  • Fig. 3 is a graphic chart showing the device characteristic of the compound semiconductor device according to the first example measured by the present inventor.
  • a device characteristic of the conventional compound semiconductor device shown in Fig. 16 is also shown in Fig. 3 for the purpose of reference.
  • a horizontal axis is a voltage between gate-source (Vgs), and a vertical axis is a transconductance (Gm).
  • Vgs gate-source
  • Gm transconductance
  • the threshold voltage approximates to "0" (zero) V more closely in the first example compared to the conventional compound semiconductor device.
  • bottom surfaces of the source electrode 8a and the drain electrode 8b are in contact with the surface of the n-type GaN layer 5, but they may be in contact with a surface of the n-type AlGaN layer 4b as shown in Fig. 15 .
  • the opening for the source electrode and the opening for the drain electrode are formed in the SiN layer 7 and the non-doped AlN layer 6 by using the resist pattern 21 shown in Fig. 2B as the mask, and thereafter, a dry etching of the n-type GaN layer 5 is performed while remaining the resist pattern 21.
  • a reactive ion etching is performed, for example, with a pressure of 2 Pa, a Cl 2 flow rate of 10 sccm, and an etching speed of 10 nm/min.
  • An end point of the dry etching may be determined by, for example, a time control.
  • an error of an etching amount is preferable to be within ⁇ 3 nm.
  • the source electrode 8a and the drain electrode 8b may be composed of, for example, a Ta film with a thickness of approximately 10 nm and an Al film with a thickness of approximately 300 nm formed thereon.
  • Fig. 4 is a sectional view showing a structure of a compound semiconductor device according to the second example.
  • the opening for the gate electrode of the non-doped AlN layer 6 is approximately equal to that of the first example, the opening for the gate electrode of the SiN layer 7 is wider than that of the first example.
  • a gate electrode 29 having an overhang portion is embedded in the opening.
  • the other structure is the same as the first example.
  • an electric field concentration in a vicinity of an interface between the gate electrode 29 and the non-doped AlN layer 6 is reduced than the electric field concentration in a vicinity of an interface between the gate electrode 19 and the non-doped AlN layer 6 in the first example.
  • a voltage of 50 V to 500 V is applied between the gate and drain in the compound semiconductor device, but according to the second example, deterioration hardly occurs furthermore even in the case as stated above.
  • FIG. 5A to Fig. 5C are sectional views showing the manufacturing method of the compound semiconductor device according to the second example in process sequence.
  • a resist pattern 23 having an opening at a region where the overhang portion of the gate electrode 29 is to be formed is formed on the SiN layer 7, the source electrode 8a and the drain electrode 8b, as shown in Fig. 5A .
  • wet etching of the SiN layer 7 is performed by using the resist pattern 23 as a mask, and thereby, the opening for the overhang portion is formed in the SiN layer 7, as shown in Fig. 5B .
  • the resist pattern 23 is removed after the opening is formed.
  • the gate electrode 29 (an embedded gate electrode) is evaporated in the opening in the SiN layer 7 and the non-doped AlN layer 6, as shown in Fig. 5C .
  • element isolation can be performed by, for example, ion-implantation, though it is not shown.
  • Fig. 6 is a graphic chart showing the device characteristic of the compound semiconductor device according to the second example measured by the present inventor.
  • a device characteristic of the conventional compound semiconductor device shown in Fig. 16 is also shown for the purpose of reference.
  • a horizontal axis is a voltage between gate-drain (Vgd), and a vertical axis is a current between gate-drain (Igd).
  • Vgd gate-drain
  • Igd current between gate-drain
  • a backward gate leak current decreases in the second example compared to the conventional compound semiconductor device.
  • the threshold voltage approximates to "0" (zero) V without decreasing saturation current.
  • a third example is described.
  • an MIS (Metal-Insulator-Semiconductor) structure is adopted.
  • Fig. 7 is a sectional view showing the structure of a compound semiconductor device according to the third example.
  • an SiN layer 7a with a thickness of approximately 10 nm is formed on the non-doped AlN layer 6. At least three openings (for a source electrode, for a drain electrode and for a gate electrode) are formed in the non-doped AlN layer 6 and the SiN layer 7a. In the present example, an SiN layer 7b with a thickness of approximately 10 nm is formed in the opening for the gate electrode among the three openings, and on the SiN layer 7a. A gate electrode 39 having an overhang portion is evaporated in the opening for the gate electrode.
  • the other structure is the same as the first example.
  • a forward gate leak current can be drastically reduced. Besides, a complete normally-off operation can be performed. Besides, it becomes possible to obtain high current because the normally-off operation is realized.
  • FIG. 8A to Fig. 8E are sectional views showing the manufacturing method of the compound semiconductor device according to the third example in process sequence.
  • the processes until the formation of the non-doped AlN layer 6 are performed as same as the first example.
  • the SiN layer 7a is formed on the non-doped AlN layer 6, as shown in Fig. 8A .
  • the formation of the SiN layer 7a may be performed by, for example, a plasma CVD method.
  • a resist pattern 24 having an opening at a region where a lower portion of the gate electrode 39 is to be formed is formed on the SiN layer 7a, the source electrode 8a and the drain electrode 8b, as shown in Fig. 8B .
  • wet etching of the SiN layer 7a and the non-doped AlN layer 6 is performed by using the resist pattern 24 as a mask, and thereby, the opening for the gate electrode is formed in the SiN layer 7a and the non-doped AlN layer 6, as shown in Fig. 8C .
  • the n-type GaN layer 5 positioning under the non-doped AlN layer 6 is not removed by the wet etching, and therefore, the etching is stopped at the surface of the n-type GaN layer 5.
  • the resist pattern 24 is removed after the opening is formed.
  • the SiN layer 7b is formed in the opening for the gate electrode and on the SiN layer 7a, as shown in Fig. 8D .
  • the formation of the SiN layer 7b may be performed by, for example, a plasma CVD method.
  • the gate electrode 39 (an embedded gate electrode) is evaporated in the opening in the SiN layer 7a and the non-doped AlN layer 6, as shown in Fig. 8E .
  • element isolation can be performed by, for example, ion-implantation, though it is not shown.
  • Fig. 9 is a graphic chart showing the device characteristic of the compound semiconductor device according to the third example measured by the present inventor.
  • a device characteristic of the conventional compound semiconductor device shown in Fig. 16 is also shown for the purpose of reference.
  • a horizontal axis is a gate voltage
  • a vertical axis is a forward gate leak current.
  • the forward gate leak current is reduced in the third example compared to the conventional compound semiconductor device. Namely, in the third example, the gate leak current scarcely flows even when the gate voltage is increased up to approximately 4 V.
  • a threshold voltage Vth a threshold voltage Vth, a variation thereof ⁇ vth and a maximum current Imax
  • Table 1 device characteristics of the conventional compound semiconductor device shown in Fig. 16 are also shown for the purpose of reference.
  • the threshold voltage Vth is a negative value in the conventional compound semiconductor device
  • the threshold voltage Vth is a positive value in the third example.
  • the variation ⁇ vth of the threshold voltage in the third example is approximately 1/10 of the conventional compound semiconductor device. This is because it is possible to form the structure in the vicinity of the gate electrode 39 with high reproducibility in the third example, but the reproducibility is low in the conventional compound semiconductor device.
  • the maximum current Imax becomes extremely high compared to the conventional compound semiconductor device in accordance with the reduction of the gate leak current.
  • Table 1 Third Example Prior Art Vth +0.1 V -0.2 V ⁇ Vth 30 mV 300 mV Imax 650 mA/mm 100 mA/mm
  • FIG. 10 is a sectional view showing a structure of a compound semiconductor device according to the first embodiment of the present invention.
  • an n-type GaN layer 11 with a thickness of approximately 7 nm is formed between the non-doped AlN layer 6 and the SiN layer 7a.
  • the n-type GaN layer 11 is doped with Si at approximately 5 ⁇ 10 18 cm -3 .
  • An opening similar to those of the non-doped AlN layer 6 and the SiN layer 7a are formed in the n-type GaN layer 11.
  • the other structure is the same as the third example.
  • a doping amount of Si in the n-type GaN layer 11 may be higher than that of the n-type GaN layer 5.
  • the n-type GaN layer 11 is formed on the non-doped AlN layer 6, and therefore, a chemical change of the non-doped AlN layer 6 hardly occurs. Accordingly, deterioration of a whole device hardly occurs, and a high reliability can be obtained.
  • the n-type GaN layer 11 is formed on the non-doped AlN layer 6 between the formation of the non-doped AlN layer 6 and the formation of the SiN layer 7a.
  • dry etching of the n-type GaN layer 11 is performed. This dry etching may be performed by a time control.
  • wet etching of the non-doped AlN layer 6 is performed as same as the first to third examples. At this time, the n-type GaN layer 5 positioning under the non-doped AlN layer 6 is not removed by the wet etching, and therefore, the etching is stopped at the surface of the n-type GaN layer 5.
  • Fig. 11 is a graphic chart showing a test data of the reliability of the compound semiconductor device according to the first embodiment measured by the present inventor.
  • test data three kinds of the conventional compound semiconductor device shown in Fig. 16 are shown for the purpose of reference.
  • a horizontal axis is test time
  • a vertical axis is a gate leak current Ig.
  • the gate leak currents are high even at a test start time, and the gate leak currents increase as the time elapses depending on samples, in the conventional compound semiconductor device. This shows that the deterioration is in progress.
  • the gate leak current at the test start time is low, and further, the increase in accordance with the elapsed time is not observed at all.
  • Fig. 12 is a sectional view showing a structure of a compound semiconductor device according to the second embodiment.
  • a non-doped GaN layer 12 is formed instead of the n-type GaN layer 5 in the first embodiment.
  • the non-doped GaN layer 12 is used instead of the n-type GaN layer 5, and therefore, the gate leak current can be reduced further more.
  • the MIS structure is adopted as same as the third example, and therefore, the characteristics may not deteriorate even if the non-doped GaN layer 12 is used.
  • FIG. 13 is a sectional view showing a structure of a compound semiconductor device according to the third embodiment of the present invention.
  • an n-type InGaN layer 13 is formed instead of the n-type GaN layer 11 in the second embodiment.
  • the n-type InGaN layer 13 is used instead of the n-type GaN layer 11, and therefore, a band in this layer decreases, and the two-dimensional electron gas increases. As a result, the maximum current increases.
  • Fig. 14 is a sectional view showing a structure of a compound semiconductor device according to the fourth example of the present invention.
  • an Si layer 14 for one atomic layer is formed between the non-doped AlN layer 6 and the n-type GaN layer 11 in the first embodiment.
  • the Si layer 14 may be formed by, for example, a planer doping method (an atomic layer doping method).
  • the Si layer 14 may be formed between the n-type GaN layer 5 and the non-doped AlN layer 6.
  • the formation of the AlN layer may be performed by an ALD (Atomic Layer Deposition) method, a sputtering method, or the like.
  • ALD Atomic Layer Deposition
  • the AlN layer is formed between the gate electrode, the source electrode and the drain electrode as a compound semiconductor layer containing N, but another compound semiconductor layer, for example, a layer such as InAlN further containing In may be formed.
  • the element isolation may be performed by, for example, the ion-implantation, a mesa etching, or the like.
  • a compound semiconductor layer containing N is formed on a protective layer, and a process of the compound semiconductor layer can be performed under a condition free from an influence on the protective layer. Accordingly, it is possible to construct a gate recess structure with high reproducibility. It is therefore possible to suppress current flowing when a gate voltage is made to be "0" (zero). Besides, it is possible to suppress a gate leak current to realize a high withstand voltage when an insulator layer is in contact with a side surface of a gate electrode.

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Ceramic Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Manufacturing & Machinery (AREA)
  • Junction Field-Effect Transistors (AREA)

Claims (5)

  1. Dispositif de semi-conducteur combiné, comprenant :
    une couche de transit de support à base de GaN (3) formée sur un substrat de semiconducteur (1) ;
    une couche d'alimentation en support à base de GaN (4b) formée sur ladite couche de transit de support (3) ;
    une couche protectrice à base de GaN (5) formée sur ladite couche d'alimentation en support (4b) ;
    une électrode source (8a), une électrode drain (8b) et une électrode grille (19) formées sur ladite couche protectrice (5) ;
    une couche d'AIN non dopé (6) formée sur ladite couche protectrice (5), et disposée entre ladite électrode grille (19) et ladite électrode source (8a), et entre ladite électrode grille (19) et ladite électrode drain (8b) ; et
    une couche d'isolant (7a) formée sur ladite couche d'AIN (6) ;
    dans lequel une couche de semi-conducteur combiné à base de GaN (11 ; 13) est formée entre ladite couche d'AlN (6) et ladite couche d'isolant (7a).
  2. Dispositif de semi-conducteur combiné selon la revendication 1, dans lequel ladite couche de semi-conducteur combiné (13) contient de l'indium.
  3. Dispositif de semi-conducteur combiné selon la revendication 1, dans lequel ladite couche de semi-conducteur combiné (11) est dopée avec du silicium.
  4. Procédé de fabrication d'un dispositif de semi-conducteur combiné, comprenant :
    la formation d'une couche de transit de support à base de GaN (3) sur un substrat de semiconducteur (1) ;
    la formation d'une couche d'alimentation en support à base de GaN (4b) sur la couche de transit de support (3) ;
    la formation d'une couche protectrice à base de GaN (5) sur la couche d'alimentation en support (4b) ;
    la formation d'une couche d'AlN non dopé (6) sur ladite couche protectrice (5) ;
    la formation d'une couche d'isolant (7a) sur la couche d'AlN (6) ;
    la formation d'une ouverture pour une électrode source (8a), d'une ouverture pour une électrode drain (8b) et d'une ouverture pour une électrode grille (19) dans la couche d'isolant (7a) et la couche d'AlN (6) ;
    la formation d'électrodes (8a, 8b, 19) dans les trois ouvertures,
    dans lequel ladite formation de l'ouverture pour l'électrode grille (19) présente une réalisation de gravure par voie humide de la couche d'AlN (6) jusqu'à ce que la couche protectrice (5) est exposée ; et
    la formation d'une couche de semi-conducteur combiné à base de GaN (11 ; 13) sur la couche d'AIN (6), entre ladite formation de la couche d'AlN (6) et ladite formation de la couche d'isolant (7a).
  5. Procédé de fabrication d'un dispositif de semi-conducteur combiné selon la revendication 4, dans lequel une couche (13) contenant de l'indium est formée comme la couche de semi-conducteur combiné.
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EP1998376A1 (fr) 2008-12-03
EP2657976A2 (fr) 2013-10-30
US20110272704A1 (en) 2011-11-10
US20110275199A1 (en) 2011-11-10
EP2166575A1 (fr) 2010-03-24
US8841706B2 (en) 2014-09-23
JP5071377B2 (ja) 2012-11-14
EP2677544A1 (fr) 2013-12-25
WO2007108055A1 (fr) 2007-09-27
EP2166575B1 (fr) 2011-08-17
EP2175494A2 (fr) 2010-04-14
EP1998376A4 (fr) 2009-07-22
US20130248934A1 (en) 2013-09-26
EP2657976B1 (fr) 2018-12-26
EP2677544B1 (fr) 2015-04-22
US8344419B2 (en) 2013-01-01
JPWO2007108055A1 (ja) 2009-07-30
US20090008677A1 (en) 2009-01-08
EP1998376B1 (fr) 2011-08-03
US8637903B2 (en) 2014-01-28
US8466029B2 (en) 2013-06-18
EP2175494A3 (fr) 2012-10-17

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