EP2167295A2 - Procédé et appareil pour fabriquer des dalles avec un effet marbré - Google Patents

Procédé et appareil pour fabriquer des dalles avec un effet marbré

Info

Publication number
EP2167295A2
EP2167295A2 EP08761425A EP08761425A EP2167295A2 EP 2167295 A2 EP2167295 A2 EP 2167295A2 EP 08761425 A EP08761425 A EP 08761425A EP 08761425 A EP08761425 A EP 08761425A EP 2167295 A2 EP2167295 A2 EP 2167295A2
Authority
EP
European Patent Office
Prior art keywords
mixture
agent
colouring
hopper
extractor belt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP08761425A
Other languages
German (de)
English (en)
Other versions
EP2167295B1 (fr
Inventor
Luca Toncelli
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of EP2167295A2 publication Critical patent/EP2167295A2/fr
Application granted granted Critical
Publication of EP2167295B1 publication Critical patent/EP2167295B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00—Producing shaped prefabricated articles from the material
    • B28B1/005—Devices or processes for obtaining articles having a marble appearance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00—Producing shaped prefabricated articles from the material
    • B28B1/08—Producing shaped prefabricated articles from the material by vibrating or jolting
    • B28B1/082—Producing shaped prefabricated articles from the material by vibrating or jolting combined with a vacuum, e.g. for moisture extraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B13/00—Feeding the unshaped material to moulds or apparatus for producing shaped articles; Discharging shaped articles from such moulds or apparatus
    • B28B13/02—Feeding the unshaped material to moulds or apparatus for producing shaped articles
    • B28B13/0215—Feeding the moulding material in measured quantities from a container or silo
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
    • B29C67/24—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 characterised by the choice of material
    • B29C67/242—Moulding mineral aggregates bonded with resin, e.g. resin concrete
    • B29C67/243—Moulding mineral aggregates bonded with resin, e.g. resin concrete for making articles of definite length
    • B29C67/244—Moulding mineral aggregates bonded with resin, e.g. resin concrete for making articles of definite length by vibrating the composition before or during moulding

Definitions

  • the present invention relates to the manufacture of conglomerate stone slabs obtained from mixtures consisting of granules of stone and/or stone-like material and a bonding agent, and more specifically to the manufacture of slabs of this type which have particular colouring effects, such as so-called veining, intended to imitate as closely as possible natural stone materials.
  • the invention relates to a method and an apparatus for producing the slabs in question.
  • reference will be made to the production of slabs with a veined effect, it being understood that reference thereto is made solely by way of a non-limiting example.
  • Bretonstone slabs For many years so-called Bretonstone slabs have been known, this name referring to a particular manufacturing technology which essentially envisages the preparation of one or more starting mixtures comprising granules of stone and/or stone-like material with a specific particle size distribution and a bonding agent which made be of an inorganic nature (such as cement) or a synthetic resin which can be hardened (by the action of heat and/or a catalyst).
  • a bonding agent which made be of an inorganic nature (such as cement) or a synthetic resin which can be hardened (by the action of heat and/or a catalyst).
  • the starting mixture is distributed in the form of a layer of predetermined thickness on a temporary moulding support (such as a conveyor belt or a tray mould) and then subjected, for a predefined period of time and under a vacuum of given intensity, to the action of a press while a vibratory movement of prechosen frequency is applied to the press ram.
  • a temporary moulding support such as a conveyor belt or a tray mould
  • the resultant rough-formed slab is then transferred to the hardening stage using procedures which depend on the nature of the bonding agent.
  • Bretonstone slabs and/or the Bretonstone method is understood as meaning slabs obtained with the method described above.
  • colouring agent is distributed in an irregular manner on the surface of the layer of mixture and then the colouring agent is mixed up with the mixture using a spiked tool so that the colouring agent penetrates into the thickness of the mixture to a depth such that the finished slab, after the usual sizing and polishing operations, has veining similar to that of the natural stone from which the granules used in the mixture are obtained.
  • This method is useful solely in the case where the finished slab must not be used such that its side edges are visible.
  • the colouring agent penetrates into the thickness of the mixture - and can therefore be seen in the finished slab - only over a section of a few millimetres, corresponding to not more than half the thickness of the finished slab.
  • the mixture is distributed on the moulding support by means of a weighing type distributor unit with the characteristic features described in the patent IT-A- 1 ,335, 533 (corresponding to WO-A-2004/039547), herein incorporated by reference.
  • the starting mixture before being loaded into the metering unit, is made to pass underneath devices which apply liquid or powder colouring or pigments agents onto its surface. Since the mixture is loaded into the metering unit, falling freely, and then conveyed to the outlet for discharging onto the moulding support, it undergoes a certain degree of remixing which in turn results, on the one hand, in a substantial shortening of the veining and, on the other hand, in a not insignificant diffusion of the pigment in the mass of the mixture which is therefore at least partly coloured throughout the mass.
  • Another technology known for many years and aimed at the manufacture of slabs designed for internal and external cladding of buildings as well as the manufacture of articles similar to ceramic articles is one where granules of stone, stone-like or ceramic material, preferably in the form of sand, with a suitable particle size distribution, are mixed with the components normally used for the manufacture of ceramic materials, usually in powder form, and consisting mainly of clay or kaolin.
  • the resultant mixture is wetted with a bonding agent, which may be sodium silicate in aqueous form or a mixture of silicasol and polyvinyl alcohol.
  • a bonding agent which may be sodium silicate in aqueous form or a mixture of silicasol and polyvinyl alcohol.
  • the slab after a drying step, in order to remove the water present in the mixture, undergoes a baking step at a high temperature (in the region of 1200 0 C).
  • a baking step at a high temperature (in the region of 1200 0 C).
  • At least one starting mixture comprising at least one granular product comprising stone or stone-like or ceramic material with a specific particle size distribution and a hardening bonding agent is prepared;
  • a metering/distributor unit comprising:
  • a hopper with a top mouth for loading the mixture and a bottom opening for discharging the said mixture; - an extractor belt which forms the bottom wall of said hopper;
  • the mixture discharged from the bottom opening of said hopper is transferred by means of said extractor belt so that, falling freely from said belt, it is distributed in the form of a layer of predetermined thickness on a temporary moulding support positioned at a lower level than said extractor belt; - the layer of mixed formed on said temporary support is subjected to vibrocompression so as to obtain a rough-formed slab;
  • said rough-formed slab is transferred into a hardening station, the method being characterized in that at least one colouring or pigmenting agent is distributed on the surface of the mixture being transferred by means of said extractor belt before the mixture is distributed, falling freely, onto said temporary moulding support.
  • the metering/distributor unit used in said method is that described and illustrated in Italian patent application No. TV 2004A000118 (corresponding to WO-A- 2006/045728), herein incorporated by reference.
  • the method according to the present invention envisages that: the bonding agent contained in the at least one starting mixture may be of an inorganic nature (such as cement) or a synthetic resin which can be hardened (by the action of heat and/or a catalyst); the layer formed on said temporary moulding support is subjected, for a predefined period of time and under a vacuum of given intensity, to the action of a press, while a vibratory movement of prechosen frequency is applied to the press ram; the resultant rough-formed slab is subjected to the hardening step using procedures which depend on the nature of the bonding agent.
  • the bonding agent contained in the at least one starting mixture may be of an inorganic nature (such as cement) or a synthetic resin which can be hardened (by the action of heat and/or a catalyst)
  • the layer formed on said temporary moulding support is subjected, for a predefined period of time and under a vacuum of given intensity, to the action of a press, while a vibratory movement of prechosen frequency is applied to
  • said starting mixture comprises, in addition to the granules of stone, stone-like or ceramic material with a prechosen particle size, in particular in the form of sand, also materials known per se for the manufacture of ceramic materials, such as clay and kaolin in powder form and an agent chosen from sodium silicate and silicasol together with polyvinyl alcohol, the rough-formed slab resulting from the vibrocompression step is subjected to a drying step and then a high-temperature baking step such that the clay or kaolin forms a bonding matrix for the abovementioned granules.
  • said at least one colouring agent is distributed on the surface of the mixture in a non-uniform manner.
  • the apparatus according to the invention is that described in the already cited Italian patent application No. TV2004A000118, except that it comprises as a characterizing aspect at least one device for dispensing colouring or pigmenting agent positioned at the downstream end of the extractor belt forming the bottom of the already mentioned hopper so as to dispense said colouring agent onto the surface of the layer of mixture transported by means of said extractor belt towards the position where it falls freely onto the said temporary moulding support.
  • the colouring agent is distributed randomly and not uniformly within the mass mixture, which falls into the temporary support producing the aforementioned veining which affects the entire thickness of the finished slab.
  • the colouring or pigmenting agent may be in solid form (preferably a dry powder) or liquid form and may be supplemented with or replaced by colouring or reflective granules which result in very attractive special effects in the finished product and throughout its thickness.
  • the colouring agent dispensing device associated with the abovementioned apparatus it may comprise a plurality of devices, namely one for each colouring agent, which are controlled independently of each other as regards the start and end of the dispensing operation, which may take place continuously or intermittently.
  • dispensing devices In the case where there is a plurality of dispensing devices, they may be mounted transversely with respect to the direction of feeding of the extractor belt which transports the layer of mixture discharged by the metering/distributor unit, so as to cover the entire width of the mixture layer.
  • Fig. 1 is a front view of the apparatus provided with a plurality of units for dispensing colouring or pigmenting agents according to the invention
  • Fig. 2 is a partially sectioned side view of the apparatus according to Fig. 1 ;
  • Fig. 3 is a side view of solely the mixture metering/distributor unit equipped with a device for dispensing colouring agent in powder form according to a first embodiment of the invention which is also visible in Fig. 2;
  • Fig. 4 is a view similar to that of Fig. 3 of a device for dispensing liquid colouring agent according to a second embodiment of the invention which is also visible in Fig. 1 ;
  • Figures 5 and 6 are axonometric views of products which can be obtained with the present invention.
  • Figures 1 and 2 show an apparatus according to the present invention for distributing, in the form of a thin layer, on a support used in a plant for producing stone articles, a mixture based on agglomerate stone or ceramic material, to which colouring substances are added depending on the predetermined aesthetic effects.
  • the apparatus comprises a frame 10 which supports a surface 12 on which a temporary moulding support 14 is placed for each operating cycle, on which support a layer of mixture 18, supplied by a metering/distributor device denoted overall by the referenced above 20, is deposited in a free-falling manner.
  • the mixture distributor 20 in turn comprises a hopper 22 with a top mouth 24 for loading fresh mixture, a shaped or conveying wall 26 with a profile curved towards the inside of the hopper 22 and a mixture discharge opening 28 at the end of said shaped wall 26.
  • the belt 30 is used to convey and deposit a uniform layer of said mixture, after it has flowed inside the hopper 22 and passed out through said discharge opening 28, on said temporary support 14 which is positioned at a lower level than said extractor belt. At the same time a relative movement of said hopper 22 and said support 14 is maintained so that the layer of mixture distributed on said support is uniform.
  • the metering/distributor device 20 is mounted on a carriage denoted overall by the reference number 34 and movable by means of roller wheels parallel to the surface 12 of the apparatus. From Figure 1 it can be readily understood how the distribution and metering hopper 22, the extractor belt 30 as well as the mixture discharge opening 28 extend substantially over the entire width of the surface 12 so that the resultant product is a slab which has notable dimensions not only lengthwise but also transversely. In this connection it is worth noting that the slabs which can be obtained with this technology may have and in reality also have widths greater than 1.5 metres and lengths greater than 3.3 metres.
  • At least one device for dispensing colouring agent is positioned at the downstream end of the extractor belt 30, preferably downstream of the discharge opening 28 of the hopper 22.
  • the colouring agent may be dispensed at any point on the upper surface 32 of the extractor belt 30, except for the zone immediately underneath the hopper 22.
  • the carriage 34 has, mounted thereon, a support structure comprising a cross-member 36 with, fixed thereto, a plurality of devices for dispensing colouring agent - denoted by the reference numbers 40 (a-m), respectively - each of which has a nozzle intended to emit a continuous or discontinuous jet of colouring agent (which, as ready mentioned, may be liquid or in the form of dry powder) which strikes a strip of the layer of mixture deposited on the tray mould, so as to cover overall the entire width of the mixture.
  • a-m a plurality of devices for dispensing colouring agent - denoted by the reference numbers 40 (a-m), respectively - each of which has a nozzle intended to emit a continuous or discontinuous jet of colouring agent (which, as ready mentioned, may be liquid or in the form of dry powder) which strikes a strip of the layer of mixture deposited on the tray mould, so as to cover overall the entire width of the mixture.
  • the surface of the mixture, before leaving the extractor belt 30, is therefore sprinkled with colouring material in a manner which depends on the operating mode of the dispensing nozzle. In fact, if the dispensing nozzle is operated intermittently and at irregular time intervals, it is evident that the distribution of colouring agent on the surface of the mixture will not be homogeneous and pre-ordered.
  • the colouring agent Since the mixture with colouring agent is then transferred by means of a free-falling action onto the temporary moulding support and since the mixture when falling produces coloured lumps on the surface, the colouring agent, without uniformly colouring the mixture, is able to produce during the subsequent vibrocompression step colouring effects which affect the entire thickness of the manufactured article, similar to the veining of natural stones.
  • the mixture were to be uniformly coloured, the desired object would not be achieved, namely the formation of veining imitating that of standard natural stone.
  • the coloured zones affect the entire thickness of the mixture, so that the predefined object of the invention is fully achieved.
  • the variant shown in Figure 4 proposes the alternative solution of mounting on the cross- member 36 an assembly with just a few colouring agent dispensing devices 38, said assembly 38 having, connected thereto, a drive system for controlled displacement thereof along the cross- member 36. It is evident that a solution midway between those described above is possible, namely one where a smaller number of dispensing devices 40 are mounted on the cross-member 36, with the each of them designed so that it is movable along the cross-member over a limited distance, so as to ensure more correct distribution of colouring agent on the surface of the mixture which is transported by the upper surface 32 of the extractor belt 30 towards the temporary support 14.
  • the product obtained fully satisfies the aforementioned requirements and has the appearance shown in Figures 5 and 6 (where it is possible to see a slab with a toroidal edge and a slab with a semi-toroidal edge, respectively, the veining being visible throughout the thickness of the slab and therefore also along its edges).

Landscapes

  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Structural Engineering (AREA)
  • Devices For Post-Treatments, Processing, Supply, Discharge, And Other Processes (AREA)
  • Press-Shaping Or Shaping Using Conveyers (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Cosmetics (AREA)

Abstract

Pendant la fabrication de dalles avec un effet marbré, un agent de coloration liquide ou en poudre est déposé sur la surface d'une mince couche de mélange de départ au moyen d'au moins un dispositif de distribution, et le mélange résultant est alimenté, en tombant librement, à partir d'une extrémité d'une courroie d'extracteur formant la partie inférieure d'une unité de mesure/distribution de mélange, après quoi le mélange est transféré, en tombant librement, sur un support de moulage temporaire. Ceci conduit à la production de dalles comportant un marbrage s'étendant à travers toute l'épaisseur des dalles et également visible le long de toute la bordure de la dalle, même après qu'elle ait été usinée.
EP08761425.1A 2007-07-16 2008-07-04 Procédé et appareil pour fabriquer des dalles avec un effet marbré Active EP2167295B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT000126A ITTV20070126A1 (it) 2007-07-16 2007-07-16 Procedimento ed apparecchiatura per la fabbricazione di lastre ad effet-to venato
PCT/EP2008/058682 WO2009010406A2 (fr) 2007-07-16 2008-07-04 Procédé et appareil pour fabriquer des dalles avec un effet marbré

Publications (2)

Publication Number Publication Date
EP2167295A2 true EP2167295A2 (fr) 2010-03-31
EP2167295B1 EP2167295B1 (fr) 2014-04-09

Family

ID=40239682

Family Applications (1)

Application Number Title Priority Date Filing Date
EP08761425.1A Active EP2167295B1 (fr) 2007-07-16 2008-07-04 Procédé et appareil pour fabriquer des dalles avec un effet marbré

Country Status (10)

Country Link
US (2) US9174358B2 (fr)
EP (1) EP2167295B1 (fr)
KR (1) KR101484350B1 (fr)
CN (1) CN101743105A (fr)
CA (1) CA2693143C (fr)
ES (1) ES2464215T3 (fr)
IL (1) IL203241A (fr)
IT (1) ITTV20070126A1 (fr)
PT (1) PT2167295E (fr)
WO (1) WO2009010406A2 (fr)

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CA2693143A1 (fr) 2009-01-22
US20100194005A1 (en) 2010-08-05
WO2009010406A2 (fr) 2009-01-22
KR20100058481A (ko) 2010-06-03
IL203241A (en) 2016-03-31
US20160016328A1 (en) 2016-01-21
CN101743105A (zh) 2010-06-16
EP2167295B1 (fr) 2014-04-09
WO2009010406A3 (fr) 2009-04-09
US9174358B2 (en) 2015-11-03
PT2167295E (pt) 2014-05-22
ES2464215T3 (es) 2014-05-30
ITTV20070126A1 (it) 2009-01-17
CA2693143C (fr) 2017-08-01
KR101484350B1 (ko) 2015-01-19
US11045973B2 (en) 2021-06-29

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