Classifications

• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M10/00—Secondary cells; Manufacture thereof
  • H01M10/60—Heating or cooling; Temperature control
  • H01M10/65—Means for temperature control structurally associated with the cells
  • H01M10/655—Solid structures for heat exchange or heat conduction
  • H01M10/6556—Solid parts with flow channel passages or pipes for heat exchange
  • H01M10/6557—Solid parts with flow channel passages or pipes for heat exchange arranged between the cells
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M10/00—Secondary cells; Manufacture thereof
  • H01M10/60—Heating or cooling; Temperature control
  • H01M10/65—Means for temperature control structurally associated with the cells
  • H01M10/655—Solid structures for heat exchange or heat conduction
  • H01M10/6556—Solid parts with flow channel passages or pipes for heat exchange
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M10/00—Secondary cells; Manufacture thereof
  • H01M10/60—Heating or cooling; Temperature control
  • H01M10/61—Types of temperature control
  • H01M10/613—Cooling or keeping cold
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M10/00—Secondary cells; Manufacture thereof
  • H01M10/60—Heating or cooling; Temperature control
  • H01M10/64—Heating or cooling; Temperature control characterised by the shape of the cells
  • H01M10/643—Cylindrical cells
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M10/00—Secondary cells; Manufacture thereof
  • H01M10/60—Heating or cooling; Temperature control
  • H01M10/65—Means for temperature control structurally associated with the cells
  • H01M10/656—Means for temperature control structurally associated with the cells characterised by the type of heat-exchange fluid
  • H01M10/6567—Liquids
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
  • H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
  • H01M50/204—Racks, modules or packs for multiple batteries or multiple cells
  • H01M50/207—Racks, modules or packs for multiple batteries or multiple cells characterised by their shape
  • H01M50/213—Racks, modules or packs for multiple batteries or multiple cells characterised by their shape adapted for cells having curved cross-section, e.g. round or elliptic
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
  • H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
  • H01M50/218—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by the material
  • H01M50/22—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by the material of the casings or racks
  • H01M50/227—Organic material
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
  • H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
  • H01M50/233—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by physical properties of casings or racks, e.g. dimensions
  • H01M50/24—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by physical properties of casings or racks, e.g. dimensions adapted for protecting batteries from their environment, e.g. from corrosion
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
  • H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
  • H01M50/289—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by spacing elements or positioning means within frames, racks or packs
  • H01M50/291—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by spacing elements or positioning means within frames, racks or packs characterised by their shape
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
  • H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
  • H01M50/289—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by spacing elements or positioning means within frames, racks or packs
  • H01M50/293—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by spacing elements or positioning means within frames, racks or packs characterised by the material
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M10/00—Secondary cells; Manufacture thereof
  • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M10/00—Secondary cells; Manufacture thereof
  • H01M10/60—Heating or cooling; Temperature control
  • H01M10/62—Heating or cooling; Temperature control specially adapted for specific applications
  • H01M10/625—Vehicles
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
  • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
  • Y02E60/10—Energy storage using batteries

Definitions

• Electric battery comprising thermal conditioning modules encased by a structural matrix
• the invention relates to an electric battery which is particularly intended for the traction of an electric motor vehicle, or hybrid, that is to say comprising an electric motor driving the driving wheels combined with a thermal engine driving the same or possibly other driving wheels.
• the energy that a battery is able to supply depends on the energy balance of the various elements as well as their operating temperature. Indeed, the energy that is able to deliver an element increases with temperature and when there are differences in available energy levels in each of the elements, for the same battery, then the battery is said unbalanced. This imbalance greatly affects the performance of the battery both in service life and average energy density because the total energy that can deliver a battery is always limited by the energy of the least charged element, and the Total charged energy is otherwise limited by the most charged element.
• differences in the level of energy between the elements, causing the imbalance may be due either to differences in the electrical properties of the elements or to variations in temperature of the elements. between these elements.
• a risk of inversion can then appear for the low states of charge.
• the chemical compositions of lithium-ion batteries are more or less stable. When subjected to extreme conditions, thermal runaway may occur. For large batteries that are required for vehicles with electrical dominance, this risk is critical, because if the thermal runaway of an element spreads to the entire battery, the energy involved in this runaway becomes very high. .
• thermal conditioning systems of the elements have therefore been integrated into the batteries.
• cooling systems have been proposed using air circulation as a cold source. Although many efforts have been made to try to guarantee by this means a temperature distribution as homogeneous as possible within the battery, the fact remains that such systems do not ensure a homogeneous cooling of the elements of the battery.
• battery solicited power as is particularly the case in applications for electric vehicles and hybrids connectable on the power grid (plug-in English).
• the thermal dissipation peaks are very large and are a function of the current densities and their variations which, for particular applications, can reach very high values, especially during the phases of strong accelerations, regenerative braking, fast recharge of the battery or highway operation in electric mode.
• the airflows required to cool the battery cells can only be achieved at the expense of significant element spacing.
• the liquid may be provided to circulate through plastic cells which are disposed between the battery cells. These cells are insulating and participate in electrical insulation between elements.
• the plastic bags in which these cells are formed are poor thermal conductors, so they must have a thickness as low as possible in order to ensure approximately correct heat transfer. This results in a maladaptation of the thin walls to the mechanical strength of the elements in the battery.
• the batteries according to the prior art pose a certain number of problems, notably because of the increase in the degree of hybridization of the thermal vehicles which can go as far as a complete electrification of the drive chain.
• the batteries then serve not only to assist the vehicles in acceleration phases but also to ensure the movement of the vehicle autonomously over more or less important distances. It is then necessary to increase the energy as well as the electric power of the batteries, which increases the durations of solicitation of the battery, as well as the currents and the average internal resistance. Thus, the energy and thermal power emitted increase, especially as the battery ages.
• the cost of a battery depends mainly on the number of elements it contains, in other words, its energy. Also, to reduce the impact of the cost of batteries in a vehicle, it seeks to use said batteries over a range of potential as wide as possible in order to extract the maximum energy.
• the high powers required give rise to large and rapid heating of the battery elements that can induce temperature gradients between the surface and the interior thereof, or even between the elements of the same battery.
• the increase of the temperature within a battery element induces risks in terms of safety and durability, related to the possible presence of hot spots in the heart of the element.
• the present invention therefore aims to improve the existing electric batteries by proposing a mechanical and thermal conditioning system that significantly improves the ratio between volume and energy and / or power, as well as the life and safety the battery both from a point of view of chemical behavior and vis-à-vis the constraints in force in the automotive industry, including those concerning the crash.
• the invention achieves levels of compactness of the system by meeting the requirements of volume density of power and power compatible with the needs of the automotive application, at lower cost and weight.
• the very low heat transfer resistances possible thanks to the invention make it possible to guarantee the cooling of the battery despite the very high level of compactness.
• the invention also makes it possible to reduce the temperature within the elements during current draw peaks, and avoids any risk of direct electrical contact of the elements in the event of an impact, which presents an advantage in terms of securing the drums.
• the efficiency of the thermal management reduces the power consumption and thus guarantees more autonomy for the electric vehicle.
• the invention proposes an electric battery comprising a plurality of elements generating electrical energy and a conditioning system.
• said system comprising a bed of thermal conditioning fluid on which said elements are arranged so as to leave a lateral space between the adjacent elements, said conditioning system further comprising a plurality of thermal conditioning modules which are each provided with a fluid flow path between an upstream port and a downstream port, each running path extending in a lateral space with the ports in fluid communication with said bed, said conditioning system further comprising a structural matrix in thermally conductive and electrically insulating polymer resin, said matrix filling the lateral spaces by at least partially coating said generator elements and said conditioning modules.
• FIG. 1 is a perspective view of a portion of an electric battery according to a first embodiment
• FIG. 2 is a perspective view of a thermal conditioning module of the electric battery according to FIG. 1; - Figures 3 are partial views of the electric battery according to Figure 1, showing the connection of the modules in the water bed respectively in perspective ( Figure 3a) and in longitudinal section (Figure 3b);
• FIGS. 4 are views of a portion of an electric battery according to a second embodiment, respectively in perspective (FIG.
• the terms of positioning in space are taken with reference to the position of the battery shown in FIG. 1.
• the tightness of the battery makes it possible to envisage its positioning in a different orientation.
• the elements 1 may be of electrochemical nature, for example of the Lithium type, are described below. ion.
• the elements 1 comprise an envelope in which the electrochemical system is confined to isolate the chemical components necessary for the generation of electricity.
• the elements may be supercapacities.
• the battery is more particularly intended to supply an electric traction motor of a motor vehicle, whether it is an electric vehicle or a hybrid electric-thermal type.
• the battery according to the invention can also find its application for the storage of electrical energy in other modes of transport, including aeronautics.
• the battery according to the invention can also be used advantageously.
• the battery comprises a mechanical and thermal conditioning system elements 1, said system for the one hand to condition the temperature elements 1 and secondly to maintain them in a reinforcing structure.
• the system ensures the electrical safety of the battery vis-à-vis the risks related to the temperature, the operation of the battery in an optimal temperature range as well as the security with respect to the risks of crash which are inherent to the application considered.
• the battery comprises a large number of elements, for example 160 elements divided into 16 rows of 10 elements.
• the battery may comprise a tray (not shown), in particular plastic, in which the elements 1 electricity generators and the packaging system are arranged for the implantation of said battery in the motor vehicle.
• the conditioning system comprises a bed 2 of thermal conditioning fluid and a circulation device (not shown) of said fluid of so as to ensure the thermal conditioning of the elements 1.
• the circulation device comprises a pump that allows to put the fluid under pressure in a closed circuit, and possibly a heat exchanger.
• the fluid may be brine
• the thermal conditioning includes both intake and calorie withdrawal so as to maintain the elements 1 in an optimal temperature operating range.
• the packaging system makes it possible quickly and efficiently to provide or remove calories in the battery, so as to ensure thermal regulation regardless of the conditions of use.
• the fluid bed 2 comprises two separate plies 3, 4 of fluid which are respectively formed in a box 5, 6, for example made of molded plastic material.
• the boxes 5, 6 are associated one on the other so as to form a lower sheet 3 and an upper sheet 4 in which the fluid flows separately.
• the upper wall of the upper box 6 comprises locations 7 for receiving the base of a generator element 1, said locations being provided for arranging the elements 1 on the fluid bed 2 leaving a lateral space between the adjacent elements 1.
• the boxes 5, 6 may be formed of sub-boxes that are associated with each other to form the number of locations 7 desired.
• the sub-boxes can be positioned in the tray to be associated with each other by the structural matrix described below.
• the submodules can be in fluid communication or be independently supplied with fluid via orifices 5a, 6a.
• the boxes 5, 6 are formed so as to leave an opening opening 8 facing the locations 7, said orifices allowing the sealed combination of the boxes 5, 6 between them, by means of rivets (FIG. 4) or by welding (FIGS. 1 to 3).
• the orifices opening 8 make it possible to let off the gases that can be emitted by the elements 1 in the event of uncapping thereof related to an overpressure of the elements 1.
• a sealed tank is provided around battery, it is equipped with a valve for emission of gases to the outside.
• a gas emission or humidity detector can be added to the battery.
• the conditioning system further comprises a plurality of thermal conditioning modules 9 which are each provided with a fluid circulation path between an upstream port 10 and a downstream port 11.
• Each circulation path extends in a lateral space with the ports 10, 11 in fluid communication with the bed 2.
• the circulation path has a height substantially equal to that of the elements 1, so as to ensure the transfer of heat over the entire periphery of said element.
• the number of modules 9 can be adapted according to the number of elements 1 used in the battery.
• the bed 2 and the modules 9 may be manufactured separately with respectively the connection sockets and the ports 10, 11, said ports being connected to said sockets when mounting said battery, depending on the presence or absence of an element nearby. It is thus possible to modulate in a particularly simple manner the power of the battery by adjusting the number of elements 1, and without requiring any modification in the architecture of the battery.
• the number of locations 7 may be greater than the number of elements 1.
• the elements 1 have a cylindrical geometry and a compact hexagonal arrangement between them, which makes it possible to optimize the space requirement as well as the mechanical strength of the battery.
• the lateral spaces formed between these elements 1 therefore also have a cylindrical geometry and a hexagonal arrangement between them.
• the elements can be of different geometry, for example parallelepiped external geometry, and / or have another type of arrangement between them.
• the packaging system further comprises a structural matrix (not shown) made of an electrically insulating thermal conductive polymer resin, said matrix filling the lateral spaces by at least partially coating the generator elements 1 and the conditioning modules 9.
• the matrix coats at least the circulation path.
• the matrix ensures the mechanical strength of the elements 1 between them, particularly with respect to crash test constraints in force in the automotive industry but also relative to other forms of mechanical stress that the battery has to undergo in a car .
• the matrix provides a heat transfer function between the elements 1 and the fluid flowing in the modules 9, as well as an electrical safety function with respect to its electrical insulative character between the elements 1.
• the important characteristic is the conductance, which is the ratio between the thermal conductivity of the matrix on its thickness.
• the matrix has a thermal conductivity of the order of 1 W / m / ° C and a thickness of about 2 mm.
• the coating electrically isolates the elements 1 and improves the heat exchange between said elements and the modules 9, in particular to prevent overheating of said elements.
• the invention makes it possible in particular not to provide a thermally insulating interface between the conditioning fluid and the elements 1, and this in an electrically secure environment, compact and mechanically resistant.
• glues can be used which have the advantage of increasing the rigidity of the battery and of retaining the elements 1 in said battery.
• the adhesives may be, for example, from the family of epoxies, silicones or acrylics, in which inorganic components having thermal conduction properties, such as Al 2 O 3 , AlN, MgO, ZnO, BeO, BN, may be added. If 3 N 4 , SiC and / or SiO 2 .
• a bicomponent epoxy resin of the type of that referenced 2605 by the company 3M can be used.
• the fluid resin is disposed in the lateral spaces so as to coat said modules and said elements, said resin then being solidified to form the structural matrix. Therefore, the realization of the battery is particularly simple and flexible, in particular not providing specific tools depending on the number of elements 1 to be disposed in said battery.
• a primer coating containing a migrating agent
• This migrating agent must be able to migrate to one of the bonding interfaces to generate a weak cohesion layer. . This migration is made possible by thermal activation, which makes it possible to dismantle the bonded assemblies.
• This migrating agent can be implemented in a primer, but also in the resin itself.
• the migrating agent may be for example a polyolefin, or more particularly PTSH (paratoluenesulfohydrazide) which is known to provide the takeoff by heat input as described in particular in document WO-2004/087829.
• the matrix may have phase change properties in a temperature range to improve the temperature conditioning of the generator elements 1.
• the circulation paths are fed in parallel by the fluid bed 2. So, the fluid flowing through each circulation path is directly from the fluid bed 2, without having previously conditioned another element 1. This therefore results in excellent thermal homogeneity by avoiding the accumulation of heat linked to a succession of heat exchanges.
• the upstream ports 10 are in communication with a sheet 3 and the downstream ports 11 are in communication with the other sheet 4.
• a sheet 3 serves to supply each module 9 with fluid
• the other sheet 4 serves to evacuate said fluid.
• one of the end portions of the traffic paths passes through the upper sheet 4 to connect the port 10 corresponding to the bottom sheet 3.
• the excellent temperature homogeneity in the battery makes it possible both to increase the balancing level between the elements 1 and to be able to thermally regulate the battery with a high degree of accuracy in order to minimize the internal resistances of the cells. elements 1 without affecting their life.
• the optimization of the thermal management then makes it possible to increase the energy and the power of the battery, without having to add additional elements.
• the conditioning system allows the dissipation of thermal energy from the thermal runaway of an element 1, without this excess heat being transferred to the adjacent elements 1 in a proportion that may lead to contagion of the phenomenon. thermal runaway.
• This role of thermal confinement makes it possible to prevent the risks of thermal runaway from spreading to the entire battery, which is very critical for high energy batteries.
• each module 9 of packaging comprises an ascending pipe 12 and a body 13 surrounding said pipe is described below.
• a module can be made by interlocking extrusions of different shapes and lengths, preferably formed of a good conductor material.
• thermal for example metal such as aluminum which has the further advantage of a low weight.
• the lower end of the pipe 12 protrudes axially from the body 13, so as to form the upstream port 10 which is introduced into a corresponding orifice of the lower caisson 5.
• the upper end of said pipe opens into the body 13 and, for allow the descent of the fluid, the body 13 is blind at the top and has at least one fluid passage 13a from the upper end of the tubing 12 to the downstream port 11 formed in said body.
• the body 13 is fitted into an orifice of the upper box 6, said orifice being provided opposite the one in which the tubing 12 is introduced.
• the body 13 has a triangular geometry, and forms three equal axial channels 13a around the tubing 12 to open on the lower wall of said body.
• This embodiment is suitable for an arrangement in which each generator element 1 is surrounded by six modules 9 and each of the modules is common to three elements 1.
• the lateral surface 13b of the body 13 has an envelope of geometry similar to that of the peripheral surface of the elements 1 arranged opposite said surface.
• the three lateral surfaces 13b of the body 13 are concave with a radius similar to that of the elements 1.
• the body 13 is surmounted by a plug 14 which has at least one peripheral support zone for the elements.
• a lug 14a is provided on each side face of the plug 14.
• the packaging system further comprises plates 16 made of thermal conductive material, in particular metal such as loops 15, said plates being associated with the loop sections. More specifically, a plate 16 is disposed in each of the conditioning loops 15 between the ascending and descending sections. In addition, plates 16 are provided for interconnecting the loops 15. In addition to improving the heat transfer, the plates 16 also make it possible to stiffen the battery.
• each element 1 is successively surrounded by a loop 15, a plate 16, a section of a loop, a plate 16, a loop 15, a plate 16, a loop section and a plate 16.

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• Chemical & Material Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Electrochemistry (AREA)
• General Chemical & Material Sciences (AREA)
• Engineering & Computer Science (AREA)
• Manufacturing & Machinery (AREA)
• Secondary Cells (AREA)
• Battery Mounting, Suspending (AREA)

Applications Claiming Priority (2)

Publications (1)

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• 2007
  • 2007-04-19 FR FR0702855A patent/FR2915320B1/fr not_active Expired - Fee Related
• 2008
  • 2008-03-17 CN CN200880012244A patent/CN101682095A/zh active Pending
  • 2008-03-17 JP JP2010503540A patent/JP2010525507A/ja active Pending
  • 2008-03-17 BR BRPI0808323-1A2A patent/BRPI0808323A2/pt not_active IP Right Cessation
  • 2008-03-17 KR KR20097023390A patent/KR20100016371A/ko not_active Application Discontinuation
  • 2008-03-17 CA CA 2679559 patent/CA2679559A1/fr not_active Abandoned
  • 2008-03-17 WO PCT/FR2008/000349 patent/WO2008142223A1/fr active Application Filing
  • 2008-03-17 MX MX2009011225A patent/MX2009011225A/es not_active Application Discontinuation
  • 2008-03-17 EP EP08787804A patent/EP2149173A1/fr not_active Withdrawn
  • 2008-03-17 US US12/596,452 patent/US20100119929A1/en not_active Abandoned

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