EP2147134A1 - Procédé de décapage d'un élément structurel - Google Patents
Procédé de décapage d'un élément structurelInfo
- Publication number
- EP2147134A1 EP2147134A1 EP08758017A EP08758017A EP2147134A1 EP 2147134 A1 EP2147134 A1 EP 2147134A1 EP 08758017 A EP08758017 A EP 08758017A EP 08758017 A EP08758017 A EP 08758017A EP 2147134 A1 EP2147134 A1 EP 2147134A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- component
- stripped
- electrolyte
- wear protection
- surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 26
- 238000000034 method Methods 0.000 title claims abstract description 25
- 239000011248 coating agent Substances 0.000 title claims abstract description 14
- 239000003792 electrolyte Substances 0.000 claims abstract description 22
- 239000000919 ceramic Substances 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 239000004094 surface-active agent Substances 0.000 claims description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 3
- 239000000956 alloy Substances 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F5/00—Electrolytic stripping of metallic layers or coatings
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/005—Repairing methods or devices
Definitions
- the invention relates to a method for stripping a component, in particular a gas turbine component, according to the preamble of claim 1.
- Components of a gas turbine such as the rotor blades, are provided with special anti-wear coatings to provide oxidation resistance, corrosion resistance, or erosion resistance on the surfaces.
- the components of gas turbines are subject to wear during operation of the same or can be damaged in any other way.
- it is generally necessary to remove or remove the wear-resistant coating from the part to be repaired in regions, partially or even in total.
- the removal or removal of coatings is also referred to as stripping. In the stripping process, a distinction is made between those in which the stripping takes place mechanically, chemically or electrochemically.
- wear protection coatings are designed as so-called multilayer coatings consisting of several alternately applied to the gas turbine component layers. It is thus possible, for example, for a wear protection coating designed as a multilayer coating to comprise a relatively soft, metallic layer and a relatively hard, ceramic layer, which are applied to the gas turbine component repeatedly alternately one behind the other.
- wear protection coatings are known in practice in which more than two different layers are alternately applied one behind the other to the gas turbine component, for example multi-layer coatings of four alternately successively applied to the gas turbine component layers, namely a first, to the material composition of the gas turbine component adapted metallic and thus relatively soft layer, also a relatively soft, metallic layer of a metal alloy material, a third, relatively hard graded metal-ceramic layer and a fourth relatively hard, ceramic layer.
- no method has been known from the prior art by means of which wear protection coatings designed as multi-layer coatings can be effectively removed without the risk of damage to the base material of the gas turbine component.
- the present invention is based on the problem to provide a novel method for stripping a gas turbine component.
- the component is positioned in a bath of an alkaline electrolyte to remove the multilayer or multi-layer wear protection coating, wherein the component positioned in the electrolyte is stripped at a current density between 1 A / dm 2 and 20 A / dm 2 .
- the method according to the invention for stripping a component has the advantage that multi-layer coatings can be removed without residue from the surface of the component to be stripped, without the risk that the base material of the component to be stripped is attacked and thus damaged.
- titanium-base alloys and nickel-based alloys are not attacked in the stripping according to the invention.
- Another advantage of the method according to the invention is that components in a single bath can be stripped of the alkaline electrolyte. In the method according to the invention for stripping a component, it is therefore not necessary to provide several different baths.
- the component positioned in the electrolyte is anodically processed at room temperature.
- the bath comprises a surfactant in addition to the alkaline electrolyte for reducing the surface tension or interfacial tension.
- the electrolyte used is in particular a sodium hydroxide solution or a potassium hydroxide solution.
- a fluorosurfactant is used as the surfactant in an amount to reduce the surface tension to between 20 dynes and 50 dynes.
- the inventive method is used for stripping of coated with multilayer wear protection coatings components such.
- the component to be stripped is arranged in a bath of an alkaline electrolyte.
- the component positioned in alkaline electrolyte is then stripped by applying an electrical current, wherein a current density between 1 A / dm 2 and 20 A / dm 2 is stripped.
- the stripping takes place by electrochemical means, the component to be stripped being processed predominantly anodically, that is to say, it is connected predominantly as an anode during stripping.
- the component to be stripped can be temporarily switched as a cathode to increase the efficiency of stripping at defined time intervals.
- the EntSchichtung of the positioned in the alkaline electrolyte component takes place with a current density between 1 A / dm 2 and 5 A / dm second
- the stripping is preferably carried out under room temperature.
- the alkaline electrolyte used is preferably sodium hydroxide solution or potassium hydroxide solution.
- a bath which comprises a surfactant in addition to the alkaline electrolyte.
- the surfactant is preferably a fluorosurfactant.
- the amount of surfactant is determined in such a way that the surface tension or interfacial tension is reduced to a value between 20 dyn and 50 dyn, in particular to a value between 25 dyn and 35 dyn.
- the component is to be stripped only on certain surface sections, not to be stripped areas or sections of the component are covered with a wax-containing material or with a waxy material prior to stripping.
- a wax-containing material or with a waxy material prior to stripping.
- This can be z. B. be used when a gas turbine blade exclusively in the region of its blade, but not in the region of the blade root, to be stripped.
- the blade root is then covered with a wax-containing material or a wax-like material before the arrangement of the gas turbine blade in the bath.
- the inventive method allows effective and gentle removal of multilayer coatings of components.
- the stripping takes place by electrochemical means, with a single bath of an alkaline electrolyte is sufficient. There is no risk that the base material of the component to be stripped is removed and thus damaged.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
La présente invention concerne un procédé de décapage d'un élément structurel, en particulier d'un élément de turbine à gaz, destiné notamment au retrait complet ou partiel d'un revêtement multicouche de protection contre l'usure qui recouvre la surface de l'élément structurel, le revêtement de protection contre l'usure comprenant au moins une couche céramique relativement dure et au moins une couche métallique relativement souple. Selon l'invention, pour permettre le retrait du revêtement multicouche de protection contre l'usure, l'élément structurel est placé dans un bain d'électrolyte alcalin, l'élément structurel qui se trouve dans l'électrolyte étant décapé avec une densité de courant comprise entre 1 A/dm<SUP>2</SUP> et 20 A/dm<SUP>2</SUP>.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102007022832A DE102007022832A1 (de) | 2007-05-15 | 2007-05-15 | Verfahren zur Entschichtung eines Bauteils |
PCT/DE2008/000756 WO2008138301A1 (fr) | 2007-05-15 | 2008-05-02 | Procédé de décapage d'un élément structurel |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2147134A1 true EP2147134A1 (fr) | 2010-01-27 |
Family
ID=39708426
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP08758017A Withdrawn EP2147134A1 (fr) | 2007-05-15 | 2008-05-02 | Procédé de décapage d'un élément structurel |
Country Status (5)
Country | Link |
---|---|
US (1) | US20100108538A1 (fr) |
EP (1) | EP2147134A1 (fr) |
CA (1) | CA2679308A1 (fr) |
DE (1) | DE102007022832A1 (fr) |
WO (1) | WO2008138301A1 (fr) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102010010770A1 (de) * | 2010-03-09 | 2011-09-15 | Lufthansa Technik Ag | Verfahren zum elektrochemischen Entschichten von Gasturbinenbauteilen |
DE102010010771A1 (de) * | 2010-03-09 | 2011-09-15 | Lufthansa Technik Ag | Verfahren zum elektrochemischen Entschichten von Gasturbinenbauteilen |
US20200055615A1 (en) * | 2017-02-01 | 2020-02-20 | Aeromet Technology Solutions, Llc | Method and apparatus for removing coatings |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4435840C1 (de) * | 1994-10-07 | 1996-03-21 | Bayer Ag | Verwendung von alkylsubstituierten Perfluoralkylsulfonamiden als Sprühnebelinhibitoren für basische Elektrolysebäder |
US6132520A (en) * | 1998-07-30 | 2000-10-17 | Howmet Research Corporation | Removal of thermal barrier coatings |
US6428683B1 (en) * | 2000-12-15 | 2002-08-06 | United Technologies Corporation | Feedback controlled airfoil stripping system with integrated water management and acid recycling system |
DE10128507B4 (de) * | 2001-06-14 | 2008-07-17 | Mtu Aero Engines Gmbh | Verwendung einer Vorrichtung zum chemischen oder elektrochemischen Bearbeiten von Bauteilen |
US6969457B2 (en) * | 2002-10-21 | 2005-11-29 | General Electric Company | Method for partially stripping a coating from the surface of a substrate, and related articles and compositions |
US7078073B2 (en) * | 2003-11-13 | 2006-07-18 | General Electric Company | Method for repairing coated components |
DE102004001392A1 (de) * | 2004-01-09 | 2005-08-04 | Mtu Aero Engines Gmbh | Verschleißschutzbeschichtung und Bauteil mit einer Verschleißschutzbeschichtung |
US20060137995A1 (en) * | 2004-12-29 | 2006-06-29 | Sukanta Ghosh | Method for removal of metal from a workpiece |
US20060226025A1 (en) * | 2005-03-16 | 2006-10-12 | Colorado School Of Mines | Electrochemical removal of die coatings |
DE102005041844A1 (de) * | 2005-09-02 | 2007-03-08 | Mtu Aero Engines Gmbh | Verfahren zum Beschichten oder Entschichten eines Bauteils |
DE102005049249B4 (de) * | 2005-10-14 | 2018-03-29 | MTU Aero Engines AG | Verfahren zur Entschichtung eines Gasturbinenbauteils |
-
2007
- 2007-05-15 DE DE102007022832A patent/DE102007022832A1/de not_active Withdrawn
-
2008
- 2008-05-02 EP EP08758017A patent/EP2147134A1/fr not_active Withdrawn
- 2008-05-02 CA CA002679308A patent/CA2679308A1/fr not_active Abandoned
- 2008-05-02 WO PCT/DE2008/000756 patent/WO2008138301A1/fr active Application Filing
- 2008-05-02 US US12/451,153 patent/US20100108538A1/en not_active Abandoned
Non-Patent Citations (1)
Title |
---|
See references of WO2008138301A1 * |
Also Published As
Publication number | Publication date |
---|---|
DE102007022832A1 (de) | 2008-11-20 |
CA2679308A1 (fr) | 2008-11-20 |
US20100108538A1 (en) | 2010-05-06 |
WO2008138301A1 (fr) | 2008-11-20 |
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Legal Events
Date | Code | Title | Description |
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PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
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17P | Request for examination filed |
Effective date: 20091112 |
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AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MT NL NO PL PT RO SE SI SK TR |
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AX | Request for extension of the european patent |
Extension state: AL BA MK RS |
|
DAX | Request for extension of the european patent (deleted) | ||
17Q | First examination report despatched |
Effective date: 20130628 |
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STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
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18D | Application deemed to be withdrawn |
Effective date: 20131109 |