Classifications

• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
  • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
  • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
  • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
  • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
  • F01N3/022—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
  • F01N3/0222—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous the structure being monolithic, e.g. honeycombs
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
  • B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
  • B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
  • B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
  • B01D46/2418—Honeycomb filters
  • B01D46/2451—Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
  • B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
  • B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
  • B01D46/2418—Honeycomb filters
  • B01D46/2451—Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure
  • B01D46/247—Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure of the cells
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
  • B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
  • B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
  • B01D46/2418—Honeycomb filters
  • B01D46/2451—Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure
  • B01D46/2474—Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure of the walls along the length of the honeycomb
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
  • B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
  • B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
  • B01D46/2418—Honeycomb filters
  • B01D46/2451—Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure
  • B01D46/2478—Structures comprising honeycomb segments
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
  • B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
  • B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
  • B01D46/2418—Honeycomb filters
  • B01D46/2451—Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure
  • B01D46/2482—Thickness, height, width, length or diameter
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
  • B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
  • B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
  • B01D46/2418—Honeycomb filters
  • B01D46/2451—Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure
  • B01D46/2484—Cell density, area or aspect ratio
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
  • B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
  • B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
  • B01D46/2418—Honeycomb filters
  • B01D46/2451—Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure
  • B01D46/2486—Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure characterised by the shapes or configurations
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
  • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
  • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
  • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
  • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
  • F01N3/022—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
  • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
  • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
  • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
  • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
  • F01N3/023—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
  • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
  • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
  • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
  • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
  • F01N3/033—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices
  • F01N3/035—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices with catalytic reactors, e.g. catalysed diesel particulate filters
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
  • B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
  • B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
  • B01D46/2418—Honeycomb filters
  • B01D46/2498—The honeycomb filter being defined by mathematical relationships
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
  • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
  • F01N2250/00—Combinations of different methods of purification
  • F01N2250/02—Combinations of different methods of purification filtering and catalytic conversion
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
  • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
  • F01N2330/00—Structure of catalyst support or particle filter
  • F01N2330/06—Ceramic, e.g. monoliths

Definitions

• the invention relates to the field of filter structures possibly comprising a catalytic component, for example used in an exhaust line of a diesel type internal combustion engine.
• Filters for the treatment of gases and the removal of soot typically from a diesel engine are well known in the prior art.
• These structures all most often have a honeycomb structure, one of the faces of the structure allowing the admission of the exhaust gas to be treated and the other side the evacuation of the treated exhaust gas.
• the structure comprises, between the intake and discharge faces, a set of adjacent ducts or channels of axes parallel to each other separated by porous walls.
• the ducts are closed at one or the other of their ends to delimit inlet chambers opening on the inlet face and outlet chambers opening along the discharge face.
• the channels are alternately closed in an order such that the exhaust gases, during the crossing of the honeycomb body, are forced to pass through the sidewalls of the inlet channels to join the outlet channels. In this way, the particles or soot are deposited and accumulate on the porous walls of the filter body.
• porous ceramic filters for example cordierite, alumina, mullite, silicon nitride, are used for the filtration of gases. in a silicon / silicon carbide or silicon carbide mixture.
• the particulate filter is subjected to a succession of filtration (soot accumulation) and regeneration phases.
• soot particles emitted by the engine are retained and are deposited inside the filter.
• soot particles are burned inside the filter, in order to restore its filtration properties.
• the filter is subjected to intense thermomechanical stresses likely to cause over the duration of microcracking may alter the filtration efficiency and eventually require the filter change in an exhaust line.
• a material having a very good thermomechanical resistance such as silicon carbide.
• a decrease in the frequency of the regeneration phases would further increase the life of the filters.
• a particulate filter as previously described in the exhaust line of the engine causes a pressure drop, that is to say a differential pressure between the incoming gas and the outgoing gas, which may affect the performance of the engine.
• the filter must therefore be configured to avoid such alteration by minimizing said pressure drop, whether in a state not loaded with soot, for example at nine or after a regeneration phase, or in a state loaded with soot. It is particularly important, in an application such as the particle filter, to minimize the pressure drop during operation so as not to degrade the power of the device. engine and not to significantly increase fuel consumption, whether or not the filter is loaded with soot or residue.
• the transformation of polluting emissions into the gaseous phase (that is to say mainly carbon monoxide (CO) and unburned hydrocarbons (HC) or even nitrogen oxides (NO x )) in less harmful gases requires additional catalytic treatment.
• the most advanced current filters thus additionally have an additional catalytic component.
• the catalytic function is obtained by impregnating the honeycomb structure with a solution comprising the catalyst or a precursor of the catalyst, generally based on a platinum group precious metal.
• soot deposition time corresponds to the time required for the filter to reach its maximum level of filtration efficiency, during its first implementation or after a regeneration phase. It is assumed that this time is a function in particular of placing a sufficient amount of soot in the porosity of the filter to block the direct passage of fine particles through the walls of the filter.
• One of the direct consequences of an unsuitable soot deposition time is the appearance of persistent and harmful black smoke, as well as the presence of traces of soot at the outlet of the exhaust line, on a new filter or after a regeneration phase. It is obvious that for environmental, image and user comfort issues, car manufacturers want the appearance of such phenomena is suppressed or at least minimized on vehicles equipped with such filters.
• soot deposition is a poorly known phenomenon, probably because the deposit mass is not measurable in real time on a filter during the solicitation. Only the soot deposition time indirectly measured from the analysis of the rate of particles present in the exhaust gas at the outlet of the filter is indeed accessible.
• the deposit of soot may be more or less homogeneous, that is to say that the thickness of this deposit may be more or less variable in the direction of the length of the filter or more or less well distributed along the section of the intake channels.
• a deposit as homogeneous as possible within the structure therefore makes it possible to minimize the soot deposition time and therefore the emission of black fumes.
• a solution that makes it possible to reduce the soot deposition time consists in reducing the porosity, that is to say typically the pore volume and / or the pore diameter of the material constituting the filtering walls of the filter, but this results in an increase notorious of the pressure loss of the filter.
• the inlet and outlet channels have a cross sectional square section.
• Such symmetrical structures have the advantage of having relatively short soot deposition times, but also certain disadvantages such as a reduced filtration area and a high pressure drop when the filter is loaded with soot.
• these symmetrical structures are characterized by a low volume of storage residues. By residues, it is understood, within the meaning of this description, the residual fraction of incombustible particles under the regeneration conditions of the filter.
• EP 1 125 704 B1 discloses a filter with channels delimited by portions of walls, a certain number of which are concave and the other straight and / or convex, as shown in FIGS. 1, 3 and 4 of this patent. . According to this teaching, such a configuration makes it possible to increase the overall surface of said walls to a constant volume, with respect to a section of the cells of the square type, and to increase the interactions between the gas and the walls. On the other hand, the storage volume of the residues of these structures is not improved compared to that of square section channels. The soot deposition time of these structures is also not improved over that of square section channels.
• the present invention aims to provide a filter structure having the best compromise between: a low pressure loss caused by a filtering structure in operation, that is to say, typically when it is in an exhaust line of an internal combustion engine, both when it is free of soot particles and when it is loaded with particles,
• the present invention relates to a filtration structure of particles-loaded gases of the honeycomb type and comprising a set of longitudinal adjacent channels of axes parallel to one another separated by porous walls, said structure characterized in that at least one, and preferably all, of the walls connecting two vertices of a channel and separating it from an adjacent channel has, in cross-section and with respect to the center of said channel, at least a concavity and at least a convexity.
• said wall or walls have at least two changes of curvature.
• the said wall or walls have at least two points of inflection.
• the number of inflection points is included according to the invention between 2 and 4 inclusive, or even between 2 and 3 inclusive and very preferably is equal to 2.
• the distance d z between two consecutive vertices of said channel may be between about 0.1 mm and about 10 mm, preferably between about
• the number of walls delimiting a channel may be equal to 3, 4, 6 or 8 and preferably may be equal to 4 or 6.
• a filtration structure comprising at least one channel delimited by three walls, the angle CC defined, in a cross section, by the straight line connecting two consecutive vertices and by the tangent to the wall at one of said peaks, is advantageously between about 13 ° and about 30 °.
• a filtration structure according to the invention comprising at least one channel defined by four walls, the angle CC defined, in a cross section, by the line segment connecting two consecutive vertices of said channel and the tangent to the central core of the wall at one of said peaks is advantageously between about 20 ° and about 45 °.
• the angle CC defined, in a cross section, by the line segment connecting two consecutive vertices of said channel and by the tangent to the central core of the wall at one of said peaks is advantageously between about 25 ° and about 60 °.
• the ratio, in a cross-section, between the maximum distance di separating the central core from said wall of the line segment connecting said consecutive vertices of a channel, and the distance d - z separating these two peaks is between 0.01 and 0.3, preferably between 0.02 and 0.1.
• the channel or channels having at least one concavity and at least one convexity have at least one longitudinal plane of symmetry and preferably at least two longitudinal symmetry planes.
• the structure according to the invention further comprises a catalytic coating for the treatment of pollutant gases of CO or HC or NOx type.
• the walls of the filtration structure have substantially constant thicknesses.
• the thickness of the walls is between 200 and 500 microns.
• the density of channels per cm 2 is between 1 and 280, preferably between 15 and 65.
• the filtering structure according to the invention may be cordierite, alumina, mullite, silicon nitride, a silicon / silicon carbide mixture, alumina titanate or preferably silicon carbide.
• the invention further relates to a filter element comprising a structure as previously described, wherein the channels are closed at one or the other of their ends to define inlet chambers opening on the intake side and outlet chambers opening along the discharge face.
• Said structure comprises for example a plurality of honeycomb filter elements interconnected by a joint cement.
• the invention relates to the use of the structure as particulate filter, catalysed or not, in an exhaust line of a diesel engine or gasoline, preferably diesel.
• FIGS. 1, 2 and 3 illustrate a nonlimiting exemplary embodiment of a structure, for example filtering, having channels according to the invention.
• Figure 1 is a cross-sectional view of a four-walled inlet channel, in which the characteristic elements of a wall according to the invention have been shown.
• Figure 2 is an overall view, in cross section, illustrating the arrangement of several channels within a structure according to the invention.
• FIG. 3 shows a front view of a monolithic element comprising input and output channels according to the invention.
• FIG. 1 shows an inlet channel 10 for the gases, consisting of four walls referenced 1 to 4 having a profile according to the invention, that is to say two concavities 5 and 6 and a convexity 7 by relative to an observer placed in the center of said cavity.
• Each wall for example the wall 1 extending between the vertices Si and S2, is characterized by: angles CC 1 and CC 2 defined on the one hand by the line segment 8 connecting the two consecutive vertices S 1 and S 2 of the channel and, on the other hand, by the tangent to the central core 9 of the wall respectively at the vertex Si for CCi and S2 for CC2.
• a distance di defined as the maximum distance separating the central core 9 from said wall of the line segment 8 connecting the vertices Si and S2.
• FIG. 1 illustrates a particular embodiment according to the invention in which the wall has a concavity and two convexities with respect to the center of the reference channel.
• Fig. 2 shows the arrangement of a set of inlet and outlet channels 11 of the gases in cross-section of a honeycomb structure according to the invention.
• Figure 3 schematically shows the arrangement of channels 10 and 11 in a monolithic filter block according to the invention.
• the first population of monolithic elements or monoliths in the form bee and silicon carbide.
• the median diameter refers to the diameter of the particles below which 50% by mass of the population is found.
• the green monoliths obtained are dried by microwave for a time sufficient to bring the water content not chemically bound to less than 1% by weight.
• the channels of each face of the monolith are alternately blocked according to well-known techniques, for example described in application WO 2004/065088.
• the monoliths are then fired to a temperature of 2200 ° C., which is maintained for 5 hours.
• the porous material obtained comprising for the most part recrystallized CC-SiC, has an open porosity of 47% and a mean pore distribution diameter of about 15 ⁇ m.
• the dimensional characteristics of the elements thus obtained are given in Table 1 below.
• An assembled filter was then formed from the monoliths. Sixteen elements from the same mixture were assembled together according to conventional techniques by bonding with a cement of the following chemical composition: 72% by weight of SiC, 15% by weight of Al 2 O 3 , 11% by weight of SiO 2 , the remainder consisting of impurities predominantly Fe2O3 and alkali and alkaline earth metal oxides. The average thickness of the joint between two neighboring blocks is of the order of 2 mm. The assembly is then machined in order to form assembled filters of cylindrical shape 14.4 cm in diameter.
• EXAMPLE 4 The technique for synthesizing the monoliths described above is also identical, but this time the die is adapted so as to produce monolithic blocks characterized by an arrangement of the channels identical to those of FIG. application EP 1 125 704, with an asymmetry rate of 7%, as defined above.
• Example 5 (according to the invention):
• the dies were configured in such a way that the monoliths obtained according to Examples 1 to 5 above have the same density of cells per unit area, in a transverse layer.
• the channel density is 180 cpsi ("cells per square inch"), which is 27.9 channels per cm 2 , a cpsi being equal to 1 cell / 6.45 cm 2 .
• the hydraulic diameter of the inlet channels is 4A / P.
• A being the area of the section of the input channels and P their perimeter.
• pressure drop the meaning of the present invention is understood to mean the differential pressure existing between the upstream and the downstream of the filter.
• the pressure drop was measured according to the techniques of the art, for a gas flow rate of 600 Nm 3 / h and a temperature of 300 0 C, initially on the new filters.
• the various filters are previously mounted on an exhaust line of a diesel engine 2.0 L run at full power (4000 rpm) for 30 minutes then dismantled and weighed to determine their initial mass.
• the filters are then reassembled on the engine bench with a speed of 3000 rpm and a torque of 50 Nm to obtain soot loads in the filter of 8 g / 1.
• the pressure drop measurement on the filter thus loaded with soot is carried out as on the new filter.
• the filter to be tested was placed on an exhaust line of a motor on a test bench.
• the engine used is of the 2.0 liter diesel type.
• the filter is gradually loaded in soot by the operation of the engine at a speed of 3000 rpm to 50 N. m.
• the bench is equipped with an Electrical Low Pressure Impactor (ELPI) system, which continuously measures the concentration of particles in a gas in real time from the moment the filter is charged.
• ELPI Electrical Low Pressure Impactor
• This gives a filtration efficiency curve as a function of time characterized by a quasi-plateau after a determined test duration.
• the bearing corresponds to a filtration efficiency greater than or equal to 99%.
• the time between the beginning of the loading of the filter and that from which an efficiency of at least 99% is obtained corresponds according to the present invention to the soot deposition time.
• the OFA is the ratio of the area covered by the sum of the cross-sections of the inlet channels on the front face of a monolith and the cross-sectional area of the said monolith.
• the structures according to the invention are characterized by a better compromise between the pressure loss generated. by the filter, whether or not it is loaded with soot and the soot deposition time.
• the structures according to the invention thus have a particular interest in the case where they incorporate an additional catalytic component. More particularly, because of this better compromise, it is possible according to the invention to synthesize high porosity structures in which the catalyst load (and consequently the efficiency of the catalytic treatment) is substantially increased, without however to bring to an unacceptable value the soot deposition time of the catalytic filter thus obtained.

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• Physics & Mathematics (AREA)
• Geometry (AREA)
• Chemical & Material Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Engineering & Computer Science (AREA)
• Combustion & Propulsion (AREA)
• Mechanical Engineering (AREA)
• General Engineering & Computer Science (AREA)
• Filtering Materials (AREA)
• Filtering Of Dispersed Particles In Gases (AREA)
• Exhaust Gas After Treatment (AREA)
• Ceramic Products (AREA)
• Catalysts (AREA)

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• 2007
  • 2007-02-05 FR FR0753062A patent/FR2912069B1/fr not_active Expired - Fee Related
• 2008
  • 2008-01-31 KR KR1020097016265A patent/KR20090108698A/ko not_active Application Discontinuation
  • 2008-01-31 EP EP08762015A patent/EP2111281A1/de not_active Withdrawn
  • 2008-01-31 JP JP2009547738A patent/JP2010517743A/ja active Pending
  • 2008-01-31 WO PCT/FR2008/050155 patent/WO2008104665A1/fr active Application Filing
  • 2008-01-31 US US12/525,674 patent/US20100101196A1/en not_active Abandoned

Non-Patent Citations (1)

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