EP2081878A2 - Engrais soufré et procédé de fabrication d'engrais soufré en granulés - Google Patents

Engrais soufré et procédé de fabrication d'engrais soufré en granulés

Info

Publication number
EP2081878A2
EP2081878A2 EP07793963A EP07793963A EP2081878A2 EP 2081878 A2 EP2081878 A2 EP 2081878A2 EP 07793963 A EP07793963 A EP 07793963A EP 07793963 A EP07793963 A EP 07793963A EP 2081878 A2 EP2081878 A2 EP 2081878A2
Authority
EP
European Patent Office
Prior art keywords
sulphur
fertilizer
granules
bentonite
air
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP07793963A
Other languages
German (de)
English (en)
Inventor
Zygmunt Pelczarski
Henryk Turbiarz
Boguslaw Krawczyk
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zaklady Chemiczne
Original Assignee
Zaklady Chemiczne
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zaklady Chemiczne filed Critical Zaklady Chemiczne
Publication of EP2081878A2 publication Critical patent/EP2081878A2/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00—Fertilisers characterised by their form
    • C05G5/30—Layered or coated, e.g. dust-preventing coatings
    • C05G5/36—Layered or coated, e.g. dust-preventing coatings layered or coated with sulfur

Definitions

  • the invention covers sulphur fertilizer in form of globular granules or pellets, and the method used to manufacture granulated sulphur fertilizer.
  • Sulphur-bentonite fertilizer is a known substance in form of globular granules and pellets, containing elementary sulphur and bentonite.
  • a commonly used sulphur-bentonite fertilizer is the one in form of hemispherical pellets, derived due to formation of drops from mixture of liquid sulphur in a dropping apparatus called Rotoformer. This apparatus is demonstrated, among other things, in "Sandvik Process Systems” catalogues. Drops formed in Rotoformer are solidified into pellets on an "endless" cooling line.
  • the American Patent Specification No. US 4,394,150 describes globular granules of sulphur-bentonite fertilizer containing 88-89% of sulphur and 11—12% of bentonite.
  • the granules are formed by mixing ground down bentonite with liquid sulphur and dropping liquid mixture passed through holes in the bottom of tank containing the mixture, while drops are solidified into granules in liquid manure salt solutions.
  • the material inside ready granule has moisture content reaching up to 0.1%, while after drying moisture content near the granule outer surface reaches up to 1.5%.
  • Polish Specification of the invention reported for patenting under ref. no. P. 319706, describes sulphur-bentonite fertilizer in form of globular granules containing 85-93% by weight of elementary sulphur and 7-15% by weight of ground down dry bentonite.
  • fabrication method for the sulphur-bentonite fertilizer granules involves preparation of bentonite suspension in liquid sulphur. At the same time, bentonite is dried up by heat contained in liquid sulphur, then the suspension is let through sprinkling screens of the granulation column, while drops of sulphur-bentonite suspension developed on the screen are solidified into granules in a stream of cool air delivered from the bottom of the granulation column.
  • This fertilizer possesses micropores, which facilitates bentonite contact with moisture everywhere inside the granule.
  • British Invention Specification No. GB 2292140 describes sulphur-bentonite fertilizer in form of globular granules containing micronised elementary network sized from 5 to 130 ⁇ m.
  • the above-mentioned fertilizer manufacturing process involves the following: micronised sulphur is mixed with bentonite powder and with water solution of lignosulfonate. Then, the mixture is granulated in a disk-type granulator/pelletizer, or compacted. After this, the granules are dried. This fertilizer easily disperses in soil, turning into sulphur micro-particles sized as above.
  • Granules made of micronised sulphur disperse in humid soil into much smaller sulphur particles than fertilizer granules formed by solidifying the mixture of liquid sulphur and bentonite.
  • Known fertilizers containing both micronised sulphur and solidified mixture of liquid sulphur and bentonite provide the base for the production of fertilizers containing main and residual additional fertilizing additives or microelements, apart from sulphur and bentonite.
  • Granulation system consists of the above-mentioned granulator with fluidized bed supplied from the bottom with air, and sulphur-bentonite mixer heated up with steam, a pump for sulphur-bentonite mixture, system exhausting air from the granulator, and filter separating dust from contaminated air.
  • Known granulation method in the FDG granulator with vanes and chute involves the following operations: fluidized bed is supplied the bottom with cool air via screen, granulation subgrain is brought into the bed, and the mixture of liquid sulphur and bentonite is sprayed onto the subgrain. Then, the mixture is solidified on the granules in cool air.
  • granulated product is sieved out of the granulator, and its undersized part is returned to the granulator.
  • Hot air received from the granulator is subject to dedusting and cooling out of the granulator, and then it is returned to it.
  • Sulphur-bentonite granules obtained through the above-mentioned method possess required mechanical strength and low moisture content of approximately 0.15%.
  • the purpose of the invention is to develop a composition of sulphur fertilizer, in form of globular granules or pellets, which would contain solidified mixture of liquid sulphur and bentonite, and disperse in contact with soil moisture into sulphur molecules of much smaller size than that is in case of known fertilizers of this type.
  • the purpose of the invention is to develop environment-friendly and inexpensive method of sulphur fertilizer production in form of globular granules characterised by low moisture content.
  • sulphur fertilizer either in form of globular granules or pellets that constitute solidified mixture of liquid sulphur and bentonite, and favourably additional components and fertilizing microelements, is characterised by its content: 60-95% of sulphur, 4-20% of bentonite and 1-8% of lignosulfonate.
  • the fertilizer contains calcium or sodium lignosulfonate and sodium or calcium bentonite.
  • bentonite and lignosulfonate have the form of powders suspended in solidified mixture with grain sizes up to 120 ⁇ m.
  • liquid sulphur is mixed with bentonite and favourably with additional components and fertilizing microelements. Then the mixture is subject to granulation in a rotary drum-type granulator with nozzles and vanes. This is effected by spraying liquid mixture through the nozzles onto the granules cyclically poured through by vanes in the granulator, and by solidifying the mixture layer by layer on the granules in air, while subgrain is returned to the granulator.
  • the above-mentioned method is characterised by splashing liquid mixture at the temperature of 120-150° C to form micro-drops, onto a curtain made by falling granules. Then, the micro-drops are solidified layer by layer on granule surfaces at the temperature of 90-115° C in a stream of air flowing through the curtain. At the same time, additional coolant is sprayed, which cools the air.
  • Granules and worn out coolant with air and dust are removed from the process in separate streams, while granules leaving the process are kept at the temperature of 40-90° C, and subgrain returned to the process favourably cools down to the temperature under 30° C.
  • liquid mixture splashes into micro-drops under the pressure of 0.5-2 MPa, while, in particular, sodium or calcium lignosulfonate is added to the liquid mixture. Then, the mixture with lignosulfonate is splashed onto a curtain of falling granules at the temperature under 13O 0 C.
  • the air is cooled down with an additional coolant in form of water mist.
  • water mist is delivered directly into the air stream.
  • the air is cooled down with additional gaseous coolant, especially nitrogen or carbon dioxide, while gaseous coolant is delivered into the air stream.
  • gaseous coolant especially nitrogen or carbon dioxide
  • the fertilizer since it contains solidified liquid sulphur, bentonites and lignosulfonates, the fertilizer disperses in humid soil into smaller sulphur molecules that it is in the case of known fertilizers, in which only bentonite is the dispersant of solidified liquid sulphur. Lignosulfonates support bentonite in the process of dispersing sulphur contained in the fertilizer.
  • the fertilizers in individual versions of fertilizers containing bentonites and calcium or sodium lignosulfonates, the fertilizers may disperse into sulphur molecules of various size and at different rates, depending on intended use of a given fertilizer.
  • Total evaporation of water micro-drops during air cooling allows to obtain product with low moisture content.
  • the fertilizer remains dry also in the case, when air is cooled with gas. Dry bentonite contained in the fertilizer and obtained using the method specified in the invention effectively bursts the fertilizer into sulphur micro-molecules, as it is able to swell when the fertilizer contacts moisture contained in soil.
  • the method applied to produce globular sulphur fertilizer granules according to the invention is cheaper than known method of sulphur- bentonite fertilizer granulation in the granulator with fluidized bed.
  • Sulphur fertilizer in form of globular granules and pellets and the method applied to produce granulated sulphur fertilizer are specified in the following examples of the invention implementation.
  • Example 1 Sulphur fertilizer in form of globular granules and pellets and the method applied to produce granulated sulphur fertilizer are specified in the following examples of the invention implementation.
  • the granules have high mechanical strength.
  • the volume of dust generated during mechanical distribution of the fertilizer is small.
  • the fertilizer in form of globular granules works better than pellets in the production of mixes with other granulated fertilizers.
  • Fertilizer granules were placed in water, and after 8 days it was found that 60% of sulphur contained in the fertilizer had micro-particles smaller than 150 ⁇ m, and 95% under 250 ⁇ m.
  • the fertilizer is intended first to feed sulphur-philic plants, and also to control the pH in soil.
  • Sodium and calcium bentonite, 50 kg of each, and 20 kg of calcium lignosulfonate, in form of dry powders with particles smaller than 75 ⁇ m, are proportioned uniformly to 880 kg of liquid sulphur and the above-mentioned components are evenly mixed at the temperature of 125-130° C in a steam-heated mixer.
  • the fertilizer nuclei of crystallization are poured into tilted, rotary drum-type granulator with vanes, nozzles and chute. These nuclei constitute granulation subgrain, at the beginning of the process in form of sulphur powder.
  • the mixture of liquid sulphur, bentonite and lignosulfonate is splashed through nozzles in rotating granulator at the temperature ranging from 125 to 130° C at nozzle outlet.
  • the mixture is sprayed by nozzles at the pressure of 0.8 MPa onto the curtain made by granulation subgrain.
  • the subgrain cyclically pours through the vanes in the granulator.
  • the mixture is solidified on granulation subgrain at the temperature of 105-110° C in the stream of air flowing along the granulator through the curtain of falling subgrain.
  • additional coolant is sprayed by nozzles into the air stream, while, according to the invention implementation example, the coolant is constituted by water sprayed into micro-drops of water mist, which evaporates and cools the air.
  • Granules leaving the process at the granulator outlet are kept at the temperature of 50-60° C, and subgrain returned to the granulator is cooled out of it down to the temperature under 30° C.
  • Granules and air with steam and sulphur- bentonite dusts are removed from granulator in separate streams, via the outlet for granulated product and air outlet from granulator, respectively.
  • Fertilizer pellets have been fabricated by solidifying drops of liquid sulphur mixture with bentonite powders and the above-mentioned fertilizing additives sized under 75 ⁇ m, to form pellets on a cooling line.
  • Pellets have high mechanical strength, and they are suitable for mechanical fertilizer distribution in soil. Pellet edges crumble to negligible extent. Fertilizer pellets sized from 2 to 4 mm were placed in water and after 8 days it was found that 70% of molecules contained in dispersed fertilizer, including elementary sulphur, were smaller than 100 ⁇ m, and 95% were under 200 ⁇ m. Elementary sulphur sized as above easily goes through microbiological oxidation to sulphatic form, which is available for plants. Moreover, the fertilizer contains microelements in form of micro-particles of magnesium oxide, manganese oxide and copper oxide, which are nutritious for plants.
  • Example 3 Example 3:
  • fertilizer nuclei of crystallization are poured into tilted, rotary drum-type granulator with vanes, nozzles and chute. These nuclei constitute granulation subgrain, at the beginning of the process in form of sulphur-bentonite powder.
  • Liquid sulphur-bentonite mixture is splashed through nozzles in rotating granulator at the pressure of 0,5 MPa and temperature reaching 135° C at nozzle outlet onto the curtain made by granulation subgrain. This results from cyclic pouring of the subgrain by vanes in the granulator. The mixture is solidified on granulation subgrain at the temperature of approximately 105° C.
  • air stream is delivered to the granulator and air flow direction stabilises along the granulator, across falling subgrain.
  • Nitrogen is delivered through nozzles into the air stream flowing through the granulator. Hot air and granules being formed are cooled simultaneously with air and decompressed nitrogen, while granules at granulator outlet are kept at the temperature of 60-65° C.
  • Granules and gaseous cooling agents with sulphur-bentonite dust are removed from the granulator in separate streams, via the outlet for granulated product and air outlet from granulator, respectively.
  • Undersized granules smaller than 2 mm are returned to the granulator, and oversized granules, larger than 4 mm in diameter, are crumbled and then sent to the mixer for remelting with other fertilizer components.
  • the method specified in this invention implementation example allowed to obtain sulphur-bentonite in form of globular granules sized from 2 to 4 mm, containing 87% of sulphur and 13% of bentonite with moisture content of 0.1%.
  • 80 kg of sodium bentonite and 20 kg of calcium lignosulfonate and 150 kg of gypsum in form of dry powders with grains smaller than 80 ⁇ m are proportioned at uniform rate to 750 kg of molten, liquid sulphur.
  • the components specified above are uniformly mixed at the temperature of approximately 125° C in a steam-heated mixer.
  • Example 5
  • Fertilizer granules sized from 2 to 4 mm. were placed in water and after 8 days it was found that 55% of molecules contained in the fertilizer were micro- particles smaller than 150 ⁇ m, and 85% under 250 ⁇ m.
  • the fertilizer is intended to supply plants with sulphur, phosphorus and magnesium at the same time.
  • the mixture is subject to granulation according to the method specified in example 1 of the invention implementation.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Fertilizers (AREA)

Abstract

Cette invention concerne un engrais soufré sous forme de granules ou de pastilles constituant un mélange solidifié de soufre liquide, de bentonite et de lignosulfonates, et en variante d'additifs fertilisants. Sous forme de mélange solidifié, l'engrais contient de 60 à 95% de soufre, de 4 à 20% de sodium ou de bentonite de calcium et de 1 à 8% de calcium ou de lignosulfonate de sodium. Le procédé appliqué pour produire l'engrais soufré en granules dans le cadre de l'invention se caractérise comme suit: pulvérisation du mélange de soufre liquide avec de la bentonite ou, en variante, avec du lignosulfate ou des agents fertilisants dans le granulateur à une température de 120-150° C pour former des gouttelettes, ceci contre un rideau de granules en train de tomber. Les gouttelettes sont ensuite solidifiées couche par couche sur des surfaces de granules en train de tomber à une température de 90-115° C dans un flux d'air traversant le rideau. Simultanément, on pulvérise du réfrigérant supplémentaire pour refroidir l'air. Les granules et le réfrigérant usés sont évacués avec l'air et la poussière par flux séparés. Les granules sortants sont maintenus à une température de 40-90° C et le sous-grain qui réintègre le processus est refroidi efficacement à une température inférieure à 30° C.
EP07793963A 2006-08-25 2007-08-20 Engrais soufré et procédé de fabrication d'engrais soufré en granulés Withdrawn EP2081878A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
PL380490A PL206943B1 (pl) 2006-08-25 2006-08-25 Nawóz siarkowy oraz sposób wytwarzania nawozu siarkowego granulowanego
PCT/PL2007/000059 WO2008024007A2 (fr) 2006-08-25 2007-08-20 Engrais soufré et procédé de fabrication d'engrais soufré en granulés

Publications (1)

Publication Number Publication Date
EP2081878A2 true EP2081878A2 (fr) 2009-07-29

Family

ID=39107232

Family Applications (1)

Application Number Title Priority Date Filing Date
EP07793963A Withdrawn EP2081878A2 (fr) 2006-08-25 2007-08-20 Engrais soufré et procédé de fabrication d'engrais soufré en granulés

Country Status (4)

Country Link
EP (1) EP2081878A2 (fr)
PL (1) PL206943B1 (fr)
UA (1) UA96161C2 (fr)
WO (1) WO2008024007A2 (fr)

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BRPI1007177B1 (pt) 2009-01-29 2020-10-13 Shell Internationale Research Maatschappij B.V. processo para a fabricação de composições de fertilizante contendo enxofre, e, composição de fertilizante contendo enxofre
CA2663119A1 (fr) * 2009-04-16 2010-10-16 Sulphur Solutions Inc. Pastilles dispersibles d'engrais soufre
WO2014001384A1 (fr) * 2012-06-26 2014-01-03 Shell Internationale Research Maatschappij B.V. Composition d'asphalte
WO2014001385A1 (fr) * 2012-06-27 2014-01-03 Shell Internationale Research Maatschappij B.V. Composition d'asphalte
CN102897719A (zh) * 2012-11-02 2013-01-30 杨佳瑶 一种硫磺成型装置及工作方法
US20140216120A1 (en) * 2013-02-07 2014-08-07 Tiger-Sul Products (Canada) Co. Sulphur-based fertilizer composition with low rock phosphate content
KR101658613B1 (ko) * 2014-04-18 2016-09-21 에이치설퍼 주식회사 친환경 식물병충해 방제용 유황 수화 조성물 및 그 제조방법
KR102645367B1 (ko) * 2015-01-16 2024-03-07 스톨러 엔터프라이지즈, 인크. 원소 황 및 수화 점토를 포함하는 유동성 혼합물
CN109134099A (zh) * 2018-10-31 2019-01-04 湖北富邦科技股份有限公司 一种圆颗粒速效高浓度硫肥及生产方法
CN109456112A (zh) * 2018-12-27 2019-03-12 湖北富邦科技股份有限公司 一种多功能植物营养母粒及生产方法
BR112021022452A2 (pt) * 2019-06-24 2022-01-04 Fertinagro Biotech Sl Composição fertilizante que inclui um potencializador de oxidação microbiológica de enxofre elementar e sua utilização

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Also Published As

Publication number Publication date
WO2008024007A2 (fr) 2008-02-28
PL380490A1 (pl) 2008-03-03
PL206943B1 (pl) 2010-10-29
UA96161C2 (ru) 2011-10-10
WO2008024007A3 (fr) 2008-07-03

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