EP2066822B1 - Cermetpulver - Google Patents
Cermetpulver Download PDFInfo
- Publication number
- EP2066822B1 EP2066822B1 EP07803590.4A EP07803590A EP2066822B1 EP 2066822 B1 EP2066822 B1 EP 2066822B1 EP 07803590 A EP07803590 A EP 07803590A EP 2066822 B1 EP2066822 B1 EP 2066822B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cermet
- powder
- powders
- cobalt
- nickel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000843 powder Substances 0.000 title claims description 53
- 239000011195 cermet Substances 0.000 title claims description 35
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 24
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 23
- 239000011159 matrix material Substances 0.000 claims description 21
- 229910052751 metal Inorganic materials 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 15
- 239000011651 chromium Substances 0.000 claims description 12
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- 229910052759 nickel Inorganic materials 0.000 claims description 12
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 11
- 239000010941 cobalt Substances 0.000 claims description 11
- 229910017052 cobalt Inorganic materials 0.000 claims description 11
- 229910052804 chromium Inorganic materials 0.000 claims description 10
- 229910052742 iron Inorganic materials 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 239000007921 spray Substances 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 238000007751 thermal spraying Methods 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 5
- 239000004411 aluminium Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 229910052758 niobium Inorganic materials 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 229910052715 tantalum Inorganic materials 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 230000004048 modification Effects 0.000 claims 2
- 238000012986 modification Methods 0.000 claims 2
- 238000009472 formulation Methods 0.000 claims 1
- 229910052720 vanadium Inorganic materials 0.000 claims 1
- 229910045601 alloy Inorganic materials 0.000 description 11
- 239000000956 alloy Substances 0.000 description 11
- 239000011230 binding agent Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 238000010285 flame spraying Methods 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 238000007750 plasma spraying Methods 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 238000007873 sieving Methods 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000007669 thermal treatment Methods 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 238000009388 chemical precipitation Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/02—Compacting only
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C2204/00—End product comprising different layers, coatings or parts of cermet
Definitions
- the invention relates to novel powder mixtures, in particular cermet powder, for the surface coating of metal substrates by thermal spraying methods, such as plasma spraying or high-velocity flame spraying (HVOF), flame spraying, arc spraying, laser spraying or build-up welding, such as the PTA process.
- thermal spraying methods such as plasma spraying or high-velocity flame spraying (HVOF), flame spraying, arc spraying, laser spraying or build-up welding, such as the PTA process.
- Such powders consist of at least one finely divided hard material powder such as WC, Cr 3 C 2 , TiC, B 4 C, TiCN, Mo 2 C, etc., as well as a finely divided metal or alloy matrix powder.
- Hard powder and matrix powder are intensively - usually mixed in the presence of a solution of an organic binder, optionally with co-grinding -, atomized, dried, sieved and then heated to remove the organic binder and generating a sintered bond under a hydrogen-containing atmosphere, so that larger agglomerates of 10 bis 100 ⁇ m particle diameter arise.
- a flame spray powder which contains as carbide metal carbides and as metal 10 to 45% aluminum and nickel.
- Cobalt- and nickel-containing powders have found their way into the art as matrix metal powders.
- GB 2,214,523 describes a material consisting of 60 to 90 vol.% Cr 3 C 2 and 40 to 10 vol.% of an alloy selected from the group consisting of Co-28-32%, Cr-9-11% Ni-3.5-5.5% W and Fe-28-31% Cr-4.5-5.5% Al-0.4-0.6% Y and mixtures thereof, the% data being on Refer to weight percent.
- JP 2005-320557 describes an abrasion resistant member consisting of a base metal and a cured coating, the cured coating 60-20 wt.% Of an Fe-Cr-C based alloy matrix and 40-80 wt.% Of hard metal particles having an average particle diameter of D50 of 60-800 ⁇ m dispersed in the matrix.
- the object of the invention is, on the one hand, to further reduce the use of cobalt, since cobalt, because of its widespread use, has become a scarce raw material.
- a further object of the invention is to provide cobalt-poor cermet coatings which have comparable or increased abrasion and cavitation resistance over conventional Co-Cr matrix alloys.
- the object of the invention is also to increase the corrosion resistance of cermet coatings, in particular to reduce the solubility of matrix metals from the coatings.
- Preferred cermet powders according to the invention comprise the matrix metals nickel and cobalt in a weight ratio of at least 2: 3, more preferably in a weight ratio of 1: 1, particularly preferably in a weight ratio of 3: 2.
- Particularly preferred cermet powders according to the invention are cobalt-free. More preferred cermet powders are cobalt and nickel free.
- the ratio of the sum of the contents of chromium and aluminum to the sum of the contents of iron, nickel and chromium in parts by weight is preferably 1: 2.2 to 1: 3.7, more preferably 1: 2, 7 to 1: 3.6.
- the matrix powders can be prepared in a manner known per se by atomizing metal or alloy or partial alloy melts.
- the alloy is applied during application (for example, by spray coating) of the cermet powders.
- Preferred cobalt, nickel and / or iron partial alloy matrix powders are prepared by chemical precipitation by reaction of corresponding salts with excess oxalic acid, drying and thermal treatment according to DE 198 22 663 A1 respectively.
- US 6,554,885 B1 won, with chromium is added as metal powder.
- Particularly suitable modifiers are steel substrate refining elements such as Mo, Nb, Si, W, Ta and / or V.
- the matrix metal or matrix alloy powders are free of further constituents.
- the present invention also relates to a cermet having the above-described composition and a molded article coated with such a cermet.
- the one or more hard material powders and the one or more matrix powders and modifying agents with optionally different average particle sizes are slurried in an aqueous solution of an organic binder in a manner known per se, and by means of Homogenized mixed grinding in a ball mill, an attritor or a stirrer, and the suspension is sprayed in a spray dryer, wherein the water evaporates from the spray droplets.
- the resulting powder agglomerate is converted into a nominal grain by means of a classification process (screening, screening) and the organic binder of the agglomerate is converted by sintering at a temperature of up to about 1300 ° C., in particular 1100 ° C. to 1300 ° C., in a hydrogen-containing atmosphere.
- the resulting sinter cake is returned to the nominal grain band by conditioning (breaking, milling, sieving).
- a tungsten carbide powder having a particle size of 0.9 ⁇ m determined by FSSS, having a carbon content of 6.1% by weight and a free carbon content of 0.05% by weight was used.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Plasma & Fusion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Powder Metallurgy (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Coating By Spraying Or Casting (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL07803590T PL2066822T3 (pl) | 2006-09-22 | 2007-09-21 | Proszki cermetowe |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102006045481A DE102006045481B3 (de) | 2006-09-22 | 2006-09-22 | Metallpulver |
PCT/EP2007/060058 WO2008034902A1 (de) | 2006-09-22 | 2007-09-21 | Metallpulver |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2066822A1 EP2066822A1 (de) | 2009-06-10 |
EP2066822B1 true EP2066822B1 (de) | 2018-09-12 |
Family
ID=38834997
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07803590.4A Active EP2066822B1 (de) | 2006-09-22 | 2007-09-21 | Cermetpulver |
Country Status (15)
Country | Link |
---|---|
US (1) | US9856546B2 (ko) |
EP (1) | EP2066822B1 (ko) |
JP (1) | JP5502481B2 (ko) |
KR (1) | KR101554047B1 (ko) |
CN (2) | CN104745998A (ko) |
AU (1) | AU2007298940A1 (ko) |
DE (1) | DE102006045481B3 (ko) |
DK (1) | DK2066822T3 (ko) |
ES (1) | ES2690126T3 (ko) |
IL (1) | IL197368A0 (ko) |
MX (1) | MX2009002908A (ko) |
PL (1) | PL2066822T3 (ko) |
RU (1) | RU2009114860A (ko) |
WO (1) | WO2008034902A1 (ko) |
ZA (1) | ZA200901578B (ko) |
Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
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DE102006045481B3 (de) | 2006-09-22 | 2008-03-06 | H.C. Starck Gmbh | Metallpulver |
JP5638185B2 (ja) * | 2007-04-06 | 2014-12-10 | 山陽特殊製鋼株式会社 | 溶融亜鉛浴部材の表面被覆用材料とその製造方法並びにその部材の製造方法 |
WO2010101215A1 (ja) * | 2009-03-05 | 2010-09-10 | 昭和電工株式会社 | 炭素繊維凝集体、及びその製造方法 |
JP5676161B2 (ja) * | 2010-07-02 | 2015-02-25 | 株式会社フジミインコーポレーテッド | 溶射用粉末及び溶射皮膜の形成方法 |
CN102373357B (zh) * | 2010-08-19 | 2013-09-18 | 比亚迪股份有限公司 | 一种金属陶瓷组合物及其制备方法、一种金属陶瓷和一种雷蒙磨 |
DE102011112435B3 (de) | 2011-09-06 | 2012-10-25 | H.C. Starck Gmbh | Cermetpulver, Verfahren zur Herstellung eines Cermetpulvers, Verwendung der Cermetpulver, Verfahren zur Herstellung eines beschichteten Bauteils, Beschichtetes Bauteil |
CN104039483B (zh) | 2011-12-30 | 2017-03-01 | 思高博塔公司 | 涂层组合物 |
US9169538B2 (en) * | 2012-05-31 | 2015-10-27 | National Tsing Hua University | Alloy material with constant electrical resistivity, applications and method for producing the same |
DE102013220040A1 (de) | 2013-10-02 | 2015-04-02 | H.C. Starck Gmbh | Gesinterte Spritzpulver auf Basis von Molybdänkarbid |
CN104120376B (zh) * | 2014-06-21 | 2016-06-01 | 上海君山表面技术工程股份有限公司 | 耐腐蚀辊及其制造方法 |
CN104060147B (zh) * | 2014-06-21 | 2016-06-01 | 上海君山表面技术工程股份有限公司 | 耐腐蚀涂层及其制备方法 |
CN104388794A (zh) * | 2014-10-22 | 2015-03-04 | 苏州莱特复合材料有限公司 | 硬质合金复合材料及其制备方法 |
CN104451340A (zh) * | 2014-10-27 | 2015-03-25 | 苏州莱特复合材料有限公司 | 一种金属陶瓷复合材料及其制备方法 |
JP6550227B2 (ja) * | 2014-10-31 | 2019-07-24 | トーカロ株式会社 | 溶射用粉末、溶射皮膜の製造方法、溶射皮膜、及びロール |
JP6550226B2 (ja) | 2014-10-31 | 2019-07-24 | トーカロ株式会社 | 溶射用粉末、溶射皮膜の製造方法、溶射皮膜、及びロール |
KR101922159B1 (ko) * | 2014-11-04 | 2018-11-27 | 현대중공업 주식회사 | 피스톤 스커트부 코팅재 조성물 및 이를 이용한 피스톤 스커트부의 코팅방법 |
CA2997367C (en) | 2015-09-04 | 2023-10-03 | Scoperta, Inc. | Chromium free and low-chromium wear resistant alloys |
CN105441936A (zh) * | 2015-11-11 | 2016-03-30 | 刘昭晖 | 高速钢锥柄麻花钻涂层工艺技术 |
KR101842158B1 (ko) * | 2016-01-14 | 2018-03-26 | 영창인물 (주) | 성능 및 수명이 향상된 프릭션쏘오 및 그 제조 방법 |
CN105695834A (zh) * | 2016-02-20 | 2016-06-22 | 杨鑫 | 一种成型凹模 |
US11085106B2 (en) * | 2016-04-15 | 2021-08-10 | Sandvik Intellectual Property Ab | Three dimensional printing of cermet or cemented carbide |
CN105821367B (zh) * | 2016-04-28 | 2018-02-23 | 宁国市开源电力耐磨材料有限公司 | 一种金属基体耐磨耐蚀耐高温复合材料表面涂层及其制备方法 |
CN106398329B (zh) * | 2016-08-30 | 2019-07-26 | 江苏同庆车辆配件有限公司 | 一种铁路棚车用门挡板 |
CN106398527B (zh) * | 2016-08-30 | 2019-02-26 | 江苏同庆车辆配件有限公司 | 一种铁路棚车内衬材料复合板 |
CN108823479A (zh) * | 2018-07-07 | 2018-11-16 | 河源市极致知管信息科技有限公司 | 一种金属陶瓷及其制备方法 |
AU2019363613A1 (en) | 2018-10-26 | 2021-05-20 | Oerlikon Metco (Us) Inc. | Corrosion and wear resistant nickel based alloys |
CN110846545B (zh) * | 2019-10-30 | 2021-04-20 | 武汉拓普准晶新材料有限公司 | 一种用粉石英矿生产的用于3d打印的金属陶瓷复合材料及其制备方法 |
JP7383498B2 (ja) | 2020-01-14 | 2023-11-20 | 日本特殊合金株式会社 | 超微粒超硬合金の製造方法 |
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JP2005068515A (ja) | 2003-08-26 | 2005-03-17 | Hitachi Tool Engineering Ltd | 微粒超硬合金 |
JP4399248B2 (ja) * | 2003-12-25 | 2010-01-13 | 株式会社フジミインコーポレーテッド | 溶射用粉末 |
JP2005305449A (ja) * | 2004-04-16 | 2005-11-04 | Sumitomo Metal Ind Ltd | 熱間加工用工具 |
JP2005320557A (ja) * | 2004-05-06 | 2005-11-17 | Daido Steel Co Ltd | 耐摩耗性部材およびその製造方法 |
ATE383450T1 (de) | 2005-11-22 | 2008-01-15 | Mec Holding Gmbh | Werkstoff für teile oder beschichtungen, die verschleiss oder reibung ausgesetzt sind, verfahren zu deren herstellung und verwendung des werkstoffes in einer vorrichtung zur drehmomentreduzierung bei bohrstrangkomponenten |
EP1857204B1 (en) | 2006-05-17 | 2012-04-04 | MEC Holding GmbH | Nonmagnetic material for producing parts or coatings adapted for high wear and corrosion intensive applications, nonmagnetic drill string component, and method for the manufacture thereof |
DE102006045481B3 (de) | 2006-09-22 | 2008-03-06 | H.C. Starck Gmbh | Metallpulver |
-
2006
- 2006-09-22 DE DE102006045481A patent/DE102006045481B3/de not_active Expired - Fee Related
-
2007
- 2007-09-21 KR KR1020097006818A patent/KR101554047B1/ko active IP Right Grant
- 2007-09-21 CN CN201510106676.3A patent/CN104745998A/zh active Pending
- 2007-09-21 US US12/441,938 patent/US9856546B2/en active Active
- 2007-09-21 ES ES07803590.4T patent/ES2690126T3/es active Active
- 2007-09-21 EP EP07803590.4A patent/EP2066822B1/de active Active
- 2007-09-21 CN CNA2007800349114A patent/CN101517109A/zh active Pending
- 2007-09-21 MX MX2009002908A patent/MX2009002908A/es unknown
- 2007-09-21 AU AU2007298940A patent/AU2007298940A1/en not_active Abandoned
- 2007-09-21 DK DK07803590.4T patent/DK2066822T3/en active
- 2007-09-21 WO PCT/EP2007/060058 patent/WO2008034902A1/de active Application Filing
- 2007-09-21 JP JP2009528736A patent/JP5502481B2/ja active Active
- 2007-09-21 PL PL07803590T patent/PL2066822T3/pl unknown
- 2007-09-21 RU RU2009114860/02A patent/RU2009114860A/ru not_active Application Discontinuation
-
2009
- 2009-03-03 IL IL197368A patent/IL197368A0/en unknown
- 2009-03-05 ZA ZA200901578A patent/ZA200901578B/xx unknown
Non-Patent Citations (1)
Title |
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None * |
Also Published As
Publication number | Publication date |
---|---|
AU2007298940A1 (en) | 2008-03-27 |
DE102006045481B3 (de) | 2008-03-06 |
IL197368A0 (en) | 2009-12-24 |
RU2009114860A (ru) | 2010-10-27 |
US9856546B2 (en) | 2018-01-02 |
CN104745998A (zh) | 2015-07-01 |
ZA200901578B (en) | 2010-05-26 |
PL2066822T3 (pl) | 2019-01-31 |
ES2690126T3 (es) | 2018-11-19 |
DK2066822T3 (en) | 2018-10-29 |
EP2066822A1 (de) | 2009-06-10 |
KR20090053941A (ko) | 2009-05-28 |
JP5502481B2 (ja) | 2014-05-28 |
MX2009002908A (es) | 2009-03-31 |
JP2010504426A (ja) | 2010-02-12 |
WO2008034902A1 (de) | 2008-03-27 |
US20100047622A1 (en) | 2010-02-25 |
KR101554047B1 (ko) | 2015-09-17 |
CN101517109A (zh) | 2009-08-26 |
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