Classifications

• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
  • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
  • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
  • A01N43/38—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
  • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
  • A01N41/10—Sulfones; Sulfoxides
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
  • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
  • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
  • A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof

Definitions

• the present invention relates to novel drug combinations which consist of known cyclic ketoenols on the one hand and other known insecticidal agents on the other hand and are very suitable for controlling animal pests such as insects and unwanted acarids.
• Trichogramma spp. known from The Pesticide Manual, 1 lth Edition, 1997, p. 1236 and / or
• insecticidal and / or acaricidal action of the active compound combinations according to the invention is substantially better than the effects of the previously known mixtures of WO 02/19824, WO 05/004603, WO 05/053405 and DE-A-05008033 consisting of cis / trans isomer mixtures of the formula Ia or II-a and one of the compounds mentioned there.
• the active ingredient combinations may also contain other fungicidal, acaricidal or insecticidal Zumischkomponenten beyond.
• the active ingredients in the active compound combinations according to the invention are present in certain weight ratios, the improved effect is shown.
• the weight ratios of the active ingredients in the drug combinations can be varied within a relatively wide range.
• the combinations according to the invention contain active compounds of the formula (I) or (II) and the mixing partner in the preferred and particularly preferred mixing ratios indicated in the table below:
• the active compound combinations according to the invention are suitable for controlling animal pests, preferably arthropods and nematodes, in particular insects and arachnids, in vineyards and fruit growing, in the garden, in agriculture, animal health in forests, in the supply and material protection and in the hygiene sector occurrence. They are effective against normally sensitive and resistant species as well as against all or individual stages of development.
• animal pests preferably arthropods and nematodes, in particular insects and arachnids, in vineyards and fruit growing, in the garden, in agriculture, animal health in forests, in the supply and material protection and in the hygiene sector occurrence. They are effective against normally sensitive and resistant species as well as against all or individual stages of development.
• the above-mentioned pests include: From the order of isopods, e.g. Oniscus asellus, Armadillidium vulgaris, Porcellio scaber.
• Thysanura e.g. Lepisma saccharina.
• Orthoptera e.g. Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp., Schistocerca gregaria.
• Phthiraptera e.g. Pediculus humanus corporis, Haematopinus spp.
• Linognathus spp. Trichodectes spp., Damalinia spp.
• Thysanoptera e.g. Herculothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella accidentalis.
• Heteroptera e.g. Eurygaster spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus, Triatoma spp.
• Lepidoptera e.g. Pectinophora gossypiella, Bupalus piniarius, Cheimatobia brumata, Lithocolletis blancardella, Hyponomeuta padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, Lymantria spp., Bucculatrix thurberiella,
• Hymenoptera e.g. Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.
• Diptera e.g. Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Calliphora erythrocephala, Lucilia spp., Chrysomyia spp., Cuterebra spp., Gastrophilus spp., Hyppobosca spp., Stomoxys spp.
• Oestrus spp. Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Oscinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratitis capitata, Dacus oleae, Tipula paludosa, Hylemyia spp.
• siphonaptera e.g. Xenopsylla cheopis, Ceratophyllus spp.
• arachnids e.g. Scorpio maurus, Latrodectus mactans, Acarus siro, Argas spp., Ornithodoros spp., Dermanyssus gallinae, Eriophyes ribis, Phyllocoptruta oleivora, Boophilus spp., Rhipicephalus spp., Amblyomma spp., Hyalomma spp., Ixodes spp., Psoropts spp , Chorioptes spp., Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa, Panonychus spp., Tetranychus spp., Hemitarsonemus spp., Brevipalpus spp.
• Scorpio maurus Latrodectus mactans, Acarus siro, Argas spp., Orni
• the plant parasitic nematodes include, for example, Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp., Bursaphelenchus spp.
• the active compound combinations can be converted into the customary formulations, such as solutions, emulsions, wettable powders, suspensions, powders, dusts, pastes, soluble powders, granules, suspension-emulsion concentrates, active substance-impregnated natural and synthetic substances and ultrafine encapsulations in polymeric substances.
• formulations are prepared in a known manner, e.g. by mixing the active compounds with extenders, ie liquid solvents and / or solid carriers, if appropriate using surface-active agents, ie emulsifiers and / or dispersants and / or foam-forming agents.
• Suitable liquid solvents are essentially: aromatics, such as xylene, toluene, or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or
• Paraffins e.g. Petroleum fractions, mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
• Suitable solid carriers are:
• ammonium salts and ground natural minerals such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic minerals, such as finely divided silica, alumina and silicates, as solid carriers for granules in question: eg broken and fractionated natural rocks such Calcite, marble, pumice, sepiolite, dolomite and synthetic granules of inorganic and organic flours and granules of organic material such as sawdust, coconut shells, corn cobs and tobacco stalks;
• suitable emulsifiers and / or foam formers are: for example nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example alkylaryl polyglycol ethers, alkylsulfonates, alkyl sulfates, arylsulfonates and also hydrolysates; suitable dispers
• adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex-like polymers, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids, such as
• Kephalins and lecithins and synthetic phospholipids may be mineral and vegetable oils.
• Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
• inorganic pigments e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
• the formulations generally contain between 0.1 and 95% by weight of active compound, preferably between 0.5 and 90%.
• the active compound combinations according to the invention can be prepared in commercial formulations and in the forms of application prepared from these formulations
• Bactericides Bactericides, acaricides, nematicides, fungicides, growth regulating substances or
• Herbicides present.
• the insecticides include, for example, phosphoric acid esters,
• the active compound combinations according to the invention may also be present when used as insecticides in their commercial formulations as well as in the formulations prepared from these formulations in admixture with synergists. Synergists are
• the active substance content of the application forms prepared from the commercial formulations can vary within wide ranges.
• the drug concentration of Use forms may range from 0.0000001 to 95% by weight of active ingredient, preferably between 0.0001 and 1% by weight.
• the application is done in a custom forms adapted to the application.
• plants are understood as meaning all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants).
• Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant varieties which can or can not be protected by plant breeders' rights.
• Plant parts are to be understood as meaning all aboveground and underground parts and organs of the plants, such as shoot, leaf, flower and root, by way of example, leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds and roots, tubers and rhizomes ,
• the plant parts also include crops and vegetative and generative
• Propagating material such as cuttings, tubers, Rhiozome, offshoot and seeds.
• the treatment according to the invention of the plants and plant parts with the active compound combinations takes place directly or by acting on their environment, habitat or storage space according to the usual treatment methods, e.g. by dipping, spraying, vaporizing, atomizing, spreading, spreading and in propagation material, in particular in seeds, further by single or multi-layer wrapping.
• plants and their parts can be treated.
• wild-type or plant species obtained by conventional biological breeding methods such as crossing or protoplast fusion
• plant cultivars and their parts are treated.
• transgenic plants and plant cultivars which have been obtained by genetic engineering methods if appropriate in combination with conventional methods (Genetically Modified Organisms), and parts thereof are treated.
• the term "parts” or “parts of plants” or “plant parts” has been explained above.
• Treated plant varieties Depending on the plant species or plant cultivars, their location and growth conditions (soils, climate, vegetation period, diet), the treatment according to the invention may also give rise to superadditive ("synergistic") effects.
• superadditive superadditive
• reduced application rates and / or enhancements of the activity spectrum and / or an enhancement of the effect of the substances and compositions which can be used according to the invention are better.
• Plant growth increased tolerance to high or low temperatures, increased tolerance to dryness or soil salt content, increased flowering efficiency, easier harvesting, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products, higher shelf life and / or Machinability of the harvested products possible, beyond the actually expected
• the preferred plants or plant varieties to be treated according to the invention to be treated include all plants which, as a result of the genetic engineering modification, obtained genetic material which gives these plants particularly advantageous valuable properties ("traits"). Examples of such
• Characteristics include better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or soil salt content, increased flowering efficiency, easier harvesting, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products, higher shelf life and / or workability of the harvested products. Further and particularly emphasized examples of such properties are an increased defense of the plants against animal and microbial pests, as against insects, mites, phytopathogenic fungi, bacteria and / or viruses as well as an increased tolerance of the plants against certain herbicidal active substances. Examples of transgenic plants are the important crops, such as cereals (wheat, rice), corn, soy, potato,
• Cotton, oilseed rape and fruit plants (with the fruits apples, pears, citrus fruits and grapes) are mentioned, whereby maize, soy, potato, cotton and oilseed rape are particularly emphasized. Traits which are particularly emphasized are the increased defense of the plants against insects by toxins which are formed in the plants, in particular those which are produced by the genetic material from Bacillus thuringiensis (for example by the genes Cry ⁇ A (a), Cry ⁇ A (b), Cry ⁇ A (c), CryllA, CrylllA, CryIIIB2, Cry9c Cry2Ab, Cry3Bb and CrylF and combinations thereof) are produced in the plants (hereinafter "Bt plants”).
• Plant plants are maize varieties, cotton varieties, soybean varieties and potato varieties which are sold under the trade names YIELD GARD® (eg corn, cotton, soya), KnockOut® (eg maize), StarLink® (eg maize), Bollgard® ( Cotton), Nucotn® (cotton) and NewLeaf® (potato).
• herbicide-tolerant plants are maize varieties, cotton varieties and soybean varieties, which are sold under the trade names Roundup Ready® (tolerance to
• Glyphosate e.g. Corn, cotton, soy
• Liberty Link® tolerance to phosphinotricin, e.g., rapeseed
• IMI® tolerance to imidazolinone
• STS® tolerance to sulfonylureas, e.g., corn.
• Herbicide-resistant plants also include the varieties sold under the name Clearfield® (e.g., corn). Of course, these statements also apply to future or future marketed plant varieties with these or future developed genetic traits.
• the listed plants can be treated particularly advantageously according to the invention with the active compound mixture according to the invention.
• the preferred ranges given for the mixtures above also apply to the treatment of these plants. Particularly emphasized is the plant treatment with the mixtures specifically mentioned in the present text.
• X means the degree of killing, expressed in% of the untreated control, when using the active substance A at a rate of m g / ha or in a concentration of m ppm,
• Y means the degree of killing, expressed in% of the untreated control, when using the active ingredient B in an application rate of n g / ha or in a concentration of n ppm
• E means the degree of killing, expressed in% of the untreated control, when using the active compounds A and B at application rates of m and n g / ha or in a concentration of m and n ppm,
• Killing over-additive ie there is a synergistic effect.
• the actually observed kill rate must be greater than the expected kill rate (E) value calculated from the above formula.
• Emulsifier 2 parts by weight of alkylaryl polyglycol ether
• Part by weight of active compound with the stated amounts of solvent and emulsifier and the concentrate is diluted with emulsifier-containing water to the desired concentration.
• Cotton leaves (Gossypium herbaceum), which are heavily infested by the cotton aphid ⁇ Aphis gossypii), are treated by being dipped into the preparation of active compound of the desired concentration.
• the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed.
• the determined kill values are calculated according to the Colby formula.
• Emulsifier 0.5 part by weight of alkylaryl polyglycol ether
• active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
• Cabbage leaves that are heavily infested with the green peach aphid ⁇ Myzus persicae are desired by spraying with the active ingredient preparation
• the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed.
• the determined kill values are calculated according to the Colby formula.
• Emulsifier 2 parts by weight of alkylaryl polyglycol ether
• Part by weight of active compound with the stated amounts of solvent and emulsifier and the concentrate is diluted with emulsifier-containing water to the desired concentration.
• Cabbage leaves ⁇ Brassica oleracea) which are heavily infested with the green peach aphid ⁇ Myzus persicae) are treated by spraying with the preparation of active compound of the desired concentration.
• the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed.
• the determined kill values are calculated according to the Colby formula.
• Emulsifier 0.5 part by weight of alkylaryl polyglycol ether
• active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
• Cabbage leaves (Brassica oleraceä) are treated by spraying with the preparation of active compound in the desired concentration and are populated with larvae of the horseradish leaf beetle ⁇ Phaedon cochleariae) while the leaves are still moist.
• the kill is determined in%. 100% means that all beetle larvae have been killed; 0% means that no beetle larvae have been killed.
• the determined kill values are calculated according to the Colby formula.
• Emulsifier 2 parts by weight of alkylaryl polyglycol ether
• Part by weight of active compound with the stated amounts of solvent and emulsifier and the concentrate is diluted with emulsifier-containing water to the desired concentration.
• Cabbage leaves (Brassica olerace®) are treated by dipping in the preparation of active compound with the desired concentration and with larvae of the cabbage moth
• the kill is determined in%. 100% means that all caterpillars have been killed; 0% means that no caterpillars have been killed.
• the determined kill values are calculated according to the Colby formula.
• Emulsifier 0.5 part by weight of alkylaryl polyglycol ether
• active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
• Cabbage leaves (Brassica oleracea) are treated by spraying with the preparation of active compound in the desired concentration and are populated with larvae of the armyworm ⁇ Spodoptera frugiperda) while the leaves are still moist.
• the kill is determined in%. 100% means that all caterpillars have been killed; 0% means that no caterpillars have been killed.
• the determined kill values are calculated according to the Colby formula.
• Emulsifier 2 parts by weight of alkylaryl polyglycol ether
• Part by weight of active compound with the stated amounts of solvent and emulsifier and the concentrate is diluted with emulsifier-containing water to the desired concentration.
• Cabbage leaves (Brassica oleraceä) are treated by dipping in the active compound preparation at the desired concentration and with larvae of the armyworm
• the kill is determined in%. 100% means that all caterpillars have been killed; 0% means that no caterpillars have been killed.
• the determined kill values are calculated according to the Colby formula.
• Emulsifier 0.5 part by weight of alkylaryl polyglycol ether
• active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
• Bean leaf discs Phaseolus vulgaris
• Triticae Triticae
• the effect is determined in%. 100% means that all spider mites have been killed; 0% means that no spider mites have been killed.
• Test insect Diabrotica balteata - larvae in soil
• Emulsifier 2 parts by weight of alkylaryl polyglycol ether
• the preparation of active compound is poured onto the ground.
• the concentration of the active ingredient in the preparation plays virtually no role, the only decisive factor is the
• Emulsifier 2 parts by weight of alkylaryl polyglycol ether
• Active substance with the stated amount of solvent and the stated amount of emulsifier and the concentrate is diluted with water to the desired concentration.
• Soybean shoots (Glycine max) of the variety Roundup Ready (trademark of Monsanto Comp. USA) are treated by spraying with the preparation of active compound in the desired concentration and are populated with the tobacco budworm Heliothis virescens while the leaves are still moist.
• the kill of the insects is determined.
• Emulsifier 2 parts by weight of alkylaryl polyglycol ether
• active compound 1 part by weight of active compound is mixed with the stated amount of solvent and the stated amount of emulsifier and the concentrate is diluted with water to the desired concentration.
• Transgenic cabbage plants (Brassica oleracea) which are heavily infested with the green peach aphid Myzus persicae are treated by spraying with the preparation of active compound in the desired concentration.
• the kill of the insects is determined.

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• Life Sciences & Earth Sciences (AREA)
• Agronomy & Crop Science (AREA)
• Pest Control & Pesticides (AREA)
• Plant Pathology (AREA)
• Health & Medical Sciences (AREA)
• Engineering & Computer Science (AREA)
• Dentistry (AREA)
• General Health & Medical Sciences (AREA)
• Wood Science & Technology (AREA)
• Zoology (AREA)
• Environmental Sciences (AREA)
• Agricultural Chemicals And Associated Chemicals (AREA)

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• 2006
  • 2006-07-11 DE DE102006031978A patent/DE102006031978A1/de not_active Withdrawn
• 2007
  • 2007-07-06 EP EP07765106A patent/EP2043438A1/de not_active Withdrawn
  • 2007-07-06 US US12/373,166 patent/US20100113437A1/en not_active Abandoned
  • 2007-07-06 CN CNA2007800259809A patent/CN101489384A/zh active Pending
  • 2007-07-06 JP JP2009518764A patent/JP2009542743A/ja active Pending
  • 2007-07-06 KR KR1020097002191A patent/KR20090028800A/ko not_active Application Discontinuation
  • 2007-07-06 BR BRPI0714184-0A patent/BRPI0714184A2/pt not_active IP Right Cessation
  • 2007-07-06 WO PCT/EP2007/005993 patent/WO2008006512A1/de active Application Filing
  • 2007-07-06 MX MX2009000015A patent/MX2009000015A/es unknown

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