Classifications

• • G—PHYSICS
  • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
  • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
  • G03G7/00—Selection of materials for use in image-receiving members, i.e. for reversal by physical contact; Manufacture thereof
  • G03G7/0006—Cover layers for image-receiving members; Strippable coversheets
  • G03G7/002—Organic components thereof
  • G03G7/0026—Organic components thereof being macromolecular
• • G—PHYSICS
  • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
  • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
  • G03G7/00—Selection of materials for use in image-receiving members, i.e. for reversal by physical contact; Manufacture thereof
  • G03G7/006—Substrates for image-receiving members; Image-receiving members comprising only one layer
  • G03G7/0073—Organic components thereof
  • G03G7/008—Organic components thereof being macromolecular
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
  • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
  • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
  • Y10T428/24934—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including paper layer

Definitions

• Olefin polymer coated substrates for electrophotographic printing process are Olefin polymer coated substrates for electrophotographic printing process
• the invention relates to a process for printing substrates, characterized in that the substrates are pretreated with a composition which contains a polymer obtainable by free-radical polymerization of ethylenically unsaturated compounds (monomers) (hereinafter referred to as polymer for short), and at least 40% by weight of the monomers are olefins.
• a composition which contains a polymer obtainable by free-radical polymerization of ethylenically unsaturated compounds (monomers) hereinafter referred to as polymer for short
• polymer ethylenically unsaturated compounds
• An essential feature of electrophotographic printing processes is that electrostatically charged dye systems, so-called toners, are used and an electrostatic charge image is generated, which can be developed in different ways.
• dry toner ie toner which is solid at room temperature and becomes liquid only at relatively high temperatures of about 130 ° C under heat
• liquid toner toner having a very low melting point having
• Electrostatic printing processes with a liquid toner are also referred to as LEP (liquid electrostatic printing) or indigo printing processes.
• the toner adhesion to paper in the LEP process is often insufficient.
• WO 96/06384 describes the improvement of the adhesion of the liquid toner to paper substrates by treating the surface with substances which have a basic functionality, exclusively and preferably polyethyleneimines (PEI), ethoxylated PEI, epichlorohydrine polyethyleneimines and polyamides being mentioned.
• PEI polyethyleneimines
• ethoxylated PEI ethoxylated PEI
• epichlorohydrine polyethyleneimines and polyamides being mentioned.
• a major disadvantage of this treatment method is the whitening (loss of whiteness) and the yellowing of the paper in longer storage.
• mixtures of salts are used to impart an alkaline pH to the paper surface, which in turn provides improved printability through liquid toner
• salts eg, aluminate salts or weak acid salts and a strong base
• WO 2004/092483 the surface treatment of paper with a combination of starch, an acrylic acid polymer and another organic compound, for.
• a polyglycerol ester described. The use of the polyglycerol ester is considered essential to achieve good toner fixation.
• WO 2005/033155 describes amino group-containing ethylene copolymers. A surface treatment of paper is not mentioned.
• the object of the present invention was the improvement of the electrostatic printing process, in particular the LEP process.
• the task was also to provide suitable substrates for such printing processes.
• the best possible fixation of the liquid toner on different paper grades should be made possible.
• an essential feature of the invention is that the substrates are pretreated with a composition which contains a polymer obtainable by free-radical polymerization of ethylenically unsaturated compounds (monomers) (hereinafter referred to as polymer for short) and is at least 40% by weight. % of the monomers are olefins.
• the polymer consists of at least 40 wt .-%, preferably at least 60 wt .-% and particularly preferably at least 80 wt .-% of olefins.
• the olefins are, in particular, ethylene, propylene or isobutylene or mixtures thereof. Preferred is ethylene.
• the polymer may be a homopolymer of the above monomers, in particular polyethylene.
• the polymer may contain other monomers in addition to the olefins.
• the polymer in addition to the olefins, contains monomers having primary, secondary, tertiary or quaternary amino groups. Preference is given to amino groups with tertiary or quaternary amino groups. The latter are cationic groups, the associated anion is z. To the anion of hydrogen acids, such as the chloride anion or sulfate anion.
• quaternary amino groups obtainable by polymer-analogous reaction of a primary or secondary amino group with an alkylating agent RX, wherein R is selected from benzyl, C1-C10 alkyl, and X is selected from halogen and R-SO4.
• the polymer is preferably composed of
• the polymer preferably has a weight-average molecular weight M w in the range from 1000 to 500,000, in particular from 1000 to 200,000, particularly preferably from 1000 to 100,000, particularly preferably from 1000 to 60000 g / mol and in a particular embodiment from 2000 to 50,000 g / mol ,
• the polymer is preferably present as an aqueous dispersion or solution.
• Suitable monomers (b) are those of any desired amino groups.
• the amino group may also be part of a heterocyclic ring system, for.
• it may be N-vinylimidazole.
• (B) is preferably a comonomer which has at least one alkylated or cycloalkylated amino group which is in each case connected via a spacer to a polymerizable group.
• the alkylated or cycloalkylated amino group of comonomer (b) may be mono- or poly-alkylated or cycloalkylated. If it is desired to copolymerize a plurality of comonomers (b), the various comonomers (b) may have identical or different spacers or may have the same or different polymerizable groups or carry the same or different alkyl groups or cycloalkyl groups on the amino group (s). It is also conceivable within the scope of the present invention that at least one comonomer (b) has two or more alkylated or cycloalkylated amino groups, which are each connected via a spacer to a polymerizable group. In a preferred embodiment, at least one comonomer (b) corresponds to the general formula I.
• R 1 and R 2 are the same or different
• R 1 is selected from hydrogen and
• Ci-Cio-alkyl such as methyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl, sec-butyl, tert-butyl, n-pentyl, iso-pentyl, sec Pentyl, neo-pentyl, 1,2-dimethylpropyl, iso-amyl, n-hexyl, iso-hexyl, sec-hexyl, n-heptyl, n-octyl, 2-ethylhexyl, n-nonyl, n-decyl; particularly preferably C 1 -C 4 -alkyl, such as methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl and tert-butyl, in particular methyl;
• R 2 is selected from unbranched and branched C 1 -C 10 -alkyl, such as, for example, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl, n-pentyl, iso -Pentyl, sec-pentyl, neo-pentyl, 1,2-dimethylpropyl, iso-amyl, n-hexyl, iso-hexyl, sec-hexyl, n-heptyl, n-octyl, 2-ethylhexyl, n-nonyl , n-decyl; particularly preferably C 1 -C 4 -alkyl such as methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl and
• R 3 are different or preferably identical and selected from hydrogen and branched and preferably unbranched Ci-Cio-alkyl, for example methyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl, sec-butyl, tert.
• C 3 -C 12 -cycloalkyl such as cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, cyclononyl, cyclodecyl, cycloundecyl and cyclododecyl; preferred are cyclopentyl, cyclohexyl and cycloheptyl where two radicals R 3 can be joined together to form a 3- to 10-membered, preferably 5- to 7-membered ring optionally substituted by C 1 -C 4 -alkyl radicals,
• an N (R 3 ) 2 group can be selected from
• radicals R 3 are different, then one of the radicals R 3 may be hydrogen.
• X is selected from sulfur, NR 4 and especially oxygen.
• R 4 is selected from straight-chain and branched C 1 -C 10 -alkyl, for example methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl, n-pentyl, iso -Pentyl, sec-pentyl, neo-pentyl, 1,2-dimethylpropyl, iso-amyl, n-hexyl, iso-hexyl, sec-hexyl, n-heptyl, n-octyl, 2-ethylhexyl, n-nonyl , n-decyl; particularly preferably C 1 -C 4 -alkyl such as methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl and tert-but
• a 1 is selected from divalent groups such as
• Ci-Cio-alkylene such as -CH 2 -, -CH (CH 3 ) -, - (CH 2 ) 2 -, -CH 2 -CH (CH 3 ) -, cis- and trans-CH (CH 3 ) -CH (CH 3 ) -, - (CH 2 ) 3 -, -CH 2 -CH (C 2 H 5 ) -, - (CH 2 ) 4 -, - (CH 2 ) 5 -, - (CH 2 ) 6 -, - (CH 2 ) / -, - (CH 2 ) 8 -, - (CH 2 ) 9 -, - (CH 2 ) io-; preferably C 2 -C 4 alkylene; such as - (CH 2 ) 2 -, -CH 2 - CH (CH 3 ) -, - (CH 2 ) 3 -, - (CH 2 ) 4 - and -CH 2 -
• Phenylene for example ortho-phenylene, meta-phenylene and most preferably para-phenylene.
• R 1 is hydrogen or methyl. Most preferably, R 1 is methyl.
• R 1 is hydrogen or methyl and R 2 is hydrogen.
• R 1 is hydrogen or methyl and R 2 is hydrogen, both R 3 are the same and are each methyl or ethyl.
• XA 1 -N (R 3 ) 2 is O-CH 2 -CH 2 -N (CHa) 2 .
• XA 1 -N (R 3 ) 2 is O-CH 2 -CH 2 -CH 2 -N (CH 3 ) 2 .
• the amine group in formula I can also be present as a qutarenary amine group and z. B. by reaction with an alkylating agent.
• ethylene copolymer waxes according to the invention contain no further copolymerized comonomers.
• the polymer contains at least one further comonomer in copolymerized form.
• Preferred further copolymerized comonomers are, for example, isobutene and (meth) acrylic esters, in particular alkyl (meth) acrylates.
• the polymers have a melt flow rate (MFR) in the range of 1 to 500 g / 10 min, preferably 5 to 200 g / 10 min, more preferably 7 to 50 g / 10 min, measured at 160 ° C and a load of 325 g according to DIN 53735.
• MFR melt flow rate
• the polymers have a catalytic melt viscosity v in the range of 500 to 10,000 mm 2 / s, preferably in the range of 800 to 4000 mm 2 / s, measured according to DIN 51562.
• the melting ranges of the polymers are in the range from 60 to 115.degree. C., preferably in the range from 65 to 110.degree. C., determined by DSC according to DIN 51007.
• the melting ranges of the polymers may be broad and relate to a temperature interval of at least 5 to at most 20 ° C, preferably at least 7 ° C to at most 15 ° C.
• the melting points of the polymers are sharp and are in a temperature range of less than 2 ° C, preferably less than 1 ° C, determined according to DIN 51007.
• the density of the polymers is 0.89 to 1.10 g / cm 3 , preferably 0.92 to 0.94 g / cm 3 , determined according to DIN 53479.
• the polymers may be alternating copolymers, block copolymers or preferably random copolymers.
• the polymers can advantageously by free-radically initiated copolymerization of olefins, in particular ethylene, and optionally the other monomers under
• High pressure conditions are produced.
• the polymerization process is carried out, for example, in stirred high-pressure autoclaves or in high-pressure tubular reactors or in combinations or in combinations of high-pressure autoclave and high-pressure tubular reactor, which are connected in series.
• the implementation in stirred high pressure autoclave is preferred.
• Suitable pressure conditions for the polymerization process according to the invention are 500 to 4000 bar, preferably 1500 to 2500 bar. Conditions of this type are also referred to below as high pressure.
• the reaction temperatures are in the range of 170 to 300 ° C, preferably in the range of 195 to 280 ° C.
• the copolymerization can be carried out in the presence of at least one regulator.
• the regulator used is, for example, hydrogen or at least one aliphatic aldehyde or at least one aliphatic ketone of the general formula III
• radicals R 5 and R 6 are the same or different and selected from
• Ci-C ⁇ -alkyl such as methyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl, sec-butyl, tert-butyl, n-pentyl, iso-pentyl, sec-pentyl, neo -Pentyl, 1, 2-dimethylpropyl, iso-amyl, n-hexyl, iso-hexyl, sec-hexyl, more preferably CrC 4 -AlkVl such as methyl, ethyl, n-propyl, iso-propyl, n-butyl, iso Butyl, sec-butyl and tert-butyl;
• C 3 -C 12 -cycloalkyl such as cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, cyclononyl, cyclodecyl, cycloundecyl and cyclododecyl; preferred are cyclopentyl, cyclohexyl and cycloheptyl.
• R 5 and R 6 are covalently linked together to form a 4- to 13-membered ring.
• R 6 and R 7 may be in common: - (CH 2 ) 4 -, - (CH 2 ) S-, - (CH 2 ) B, - (CH 2 ) / -, -CH (CHa) -CH 2 -CH 2 - CH (CH 3 ) - or -CH (CHa) -CH 2 -CH 2 -CH 2 -CH (CH 3 ) -.
• Suitable regulators are furthermore alkylaromatic compounds, for example toluene, ethylbenzene or one or more isomers of xylene.
• suitable regulators are also paraffins such as isododecane (2,2,4,6,6-pentamethylheptane) or isooctane.
• the customary free radical initiators such as organic peroxides, oxygen or azo compounds can be used. Also mixtures of several radical starters are suitable.
• tert-butyl peroxybenzoate di-tert-amyl peroxide, dicumyl peroxide, the isomeric di- (tert-butylperoxyisopropyl) benzenes, 2,5-dimethyl-2,5-di-tert-butylperoxyhexane, tert-butylcumyl peroxide, 2, 5-dimethyl-2,5-di (tert-butylperoxy) -hex-3-yne, di-tert-butyl peroxide, 1,3-diisopropylbenzene monohydroperoxide, cumene hydroperoxide or tert-butyl hydroperoxide; or
• radicals R 7 to R 12 are identical or different and selected from
• d-Cs-alkyl such as methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl, isobutyl, tert-butyl, n-pentyl, sec-pentyl, isopentyl, n-hexyl, n-heptyl, n-octyl; preferably linear Ci-C ⁇ -alkyl such as methyl, ethyl, n-propyl, n-butyl, n-pentyl, n-hexyl, particularly preferably linear CrC 4 -AlkVl such as methyl, ethyl, n-propyl or n-butyl, very particularly preferred is methyl and ethyl;
• C 6 -C 4 aryl such as phenyl, 1-naphthyl, 2-naphthyl, 1-anthryl, 2-anthryl, 9-anthryl, 1-phenanthryl, 2-phenanthryl, 3-phenanthryl, 4-phenanthryl and 9-phenanthryl Phenyl, 1-naphthyl and 2-naphthyl, more preferably phenyl.
• Peroxides of the general formulas Ml a to IM c and processes for their preparation are known from EP-A 0 813 550.
• peroxides are di-tert. Butyl peroxide, tert-butyl peroxypivalate, tert-butyl peroxyisone nonanoate or dibenzoyl peroxide or mixtures thereof are particularly suitable.
• azo compound azobisisobutyronitrile ("AIBN") is mentioned as an example Radical starters are metered in amounts customary for polymerizations.
• AIBN azobisisobutyronitrile
• Radical starters are metered in amounts customary for polymerizations.
• Many commercially available organic peroxides are added to so-called phlegmatizers before they are sold to make them more manageable. For example, white oil or hydrocarbons, in particular isododecane, are suitable as phlegmatizers.
• such phlegmatizers can have a molecular-weight-regulating effect.
• the use of molecular weight regulators should be understood as the additional use of further molecular weight regulators beyond the use of such phlegmatizers.
• the quantitative ratio of comonomers at the dosage usually does not correspond exactly to the ratio of the units in the polymer.
• the one or more comonomers and olefins can be dosed together or separately.
• the polymerization process may optionally be carried out in the absence and in the presence of solvents, with mineral oils, white oil and other solvents present in the reactor during the polymerization and used to quench the radical initiator or initiators not being considered solvents in the context of the present invention.
• solvents are, for example, toluene, isododecane, isomers of xylene.
• the polymers are obtained, from which it is advantageously possible to remove residual monomer which is still present, for example with the aid of an extruder.
• polymers having units derived from the monomers (b) are prepared by preparing polymers by copolymerization of ethylene and at least one comonomer having a functional group and then reacting them in a polymer-analogous reaction with at least one Substance having at least one alkylated or cycloalkylated amino group and a spacer to which a reactive group depends, which is capable of reacting with the functional group on at least one copolymerized comonomer.
• a catalyst preferably an acidic catalyst
• Y is selected from OH and OR 13 and R 13 is C 1 -C 4 -alkyl, such as methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl and tert-butyl.
• copolymerization of ethylene with at least one comonomer with functional group can be carried out as above.
• the polymer-analogous reaction can be carried out, for example, in a solvent.
• ionic polymers are also suitable. These are z. B. obtainable by reacting polymers with Br ⁇ nsted acid.
• the amino groups contained in the polymers are partially or completely protonated.
• Suitable Br ⁇ nsted acids are, for example, aqueous mineral acids such as hydrohalic acids, for example HCl, HBr, Hl, HF, H 2 SO 4 , H 3 PO 4 , HCIO 4 , HNO 3 ; Acids of pseudohalogens such as HSCN and isocyanic acid, acid salts such as alkali hydrogen sulfates, for example KHSO 4 and NaHSO 4 , Alkalidihydro- gengen such as NaH2PO4 and KH2PO4, organic acids such as CH 3 OSO 3 H, formic acid, acetic acid, oxalic acid or citric acid.
• hydrohalic acids for example HCl, HBr, Hl, HF, H 2 SO 4 , H 3 PO 4 , HCIO 4 , HNO 3
• Acids of pseudohalogens such as HSCN and isocyanic acid
• acid salts such as alkali hydrogen sulfates, for example KHSO 4 and NaHS
• the polymer may, for. B. in an autoclave or a kettle and heated, are at least one Bronsted acid and optionally other substances, such as water, to, with the order of addition of Bronsted acid or Bronsted acids and optionally other substances is arbitrary. Homogenize the resulting emulsion, for example by mechanical or pneumatic stirring or by shaking. It is advantageous to heat to a temperature above the melting point of the polymer or polymers. Advantageously is warmed to a temperature of at least 10 ° C, particularly advantageous to a temperature which is at least 30 ° C above the melting point of the polymers.
• so much Bransted acid or Br ⁇ nsted acids are added that at least half, preferably at least 60, mol% of the amino groups of the polymer (s) are protonated.
• Polymers with quaternary amino groups are z. B. obtainable by reaction of polymers with an alkylating agent R 11 -Z, wherein R 11 z. B. is selected from benzyl and C 1 -C 10 -alkyl and in particular benzyl and methyl, and Z is selected from halo gen, preferably chlorine, bromine or iodine, and R 11 SO 4 .
• the amino groups present in the polymers are partially or completely alkylated (quaternized).
• so much alkylating agent is added that at least half, preferably at least 60, preferably 100%, of the amino groups of the polymer are alkylated to give quaternary amino groups.
• the above preparation process gives solutions or dispersions, preferably aqueous solutions or dispersions of the polymers.
• solutions or dispersions of the polymers preferably have pH values of from 1 to 6.5, more preferably from 1.5 to 5.
• solutions or dispersions of the polymers having quaternary amino groups are preferably in the pH range from 7 to 10, preferably from 8 to 9.5.
• the solids content of the solutions or dispersions can be selected within wide limits. Suitable solids contents are, for example, 0.1% by weight to 50% by weight. To other components
• the composition also contains starch in addition to the polymer.
• Strength in this context should be understood as meaning any native, modified or degraded starch.
• Native starches may consist of amylose, amylopectin or mixtures thereof.
• Modified starch may be oxidized starch, starch ester or starch ether.
• Anionic, cationic, amphoteric or nonionic modified starch may be considered.
• the molecular weight of the starch can be reduced (degraded starches) As degradation products are oligosaccharides or dextrins into consideration.
• the strength can come from different sources, it can, for. B. cereals corn or potato starch, in particular z.
• Potato starch or modified or degraded potato starch is preferred.
• the composition contains 10 to 100 parts by weight, particularly preferably 50 to 100% by weight of polymer and 90 to 0 parts by weight, particularly preferably 50 to 0% by weight, based on 100 parts by weight of the sum of polymer and strength.
• composition may contain other ingredients, suitable additives are e.g. As described in WO 2004/092483; is called z. B. Polygylcerinester.
• aqueous composition in particular a composition in which the polymer and optionally the starch are dissolved or dispersed.
• composition can be applied to the substrates to be printed by customary methods, preferably processes in which the composition does not or hardly diffuses into the substrate, eg. B. Order with the film press, by spraying or by curtain coating).
• the solids content of the aqueous composition may, for. B. 2 to 70 wt .-%, preferably 10 to 60 wt .-% amount.
• the substrates pretreated with the composition are preferably printed in an electrophotographic printing process.
• An essential feature of electrophotographic printing processes is that electrostatically charged dye systems, so-called toners, are used and an electrostatic charge image is generated, which can be developed in different ways.
• LEP liquid electrostatic printing
• indigo printing process is particularly preferred.
• An essential feature of this printing process is the use of a liquid toner which is present at room temperature (20 ° C.) as a liquid or as a viscous paste.
• the temperature at which the toner is fixed on the substrate is relatively low compared to other electrostatic methods and is e.g. B. between 40 and 100 0 C.
• the substrate to be printed it may, for. B. is paper or polymer film.
• uncoated paper ie base paper, which is not coated with a paper coating slip, but other paper grades can also be treated with it in order to improve the adhesion of the liquid toner.
• the substrate to be printed may also be wood-free paper.
• the substrate to be printed is pretreated with the composition, in particular coated (see above).
• the amount of the composition is preferably 0.05 g / m 2 to 15 g / m 2 (solid), preferably 0.1 g / m 2 to 5 g / m 2 (solid.
• DMAEMA dimethylaminoethyl methacrylate
• ID isododecane (2,2,4,6,6-pentamethylheptane)
• PO tert-amyl peroxypivalate
• EC ethylene copolymer
• PO in ID solution of tert.
• Amyl peroxypivalate in isododecane c (PO) concentration of PO in ID in mol / l
• content is meant the proportion of polymerized ethylene or DMAEMA in the respective copolymer.
• v kinetic melt viscosity measured at 120 ° C according to DIN 51562.
• the content of ethylene and DMAEMA in the copolymers 1.1, 1.2 and 1. 3 was determined by 1 H-NMR spectroscopy. The density was determined in accordance with DIN 53479. The melting point T me ⁇ t or melting range was determined by DSC (differential scanning calorimetry, differential thermal analysis) determined according to DIN 51007.
• the printing tests were carried out on a Hewlett-Packard Indigo Digital Printing Machine 3000.
• the toner adhesion was carried out according to the tape pull method (DIN V EN V 12283) with a 3M # 230 adhesive tape. To this end, the adhesive tape was adhered bubble-free to the printed surface and then withdrawn at a constant speed at an angle of almost 180 °.
• the color density of the print was determined by means of a densitometer and indicated as a value in the result table.
• the determination of the toner adhesion or the color density after the picking test was carried out after certain time intervals (immediately / 1 min / 10 min / 1 h / 24 h).

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• Spectroscopy & Molecular Physics (AREA)
• General Physics & Mathematics (AREA)
• Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
• Laminated Bodies (AREA)
• Paper (AREA)

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• 2007
  • 2007-05-16 WO PCT/EP2007/054732 patent/WO2007135040A1/de active Application Filing
  • 2007-05-16 CN CNA2007800188837A patent/CN101454725A/zh active Pending
  • 2007-05-16 EP EP07729180A patent/EP2030085A1/de not_active Withdrawn
  • 2007-05-16 US US12/301,618 patent/US20090258204A1/en not_active Abandoned
  • 2007-05-16 JP JP2009511470A patent/JP2009537354A/ja active Pending

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