EP1922398A1 - Consumer products having varying odor patterns - Google Patents

Abstract

Conventional, perfumed consumer products, such as e.g. washing powders, have a uniform odor throughout the entire product, which remains substantially the same during application. The invention relates to odorized consumer products which are capable of developing different odor patterns that can be separately detected. The leading edge concept of consumer products having odor dynamics allows the consumer to experience, using one and the same product, different odors during a single application, e.g. during manual dishwashing, thereby completely breaking the limited range and monotony of odors associated with conventional, perfumed consumer products.

Description

 6 007953

"Consumable products with changing odor images"

The present invention relates to a perfume-containing consumer product, in which in the course of the application of the product distinguishable and separately perceptible odor images occur, for example a product in which at least two differently fragrant Par- fumole contained, which are odorously distinguishable dominant in the application of the product

The consumer product can be any commercially applicable, perfumed product, but above all products from the field of detergents and cleaners and cosmetics

The use of fragrances in typical consumer products such as detergents usually serves two different purposes. On the one hand, the products should be scented as such, on the other hand, the objects on which the products are to be scented. or detergent should give the freshly cleaned surfaces or freshly washed laundry in most cases a "freshly cleaned" olfactory impression that should last as long as possible, on the other hand, the sometimes quite strong odor of detergents and cleaners should be covered

For many consumers, the fragrance of the consumer product, eg a washing or cleaning agent, ultimately also provides a welcome opportunity for differentiation in the face of an ever more confusing supply of products, for example in the field of detergents and cleaners

Since many consumers, for example, see in the scent of their detergent or cleaning agent also contribute to increasing their well-being and personal comfort, many washing and Remungsmittelmittelhersteller now serve the consumer need for a wide range of detergents or cleaning agents with different fragrances So there are z Whole Produktlmien from the field of detergents and cleaning agents, such as Textilweichspuler, which differ essentially only by the scent offered and are gathered under the same brand name

The fragrance fulfills very specific consumer preferences. Thus, for example, for the same roof product, for example for a textile softener, usually diverse fragrance forms such as "almond and honey", "peach and lime blossom", "wild rose", "orchid and lotus - Blood ¹ or z B "White tulip and tender mint" etc so that the consumer can then select the product according to his individual sensitivities and preferences However, the problem remains the odor monotony in connection with one and the same consumer product and its application

The object underlying the present invention is therefore to provide the consumer with a need for fragrance variety an improved offer

This object is achieved by a perfume-containing consumer product, in which in the course of the application of the product distinguishable odor images occur, which are separately perceptible The distinctive odor images occur preferably in chronological order

The term "in the course of the application" covers the widest possible arc of an application The starting point of an application is in the context of the invention, the Hernähme of the consumer product and the opening of the packaging of the consumer product to this its destination under the example of the application "textile wash" this would be Taking a bottle of liquid detergent and opening the bottle This is followed by steps such as measuring a certain quantity of liquid, etc. The first odor image is formed when the bottle is opened, because then fragrances emanate from the open bottle Context of the invention in terms of time significantly after the concrete use of the consumer product are the example of the application "textile wash" this would be, for example, the time at which the washed laundry was dried, eg by hanging on a leash The dried wash unfolded in general a characteristic odor picture, which then becomes weaker and weaker over time. The odor images of the starting point (middle odor) and end point (odor of dry wash) could be different, for example

Using the example of manual dishwashing, the starting point of the application would be to open the dishwashing bottle and the endpoint of the application would be reached in the broadest sense when both dishes and hands are dry again. The odor images from the starting point (middle odor, eg freshness odor) and end point (Smell of dry hands, such as cream odor) could be different for example

The fact that the odor images are odorily distinguishable when using the product should advantageously mean that not only a single, uniform odor image results in the application, but that at least two different odor images are distinctive, which are perceptible separately, advantageously temporally and / or or locally separated For example, once a fresh smell is formative, another time a creamy smell The distinguishable odor images may be linked to the progress of the application, preferably

(a) in the concrete application act (= actual use of the consumption product) and / or

(b) immediately upon completion of the specific application act and / or

(c) different smell patterns occur after the application act This corresponds to a preferred embodiment

In this case, the distinguishable odor images with respect to

(a) the product itself,

(b) the object treated therewith and / or

(c) the treatment medium occur This corresponds to a preferred embodiment

This makes it clear that the odor image of the actual consumption product is also an original odor image, which occurs when the product is used in the context of the invention

A product according to the invention can combine at least two functions, preferably a cleaning function and a care function. This corresponds to a preferred embodiment. It is perfectly clear that appropriate ingredients must be present in the product. However, the selection of these ingredients poses no problems for the person skilled in the art For example, B can name a large number of ingredients with a cleansing or care effect

The product according to the invention may contain at least one perfume containing fragrances which, when the product is used, are at least partially dominant in odor in such a way that distinguishable odor images occur. This corresponds to a preferred embodiment

According to a preferred embodiment, in a product according to the invention at least two differently fragrant perfumes A and B are contained, which are dominant in the course of the use of the product odorily distinguishable

A perfume oil is then dominant in the sense of the invention if it imprints the respectively present odor image

Em consumption product typically has a single uniform odor image which within this odor image according to the invention a Parfumol can be dominant If this consumption product is now supplied in the context of application of a specific use (eg perfumed washing powder which is used for machine textile washing here object = textiles medium = water ), a new odor image can occur and according to the invention another For example, the odor image of the washed, wet wash may be dominated by this other perfume. In other words, this may mean the greatest possible simplification. The product smells differently than the object treated with it or the medium in use relative to a washing powder that is, that it exudes a different smell than the washed wet or dry wash or as the wash liquor

If the differently perfumed perfumes each comprise at least 2 or more fragrances, then there is a further preferred embodiment of the invention

According to a preferred embodiment, the perfumes are in a chronological order odorably distinguishable dominant

The fact that the perfumes are odorably distinguishable dominant in time, should preferably mean that the different fragrant perfume advantageously not simultaneously determine the odor image, but that in the course of application first a first Parfumol characterizes the odor, then later a second, if necessary later third, but advantageously not as a mere function of time, but as a result of the progress of the application

This is the example of a so-called 2-ιn-1 detergent explained 2-ιn-1 detergents as such are already available on the market for a long time They commonly combine the cleaning power of a normal detergent with an additional softening effect in only one product The marketable 2-ιn However, detergents are usually distinguished by a single, uniform perfume, which also acts uniformly on the objects to be treated. Medium, wet and also dry laundry thus smell essentially the same. In connection with the application, essentially the same odor always occurs

In contrast, there is a 2-ιn-1 detergent in the context of the invention such as may contain, for example, two differently perfumed perfume, which may be odorily distinguishable dominant in the application means that in connection with such a detergent different, distinguishable odor images are generated This can be realized according to a first illustrative example, for example in such a way that the actual product (2-ιn-1 detergent) smells different (odor image 1) than the treated with this product wash (odor image 2) This can according to a second illustrative example z be realized in such a way that both the actual product (2-ιn-1 detergent) and the freshly washed wet laundry smell differently (each odor image 1) than the then dried wash (odor image 2) odor image 1 would be essentially characterized by Parfumol 1 whereas odor image 2 essentially consists of parfumol 2 would be significant In these illustrative examples, first the perfume 1 is dominant, namely based on the product fragrance (illustrative example 1) or based on the product fragrance and the smell of wet laundry (illustrative example 2), each having the odor image 1 With progression of the application then parfumol 2 is dominant, namely based on the smell of wet laundry (illustrative example 1) or based on the smell of dry laundry (illustrative example 2) In this way, it is thus possible to produce 2-n-1 detergents which have or form distinct odor images on application, the odor images are separately perceived

For example, a corresponding detergent as such have a pronounced citrus fragrance Even washed with such a detergent wash may then have this citrus scent in the freshly washed state, the dry laundry can then but smell creamy B. The odor images "citrus fragrance" and "cream Fragrance "are obviously distinguishable by smell and also separately perceptible, namely once as" citrus fragrance "and the other times as" cream fragrance "

According to a preferred embodiment, the dominance of a perfume may be linked to the progression of the application, the perfume being preferably

(a) in the concrete application act (= actual use of the consumption product) and / or

(b) immediately upon completion of the specific application act and / or

(c) distinctively dominant after the act of application

"Immediately at the completion of the concrete application act" is a term that is based on the particular application In the machine textile laundry, this is the period in which you open the washing machine and removes the wet laundry, which then z B. To dry on the Leash is hanging

"After the application act" is a term which is oriented to the respective application. In the case of machine textile washing, this means, for example, the point in time from which the dry laundry is present. The actual application act is therefore already clearer than at its immediate termination

According to a preferred embodiment, the perfume based on the actual product so treated objects and / or the treatment media odorily distinguishable dominant

Advantageously, the perfume oils which can be used in each case are characterized by at least one specific perfume note, which at least temporarily can form the conductive odor, in particular selected from (a) green notes, corresponding to an odor perception of leaves, meadows and / or grass, the scent impression is also referred to as fresh / balsamic and advantageously comprises light, cool notes,

(B) Flowery notes, here the general fragrance description is directed to terms such as flowery-fruity, fresh and / or sweet

(c) Aldehyde notes They have points of contact with flowery and woody notes

(d) Chypre notes, where the general description of the fragrance is directed to terms such as fruity-mossy-aldehyde, floral-mossy-animal, mossy-fruity. These notes may have a special accent due to complementary dry, algige, woody, mossy notes receive

(e) Oriental notes, which mainly mean heavy sweet and spicy scents rounded off by animal notes

(Tj Citrus notes, usually have a refreshing character, for example, may consist of the essential oils of citrus fruit

(l) notes of lavender, usually have a pleasant fresh sweet-balsamic to herbaceous odor, sometimes with floral-woody nuances

(h) Fougere notes (fern notes) are related to the chypre notes

(ι) spice notes, which are accompanied by an odor of spices, such as thyme, pepper nutmeg, cinnamon, cloves, ginger, marjoram, cardamom, coriander, etc ..

(j) Woody notes associated with an odor perception of wood, such as cedar, sandalwood, from herb-fresh to woody-herb

(k) tobacco notes, in variations from fπsch-tart-nutritious to heavy-sweet-honιgartιg,

(I) Leather notes, reminiscent of the smell of leather goods

The example of a detergent according to the invention in the context of the invention has been advantageously used at least two such different perfume oils, which are generally associated with certain impressions A parfumol should advantageously associate with impressions such as "cleanliness" and "freshness", which in general with the Use of detergents to be associated The other Parfumol, however, should advantageously support the impression of "care"

Perfume compositions which are capable of imparting fragrance impressions in the direction of "cleanliness" and "freshness" are well known to the person skilled in the art because almost all detergents or cleansers are perfumed in such a way that the consumer perceives the corresponding fragrance as "fresh" and the so that scented surfaces or surfaces perceive as 'clean' Often it is even the case that the consumer is subjectively convinced of an adequate purity performance only if it is accompanied by suitable scenting

In the context of this invention, preferred fragrances which can be used to advantage in order to give the impression of "cleanliness" and "freshness" are bergamot oil, tangezene oil, dimethyl anthranilate, aldehyde C 11 (s), dihydromyrcenol, 4-tert-butylcyclohexyl acetate, allylamyl glycolate, tetrahydrolinalool, 6-methylgammonone, isobomylacetate, cyclovertal, ethylnalool, aldehyde C 12, dynascone 10, limonene, Orange oil, isobromyl acetate, eucalyptus oil (globulus), calone, cyclovertal, ethyl-2-methyl butyrate, tetrahydrolinalool, aldehyde C 10, styrolyl acetate, otbca, waterfruit base, citronitπl, undecavertol, styrolyl acetate, tartalide and / or dihydro-methyl jasmonate, but in particular Dihydromyrcenol and / or 4-tert-butylcyclohexylacetate Preferred perfume oils may thus comprise at least one of the aforementioned fragrances

Perfume compositions which are capable of imparting fragrance impressions in the direction of a "nourishing agent" are also familiar to the person skilled in the art, since, for example, all softeners, which are supposed to serve the washing care, are perfumed in such a way that the consumer receives the corresponding fragrance with ideas associated with a care effect and thus perceived laundry perceived as well groomed Preferably, this perfume composition is applied to a betonite-bearing carrier

In the context of this invention preferred fragrances which can be used in this sense to enhance the impression of a "nourishing effect" are aldehyde C 14, decalactone gamma, cyclamen aldehyde, lilial, troenan, canthoxal, citronellol, geraniol, musk , Phenylethyl alcohol, dihydroflophones, dmbca, phenirate, phenylethyhsobutyrate, rose oxide, jasmeha, hexylcinnamaldehyde (alpha), ionone beta, ylang, cyclohexylsahcylate, hexenylsalicylate (cis-3), sandelice, santobar, bacdanol, guaiacolite, Iso E Super, Timberol (forte) , Norlimbanol, ambroxan, cinnamyl alcohol, cyclopentadecanolides, nirvanol, javanol, aldehyde C 11, halohanolides, maltol, benzylacetone, coumarin, benzyl salicylate, melonal, galbanum (oil), ethyl vanillin, koavone, Ptbca 25 ice, hedione, lilial, dihydroflophones, Isoraldem, methyl palmitate, methyl oleate and / or methyl myristate. Preferred perfume oils may thus comprise at least one of the aforementioned fragrances and are preferably one em betonithaltigen carrier applied

According to a further preferred embodiment, the product according to the invention contains at least one fragrance, preferably 2, 3 or more fragrances from the list Galaxohd, Dihydromyrcenol, 4-tert-Butylcyclohexylacetat, gamma-iso-methylionone, tetrahydro-hnalool, Hexylcmna- maldehyd, Lilial, Linalool, Amylcmnamaldehyd, 6-methyl-gamma-ιonon, methyl oleate, neryl acetate, 15-pentadecalactone, Phenoxyethyhsobutyrat, phenylethylmethanoate, a-Pιnene, b-Pιnene, rose oxides, Sabinene, anethole, benzoic acid 2-hydroxy-pentyl ester, diphenyl ether, benzophenone , Cyclamen aldehyde, a-damascone, decanal, dicyclopentadiene, alcohol, allylcyclohexylpropionate, isoboronyl acetate, bornylacetate, dihydromethyljasmonate, eucalyptol, n-dodecanol, ethyl palmitate, geraniol acetate, hexyl acetate, n-hexyl salicylate, a-ionone, methyl palmitate, 2- Naphthylmethylketone, isopropylmagnate, rosephenone, α-terpιneol, styrallyl acetate, thujops, dimethylbenzylcarbinyl butyrate, d-limonene, dimethylbenzylcarbinylacetate, citronello l, 2-tert-butylcyclohexanol, caryophyllene, ethyl stearate, tartalide, 2,4-hexadienal, methanoazulene, methyl laurate, methylmyrate, 2-methylundecanal, Myrcene, nonanal, nopyl acetate, 15-pentadecalactone, beta-phellandrene, 3-phenyl-2-methylpropene, rosacetate, Traseohde, Widdrene and / or d-Lmonen

According to the spirit of the invention, there are also in the cosmetics sector preferred product categories, eg

(a) 2-in-1 shower gels, preferably nourishing shower gels, the latter being shower gels, which serve to cleanse the skin but also care for the skin, for example with jerk-moisturizing substances

(b) 2-in-1 hair shampoos, preferably hair care shampoos, the latter being hair shampoos which serve for hair cleansing but which also contain a conditioning component

(c) 2-in-1 bubble bath, preferably Pflegeschaumbad

(d) 2-in-1 soap, preferably cream soap

(e) 2-in-1 hand dishwashing agent, preferably hand-care dishwashing agent

A hand-caring dishwashing agent is a preferred embodiment of the invention Hand-care dishwashing contain, for example jerkfettende substances and assets to care for the act of dishwashing, so that, for example, can be dispensed with the use of rubber gloves and it is not necessary to cream the skin later A dishwashing agent according to the invention now preferably contains at least two differently perfumed perfumes, which are dominant in chronological order. Parfumol 1 is preferably dominant with respect to the odor of the actual agent and the dishwashing water, ie, both the detergent and the dishwashing liquid smell, for example, perfumeol 2 then dominant in the further temporal sequence, namely after done spool work, ie the hands with which was spooled, smell after care The effect of the agent, namely to ensure a care effect of the hands, can therefore smell The hands smell to delight the consumer, for example, as if they were freshly creamed

Preferably, the dominant perfume provides the consumer with a clear signal, such as "freshness", "purity" or "care"

Preferably, one of the perfumes is dominant in the product, that is, it imprints the odor image of the product, and advantageously another is perfumol

(A) in the concrete application dominant z B in the process of dishwashing the hair washing and / or

(b) dominant immediately upon completion of the application, eg, characterizes the odor of freshly washed wet laundry or the odor of freshly-washed, damp dishes

(c) significantly dominates clearly after use z B the smell of dry laundry or the smell of the hands after the dishwasher work While perfume oils are generally perfume mixtures, they advantageously form a uniform, recognizable odor image, ie they are preferably associated with a uniform scent impression

According to a preferred embodiment, at least two constituents of a perfumeol are differently dominant on different substrates, for example on dishes vs. human skin

As can be seen, the invention can provide the consumer in particular in the field of detergents and cleaners and cosmetics, so that according to a preferred embodiment, a product according to the invention contains ingredients from the field of detergents, detergents and / or cosmetics

In the following, two illustrative examples are sketched in a brief form, with which the realization of the invention, ie a consumable product having a fragrance, in which distinguishable odor images occur in the course of the application of the product, which are separately perceptible, is illustrated in a practical manner

In the first illustrative example is a particulate detergent This consists of a normal washing powder which has been sprayed with a perfume 1 (citrus scent) In this washing powder small balls are mixed, which consist of a core, which consists of perfume 2 (cream fragrance ), which is encapsulated by a polymer These spheres are odor-neutral to the outside, only when the polymer is eliminated can a fragrance unfold The particulate detergent containing the spheres has per se the odor image "citrus fragrance" This is the smell, Under the conditions of textile washing, the spheres also lose their integrity, whether due to the mechanical load, be it by contact with water, or by reaching a certain temperature or a certain pH When Waschvorga ng is released so the Parfumol 2 This is in relation to Parfumol 1 dosed significantly higher, eg B in the ratio> 5 1 Thus, Parfumol 2 is clearly dominant in the following When the washing machine is opened unfolds a creamy smell, which also the dry laundry adheres

In the second illustrative example, it is a liquid washing detergent with small small spheres distributed uniformly in the product and neither creaming nor sinking. The liquid washing detergent as such contains in the liquid a perfume oil 1 (citrus fragrance) The small balls which consist of a core which consists of perfume oil 2 (cream fragrance) which is encapsulated by a polymer are odor-neutral to the outside, only when the polymer has disappeared, a fragrance can unfold The liquid detergent containing the globules per se has the odor (citrus fragrance) on This is the Smell the consumer at Under the conditions of the textile washing, the balls also contained lose their integrity, be it by the mechanical load, be it by contact with water, be it by reaching a certain temperature or a certain pH value during the washing process is released as the Parfumol 2 This is dosed in relation to Parfumόl 1 significantly higher, z B in the ratio> 5 1 Thus, Parfumol 2 is clearly dominant in the following When the washing machine is opened unfolds a creamy odor, which also adheres to dry laundry

The term parfumol preferably means self-contained perfume compositions, which are commonly used for product scenting and are fragrant in particular according to human discretion. This is illustrated by an example. If a professional, for example, makes a fragrant shower gel, he usually does not only add one to him (Fragrant substance, but a collective (well) rιechender substances in Em such collective usually consists of a variety of individual fragrances, for example more than 10 or 15, preferably up to 100 or more of these rich together form a desired fragrant, harmonious odor Such a group of fragrant substances, a fragrance composition which may possibly also contain perfume-like auxiliaries, is described according to the invention by the term parfumol. The words "self-contained" are intended to clarify that the constituents of a perfume do not generally comprise g Separate from each other, so not be perceived side by side, but form a common, uniform fragrance collective This everyone knows from his everyday view For example, a shower gel also unfolds a single characteristic scent, for example to lemon or a single mixed odor It usually does not develop multiple odors Separate from one another This would normally only be possible if two or more different shower gels were used separately

In an exceptional case, a perfume oil according to the invention can even consist of only a single perfume, which is extremely unusual and unlikely, but is within the scope of the invention. In the usual case, a perfume according to the invention (ie a perfume composition) consists of at least 2, preferably at least 3, advantageously at least 4 different fragrances, which together develop a preferably fragrant odor image

A perfume oil according to the invention can therefore contain individual perfume compounds, for example the synthetic products of the ester type, ethers, aldehydes, ketones, alcohols and hydrocarbons. Fragrance compounds of the ester type are, for example, benzyl acetate phenoxyethyl isobutyrate p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinyl acetate ( DMBCA), phenylethyl acetate benzyl acetate, ethylmethylphenylglycinate allylcyclohexylpropionate, styrallylpropionate benzylsalicylate cyclohexylsalicylate, floramate, melusate and jasmecyclate Pay to the ethers for example, benzyl ethyl ether and ambroxane, to the aldehydes z B the linear alkanals with 8 - 18 carbon atoms, citral, citronellal, citronellyloxy-acetaldehyde, cyclamen aldehyde, Lilial and Bourgeonal, to the ketones z B the Jonone, "-Isomethylionon and Methylcedrylketon , the alcohols include anethole, citronellol, eugenol, geraniol, linalool, phenylethyl alcohol and terpineol, the hydrocarbons include mainly the terpenes such as limonene and pmen. Preferably, however, mixtures of different fragrances are used, which together produce an appealing scent of the perfume formed

The perfume oils may also contain natural fragrance mixtures, such as those obtainable from vegetable sources, such as pine, citrus, jasmine, patchouli, rose or ylang-ylang oil. Also suitable are muscatel salvia, chamomile oil, clove oil, Mehssenol, mint oil, cinnamon leaf oil, linden blutenol, juniper berry oil, vetiverol, olibanumol, galbanumol and labdanumol, as well as orange blossom oil, Nerohol, orange peel sol and sandalwood oil

In order to be perceptible, a fragrance must be volatile, in addition to the nature of the functional groups and the structure of the chemical compound, the molecular weight also plays an important role So most fragrances have molecular weights up to about 200 daltons, while molecular weights of 300 daltons and more represent an exception Due to the different odor of fragrances, the smell of a fragrance composed of several fragrances changes during evaporation, whereby the odor impressions in "top note", "middle note or body" as well as " Base note "(end note or dry out)

Adhesive-resistant fragrances, which are advantageously usable in the present invention in the perfumoles, are, for example, the essential oils such as angelica root aol, anisole, amikablutenol, basilol, bayol, champacablutenol, edeltannenol, arctic pine oil, elemiol, eucalyptus oil, fenchelol, spruce nelderol, galbanumol, Geraniumol, gingergrasol, guaiacol, gurunbalsamol, helichrysumol, Ho oil, gingerol, indol, kajeputol, calmusol, chamomile oil, camphor oil, kanagaol, cardamomoleol, kassiaol, pine nadelol, copaivabalamol, koanderol, curledolzeol Kummelol, kuminol, lemongrasol, musk cornerol, myrrh oil , Clove oil, Nerohol, Niaculol, Olibanumol, Ongganumol, Palmarosaol, Patchouliol, Perubalsamol, Petitgrainol, Pepperol, Peppermintole, Pimentol, Pine oil, Rose oil, Rosmarynol, Sandalwood oil, Selleπeol, Starch anole, Thujaol, Thymianol, Verbenaol, Vetiverol, Juniper berry, Wermutol, wintergrunol, ylang-ylang oil, hyssop-ol cinnamon, cinnamon leafol as well as cyprus ssenol

But also the high-boiling or solid fragrances of natural or synthetic origin can be used in the context of the present invention advantageously as adherent fragrances or fragrance mixtures in the perfume oils to these compounds pay the compounds listed below and mixtures of these Ambrettolid α-Amylzιmtal- dehyde anethol anisaldehyde, anisalcohol , Anisole Anthranilic Acid Methyl Ester Acetophenone Benzyl acetone, benzaldehyde, ethyl benzoate, benzophenone, benzyl alcohol, borneol, bornyl acetate, α-bromostyrene, n-decyl aldehyde, n-dodecyl aldehyde, eugenol, eugenol methyl ether, eucalyptol, farnesol, fenchone, fenchyl acetate, geranyl acetate, geranyl formate, hehotropin, heptincarboxylic acid methylester , Heptaldehyde, hydroquinone di-methyl ether, hydroxycinnamaldehyde, hydroxycinnamyl alcohol, indole, iron, isoeugenol, isoeugenol methyl ether, isosafrole, jasmon, camphor, karvakrol, karst, p-cresolmethyl ether, coumarin, p-methoxyacetophenone, methyl-n -amyl ketone, methyl acrylate, p-methyl acetophenone, methyl chaviol, p-methylquinoline, methyl-.beta.-naphthyl ketone, methyl-n-nonylacetaldehyde, methyl n-nonyl ketone, Muskon, .beta.-naphtholethyl ether, .beta.-naphthol methyl ether, nerol , Nitrobenzene, n-nonylaldehyde, nonyl alcohol, n-octylaldehyde, p-oxy-acetophenone, pentadecanolide, β-phenylethyl alcohol, phenylacetaldehyde dimethyl acetal, phenylacetic acid, pulegone, safrole, salicylic acid isoamyl ester, Sahcylsau remethyl ester, salicylic acid hexyl ester, salicylic acid cyclohexyl ester, santalol, skatole, terpineol, thymes, thymol, γ-undelactone, vanilm, veratrum aldehyde, cinnamaldehyde, cinnamyl alcohol, cinnamic acid, cinnamic acid ethyl ester, cinnamic acid benzyl ester

Among the more easily perfumed fragrances, which are advantageously used in the context of the present invention in the perfume, pay in particular the lower-boiling fragrances of natural or synthetic origin, which can be used alone or in mixtures Examples of easily volatile fragrances are Alkyisothiocyanate (Alkylsenfole), butanedione , Limonene, linalool, malate acetate and propionate, menthol, menthone, methyl-n-heptenone, phellandrene, phenylacetaldehyde, terpinyl acetate, citral, citronellal

All of the aforementioned fragrances can be used alone or as a mixture in the perfume oils according to the present invention with the advantages already mentioned

In particular, fragrances from the group of allyl alcohol esters, esters of secondary alcohols, esters of tertiary alcohols, allylic ketones, acetals, ketals, condensation products of amines and aldehydes and / or mixtures thereof may be contained in the perfume

Allyl alcohol esters are the esters of allyl alcohol which has the following structural feature, C (OH) -C =C Examples of allyl alcohol esters are in particular allylamyl glycolate, allyl anthranilate, allyl benzoate, allyl butyrate, allyl caprate, allyl caproate, allyl cinnamate, allyl cyclohexane acetate, allylcyclohexane butyrate, allyl cyclohexane propionate, allyl heptoate, allyl nonanoate, Allylsalicylat, Amylcinnamyla- acetate, Amylcinnamylformiat, Cinnamylformiate, Cinnamylacetate, cyclogalbanate, geranyl acetate GSM eranylacetoacetat, geranyl benzoate, Geranylcinnamat, Methallylbutyrat, Methallylcaproat, Nerylace- did Nerylbutyrat, Amylcinnamylformiat, Alphamethylcinnamylacetat, tiglat Methylgeranyl, Mertenyl- acetate, farnesyl acetate fenchyl acetate, geranyl butyrate Geranylanthranilat, Gerany iso-butyrate geranyl caproate geranyl caprylate, geranyl ethyl carbonate geranyl formate, geranyl furoate geranylheptate geranyl methoxyacetate geranyl pelargonate geranyl phenylacetate geranyl phthalate geranyl propionate geranyl iso-propoxyaceta t, geranyl valerate Geranyhs-valerate, trans-2-hexenyl acetate trans-2-hexenyl butyrate, trans-2-hexenyl caproate, trans-2-hexenylphenylacetate, trans-2-hexenyl propionate, trans-2-hexenylti-glate, trans-2-hexenyl valerate, beta-pentenyl acetate, alpha-phenyl allyl acetate, Prenyl acetate, Tnchloromethylphenylcarbinylacetat and / or mixtures thereof Allylalkoho- lester may preferably be contained in the perfume according to the invention

Examples (for esters of secondary alcohols secondary alcohols are present if the C-atom which bears the OH group, two hydrogen atoms by organic moieties (R ¹ and R ² are substituted) [general formula R ¹ -CH (OH) R ² ]) are, in particular, ortho-tert-amylcyclohexyl acetate, isoamylbenzyl acetate, secondary n-amyl butyrate, amylvinylcarbinyl acetate, amylvinylcarbinylpropionate, cyclohexylsalicylate, dihydro-nor-cyclopentadienylacetate, dihydro-nor-cyclopentadienylpropylate, isobornylacetate, isobornylsalicylate, Isobomyl valerate, Frutene, 2-methylbutene-2-ol-4-acetate, methyl phenyl carbinyl acetate, 2-methyl-3-phenylpropan-2-yl acetate, prenyl acetate, 4-tert-butylcyclohexyl acetate, 1-dimethoxy (2- tert-butyl) butyl cyclohexyl acetate), Ieneverene (4-tert-butylcyclohexylacetate), Viohff (carboxylic acid 4-cycloocten-1-yl methyl ester), ethenylisoamylcarbinylacetate, fenchyl acetate, fenchyl benzoate, fenchyl n-butyrate, fenchyl isobutyrate, Laevo-menthyl acetate, dl-menthyl acetate, menthylanethranilate, ment butyl benzoate, menthyl isobutyrate, menthyl formate, levo-menthyl phenylacetate, methyl propionate, menthyl salicylate, menthyl iso-valerate, cyclohexyl acetates, cyclohexyl anthranilate, cyclohexyl benzoate, cyclohexyl butyrate, cyclohexyl isobutyrate, cyclohexyl caproate, cyclohexyl cinnamate, cyclohexyl formate, cyclohexylheptoate, cyclohexyl oxalate, cyclohexyl pelargonate, cyclohexyl phenylacetate, cyclohexyl propionate, cyclohexyl thioglycolate, cyclohexyl valerate, cyclohexyl isovalerate, methyl amylacetate, methylbenzylcarbinylacetate, methylbutylcyclohexanylacetate, 5-methyl-3-butyl-tetrahydropyran-4-yl acetate, methyl citrate, methyl isobutoxide. campholate, 2-methylcyclohexyl acetate, A-methylcyclohexyl acetate, 4-methylcyclohexylmethylcarbinyl acetate, methylethylbenzylcarbinylacetate, 2-methylheptanol-6-acetate, methylheptenylacetate, alpha-methyl-n-hexylcarbinylate, methyl-2-methylbutyrate, methylnonylcarbinylacetate, methylphenylcarbinylacetate, methylphenylcarbinylanthra- nilate, methylphenylcarbinylbenzoate , Me methylphenylcarbonynyl-n-butyrate, methylphenylcarbinylphenyl, caproate, methylphenylcarbinylcaprylate, methylphenylcarbinyl cinnamate, methylphenylcarbinylformate, methylphenylcarbinylphenylacetate, methylphenyl carbinylpropionate, methylphenylcarbinylsahcylate, methylphenylcarbinyl-iso-valerate, 3-nonanylacetate, 3-nonenylacetate, nonane dimethyl 2,3-acetate, nonynol acetate, 2-octanyl acetate, 3-octanyl acetate, n-octyl acetate, sec-octyl isobutyrate, beta-pentenyl acetate, alpha-phenylallyl acetate, phenylethylmethylcarbinyl iso-valerate, phenylethylene glycol diphenylacetate, phenylethyl ethylcarbamylacetate , Phenylglycoldiacetate, sec-phenylglycol monoacetate, phenylglycol monobenzoate, isopropylcaprate, isopropylcaproate, isopropylcaprylate isopropylcinnamate, para-isopropylcyclohexanylacetate, propylglycol diacetate, propylene glycol glycol isobutyrate, propylene glycol dipropionate, isopropyl n-heptoate, isopropyl-n-hept-1-yne carbonate Isopropyl pelargonate, isopropylpropionate, isopropylun decylenate, isopropyl n-valerate isopropyl n-valerate, isopropyl iso-valerate, isopropyl sebacinate isopulegyl acetate, isopulegyl acetoacetate isopulegly isobutyrate isopulegyl formate, thymyl propionate, alpha-2 4-trimethylcyclohexanemethylacetate trimethylcyclohexyl acetate vanillin acetate vanillyliden diacetate vanillylvanilate, and / or mixtures of these These esters may preferably be contained in the perfume according to the invention

Preferred examples of esters of tertiary alcohols (tertiary alcohols are those in which three H atoms are substituted by organic radicals R ¹ , R ² , R ³ at the α-C atom which carries the OH group (general formula R ¹ R ² R ³ C-OH)) are tertiary amyl acetate, Caryophylleneacetat Cedrenyl acetate, Cedrylacetat, Dihydromyrcenylacetat, Dihydroterpinylacetat, dimethylbenzyl carbmylacetat, Dimethylbenzylcarbinylisobutyrat, Dimethylheptenylacetat, Dimethylheptenyl formate, Dimethylhep- tenylpropionate, Dιmethylheptenyl-iso-butyrate, Dimethylphenylethylcarbinylacetat, dimethylphenyl ethylcarbιnyl iso-butyrate, dimethylphenylethylcarbinyl iso-valerate, dihydro-nor-dicyclopentadienyl acetate, dimethylbenzylcarbinylbutyrate, dimethylbenzylcarbylformate, dimethylbenzylcarbmylpropionate, dimethylphenylethylcarbinyl-n-butyrate, dimethylphenyletylcarbinylformate, dimethylphenyl-ethylcarbylpropionate, elemylacetate, ethynylcyclohexylacetate, eudesylacetate, eugenylcinnamate, eugenylfor formate, ethyl carbonate iso-eugenyl formate, Eugenylphenylacetat, Isoeudehylphenylacetat, Guaiylacetat, Hydroxycitronellyl, Linallylacetat, Linallylanthranilat, Linallylbenzoat, Linallylbutyrat, Linallyl losbutyrat, Linallylcarproat, Linallylcaprylat, Linallylcinnamat, Lmallylcitronellat, Linallyl formate, Linallylheptoat, Lιnallyl-N-methylanthranιlat, Lmallylmethyltiglat, Linallyl pelargonate , Linallyl phenylacetate, linallyl propionate, linallylpyruvate, linallyl acylate, vinylallyl-n-valerate, vinylallyvalvalate, methylcyclopentenolone butyrate, methylcyclopentenolonepropionate, methylethylphenylcarbinylacetate, methylheptincarbonate, methylnicotmat, myrcenylacetate, myrcenylformate, myrcenylpropionate, cis-ocylenate acetate, Phenylsahcylate, terpinyl acetate, terpinyl anthranilate, terpinyl benzoate, terphenyl-n-butyrate, terphenyl-butyrate, terpinyl cinnamate, terpinyl formate, terpinyl phenylacetate, terpinyl propionate, terpinyl n-valerate, terphenyl-valerate, butylpentyl acetyl citrate, and / or the mixtures thereof These esters may preferably be present in the perfume of the invention

Some fragrance esters may be both esters of allylic and secondary or allylic and tertiary alcohols, such as, in particular, amylvinylcarbinylacetate, amylvinylcarbinylpropionate, hexylvinylcarbinylacetate, 3-nonenylacetate, 4-hydroxy-2-hexenylacetate, linallylanthranilate, linallylbenzoate, linallylbutyrate, linallyliosbutyrate, linallyl carproate, linallyl caprylate, linallyl cinnamate, linallyl citronelate, linallyl formate, linallylheptoate, vinylallyl-N-methylanthranilate, imallylmethyltiglate, linallyl pelargonate, linalin phenylacetate, linallyl propionate, linallyl pyruvate, linallyl acylate, linallyl n-valerate, linalyl iso-valerate, myrtenyl acetate, Nerohdylacetate, Nerohdylbutyrat, beta-pentenyl acetate, alpha-phenylallylacetat, and / or mixtures thereof These esters may also be preferably contained in the inventive Parfumol

Allylic ketones are characterized by the following structural feature: C - C (= O) - C = C Preferred examples are acetylfuran, allethrolone allylionone, allylpulegone, amylcyclopentenone, benzylideneacetone, benzylideneacetophenone, alphaisomethylionone, 4- (2,6,6-tri-methyl-1-cyclohexene-1 -yl) 3-buten-2-one, beta-damascone (1- (2,6,6-t-methylcyclohexene-1-yl) -2-butene-1-one), damascenone (1- (2,6-tri-methyl) 1, 3-cyclohexadien-1-yl) -2-buten-1-one), Delta Damascon (1- (2,6,6-tri-methyl-3-cyclo) hexene-1-yl-2-butene-1-one), alpha-ionone (4- (2,6,6-tri-methyl-1-cyclohexenyl-1-yl) -3-butene-2-one), beta-ionone ( 4- (2,6,6-t-methyl-1-cyclohexen-1-yl) -3-butene-2-one), gamma methyl ionone, (4- (2,6,6-t-methyl-2-cyclohexyl-1 -yl) -3-methyl-3-buten-2-ones), pulegone and / or mixtures thereof Allylic ketones may preferably be present in the perfume according to the invention

Acetals are geminal diethers of the general formula R ¹ CH (OR ² ) (OR ³ ) Preferred examples are acetaldehyde-benzyl-beta-methoxyethyl acetal, acetaldehyde-dι-ιso-amyl acetal, acetaldehyde dι-pentaneιolacetal, acetaldehyde dι-n- propyl acetal, acetaldehyde-ethyl-trans-3-hexenyl acetal acetaldehyde-phenylethylene glycol acetal, acetaldehyde, phenylethyl-n-propyl acetal, cinnamic acid dimethyl acetal, acetaldehyde benzyl-beta-methoxyethyl acetal, acetaldehyde-1-yl-amyl acetal, acetaldehyde, diethyl acetal, acetaldehyde dι -cis-3-hexenyl acetal, acetaldehyde-dipentanediol acetal, acetaldehyde-d-n-propyl acetal, acetaldehyde-ethyl-trans-3-hexenyl acetal, acetaldehyde-phenyl-ethylene glycol acetal, acetaldehyde, phenylethyl-n-propyl acetal, acetylvanillin dimethyl acetal, Al - Pha-amylcιnnamιc aldehyde-dι-ιso-propyl acetal, p-tert-amyl phenoxy acetaldehydediethylacetal, Amsaldehydediethylacetal, Anisaldehydedimethylacetal, iso apiole, Benzaldehyddiethylacetal, benzaldehyde dι- (ethylenegly col monobutyl ether) acetal, benzaldehyde dimethylacetal, Benzaldehy- dethyleneglycolacetal, Benzaldehydglyceryl acetal, Benzaldehydepropylenglycolacetal, Cinnami- caldehyddiethylacetal, Citraldiethyl acetal, citral dimethyl acetal, Citralpropyleneglycolacetal, alpha- Methylcinn-amicaldehyd diethylacetal, alpha-Cinnamicaldehyddimethylacetal, Phenylacetaldehyd- 2,3-butyleneglycol acetal, Phenylacetaldehydcitronellylmethylacetal, Phenylacetaldehyddiallylace - tal, Phenylacetaldehyddiamylacetal, Phenylacetaldehyddibenzylacetal Phenylacetaldehyddibutyla- CETAL, phenylacetaldehyde, Phenylacetaldehyddigeranylacetal, Phenylacetaldehyddime- thylacetal, Phenylacetaldehydethyleneglycolacetal, Phenylacetaldglycerylacetal, Citronellalcyclo- monoglycolacetal, Citronellaldiethylacetal, Citronellaldimethylacetal, Citronellaldiphenylethylacetal, Geranoxyacetaldehyddiethylacetal and / or mixtures thereof acetals may be preferably included in the inventive Parfumol

Ketals are geminal diethers of the general formula R ¹ R ² C (OR ³ ) (OR ⁴ ) Preferred examples are acetone diethyl ketal, acetone dimethyl ketal, acetophenone diethyl ketal, methyl amyl catechol ketal, methyl butyl catechol ketal and / or mixtures thereof. Ketals may preferably be present in the perfume of the invention

Preferred examples of condensation products of amines and aldehydes are anisaldehyde methylanthranilate, aurantiol (hydroxycitronellalmethyl anthranilate), verdantiol (4-tert-butyl-alpha-methyldihydrocinnamaldehyde-methyl anthranilate), vertosin (2,4-dimethyl-3-cyclohexene carbaldehyde), hydroxycitronellalcyl anthranilate, hydroxycitronellalinallylanthramlate methyl N- (4- (4-hydroxy-4-methylpentyl) -3-cyclohexenyl-methyl-1-ene) -anthranilate Methylnaphthyl-ketone-methylanthranilate Methyl-nonyl-acetaldehyde-methyl-anthranilate, methyl-N- (3,5-tri-methyl-hexyl) -anthranilate, vanilane Linmethyl anthranilate and / or mixtures thereof Condensation products of amines and aldehydes may preferably be present in the perfume of the invention

In particular, it is advantageous if fragrances such as, for example, adoxal (2,6,10-tri-methyl-9-undecene-1-al), amyl acetate, anisaldehyde (4-methoxy-benzaldehydes), bacdanol (2-ethyl-4- (2, 2,3-trimethyl-3-cyclopenten-1-yl) -2-buten-1-ol), benzaldehyde, benzophenone, benzyl acetate, benzyl salicylate, 3-hexen-1-ol, cetalox (dodecahydro-3A, 6, 6,9A-tetramethyl-uaphtho [2,1B] -furan), cis-3-hexenylacetate cis- 3-hexenylsalicylate, citronellol, Coumaπn, cyclohexyl salicylate, cymal (2-methyl-3- (para-isopropyl-phenyl) propionaldehyde) , Decyl aldehyde, ethyl vanillm, ethyl 2-methyl butyrate, ethylene brazylate, eucalyptol, eugenol, exaltolide (cyclopentadecanolide), florhydral (3- (3-isopropylphenyl) butanal), galaxolide (1, 3,4,6,7,8-hexahydroxy) 4,6,6,7,8,8-hexamethylcyclopenta-gamma-2-benzopyran), gamma decalactone, gamma dodecalactone, geraniol, geranylnitnl, helional (alpha-methyl-3,4, (methylenedioxy) hydroquinamide), heliotropin , Hexylacetat, Hexylzimtaldehyd, Hexylsalicylat, Hydroxyambran (2-cyclododecyl-pro panol), hydroxycitronellal, iso E super (7-acetyl-1, 2,3,4,5,6,7,8-octahydro-1, 1, 6,7, tetramethylnaphthalene), isoeugenol, isojasmon, koavon (Acetyl-1-yno-amylene), lauryl aldehyde, Irg 201 (methyl 2,4-dihydroxy-3,6-dimethylbenzoate), lyral (4- (4-hydroxy-4-methylpentyl) 3-cyclohexene-1 -carboxaldehyde), Majantol (2,2-dimethyl-3- (3-methylphenyl) -propanol), mayor (4- (1-methylethyl) cyclohexanemethanol), methyl anthranilate, methylbeta naphthylketoe, methylcedrylon (methyl cedryl ketone), methylchavicol ( 1-Methyloxy-4,2-propen-1-yl benzene), Methyldihydrojasmonat, Methylnonylacetaldehyd, musk indanone (4-acetyl-6-tert-butyl-1, 1-methyl indan din), nerol, nonalactone (4-Hydroxynonanonsaure , Lactone), norlimbanol (1- (2,2,6-tri-methylcyclohexyl) -3-hexanol), PT Bucinal (2-methyl-3 (para tert-butylphenyl) propionaldehyde), para-hydroxyphenylbutanone, patchouline, phenylacetaldehyde, Phenylethyl acetate, phenylethyl alcohol, phenylethyl phenylacetate, phenylhexanol / phenoxanol (3-met hyl-5-phenylpentanol), polysantol (3,3-dimethyl-5- (2,2,3-tri-methyl-3-cyclopenten-1-yl) -4-penten-2-ol), rosaphen (2- Methyl 5-phenylpentanol), sandalwood, alpha-terpinene, tartalide / musk plus (7-acetyl-1,1,1,4,4,6-hexamethyltetralin), undecalactone, undecavertol (4-methyl-3-ol) decene-5-ol), undecylaldehyde or undecenealdehydes, vanillin and / or mixtures are contained in the perfume according to the invention

If desired, at least one of the contained perfumes may also be combined with a perfume fixative. It is believed that perfume fixatives may slow the evaporation of the high volatile levels of perfume, which may be advantageous in the present invention

According to a further preferred embodiment, at least one of the perfumes contained comprises a perfume fixative, preferably in the form of diethyl phthalates, musk (derivatives) and mixtures thereof, the amount of fixative preferably being from 1 to 55% by weight, advantageously from 2 to 50% by weight. even more advantageously 10 to 45% by weight, in particular 10 to 40% by weight, of the total amount of the particular perfume concerned According to a further preferred embodiment, at least one of the perfume oils contained contains a viscosity of liquids, in particular of perfume-increasing agent, preferably PEG (polyethylene glycol), advantageously having a molecular weight of 400 to 2000, wherein the viscosity-increasing agent in a preferred manner in amounts of 0.1 to 20% by weight, advantageously from 0.15 to 10% by weight, more preferably from 0.2 to 5% by weight, in particular from 0.25 to 3% by weight, based on the total amount of the respective perfume

It has been found that the viscosity of liquids, especially perfume-raising agents, can contribute to perfume stabilization

According to a preferred embodiment of the invention, at least one perfume oil contains a viscosity-increasing agent, preferably polyethylene glycols (PEG for short), which can be described by the following general formula

H- (O-CH ₂ -CH ₂ ) _H -OH

The degree of polymerization n can vary from about 5 to> 100,000, corresponding to molar masses of 200 to 5,000,000 gmol.sup.- ¹ . The products having molecular weights below 25,000 gmol.sup.- ¹ are referred to as actual polyethylene glycols, while high molecular weight products are often referred to in the literature polyethylene glycols (PEOX for short) The polyethylene glycols preferably used may have a linear or branched structure, with linear polyethylene glycols in particular being preferred, and end-capped

The particularly preferred polyethylene glycols include those having relative molecular weights between 400 and 2000. Polyethylene glycols which are present in a liquid state at room temperature and a pressure of 1 bar can also be used in particular. Polyethylene glycol having a relative molecular mass of 200 is especially important here , 400 and 600 the speech

As already mentioned before, the structure of a perfume composition is classified into "top note", "middle note or body" and "base note" (end note or dry out). The top note (Tete The center note (Bouqet, Corps, Coeur, Herznote body) comprises essentially moderate volatile fragrances, preferably mostly flowery character and the base note (rear, smell) comprises substantially little volatile Fragrances, essentially determine the basic character (Leitgeruch) of the perfume

This means that the top note essentially determines the first phase of the perfume process of a perfume or of a perfume-scented agent, such as a detergent. It plays the decisive role in the first impression of the scent experience, ie when opening the scent Detergent pack and when filling the detergent in the washing machine The top note should attract substantial attention and interest in the perfume and thus the scented agent, which is why it is essentially a mixture of light, volatiles, although sometimes even notes of heart and base already in the first fragrance phase can play a role Typical ingredients of the top note are, for example, the Agrumenole, fruit notes, lavender, Dihydomyrcenol or rose oxide The expert knows a lot of other ingredients from the daily view or can refer to the relevant literature

The second, middle phase of the perfume process of a perfume or perfume scented agent, such as a detergent, is determined by the heart note. This is preferably formed by a mixture of rounder, more complex notes that give a perfume fullness, character and a particular perfume For example, it can be dominated by floral components such as lily-of-the-valley, jasmine or rose. In addition, many of the spicy components of a perfume such as eugenol (essential carnation fragrance) can be found here. The skilled person is familiar with a large number of other components from the daily intuition or can take these from the relevant literature

The base note of the perfume (with which, for example, a detergent is perfumed) determines the character of the fragrance. It adheres very well to the fragranced objects and is essentially composed of heavier, warmer notes. For example, you can use a precious wood base with isolated odor carriers from other woods and woods for example also with

Moschusπechstoffen and / or an animal complex and predestined base notes such as patchouli and vanilla combine

On the basis of this generalized fragrance note concept, the perfume compositions are generally created, whereby a perfume of complex structure can even consist of several hundred individual components. Experience has shown that often only a very well balanced mixture of many components (for example at least 15 or 10, in many cases at least 30) or 50 or more) to perfumistic success, ie to a fragrance

According to a preferred embodiment, the grades of the same parfumol differ with respect to their quantitative weighting, preferably

(a) the headnote is weighted higher in terms of quantity than the middle note and the base note, wherein the two lower-weighted notes may be substantially equally weighted to one another or one of the lower-weighted notes is weighted higher than the other, or

(b) the middle note is weighted quantitatively higher than the top note and base note, wherein the two lower weighted notes may be substantially equally weighted to each other, or one of the lower weighted notes is weighted higher than the other or (c) the base note is weighted quantitatively higher than the top note and middle note, whereby the two lower weighted notes may be substantially equally weighted to each other, or one of the lower weighted notes is weighted higher than the other one note is weighted quantitatively higher than another means that the total mass of the fragrances forming the high weighted note is greater than the total mass of the fragrances forming the lower weighted note, advantageously by at least 10% by weight, preferably at least 20% by weight, in particular at least 30% by weight on the total mass of the respective perfume composition

According to a preferred embodiment, the notes of at least two different perfumes differ with regard to their quantitative weighting, preferably

(a) the top note of parfumol 1 is weighted quantitatively higher than the top note of parfumol 2, or vice versa, and / or

(b) the middle note of parfumol 1 is weighted quantitatively higher than the middle note of parfumol 2, or vice versa, and / or

(c) the base note of Parfumol 1 is weighted quantitatively higher than the base note of Parfumol 2, or vice versa

One note, quantitatively more highly weighted than another, means here that the total mass of the fragrances of one perfume forming the high weighted note is greater than the total mass of the less weighted fragrances of the other perfume, advantageously at least 10 wt. %, preferably at least 20% by weight, in particular at least 30% by weight, based on the respective total mass of the particular perfume concerned

According to another preferred embodiment, all notes of the perfume composition are weighted substantially equally

As has already become clear, the present invention allows the skilled person a breakthrough in the scenting of products, thus enabling him to produce products with a completely new, namely changing fragrance profile. The skilled person now has access to products with dynamic fragrance It is particularly preferred if the perfume oils to be used comprise very specific odor notes. For this purpose, the product according to the invention can, according to a preferred embodiment, in particular perfumes

(a) almond-like odor, such as preferably benzaldehyde pentanal, heptenal, 5-methylfurfural, methylbutanal furfural and / or acetophenone or

(b) apple-like odor, such as preferably (S) - (+) - ethyl-2-methylbutanoate diethyl malonate, ethyl butyrate geranyl butyrate geranyl isopentanoate isobutyl acetate linalyl isopentanoate (E) -β- da mascone heptyl 2-methyl butyrate methyl 3-methyl butanoate 2 Hexenal pentyl methyl butyrate ethyl methyl butyrate and / or methyl 2-methyl butanoate or (c) apple peel-like odor, such as preferably ethyl hexanoate, hexyl butanoate and / or hexyl hexanoate or

(d) apricot-like odor, preferably γ-undecalactone, or

(e) banana-like odor, such as preferably isobutyl acetate, isoamyl acetate, hexenyl acetate and / or pentyl butanoate or

(f) bitter almond-like odor such as preferably 4-acetyltoluene or

(g) blackcurrant-like odor, such as preferably mercaptomethylpentanone and / or methoxymethylbutanethiol or

(c) citrus-like odor, such as, preferably, lalyl pentanoate, heptanal, linalylsopentanoate dodecanal, linalyl formate, α-p-dimethylstyrene, p-cymenol, nonanal, β-cube level, (Z) -methylene oxime, cis-6-ethenyltetrahydro-2,2, 6-tri methylpyran-3-ol, cis-pyranoidhnalooloxid, dihydrolinalool, 6 (10) -Dιhydromyrcenol, dihydromyrcenol, ß-Farnesen, (Z) -ß-Farnesen, (Z) -Ocιmen, (E) -Lιmo- nenoxid, Dihydoterpmylacetat , (+) - Lιmonen, (Epoxymethylbutyl) -methylfuran and / or p-cymene or

(i) cocoa like odor, preferably dimethylpyrazine, butylmethyl butyrate and / or methylbutanal or

(j) coconut-like odor, such as preferably γ-octalactone, γ-nonalactone, methyl laurate, tetradecanol, methyl nonanoate, (3S, 3aS, 7aR) -3a, 4,5,7a-tetrahydro-3,6-dimethylbenzofuran-2 (3H) - on, 5-butyldιhydro-4-methyl-2 (3H) -furanone, ethyl undecanoate and / or δ-decalactone or

(K) creamy odor such as preferably diethyl acetal, 3-hydroxy-2-butanone, 2,3-pentadιon and / or 4-heptenal or

(I) flower-like odor, preferably benzyl alcohol, phenylacetic acid, trimellal, p-anisyl alcohol, hexanol, (E, E) -famesylacetone, methyl geranate, trans-crotonaldehyde, tetradecylaldehyde, methyl anthranilate, linalooloxide, epoxylinalool, phytol, 10-epι-γ -Eftermol, nerol oxide, ethyldihydrocinnamate, γ-dodecalactone, hexadecanol, 4-mercapto-4-methyl-2-pentanol, (Z) - Ocimene, cetyl alcohol, nerolidol, ethyl (E) -carnate, Elemicm, Pinocarveol, α-Bιsabolol , (2R, 4R) -Tetrahydro-4-methyl-2- (2-methyl-1-propenyl) -2H-pyran, (E) -Isoelemιcιn, methyl 2-methylpropanoat, Tπmethylphenylbutenon, 2-Methylanιsol, ß -Farnesol, (E) -isoeugenol, nitrophenylethane, ethyl vanillate, 6-methoxyeugenol, linalool, β-ionone, t-methylphenylbutenone, ethylbenzoate, phenylethyl benzoate, isoeugenol and / or acetophenones or

(m) freshness odor, preferably methylhexanoate, undecanone, (Z) -immunoxymet, benzylacetate, ethylhydroxyhexanoate, isopropylhexanoate, pentadecanal, .beta.-elemene, .alpha.-zigen-alkenes, (E) -limesonoxide, (E) -p-mentha- 2,8-dien-1-ol, menthone, Pipeπton, (E) -3-hexenol and / or carveol or

(n) Fruit odor, such as ethylphenyl acetate, geranyl valerate, γ-heptalactone, ethyl propionate, diethyl acetal, geranyl butyrate, ethyl heptylate, ethyloctanoate, methylhexanoate, dimethylheptylate, pentanone, ethyl-3-methylbutanoate, geranylisovalerate, lobutylacetate, ethoxypropanol, ethylamine 2-butenal, methylnonanedione, linalyl acetate, methyl geranate, ammonium oxide, hdrocinnamic alcohol, ethyl succinate, ethyl hexanoate, ethyl methyl pyrazine, nylate, cetronellyl butyrate Heylace- nonyl acetate, butylmethyl butyrate, pentenal, isopentyldimethylpyrazine, p-menth-1-en-9-ol, hexadecanone, octylacetate, γ-dodecalactone, epoxy-β-ionone, ethyloctenoate, ethylhexanoate, isobornylpropionate, cedrenol, p-menth-1 en-9-yl acetate, cadinadiene, (Z) -3-hexenylhexanoate, ethylcyclohexanoate, 4-methylthιo-2-butanone, 3,5-octadιenone, methylcyclohexanecarboxylate, 2-pentylthiophene, α-ocylenes, butanediol, ethylvalerate, pentanol, Isopipeπton , Butyloctanoate, ethenyl, methylbutanoate, 2-methylbutylacetate, propylhexanoate, butylhexanoate, isopropylbutanoate, spathulenol, butanol, δ-dodecalactone, methylquimoxaline, sesquiphellandrene, 2-hexenol, ethylbenzoate.isopropylbenzoate, ethyllactate and / or citronellylisobutyrate or

(o) Geranium-like odor, such as preferably geraniol, (E, Z) -2,4-nonadιenal, octadienone and / or o-xylene or

(p) grape-like odor such as preferably ethyl decanoate and / or hexanone or

(q) grapefruit-like odor, such as preferably (+) - 5,6-dimethyl-8-isopropenyl-cyclo [4 4 0] dec-1-en-3-one and / or p-menthenethol or

(R) grassy odor such as preferably 2-Ethylpyrιdιn 2,6-dimethylnaphthalene, hexanal and / - or (Z) -3-hexenol or

(s) green note, preferably 2-ethylhexanol, 6-decenal, dimethylheptenal, hexanol, heptanol, methyl-2-butenal, hexyloctanoates, nonanoic acid, undecanone, methyl geranate, isobornylformiate, butanal, octanal, nonanal, epoxy-2-decenal, cis -Linalool, pyranoxide, nonanol, alpha, γ-dimenthylallylalcohol, (Z) -2-penten-1-ol, (Z) -3-hexenylbutanoate, isobutylthiazole, (E) -2-nonenal, 2-dodecenal, ( Z) -4-decenal, 2-octenal, 2-hepten-1-al, bicyclogermacrene, 2-octenal, α-thujene, (Z) -β-farnesene, (-) - γ-elemene, 2,4-octadienal , Fucoserraten, hexenyl acetate, geranylacetone, valencene, ß-eudesmol, 1 -hexenol, (E) -2-undecenal, Artemisia ketone, Viπdiflorol, 2,6-non-adienal, Tπmethylphenylbutenon, 2,4-Nonadιenal, Butyhsothiocyanat, 2-pentanol , Elemol, 2-hexenal, 3-hexenal, (+) - (E) - limonene oxide, cis-isocitral, dimethyloctadienal, bornyl formate, boronyl isovalerate, isobutyraldehyde, 2,4-hexadienal, trimethylphenylbutenone, nonanone, (E) -2 - Hexenal, (+) - cιs-Rosenoxιde, Menthone, coumarin, (Epoxymethylbutyl) -methylfuran, 2-hexenol, (E) -2-hexenol and / or carvyl acetate or

(t) Green Tea-like odor, preferably (-) - Cubenol or

(u) Creeping odor, preferably octanone, hexyloctanoate, caryophyllene oxides, methylbuteneol, safranal, benzyl benzoate, bornyl butyrate, hexyl acetate, β-metabolol, pipetol, β-selenium α-cubebene, p-menth-1-en-9-ol 1, 5 θ, tetramethyl, ω-oxabicyclododeca, γ-diene, ot-muurol, (-) - cubenol, levomenol, ocimene, α-thujene, p-menth-1-en-9-yl acetate, Dehydrocarveol, Artemisia alcohol, γ-Muurolene, hydroxypentanone, (Z) -Ocιmene, ß-elemene, δ-cadinol, (E) -ß- Ocimene, (Z) -Dιhydrocarvone, α-Cadιnol Calamenen, (Z) -Pιperιtol lavandulol , β-Bourbonene (Z) -3-hexenyl-2-methylbutanoate, 4- (1-methylethyl) -benzenemethanol, Artemisia ketone, methyl-2-butenol heptanol, (E) -dιhydrocarvon p-2-menthene-1 -ol, α-Curcumene, Spathulenol, Sesquiphellandren, Citronellylvalerat Bornylisovalerat, 1 5-octadien-3-ol, methyl benzoate. 2,3,4,5-Tetrahydroanιsol and / or Hydroxycalamenen or (v) honey-like odor, preferably ethyl cinnamate, β-phenethyl acetate, phenylacetic acid phenylethanal, methyl anthranilate, cinnamic acid, β-damascenone, ethyl (E) -carnamide, 2-phenylethylalcohol, citronellyl valerates, phenylethyl benzoates and / or eugenol or

(w) Hyacinth-like odor, preferably Hotnenol or

(x) jasmine-like odor, preferably methyl jasmonate, methyldihydroepijasmonate and / or methylepijasmonate or

(y) lavender-like odor, preferably linalyl valerate and / or linalool or

(Z) Lemon-like odor, preferably neral, octanal, δ-3-carene, limonene, geranial, A-mercapto-4-methyl-2-pentanol, citral, 2,3-dehydro-1, 8-cιneol and / or α -Terpines or

(aa) lιlιenartιgem smell, preferably dodecanal or

(bb) magnolia-like odor, preferably geranylacetone or

(cc) mandarin-like odor, preferably undecanol or

(dd) melon-like odor, preferably dimethylheptenal or

(ee) Mιnze-artigem smell, preferably menthone, ethyl salicylate, p-Anεsaldehyd, 2,4,5,7a-tetrahydro-3,6-dιmethyl-benzofuran, epoxy-p-menthene, geranial, (methylbutenyl) -methylfuran , Dihydrocarvylacetate, β-cyclocitral, 1,8-cinnoline, β-phellandrenes, methylpentanone, (+) - -lomones, dihydrocarveol (-) - carvone, (E) -p-mentha-2,8-diene-1 ol, isopulegyl acetate, Pipeπton, 2,3-dehydro-1, 8-cιneol, α-terpιneol, DL-carvone and / or α-Phellandrene or

(ff) Nutty odor, preferably 5-methyl- (E) -2-hepten-4-one, γ-heptalactone, 2-acetylpyrrole. 3-octen-2-one, dihydromethylcyclopentapyrazine, acetylthiazole, 2-octenal, 2,4-heptadιenal, 3-octenone, hydroxypentanone, octanol, dimethylpyrazine, methylquinoxaline and / or acetylpyrrimine or

(gg) orange-like odor, preferably methyloctanoate, undecanone, decyl alcohol, limonene and / or 2-decenal or

(hh) orange peel-like odor, preferably decanal and / or beta-carene or

(ιι) peach-like odor, preferably γ-nonalactone, (Z) -6-dodecene-γ-lactone, δ-decalactone, R-δ-decenolactone, hexylhexanoate, 5-Octanolιd, γ-decalactone and / or δ-undecalactone or

(jj) peppermint-like odor, preferably methyl salicylate and / or I-menthol or

(kk) Pine-like odor, preferably α-p-dimethylstyrene, β-pyrene, bornyl benzoate, δ-terpinene, dihydroterpinyl acetate and / or α-pinene or

(II) pineapple-like odor, preferably propyl butyrate, propyl propanoate and / or ethyl acetate or

(mm) plum-like odor, preferably benzyl butanoate, or

(nn) raspberry-like odor, preferably β-ionone or

(oo) Rose-like odor, preferably β-phenethyl acetate 2-ethylhexanol geranyl valerate, geranyl acetate, citronellol, geraniol, geranyl butyrate, geranyl isovalerate, citronellyl butyrate, citronellyl acetate, isogeraniol, tetrahydro-4-methyl-2- (2-methyl-1 -propenyl) -2,5-cis-2H-pyran isogermanone 2-phenylethyl alcohol, citronellyl valerate and / or citronellyhsobutyrate, or

(PP) Green mint-like odor, preferably carvylacetate and / or carveol or (qq) strawberry-like odor, preferably hexylmethyl butyrate, methyl cinnamate, pentenal, methyl cinnamate or

(rr) Sweetish odor, preferably benzyl alcohol, ethyl phenylacetate, trimellal, nerol, methylhexanoate, linalylisovalerate, undecanedehyde, caryophyllene oxide, linalylacetate, safranal, unlicene, phenylethanal, p-anisaldehyde, eudesmol ethylmethylpyrazine, citronellylbutyrate, 4-methyl-3 penten-2-one, nonyl acetate, 10-ep-γ-eudesmol, β-metabolol, (Z) -6-dodecen-γ-lactone, β-farnesene, 2-dodecenal, γ-dodecalactone, epoxy-β-ionone, 2-undecenal, styrene glycol methyl furanoleol, (-) - cis-Rosenoxιd, (E) -ß-Ocιmene, Dimethylmethoxyfuranon, 1, 8-Cιneole, ethyl benzaldehyde, 2-Pentylthιophen, α-Farnesene, methionol, 7-Methoxycoumaπn , (Z) -3-hexenyl-2-methylbutanoate, o-aminoacetophenone, vindiflorol, isopipentones, β-silanol, ethyl vanillate, methyl butanoate, p-methoxystyrene, 6-methoxyeugenol, 4-hexanol, δ-dodecalactone, sesquip-brightandren, diethyl malate , Linalyl butyrate, guaiacol, coumarin, methyl benzoate, isopropyl benzoate, safroles, durene, γ-butyrolactone, ethyl isobutyrate and / or Fu rfural or

(ss) vanilla-like odor, preferably vanillin, methyl vanillate, acetovanillon and / or ethyl vanillate or

(tt) watermelon-like odor, preferably 2,4-nonadιenal or

(uu) woody odor, preferably α-Muurolene, Cadιna-1, 4-dιen-3-ol, Isocaryophyllene, Eudesmol, α-ionone, bornyl butyrate, (E) -α-bergamotene, linalooloxide, ethylpyrazine, 10-epι-γ Eudesmol, α-ionone, bornyl butyrate, (E) -α-bergamotene, linalooloxide, ethylpyrazine, 10-epι-γ-eudesmol, germacrene B, trans-sabber hydrate, dihydro-nalool, isodihydrocarveol, β-farnesene, β-sesquipellandrene, δ-Elemene, α-Calacorene, Epoxy-β-Ionone, Germacrene D, Bicyclogermacrene, Alloaromadendrene, α-Thujene, Oxo-β-Ionone, (-) - γ-Elemene γ-Muurolene Sabinene, α-Guaiene, α-Copaene , γ-Cadinylene, nerohdol, β-eudesmol, α-cadmium, δ-cadenines, 4,5-dimethoxy-6- (2-propenyl) -1,3-benzodioxol, [1ar (1aalpha, 4aalpha, 7alpha, 7abeta , 7balpha)] - decahydro-1, 1, 7-tri methyl-4-methylene-1 H-cycloprop [e] azulen, α-gurjunen, guaiol, α-Farnesene, γ-Selιnene, 4- (1-methylethyl ) -beπzenemethanol, Peπllen, elemole, α-humulenes, ß-caryophyllene and / or ß-Guaιene or

(vv) mixtures of the above contain

The aforementioned fragrances may preferably be present in the perfume oil of the invention. They are highly suitable, in particular, for the scenting of washing, cleansing or care compositions or cosmetic products

As the person skilled in the art immediately recognizes, various creations can be realized according to the invention, for example a detergent which first develops an apple-like odor like an apple-like later

In the context of the present invention, it also corresponds to a preferred embodiment. form, if at least one, preferably at least two, advantageously at least three, in particular at least four of the perfume contained in each case at least one, preferably at least two, advantageously at least three, more preferably at least four, more preferably at least five, especially at least six fragrance alcohols which are preferably selected from acetovanillon, allylamylglycolate, allyhsoamylglycolate, α-amylcinammylalcohol, anisylalcohol, benzoin, benzylalcohol, benzylsahcylate, 1-butanol, butylactate, 2-t-butyl-5-methylphenol, 2-t-butyl-6- methylphenol, carvacrol, carveol, A-carvomenthenol, cedrol, cetyl alcohol, cinnamic alcohol, citronellol, o-cresol, m-cresol, p-cresol, crotyl alcohol, decahydro-2-naphthol, 1-decanol, 1-decene-3 ol, 9-decene-1-ol, diethyl malate, diethyl tartrate, dihydro carveol, dihydromyrcenol, 2,6-diisopropylphenol, Dimethiconecopolyol, 2,6-Dιmethoxyphenol, 1, 1 -Dιmethoxy-3,7-dιmethylo ctan-7-ol, 2,6-dimethyl-4-heptanol, 2,6-dimethylheptan-2-ol, 6,8-dimethyl-2-nonanol, 3,7-dimethyl-2,6-octadiene 1-ol, 3,7-dimethyl-1, 6-octadien-3-ol, 3,7-dimethyl-1-octanol, 3,7-dimethyl-3-octanol, 3,7-dimethyl-6-octene 1-ol, 3,7-dimethyl-7-octen-1-ol, dimetol, 2-ethylfenchol, 4-ethylguanacol, 2-ethyl-1-hexanol, ethyl 2-hydroxybenzoate, ethyl 3-hydroxybutyrate, 3-ethyl 2-hydroxy-2-cyclopenten-1-one, ethyl 2-hydroxycaproate, ethyl 3-hydroxyhexanoate, ethyl lactate, ethyl maltol, p-ethylphenol, ethyl salicylate, eugenol, farnesol, fenchyl alcohol, geraniol, glucose pentaacetate, glycerol, Glyceryl monostearate, guaiacol, 1-heptanol, 2-heptanol, 3-heptanol, cis- 4-heptenol, cs-3-heptenol, n-hexanol, 2-hexanol, 3-hexanol, cis-2-hexenol, cιs-3 Hexenol, trans-3-hexenol, 4-hexenol, cis-3-hexenylhydro-cnamnamylalkohol, 2-hydroxybenzoate, 2-hydroxy-acetophenone, 4-hydroxybenzyl alcohol, 3-hydroxy-2-butanone, hydroxycitronellal, 4- (4-hydroxy -3-methoxyphenyl) -2-butanone, 2-hydrox y-3-methyl-2-cyclopenten-1-one, 4- (p-hydroxyphenyl) -2-butanone, 2-hydroxy-3,5,5-tri-methyl-2-cyclohexenone, delta-isoascorbic acid, isoborneol , Isoeugenol, isophytol, isopropyl alcohol, p-isopropylbenzyl alcohol, 4-isopropylcylcohexanol, 3-isopropylphenol, 4-isopropylphenol, 2-isopropylphenol, isopulegol, lauryl alcohol, lmalool, maltol, menthol, A-methoxybenzyl alcohol, 2-methoxy-4-methylphenol, 2 - Methoxy-4-propylphenol, 2-methoxy-4-vinylphenol, α-methylbenzyl alcohol, 2-methylbutanol, 3-methyl-2-butanol, 3-methyl-2-buten-1-ol, 2-methyl-3 -butene-2-ol, methyl 2,4-dihydroxy-3,6-dimethylbenzoate, 4-methyl-2,6-dimethoxyphenol, methyl N-3,7-dimethyl-7-hydroxyoctylideneanthranilate, methyl 3-hydroxyhexanoate, 6 -Methyl-5-hepten-2-ol, 2-methylpentanol, 3-methyl-3-pentanol 2-methyl-4-phenylbutan-2-ol, 2-methyl-3-phenylpropan-2-ol, methyl salicylate, 3 Methyl 5- (2,2,3-t-methyl-3-cyclopenten-1-yl) -4-penten-2-ol, 2-methyl-2-vinyl-5- (1-hydroxy-1-methyl-ethyl ) -3,4-diphohydrofuran, Myrteno l, Neohespeπdin dihydrochalcone neomenthol, nerol, nerohdol, trans-2-cis-6-Nonadιenol, 1, 3-Nonanedιol acetate, nonadyl 2-nonanol, cs-6-nonene-1-ol, trans-2-Nonen- 1-ol, nonyl alcohol 1-octanol, 2-octanol, 3-octanol cis-3-octen-1-ol, cis-2-octen-1-ol, trans-2-octene-1-ol, cιs-6- Octene-1-ol, cis-octene-1-ol 1-octene-3-ol, oleyl alcohol, patchouli alcohol, 3-pentanol n-pentanol, 2-pentanol, 1-penten-1-ol cιs-2-pentene-1 -ol, Peπllylalkohol, 2-phenoxyethanol-arabιnogalactan, beta-phenethyl alcohol, phenethyl salicylate, phenol, phenylacetaldehyde glyceryl acetal 3-phenyl-1-pentanol, 5-phenyl-1-pentanol, 1-phenyl-1-pentanol, 1-phenyl-2 -pentanol 1-phenyl-3-methyl-1-pentanol, Phytol Pinacol, polyalkylene glycol polysorbate 20 polysorbate 60 polysorbate 80 prenol n-propanol propenylguaethol Propylene glycol, 2-propylphenol, 4-propylphenol, resorcinol, retinol, salicylaldehyde, sorbitan monostearate, sorbitol, stearyl alcohol, syngealdehyde, α-terpιneol, tetrahydrogeraniol, tetrahydro-naphane, tetrahydromyrcenol, thymol, trimethyl citrate, 1, 2,6-trihydroxyhexane, p-α, α-trimethylbenzyl alcohol, 2- (5,5,6-tri methylbicyclo [2 2 1] hept-2-ylcyclohexanol, 5- (2,2,3-trimethyl-3-cyclopentenyl) -3 -methylpentan-2-ol, 3.7, -1 1 -trimethyl-2,6,10-dodecatrien-1-ol, 3,7,11-trimethyl-1, 6,10-dodecatrien-3-ol, 3 , 5,5-trimethyl-1-hexanol, 10-undecen-1-ol, undecyl alcohol, vanillin, o-Vanιllιn, vanillyl butyl ether, 4-vinylphenol, 2,5-xylenol, 2,6-xylenol, 3,5-xylenol , 2,4-xylenol and / or xylose It is preferred, if more than one perfume contains Duftstoffalkohole that all Par fumole contain different fragrance alcohols Furthermore, it is according to the invention clearly preferred if the product according to the invention at least 1, 2, 3 , 4, 5, or 6 or even more of the pre included smell pouches

In the context of the present invention, it also corresponds to a preferred embodiment, if at least one, preferably at least two, advantageously at least three, especially at least four of the perfume contained in each case at least one, preferably at least two, advantageously at least three, more preferably at least four, in more preferably containing at least five, in particular at least six fragrances with carbonyl function, which are preferably selected from 4-acetoxy-3-pentyl-tetrahydropyran, allyl cinnamate, allyl 2-ethyl butyrate, allyl cyclohexane propionate, allyl heptanoate, allyl hexanoate, allyl soalerate, allyl nonanoate, allyloctanoate , Allylphenoxyacetate, allylphenylacetate, allylpropionate, α-amylcinnamylacetate, amyloctanoate, anisylacetate, anisylphenylacetate, benzylacetate, benzylacetoacetate, benzylbutyrate, benzylcinnamate, benzylisobutyrate, benzyhsovalerate, benzylphenylacetate, benzylpropionate, bomylacetate, bornyhsoval erat, bornyl valerate, butyl acetate, butyl butyrate, butyl butyryl lactate, 4-t-butyl cyclohexyl acetate, butyl heptanoate, butyl hexanoate, butyl isobutyrate, butyl isovarate, butyl laurate, butyl propionate, butyl stearate, 3-butyl-1-ene-phthalate, butyl-2-methyl-butyrate, butyl-10 undecenoate, gamma-butyrolactone, carvyl acetate, carvylpropionate, caryophyllene acetate, cedryl acetate, trans-cinnamyl acetate, trans-cinnamyl butyrate, cinnamyl cinnamate, cinnamyl isobutyrate, citronellyl acetate, citronellyl butyrate, citronellyl isobutyrate, citronellyl propionate, citronellyl valerate, cyclohexane ethyl acetate, cyclohexyl acetate, cyclohexyl butyrate, cyclohexyl isovalerate, Cyclohexylpropionate, delta-decalactone, epsilon-decalactone, gamma-decalactone, 4-decanolyl, decylacetate, decylbutyrate, decylpropionate, diethylmalonate, diethyl sebacate, diethylsuccinate, dihydrocarvylacetate, dihydrocoumarin, dihydromyrcenylacetate, dihydro-nor-dicyclopentadienylacetate, dihydroterpinylacetone did, 3,7-dimethyl-1, 6-octadien-3-yl acetate, 3.7 Dimethyl-1,6-octadien-3-yl propylate 3,7-dimethyl-octan-3-yl-acetate, α, α-dimethylphenethyl acetate, α, α-dimethylphenethyl butyrate, 6,10-dimethyl-5,9- undecadien-2-yl-acetate, delta-dodecalactone, epsilon-dodecalactone, gamma-dodecalactone, ethyl acetate, ethylacetoacetate, ethyl-6-acetoxyhexanoate, ethyl-2-acetyl-3-phenylpropylate, ethylbenzoyl acetate, 2-ethylbutyl acetate, ethyl butyrate, ethyl cinnamate , Ethylcyclohexanepionate, ethyldecanoate, ethylenebasylate, ethyl-2-ethyl-6,6-dimethyl-2-cyclohexenecarboxylate ethyl-2-3-epoxy-butyrate ethyl-2-methyl-4-penteno neoate, ethylheptanoate ethylhexanoate, ethyl-trans-3-hexenoate 2-ethylhexyl acetate, ethyl isobutyrate, ethyl isovalerate, ethyl laurate, ethyl 2-mercaptopropionate, ethyl 3-mercaptopropionate, ethyl 2-methyl butyrate, ethyl 2-methyl pentanoate, ethyl (methylthio) acetate, methyl (methylthio) acetate , Methyl 2- (methylthio) propionate, Ethylmyπstat, ethylnonanoate, ethyloctanoate, ethyl palmitate, ethyl phenylacetate, ethyl 3-phenylpropylate, ethyl 3-phenyl-2,3-epoxybutyrate, ethyl 3-phenylpropionate, ethyl propionate, ethyl stearate, Ethyl 2,3,6,6-tetramethyl-2-cyclohexene carboxylate ethyl (p-tolyloxy) acetate, ethyl undecanoate, ethyl valerate, eugenyl acetate, fenchyl acetate, geranyl acetate, geranyl butyrate, geranyl phenylacetate, geranyl propionate, guaiacylphenyl acetate, guaicwood acetate, gamma Heptalactone, heptyl acetate, heptyl butyrate, Heptyhsobutyrat, omega-6-Hexadecenlac- tone, delta-hexylactone, gamma-hexylactone, 3-hexenyl acetate, cis-3-hexenyl 2-methylbutanoate, cιs-3-hexenyl cιs-3-hexenoate, cιs 3-hexenylphenylacetate, trans-2-hexenylacetate, hexylacetate, hexylbutyrate, hexylhexano at, Hexyhsobutyrat, Hexylpropionat, hexyl-2- methybutanoat, hexyl-3-methylbutanoate, Hexylphenylacetat, isoamyl acetate, Isoamylacetoacetat, isoamyl butyrate, isoamyl cinnamate, Isoamylhexanoat, Isoamylisobutyrat, Isoamylisovalerat, Isoamyllaurat, Isoamylnonanoat, Isoamyloctanoat, Isoamylphenylacetat, isoamyl propionate, Isobomylacetat, Isobornylpropionat, Isobutyl acetate, isobutyl butyrate, isobutyl cinnamate, isobutyl hexanoate, isobutyl isobutyrate, isobutyl-2-methylbutyrate, isobutyl propionate, isoeugenyl acetate, isopropyl cinnamate, isobutylphenyl acetate, isopropyl acetate, isopropyl butyrate, isopropyl isobutyrate, isopropylmactitol, isopropyl palmitate, isopropylphenyl acetate, lauryl acetate, linalyl acetate, lmalyl butyrate, Linalyl isovalerate, menthalactone, menthyl acetate, menthylcyclohexanecarboxylate, menthyl isovalerate, 4-methoxybenzylacetate, 4-methoxybenzylpropionate, 2-methoxyphenylacetate, 2-methoxy-4- (1-propenyl) phenylacetate, methyl acetate, α-methylbenzylacetate, α-methylbenzyl butyrate , α-methylbe 2-methylbutyl acetate, 2-methylbutyl butyrate, 2-methylbutyl isovalerate, 3-methylbutyl 2-methylbutanoate, 2-methylbutyl 2-methylbutanoate, methyl p-butylphenylacetate, methyl butyrate, methyl cinnamate, methyl decanoate, methyl heptanoate, methyl methylhexanoate, methyl isobutyrate, methyl isovalerate, methyl laurate, methyl N-2-methyl-3- (4-t-butylphenylpropylidene) anthranilate, methylmethylstate, methyl nonanoate, methyl octanoate, methyl palmitate, 4- (4-methyl-3-pentenyl) -3 - cyclohexenylmethyl acetate, methyl 2-methylbutyrate, 2-methyl-6-methylene-7-octene-2-yl acetate, methyl 4-methylvalerate, methyl 2-methylpentanoate, methylphenoxyacetate, 2-methyl-3-phenylpropane-2 -yl acetate, methyl 3-phenylpropionate, methyl propionate, 2-methylpropylphenylacetate, methylphenylacetate, 2-methyl-3-phenylpropan-2-yl acetate, methyl stearate, methyl (p-tolyloxy) acetate, methyl 9-undecenoate, methyl valerate, Myrtenyl acetate, neryl acetate, neryl butyrate, neryl isobutyrate, delta-nonalactone, gamma-nonalactone, 1,3-nonanediol acetate, nonyl acetate, octahydrocoumine, gamma-octalactone, 1-octen-3-yl-acetate, 1-octen-3-yl-butyrate, octylacetate, octyl-butyrate, octylisobutyrate, octylisovalerate, octyloctanoate, octylpropionate, oxacycloheptadec-10-ene-2 -one, omega-pentadecalactone, pentylacetate pentylbutyrate, pentylhexanoate, pentyloctanoate phenethylacetate, phenethylbutyrate, phenethylcinnamate phenethylhexanoate, phenethylisobutyrate phenethylisovalerate, phenethyl 2-methylbutyrate, phenethyl 2-methylbutyrate, phenethyl 2-methylpropionate phenethyloctanoate, phenethylphenylacetate phenethylpropionate, phenoxyethylpropionate, 2-phenoxyethyl 2-methylpropionate , 3-phenyl-2-propenyl propionate 3-phenylpropyl acetate, 2-phenylpropyl butyrate, 2-phenylpropyl isobutyrate, 2-phenylpropyl isovalerate piperonyl acetate, piper nyhsobutyrate, prenylacetate, propylacetate, propylbutyrate, propylheptanoate, propylhexanoate, 3-prophyidenephthalide, propylisobutyrate, propylpropionate, propylphenylacetate, sucrose octaacetate, terpinylacetate, terpinylbutyrate, terpinyhsobutyrate, terpinylpropionate, tetrahydrofurfurylacetate, tetrahydrofurfurylbutyrate, tetrahydrofurfurylpropionate, tetrahydro-nalalacetate, 2.6 , 6,8-tetramethyl-t-cyclopentane-5-yl-acetate, p-tolylacetate, p-tolyhsobutyrate, p-tolylphenylacetate, trimethylpyridine, t-butylacetylcitrate, t-butyne, t-propionine, 3 5,5-t-methylhexyl acetate, 6-undecalactone, gamam-undecalactone, gamma-valerolactone, vanilohacetate, vanillyl isobutyrate, 1-vinyl-2- (1-methylpropyl) cyclohexyl-acetate, whiskeylactone, butyraldehyde, citronellal, decanal, cis-4-decenal, trans-4-decenal, 2,4-dimethyl-3-cyclohexene-1-carbaldehyde, 2,6-dimethyl-5-heptenal, 3,7-dimethyl-octanal, 2-ethyl-butyraldehyde, glutacaldehyde, heptanal, cis-4-heptenal, hexanal, hydrocinnamaldehyde, Isobu tetraldehyde, 3- (p-isopropylphenyl) -propylaldehyde, isovaleraldehyde, lauric aldehyde, 2-methylbutyraldehyde, 2-methyl-3- (p-isopropylphenyl) propionaldehyde, 2-methylpentanal, 4- (4-methyl-3-pyridyl) pentenyl) -3-cyclohexene-1-carbaldehyde, 4-methylphenylacetaldehyde, 3- (methylthio) butanal, 2-methyl-4- (2,6,6-tri-methyl-2-cyclohexen-1-yl) butanal, 2-methyl -undecanal, nonanal, cis-6-nonenal, octanal, phenylacetaldehyde, 2-phenylpropionaldehyde, 3-phenylpropionaldehyde, propionaldehyde, p-tolylacetaldehyde, tetanuclear, 2,4,6-trimethyl-3-cyclohexene-1-carbaldehyde, 2,6 , 10-trimethyl-9-undecanal, 7-undecenal, 8-undecenal, 9-undecenal, 10-undecenal, valeraldehyde, acetanisole V-acetonaphthone, 2'-acetonaphthone, acetone, acetophenone, 2-acetoxy-2,5-dimethyl -3 (2H) furanone, 2-acetylcyclopentanone, 4-acetyl-1, 1-dimethyl-6-t-butylindane, 7-acetyl-1,1,1,44,4,6-hexamethylolane 2-acetyl-2 thιzolιn, 6-acetyl-1, 1, 2,4,4,7-hexamethyltetralιn, allyl-α-ionone, Benzyhdeneaceton, 2 3-Butanedιon, 2-sec-Butylcy clohexanone, 5-t-butyl-3,5-dimethy-2,6-dimethylacetophenone, butyrophenone, camphor, 2-decanone, 3-decanone, 3-decen-2-one, dihydrocarvone, dihydro-beta-ionone dihydrojasmon , 4,5-dihydro-3 (2H) -thiophenone, 2 ', 4'-dimethylacetophenone, 3,4-dimethyl-1, 2-cyclopentadione, 3,5-dimethyl-1, 2-cyclopentadione, 2, 6-dimethyl-4-heptanone, 1,3-diphenyl-2-propanone, 4- (1-ethoxy-vinyl) -3,3,5,5-tetramethylcyclohexanone, p-ethylacetophenone, ethyl vinyl ketone, geranylacetone, 2,3- Heptanedιon, 2-heptanone, 3-heptanone, 4-heptanone, 3,4-Hexanedιon, 3-hexanone, 4-hexen-3-one, 2-Hexylιdene cyclopentanone, α-ionone, beta-ionone, 4-isobutyl -2,6-dimethyl-3,5-dmitroacetophenone, isophorone, 6-isopropyldecahydro-2-naphthone, ice-jasmone, livescone, A-methoxyacetophenone, 4- (p-methoxyphenyl) -2-butanone, 4'-methylacetophenone, 3-methyl-1,2-cyclohexanedione, 3-methyl-2-cyclohexene-1-one, 2- (2- (4-methyl-3-cyclohexen-1-yl) -propyl) -cyclopentanone, 3-methyl 2-cyclopenten-1-one, methyldihydrojasmonate, methylethylk eton, 2-methyl-3-heptanone, 5-methyl-2-hepten-4-one, 6-methyl-5-hepten-2-one, 5-methyl-α-ionone, 1- (2-methyl-5 -isopropyl-2-cyclohexenyl) -1-propanone, 4-methyl-2-pentanone, 3-methyl-2- (2-pentenyl) -2-cyclopenten-1-one 4-methyl-1-phenyl-2 -pentanone, 2-methyltetrahydrofuran-3-one 2-methyltetrahydrothiophen-3-one 2-nonanone 3-nonanone, 2-octanone, 3-octanone 1-octen-3-one 3-octen-2-one, 4-oxo-isophorone 2 Pentadecanone, 2,3-pentanedion, 2-pentanone 3-pentanone, 3-penten-2-one, 1-phenyl-1 2-propiontione propiophenone, pulegone, 2-trimellan, 2,2,6-trimethylcyclohexanone, 4- (2,6-tri-methyl-2-cylcohexen-1-yl) -3-methyl-3-buten-2-one, 2-undecanone and 6-undecanone Further, it is invented It is clearly preferred according to the invention if the product according to the invention comprises at least 1, 2, 3, 4, 5, or 6 or even more of the abovementioned fragrances

In a preferred embodiment, the product contains certain minimum levels of perfume, namely at least 0.05% by weight, advantageously at least 0.1% by weight, in a considerably advantageous manner at least 0.15% by weight, more preferably at least 0.2% by weight %, more preferably at least 0.25% by weight, more preferably at least 0.3% by weight, most preferably at least 0.35% by weight, most preferably at least 0.4% by weight, %, in a particularly advantageous manner at least 0.45% by weight, in a significantly advantageous manner at least 0.5% by weight, very advantageously at least 0.55% by weight, very advantageously at least 0.6% by weight %, in most advantageously at least 0.65% by weight, most advantageously at least 0.7% by weight, in an exceptionally advantageous manner at least 0.75% by weight, in an exceptionally advantageous manner at least 0.8% by weight, in extraordinary amounts advantageously at least 0.8 5% by weight, in particular at least 0.9% by weight of perfume, based on the total product

In a preferred embodiment, however, the product contains relatively large amounts of perfume, namely at least 1% by weight, advantageously at least 2% by weight, in a considerably advantageous manner at least 5% by weight, more preferably at least 10% by weight, in a further advantageous manner at least 13 wt%, more preferably at least 14 wt%, most preferably at least 15 wt%, most preferably at least 16 wt%, most preferably at least 17 wt%, in substantial advantageously at least 18% by weight, very advantageously at least 19% by weight, in particular at least 20% by weight of perfume, based on the entire product Such products may be, for example, so-called aroma shower gels

However, it is rather uncommon in consumer products to realize very high perfume levels to prevent the product from being too intrusive. Rather, it is often desirable that the amount of perfume contained is limited. In a preferred embodiment, therefore, the product contains certain maximum levels of perfumeol. Namely, not more than 15% by weight, advantageously not more than 10% by weight, in a considerably advantageous manner not more than 9% by weight, more preferably not more than 8% by weight, more preferably not more than 7% by weight %, more advantageously not more than 6% by weight, very advantageously not more than 5% by weight, in a particularly advantageous manner not more than 4.5% by weight, and in a particularly advantageous manner not more than 4% by weight. in a substantially advantageous manner not more than 35% by weight, in particular not more than 3% by weight of perfume, based on the total product

It may also be advantageous to match the amounts of the different perfumes contained in one another. Thus, according to a preferred embodiment, which comprises two different although the ratio of perfume 1 to perfume 2 is more than 1/1, but less than 6/1, preferably less than 5/1, advantageously less than 4/1, more preferably less than 3/1, even more advantageously less than 2/1, in particular less than 3/2

In a preferred embodiment, the perfume oils contain less than 8, advantageously less than 7, more preferably less than 6, more preferably less than 5, more preferably less than 4, even more preferably less than 3, preferably less than 2, especially no fragrances from the list Amylcinnamal, Amylcinnamylalkohol, Benzylalkohol, Benzylsalicylat, Cinnamylalkohol, Cinnamal, Citral, Cumarin, Eugenol, Geraniol, Hydroxy- citronellal, Hydroxymethylpentylcyclohexencarboxaldehyd, Isoeugenol, Anisylalkohol, Benzylbenzoat, Benzylcinnamat, Citronellol, Farnesol, Hexylcinnamaldehyd, Lilial , d-Lιmonen, linalool, methylheptincarbonate, 3-methyl-4- (2,6,6-trmethyl-2-cyclohexen-1-yl) -3-buten-2-one, oakmouth, tree moss extract

According to general dermatological findings, in particular for detergents or cleaners, which are preferred agents according to the invention, the use concentrations hardly contain the amount of fragrance which could trigger a skin allergy, but it may be desirable to include certain substances, which may come from a third party allergenic potential is attributed rather to avoid Paying to those just mentioned

Preferred products according to the invention are detergents or cleaners, cosmetic agents and air fresheners

Preferred products within the meaning of the invention are also the so-called washing aids

(a) Gravity enhancers, such as grease removers These are mainly used for the (pre-) treatment of locally occurring grease and / or pigment soiling, and are applied directly to the textiles

(b) Pre-soaking agents These are usually strongly alkaline adjuvants (up to about pH 13) with a lower surfactant content. They promote swelling during soiling and reduce soil adhesion

(c) Separate bleaching agents such as stain salts, liquid bleaches, detergency builders They can be used both as a detergent additive and for pretreatment

(d) separate softeners, preferably containing builders such as citrates and / or zeolites and dispersants such as polycarboxylates

(e) separate discoloration inhibitors,

(a) (f) Special stain removal medium for individual stain types Preferred products within the meaning of the invention are also aftertreatment agents

(A) Weichspuler, also known as softening agent or fabric conditioner, as well as Tucher for the Trocknungsapphkation

(b) washing stiffeners which have the effect of imparting a stiff and full-bodied shape to the wash

(c) Form wipers which have the effect of consolidating textiles treated therewith in the fiber structure so that the wash obtains a light finish to strong thickening

(D) Hygienespuler, which are preferably added to the last Spulgang and contain an antimicrobial agent and preferably nonionic surfactants

(e) Bugelhilfen, which are sprayed, for example, and even without Bugein to some extent fiber-smoothing, if z B after spraying the still moist wash by hand is tightened

(f) (Gardinen) -Weιßspuler, which have the purpose to increase the whiteness (curtains) and optionally act fiber-fixing

(g) conditioning powders which provide the textile with textile treatment (eg machine washing) with active ingredients (eg oils) which can be given off to the human skin when the textile is worn and which benefit or care for the skin

(h) Bugelwasser, which mineral water or demineralized water, preferably preservatives and fragrances include, for use in steam irons

(ι) Textilerfπscher, d h products which remove odors from many textile materials, eg via encapsulation of the odors to be removed by suitable means such as cyclodextrin NEN or via other active ingredients, such as zinc ricinoleate

Preference is also 2-in-1-Waschmιttel, which in addition to the cleaning component one of the aforementioned components (a) to (ι) mitumzufassen

However, particularly preferred are any textile treatment agents, such as, for example, detergents or softeners, in liquid or in solid form. Preferred products in the meaning of the invention are therefore detergents

(a) heavy-duty detergent (preferably contains bleach, optical brightener, enzymes, etc.)

(b) color detergent, (substantially free from bleach and optical brighteners, preferably containing discoloration inhibitors, cellulases, etc.)

(c) mild detergent, (substantially free from bleach and optical brighteners, preferably lower alkalinity),

(D) special detergents, such as in particular ι) wool detergent, (preferably free of bleaching agents, optical brighteners enzymes preferably pH-neutral) ιι) Gardinenwaschmittel, in) detergent for hand washing iv) added-benefit detergent, as preferably

Detergent with Odor Absorber - UV protection detergent, hygiene detergent, cleaning aid for ballistic laundry, special detergent for black or white laundry,

Sensitive detergent, preferably containing nourishing substances, such as almond oil, aloe vera extract, etc. Duftintensiv- or aroma detergent)

In particular, the hand dishwashing means and the machine dishwashing means pay particular attention to the most preferred cleaning agents

Among the preferred cleaning agents include the toilet cleaner or toilet Reιnιger, ie products for cleaning toilet bowls and urinals, which are preferably as powder, tablets, Formkorper or liquids, preferably gels, offered Besides other conventional ingredients such as surfactants, they usually contain organic Acids (for example citric acid and / or lactic acid) or sodium hydrogen sulfate, amidosulfuric acid or phosphoric acid for the removal of calcium deposits or so-called urine stones

The preferred cleaning agents include, inter alia, the pipe cleaning agents or Abflußremi- ger These are preferably strong alkaline preparations, which are usually the elimination of pipe blockages of organic materials - such as hair, fat, food residues, soaps deposits etc - serve Zur Formation of H ₂ -GaS with a sparkling effect can serve additions of Al or Zn powder. Possible ingredients are generally alkalis, alkaline salts, oxidizing agents and neutral salts. Powdered formulations preferably also contain sodium nitrate and sodium chloride. Pipe cleaners in liquid form may preferably be present Also contain Hypochlorite There are also Enzyme-based drain cleaners. Sour preparations are also possible

The preferred cleaning agents include the universal or all-purpose cleaners or all-purpose cleaners These are universal cleaners for all hard surfaces in household and commercial use, which can be wiped wet or damp. Usually they are neutral or slightly alkaline or weakly acidic products. In particular Flussigprodukte all - purpose cleaner or all - purpose cleaner usually contain surfactant scaffolds, solvents and hydrotropes preservatives etc

There are also special disinfectant all-purpose cleaners These additionally contain antimicrobial agents (eg aldehydes, alcohols, quaternary ammonium compounds, amphoteric surfactants, tinclosans) The sanitary cleaners are also used to remove grease soiling, while the acidic sanitary cleaners are mainly used to remove limescale deposits a significant disinfecting effect, especially the strongly alkaline, chlorine-containing sanitary cleaner

The preferred cleaning agents include the oven cleaners or greasy cleaners, which are advantageously offered in the form of gels or foam sprays. These are generally used to remove burnt or charred food particles. Oven cleaners such as sodium hydroxide, sodium metasilicate and 2-aminoethanol are highly alkaline In general, they also contain anionic and / or nonionic surfactants, water-soluble solvents and some thickeners such as polycarboxylates, carboxymethylcellulose Among the preferred cleaning agents pay including the metal cleaning agents that are cleaners for certain types of metals such as stainless steel or silver stainless steel cleaner preferably contain in addition to acids (preferably up to 3% by weight, for example citric acid, lactic acid), surfactants (in particular up to 5% by weight, preferably nonionic and / or anionic surfactants), water also solvents (preferably up to 15% by weight) for eliminating fat-containing compounds Dyes and other substances such as thickeners and preservatives Very fine Polierkorper are also contained in products for preferably glossy stainless steel surfaces Silberputzmittel in turn are preferably acidic They contain, in particular for the removal of black deposits of silver sulfide preferably complexing agent (eg thiourea, Natπumthiosulfat) Typical supply forms are cleaners, immersion baths, pastes, liquids To remove dark discolorations (oxide layers), copper and non-ferrous metal cleaners (eg brass and bronze) are used. These are usually slightly alkaline (preferably with ammonia) and usually contain polishing agents as well as preferably Ammonium soaps and / or complexing agents

The preferred cleaning agents include the glass cleaners or window cleaners which are preferably used to remove greasy dirt from glass surfaces. They preferably contain substances such as anionic and / or nonionic surfactants (in particular up to 5% by weight), ammonia and / or ethanolamine (in particular bis 1% by weight), ethanol and / or 2-propanol, glycol ethers (especially 10-30% by weight), water, preservatives, colorants, anti-fogging agents, etc

The preferred cleaning agents include, among other things, all special cleaning agents, such as those for glass ceramic hobs, as well as carpet and upholstery cleaner and stain remover According to the invention preferred products are also car care products Among the preferred car care products include paint preservatives, paint polishes Lackreiniger Waschkonservierer Sham- poos for car wash, car wash and wax products, polishes for decorative metals, protective films for decorative metals, plastic cleaners, tar removers, window cleaners, engine cleaners, etc

Adhesives, sealants, lacquers and / or solvent-containing liquids may likewise be preferred products according to the invention

Preferred cosmetic agents are preferred

(a) cosmetic preparations for skin care, in particular bath preparations, skin washing and cleaning compositions, skin care preparations, ocular cosmetics, lip care preparations, nail care products, personal care products, foot care products, shower gel

(b) cosmetic agents having a specific action, in particular light stabilizers, skin tanning agents, depigmentation agents, deodorants, antihidrotic agents, depilatories, shaving compositions, fragrances,

(c) cosmetic preparations for dental care, in particular dental and oral care products, denture care products, denture cleansing preparations, denture adhesives,

(D) cosmetic compositions for hair care, in particular shampoo, hair care products, hair setting, hair shaping, hair dye

Preferred ingredients of the consumer products according to the invention, in particular of the cosmetic agents, can be defined by their function. Of course, some ingredients may also be multifunctional

Preferred ingredients of the inventive consumption products, preferably cosmetic products may be a) absorbent

These preferably have the task of absorbing water and / or oil-soluble dissolved or finely divided substances b) antimicrobial substances

These can be added to the products to generally reduce the activities of microorganisms, such as on the skin and in the oral cavity. C) Antioxidants

These are intended to prevent oxygen-triggered reactions such as oxidation and thus prolong the shelf life of the products, ie the quality of the products obtained d) antiperspirants

These are preferably used in cosmetics and reduce the sweat e) antifoam

These may be added, for example, to remove foam during manufacture or to reduce the tendency of finished products to over-foam. F) Antidandruff active ingredients These are used primarily in hair care products, as they can counteract dandruff g) antistatic agents

These are, for example, combability aids in hair care products. They generally reduce the electrostatic charge on objects, for example the hair-surface hairs can be combed so much more easily h) Binders

They ensure, for example, the cohesion of powdered and powdered products, such as cosmetic preparations, for example, substances of biological origin

These are, for example, certain phytonutrients, such as Gruner tea extract. They are intended to confer on a product certain desired properties which are related to the corresponding biological material or to further improve existing properties or to suppress undesired properties as far as possible reduce j) bleach

These can be used, for example, to lighten the color of the hair or the skin. K) Chelating agents

These are added, for example, to cosmetics to form complexes with metal ions, for example to manipulate the stability and / or the appearance of the agents. I) Deodorizers / antiperspirants

These can help prevent or reduce the appearance of unpleasant body odors. They can mask such odors and reduce perspiration if necessary. M) Emollients

These have, for example, in the cosmetic field, the task of making the skin supple and smooth n) emulsifiers

These are surface-active substances which are preferably capable of stably dispersing immiscible liquids such as oil and water into one another o) emulsion stabilizers

These can further support the process of emulsification (see emulsifiers) and thus further improve the stability and shelf life of the product. P) depilatories

These serve the preferably selective removal of body hair q) moisturizer

These can contribute to the maintenance or restoration of skin moisture and counteract the drying out of the skin. R) Film formers These are able to do so, for example, in cosmetic products a protective stabilizing film on surfaces Preferably to produce skin, hair or nails s) dyes

These are, for example, also added to cosmetic products in order to produce a product color or else to bring about an indirect object coloration, for example hair coloring t) preservatives

These are added, for example, to cosmetic products in order to protect them from the harmful action of microorganisms (bacteria, fungi, yeasts) and thus to prevent their spoilage u) anticorrosive agents

These can serve, for example, to prevent the corrosion of the packaging, for example of a cosmetic agent, or else the corrosion of parts which otherwise come into contact with the agent

They may, for example, be the basis for, for example, liquid cosmetic preparations or else be part of solid products w) oral care substances

These can serve the care of teething and gums x) oxidizing agents

They can serve to change the chemical nature of other substances by oxidation y) pH regulator / buffer substances

These may serve, for example, in cosmetics to adjust or stabilize a desired pH z) reducing agent

These are able to change the chemical nature of another substance by redox processes aa) abrasives

These can be used to remove materials from different (body) surfaces, for example, to assist the mechanical cleaning of the teeth or to improve tooth gloss. B) Surfactants / wash-active substances

These are surface-active compounds used for cleaning purposes cc) propellants

These are gaseous substances with which products z B cosmetic agents can be placed under pressure in pressure-resistant containers to bring out the content then at pressure relief dd) turbidity

These can be added preferably transparent or translucent products to make them more impenetrable to visible light or near-light radiation ee) UV absorber / light filter substances They are able to filter certain UV rays and can thus protect the skin, for example, from premature light-induced aging and from sunburn

These are added, for example, to cosmetics containing ethanol in order to render them inedible. Gg) Viscosity regulators These are able to increase or decrease the viscosity of a product

The aforementioned ingredients may be contained according to a preferred embodiments in the inventive products, preferably cosmetic agents

According to the invention, it can be of great advantage if certain fragrances are contained in the products, preferably in certain products

It corresponds to a preferred embodiment, if the inventive products at least one fragrance, preferably 2, 3 or more fragrances from the list Galaxolid, Dihydro- myrcenol, 4-tert-Butylcyclohexylacetat, gamma-ιso-Methylιonon, tetrahydrolmalool, Hexylcinna- maldehyde, Lihal , Linalool, amyl cinnamaldehyde, 6-methyl-gamma-1-methyloleate, neryl acetate 15-pentadecalactone, phenoxyethyhsobutyrate, phenylethylmethanoate, α-pyrene, b-pillene, rose oxides, sabinene, anethole, benzoic acid 2-hydroxypentyl ester, diphenyl ether, benzophenone, cyclobutene lamenaldehyde, a-damascone, decanal, dicyclopentadiene, alcohol, allylcyclohexylpropionate, isoboronyl acetate, bornylacetate, dihydromethyljasmonate, eucalyptol, n-dodecanol, ethyl palmitate, geranoacetate, hexyl acetate, n-hexyl salicylate, a-ionone, 1-methylene, methyl palmitate, 2 Naphthyl methyl ketone, isopropyl, rosephenone, a-terpιneol, styrallyl acetate, thujops, Dimethylbenzylcarbinyl- butyrate, d-Lιmonen, Dimethylbenzylcarbinylace citronellol, 2-tert-butylcyclohexanol, caryophyllenes, ethyl stearate, tartalide, 2,4-hexadienal, methanoazulene, methyl laurate, methylmyristate, 2-methyl undecanal, myrcene, nonanal, nopyl acetate, 15-pentadecalactone, beta-phellandrene 3 Phenyl 2-methylpropene, rosacetate, Traseohde, Widdrene and / or d-Lιmonen, contain most preferred are the fragrances methyl oleate, methyl palmitate, methyl laurate, eucalyptol, Dihydromethyljasmonat, Dimethylbenzylcarbinylacetat, diphenyl ether, Hexylcinnamaldehyd, Lihal, linalool, methyl oleate, Methylmyπstat , d-Lιmonen, dihydromyrcenol, 4-tert-butylcyclohexyl acetate, a-Damascon, a-terpιneol, Tonalid, Galaxolid, dodecanol, isopropyl, gamma-iso-methylionone, Isobornylacetat, Bornylacetet, 6-methyl-γ-γ-ionone and / or Tetrahydrolinalooi Especially in solid, preferably powdery products of the fragrance dihydromyrcenol is extremely preferred, especially in detergents and Maschinengeschirrspulmitteln particular in liquid, preferably gelformigen products of the fragrance d-Lιmonen be preferred, especially in the cleaning agents

The aforementioned embodiment is particularly preferred very strongly when the products according to the invention are detergents or cleaners Particularly preferred products are also the air improvers and room fragrancing agents Such products contain volatiles and usually pleasant smelling substances, which can advantageously cover even in very small amounts of bad smells Air freshener for living spaces contain in particular natural and synthetic essential oils such as Komferennadelόle, Citrusol, Eucalyptusöl, Lavendelol etc, For example, in amounts of up to 50% by weight. As aerosols, they contain rather lower amounts of such essential oils, for example less than 5% by weight or less than 2% by weight, but preferably also substances such as acetaldehyde (in particular <0.5% by weight). Isopropyl alcohol (in particular <5% by weight), mineral oil (in particular <5% by weight) and propellant gases. Other dosage form are sticks and blocks. A gel concentrate of essential oils is preferably used in their preparation. Advantageously, formaldehyde (for preservation) and chlorophyll (preferably <5 Gew -%) are added, as well as other ingredients

However, air fresheners are not restricted to living spaces, but can also be provided for cars, barriers, winders, refrigerators, shoes and even use in vacuum cleaners. In households (eg in barriers) disinfectants are used in addition to the odor improvers , which preferably contain substances such as calcium phosphate, talc, stearin and essential oils, for example in the form of sachets

The means according to the invention can be used for scenting an article, a surface or a room, preferably textile fabrics, household surfaces, shoes, garbage containers, recycling containers, air, larger domestic appliances, cat litter, pets, pet sleeping items, in particular garments, carpets, carpeting, curtains , Curtains, upholstered furniture, bed linen, tents, sleeping bags, car seats, car mats, textile car interior linings, bar surfaces, walls, floors, bathroom surfaces, cake surfaces, refrigerators, freezers, washing machines, dishwashers, washers, ovens and microwave ovens used directly or indirectly can be applied in any form, for example, be sprayed by means of a Spruhapplikators

According to a further preferred embodiment, the perfume substances from the group essences of fruits fruit parts and / or other parts of plants, preferably herbs drugs derived essential oils preferred terpene-free oils and / or artificial essences preferably from synthetic odorants and / or flavors particularly preferably vanillin, Menthol and / or eucalyptol, and / or

Flavors, preferably essential oils Anisole Star anisole Bitter almond oil Eucalyptol, Fencholol, Peppermintol Citron oil Wintergrunol Clove oil, Menthol and / or Kummelol and / or EP2006 / 007953

38

synthetic odoriferous compounds of the ester type, preferably benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinyl acetate, phenylethyl acetate, lmalyl benzoate, benzyl formate, ethylmethylphenyl glycinate, allylcyclohexyl propionate, styrallyl propionate and / or benzyl salicylate, and / or synthetic fragrance compounds of the ether type, preferably benzyl ethyl ether, and / or synthetic fragrance compounds of the aldehyde type, preferably linear alkanals having 8-18 C atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamaldehyde, hydroxycitronellal, Lilial and / or Bourgeonal, and / or synthetic fragrance compounds of the ketone type, preferably ionone, isomethyhonone and / or methyl cedryl ketone, and / or synthetic fragrance compounds of the alcohol type, preferably anole, citronel, citronellol, eugenol, geraniol , Linalool, phenylethyl alcohol and / or terpineol, and / or synthetic R hydrocarbon compounds of the hydrocarbon type, preferably terpenes, preferably limonene and pine, and / or natural perfume mixtures from vegetable sources, preferably pine, citrus, jasmine, patchouli, rose or ylang-ylang oil, muscatel, salbeiol, chamomile oil , Clove oil, melis- senol, mint oil, cinnamon leaf lateol, linden blutenol, juniper berberol, vetiverol, olibanumol, galabumol, labdanumol, orange blutenol, neroliol, orange peel oil and / or Sandelhol.zol

It may be advantageous to accelerate or retard the release of the fragrances, ie the perfume ingredients, depending on the particular application. For example, when applying agents according to the invention in a washing or cleaning liquor, it may be advantageous to release with a delay, since in such cases It may be desirable that the fragrances should unfold fully on the treated article

However, it may also be desirable, for example in the cleaning of hard surfaces, that the fragrances of the perfumes develop substantially evenly over the duration of the cleaning step

For these purposes one can combine the perfumes with carriers or incorporate them into carriers which corresponds to a preferred embodiment

Suitable carriers for the perfumes or perfumes may preferably be selected from the group comprising polymers siloxanes, silicon-containing compounds modified with organic radicals. Betaine paraffin surfactants, in particular ethoxylated fatty alcohols, fatty acid siliconeols and / or fatty alcohol, preferably lipophilic substances, lipophilic substances having a melting point above 25 ° C. particularly preferred are erfmdungsgemaß particularly suitable carriers for the erfmdungsgemaß usable fragrances or perfumes are meltable or softenable substances from the group of waxes paraffins polyalky- 006/007953

39

glycols and the like The meltable or softenable substances preferably have a melting range of between about 45 ° C and about 75 ° C. That is, in the present case, the melting range occurs within the specified temperature interval and does not indicate the width of the melting range

"Waxes" a number of natural or synthetic substances is understood that melt usually about 4O ⁰ C. without decomposition and even a little of relatively low viscosity above the melting point and not stringy you have a highly temperature-dependent consistency and Loshchkeit on by origin shares the waxes into three groups, the natural waxes, chemically modified waxes and the synthetic waxes

The natural waxes include, for example, vegetable waxes such as candelilla wax, carnauba wax, Japan wax, Espartograswachs, cork wax, guarumewax, rice germ wax, sugarcane wax, ouricury wax, or montan wax, animal waxes such as beeswax, shellac wax, spermaceti, lanolin (wool wax), or Burzelfett, mineral waxes such as Ceresin or Ozokent (ground wax), or petrochemical waxes such as petrolatum, paraffin waxes or microwaxes

For example, hard waxes such as montan ester waxes, Sassol waxes or hydrogenated jojoba waxes pay for the chemically modified waxes

Synthetic waxes are generally understood as meaning polyalkylene waxes or polyalkylene glycol waxes. It is also possible to use compounds of other substance classes which meet the stated requirements with regard to the softening point as meltable or softenable substances for the compositions curing by cooling. Suitable synthetic compounds are, for example Higher esters of phthalic acid, in particular dicyclohexylphthalate, which is commercially available under the name Unimoll® 66 (Bayer AG), are also suitable Synthetically prepared waxes of lower carboxylic acids and fatty alcohols, for example Dimyπstyl tartrate, sold under the name Cosmacol® ETLP ( Conversely, synthetic or partially synthetic esters of lower alcohols with fatty acids from native sources can also be used. For example, the Tegm.RTM. 90 (Goldschmidt), a glycerol monostearate palmitate, is also found in this class of substances For example, shellac KPS-Dreιrιng-SP (Kalkhoff GmbH) is erfmdungsgemaß used as meltable or softenable substances

Wax alcohols are high molecular weight, water-insoluble fatty alcohols with generally about 22 to 40 carbon atoms. The wax alcohols are used, for example, in the form of wax esters of high molecular weight fatty acids (wax acids) as the main constituent of many natural waxes Examples of wax alcohols are lignoceryl alcohol (1) ⁱⁱ vu. ^v,, . ~. PCT / EP2006 / 007953

40

Tetracosanol), Cetylalkohol, Myπstylalkohol or Melissylalkohol Further usable melt and softenable substances are the Wollwachsalkohole, which are understood by Tnterpenoid- and Steroidalko, for example lanolin, which is available for example under the trade name Argowax® (Pamentier & Co) likewise at least in the context of the present invention, fatty acid glycine esters or fatty acid alkanolamides but optionally also water-insoluble or only slightly water-soluble polyalkylene glycol compounds can be used as part of the meltable or softenable substances

Particularly preferred meltable or softenable carriers are those from the group of polyethylene glycols (PEG) and / or polypropylene glycols (PPG), with polyethylene glycols having molecular weights between 1500 and 36,000 are preferred, those having molecular weights of 2000 to 6000, more preferably and those with Molecular weights of from 3,000 to 5,000 are particularly preferred. Corresponding processes are characterized in that the plastically deformable mass (s) contains / contain at least one substance from the group of polyethylene glycols (PEG) and / or polypropylene glycols (PPG) prefers

Particular preference is given to compositions which comprise propylene glycols (PPG) and / or polyethylene glycols (PEG) as the only meltable or softenable substances. Polypropylene glycols (abbreviated PPG) which can be used according to the invention are polymers of propylene glycol which satisfy the following general formula, n values being between 10 and 2000. Preferred PPG's have molecular weights between 1000 and 10,000, corresponding to values of n between 17 and about 170

Polyethylene glycols (abbreviation PEG) which can preferably be used as polymeric carriers in accordance with the invention are polymers of ethylene glycol which satisfy the general formula H- (O-CH ₂ -CH ₂ ) _n -OH, where n can assume values between 20 and about 1000 Preferred molecular weight ranges correspond to preferred ranges of the value n in formula IV of from 30 to 820, in particular from 34 to 818, particularly preferably from 40 to 150, in particular from 45 to 136 and more preferably from 70 to 120, in particular from 68 to 113

According to a further preferred embodiment of the invention, the product according to the invention thus comprises perfume or perfume which has been stored. The carrier substances are preferably selected from the group consisting of polymers containing siloxanes with organically modified silicon-containing compounds, betaines, paraffins, surfactants, in particular ethoxylated fatty alcohols, fatty acids , Silicone oils and / or fatty alcohol, preferably hpophile substances, with lipophilic substances having a melting point above 25 ⁰ C are particularly preferred

According to a further preferred embodiment of the product according to the invention, the ratio of parfumol to carrier substance / e in the case of a stored perfume oil is in the range from 20 l to 110, preferably from 5 l to 10 l and preferably 31 l In a further preferred embodiment, the fusible and softenable carriers which can be used according to the invention contain predominantly paraffin wax. This means that at least 50% by weight of the total meltable or softenable substances contained, preferably more, consist of paraffin wax. Paraffin wax contents (based on the Total amount of meltable or softenable substances) of about 60% by weight, about 70% by weight or about 80% by weight, even higher proportions of, for example, more than 90% by weight being particularly preferred. In one particular embodiment of the invention, the total amount is the meltable or softenable substances used at least one mass exclusively of paraffin wax

In the context of the present invention, paraffin waxes have the advantage over the other natural waxes mentioned that no hydrolysis of the waxes takes place in an alkaline cleaning agent environment (as is to be expected, for example, with wax esters), since paraffin wax does not contain any hydrosettable groups

Paraffin waxes consist mainly of alkanes and small amounts of iso- and cyclo alkanes The erfmdungsgemaß usable paraffin preferably has substantially no constituents with a melting point of greater than 7O ⁰ C, particularly preferably of more than 6O ⁰ C, high-melting alkanes in the paraffin may leave below the melt temperature in the detergent liquid unwanted wax residue on the surfaces to be cleaned or the good to be cleaned Such wax residue usually lead to an ugly appearance of the cleaned surface and should therefore be avoided

Preferably to be processed meltable or softenable carrier substances or Tragerstoffgemische contain at least one paraffin wax having a melting range of 5O ⁰ C to 60 ⁰ C, said method preferred are CHARACTERIZED in that the warp face (s) Mass (s) a paraffin wax having a melting range of 50 ⁰ C to 55 ⁰ C contains / contain

Preferred carriers suitable for use with the perfume oils can also be selected from the group of water-soluble polymers, of which only the most important are water-soluble nonionic polymers (polyvinylpyrrolidones, vinylpyrrolidone / vinylester copolymers, cellulose ethers), water-soluble amphoteric polymers (alkylacrylamide / Acrylic Acid Copolymers Alkylacrylamide / Methacrylic Acid Copolymers, Alkylacrylamide / Methylmethacrylic Acid Copolymers Alkylacrylamide / Acrylic Acid / Alkylaminoalkyl (meth) acrylic acid Copolymers, Alkylacrylamide / Methacrylic Acid / AlkylaminoalkyKmethacrylic Acid Copolymers Alkylacrylamide / Methyl- methacrylic acid / alkylamino-alkyl (meth) acrylic acid copolymers alkylacrylamide / alkymethacrylate / alkylaminoethyl methacrylate / alkyl methacrylate copolymers, copolymers of unsaturated carboxylic acids EP2006 / 007953

42

cationically denatured unsaturated carboxylic acids, optionally further ionic or nonionic monomers, water-soluble zwitteπonischen polymers (Acrylamidoalkyltπalkyl- ammoniumchloπd / acrylic acid copolymers and their alkali and Ammomumsalze, Acrylamidoal- kyltnalkylammoniumchloπd / methacrylic acid copolymers and their alkali metal and Ammomumsalze, methacroylethylbetam / methacrylate Copolymers), water-soluble anionic polymers (vinyl acetate / crotonic acid copolymers, vinylpyrrolidone / vinyl acrylate copolymers, acrylic acid / ethyl acrylate / N-tert-butylacrylamide terpolymers, graft polymers of vinyl esters, esters of acrylic acid or methacrylic acid alone or in a mixture, copolymerized with Crotonic acid, acrylic acid or methacrylic acid with polyalkylene oxides and / or polyalkylene glycols), grafted and crosslinked copolymers (from the copolymerization of a) at least one nonionic type monomer, b) at least one ionic type monomer, c) from polyethyl englycol and d) a crosslinked copolymer obtained by copolymerizing at least one monomer of each of the following three groups a) esters of unsaturated alcohols and short-chain saturated carboxylic acids and / or esters of short-chain saturated alcohols and unsaturated carboxylic acids, b) unsaturated carboxylic acids, c) esters of long-chain carboxylic acids and unsaturated alcohols and / or esters of the carboxylic acids from the group of saturated or unsaturated, straight-chain or branched C 8-18 alcohols, terpolymers of crotonic acid, vinyl acetate and an allyl or methyl thallylester, tetra and pentapolymers of a) crotonic acid or Allyloxyacetic acid, b) vinyl acetate or vinyl propionate, c) branched allyl or methallyl esters, d) vinyl ethers, vinyl esters or straight-chain allyl or methallyl esters, crotonic acid copolymers with one or more monomers selected from ethylene, vinylbenzene, vinylmethyl ether, acrylamide and their water-soluble salts , Terpolymer e from vinyl acetate, crotonic acid and vinyl esters of a saturated aliphatic branched monocarboxylic acid), water-soluble cationic polymers (quaternized cellulose derivatives, polysiloxanes with quaternary groups, cationic guar derivatives, polymers dimethyl-diallylammonium salts and their copolymers with esters and amides of acrylic acid and methacrylic acid, copolymers of vinylpyrrolidone with quaternized derivatives of dialkylamino acrylate and methacrylate, vinylpyrrolidone-methoimidazolinium-chloπd copolymers, quaternized polyvinyl alcohol, under the INCI names Polyquaternium 2, Polyquaternium 17, Polyquaternium 18 and Polyquaternium 27 specified polymers carriers in the form of water-soluble polymers in the context of the invention are those polymers which are soluble in water at room temperature in water to more than 2.5 wt .-% The carriers can erfmdungsgemaß alone or as mixtures are used

According to a preferred embodiment, a erfmdungsgemaßes means thus entraerged parfumol

According to a further preferred embodiment, the product according to the invention, such as, in particular, washing, care or cleaning agents, at least one, preferably several, active components, in particular washing, care and / or cleaning-active components advantageously. optionally selected from the group comprising anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, acidifiers, alkalizing agents anti-wrinkle compounds, antibacterial agents, antioxidants, anti redeposition agents, antistatic agents, builders, bleaches, bleach activators, bleach stabilizers, bleach catalysts, Ironing aids, cobuilders, anti-shrinkage agents, electrolytes, enzymes, colorants, colorants, dyes, color transfer inhibitors, fluorescers, fungicides, germicides, odor-complexing substances, auxiliaries, hydrotropes, rinse aids, complexing agents, preservatives, corrosion inhibitors, optical brighteners, perfume carriers, pearlescers, pH adjusters Adjusting agents, repellents and impregnating agents, polymers, swelling and anti-slip agents, foam inhibitors, phyllosilicates, dirt-repellent substances, silver protection agents, silicone polyols, UV protection substances Viscosity regulators, thickeners, Ver color inhibitors, grayness inhibitors, vitamins and / or Weichspuler

For the purposes of this invention, details for the product according to the invention in% by weight, unless stated otherwise, relate to the total weight of the product according to the invention. The terms product according to the invention, product of consumption and agent are used synonymously unless otherwise stated

The amounts of the individual ingredients in the compositions according to the invention are in each case based on the intended use of the agents in question and the person skilled in the art is familiar with the magnitudes of the amounts of ingredients to be used or can refer to the corresponding technical literature Typically, for example, the surfactant content of, for example, laundry detergents z B may be between 10 and 50% by weight, preferably between 12.5 and 30% by weight and in particular between 15 and 25% by weight, while dishwasher detergents may be used for example usually between 0.1 and 10% by weight, preferably between 0.5 and 7.5% by weight and in particular between 1 and 5% by weight of surfactants

Preferred ingredients of the compositions according to the invention are described in more detail below. Aniomic surfactants are preferably contained in the products according to the invention. Suitable anionic surfactants are, for example, those of the sulfonate and sulfates type. The surfactants of the sulfonate type are preferably C ₉ . _13- Alkylbenzolsulfonate, olefinsulfonates ie mixtures of alkene and hydroxyalkanesulfonates and disulfonates, as obtained for example from C _{12 18} monoolefins with terminal or internal double bond by sulfonation with gaseous sulfur trioxide and subsequent alkaline or acidic hydrolysis of the sulfonation in consideration Suitable are also alkanesulfonates which are obtained from C _{12 18} alkanes, for example, by sulfochlorination or sulfoxidation followed by hydrolysis or neutralization. Likewise, the esters of α-sulfo fatty acids (ester sulfonates) z B, the α-sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow fatty acids are suitable Further suitable anionic surfactants are sulfonated fatty acid glycyl esters. Fatty acid glyceryl esters are the mono-, di- and tri-esters and mixtures thereof, as in the preparation by esterification of a monoglycerine with 1 to 3 mol fatty acid or in the transesterification of triglycerides with Preferred sulfated fatty acid glycyl esters are the sulfonation products of saturated fatty acids containing 6 to 22 carbon atoms, for example caproic acid, caprylic acid, capnic acid, myristic acid, lauric acid, palmitic acid, stearic acid or behenic acid

Alk (en) ylsulfates are the alkali metal salts and in particular the sodium salts of the sulfuric monoesters of C ₁₂ -C ₁₈ -FeHaIkOhOIe, for example from coconut fatty alcohol, tallow fatty alcohol, lauryl, Myπstyl-, cetyl or stearyl alcohol or C ₁₀ -C ₂₀ -oxo alcohols and those half-esters of secondary alcohols of these chain lengths are furthermore preferred. Alk (en) ylsulfates of said chain length which contain a synthetic, petrochemical-based straight-chain alkyl radical which has an analogous decomposition behavior to the adequate compounds based on oleochemical raw materials washing technology, the C ₁₂ -C ₁₆ alkyl sulfates and C ₁₂ -C ₁₅ alkyl sulfates and C ₄ -C ₅ alkyl sulfates preferably 2,3-alkyl sulfates can be obtained as commercial products from Shell Oil Company under the name DAN ^®, are suitable anionic surfactants

Also the sulfuric acid monoesters of the straight-chain or branched C ₇ ethoxy-esterified with 1 to 6 moles of ethylene oxide. ₂₁ -alcohols, such as 2-methyl-branched C _9-11 alcohols having on average 3.5 moles of ethylene oxide (EO) or C ₁₂ . _18- fatty alcohols with 1 to 4 EO, are suitable They are particularly in detergents due to their high foaming behavior preferably only in relatively small amounts, for example in amounts of 1 to 5 wt -%, used

Another class of anionic surfactants is the class of ether carboxylic acids obtainable by reaction of fatty alcohol ethoxylates with sodium chloroacetate in the presence of basic catalysts. They have the general formula R ¹⁰ O- (CH ₂ -CH ₂ -O) _p -CH ₂ -COO H with R ¹⁰ = C ₁ -C ₁₈ and p = 0, 1 to 20 Ethercarbonsauren are wasserharteunempfindlich and have excellent surfactant properties

Examples of suitable anionic surfactants are the partial esters of di- or polyhydroxyalkanes, mono- and disaccharides, polyethylene glycols with the maleic anhydride adducts of at least monounsaturated carboxylic acids having a chain length of from 10 to 25 carbon atoms with an acid number of from 10 to 140

Preferred anionic surfactants have, in addition to an unbranched or branched saturated or unsaturated aliphatic or aromatic, acyclic or cycloaliphatic alkoxy- lierten alkyl radical having 4 to 28, preferably 6 to 20, especially 8 to 18, particularly preferably 10 to 16, most preferably 12 to 14 carbon atoms, two or more anionic especially two, acid groups, preferably carboxylate, sulfonate and / or sulfate groups in particular a carboxylate and a sulfate group, examples of these compounds are the '- sulfo fatty acid salts, the acyl glutamates, the Monoglyceπddisulfate and the alkyl ethers of glyceπn disulfate and in particular the monoester sulfosuccinates described below

Particularly preferred anionic surfactants are the sulfosuccinates, sulfosuccinamates and sulfosuccinamides, in particular sulfosuccinates and sulfosuccinamates, most preferably sulfosuccinates. The sulfosuccinates are the salts of the mono- and di-esters of sulfosuccinic acid HOOCCI-I (SO ₃ H). CH ₂ COOH, while among the sulfosuccinamates the salts of the monoamides of sulfosuccinic acid and of the sulfosuccinamides are the salts of the diamides of sulfosuccinic acid

The salts are preferably alkali metal salts, ammonium salts and mono-, di- or tri-alkanolammonium salts, for example mono-, di- or triethanolammonium salts, in particular lithium, sodium, potassium or ammonium salts, particularly preferably sodium or ammonium salts preferably sodium salts

In the sulfosuccinates, one or both carboxy groups of the sulfosuccinic acid are preferably with one or two identical or different unbranched or branched, saturated or unsaturated, acyclic or cyan, optionally alkoxylated alcohols having 4 to 22, preferably 6 to 20, in particular 8 to 18, especially The esters of unbranched and / or saturated and / or acyclic and / or alkoxylated alcohols, in particular unbranched, saturated fatty alcohols and / or unbranched, saturated, with ethylene and / or. preferably are from 10 to 16, more preferably 12 to 14 carbon atoms esterified Propylene oxide, preferably ethylene oxide, alkoxylated fatty alcohols having a degree of alkoxylation of 1 to 20 preferably 1 to 15, especially 1 to 10, particularly preferably 1 to 6, most preferably 1 to 4 The monoesters are preferred in the context of the present invention over the diesters A particularly preferred Sulfosucci nat is Sulfobernsteιnsaurelaurylpolyglykolester-dι- Natπum salt (lauryl EO sulfosuccιnat, di-Na salt, INCI Disodium Laureth Sulfosuccinate) containing 30 (Goldschmidt) with a Sulfosuccmatgehalt of 30 wt example as Tego ^® sulfosuccinate F - is% commercially available

In the sulfosuccinamates or sulfosuccinamides, one or both carboxy groups of the sulfosuccinic acid, preferably with one primary or secondary amine, forms the one or two identical or different unbranched or branched saturated or unsaturated acyclic or cyclic optionally alkoxylated alkyl radicals having 4 to 22, preferably 6 to 20, in particular 8 to 18, more preferably 10 to 16, most preferably 12 to 14 carbon atoms A carboxylic acid amide is particularly preferred are unbranched and / or saturated and / or acyclic alkyl radicals, in particular unbranched, saturated fatty alkyl radicals

Further suitable examples are the following according to INCI sulfosuccinates and sulfosuccinamates, which are described in more detail in the International Cosmetic Ingredient Dictionary and Handbook Ammonium Dinonyl Sulfosuccinate, Ammonium Lauryl Sulfosuccinate, Diammonium Dimethicone Copolyol Sulfosuccinate, Diammonium Lauramido-MEA Sulfosuccinate, Diamonium Lauryl Sulfosuccinate , Diammonium Oleamido PEG-2 Sulfosuccinate, Diamyl Sodium Sulfosuccinate, Dicapryl Sodium Sulfosuccinate, Dicyclohexyl Sodium Sulfosuccinate, Diheptyl Sodium Sulfosuccinate, Dihexyl Sodium Sulfosuccinate, Diisobutyl Sodium Sulfosuccinate, Dioctyl Sodium Sulfosuccinate, Disodium Cetearyl Sulfosuccinate, Disodium Cocamido MEA Sulfosuccmate, Disodium Cocamido Glucoside Sulfosuccinates, disodium cocoyl butyl gluceth-10 sulfosuccinates, disodium C12-15 pareth sulfosuccinates, disodium deceth-5 sulfosuccinates, disodium deceth-6 sulfosuccinates, disodium dihydroxyethyl sulfosuccinyl undecylenates, disodium dimes thicone Copolyol Sulfosuccinate, Disodium Hydrogenated Cottonseed Glyceπde Sulfosuccinate, Disodium Isodecyl Sulfosuccinate, Disodium Isostearamido MEA Sulfosuccmate, Disodium Isostearamido MIPA Sulfosuccinate, Disodium Isostearyl Sulfosuccinate, Disodium Laneth-5 Sulfosuccinate, Disodium Lauramido MEA Sulfosuccmate, Disodium Lauramido PEG-2 Sulfosuccinate , Disodium lauramido PEG-5 sulfosuccinates, disodium laureth-6 sulfosuccinates, disodium laureth-9 sulfosuccinates, disodium laureth-12 sulfosuccinates, disodium lauryl sulfosuccinates, disodium my- stamido MEA sulfosuccinates, disodium nonoxynol-10 sulfosuccinates, disodium oleamido MEA sulfosuccinates, Disodium Oleamido MIPA Sulphosuccinates, Disodium Oleamido PEG-2 Sulfosuccinates, Disodium Oleth-3 Sulfosuccinates, Disodium Oleyl Sulfosuccinates, Disodium Palmitamido PEG-2 Sulfosuccinates, Disodium Palmitoleamido PEG-2 Sulfosuccinates, Disodium PEG-4 Cocamido MIPA Sulfosuccinates, Disodium PEG-5 Lauryl citrate sulfosuccinate, disodium PEG-8 Pa In Glyceπdes Sulfosuccinate, Disodium Ricinoleamido MEA Sulfosuccmate, Disodium Sotostereth-14 Sulfosuccinate, Disodium Stearamido MEA Sulfosuccmate, Disodium Stearyl Sulfosuccinamate, Disodium Stearyl Sulfosuccinate, Disodium Tallamido MEA Sulfosuccmate, Disodium Tallowamido MEA Sulfosuccmate, Disodium Tallow Sulfosuccinamate, Disodium Tπdecylsulfosuccinate, Disodium Undecylenamido MEA Sulfosuccinate, Disodium Undecylenamido PEG-2 Sulfosuccinate, Disodium Wheat Germamido MEA Sulfosuccmate, Disodium Wheat Germamido PEG-2 Sulfosuccinate, DICA-Oleamido PEG-2 Sulfosuccinate, Ditπdecyl Sodium Sulfosuccinate, Sodium Bisglycol Ricinosulfosuccinate , Sodium / MEA Laureth-2 Sulfosuccinate and Tetrasodium Dicarboxyethyl Stearyl Sulfosuccinamate Yet another suitable sulfosuccinamate is Dιnatrιum-C ₁₆ .i ₈ - alkoxypropyiensulfosuccinamat

The content of the agent according to the invention of anionic surfactants, preferably of the stated anionic surfactants, can vary within wide ranges, depending on the purpose of the agent in question. Thus, an agent according to the invention can contain very large amounts of anionic surfactants. Also, an agent according to the invention may contain only very small amounts of anionic surfactant, for example less than 15 or 10% by weight or less than 5% by weight or even less Advantageously, however, the compositions according to the invention contain anionic surfactants in amounts of from 2 to 35% by weight and in particular from 5 to 30% by weight, with concentrations above 10% by weight and even above 15% by weight having particular preference preferred embodiment contains the product according to the invention anionic surfactants, preferably in amounts of at least 0, 1 wt -%

It should be noted at this point that a percentage by weight, unless otherwise stated, relates in each case to the entire agent or product

In addition to the anionic surfactants mentioned, but also independently of these, soaps may be present in the inventive compositions are particularly saturated fatty acid soaps, such as the salts of lauric, Myπstinsaure, palmitic, stearic hydrogenated erucic acid and behenic acid and in particular from natural fatty acids, c coconut, palm kernel or tallow fatty acids, derived soap mixtures The content of the soap soaps is independent of other anionic surfactants, preferably not more than 3% by weight and in particular 0.5 to 2.5% by weight

The anionic surfactants and soaps can be present in the form of their sodium, potassium or ammonium salts and as soluble salts of organic bases, such as mono-, di- or triethanolamine, preferably in the form of their sodium or potassium salts, in particular in the form of Sodium salts prior to anionic surfactants and soaps may also be prepared in situ by incorporating into the composition to be spray dried the anionic surfactant acids and optionally fatty acids, which are then neutralized by the alkali carriers in the composition to be spray-dried

Advantageously, nonionic surfactants may also be included in the compositions of the invention, both in solid and in liquid compositions. For example, their content may be up to 2 or 3 or 5% by weight. Larger amounts of nonionic surfactant may also be included, for example up to 5% by weight. % or 10% by weight or 15% by weight or 20% by weight or 30% by weight or even beyond, if appropriate Sensible lower limits may be 1, 2, 3 or 4% by weight

Preferably, however, the nonionic surfactants are in larger amounts, ie up to 50% by weight, advantageously from 0.1 to 40% by weight, more preferably from 0.5 to 30 and in particular from 2 to 25% by weight, in each case based on the total agent included According to a preferred Embodiment contains the product according to the invention nonionic surfactants, preferably in amounts of at least 0, 1 wt -%

Advantageously, all nonionic surfactants known from the prior art may be present in the compositions according to the invention. Preferred nonionic surfactants are presented below

The compositions according to the invention, in particular remits, care agents and detergents, may preferably also contain cationic surfactants. Suitable cationic surfactants are, for example, surface-active quaternary compounds, in particular with an ammonium, sulfomum, phosphonium, iodonium or arsonium group Compounds with antimicrobial action, the agent can be designed with an antimicrobial effect or its possibly existing antimicrobial effect can be improved due to other ingredients

Particularly preferred cationic surfactants are the quaternary, z T antimicrobial ammonium compounds (QAV, INCI quaternary ammonium compounds) according to the general formula (R ') (R ") (R"') (R ^IV ) N ⁺ X ^" , in the R ¹ to R ^IV are identical or different d ₂₂ alkyl C _{7 28} -.. aralkyl radicals or heterozykhsche radicals, or in the case of an aromatic compound as in the Pyπdin even three groups together with the nitrogen atom forming the heterocycle, for example a Pyπdinium- or imidazolinium compound, form, and X ^" halide ions, sulfate ions are hydroxide ions or similar anions For optimum antimicrobial activity preferably at least one of the radicals has a chain length of 8 to 18 ιnsbesondere12 to 16, carbon atoms

QACs can be prepared by reacting tertiary amines with alkylating agents, such as methyl chloride, benzyl chloride dimethyl sulfate, dodecyl bromide, but also ethylene oxide. The alkylation of tertiary amines with a long alkyl radical and two methyl groups is particularly easy to quaternize tertiary amines with two long radicals and one methyl group can be carried out under mild conditions with the aid of methyl chloride. Amines which have three long alkyl radicals or hydroxy-substituted alkyl radicals are less reactive and are preferably quaternized with dimethyl sulfate

Suitable QACs are, for example, benzalkonium chloride (N-alkyl-N, N-dimethylbenzylammoniumammonium CAS No 8001-54-5), benzalkone B (mp-dichlorobenzyl-dimethyl-C 1-4 -alkylammonium chloride CAS No. 58390-78-6), Benzoxonium chloride (benzyldodecyl-bis (2-hydroxyethyl) -ammonium chloride), cetrimonium bromide (N-hexadecyl-N, N-t-methylammonium bromide, CAS No 57-09-0), benzotonium chloride (N, N-dimethyl) N- [2- [2- [p- (1,1,3,3-tetramethylbutyl) phenoxy] ethoxy] ethyl] -benzyl ammonium chloride CAS No. 121-54-0), dialkyldimethylammonium chlorides such as D-n- decyl dιmethyl- ammonium chloride (CAS No. 7173-51-5-5), didecyldimethylammonium bromide (CAS No. 2390-68-3), dioctyl-dimethylammonium chloride, 1-cetylpyrrolidimine chloride (CAS No. 123-03-5) and thiazoline iodide (CAS No. 15764 -48-1) and mixtures thereof. Preferred QAC are the benzalkonium chlorides having C ₈ -C ₁₈ -alkyl radicals, in particular C 1 -C 4 -alkyl-benzyl-dimethylamnomonium chloride. A particularly preferred QAC cocospentaethoxymethylammonium methosulfate (INCI PEG-5 Cocomonium methosulfate, Rewoquat ^® CPEM)

To avoid possible incompatibilities of the antimicrobial cationic surfactants with anionic surfactants contained in the agent according to the invention as far as possible amontenside contractual and / or optionally cationic surfactant are used or omitted in a particular embodiment of the invention entirely cationic surfactants

Further below, in particular in connection with conditioning agents and plasticizers, further cationic surfactants, including quaternary ammonium compounds, are described. These too may preferably be present in the compositions according to the invention

The agents according to the invention, such as preferably removers, care agents and detergents, may contain one or more cationic surfactants, advantageously in amounts, based on the total composition, of from 0 to 30% by weight, more preferably from 0 to 20% by weight, preferably 0.01 to 10% by weight, in particular 0 to 1 to 5% by weight Suitable minimum values may also be present at 0.5, 1, 2 or 3% by weight. According to a preferred embodiment, the product according to the invention contains cationic surfactants, preferably in quantities of at least 0.1% by weight

Likewise, the agents according to the invention, such as preferably removers, care agents and detergents, may also contain amphoteric surfactants. These are described in more detail below, in particular in connection with conditioning agents and plasticizers

The agents according to the invention, such as removers, care agents and detergents, may contain one or more amphoteric surfactants, advantageously in amounts, based on the total composition, of from 0 to 30% by weight, more preferably from 0 to 20% by weight, preferably 0 From 01 to 10% by weight, in particular from 0.1 to 5% by weight

Other ingredients of the compositions according to the invention may be inorganic and organic builders. The inorganic builders include water-insoluble or non-water-soluble ingredients, such as aluminosilicates and, in particular, zeolites

In a preferred embodiment, the agent according to the invention contains no phosphate and / or no zeolite. However, it is also possible that the agent contains zeolite. It may be preferred then be that this zeolite content, based on the total weight of the agent, less than 5% by weight, preferably not more than 4% by weight, not more than 3% by weight or at most 2% by weight

However, it can also be advantageously provided that the agent according to the invention has a zeolite content of at least 10% by weight, for example at least 15% by weight or at least 20% by weight or at least 30% by weight or even beyond, for example at least 50% by weight. % having

Soluble builders may preferably contain the agent according to the invention in amounts of 10% by weight to 30% by weight, preferably 15% by weight to 25% by weight and particularly preferably 18% by weight to 20% by weight, based on the total weight of the composition. Natnumcarbonat is particularly preferred as a soluble builder but it can also be advantageously provided that the inventive composition contains less than 10 wt -%, for example less than 5 wt -% soluble builder

Usable fine crystalline, synthetic and bonded water-containing Zeohth is preferably zeolite A and / or P zeolite P is, for example, Zeohth MAP ^(R) (commercial product of the company Crosfield) is especially preferred suitable are However, zeolite X and mixtures of A, X and / or P of particular interest is a cokπstallisiertes Natπum / potassium aluminum is miniumsilikat of zeolite a and zeolite X, which as VEGOBOND AX ^® (from Condea Augusta S p a commercial product) is commercially obtainable, this product is described in more detail below the Zeohth can be used as a spray-dried powder or else as an undried, still moist, stabilized suspension of its preparation. In the case where the Zeohth is used as a suspension, it may contain minor additions of nonionic surfactants as stabilizers, for example 1 to 3% by weight, based on Zeohth, on ethoxylated C ₁₂ -C ₁₈ -FEK alcohols having 2 to 5 ethylene oxide groups, C Suitable C ₁₂ -C ₁₄ fatty alcohols having from 4 to 5 ethylene oxide groups or ethoxylated isotope decanols have a mean particle size of preferably less than 10 μm (volume distribution, Coulter Counter method) and preferably contain from 18 to 22% by weight, in particular from 20 to 22% by weight. % of bound water

Other particularly suitable zeolites are faujasite-type zeolites. Together with the zeolites X and Y, the mineral faujasite belongs to the faujasite types within the zeolite structure group 4 which are characterized by the double-six-membered subunit D6R. Structure group 4 pay next to the mentioned faujasite types nor the minerals chabazite and Gmehnit and the synthetic zeolites R (chabazite type), S (Gmehnit type), L and ZK-5 The latter two synthetic Zeohthe have no mineral analogues

Zeolites of the faujasite type are made up of beta-caffins, which are linked to tetrahedrally via D6R subunits, the beta cages being arranged similar to the carbon atoms in the diamond The three-dimensional network of the faujasite-type zeolites suitable for the invention has pores of 2.2 and 7.4 Å, the unit cell also contains 8 cavities of about 13 Å diameter and can be represented by the formula Na ₈ 6 [(AlO ₂ ) 86 (Sι0 ₂₎ io _6] 264 H ₂ O describe the network of the zeolite X contains thereby a void volume of about 50% based on the dehydrated crystal what the greatest empty space of all known zeolites represents (zeolite Y about 48% void volume, faujasite approx. 47% void volume)

In the context of the present invention, the term "faujasite-type zeolite" denotes all three zeolites which form the faujasite subgroup of the zeolite structure group 4. In addition to the zeolite X, according to the invention zeolite Y and faujasite and mixtures of these compounds are also suitable pure zeolite X is preferred

Mixtures or cocatalysts of faujasite-type zeolites with other zeolites, which need not necessarily belong to the zeolite structure group 4, are also suitable according to the invention, wherein preferably at least 50% by weight of the faujasite-type zeolites are

The suitable aluminum biscates are commercially available and the methods for their preparation are described in standard monographs

Examples of commercially available X-type zeolites can be described by the following formulas

Na ₈₆ [(AIO ₂ ) ₈₆ (SiO ₂ ) ₁₀₆ ] x H ₂ O,

K86 [(AIO ₂ ) 86 (SIO ₂ ) ₁₀ 6] XH ₂ O,

Ca ₄ oNa ₆ [(AlO ₂ ) ₈ 6 (SiO ₂ ) ₁₀ 6] x H ₂ O, Sr ₂₁ Ba ₂₂ [(AIO ₂ ) ₈₆ (SiO ₂ ) ₁₀ 6] x H ₂ O, in which x values of large O to 276 can assume these zeolites have pore sizes of 8.0 to 8.4 A.

Suitable, for example, zeolite A-LSX, corresponding to a Co-Krιstallιsat of zeolite X and zeolite A, and in its anhydrous form the formula (M _27n O + M _{'2 / n} O) Al ₂ O ₃ ZSiO _2, said M and M 'may be alkali or alkaline earth metals and z is a number from 2.1 to 2.6. This product is commercially available under the trade name VEGOBOND AX from the company CONDEA Augusta S p A

Y-type zeolites are also commercially available and can be obtained, for example, by the formulas

Na ₅ 6 [(AIO ₂ ) 56 (SiO ₂ ) ₁₃ 6] x H ₂ O, K ₅ 6 [(AIO ₂ ) ₅ 6 (SiO ₂ ) ₁₃ 6] x H ₂ O, in which x is a large number O to 276 is described These zeolites are pore-sized from 8.0 A up

The particle sizes of the suitable zeolites advantageously lie in the range from 0.1 μm to 100 μm, preferably from 0.5 μm to 50 μm and in particular from 1 μm to 30 μm, in each case measured using standard particle size determination methods

In a preferred embodiment of the invention, all the inorganic constituents contained are preferably water-soluble. In these embodiments, therefore, builder substances other than the zeolites mentioned are used

Further suitable builder substances are polyacetals which can be obtained by reacting dialdehydes with polyolcarboxylic acids which have 5 to 7 C atoms and at least 3 hydroxyl groups. Preferred polyacetals are prepared from dialdehydes such as glyoxal, glutaraldehyde, terephthalaldehyde and mixtures thereof and from polyolcarboxylic acids such as Gluconic acid and / or glucoheptonic acid obtained

Further suitable organic builder substances are dextrins, for example oligomers or polymers of carbohydrates, which can be obtained by partial hydrolysis of starches. The hydrolysis can be carried out by customary, for example acid or enzyme catalyzed processes. Preferably, the hydrolysis products have average molecular weights in the range of 400 up to 500,000 g / mol. A polysaccharide with a dextrose equivalent (DE) in the range from 0.5 to 40, in particular from 2 to 30, is preferred, DE being a useful measure of the reducing action of a polysaccharide in comparison with dextrose Useful are both maltodextrins with a DE of between 3 and 20 and dry glucose syrups with a DE of between 20 and 37 and also so-called yellow dextrins and white dextrins with higher molecular weights in the range from 2000 to 30 000 g / mol. A preferred dextrin is in British Patent Application 94 19 091 described n The oxidized derivatives of such dextrins are their reaction products with oxidizing agents which are capable of oxidizing at least one alcohol function of the saccharide to the carboxylic acid function

Oxydisuccinates and other derivatives of Disuccmaten, preferably Ethylendiammdisucci- nat are further suitable cobuilders Ethylenediamine-N, N ^{'-di-succinate} (EDDS) is preferably in the form of its sodium or magnesium salts thereof Furthermore, Glyceπndisuccinate Glycerintπsuccinate and are preferred in this context quantities used For example, they are from 3 to 15% by weight, based on the total agent

Other useful organic cobuilders are, for example, acetylated hydroxycarboxylic acids or their salts, which may optionally also be present in lactone form and which min. contain at least 4 carbon atoms and at least one hydroxy group and a maximum of two acid groups

A further class of substances with cobuilder properties are the phosphonates. These are, in particular, hydroxyalkane or aminoalkanephosphonates. Among the hydroxyalkanes, 1-hydroxyethane-1,1-diphosphonate (HEDP) is of particular importance as a cobuilder. It is preferably used as the sodium salt. The dinate salt is neutral and the tetrasodium salt is alkaline (pH 9). Preferred aminoalkane phosphonates are ethylenediaminetetramethylenephosphonate (EDTMP), diethylenetaminepentamethylenephosphonate (DTPMP) and their higher homologs. They are preferably in the form of the neutrally reacting sodium salts, eg B as the hexasodium salt the EDTMP or as Hepta- and Octa Natπumsalz of DTPMP, used as a builder here from the class of phosphonates preferably HEDP is used The Aminoalkanphosphonate also have a pronounced Heavymetbindervermogen Accordingly, it may, especially if the agent also contains bleach old, be preferred, aminoalkane phosphonates in particular DTPMP use, or to use mixtures of the phosphonates mentioned

In cases in which a phosphate content is tolerated, it is also possible to use phosphates, in particular pentasodium t-phosphate, optionally also pyrophosphates and orthophosphates, which act primarily as precipitants for calcium salts. Phosphates are predominantly used in automatic dishwashing agents, but sometimes also in dishwashing detergents Alkali metal phosphates is the summary term for the Alkahmetall- (especially sodium and potassium) salts of various phosphoric acids, in which one can distinguish metaphosphoric acid (HPO ₃ ) _n and orthophosphoric H ₃ PO _{4 in} addition to high molecular weight representatives The phosphates combine several advantages They act as Alkahträger prevent calcification on machine parts or Kalkmkrustationen in tissues and also contribute to the cleaning performance

Natπumdihydrogenphosphat, NaH ₂ PO ₄ , exists as a dihydrate (density 1, 91 like ^"3 , melting point 60 °) and as a monohydrate (density 2.04 like ^'3 ) Both salts are white, very soluble in water powder when heated lose the water of crystallization and at 200 ⁰ C in the weakly acidic diphosphate (Dinatπumhydrogendiphosphat, Na ₂ H ₂ P ₂ O ₇ ), at higher temperature in Natiumtπme- taphosphate (Na ₃ P ₃ O ₉ ) and Maddrell's salt (see below), go over NaH ₂ PO ₄ reacts acidically. It is formed when phosphoric acid is adjusted to pH 4.5 with caustic soda and the mash is sprayed. Kahum dihydrogen phosphate (potassium phosphate, potassium phosphate or potassium phosphate, KDP), KH ₂ PO ₄ , is a white one Salt of density 2.33, like ^"3 , has a melting point of 253 ° [decomposition to form potassium polyphosphate (KPO ₃ ) _X ] and is readily soluble in water Dinatπumhydrogenphosphat (secondary sodium phosphate), Na ₂ HPO ₄ , is a colorless, very slightly water-soluble crystalline salt It exists anhydrous and with 2 mol (density 2.066 like ^"3 , water loss at 95 °), 7 mol (density 1.68 like ^'3rd , Melting point 48 ° C with loss of 5 H ₂ O) and 12 MoI water (density 1, 52 like ^"3 , melting point 35 ° with loss of 5 H ₂ O), becomes anhydrous at 100 ° C and goes into the diphosphate upon increased heating Na ₄ P ₂ O ₇ via Dinatπumhydro- genphosphat is prepared by neutralization of phosphoric acid with sodium carbonate solution using phenolphthalein as an indicator Dι-kaliumhydrogenphosphat (secondary or dibasic potassium phosphate), K ₂ HPO ₄ , is an amorphous, white salt, which is light in water is soluble

Tπnatπumphosphat, tertiary sodium phosphate, Na ₃ PO ₄ , are colorless crystals, the dodecahydrate a density of 1, 62 like ^"3 and a melting point of 73-76 ⁰ C (decomposition), as decahydrate (corresponding 19-20 % P ₂ O ₅ ) have a melting point of 100 ° C and in anhydrous form (corresponding to 39-40% P ₂ O ₅ ) have a density of 2.536 ^"3 Trinatnum phosphate is readily soluble in water under alkaline reaction and is evaporated Tπ-potassium phosphate (tertiary or tri-basic potassium phosphate), K ₃ PO ₄ , is a white, fissile, granular powder of density 2.56 ^"3 , has a melting point of 1340 ° and is easily soluble in water with an alkaline reaction. It arises, for example, when heating Thomasschlacke with coal and potassium sulphate. Despite the higher price, the more easily soluble, and therefore highly effective, potassium phosphates are in the detergent industry r corresponding sodium compounds are often preferred

Tetranatπumdiphosphat (Natπumpyrophosphat), Na ₄ P ₂ O ₇ , exists in anhydrous form (density 2.534 like ^'3 , melting point 988 °, also 880 ° indicated) and as decahydrate (density 1, 815-1, 836 like ^"3 , melting point 94 Both substances are colorless crystals which are soluble in water with an alkaline reaction. Na ₄ P ₂ O ₇ is formed by heating dinate phosphate to> 200 ° or by reacting phosphoric acid with soda in the stoichiometric ratio and dehydrating the solution by spraying. The decahydrate is complexed heavy metal salts and Har- tebildner and therefore reduces the hardness of the water, potassium diphosphate (Kahumpyrophosphat), K ₄ P ₂ O _7, exists in the form of the trihydrate and is a colorless, hygroscopic powder with a density of 2.33 ^{gcm -3,} which is soluble in water, wherein the pH of the 1% solution at 25 ° 10,44 amounts

Condensation of NaH ₂ PO ₄ or KH ₂ PO ₄ gives rise to high molecular weight sodium and potassium phosphates in which cyclic representatives are the sodium or potassium metaphosphates and chain types that can differentiate between sodium and potassium polyphosphates Common names of glulphic or gluhphosphates Graham's salt, Kurrolsches and Maddrell's salt All higher sodium and potassium phosphates are collectively referred to as condensed phosphates The technically important Pentasatriumtπphosphat, Na ₅ P ₃ O ₁₀ (Natriumtπpolyphosphat), is an anhydrous or with 6 H ₂ O crystallizing, non-hygroscopic, white, water-soluble salt of the general formula NaO- [P (O) (ONa) -O] _n -Na with n = 3 In 10O g of water dissolve at room temperature about 17 g, at 60 ° about 20 g, at 100 ° about 32 g of the anhydrous salt, after two hours of heating the solution to 100 ° caused by hydrolysis about 8% orthophosphate and 15% diphosphate In the preparation of pentanate phosphate, phosphoric acid is reacted with soda solution or caustic soda in a stoichiometric ratio and the solution is dehydrated by spraying. Similar to Graham's salt and sodium diphosphate pentanatetriphosphate dissolves many insoluble metal compounds (also lime soaps, etc.) pentakali - umtπphos-phat, K ₅ P ₃ O ₁₀ (Kaliumtπpolyphosphat), for example, in the form of a 50 Gew -böigen solution (> 23% P ₂ O ₅ , 25% K ₂ O) in the Ha The potassium polyphosphates are widely used in the detergents and cleaners industry. There are also sodium potassium polyphosphates which can likewise be used in the context of the present invention. These are formed, for example, by hydrolyzing sodium trimetaphosphate with KOH

(NaPOa) ₃ + 2 KOH -> Na ₃ K ₂ P ₃ O ₁₀ + H ₂ O

These are erfmdungsgemaß exactly as Natnumtripolyphosphat, Kaliumtπpolyphosphat or mixtures of these two used, and mixtures of Natriumtπpoly-phosphate and Natπumkaliumtripolyphosphat or mixtures of Kaliumtπpolyphosphat and Natπumka- liumtπpolyphosphat or mixtures of Natnumtripolyphosphat and Kaliumtπpolyphosphat and Natriumkaliumtπpolyphos-phat are erfmdungsgemaß used

In a preferred embodiment of the invention, in particular carbonates and silicates are used as inorganic builder substances

Particularly noteworthy here are crystalline, layered sodium silicates of the general formula NaMSi _x O _{2x +} 1yH ₂ O, where M is sodium or hydrogen, x is a number from 1.6 to 4, preferably 1.9 to 4.0 and y is a number from 0 to 20 and are preferred values for x 2, 3 or 4. However, since such crystalline crystals at least partially lose their crystalline structure in a spray-drying process, crystalline silicates are preferably subsequently added to the direct or post-treated spray-drying product. Preferred crystalline layer silicates of the formula given are those in which M is sodium and x is 2 or

In particular, both ß- and δ-Natπumdisihcate Na ₂ Si ₂ O ₅ yH ₂ O are preferred Commercially, such compounds are, for example, under the name SKS * (Clanant) So it is at SKS-O ^ predominantly one δ-Natπumdi-silicate with the formula

Na ₂ Si ₂ O ₅ .yH ₂ O, mainly produced during SKS-7 ^® to the ß-Natπumdιsιlιcat By reaction with acids (for example citric acid or carbonic acid) from the δ-Natπumdisilicat kanemite NaH

Si ₂ O ₅ yH ₂ O commercially under the names SKS-9 ^® or SKS-10 * (Clanant) Advantage It may also be possible to use chemical modifications of these phyllosilicates Thus, for example, the alkalinity of the phyllosilicates can be influenced appropriately phyllosilicates doped with phosphate or carbonate have in comparison to the δ-Natrιumdιsιlιcat on Kπs- tallmorphologien on, loose more quickly and show in comparison to δ -Natπumdιsιlιcat an increased Calciumbindevermogen Thus, phyllosilicates of the general empirical formula x Na ₂ O • y SiO ₂ • z P ₂ O ₅ in which the ratio x to y a number 0.35 to 0.6, the ratio x to z a number of The solubility of the phyllosilicates can also be increased by using particularly finely divided phyllosilicates. Compounds of the crystalline phyllosilicates with other constituents can also be used. Compounds in particular are used here with cellulose derivatives, the advantages in desint egrierenden effect, as well as compounds with polycarboxylates, eg citric acid, or polymeric polycarboxylates, eg copolymers of acrylic acid, to call

Among the preferred builders include amorphous Natπumsilikate with a modulus Na ₂ O SiO ₂ of 1 2 to 1 3.3, preferably from 1 2 to 1 2,8 and in particular from 1 2 to 1 2.6, which have Sekundarwascheigenschaften In the frame This invention means that the silicates do not give sharp X-ray reflections in X-ray diffraction phenomena, as are typical for crystalline substances, but at most one or more maxima of the scattered X-radiation, which have a width However, it may very well lead to particularly good builder properties when the Sihkat particles provide blurred or even sharp diffraction maxima in electron diffraction phenomena. This is to be interpreted as showing that the products have microcrystalline regions of size 10 to a few hundred nm , where values up to max. 50 nm and in particular up to max. 20 n Particularly preferred are compacted / compacted amorphous silicates, compounded amorphous silicates and dried X-ray silicates. The content of the (X-ray) amorphous silicates in particular Freeze-free agents are preferably from 1 to 10% by weight, which corresponds to a preferred embodiment of the invention

Particularly preferred inorganic water-soluble builders are alkali metal carbonates and alkali metal bicarbonates, with sodium and potassium carbonate and, in particular, sodium carbonate being preferred embodiments. The content of alkali metal carbonates in particular environmentally-free compositions can vary within a very wide range and is preferably from 5 to 40% by weight. in particular from 8 to 30% by weight, the content of alkali metal carbonates usually being higher than that of (radiopaque) amorphous silicates Useful organic Gerustsubstanzen are, for example, usable in the form of their alkali and especially sodium polycarboxylic acids, such as citric acid, adipic acid, succinic, glutaric, tartaric, succinic, aminocarboxylic, Nitπlotriessigsaure (NTA), if such use for environmental reasons is not objectionable, and Mixtures of these Preferred salts are the salts of the polycarboxylic acids such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids and mixtures thereof. The acids themselves can also be used. Apart from their builder effect, the acids also typically have the property of an acid component and thus serve as for example in the granules according to the invention, also for setting a lower and milder pH of detergents and cleaners. In particular, citric acid, succinic acid, glutaric acid, adipic acid, gluconic acid and any desired mixture are used to name from these

Further suitable organic builders are polymeric polycarboxylates, for example the alkali metal salts of polyacrylic acid or polymethacrylic acid, for example those having a relative molecular mass of 500 to 70,000 g / mol. The molecular weights stated for polymeric polycarboxylates are weight-average molar masses for the purposes of this document M _{w of} the respective acid form, which in principle were determined by means of gel permeation chromatography (GPC) using a UV detector. The measurement was carried out against an external polyacrylic acid standard, which provides realistic molecular weight values due to its structural relationship with the polymers investigated From the molecular weight data in which Polystyrolsulfonsauren be used as standard The molar masses measured against Polystyrolsulfonsauren are generally much higher than the molecular weights specified in this document

The inventive compositions may also contain polymers, in particular as a carrier for the perfume. Suitable polymers which are also useful as vehicles in combination with fragrance include in particular polyacrylates, which preferably have a molecular weight of 2,000 to 20,000 g / mol. Due to their superior solubility can from This group in turn, the short-chain polyacrylates, the molecular weights of 2000 to 10,000 g / mol, and more preferably from 3000 to 5000 g / mol, preferably be

Also suitable are copolymeric polycarboxylates, in particular those of acrylic acid with methacrylic acid and acrylic acid or methacrylic acid with maleic acid. Copolymers of acrylic acid with maleic acid have proven to be particularly suitable for containing 50 to 90% by weight of acrylic acid and 50 to 10% by weight of maleic acid relative molecular mass, based on free acids, is generally from 2000 to 70000 g / mol, preferably from 20,000 to 50,000 g / mol and in particular from 30,000 to 40,000 g / mol The content of the organic builder substances may vary within a broad range. Preference is given to contents of from 2 to 20% by weight, in particular contents of not more than 10% by weight being particularly preferred

The agents according to the invention may contain components from the classes of the grayness inhibitors (soil carriers), the neutral salts and / or the textile-softening auxiliaries (for example cationic surfactants), which is preferred

Graying inhibitors have the task to keep suspended from the fiber debris suspended in the fleet and so prevent the re-uptake of dirt For this purpose, water-soluble colloids are mostly organic nature suitable, for example, the water-soluble salts of polymeric carboxylic acids, glue, gelatin, salts of ether carboxylic acids or ether sulfonic acids of starch or cellulose or salts of acid or acidic acid or sulfuric acid esters. Also, water-soluble, acidic group-containing polyamides are suitable for this purpose. Furthermore, soluble starch preparations and starch products other than those mentioned above can be used, for example, degraded starch, aldehyde starch Polyvinylpyrrolidone is also useful. However, preference is given to cellulose ethers, such as carboxymethylcellulose (Na salt), methylcellulose, hydroxyalkylcellulose and mixed ethers, such as methylhydroxyethylcellulose, methylhydroxypropylcellulose, methylcarboxymethylcellulose and the like Mixtures, and polyvinyl pyrrohdone, for example, in amounts of preferably 0, 1 to 5% by weight, based on the agents used

A typical example of a suitable representative of the neutral salts is sodium sulfate. It can be used in amounts of, for example, from 0 to 60% by weight, preferably from 2 to 45% by weight

Suitable plasticizers, which are described in more detail below, are, for example, swellable phyllosilicates of the type of corresponding montmorillonites, for example benzonite, as well as cationic surfactants. According to a preferred embodiment, an agent according to the invention contains suitable plasticizers

The content of water on average depends, inter alia, on whether the composition is in liquid or solid form, and therefore preferably amounts to 0 to less than 100% by weight and in particular 0.5 to 95% by weight, values of not more than 5% by weight in particular to find particular preference for solid or non-aqueous liquids. In the case of the solid agents, the water which is attached to the optionally present aluminosilates, such as zeolite, was not included

In the case of liquid agents, the inventive composition according to a preferred embodiment contains water in an amount of more than 20% by weight, advantageously more than 30% by weight, more preferably more than 40% by weight, more preferably more than 50% by weight, in particular from 60 to 95% by weight, more preferably from 70 to 93% by weight and most preferably from 80 to 90% by weight

The agent according to the invention can, if it is a solid, have an excellent trickling behavior. According to a preferred embodiment, the agent according to the invention is essentially solid, preferably in powdery, compressed or granular form

If the agent is in particulate form, the particles can be aftertreated, for example, by rounding the particles of the agent. The rounding can be carried out in a conventional rounding agent. Preferably, the rounding time does not exceed 4 minutes, in particular not more than 3.5 minutes, of rounding times of a maximum of 1.5 minutes or less are particularly preferred. The rounding achieves a further standardization of the grain spectrum, since optionally formed agglomerates are comminuted

A composition according to the invention in particulate form can be obtained in particular with nonionic surfactants, perfume oil and / or foam inhibitors or preparation forms which contain these ingredients, preferably with amounts of up to 20% by weight of active substance, in particular with amounts of from 2 to 18% by weight of active substance on the aftertreated product, in a conventional manner, preferably in a mixer or optionally a fluidized bed, post-treatment

In particular, an agent according to the invention can also be post-treated or powdered with solids, preferably in amounts of up to 15% by weight, in particular in amounts of from 2 to 15% by weight, based in each case on the total weight of the post-treated agent

Bicarbonate, carbonate, zeolite, silica, citrate, urea or mixtures thereof, in particular in amounts of from 2 to 15% by weight, based on the total weight of the aftertreated product, can preferably be used as the aftertreatment agents. The aftertreatment can be advantageously achieved in a mixer and / or run through Verrunder

In a preferred embodiment of the invention, an agent according to the invention is aftertreated with nonionic surfactants, which may also contain, for example, optical brighteners and / or hydrotropes, perfume, and / or a solution of optical brightener and / or foam inhibitors or preparation forms which may contain these ingredients Preferably, these ingredients or formulations containing these ingredients are applied in liquid molten or pasty form to the particular agent to be aftertreated

It is preferred that the aftertreatment with the substances mentioned here in one conventional mixer, only for example in a 2-shaft Mιscher within a maximum of 1 minute, preferably within 30 seconds and, for example, within 20 seconds, wherein the times are also for addition and mixing time, done

These nonionic surfactants may be applied to the particulate agents in an aftertreatment step. Of course, all nonionic surfactants may advantageously be present directly in the composition of the invention, liquid or solid, foaming or gelatinous

The nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary alcohols having preferably 8 to 18 carbon atoms and on average 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical may be linear or preferably methyl-branched in the 2-position In particular, however, are alcohol ethoxylates with linear radicals of alcohols of natural origin having 12 to 18 carbon atoms, such as coconut, palm, palm kernel The preferred ethoxylated alcohols include, for example, C ₁₂ -C ₁₄ -alcohols containing 3 EO to 6 EO, C ₉ -C ₁₁ -alkyl containing 7 EO, C, and .alpha., Tallow fatty or oleyl alcohol, and on average 2 to 8 EO per mole of alcohol ₁₃ -C ₁₅ -alcohols with 3 EO, 5 EO, 7 EO or 8 EO, C ₁₄ -C ₁₅ -alkyl with 4 EO, 5 EO, 7 EO or 9 EO, C ₁₂ -C ₁₈ -alcohols with 3 EO, 5 EO or 7 EO and mixtures of d such as mixtures of C ₁₂ -C ₄ -alcohol with 3 EO and C ₁₂ -C ₁₈ -alcohol with 7 EO The stated degrees of ethoxylation represent statistical averages, which for a particular product may be an integer or a fractional number

Preferred alcohol ethoxylates have a narrow homolog distribution (narrow rank ethoxylates, NRE). In addition to these nonionic surfactants, fatty alcohols with more than 12 EO can also be used. Examples of these are (TaIg) fatty alcohols with 14 EO, 16 EO, 20 EO, 25 EO. 30 EO or 40 EO

Preferred nonionic surfactants are one or more ethylene oxide (EO) and / or propylene oxide (PO) alkoxylated, unbranched or branched, saturated or unsaturated C ₁₀ . ₂₂ alcohols having an alkoxy degree of up to 30, preferably ethoxylated C ₁₀ -ββ fatty alcohols having an ethoxylation degree of less than 30, preferably 1 to 20, in particular 1 to 12, more preferably 1 to 8, most preferably 2 to 5, for example, C _12-14 fatty alcohol ethoxylates having 2, 3 or 4 EO or a mixture of the C _{12th 14} -fatty alcohol ethoxylates with 3 and 4 EO in the weight ratio of 1 to 1 or Isotridecylalkoholethoxylat with 5 8 or 12 EO

In addition, other nonionic surfactants which can also be employed are alkylglycosides of the general formula RO (G) _x in which R is a primary straight-chain or methyl-branched aliphatic radical, especially branched in the 2-position, having 8 to 22, preferably 12 to 18 C represents atoms and G is the symbol which represents a glucose unit with 5 or 6 C atoms, preferably glucose. The degree of oligomerization x, which indicates the distribution of monoglycosides and oligoglycosides, is an arbitrary number of 1 to 10, preferably x is 1 1 to 1, 4

Another class of preferred nonionic surfactants which are used either as a sole nonionic surfactant or in combination with other nonionic surfactants, in particular together with alkoxylated fatty alcohols and / or alkyl glycosides, are xyloxy, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, are preferably of 1 to 4 carbon atoms in the alkyl chain, in particular Fettsauremethylester particularly preferred C ₁₂ -C ₈ -Fettsauremethylester with an average of 3 to 15 EO, in particular with an average of 5 to 12 EO

Nonionic surfactants of the amine oxide type, for example N-cocoalkyl-N, N-dimethyl-amm-oxide and N-tallow-alkyl-N, N-dimethylhydroxylamine, and the fatty acid alkanolamides may also be suitable. The amount of these nonionic surfactants is preferably not more than that the ethoxylated fatty alcohols, especially not more than half of them

Also suitable are alkoxylated amines, advantageously ethoxylated and / or propoxylated, in particular primary and secondary amines having preferably 1 to 18 carbon atoms per alkyl chain and an average of 1 to 12 MoI ethylene oxide (EO) and / or 1 to 10 MoI propylene oxide (PO) per Mole of amine

In the case of compositions according to the invention which are particularly suitable for automatic dishwashing, in particular dishwashing agents in the form of tablet moldings, such as tabs, surfactants are in principle all surfactants in question. However, the nonionic surfactants described above and, above all, the low-foaming detergents are particularly preferred for this purpose. The alkoxylated alcohols, especially the ethoxylated and / or propoxylated alcohols, are particularly preferred. The person skilled in the art generally understands by alkoxylated alcohols the reaction products of alkylene oxide, preferably ethylene oxide, with alcohols, preferably the long-chain alcohols C ₁₀ to C according to the present invention ₁₈ , preferably from C ₁₂ to C ₁₆ , such as C ₁₁ -, C ₁₂ -, C ₁₃ -, C -, .-, C ₁₅ -, C ₁₆ -, C ₁₇ - and C ₁₈ -alcohols usually arise from n moles of ethylene oxide and one mole of alcohol, depending on the reaction conditions, a complex mixture of addition Another embodiment is the use of mixtures of alkylene oxides preferably of the mixture of ethylene oxide and propylene oxide. If desired, final etherification with short-chain alkyl groups, such as preferably the butyl group, can also yield the substance class of the "closed" alcohol ethoxylates which are likewise within the meaning of the invention It is very particularly preferred for the purposes of the present invention are highly ethoxylated fatty alcohols or mixtures thereof with end-capped fatty alcohol ethoxylates

Advantageously, the agents according to the invention may also contain foam inhibitors, for example foam-inhibiting paraffinol or foam-inhibiting polymolefin, for example dimethylpolysiloxane. It is also possible to use mixtures of these active substances as additives which are solid at room temperature, in particular for the foam-inhibiting active ingredients mentioned, paraffin waxes, silicic acids may also be hydrophobicized in a known manner, and of C ₂ . ₇ -Dιamιnen and C _12-22 -carboxylic acid bisamides derived

For use, preferably suitable foam-inhibiting paraffin oils, which may also be present in admixture with paraffin waxes, are generally complex mixtures without a sharp melting point. For characterization, the melting range is usually determined by differential thermoanalysis (DTA) and / or the solidification point By this is meant the temperature at which the paraffin passes from the liquid to the solid state by slow cooling. Paraffins having less than 17 carbon atoms are not useful according to the invention, their proportion in the paraffinol mixture should therefore be as low as possible and preferably below that It is preferred to use paraffins which solidify in the range from 20 ° C. to 70 ° C. It should be noted that even paraffin wax mixtures which appear solid at room temperature have different proportions of liquid paraffinols may contain at inventively paraffin waxes is the Flussiganteil at 40 ⁰ C as high as possible without at this temperature already 100% to be Preferred paraffin wax mixtures have at 40 ° C a Flussiganteil of at least 50 wt -%, especially from 55 weight -% to 80 wt -%, and at 60 ⁰ C a Flussiganteil of at least 90 wt -% to This has the consequence that the paraffins at temperatures down to at least 70 ° C, preferably down to at least 6O ⁰ C are fließfahig and pumpable is also Care must be taken that the paraffins contain as far as possible no volatile constituents Preferred paraffin waxes contain less than 1% by weight, in particular less than 0.5% by weight, vaporizable at 110 ° C. and normal pressure Paraffins which can be used according to the invention can be obtained, for example, under the trade names Lunaflex® Company filler and Deawax® of DEA Mineralöl AG

The paraffin oils may contain at room temperature solid bisamides derived from saturated fatty acids having 12 to 22, preferably 14 to 18 carbon atoms and alkylenediamines having 2 to 7 carbon atoms. Suitable fatty acids are lauric, myπstin, stearic, Arachin and bovine acids and mixtures thereof, such as those obtainable from natural fats or hydrogenated oils such as tallow or hydrogenated palmol. Suitable diamines are, for example, ethylenediamine 1, 3-propylenediamine, tetramethylenediamine, pentamethylenediamine, hexamethylenediamine p-phenyl-endylamine. amine and toluenediamine Preferred diamines are ethylenediamine and hexamethylenediamine Particularly preferred bisamides are bis-myπstoyl-ethylenediamine, bis-palmitoyl-ethylenediamine, bis-stearoyl-ethylenediamine and mixtures thereof and the corresponding derivatives of hexamethylenediamine

The products according to the invention can preferably be mixed with further constituents, in particular of washing, care and / or cleaning agents or cosmetic ingredients. It is generally known from the broad state of the art which ingredients of washing or cleaning agents and which raw materials can usually be added These are, for example, substances such as bleaching agents, bleach activators and / or bleach catalysts, enzymes, temperature-sensitive dyes, etc., which of course may also be contained directly in the composition

Preferably, the agent UV absorber, which advantageously aufzubt on the treated textiles and improve the light resistance of the fibers and / or the light stability of other Recept- turbestandbestandteile have, Under UV absorber are organic substances (light protection filter) to understand that in the Able to absorb ultraviolet rays and re-release the absorbed energy in the form of long-wave radiation, for example, heat. Compounds having these desired properties are, for example, the non-radically deactivating compounds and derivatives of benzophenone having substituents in 2- and / or 4 Substituted Benzotπazole, in the 3-position phenylsubsti- tuierte acrylates (Zimtsauredπvate), optionally with cyano groups in the 2-position, Sahcylate organic Nι-complexes and natural substances such as umbelliferone and the body's own Urocansaure are particularly important biphenyl and especially lem stilbene derivatives, for example as Tinosorb FD ^{® ®} or Tinosorb FR ex Ciba obtainable as UV-B absorbers are commercially to name a 3-benzylidenecamphor or 3-Benzylιdennorcampher and its derivatives, for example 3- (4-methylbenzylidene lιden) camphor, 4-aminobenzoic acid derivatives, preferably 4- (dimethylamino) benzoic acid 2-ethylhexyl ester, 4- (dimethylamino) benzoic acid 2-octyl ester and 4- (dimethylamino) benzoic acid amyl ester, esters of cinnamic acid, preferably 4 -Meth-oxyzιmtsaure-2-ethylhexyl ester, 4-methoxyzimtsaurepropylester, 4-Methoxyzιmtsaureιso-amyl ester, 2-cyano-3,3-phenylzιmtsäure-2-ethylhexyl ester (octocrylene), esters of Sahcylsaure, preferably-Salιcylsäure-2 ethylhexyl ester, 4-isopropylbenzylseacylate, salicylic acid homomenthyl esters, derivatives of benzophenone, preferably 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2,2'-methylbenzophenone Dihydroxy-4-methoxybenzophenone, esters of benzalmalonic acid, preferably 4-methoxybenzmalonsauredi 2-ethylhexyl, Tπazinderivate, such as 2,4,6-Trιanιlιno- (p-carbo-2 - ethyl-1 'hexyloxy) -1, 3,5-trιazιn and octyl Tπazon or dioctyl Butamido Tnazone (Uvasorb® HEB ), Propan-1 3-dιone, such as 1- (4-tert-butylphenyl) -3- (4'methoxyphenyl) propane-1, 3-dιon Ketotπcyc- lo (5 2 1 O) decane Derιvate are also suitable 2-phenylbenzimidazol-5-sulfonic acid and its alkali metal, alkaline earth metal, ammonium alkylammonium, alkanolammonium and glucomethylene salts sulfonic acid derivatives of benzophenones, preferably 2-hydroxy-4-methoxybenzophenone-5 sulfonic acid and its salts, Sulfonsauredπvate of 3-Benzylιdencamphers, such as 4- (2-oxo-3-boron-nylιdenmethyl) benzenesulfonic acid and 2-methyl-5- (2-oxo-3-bornylιden) sulfonic acid and their salts

As a typical UV-A Fιlter particular derivatives of benzoylmethane come into question, such as 1- (4'-tert-butylphenyl) -3- (4'-methoxyphenyl) propane-1, 3-dιon, 4-tert-butyl-4 'Methoxydi benzoylmethane (Parsol 1789), 1-phenyl-3- (4'-isopropylphenyl) propane-1, 3-dιon and Enaminver- compounds The UV-A and UV-B Fιlter can of course also used in mixtures In addition to the above-mentioned soluble substances, insoluble photoprotective pigments, namely finely disperse, preferably nano-metal oxides or salts are suitable. Examples of suitable metal oxides are in particular zinc oxide and titanium dioxide and, in addition, oxides of iron, zirconium, silicon, manganese, aluminum and cerium as well as their mixtures As salts silicate (talc), barium sulfate or Zmk stearat be used The oxides and salts are already used in the form of the pigments for skin-nurturing and skin-protecting emulsions and decorative cosmetics They may have a mean diameter of less than 100 nm, preferably from 5 to 50 nm and in particular from 15 to 30 nm They may have a spherical shape, but it can also be used those particles which are ellipsoidal or otherwise from the The pigments may also be surface-treated, ie hydrophilized or hydrophobed. Typical examples are coated titanium dioxides, for example titanium dioxide T 805 (Degussa) or Eusolex® T2000 (Merck) Silicones are used as hydrophobic coating agents in particular and in particular Tπalkoxyoctylsilane or simethicone in question Preferably, micronized zinc oxide is used Further suitable UV-Lιcht-Schutzfιlter can be found in the relevant state of the art

The UV absorbers may advantageously be present in amounts of from 0.01% by weight to 5% by weight, preferably from 0.03% by weight to 1% by weight, in the composition. They may also be added subsequently to the composition, for example together with other substances are added

The agents according to the invention, if they are solid, may also be in the form of tablets or shaped bodies. As "tablet" or "shaped body", dimensionally stable, solid bodies are referred to in the context of the present application. Such bodies can be crystallized, for example , Molding, injection molding, reactive or thermal sintering, (co) extrusion, Verpπlllung, pastillation, or compaction process such as the Kalandπerung or tableting manufacture The preparation of the "tablets" or "Formkorper" by tabletting is particularly preferred in the present application The tablet is So preferably made of compressed, teilchenformigen material

Composition according to the invention in solid form, preferably present as tablet or shaped body may preferably contain disintegration aids Suitable swellable disintegration aids are, for example, bentonites or other swellable silicates. It is also possible to use synthetic polymers, in particular the superabsorbents or crosslinked polyvinylpyrrolidone used in the hygiene sector

Polymers based on starch and / or cellulose are used with particular advantage as swellable disintegration aids. These basic substances can be processed alone or mixed with other natural and / or synthetic polymers to form swellable disintegrating agents. In the simplest case, a cellulosic material or pure cellulose be transferred by granulation, compaction or other application of pressure in secondary particles, which swell when in contact with water and thus serve as a disintegrating agent As cellulose-containing material has proven wood pulp accessible by thermal or chemical-thermal process of wood or wood chips (Sagespane Sagereiabfalle) This cellulose derivative from the TMP process (thermomechanical pulp) or the CTMP process (thermo-mechanical mechanical pulp) can then be compacted by application of pressure, preferably roller compacted and converted into particle form Of course, it is also possible to use pure cellulose in a completely analogous manner, although it is more expensive from the raw material base. Here, both microcrystalline and amorphous fine-particle cellulose and mixtures thereof can be used

Another way is then to granulate the cellulosic material with the addition of Granuherhilfsmitteln As Granuherhilfsmittel, for example, solutions of synthetic polymers or nonionic surfactants To avoid residue on the fabrics washed fabrics according to the invention, the Pπmarfaserlange the cellulose or cellulose used in cellulose-containing Material are less than 200 microns, with primary fiber lengths below 100 microns, especially below 50 microns are preferred

The secondary particles ideally have a particle size distribution in which preferably more than 90% by weight of the particles have sizes above 200 μm. A certain amount of dust can contribute to an improved storage stability of the tablets produced therewith. Particles of a fine dust fraction of less than 0.1 mm up to 10% by weight %, preferably up to 8% by weight may be present in the agents used according to the invention with disintegrant granules

Furthermore, the agents according to the invention can be present in the form of a conditioning agent and / or conditioner substrate and accordingly comprise components. For the purposes of this invention, the term conditioning is preferably understood to mean the reviving treatment of textiles, fabrics and fabrics. Conditioning gives the textiles positive properties such as an improved softness, increased gloss and color brilliance an improved fragrance impression reduction of felt formation ball relief by reduction sliding properties, reduction of wrinkling and static charge and color transfer inhibition in dyed textiles

Compositions according to the invention, in particular conditioning agents, may contain, for example, polymerizable betaine esters of the general formula (I)

[R ^a -X- (CH ₂ ) _k -NR ^b R ^c - (CR ^d R ^e ) ι- (C =O) -O- (R ^f -O) _m -R ⁹ ] ⁽⁺⁾ A ^H ( I) in those

R ^{a is} an ethylenically unsaturated radical containing at least one carbonyl function, for example acryloyl, methacryloyl, malemoyl or itaconoyl,

X is an oxygen atom, -N (CH ₃ ) - or -NH-,

R ^b , R ^c independently of one another are optionally branched alkyl radicals having 1 to 4 C atoms, these heteroatom substituents, in particular 0, S, N, P, being able to contain the radicals

R ^d , R ^{e are} independently selected from hydrogen (H), optionally branched alkyl radicals having 1 to 4 carbon atoms, optionally substituted aryl or benzyl radicals and -CH ₂ COOH, - CH ₂ COOR, -CH ₂ CH ₂ COOH ₁ -CH ₂ CH ₂ COOR, wherein R optionally multiple bonds containing, linear or branched and / or cyclic and / or substituted and / or halogen atoms and / or containing heteroatoms and / or carbonyl-containing hydrocarbon radicals having 1 to 18 carbon atoms or is a polyether made exclusively of ethylene or propylene or butylene or styrene oxide,

R ^{f is} an optionally multiple bonds containing branched and / or substituted and / or cyclic hydrocarbon radical having 1 to 10, preferably 2 or 3 carbon atoms, or a styrene radical or is composed solely of ethylene or propylene or butylene or styrene radicals, or a the block-containing copolymer or random copolymer is

R ^{9 is} an optionally branched, optionally double bonds, optionally cyclic hydrocarbon radical having 1 to 22 carbon atoms, wherein R ^{9 is} an optionally branched, optionally double bonds contained hydrocarbon radical when m = O and R ⁹ can be H, if m > O is, k, l independently of one another are 1 to 4, where k is preferably 2 or 3 and I is preferably 1, and m has a value between 0 to 100, preferably 0 to 40,

A ^{1 "} 'is an anion, and / or

Homopolymeπsate prepared from polymeπsierbaren betaine esters of the general formula (I) and Copolymeπsate prepared from polymeπsierbaren betaine esters of the general formula (I) and suitable comonomers of the general formula (II)

R ^w R ² C = CR ^x R ^y (II) in which

R ^x and R are ^γ H,

R ^{w is} H or CH ₃ and

R ^{z is} a group containing at least one carbonyl group, for example

C (O) OR, -C (O) NR ¹ R ", where R, R ¹ and R" are H or optionally containing multiple bonds, containing linear and branched and / or cyclic and / or substituted and / or halogen atoms and / or Heteroatom-containing and / or carbonyl-containing hydrocarbon radicals having 1 to 18 carbon atoms, or in which

R ^w and R ^x H are,

R ^γ and R ^z contain a carbonyl group-containing radicals, such as, for example, -C (O) OR,

-C (O) NR ¹ R ", wherein RR 'and R" H or optionally multiple bonds containing, linear or branched and / or cyclic aliphatic or aromatic and / or substituted and / or halogen atoms and / or hetero atoms containing hydrocarbon radicals having 1 to 18 C atoms are, or in which

R ^w , R ^x and R ^{γ are} H and

R ^{z is} an aromatic or heteroaromatic radical optionally containing halogen atom and / or heteroatom-substituted, linear and / or branched alkyl substituents, or in which

R ^w , R ^x and R ^{γ are} H and

R ^{z is} - (CH ₂ J _a -OR ¹ ", where R ¹ " is H or an optionally carbonyl-containing alkyl radical having 1 to 22 C atoms or an exclusively of ethylene or propylene or butylene or styrene oxide constructed polyether which is a block-containing or random copolymer containing said radicals and is a is O or 1

The above-mentioned polymerizable betaine esters of the formula (I) and / or the polymeric betaine esters which, in the case of the homopolymerates, are prepared from the monomeric polymerizable betaine esters of the general formula (I) and / or in the case of the copolymers of polymerizable betam esters of the general formula (I) and suitable comonomers of the general formula (II) can be used erfmdungsgemaß preferably in conditioners Particularly stable and therefore also preferably used as conditioning are the polymerizable Betainester the general formula (I) and / or the polymeric Betainester , which in the case of the homopolymerates are prepared from the monomeric polymerizable betaine esters of the general formula (I) and / or in the case of the copolymers are prepared from polymerizable betaine esters of the general formula (I) and suitable comonomers of the general formula (II) for which X is -N (CH ₃ ) - or -NH-

The agents according to the invention may preferably contain in particular conditioning agents oligomers and polymers prepared by copolymerization of from 0.5 to 100 mol% of a polymeπ- beta-esters of general formula (I) (100 mol% are homopolymers) and 0 to 99.5 mol% of an ethylenically unsaturated comonomer of general formula (II), preferably prepared by copolymerization from 20 to 70 mol% of a polymerizable betaine ester of the general formula (I), and from 30 to 80 mol% of an unsaturated co-monomer of the general formula (II), more preferably prepared by copolymerization of from 40 to 60 mol % of a polymerizable betaine ester of the general formula (I) and 60 to 40% by mole of an ethylenically unsaturated comonomer of the general formula (II) Homopolymers prepared from polymerizable betaine esters of the formula (I) are very particularly preferably used in the compositions according to the invention Homopolymeπsate offer the advantage that they carry a higher content of esterified active alcohols and also an improved elevator behavior and thus improved textile-conditioning E In the case where X = -N (CH ₃ ) - or -NH-, the polymers also exhibit a particularly good hydrolytic stability, resulting in a desired slow, that is sustained, release of the esterified perfumes Homopolymers in which k = 3 are particularly advantageous. Particularly suitable polymerizable beta-esters of the formula (I) and polymeric betamesters obtainable therefrom are those in which m = 0 and R ^{9 is} a perfume alcohol

Compositions according to the invention, in particular conditioning agents, may comprise polymerizable betam esters of the formula (I) and / or polymeric betamesters which, in the case of homopolymers, are prepared from the monomeric polymerizable betaine esters of the general formula (I) and / or in the case of copolymerizable polyesters of the betaine esters of formula (I) and suitable comonomers of the general formula (II) are prepared in which R ^{9 is} an aromatic perfume alcohol. Particularly preferred perfume alcohols are therefore phenolethanol, phenoxyethanol, 2-phenylpropanol, 3-phenylpropanol, .alpha.-methylbenzylalcohol , Amylsyl cylate, benzyl alcohol, benzyl salicylate, butyl salicylate, cyclohexylsahcylate, dimethylbenzylcarbinol, ethyl salicylate, ethylvanihn, eugenol, hexyl salicylate, isoeugenol, phenol, phenyl salicylate, thymol, vanillin, cinnamyl alcohol and 3-methyl-5-phenyl-1-pentanol

The above selection, however, is not a limitation on the aromatic perfume alcohols in question

Compositions according to the invention, in particular conditioners, may advantageously have a pH of less than or equal to 8, preferably less than 7, more preferably between 1 and 6 and in particular between 2 and 5

In one preferred embodiment, the conditioners according to the invention may additionally contain surfactants. The additional use of surfactants causes an enhancement of the conditioning properties and, moreover, contributes to improved storage stability and dispersing properties. availability or emulsifiability of the individual conditioning agent components

To improve the softness and the scavenging properties, the compositions according to the invention can comprise plasticizer components. Examples of such compounds are quaternary ammonium compounds, cationic polymers and emulsifiers, as are used in hair care compositions and also in agents for textile softening. These softening compounds are also referred to below may be contained in all inventive compositions, but in particular in the conditioners or agents with the desired plasticizing effect

Suitable examples are quaternary ammonium compounds of the formulas (III) and (IV),

(IV) wherein in (III) R and R ^{1 is} an acyclic alkyl radical having 12 to 24 carbon atoms, R ^{2 is} a saturated C ₁ -C ₄ alkyl or hydroxyalkyl radical, R ^{3 is} either R, R ¹ or R ² or is a aromatic radical X ^" is either a halide, methosulfate, methophosphate or phosphate ion and mixtures of these examples of cationic compounds of the formula (III) are Didecyldimethylammoniumchloπd, Ditalgdimethylammoniumchloπd or Dihexadecylammoniumchloπd

Compounds of the formula (IV) are what are known as esterquats. Esterquats are distinguished by excellent biodegradability. Here R 4 is an aliphatic alkyl radical

12 to 22 carbon atoms having 0, 1, 2 or 3 double bonds, R 5 is H, OH or 0 (CO) R ⁷ , R ⁶ is independently of R ^{5 is} H, OH or 0 (CO) R ⁸ , wherein R ⁷ and R ⁸ each independently represents a ahphatischen alk (en) yl group containing 12 to 22 carbon atoms having O, 1, 2 or 3 double bonds, m, n and p independently of one another have the value 1, 2 or 3. X ^"can be either a halide, methosulfate, methophosphate or phosphate ion, and mixtures thereof. Preferred are compounds which contain the group 0 (CO) R ⁷ for R ⁵ and for R ⁴ and R ⁷ contain alkyl radicals having 16 to 18 carbon atoms are particularly preferred Compounds in which R ⁶ additionally represents OH Examples of compounds of the formula (IV) are methyl-N- (2-hydroxyethyl) -N, N-di (tallow-acyl-oxy-ethyl) -ammonium methosulfate, bis (palm-to-iodo) ethyl-hydroxyethyl-methyl-ammonium-methosulfate or methyl-N, N-bis (acyl-oxy-ethyl) -N- (2-hydroxy-ethyl) -ammonium methosulfate used unsaturated compounds of formula (IV) having unsaturated alkyl chains, the acyl groups are preferred whose corresponding fatty acids have an iodine value between 5 and 80, preferably between 10 and 60 and in particular between 15 and 45 and which behaves cis / trans isomers (in% by weight) of greater than 30 70, preferably greater than 50 50 and especially greater than 70 30 have commercial common examples are available from Stepan under the tradename Stepantex ^® marketed methyl hydroxyalkyldi-alkoyloxyalkyl-methosulfates or those known under Dehyquart ^® products from Cognis or under Rewoquat ^® known products from Goldschmidt-Witco Further preferred compounds are the diesterquats corresponding to formula (V) , which are available under the name Rewoquat® W 222 LM or CR 3099 and in addition to the softness for stability and color protection

R ²¹ and R ²² are each independently an aliphatic radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds

In addition to the quaternary compounds described above, it is also possible to use other known compounds, for example quaternary imidazolium compounds of the formula (VI),

where R ^{9 is} H or a saturated alkyl radical having 1 to 4 carbon atoms, R ¹⁰ and R ¹¹ are each independently an aliphatic, saturated or unsaturated alkyl radical having 12 to 18 carbon atoms, R ^{10 may} alternatively be O (CO) R ²⁰ where R ^{20 is} an aliphatic, saturated or unsaturated alkyl radical having 12 to 18 carbon atoms, and Z is an NH group or oxygen and X ^"is an anion q can assume integer values between 1 and 4

Further suitable quaternary compounds are described by formula (VII)

R13 H

R 12 - N i - ₊ (CH ₂ V - Cl - O (CO) R 15 X - (VII)

R ^{14 is} CH ₂ -O (CO) R ¹⁶ where R ¹² , R ¹³ and R ¹⁴ independently of one another are a d_ _4- alkyl, alkenyl or hydroxyalkyl group, R ¹⁵ and R ^{16 are} each independently selected C ₈ _ ₂₈ - Alkyl group and r is a number between 0 and 5

In addition to the compounds of the formulas (III) and (IV), it is also possible to use short-chain, water-soluble, quaternary ammonium compounds such as Tπhydroxyethylmethylammoniurπ-methosulfate or the Alkyltrimethylammoniumchloπde, Dialkyldimethylammo- niumchloπde and Tπalkylme- thylammo-niumchloπde z B cetyltπmethylammonium stearyltπmethylammoniumchlorid Distearyldi-methylammonium chloride, lauryldimethylammonium chloride, lauryldimethylbenzylammonium chlorite and tricetylmethylammonium chloride

Also protonated alkylamine compounds which have plasticizing effect, as well as the non-quaternized, protonated precursors of cationic emulsifiers are suitable

Other cationic compounds which can be used according to the invention are the quaternized protein hydrolysates

Among the suitable cationic polymers pay the Polyquaternium polymers, as they are mentioned in the CTFA Cosmetic Ingredient Dictionary (The Cosmetic, Toiletry and Fragrance, Ine, 1997), in particular referred to as Merquats Polyquaternιum-6, Polyquaternιum-7, Polyquatemιum -10-polymers (Ucare Polymer IR 400, Amerchol), polyquaternium-4-copolymers, such as graft copolymers with a cellulose backbone and quaternary ammonium groups, which are bonded via allyl dimethylammonium chloride, cationic cellulose derivatives, such as cationic guar, such as guar-hyaluronic acid. droxypropyltπammoniumchlorid, and similar quaternized guar Denvate (z B cos media guar, supplier Cognis GmbH), cationic quaternary sugar derivatives (cationic Aikylpo- lyglucoside), for example the commercial product Glucquat ^® 100, according to CTFA nomenclature a "lauryl methyl Gluceth-10 Hydroxypropyl Dimonium Chloride ", copolymers of PVP and dimethylamino methacrylate, copolymers of vinylimidazole and vinylpyrrolidone, Aminosihc on-polymers and copolymers

Polyquaternized polymers (e.g. B Luviquat Care from BASF) and also cationic biopolymers based on chitin and derivatives thereof, for example, under the trade designation chitosan ^® (manufacturer Cognis) polymer obtainable

Also useful in the present invention are cationic silicone sols such as the commercially available products Q2-7224 (manufactured by Dow Corning, a stabilized trimethylsilylamido-meth-icon), Dow Corning 929 emulsion (containing a hydroxylamino-modified silicone, also referred to as amodimethicones ), SM-2059 (General Electric), SLM-55067 (manufacturer Wacker) Abιl ^® quat 3270 and 3272 (manufacturer Goldschmidt Rewo, diquartare polydimethylsiloxanes, Quaternιum-80), and Silicone quat Rewoquat ^® SQ 1 (Tegopren® ^® 6922, manufacturer Goidschmidt-Rewo)

It is likewise possible to use compounds of the formula (VIII) the alkylamidoamines can be in their quaternized or their quaternized form as shown R ¹⁷ can be an aliphatic alk (en) yl radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds s can assume values between 0 and 5 R ¹⁸ and R ¹⁹ are each independently H, C _1-4 -alkyl or hydroxyalkyl Preferred compounds are dopropyldimethylamin Fettsaureamidoamine as Stearylami- obtainable under the name Tego Amιd ^® S 18 or obtainable under the name Stepantex ^® X 9124 3-Talgamι - Dopropyl-tπmethylammo-nium methosulfate, which are characterized in addition to a good conditioning effect also by Farbubertragungsinhibierende effect and especially by their good biodegradability

Particularly preferred are alkylated quaternary ammonium compounds, of which at least one alkyl chain is interrupted by an ester group and / or amido group, in particular N-methyl-N (2-hydroxyethyl) -N, N- (dιtalgacyloxyethyl) ammonium methosulfate

Particularly suitable nonionic plasticizers are polyoxyalkylene glycol alkanoates, polybutylenes long-chain fatty acids, ethoxylated fatty acid ethanolamides, alkyl polyglycosides, in particular sorbitan mono-, di- and tertiates and fatty acid esters of polycarboxylic acids

In an agent according to the invention, preferably conditioning agents, plasticizers may be used in amounts of from 0.1 to 80% by weight, usually from 0.1 to 70% by weight, preferably from 0.2 to 60% by weight and in particular from 0.5 to 40% by weight. , in each case based on the total agent, be included

Conditioners according to the invention may preferably contain one or more anionic surfactants, in particular those which have already been described above

Conditioners according to the invention may preferably contain one or more nonionic surfactants, in particular those which have already been described above

Other suitable surfactants for all agents according to the invention, in particular for the conditioning agents, are so-called gemini surfactants. These are generally understood to mean those compounds which have two hydrophilic groups and two hydrophobic groups per molecule. These groups are generally characterized by a so-called "spacer". separated from one another This spacer is usually a carbon chain, which should be long enough that the hydrophilic groups have a sufficient distance to act independently of each other Such surfactants are generally characterized by an unusually low critical micelle concentration and the ability to greatly reduce the surface tension of the water. In exceptional cases, however, the term gemmi surfactants is understood to mean not only dicers but also trimeric surfactants

Suitable gemmi surfactants are, for example, sulfated hydroxy mixed ethers or dimer alcohol bis- and trimeryl alcohol tris sulfates and ether sulfates. End-capped dimeric and tertiary mixed ethers are distinguished, in particular, by their bi- and multifunctional nature. The end-capped surfactants mentioned have good wetting properties and are low in foam, so that they are particularly suitable for use in machine washing or cleaning processes

Gemim polyhydroxy fatty acid amides or poly-polyhydroxy fatty acid amides, as described in the relevant prior art, can also be used

Further suitable surfactants are polyhydroxy fatty acid amides of the following formula

R ²³

I R-CO-N- [Z] in the RCO for an aliphatic acyl radical having 6 to 22 carbon atoms, R ²³ for hydrogen, an alkyl or hydroxyalkyl radical having 1 to 4 carbon atoms and [Z] for a linear or branched polyhydroxyalkyl radical with 3 The polyhydroxy fatty acid amides are known substances which can usually be obtained by reductive amming of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride

The group of polyhydroxy fatty acid amides also includes compounds of the following formula

R ²⁴ -OR ²⁵

I

R-CO-N- [Z] in the R is a linear or branched alkyl or alkenyl radical having 7 to 12 carbon atoms, R ^{24 is} a linear, branched or cyclic alkyl radical or an aryl radical having 2 to 8 carbon atoms and R ^{25 is} a linear branched or cyclic alkyl radical or an aryl radical or an oxyalkyl radical having 1 to 8 carbon atoms, wherein d ^ -alkyl or phenyl radicals are preferred and [Z] is a linear polyhydroxyalkyl radical whose alkyl chain is substituted with at least two hydroxyl groups or alkoxylated preferably ethoxylated or propoxylated derivatives of this group [Z] is preferably obtained by reductive amination of a reduced sugar, for example glucose, fructose, maltose, lactose, galactose, mannose or xylose. The N-alkoxy- or N-aryloxy-substituted compounds can then be prepared, for example, by reaction with fatty acid methyl esters in the presence an alkoxide as a catalyst in the desired polyhydroxy fatty acid amides überfuhrt

The erfmdungsgemaßen agents preferably also contain amphoteric surfactants In addition to numerous mono- to tri-alkylated amine oxides, the betaines constitute an important class

Betaines are known surfactants which are predominantly produced by carboxyalkylation, preferably carboxymethylation of aminic compounds. The starting materials are preferably condensed with halocarboxylic acids or their salts, in particular with sodium chloroacetate, one mole of salt being formed per mole of betaine. For the nomenclature and especially for the distinction between betaines and "real" amphoteric surfactants, reference should be made to the relevant literature. Examples of suitable betaines are the carboxyalkylation products of secondary and in particular tertiary amines which follow formula (IX) .

R ²⁷ R ²⁶ -N- (CH ₂ ) _n COOX ¹ (IX) k - in the R ^{26 is} alkyl and / or alkenyl radicals having 6 to 22 carbon atoms, R ^{27 is} hydrogen or alkyl radicals having 1 to 4 carbon atoms, R ²⁸ Typical examples are the carboxymethylation products of hexylmethylamine, hexyldimethylamine, octyldimethylamine, decyldimethylamine, dodecylmethylamine, dodecyldimethylamine, n is 1 to 4 carbon atoms, n is a number from 1 to 6 and X ^{1 is} an alkali and / or alkaline earth metal or ammonium. Dodecylethyl- methylamine, Ci _{2 /} ryldimethylamin i ₄ -Kokosalkyldιmethylamιn, Myπstyldimethylamin, cetyldimethylamine, stearic, Stearylethyl-methyl amine, oleyl dimethyl amine, Ci _6/18 -Talgalkyldιmethylamιn and technical mixtures thereof

Also suitable are carboxyalkylation products of amidoamines which follow the formula (X),

R ²⁹ R ³¹ CO-NH- (CH ₂ ) _m -N- (CH ₂ ) _n COOX ² (X)

in which R ^{31 is} CO for an aliphatic acyl radical having 6 to 22 carbon atoms and 0 or 1 to 3 double bonds m is from 1 to 3 and R ^{29 is} R ³⁰ n and X ² are those indicated above Meanings have Typical examples are reaction products of fatty acids having 6 to 22 carbon atoms, namely caproic acid, caprylic acid, capnic acid, lauric acid, myπstin acid, palmitic acid, palmaric acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroseic acid, imino acid, linolenic acid, elaeosteann acid, arachidic acid, gadoleic acid, behenic acid and erucic acid and their technical mixtures, with N, N-Dιmethylamιnoethylamιn, N, N-dimethylaminopropylamine, N, N-Dιethylamιnoethylamιn and N, N-Dιethylamιnopropylamιn which are condensed with Natnumchloracetat Preferred is the use of a Condensation product of Cβnβ coconut fatty acid N, N-dimethylaminopropylamide with Natnumchloracetat

Furthermore suitable imidazoles which follow the formula (XI) are suitable starting materials for the acids which can be used in the context of the invention.

in which R ^{32 is} an alkyl radical having 5 to 21 carbon atoms, R ^{33 is} a hydroxyl group, an OCOR ³² or NHCOR ³² radical and m is 2 or 3 These substances are also known substances which, for example, by cychsierende Condensation of 1 or 2 moles of fatty acid with polyvalent amines, such as aminoethyl-ethanolamine (AEEA) or Diethylentπamin can be obtained The corresponding Carboxyalkylierungsprodukte represent mixtures of different open-chain betaines Typical examples are condensation products of the above fatty acids with AEEA, preferably imidazoles based on lauric acid or again Ci _{2 /} i ₄ coconut fatty acid, which are then betainisiert with Natnumchloracetat

In a preferred embodiment, the agents according to the invention are in liquid form, for example in the form of conditioning agents or liquid detergents, etc. The use of both liquid organic solvents and water can be indicated to achieve a liquid consistency In a preferred embodiment, a product of the invention which is substantially in liquid form comprises suspended solids which carry perfume (s)

Solvents that can be used in the compositions according to the invention are obtained, for example, from the group of monohydric or polyhydric alcohols, alkanolamines or glycol ethers provided that they are miscible with water in the given concentration range. Preferably, the solvents are selected from ethanol, n- or 1-propanol, butanols, glycol , Propane or butanediol, glycine, diglycol, propyl or butyl diglycol, hexylene glycol, ethylene glycol methyl ether Ethylene glycol ethyl ether, ethylene glycol monopropyl ether, ethylene glycol mono n-butyl ether, diethylene glycol methyl ether, diethylene glycol ethyl ether, propylene glycol methyl, ethyl or propyl ether, butoxy-propoxy-propanol (BPP), dipropylglycol monomethyl or ethyl ether, Dι 1-butoxyethoxy-2-propanol, 3-methyl-3-methoxybutanol, propylene glycol t-butyl ether and mixtures of these solvents

Some glycol ethers are available under the trade names Arcosolv ^® (Arco Chemical Co.) or Cellosolve ^®, carbitol ^® or Propasol ^® (Union Carbide Corp.), this includes for example ButylCarbitol® ^®, hexyl carbitol ^®, MethylCarbitol® ^®, and carbitol ^® itself, (2 - (2-Ethoxy) ethoxy) ethanol The choice of glycol ether can be easily made by a person skilled in the art on the basis of its moisture, wateriness, its weight percent of the total dispersion and the like pyrrolidone solvents, such as N-alkyl-pyrrolidones, for example N Methyl-2-pyrrolιdone or NC ₈ -C ₁₂ - alkyl pyrrolidone, or 2-Pyrrolιdon, can also be used Further preferred as the sole solvent or as part of a solvent mixture Glyceπnderivate are in particular Glyceπncarbonat

Among the alcohols which may preferably be used as cosolvents in the present invention are low molecular weight liquid polyethylene glycols, for example, polyethylene glycols having a molecular weight of 200, 300, 400 or 600. Further suitable cosolvents are other alcohols, for example (a) lower (C) ketones such as acetone and methyl ethyl ketone, (c) C ₂ -C ₄ polyols such as a diol or a triol, for example, ethylene glycol, propylene glycol, glycene, or mixtures thereof from the class of diols 1, 2-octanediol

In a preferred embodiment, the agent according to the invention contains one or more solvents from the group comprising C ₁ to C ₄ monoalcohols, C ₂ to C ₆ glycols, C ₃ to C ₁₂ glycol ethers and glycine, in particular ethanol The inventive C ₃ - to C ₁₂ glycol ethers contain alkyl or alkenyl groups having less than 10 carbon atoms, preferably up to 8, in particular up to 6, more preferably 1 to 4 and most preferably 2 to 3 carbon atoms

Preferred C ₁ - to C ₄ -monoalcohols are ethanol, n-propanol, / so-propanol and terf-butanol. Preferred C ₂ - to C ₆ -glycols are ethylene glycol, 1, 2-propylene glycol, 1, 3-propylene glycol, 1, 5-pentanediol neopentyl glycol and 1 6-hexanediol, in particular ethylene glycol and 1 2-propylene glycol Preferred C ₃ - to C ₁₂ glycol ethers are di-, tri-, tetra- and pentaethylene glycol di-tri- and tetrapropylene glycol propylene glycol monotertiarbutyl ether and propylene glycol monoethyl ether, and INCI referred to solvents butoxydiglycol butoxyethanol butoxyisopropanol, butoxypropanol, butyloctanol ethoxydiglycol ethoxyethanol, ethyl hexanediol isobutoxypropanol isopentyldiol 3-methoxybutanol methoxyethanol methoxyisopropanol and methoxymethylbutanol The composition according to the invention, preferably conditioning agent or liquid detergent, may contain one or more solvents in an amount of usually up to 40% by weight, preferably 0.1 to 30% by weight, in particular 2 to 20% by weight, particularly preferably 3 to 15% by weight %, very preferably 5 to 12% by weight, for example 5.3 or 10.6% by weight, in each case based on the total agent

In a preferred embodiment, the agent according to the invention, in particular the conditioning agent, may optionally contain one or more complexing agents

Chelating agents (INCI), also called sequestering agents, are ingredients that can complex and inactivate metal ions, for example to prevent their adverse effects on the stability or appearance of the agents, such as cloudiness Complexing of incompatible calcium and magnesium ions of the hard water The complexation of the ions of heavy metals such as iron or copper delays the oxidative decomposition of the finished agents

Suitable, for example, are the following according to INCI designated complexing agents, which are described for example in the International Cosmetic Ingredient Dictionary and Handbook Aminotπmethylene Phosphomc Acid, Beta Alanine Diacetic Acid, Calcium Disodium EDTA, Citric Acid, Cyclodextπn, Cyclohexanediamine Tetraacetic Acid, Diammonium Citrate, Diammonium EDTA , Diethylenetetamine Pentamethylene Phosphomc Acid, Dipotassium EDTA, Disodium Azacycloheptane Diphosphonate, Disodium EDTA, Disodium Pyrophosphate, EDTA, Etidronic Acid, Galactic Acid, Gluconic Acid, Glucuronic Acid, HEDTA, Hydroxypropyl Cyclodextπn, Methyl Cyclerate, Pentapotassium Tπphosphate, Pentasodium Aminotrmethylene Phosphonates, Pentasodiene Ethylenediamines Tetramethylene Phosphonates, Pentasodium Pentetates, Pentasodium Phosphates, Pentetic Acid, Phytic Acid, Potassium Citrate, Potassium EDTMP, Potassium Gluconate, Potassium Polyphosphates, Potassium Tπsphosphonomethylamine Oxides, Ribonic Acid, Sodium Chitosan Methylene Phosphonates, Sodium Citrate, Sodium Diethylenetπamine Pentamethylene Phosphonates, Sodium Dihydroxyethyl Glycolate, Sodium EDTMP, Sodium Gluceptate, Sodium Gliconate, Sodium Glycereth-1 Polyphosphate, Sodium Hexametaphosphate, Sodium Metaphosphate, Sodium Metasilicate, Sodium Phytate, Sodium Polydimethylglycinophenolsulfonates, Sodium Tπmetaphosphates, TEA-EDTA, TEA Polyphosphates Tetrahydroxyethyl Ethylenediamines Tetra-hydroxypropyl Ethylenediamines, Tetrapotassium Etidronates, Tetrapotassium Pyrophosphates, Tetrazorium EDTA, Tetrasodium Etidronates, Tetrasodium Pyrophosphates Tπpotassium EDTA, Tπso dium Dicarboxymethyl Alanmate, Trisodium EDTA Trisodium HEDTA Tπsodium NTA and trisodium phosphates

Preferred complexing agents are tertiary amines, in particular tertiary alkanolamines (aminoalcohols). alcohols) The alkanolamines have both amino and hydroxyl and / or ether groups as functional groups. Particularly preferred tertiary alkanolamines are triethanolamine and tetra-2-hydroxypropyl-ethylenediamine (N, N, N'-N'-tetrakycene). 2-hydroxy-propyl) ethylendιamιn) Particularly preferred combinations of tertiary amines with Zinkπcinoleat and one or more ethoxyher- th fatty alcohols as nonionic solubilizers and optionally solvents are described in the prior art

A particularly preferred complexing agent is etidronic acid (1-hydroxyethylidene-1, 1-diphosphonous acid, 1-hydroxyethyl-1, 1-diphosphonic acid HEDP acetophosphonic acid, INCI Etidronic Acid), including its salts. In a preferred embodiment, the compound of the invention contains Accordingly, the complexing agent etidronic acid and / or one or more of its salts

In a particular embodiment, the inventive composition contains a complexing agent combination of one or more tertiary amines and one or more further complexing agents, preferably one or more complexing agents or salts thereof, in particular from Tπethanolamin and / or tetra-2-hydroxypropylethylendιamιn and etidronic acid and / or one or more of their salts

The agent according to the invention, in particular conditioner agent, advantageously contains complexing agents in an amount of usually 0 to 20% by weight, preferably 0 1 to 15% by weight, in particular 0.5 to 10% by weight, particularly preferably 1 to 8% by weight preferably 1 5 to 6% by weight

In a further embodiment, the agent according to the invention, in particular conditioning agent, optionally contains one or more viscosity regulators, which preferably act as thickener

The viscosity of the agent may be measured using standard methods (e.g., Brookfield viscometer RVD-VII at 20 U / mιn and 2O ⁰ C, spindle 3) and is preferably in the range of 10 to 5000 mPas Preferred LIQUID to gelformige agents have viscosities from 20 to 4000 mPas, with values between 40 and 2000 mPas being particularly preferred

Suitable thickeners are inorganic or polymeric organic compounds. Mixtures of several thickeners can also be used

Examples of inorganic thickeners include polysilicic acid clay minerals such as montmorillonite zeolites, silicic acid, aluminum silicates, layered silicates and bentonites

The organic thickeners originate from the groups of natural polymers of the modified natural polymers and fully synthetic polymers

Naturally derived polymers which are used as thickeners are, for example, xanthan gum, agar agar, carrageenan, tragacanth, gum arabic, alginates, pectins, polyoses, guar gum, gellan gum, locust bean gum, starch, dextrins, gelatin and casein

Modified natural substances are derived primarily from the group of modified starches and celluloses, examples being carboxymethylcellulose and other cellulose ethers, hydroxyethyl and propylcellulose, highly etherified methylhydroxyethylcellulose and core flour ethers

A large group of thickeners, which are widely used in the most diverse fields of application, are the fully synthetic polymers, such as polyacrylic and polymethacrylic compounds, which may be crosslinked or uncrosslinked and, if necessary, cationically modified, vinyl polymers, polycarboxylic acids, polyethers, activated polyamide derivatives, castor oil derivatives, polyimines, polyamides and polyurethanes Examples of such polymers are acrylic resins, ethyl acrylate-acrylamide copolymers, acrylic acid ester-methacrylic acid ester copolymers, ethyl acrylate-acrylic acid-methacrylic acid copolymers, N-methylolmethacrylamide, maleic anhydride methyl vinyl ether Copolymers, polyether-polyol copolymers and butadiene-styrene copolymers

Further suitable thickeners are derivatives of organic acids and their alkoxide adducts, for example aryl polyglycol ethers, carboxylated nonylphenol ethoxylate derivatives, natural amalgam, diglycerol monoisostearate, nonionic ethylene oxide adducts, coconut fatty acid diethanolamide, isodenecenylsuccinic anhydride and galactomannan. Thickeners from the mentioned classes of substances are commercially available and are used, for example, among US Pat Trade name Acusol®-820 (methacrylic acid (stearyl alcohol-20-EO) ester-acrylic acid copolymer, 30% in water, Rohm & Haas), Da-pral®-GT-282-S (alkyl polyglycol ether, Akzo), Deuterol®- Polymer-11 (dicarboxylic acid-co-polymer, Schoner GmbH), Deuteron®-XG (anionic heteropolysaccharide based on β-D-glucose, D-manose, D-glucuronic acid, Schoner GmbH), Deuteron®-XN (not -ionogenic polysaccharide, Schoner GmbH), Dιcrylan® Verdιcker-0 (ethylene oxide adduct, 50% strength in water / isopropanol, Pfersse Chemie), EMA®-81 and EMA®-91 (ethylene-maleic acid anhydride copolymer, Monsanto), Verdiicker-QR-1001 (polyurethane emulsion, 19-21% strength in water / diglycol ether, Rohm & Haas), Mιrox® AM (anionic acrylic acid-acrylic acid ester copolymer dispersion, 25 % in water Stockhausen), SER-AD-FX-1100 (hydrophobic urethane polymer Servo Delden), Shellflo®-S (high-molecular polysaccharide, stabilized with formaldehyde, Shell), Shellflo®-XA (xanthan biopolymer stabilized with formaldehyde, Shell), Kelzan, Keltrol T (Kelco)

In a further preferred embodiment, the agent according to the invention, in particular conditioning agent, optionally contains one or more enzymes Particularly suitable enzymes are those from the classes of hydrolases such as proteases, esterases, lipases or lipolytic enzymes, amylases, cellulases or other glycosyl hydrolases and mixtures of the enzymes mentioned. All of these hydrolases in the wash contribute to the removal of stains such as protein -, fats or graying stains and graying in cellulases and other glycosyl hydrolases may also contribute by removing Pilhng and myofibrils for color retention and to increase the softness of the textile Oxireduktasen can be used to bleach or to inhibit the color transfer

Enzymatic active substances obtained from bacterial stocks or fungi such as Bacillus subtilis, Bacillus licheniformis, Streptomyceus griseus and Humicola insolens are particularly suitable. Proteases of the subtilin type and in particular proteases obtained from Bacillus lentus are preferably used. In this case, enzyme mixtures are used, for example Protease and amylase or protease and lipase or lipolytic enzymes or protease and cellulase or cellulase and lipase or lipolytic enzymes or protease, amylase and lipase or lipolytic enzymes or protease, lipase or lipolytic enzymes and cellulase, but especially protease and / or or lipase-containing mixtures or mixtures with lipolytic enzymes of particular interest. Examples of such lipolytic enzymes are the known cutinases. Peroxidases or oxidases have also proved to be suitable in some cases Amylases include in particular α-amylases, iso-amylases, pullulanases and pectmas. Preferred cellulases are cellobiohydrolases, endoglucanases and β-glycosides, which are also called celiotrises, or mixtures of these. Different types of cellulases are distinguished by their CMCase - and avicelase activities differ, can be adjusted by targeted mixtures of cellulases the desired activities

The enzymes may be adsorbed or coated on molded materials as molded articles in order to protect them against premature decomposition. The proportion of the enzymes, enzyme mixtures or enzyme granules may be, for example, about 0.1 to 5% by weight, preferably 0.12 to about 2% by weight. amount, based on the total amount

The agents according to the invention, in particular washing or cleaning agents, conditioners or conditioners, may optionally contain bleaches. Among the compounds which serve as bleaches and deliver H ₂ O ₂ in water, the sodium carbonate, the sodium perborate tetrahydrate and the sodium borate monohydrate have particular significance bleaching agents are, for example, peroxypyrophosphates, citrate perhydrates and _{H2 O2} -yielding peracidic salts or peracids, such as persulfates or Perschwefelsaure also useful is the urea peroxohydrate percarbamide, which may be described by the formula H ₂ N-CO-NH ₂ H ₂ O ₂ in particular, the use the means for cleaning hard surfaces for For example, in automatic dishwashing, they may optionally contain bleach from the group of organic bleaches, although their use is in principle also possible for detergents for detergents Typical organic bleaching agents are the diacyl peroxides, such as dibenzoyl peroxide Further typical organic bleaching agents are the peroxyacids, wherein Preferred representatives are the peroxybenzoic acid and its ring-substituted derivatives, such as alkylperoxybenzoic acids, but also peroxy-α-naphthoic acid and magnesium monoperphthalate, the aliphatic or substituted aliphatic peroxyacids, such as peroxylic acid, peroxystearic acid , ε-Phthahmidoperoxycapronsaure (Phthalimidoperoxyhexansure, PAP), o-Carboxybenzamιdoper- oxycapronsaure, N-nomenylamιdoperadιpιnsaure and N-Nonenylamιdopersuccιnate, and ahpha- tical and araliphatic Peroxydicarbonsau ren, such as 1, 12-Dιperoxycarbonsaure, 1, 9-Dιperoxyaze- lainsaure, Diperoxysebacinsaure, Diperoxybrassylsaure, the Diperoxyphthalsauren, 2-Decyl- dιperoxybutan-1, 4-diacid, N, N-Terephthaloyl-dι (6-aminopercapronsaure) can be used become

The bleaching agents may preferably be coated to protect against premature decomposition

Dyes can be used in the inventive means, wherein the amount of one or more dyes is to be chosen so low that after application of the agent no visible residues remain Preferably, the inventive composition is free of dyes

The agent according to the invention may preferably contain one or more antimicrobial active ingredients or preservatives in an amount of usually 0.0001 to 3% by weight, preferably 0.0001 to 2% by weight, in particular 0.0002 to 1% by weight, particularly preferably 0, 0002 to 0.2% by weight, most preferably 0.0003 to 0.1% by weight

Antimicrobial agents or preservatives are differentiated depending on antimicrobial spectrum and mechanism of action between Baktπostatika and bactericides, Fungistatika and fungicides, etc. Important substances from these groups are, for example Benzalkoniumchloπde alkylarylsulfonates, halophenols and Phenolmercuriacetat The terms antimicrobial action and antimicrobial active ingredient in the teaching of the invention Relevance Relevant antimicrobial agents are preferably selected from the groups of alcohols, amines, aldehydes, antimicrobial acids or their salts, carboxylic esters, acid amides, phenols, phenol derivatives, diphenyls, diphenylalkanes, urea derivatives, oxygen-nitrogen acetals, and formaldehyde, benzamidines, isothiazolines, phthalimide derivatives, pyridine derivatives, antimicrobial surface-active compounds, guanidines antimicrobial amphoteric compounds quinolines 1 2-dibromo-2 4-dicycanobutane iodo-2-propyl-butyl-car bamat lod lodophore Peroxo compounds, halogen compounds and any mixtures of the above

The antimicrobial active ingredient may be selected from ethanol, n-propanol, ι-propanol, 1,3-butanediol, phenoxyethanol, 1,2-propylene glycol, glycine, undecylenic acid, benzoic acid, sahacylic acid, dihydracetic acid, o-phenylphenol, N-methylmorpholine-acetonitrile (MMA), 2-benzyl-4-chlorophenol, 2,2'-methylene-bis (6-bromo-4-chlorophenol), 4,4'-dichloro-2 '-hydroxydiphenyl ether (dichlorosilane), 2,4,4'-trichloro-2'-hydroxydiphenyl ether (trichlosan), chlorhexidine, N- (4-chlorophenyl) -N- (3,4-diclorophenyl) -urea, N, N '- (1, 10-decanediyldι-1-pyrιdιnyl-4-yl) -bιs- (1-octanamιn) -dιhydro- chloride, N, N'-bis (4-chlorophenyl) -3, 12- dιιmιno-2,4,11, 13-tetraaza-tetradecandιιmmdamιd, glucopro- tamines, antimicrobial surface-active quaternary compounds, guanidines including the Bi- and Polyguani-dmen, such as 1, 6-bis (2-ethylhexyl-bιguanιdo-hexane) -dιhydrochlorιd, 1, 6-di- (N ₁ , NΛphenyldiguanido-Ns.Ns'J-hexane-tetrahydrochloride, 1, 6-di- (N ₁ , N ^ -p henyl-N ,, N ₁ -methyldιguanιdo-N ₅ , N ₅ ') -hexane-dιhydro-chloro-1, 1, 6-di- (N ₁ , N ₂ -o-chlorophenyl-diguanido- N ₅₁ N ₅ ') - hexane-dihydrochloride, 1,6-di- (N ₁ , N _T '-Σ.Θ-dichlorophenyldiguanido-N s. Ns) hexane-dihydrochloride, 1, 6-di- [N ₁ , Ni' -beta (p-) methoxyphenyl) dιguanιdo-N ₅ , N ₅ '] -hexane-dιhy-drochloπd, 1, 6-di- (N ₁ , Ni' alpha-alpha-beta -phenyldιguanιdo-N ₅ , N ₅ ') -hexan-dιhydro -chloride, 1, 6-di- (N ₁ , N ₁ '-p-nιtrophenyldιgua- nιdo-N ₅ , N ₅ ') hexane-dιhydrochloπd, omega omega-di- (N ₁ , N ₁ 'phenyldiguanido-N ₅ , N ₅ ^l ) -di-n-propyl ether dihydrochloride, omega omega-Dι- (N ₁ , N ₁ '-p-chlorophe-nyldιguanιdo-N ₅ , N ₅ ') -dι-n-propyl ether - Tetrahydrochloπd, 1, 6-di- (N ₁ , Ni'-2,4-dιchlorophenyldιguanιdo-N ₅ , N ₅ ') hexane-tetrahydrochlorιd, 1, 6-di- (N ₁ , N ₁ ' p-methylphe -nyldιguanιdo- N ₅ , N ₅ ') hexane-dιhydrochlorιd, 1, 6-Dι- (Ni, Ni'-2,4,5-tπchloro- phenyldι-guanιdo-N ₅ , N ₅ ') hexane-tetrahydrochlorιd, 1 , 6-di- [N ₁ , Ni'-alpha (p-chloro (n-phenyl) ethyldiguanamido-N ₅ , N ₅ '] hexanedihydrochloride, omega-omega-di-N _L N _T ' -p-chlorophenyl-niguano-N, N, n-yl-xylenes dihydrochloride, 1, 12 Di- (Ni, N'-p-chlorophenyldiguanido-Ns, N ₅ ') dodecane dihydrochloride, 1, 10-di- (N ₁ , N ₁ ' -phenyl-diguanido- N ₅ , N ₅ ') -decane tetrahydrochlorιd, 1, 12-di- (N ₁ , N ₁ '-phenyl-diguanido- N ₅₁ N ₅ ') dodecane-tetrahydrochloπd, 1, 6-di- (N ₁ , N ^ -o-chlorophenyldi guanido- N ₅₁ N ₅ ¹ ) hexane-dihydrochloride, 1,6-di- (N ₁ , N ₂ -o-chloro-phenyldiguanido-N ₅₁ N ₅ ') hexane-tetrahydrochloride, ethylene-bis (1-tolyl biguanide), ethylene-bis - (p-tolyl biguanide), ethylene-bιs- (3,5-dιmethylphenylbιguanιd), ethylene bιs- (p-tert-amylphenylbιguanιd), ethylene-bιs- (nonylphenylbιguanιd), ethylene-bιs- (phenylbι-guanιd) ethylene -bιs- (N-butylphenylbι-guanιd), ethylene bis (2,5-dιethoxyphenylbιguanιd), ethylene bis (2,4-dimethylphenyl biguanide), ethylene bis (o-dιphenylbιguanιd), ethylene bis (mixed amyl naphthylbigu - Anid), N-butyl ethylene -bιs- (phenylbιguanιd), Tπmethylen bis (o-tolylbιguanιd), N-butyl-trιmethyle- bιs- (phenyl biguanide) and the corresponding salts such as acetates, gluconates, Hydrochloπde, hydro-, citrates, bisulfites, fluorides, polymaleates N Cocoalkyl sarcosinates phosphites hypophosphites, perfluorooctanoates, silicates, sorbates, salicylates, maleates, tartrates, fumarates, ethylene diamine tetraacetates, iminodiacetates, cinnamates, thiocyanates, arginates, pyromellitates, tetracarboxylic butyrates, benzoates, glutarates, monofluorophosphates, perfluoropropionates and any mixtures thereof halogenated xylene and cresol derivatives, such as p-chlorometacresol or p-chloro-meta-xylene, as well as natural antimicrobial agents of vegetable origin (eg from spices or herbs), of animal and microbial origin may be preferred antimicrobial surface-active quaternary compounds, a natural antimicrobial agent of plant origin and / or a natural antimicrobial agent of animal origin, most preferably at least one natural antimicrobial agent of plant origin from the group comprising caffeine, theobromine and theophylline and essential oils such as eugenol, thymol and geraniol and / or at least one natural antimicrobial agent of animal origin from the group comprising enzymes such as milk proteins, lysozyme and lactoperoxidase and / or at least one antimicrobial surface active quaternary compound having an ammonium, sulfonium, phosphonium, iodonium or arsonium group Also substances of microbial origin, so-called Baktπozine, can be used are preferably found Glycine, Glycindeπvate formaldehyde compounds that easily formaldehyde a cleavage, formic acid and peroxides use

Suitable as antimicrobial active ingredients quaternary ammonium compounds (QAC) have already been described above is particularly suitable for example Benzalkoniumchloπd etc Benzalkoniumhalogemde and / or substituted benzalkonium halides are for example commercially available as Barquat ^® ex Lonza, Marquat® ^® ex Mason, Vanquat ^® ex Witco / Sherex and Hyamme ^® ex Lonza, and Bardac ^® ex Lonza Further commercially available antimicrobial agents are N- (3-chloroallyl) -hexamιnιumchlorιd as Dowicide ^® and Dowicil ^® ex Dow, Benzethonium- chloπd as Hyamme ^® 1622 ex Rohm & Haas, Methylbenzethoniumchloπd as Hyamme ^® 10X ex Rohm & Haas, cetylpyridinium chloride, such as Cepacolchloπd ex Merrell Labs

Furthermore, the agents according to the invention, in particular washing or cleaning agents, conditioners or conditioning agents, optionally Bugelhilfsstoffe to improve the Wassabsorptionsvermogens, the rewettability of the treated textiles and to facilitate the Bugeins the treated textiles may contain, for example Sihkonderivate be used in the formulations additionally improve the unwinding behavior of the wash-active formulations by their foam-inhibiting properties. Preferred silicone derivatives are, for example, polydialkyl or alkylaryl siloxanes in which the alkyl groups have one to five carbon atoms and are fully or partially fluorinated. Preferred silicones are polydimethylsiloxanes which may be deπvatisiert and then are amino-functional or quaternized or have Si-OH-Si-H and / or Sι-Cl bonds. The viscosities of the preferred silicones are in the range between 25 ° C. 100 and 100 000 mPas, wherein the silicones can be used in amounts of between 0 2 and 5% by weight, based on the total agent

The agents according to the invention, in particular conditioning agents, can be obtained by all known techniques known to those skilled in the art. The agents can be obtained, for example, by mixing them directly from their raw materials, if appropriate using high-shear mixing apparatuses. For liquid formulations, in particular conditioning agents, it is recommended to melt any plasticizer components present and any subsequent dispersing of the melt in a solvent, preferably water The polymerizable betaine esters of the formula (I) which can be used according to the invention or polymers which can be produced therefrom according to the invention can be incorporated into the conditioning agents by simple admixing

Preferably, the conditioning agents act as a softening agent and are usually incorporated in the afterfeed of an automatic washing machine

A further subject of the invention is a substrate, in particular conditioning substrate, which is impregnated and / or coated with an agent according to the invention, in particular conditioning agent, which therefore contains, among other constituents, the fragrance composition according to the invention

The Substratmateπal preferably consists of porous flat towelettes They may consist of a fibrous or cellular flexible material which has sufficient thermal stability for use in the dryer and sufficient amounts of Impragnierungs- or Coating agent can be used to effectively condition fabrics without appreciable bleeding or bleeding during storage. These cloths include cloths of woven and non-woven synthetic and natural fibers, felt, paper or foam, such as hydrophilic polyurethane foam

Nonwoven fabric wipers are generally used herein. Nonwovens are generally defined as adhesively bonded fibrous products having a mat or layered fibrous structure, or those comprising fibrous mats in which the fibers are randomly or randomly distributed Fibers may be natural, such as wool, silk, jute, hemp, cotton, flax, sisal, or ramie, or synthetic, such as rayon, cellulose, polyvinyl, polyolefins, polyamides, or polyesters Invention Suitable The nonwoven fabrics employed herein tend not to rupture or disintegrate due to the random or random arrangement of fibers in the unwoven fabric that impart excellent strength in all directions when used in, for example, a household washer-dryer non-woven fabrics, si WO 93/23603 are known, for example, as preferred substrates. Preferred porous and planar cleaning cloths consist of one or more fiber materials, in particular cotton, refined cotton, polyamide, polyester or mixtures thereof. The cleaning substrates in fabric form preferably have one Flat from 10 to 5000 cm ² , preferably from 50 to 2000 cm 'in particular from 100 to 1500 cm ² and more preferably from 200 to 1000 cm ² on the grammage of the material is usually between 20 and 1000 g / m *, preferably of 30 Up to 500 g / m ² and in particular from 50 to 150 g / m ^* conditioning substrates can by Soaking or impregnation or by melting the agents or conditioners of the invention are obtained on a substrate

A further subject of the invention is the use of a conditioner according to the invention or a conditioning substrate according to the invention in a textile conditioner process such as, for example, a post-pulp feed, a textile drying process and a textile drying or textile pickling process

Preferred agents according to the invention are liquid detergents, preferably containing surfactants (e) and other customary ingredients of detergents or cleaners. For example, suitable liquid detergents according to the invention can be used as thickening system, in each case based on the total agent a) 0.1 to 5% by weight of a polymeric thickener, b ) 0.5 to 7% by weight of a boron compound and c) 1 to 8% by weight of a complexing agent

In the context of the present invention, aqueous, highly viscous liquid detergents are preferred whose content of surfactant (s) is above 35% by weight

Suitable thickening agents, also called swelling agents, such as, for example, alginates or agar agar, have been described above. Preferred aqueous spray detergents contain 0.2 to 4% by weight, preferably 0.3 to 3% by weight and in particular, as thickening system 0.4 to 1.5% by weight of a polysaccharide

A preferred polymeric thickening agent is xanthan gum, a microbial anionic heteropolysaccharide produced by Xanthomonas campestris and some other species under aerobic conditions and having a molecular weight of 2 to 15 million daltons. Xanthan gum is selected from a β-1, 4- bound glucose (cellulose) with side chains The structure of the subgroups consists of glucose, mannose, glucuronic acid, acetate and pyruvate, the number of pyruvate units determining the viscosity of the xanthan gum

Liquid washing detergents according to the invention may preferably contain a boron compound which is used in amounts of from 0.5 to 7% by weight. Examples of boron compounds which can be used in the context of the present invention are boric acid, boric oxide, alkali metal borates such as ammonium, sodium and ammonium borates Kahum ortho-, meta- and pyroborates, borax in its various stages of hydration and polyborates such as alkali metal pentaborates

It is also possible to use organic boron compounds such as esters of boric acid. Reaction products of boric acid with nonionic surfactants can likewise be used

Preferred liquid detergents contain from 0.5 to 4% by weight, preferably from 0.75 to 3% by weight, and in particular 1 to 2% by weight boric acid and / or sodium tetraborate

Furthermore, liquid washing detergents according to the invention can contain from 1 to 8% by weight of a complexing agent. Particularly preferred liquid washing detergents contain citric acid or sodium citrate, with liquid detergents being preferred which contain from 2.0 to 7.5% by weight, preferably from 3.0 to 6.0% by weight % and in particular 4.0 to 5.0% by weight of sodium citrate

In addition to the constituents of the thickening system, the liquid detergents according to the invention contain surfactants (e), anionic, nonionic, cationic and / or amphoteric surfactants being used. From an application point of view, preference is given to mixtures of anionic and nonionic surfactants, the proportion of nonionic surfactants preferably being greater than the proportion of anionic surfactants The use of sugars and / or sugar derivatives such as alkyl polyglucosides or cyclodextrins can also be done

Examples Example 1:

A solid detergent was sprayed with a parfumol 1 "odor image of lemon fresh" and then supplemented with another perfume oil, representing the odor direction "care" by "post addition". In the context of the "post addition" small balls were mixed in which consisted of a core which contained a perfume 2 (cream fragrance), which was encapsulated by a polymer These balls were as good as odorless to the outside The balls were added to the detergent with very little mechanical effort

As such, the solid detergent containing the pebbles had the clearly discernible odor image "citrus scent". This was also the odor that could be experienced, for example, when the package was opened. Under the conditions of laundering in an automatic washing machine (alkaline environment, T = 40 ° C, mechanical load) lost the balls also contained their integrity, so that in the course of the washing process, the Parfumol 2 was released This was dosed in relation to Parfumol 1 significantly higher, namhch in quantity ratio 8 1 When the washing machine opened became a strong and clearly perceptible "cream" odor, which also adhered to the dry wash

Example 2:

A liquid detergent (gel) with suspended small pebbles evenly distributed in the product and neither framed nor sank was prepared in the usual way. The liquid detergent as such contained in the liquid a perfume oil 1 (citrus scent). The small pebbles consisting of a core which consisted of perfumeol 2 (cream fragrance), which was encapsulated by a polymer, were as good as odorless to the outside

As such, the liquid detergent containing the bullets had the clearly recognizable "citrus scent" odor image. This was also the smell that the consumer could perceive when the package was opened and when the agent was poured into the washing machine. Under the conditions of textile laundering now the balls also contained their integrity, due to the mechanical stress prevailing in the machine wash As a result, the parfumol 2 was released during the washing process This was in relation to perfume 1 significantly higher doses, namely in the ratio 7 1 When the washing machine was opened, unfolded immediately a very strong and clearly perceptible "cream" odor, which also adhered to the dry laundry

Example 3:

A solid, highly soluble powder detergent of fine structure was perfumed with the aid of a perfume containing iso-E-super, dihydro-floπffone, propidyl, dihydromyrcenol and acyl A perfume containing the fragrances tetrahydro-linalool, limonene, isoraldein, benzylacetone lilial and larger amounts of hedione were additionally applied to a separate, bentonite-containing carrier material

The powder detergent and the perfumed bentonite-containing carrier material were mixed together

In addition, capsules containing a perfume with a pronounced fruity smell were also mixed. The capsules were such that they could lose their integrity and release the perfume contained under the conditions of mechanical stress in an automatic textile wash

Example 4:

A gel-form detergent with an odor-neutral base was prepared. This base was provided with the odor image "1" with the aid of a perfume containing citronellol, iso-E-super, acyl, geraniol, propidyl and terpineol. Additionally, a second perfume oil "2" was added This parfumol was encapsulated. It included the fragrances linalyl acetate, dimethylbenzyl carbinyl acetate, undecabertol, isobornyl acetate, linalool, hexyl cinnamic aldehyde, lilial, xylsalicylate, OTBCA, tetrahydrogeraniol. The capsules were cautiously absorbed into the gel matrix under the conditions of mechanical stress in an automatic textile wash lost its integrity and could release the contained perfume

Example 5:

A gel-form detergent with an odor-neutral base was prepared. This base was provided with the odor image "1" with the aid of a perfume containing terahydrohnala lool, Iso-E-Super, limonene, habanohde, OTBCA, PTBCA, geranyl nitrite, hedione Parfumol added This 2 parfumol was encapsulated It included the fragrances hexylcinnamic aldehyde, linalyl acetate, ambroxan, citronellol, anisaldehyde tetrahydro- ryrenecole, C12-aldehyde, cyclopentadecanolide The capsules were gently suspended into the gel matrix. The capsules were such that they were stable under mechanical conditions Burden on an automatic textile wash could lose its integrity and release the contained perfume

Claims

 claims

Perfume-containing consumer product, characterized in that in the course of the application of the product distinguishable odor images occur, which are separately perceptible

Consumable product according to claim 1, characterized in that the distinguishable odor images occur in chronological order

Consumable product according to one of claims 1 or 2, characterized in that the distinguishable odor images are linked to the progress of the application, preferably

(a) in the case of a concrete application act and / or

(b) immediately upon completion of the application act and / or

(c) different smell patterns occur after the application act

Consumable product according to one of claims 1 to 3, characterized in that the distinguishable odor images with respect to

(a) the product itself,

(b) objects treated therewith and / or

(c) the treatment media occur

Consumable product according to one of claims 1 to 4, characterized in that it combines at least 2 functions in itself, preferably a cleaning function and a care function

Consumable product according to one of Claims 1 to 5, characterized in that it contains at least one perfume which combines odoriferous substances which are at least partially different in odor in the use of the product in such a way that distinguishable odor images occur

Consumable product according to one of claims 1 to 6, characterized in that at least two differently fragrant perfumes A and B are present which are odorily distinguishable in the course of the application of the product

Consumable product according to claim 7, characterized in that the perfumes are odorily distinguishable in chronological order

Consumable product according to claim 8, characterized in that the dominance is linked to the progression of the application, the perfumes preferably being

(a) in the case of a concrete application act and / or

(b) immediately upon completion of the application act and / or

(c) after the application act Distinctively dominant appearance Consumption product according to one of claims 7 to 9, characterized in that the perfume oils are based on

(a) the actual product,

(b) objects treated therewith and / or

(c) the treatment media are odorably distinguishable. Consumption product according to one of Claims 1 to 10, characterized in that at least one fragrance, preferably 2, 3 or more fragrances, from the list Galaxohd dihydromyrcenol, 4-tert-butylcyclohexyl acetate, gamma-iso Methylionone, tetrahydro-naphthalene, hexylcinnamaldehyde, Lihal, lmalool, amylcinnamaldehyde, 6-methyl-gamma-1-ionone, methyloleate, nerylacetate, 15-pentadecalactone, phenoxyethyhsobutyrate, phenylethylmethanoate, a-pinene, b-pillene, rose oxides, sabinene, anethole, benzoic acid 2-hydroxypentyl ester, diphenyl ether, benzophenone, cyclamen aldehyde, α-damascone, decanal, dicyclopentadiene, alcohol, allylcyclohexyl propionate, isobomyl acetate, bornyl acetate, dihydromethyl jasmonate, eucalyptol, n-dodecanol, ethyl palmitate, geraniol acetate, hexyl acetate, n-hexyl salicylate, ionone, I-limonene, methyl palmitate, 2-naphthyl methyl ketone, isopropyl propionate, rosephenone, α-terpylenol, styrallyl acetate, thujopsen, dimethylbenzylcar binyl butyrate, α-lactones, dimethyl benzyl carbinyl acetate, citronellol, 2-tert-butylcyclohexanol, caryophyllene, ethyl stearate, tartalide 2,4-hexadiened methanoazulene, methyl laurate methyl myristate, 2-methyl undecanal, mycene nonanal, nopyl acetate, 15-pentadecalactone, beta-phellandrene, Contains 3-phenyl-2-methylpropene, rosacetate, Traseohde, Widdrene and / or d-Lιmonen, Consumable product according to one of claims 1 to 11, characterized in that it contains ingredients from the field of detergents, detergents and / or cosmetics comprises consumable product according to one of claims 1 to 12, characterized in that it contains anionic surfactants, preferably in amounts of at least 0.1% by weight, based on the total product of the consumption product according to one of claims 1 to 13, characterized in that it contains nonionic surfactants, preferably in amounts of at least 0.1% by weight, based on the total product of the consumption product according to any one of claims 1 to 14, characterized in that it contains cationic surfactants, preferably in amounts of at least 0 1% by weight, based on the total product. Consumption product according to one of Claims 1 to 15, characterized in that it is substantially solid, preferably in powdered pressed or granular form Consumable product according to one of claims 1 to 15, characterized in that it is present in substantially liquid form. Consumption product according to claim 17, characterized in that it contains suspended solids, which carry perfume (s) according to one of claims 1 to 18, characterized characterized in that it comprises perfumed perfumery product according to one of Claims 1 to 19, characterized in that it contains components from the group comprising anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, acidifiers, alkalizing agents, anti-crease compounds, antibacterial substances, antioxidants, anti-redeposition agents, antistatics, builders, bleaches, bleach activators, bleach stabilizers, bleach catalysts, brighteners, cobuilders, anti-shrinkage agents, electrolytes, enzymes, colorants, colorants, dyes, color transfer inhibitors, fluorescers, fungici de, germicides, odoriferous substances, auxiliaries, hydrotropes, rinse-off agents, chelating agents, preservatives, corrosion inhibitors, optical brighteners, perfume carriers, pearlescers, pH adjusters, repellents and impregnating agents, polymers, queli- and slip-resistance agents, foam inhibitors, phyllosilicates, dirt-repellent substances , Silver protectants, silicone glycols, UV protectants, viscosity regulators, thickeners, discoloration inhibitors, grayness inhibitors, vitamins and / or softeners